docker: production image + Gitea Actions for monthly refresh
Image rebuild (skip scrape) / build (push) Failing after 1h37m12s
Image rebuild (skip scrape) / build (push) Failing after 1h37m12s
Dockerfile: self-contained image with corpus + Chroma + BM25 baked in. Drawbar's compose pulls + runs without volume mounts. Built from sources.json (labels schema), PRODUCT_NAME=crop_chem by default, HYBRID_SEARCH=true (always-on for production quality). RERANK_URL + OLLAMA_URL get set at compose time. .gitea/workflows/refresh.yml: monthly cron (1st @ 06:00 UTC) does full scrape → reindex → image push. Scrapes Bayer (~30 min) + EPA PPLS row-crop filtered (~7h). Skips reindex+push if no corpus diff. Tags pushed: :latest, :<sha12>, :corpus-<YYYY.MM.DD>. .gitea/workflows/image-only.yml: on-demand or auto on code-only pushes to main (paths: docs_mcp/, rag/, scrape/, requirements.txt, Dockerfile, sources.json). Reindexes from committed corpus, builds image, pushes. ~10 min vs ~9h full refresh. .gitignore: corpus/ now COMMITTED (4,159 labels, 265 MB of .md + sidecars). Lets image-only.yml rebuild indexes without re-scraping. chroma/ + bm25/ still gitignored (regenerable binary indexes). .dockerignore: drops venv, eval results, PLAN/README/CLAUDE.md, deploy/, .git/ — keeps the image lean. corpus + chroma + bm25 explicitly NOT in dockerignore (those go INTO the image). Co-Authored-By: Claude Opus 4.7 (1M context) <noreply@anthropic.com>
This commit is contained in:
@@ -0,0 +1,940 @@
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# DUPONT LEADOFF (MP) HERBICIDE
|
||||
|
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- EPA Reg No: **352-843**
|
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- Registrant: CORTEVA AGRISCIENCE, LLC
|
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- Signal word: Caution
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- Active ingredients: Thifensulfuron (50%); Rimsulfuron (25%)
|
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- Label accepted: 2010-12-30
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- Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/000352-00843-20101230.pdf
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|
||||
---
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||||
(
|
||||
u.s. Environmental Protection Agency
|
||||
Office of Pesticide Programs
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Registration Division (7505P)
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1200 Pennsylvania Ave., N.W.
|
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Washington, D.C. 20460
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||||
NOTICE OF PESTICIDE:
|
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(under FIFRA, as amended)
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X Registration
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_ Reregistration
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Name and Address of Registrant (include ZIP Code):
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E.!. du Pont de Nemours & Company
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1007 Market Street
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~UUU~5"VU, DE 19898
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==~~~~~~~~~~
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EPA Reg.
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Number:
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(
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352-843
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Date of Issuance:
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OEL 3D 2010
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Term ofIssuance: Unconditional
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Name of Pesticide Product:
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Dupont Leadoff (mp)
|
||||
Herbicide
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On the basis of information furnished by the registrant, the above named pesticide is hereby registered/reregistered under the Federal Insecticide,
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Fungicide and Rodenticide Act.
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Registration is in no way to be construed as an endorsement or recommendation of this product by the Agency. In order to protect health and the
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environment, the Administrator, on his motion, may at any time suspend or cancel the registration of a pesticide in accordance with the Act. The
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acceptance of any name in connection with the registration of a product under this Act is not to be construed as giving the registrant a right to
|
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exclusive use of the name or to its use if it has been covered by others.
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This product is unconditionally registered in accordance with FIFRA section 3(c)(5) provided you
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||||
agree in writing to:
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1. Submit and/or cite all data required for registration review/reregistration of your product
|
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when the Agency requires all registrants of similar products to submit data.
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2. Revise the EPA Registration Number from 352-XXX to 352-843 on the label.
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3. Add an appropriate EPA Establishment Number to the label.
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4. Add a box around the Use statements
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Signature of Approving Official: Date:
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DEC ') ,.
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GEe 3 0 2010
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EPA Form 8570·6
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( (
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Page 2
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EPA Reg. No. 352-843
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Note: Each compartment of the co-pack packaging must be identified by either "Component A" or
|
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"Component B" or the associated Ingredient Statement for that component.
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The basic formulation CSF [dated December 1, 2010] of the product referred to above,
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submitted in connection with registration under the Federal Insecticide, Fungicide, and Rodenticide
|
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Act is acceptable. The basic CSF will be added to your file.
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You will submit one (l) copy of your final printed labeling before you release the product
|
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for shipment. If these conditions are not complied with, the registration will be subject to
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cancellation in accordance with FIFRA section 6(e). A stamped copy of labeling is enclosed for
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your records. If you have any questions, please contact Hope Johnson t 703-305-5410.
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u. ~
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~
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l~ Tompkins
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. Pro~tct Manager (25)
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Herb cide Branch
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e~tration Division (7505P)
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|
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. :
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(
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<[UPON~
|
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( .-3-
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H _ l t
|
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DuPont™ LeadOrr
|
||||
M
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(mp)
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herbicide
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DRAFT LABEL
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|
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ACCbl'ltU
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||||
( with COMMENTS
|
||||
in EPA Letter Dated (
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~;:c J [) 2010
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||||
<[OPO~
|
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Under the Federal Insecticide,
|
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fungicide, and Rodenticide. ~ct
|
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as amended, for the pesticIde
|
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register,=d under EPA Reg. No.
|
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DuPont™ 35~-~'-t3
|
||||
Leadoff
|
||||
M
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(mp)
|
||||
herbicide
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For preplant and preemergence weed
|
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control in field corn
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Component A
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... A ... c ... ti .... ve ...... Tn ... flO'Tul! ... d""ie""n .. t---,,....-_-------- ....... 'b' Weight
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||||
Rimsulfuron
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||||
N-«4,6-dimethoxypyrimidin-2-yl)
|
||||
aminocarbonyl)-3-(ethylsulfonyl)-
|
||||
2-pyridinesulfonamide
|
||||
Other Ingredients
|
||||
TOTAL
|
||||
ComponentB
|
||||
25.0%
|
||||
75.0%
|
||||
100.00%
|
||||
A;.;;;.;;..cti;.;..·v;..;e;..;I;;.;.n;.gg"-r.;;.;ed;;.;i.;;.;en;.;.;t'--_________ ~By Weight
|
||||
Thifensulfuron-methyl
|
||||
MethyI3-[[[[(4-methoxy-6-methyl-l,3,
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||||
5-triazin-2-yl) amino]carbonyl]amino]
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sulfonyl]-2-thiophenecarboxylate
|
||||
Other Ingredients
|
||||
TOTAL
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50.0%
|
||||
50.0%
|
||||
100.00%
|
||||
EPA REG. NO. 352-XXX
|
||||
Nonrefillable Container
|
||||
EPA Est. No. ___ _
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||||
Net: 40 oz. Component A and 20 oz. Component B
|
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KEEP OUT OF REACH OF CHILDREN
|
||||
CAUTION.
|
||||
FIRST AID
|
||||
IF IN EYES: Hold eye open and rinse slowly and gently
|
||||
with water for 15-20 minutes. Remove contact lenses, if
|
||||
present, after the first 5 minutes, then continue rinsing eye.
|
||||
Call a poison control center or doctor for treatment advice.
|
||||
IF ON SKIN OR CLOTHING: Take off contaminated
|
||||
clothing. Rinse skin immediately with plenty of water for
|
||||
15-20 minutes. Call a poison control center or doctor for
|
||||
treatment advice.
|
||||
IF SWALLOWED: No specific intervention is indicated
|
||||
as the compound is not likely to be hazardous by
|
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ingestion. However, consult a poison control center or
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doctor if necessary.
|
||||
Have the product container or label with you when calling
|
||||
a poison control center or doctor, or going for treatment.
|
||||
You may also contact 1-800-441-3637 for emergency
|
||||
medical treatment information.
|
||||
1
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PRECAUTIONARY STATEMENTS
|
||||
HAZARD TO HUMANS
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||||
AND DOMESTIC ANIMALS
|
||||
CAUTION! Avoid contact with skin, eyes, or clothing.
|
||||
Wash thoroughly with soap and water after handling and
|
||||
before eating, drinking, chewing gum, or using tobacco.
|
||||
PERSONAL PROTECTIVE EQUIPMENT (PPE)
|
||||
Some of the materials that are chemical resistant to this
|
||||
product are listed below. If you want more options follow
|
||||
the instructions for category A on an EPA chemical
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resistant category selection chart.
|
||||
Applicators and other handlers must wear:
|
||||
Long-sleeve shirt and long pants.
|
||||
Chemical resistant gloves Category A (such as butyl
|
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rubber, natural rubber, neoprene rubber, or nitrile
|
||||
rubber), all > 14 mils.
|
||||
Shoes plus socks.
|
||||
Follow manufacturer's instructions for cleaning/maintaining
|
||||
PPE. If no such instructions for washables exist, use
|
||||
detergent and hot water. Keep and wash PPE separately
|
||||
from other laundry.
|
||||
Engineering Control Statement: When handlers use closed
|
||||
systems, enclosed cabs, or aircraft in a manner that meets the
|
||||
requirements listed in the Worker Protection Standard (WPS)
|
||||
for agricultural pesticides [40 CFR 170.240( d)( 4-6)], the
|
||||
handler PPE requirements may be reduced or modified as
|
||||
specified in the WPS.
|
||||
Important: When reduced PPE is worn because closed system
|
||||
is being used, handlers must be provided all PPE specified
|
||||
above for "Applicators and Other Handlers" and have such
|
||||
PPE immediately available for use in an emergecy, such as a
|
||||
spill or equipment breakdown.
|
||||
USER SAFETY RECOMMENDATIONS
|
||||
USERS SHOULD: Wash hands before eating, drinking,
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||||
chewing gum, using tobacco or using toilet. Remove
|
||||
clothinglPPE immediately if pesticide gets inside. Then wash
|
||||
thoroughly and put on clean clothing. Remove PPE
|
||||
immediately after handling this product. Wash the outside of
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||||
gloves before removing. As soon as possible, wash
|
||||
thoroughly and change into clean clothing.
|
||||
ENVIRONMENTAL HAZARDS
|
||||
Do not apply directly to water, or to areas where surface
|
||||
water is present, or to intertidal areas below the mean high
|
||||
water mark. Do not contaminate water by cleaning of
|
||||
equipment or disposal of wastes. Do not apply where/when
|
||||
conditions favor runoff.
|
||||
|
||||
(
|
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DIRECTIONS FOR USE
|
||||
It is a violation of Federal law to use this product in a manner
|
||||
inconsistent with its labeling.
|
||||
Do not apply this product in a way that will contact workers or
|
||||
other persons, either directly or through drift. Only protected
|
||||
handlers may be in the area during application. For any
|
||||
requirements specific to your State or Tribe, consult the agency
|
||||
in your State responsible for pesticide regulation.
|
||||
AGRICUL TURAL USE REQUIREMENTS
|
||||
Use this product only in accordance with its labeling and
|
||||
with the Worker Protection Standard, 40 CPR part 170.
|
||||
This Standard contains requirements for the protection of
|
||||
agricultural workers on farms, forests, nurseries, and
|
||||
greenhouses, and handlers of agricultural pesticides. It
|
||||
contains requirements for training, decontamination,
|
||||
notification, and emergency assistance. It also contains
|
||||
specific instructions and exceptions pertaining to the
|
||||
statements on this label about personal protective
|
||||
equipment (PPE) and restricted-entry interval. The
|
||||
requirements in this box only apply to uses of this
|
||||
product that are covered by the Worker Protection
|
||||
Standard.
|
||||
Do not enter or allow worker entry into treated areas
|
||||
during the restricted entry interval (REI) of 4 hours.
|
||||
PPE required for early entry to treated areas that is
|
||||
permitted under the Worker Protection Standard and that
|
||||
involves contact with anything that has been treated, such
|
||||
as plants, soil, or water, is:
|
||||
Coveralls.
|
||||
Chemical resistant gloves Category A (such as butyl
|
||||
rubber, natural rubber, neoprene rubber, or nitrile
|
||||
rubber), all> 14 mils.
|
||||
Shoes plus socks.
|
||||
PRODUCT INFORMATION
|
||||
DuPont™ LEADOfFT M (mp) herbicide is packaged in a
|
||||
convenient unit area package. After opening the package,
|
||||
empty the enitre contents of both compartments into the
|
||||
spray tank. LEADOFFTM (mp) herbicide must be used only
|
||||
in accordance with instructions on this label or in
|
||||
supplemental DuPont publications. DuPont will not be
|
||||
responsible for losses or damage resulting from use of this
|
||||
product in any manner not specifically specified by DuPont.
|
||||
LEADOFF (mp) herbicide is a co-pack containing the
|
||||
active ingredients rimsulfuron and thifensulfuron-methyl.
|
||||
LEADOFFTM (mp) is a selective herbicide for bumdown and
|
||||
residual control of certain annual grass and broadleaf weeds
|
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when applied preplant or preemergence to field com.
|
||||
Residual weed control is dependent on rainfall or sprinkler
|
||||
irrigation for herbicide activation. LEADOFF (mp)
|
||||
herbicide may be applied in tank mixtures with other
|
||||
herbicides labeled for use in the intended crop. However, in
|
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the case of tank mixes with other herbicides, the most
|
||||
restrictive label must be followed.
|
||||
LEADOFF (mp) is absorbed through the roots of plants,
|
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rapidly inhibiting the growth of susceptible weeds. Rainfall
|
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or sprinkler irrigation is needed to move LEADOFFTM (mp)
|
||||
into the soil. Susceptible weeds will generally not emerge
|
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from pre emergence application. In some cases susceptible
|
||||
weeds may germinate and emerge a few days after
|
||||
2
|
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(
|
||||
application, but growth then ceases and leaves become
|
||||
chlorotic three to five days after emergence. Death of leaf
|
||||
tissue and growing point will follow in some species, while
|
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others will remain green but stunted and noncompetitive.
|
||||
The herbicidal action ofLEADOFFTM (mp) may be less
|
||||
effective on weeds stressed from adverse environmental
|
||||
conditions (such as extreme temperatures or moisture),
|
||||
abnormal soil conditions, or cultural practices.
|
||||
Consult with your local DuPont representative or the
|
||||
DuPont Label Web Site (http://cropprotection.dupont.com/)
|
||||
for any additional supplemental labeling information
|
||||
relative to potential com hybrid sensitivity to LEADOFFTM
|
||||
(mp).
|
||||
APPLICATION INFORMATION
|
||||
Field Corn - Preplant-Preemergence
|
||||
Rate
|
||||
Apply LEADOfFT M (mp) at 1.5 - 2.5 ounces product per acre.
|
||||
DuPont specifies a use rate of 1.5 ounces product per acre for most
|
||||
applications. Consult DuPont technical bulletins for
|
||||
additional application information. See cumulative rimsulfuron rate
|
||||
limitations noted in this label.
|
||||
Unit Area Pack
|
||||
LEADOFFTM (mp) herbicide is a unit area pack herbicide that is
|
||||
used at the rate of 1.5 - 2.5 ounces product per acre per application.
|
||||
One 60 ounce unit area pack will treat 40 - 24 acres at the
|
||||
1.5 - 2.5 ounces product per acre application rate.
|
||||
Timing to Crop
|
||||
LEADOFF (mp) may be applied preplant after fall
|
||||
harvest through early spring, up to planting, whenever the
|
||||
ground is not frozen, to control emerged weeds and to
|
||||
provide limited residual control of early-emerging spring
|
||||
weeds.
|
||||
Additionally, LEADOFFTM (mp) may be applied anytime
|
||||
after planting, but before com emer&ence.
|
||||
Control of emerged weeds will requITe the addition of spray
|
||||
adjuvants as noted in this label.
|
||||
Sequential Application
|
||||
LEADOFFTM (mp) may be used as a sequential herbicide
|
||||
program in com. Apply LEADOFFTM (mp) for bumdown
|
||||
and residual weed control, followed by a post, in-crop
|
||||
application of DuPont™ RESOL VE® Q or DuPont™
|
||||
STEADFAST® Q herbicides. Refer to the appropriate
|
||||
product label for use restrictions, application information,
|
||||
rotational crop guidelines, and cautionary statements prior
|
||||
to application.
|
||||
Additional Control of Grasses and Broadleaves
|
||||
LEADOFF (mp) may be tank mixed with full or reduced
|
||||
rates of labeled preplantipreemergence grass and broadleaf
|
||||
herbicides such as atrazine, DuPont™ CINCH® brands and
|
||||
DuPont™ BREAKFREE® brands to provide added residual
|
||||
activity or bumdown activity on emerged weeds. Sequential
|
||||
applications of DuPont™ PREQUEL®, CINCH® brands
|
||||
and BREAKFREE® brands may also be made following
|
||||
preplant applications of LEADOFFTM (mp). Consult tank
|
||||
mix partner labeling for rate and soil-type restrictions.
|
||||
|
||||
(
|
||||
SPRAY ADJUVANTS
|
||||
For control of emerged weeds, application of LEADOFfTM
|
||||
(mp) must contain an appropriate adjuvant. If applied in
|
||||
tank mix combination with a glyphosate or glufosinate
|
||||
herbicide that contains a built-in adjuvant system, no
|
||||
additional surfactant needs to be added. Consult local
|
||||
DuPont fact sheets, technical bulletins, and service policies
|
||||
prior to using other adjuvant systems. Products must contain
|
||||
only EPA-exempt ingredients (40 CFRlOOl.
|
||||
Petroleum Crop Oil Concentrate (COC) or Modified
|
||||
Seed Oil (MSO) .
|
||||
• Apply at 1 % v/v (1 gallon per 100 gallons spray solution)
|
||||
or 2% under arid conditions.
|
||||
• MSO adjuvants may be used at 0.5% v/v (0.5 gallon per
|
||||
100 gallons spray solution) if specifically noted on
|
||||
adjuvant product labeling.
|
||||
• Oil adjuvants must contain at least 80% high quality,
|
||||
petroleum (mineral) or modified vegetable seed oil with
|
||||
at least 15% surfactant emulsifiers.
|
||||
3
|
||||
(
|
||||
Nonionic Surfactant (NIS)
|
||||
• Apply at 0.25% v/v (l qt per 100 gal spray solution).
|
||||
• Surfactant products must contain at least 60% nonionic
|
||||
surfactant with a hydrophilic/lipophilic balance (HLB)
|
||||
greater than 12.
|
||||
Ammonium Nitrogen Fertilizer
|
||||
In addition to a spray adjuvant, an ammonium nitrogen
|
||||
fertilizer may be used.
|
||||
• Use 2 qt/acre of a high-quality urea ammonium nitrate
|
||||
(UAN) such as 28%N or 32%N, or 2lb/acre of a spray
|
||||
grade ammonium sulfate (AMS).
|
||||
Special Adjuvant Types
|
||||
• Combination adjuvant products may be used at doses that
|
||||
provide the required amount of NIS and ammonium
|
||||
nitrogen fertilizer. Consult product literature for use rates
|
||||
and restrictions.
|
||||
WEEDS CONTROLLED/SUPPRESSED
|
||||
Preplant/Preemergence Tank Mixtures
|
||||
LEADOFFM Cmp) may be tank mixed with glyphosate,
|
||||
paraquat, glufosinate, 2,4-D L VE, and dicamba herbicides for
|
||||
improved control of the following emerged weed species
|
||||
when applied preplant or preemergence.
|
||||
Alfalfa,volunteer
|
||||
Barley, volunteer
|
||||
Bamyardgrass
|
||||
Bluegrass, annual
|
||||
Canada thistle
|
||||
Chamomile, false
|
||||
Chickweed, common
|
||||
Cocklebur
|
||||
Crabgrass
|
||||
Dandelion (6" diameter)
|
||||
Filaree, redstem
|
||||
Foxtail (bristly, giant, green, yellow)
|
||||
Henbit
|
||||
Johnsongrass, seedling
|
||||
Kochia
|
||||
Lambsquarters, common
|
||||
Marestail (Horseweed)
|
||||
Millet, wild proso
|
||||
Momingglory, ivyleaf
|
||||
Mustard (birds rape, black, wild)
|
||||
Nightshade, hairy
|
||||
Panicum, fall
|
||||
Pigweed (prostrate, redroot, smooth)
|
||||
Purslane, common
|
||||
Quackgrass
|
||||
Ragweed, common
|
||||
Ryegrass, Italian
|
||||
Sandbur (field, longspine)
|
||||
Shepherd's purse
|
||||
Signal grass, broadleaf
|
||||
Smartweed, Pennsylvania
|
||||
Stinkgrass
|
||||
Velvetleaf
|
||||
Wheat, volunteer
|
||||
Wild buckwheat
|
||||
Wild oat
|
||||
Wild radish
|
||||
Yellow nutsedge
|
||||
|
||||
(
|
||||
Burndown Control- DuPont™ LEADOFFTM (mp) Alone
|
||||
Grasses (1 - 2")*
|
||||
Barley, volunteer
|
||||
Barnyardgrass
|
||||
Bluegrass, annual
|
||||
Crabgrass, large (112")
|
||||
Cupgrass, woolly (I")
|
||||
Foxtail (bristly, giant, green, yellow)
|
||||
Johnsongrass, seedling*
|
||||
Millet, Wild Proso*
|
||||
Panicum, fall
|
||||
Quackgrass*
|
||||
Ryegrass, Italian *
|
||||
Shattercane (4")
|
||||
Signalgrass, broadleaf*
|
||||
S tinkgrass '"
|
||||
Wheat, volunteer
|
||||
Wild oat*
|
||||
Yellow nutsedge*
|
||||
Broadleaves (1 - 3")*
|
||||
Alfalfa, volunteer
|
||||
Canada thistle*
|
||||
Chickweed, common
|
||||
Cocklebur'"
|
||||
Dandelion (6" diameter)
|
||||
Henbit
|
||||
Kochia
|
||||
Lambsquarters, common*
|
||||
Morningglory, ivyleaf*
|
||||
Mustard, (birdsrape, black, wild)
|
||||
Nightshade, hairy*
|
||||
Pigweed, (prostrate, redroot, smooth)
|
||||
Purslane, common*
|
||||
Ragweed, common*
|
||||
Shepherd's purse
|
||||
Smartweed, Pennsylvania*
|
||||
Velvetieaf
|
||||
Wild radish
|
||||
* Partial control/suppression
|
||||
Residual Control- LEADOFFTM (mp) Alone
|
||||
Grasses
|
||||
Barnyardgrass
|
||||
Bluegrass, annual *
|
||||
Crabgrass, large*
|
||||
Foxtail (bristly, giant, green, yellow)
|
||||
Panic urn, fall *
|
||||
Signalgrass, broadleaf
|
||||
Wheat, Volunteer
|
||||
WildOat*
|
||||
* partial control/suppression
|
||||
Broadleaves
|
||||
Carpetweed*
|
||||
Chamomile, false
|
||||
Cocklebur*
|
||||
Filaree, Redstem
|
||||
Henbit
|
||||
Jimsonweed*
|
||||
Kochia (ALS-sensitive)
|
||||
Lambsquarters, common
|
||||
Marestail (Horseweed)
|
||||
Morningglory, ivyleaf*
|
||||
Mustard (birdsrape, black)
|
||||
Nightshade* (hairy, black)
|
||||
Palmer amaranth*
|
||||
Pigweed (prostrate, redroot, smooth)
|
||||
Purslane, common
|
||||
Ragweed, common*
|
||||
Russian thistle, seedling*
|
||||
Smartweed, Pennsylvania*
|
||||
Velvetleaf'"
|
||||
* Partial control/suppression
|
||||
4
|
||||
(
|
||||
Mixing Instructions
|
||||
Fertilizer Carrier Instructions
|
||||
LEADOfFT M (rnp) may be mixed with water or pre-dissolved
|
||||
in water and added to liquid fertilizer for preemergence
|
||||
application. When using liquid fertilizer as the carrier, always
|
||||
pre-slurry LEADOfFT M (mp) in water before adding fertilizer
|
||||
solutions. Add the LEADOFFTM (mp) slurry to the final
|
||||
complete liquid fertilizer mixture - do not add LEADOfFT M
|
||||
(mp) during the fertilizer mixing process.
|
||||
Always use good agitation while adding the LEADOfFT M
|
||||
(mp) slurry to liquid fertilizers and maintain good agitation
|
||||
until sprayed. When using liquid fertilizer as the carrier,
|
||||
conduct a compatibility test with all components prior to
|
||||
mixing.
|
||||
Do not use with spray additives or liquid fertilizer carriers that
|
||||
alter the pH of the spray solution below pH 5.0 or above pH
|
||||
9.0 as rapid product degradation can occur. Spray solutions of
|
||||
pH 6.0 -8.0 allow for optimum stability of LEADOfFT M
|
||||
(mp).
|
||||
Water Carrier Instructions
|
||||
I. Fill the tank 114 to 113 full of water.
|
||||
2. While agitating, add the required amount of LEADOfFT M
|
||||
(mp).
|
||||
3. Continue agitation until the LEADOFFTM (mp) is fully
|
||||
dispersed, at least 5 minutes.
|
||||
4. Once the LEADOfFT M (mp) is fully dispersed, maintain
|
||||
agitation and continue filling tank with water.
|
||||
LEADOfFT M (mp) should be thoroughly mixed with water
|
||||
before adding any other material.
|
||||
5. As the tank is filling, add tank mix partners (if desired).
|
||||
6. If the mixture is not continuously agitated, settling will
|
||||
occur. If settling occurs, thoroughly re-agitate before using.
|
||||
7. Apply LEADOfFT M (mp) spray mixture within 48 hours
|
||||
of mixing to avoid product degradation.
|
||||
If the selected companion herbicide has a ground or surface
|
||||
water advisory, consider this advisory when using the
|
||||
companion herbicide.
|
||||
Tank Mix Compatibility Testing
|
||||
Perform a jar test prior to tank mixing to ensure compatibility
|
||||
of LEADOFFTM (mp) and other pesticides. Use a clear quart
|
||||
jar with lid and mix the tank mix ingredients in their relative
|
||||
proportions. Invert the jar containing the mixture several
|
||||
times and observe the mixture for approximately 1 hour. If the
|
||||
mixture balls-ups, forms flakes, sludge, gel, oily film or
|
||||
layers, or other precipitates, it is not compatible and the tank
|
||||
mix combination should not be used.
|
||||
Broadcast Application
|
||||
Use a minimum of 15 gallons of water per acre (GPA) to
|
||||
ensure thorough coverage of the weeds and the best
|
||||
performance. Use a minimum of 10 GPA for light, scattered
|
||||
stands of weeds. For best performance, select nozzles and
|
||||
pressure that deliver MEDIUM spray droplets, as indicated,
|
||||
for example, by ASAE Standard S572. Nozzles that deliver
|
||||
COARSE spray droplets may be used to reduce drift,
|
||||
provided spray volume is increased to maintain coverage on
|
||||
small weeds.
|
||||
")
|
||||
-\ l
|
||||
|
||||
(
|
||||
For optimal product performance and minimal spray drift,
|
||||
adjust the spray boom to the lowest possible spray height
|
||||
recommended in manufacturers' specifications
|
||||
Aerial Application
|
||||
Use nozzle types and arrangements that will provide optimum
|
||||
spray distribution and maximum coverage at a minimum of 5
|
||||
GPA.
|
||||
Do not apply during a temperature inversion, when winds are
|
||||
gusty, or when conditions favor poor coverage and/or
|
||||
off target spray movement.
|
||||
Do not apply this product using aerial application in the State
|
||||
of New York.
|
||||
RESTRICTIONS/PRECAUTIONS
|
||||
• Do not apply to field com grown for seed, to popcorn,
|
||||
or to sweet corn.
|
||||
• Limit preemergence rates to 1.875 ounces LEADOFfT M (mp)
|
||||
(0.02 lbs. rimsulfuron) iffollowing with a postemergence
|
||||
application of a different product containing rimsulfuron.
|
||||
• Allow at least 60 days between preplant or preemerge
|
||||
application ofLEADOFfTM(mp) and application of
|
||||
organophosphate insecticide such as "Counter" since
|
||||
crop injury may result.
|
||||
• Allow at least 3 weeks between preemergence
|
||||
applications ofLEADOFfTM(mp) and
|
||||
postemergence applications of rimsulfuron containing
|
||||
products, such as DuPont™STEADF AST®Q, or
|
||||
DuPont™RESOL VE®Q
|
||||
• A cumulative total of 0.5 oz active rimsulfuron from
|
||||
all sources may be applied to field corn iri a single
|
||||
crop year. This includes combinations of preplant and
|
||||
preemergence applications ofLEADOFfTM(mp) and
|
||||
DuPont™PREQUEL®, as well as rimsulfuron from
|
||||
postemergence application(s) of products such as
|
||||
STEADFAST®Q or RESOL VE®Q.
|
||||
• Do not apply preemergence on corn when planted to coarse
|
||||
textured soils (sand, loamy sand or sandy.loam) with less
|
||||
than 1 % organic matter.
|
||||
• Do not apply postemergence to any crop.
|
||||
• Crop injury may occur following an application of
|
||||
LEADOFfTM(mp) if there is a prolonged period of cold
|
||||
weather and/or in conjunction with wet soils.
|
||||
• Do not graze, feed forage, grain or fodder (stover) from
|
||||
treated areas to livestock within 30 days ofLEADOFfT M
|
||||
(mp) application.
|
||||
• Do not make more than one preplant or at planting
|
||||
application to com.
|
||||
(
|
||||
'.
|
||||
Injury or loss of desirable trees or vegetation may result from
|
||||
failure to observe the following:
|
||||
- Do not apply LEADOFfT M (mp) or drain or flush
|
||||
application equipment on or near desirable trees or other
|
||||
plants, or on areas where their roots may extend, or in
|
||||
locations where the chemical may be washed or moved into
|
||||
contact with their roots.
|
||||
- Do not use on lawns, walks, driveways, tennis courts, or
|
||||
similar areas.-Prevent drift or spray to desirable plants.
|
||||
- Do not contaminate any body of water.
|
||||
- Thoroughly clean application equipment immediately after
|
||||
use.
|
||||
- (See Sprayer Cleanup section of this label for instructions).
|
||||
Soil Insecticide Interaction Information
|
||||
• LEADOFfTM(mp) may interact with certain insecticides
|
||||
applied to corn. Crop response varies with field crop,
|
||||
insecticide used, insecticide application method, and soil
|
||||
type.
|
||||
• LEADOFfTM(mp) may be applied to crops previously
|
||||
treated with "Fortress", "Aztec", or "Force" insecticides or
|
||||
other nonorganophosphate (OP) soil insecticides regardless
|
||||
of soil type.
|
||||
• PreplantiPreemergence applications ofLEADOFfTM(mp)
|
||||
to corn where an application of "Lorsban" , or "Thimet" is
|
||||
planned may cause unacceptable crop injury, especially on
|
||||
soils of less than 4% organic matter.
|
||||
|
||||
(
|
||||
6
|
||||
(
|
||||
ROTATIONAL CROP GUIDELINES
|
||||
The following rotational intervals should be observed:
|
||||
1.5 OZ PRODUCT MAXIMUM USE RATE
|
||||
Rotation Crop Interval (months)
|
||||
Com, field Anytime
|
||||
Potatoes Anytime
|
||||
Tomato 1
|
||||
Cereals, Winter (wheat) 4
|
||||
Cereals, Spring (wheat, oats, barley) 9
|
||||
Alfalfa IO
|
||||
Cotton 1
|
||||
Canola IO
|
||||
Cucumber IO
|
||||
Flax IO
|
||||
Peas IO
|
||||
Rice 10
|
||||
Red Clover 10
|
||||
Sorghum IO
|
||||
Com, pop or sweet IO
|
||||
Soybeans 10
|
||||
Sulfonylurea Tolerant Soybean (STS)
|
||||
Snap beans, dry beans IO
|
||||
Sunflower IO
|
||||
Sugarbeets IO
|
||||
Crops Not Listed 18
|
||||
2.5 OZ PRODUCT MAXIMUM USE RATE
|
||||
Rotation Crop Interval (months)
|
||||
Com, field Anytime
|
||||
Potatoes Anytime
|
||||
Tomato
|
||||
Sulfonylurea Tolerant Soybean (STS) 4
|
||||
Cereals, Winter (wheat) 4
|
||||
Cereals, Spring (wheat, oats, barley) 9
|
||||
Com (pop or sweet) IO
|
||||
Cottont IO
|
||||
Cucumber IO
|
||||
Flax IO
|
||||
Soybeans IO
|
||||
Snap beans, dry beans IO
|
||||
Sunflower IO
|
||||
Crops Not Listed 18
|
||||
tTbe rotation interval should be extended to 18 months if drought
|
||||
conditions prevail after application and before the rotational crop is
|
||||
planted, unless sprinkler irrigation has been applied and totals greater
|
||||
than 15" during the growing season.
|
||||
|
||||
(
|
||||
SPRAYER PREPARATION/CLEANUP
|
||||
The spray equipment must be cleaned before DuPont™
|
||||
LEADOfFTM (mp) is sprayed. Follow the cleanup procedures
|
||||
specified on the labels of the previously applied products. If
|
||||
no directions are provided, follow the steps outlined in the
|
||||
"After spraying LEADOfFTM (mp)" section of this label
|
||||
(below).
|
||||
It is recommended that during periods when multiple loads of
|
||||
LEADOFPM (mp) herbicide are applied, at the end of each
|
||||
day of spraying, the interior of the tank be rinsed with fresh
|
||||
water and then partially filled, and the boom and hoses
|
||||
flushed. This will prevent the buildup of dried pesticide
|
||||
deposits, which can accumulate in the application equipment.
|
||||
After spraying LEADOFFTM (mp) and before spraying
|
||||
crops other than field corn
|
||||
To avoid subsequent injury to desirable crops, thoroughly
|
||||
clean all mixing and spray equipment immediately following
|
||||
applications ofLEADOFPM (mp) as follows:
|
||||
1. Empty the tank and drain the sump completely.
|
||||
2. Spray the tank walls with clean water using a minimum
|
||||
volume of 10% of the tank volume. Circulate the water
|
||||
through the lines, including all by-pass lines, for at least
|
||||
two minutes. Flush the boom well and empty the sprayer.
|
||||
Completely drain the sump.
|
||||
3. Repeat step 2.
|
||||
4. Remove the nozzles and screens and clean separately in a
|
||||
bucket containing water.
|
||||
The rinsate solution may be applied back to the crop(s)
|
||||
recommended on this label. Do not exceed the maximum
|
||||
labeled use rate. If cleaners are used, consult the cleaner label
|
||||
for rinsate disposal instructions. If no instructions are given,
|
||||
dispose of the rinsate on site or at an approved waste disposal
|
||||
facility.
|
||||
Notes:
|
||||
1. Always start with a clean spray tank.
|
||||
2. A steam-cleaning aerial spray tank is recommended to
|
||||
facilitate the removal of any caked deposits.
|
||||
3. When LEADOFFTM (mp) is tank mixed with other
|
||||
pesticides, all cleanout procedures for each product
|
||||
should be examined and the most rigorous procedure
|
||||
should be followed.
|
||||
4. Follow any pre-cleanout guidelines recommended on
|
||||
other product labels.
|
||||
SPRAY DRIFT MANAGEMENT
|
||||
The interaction of many equipment and weather-related
|
||||
factors determines the potential for spray drift. The
|
||||
applicator is responsible for considering all these factors
|
||||
when making application decisions.
|
||||
AVOIDING SPRAY DRIFT IS THE RESPONSIBILITY
|
||||
OF THE APPLICATOR.
|
||||
Importance of Droplet Size
|
||||
The most effective way to reduce drift potential is to apply
|
||||
large droplets (>150 - 200 microns). The best drift
|
||||
management strategy is to apply the largest droplets that
|
||||
provide sufficient coverage and control. The presence of
|
||||
sensitive species nearby, the environmental conditions, and
|
||||
pest pressure may affect how an applicator balances drift
|
||||
7
|
||||
(
|
||||
control and coverage. Applying larger droplets reduces drift
|
||||
potential, but will not prevent drift if applications are made
|
||||
improperly or under unfavorable environmental conditions! .
|
||||
See Wind, Temperature and Humidity, and Temperature
|
||||
Inversions sections of this label.
|
||||
Controlling Droplet Size· General Techniques
|
||||
• Volume - Use high flow rate nozzles to apply the highest
|
||||
practical spray volume. Nozzles with higher rated flows
|
||||
produce larger droplets.
|
||||
• Pressure - Use the lower spray pressures recommended
|
||||
for the nozzle. Higher pressure reduces droplet size and
|
||||
does not improve canopy penetration. When higher flow
|
||||
rates are needed, use a higher-capacity nozzle instead of
|
||||
increasing pressure.
|
||||
• Nozzle Type - Use a nozzle type that is designed for the
|
||||
intended application. With most nozzle types, narrower
|
||||
spray angles produce larger droplets. Consider using low
|
||||
drift nozzles.
|
||||
Boom Height
|
||||
Set the boom at the lowest height that provides uniform
|
||||
coverage and reduces the exposure of droplets to
|
||||
evaporation and wind. For ground equipment, the boom
|
||||
should remain level with the crop and have minimal bounce.
|
||||
Wind
|
||||
Drift potential increases at wind speeds of less than 3 mph
|
||||
(due to inversion potential) or more than 10 mph. However,
|
||||
many factors, including droplet size and equipment type
|
||||
determine drift potential at any given wind speed. A void
|
||||
applications during gusty or windless conditions.
|
||||
Note: Local terrain can influence wind patterns. Every
|
||||
applicator should be familiar with local wind patterns and
|
||||
how they affect spray drift.
|
||||
Temperature and Humidity
|
||||
When making applications in hot and dry conditions, set up
|
||||
equipment to produce larger droplets to reduce effects of
|
||||
evaporation.
|
||||
Temperature Inversions
|
||||
Drift potential is high during a temperature inversion.
|
||||
Temperature inversions restrict vertical air mixing, which
|
||||
causes small suspended droplets to remain close to the
|
||||
ground and move laterally in a concentrated cloud.
|
||||
Temperature inversions are characterized by increasing
|
||||
temperature with altitude and are common on nights with
|
||||
limited cloud cover and light to no wind. They begin to form
|
||||
as the sun sets and often continue into the morning. Their
|
||||
presence can be indicated by ground fog; however, if fog is
|
||||
not present, inversions can also be identified by the movement
|
||||
of smoke from a ground source or an aircraft smoke
|
||||
generator. Smoke that layers and moves laterally in a
|
||||
concentrated cloud (under low wind conditions) indicates an
|
||||
inversion, while smoke that moves upward and rapidly
|
||||
dissipates indicates good vertical air mixing.
|
||||
Shielded Sprayers
|
||||
Shielding the boom or individual nozzles can reduce the
|
||||
effects of wind. However, it is the responsibility of the
|
||||
applicator to verify that the shields are preventing drift and
|
||||
not interfering with uniform deposition of the product.
|
||||
|
||||
(
|
||||
Air-Assisted (Air Blast) Field Crop Sprayers
|
||||
Air-assisted field crop sprayers carry droplets to the target via
|
||||
a downward-directed airstream. Some may reduce the
|
||||
potential for drift, but if a sprayer is unsuitable for the
|
||||
application and/or set up improperly, high drift potential can
|
||||
result. It is the responsibility of the applicator to determine
|
||||
that a sprayer is suitable for the intended application and is
|
||||
configured properly, and that drift is not occurring.
|
||||
INTEGRATED PEST MANAGEMENT
|
||||
This product may be used as part of an Integrated Pest
|
||||
Management (IPM) program that can inClude biological,
|
||||
cultural, and genetic practices aimed at preventing
|
||||
economic pest damage. IPM principles and practices
|
||||
include field scouting or other detection methods, correct
|
||||
target pest identification, population monitoring, and
|
||||
treating when target pest populations reach locally
|
||||
determined action thresholds. Consult your state cooperative
|
||||
extension service, professional consultants or other qualified
|
||||
authorities to determine appropriate action treatment
|
||||
threshold levels for treating specific pest/crop systems in
|
||||
your area.
|
||||
RESISTANCE
|
||||
When herbicides that affect the same biological site of
|
||||
action are used repeatedly over several years to control the
|
||||
same weed species in the same field, naturally-occurring
|
||||
resistant biotypes may survive a correctly applied herbicide
|
||||
treatment, propagate, and become dominant in that field.
|
||||
Adequate control of these resistant weed biotypes cannot be
|
||||
expected. If weed control is unsatisfactory, it may be
|
||||
necessary to retreat the problem area using a product
|
||||
affecting a different site of action.
|
||||
To better manage herbicide resistance through delaying the
|
||||
proliferation and possible dominance of herbicide resistant
|
||||
weed biotypes, it may be necessary to change cultural
|
||||
practices within and between crop seasons such as using a
|
||||
combination of tillage, retreatment, tank-mix partners
|
||||
and/or sequential herbicide applications that have a different
|
||||
site of action. Weed escapes that are allowed to go to seed
|
||||
will promote the spread of resistant biotypes.
|
||||
It is advisable to keep accurate records of pesticides applied
|
||||
to individual fields to help obtain information on the spread
|
||||
and dispersal of resistant biotypes. Consult your
|
||||
agricultural dealer, consultant, applicator, and/or
|
||||
appropriate state agricultural extension service
|
||||
representative for specific alternative cultural practices or
|
||||
herbicide recommendations available in your area.
|
||||
8
|
||||
(
|
||||
STORAGE AND DISPOSAL
|
||||
Do not contaminate water, food or feed by storage or
|
||||
disposal.
|
||||
Pesticide Storage: Store product in original container
|
||||
only. Do not contaminate water, other pesticides,
|
||||
fertilizer, food or feed in storage. Store in a cool, dry
|
||||
place.
|
||||
Pesticide Disposal: Do not contaminate water, food, or
|
||||
feed by disposal. Waste resulting from the use of this
|
||||
product must be disposed of on site or at an approved
|
||||
waste disposal facility.
|
||||
Container Handling:
|
||||
Nonrefillable Plastic and Metal Containers
|
||||
(Capacity Equal to or Less Than SO Pounds):
|
||||
Nonrefillable container. Do not reuse or refill this
|
||||
container. Triple rinse container (or equivalent)
|
||||
promptly after emptying. Triple rinse as follows:
|
||||
Empty the remaining contents into application
|
||||
equipment or a mix tank. Fill the container 114 full
|
||||
with water and recap. Shake for 10 seconds. Pour ,
|
||||
rinsate into application equipment or a mix tank or
|
||||
store rinsate for later use or disposal. Drain for 10
|
||||
seconds after the flow begins to drip. Repeat this
|
||||
procedure two more times. Then, for Plastic
|
||||
Containers, offer for recycling if available or puncture
|
||||
and dispose of in a sanitary landfill, or by incineration.
|
||||
Do not bum, unless allowed by state and local
|
||||
ordinances. For Metal Containers, offer for recycling if
|
||||
available or reconditioning if appropriate, or puncture
|
||||
and dispose of in a sanitary landfill, or by other
|
||||
procedures approved by state and local authorities.
|
||||
Do not transport if this container is damaged or
|
||||
leaking. If the container is damaged, leaking or
|
||||
obsolete, or in the event of a major spill, fire or other
|
||||
emergency, contact DuPont at 1-800-441-3637, day or
|
||||
night.
|
||||
NOTICE TO BUYER: Purchase of this material does not
|
||||
confer any rights under patents of countries outside of the
|
||||
United States.
|
||||
The DuPont Oval Logo, DuPont™, LEADOFFM,
|
||||
ASSURE®, BREAKFREE®, CINCH®, CLASSIC®,
|
||||
ENLlTE®, ENVIVE®, FlRSTSHOT®, PREQUEL®,
|
||||
RESOLVE®, STEADFAST® and SYNCHRONY® are
|
||||
trademarks or registered trademarks of E. I. duPont de
|
||||
Nemours and Company
|
||||
"Roundup Ready", "Roundup Original", "Roundup Weathermax"
|
||||
are registered trademarks of Monsanto Technology LLC
|
||||
"Counter", "Fortress", and "Thimet" are registered trademarks of
|
||||
Amvac Chemical Corporation
|
||||
"Lorsban" is registered trademark of Dow AgroSciences, LLC
|
||||
"Aztec" is registered trademark of Bayer CropScience
|
||||
"Force" is registered trademark of a Syngenta Group Company
|
||||
D - 1609 120210 122910 TM revision
|
||||
\ , -
|
||||
|
||||
(
|
||||
I.
|
||||
LIMITATION OF
|
||||
WARRANTY AND LIABILITY
|
||||
NOTICE: Read this Limitation of Warranty and
|
||||
Liability Before Buying or Using This Product. If the
|
||||
Terms Are Not Acceptable, Return the Product at Once,
|
||||
Unopened, and the Purchase Price Will Be Refunded.
|
||||
It is impossible to eliminate all risks associated with the
|
||||
use of this product. Such risks arise from weather
|
||||
conditions, soil factors, off target moveinent,
|
||||
unconventional farming techniques, presence of other
|
||||
materials, the manner of use or application, or other
|
||||
unknown factors, all of which are beyond the control of
|
||||
DuPont. These risks can cause: ineffectiveness of the
|
||||
product, crop injury, or injury to non-target crops or
|
||||
plants. WHEN YOU BUY OR USE THIS PRODUCT,
|
||||
YOU AGREE TO ACCEPT THESE RISKS.
|
||||
DuPont warrants that this product conforms to the
|
||||
chemical description on the label thereof and is
|
||||
reasonably fit for the purpose stated in ~he Directions for
|
||||
Use, subject to the inherent risks described above, when
|
||||
used in accordance with the Directions for Use under
|
||||
normal conditions.
|
||||
TO THE EXTENT CONSISTENT WITH
|
||||
APPLICABLE LAW, DUPONT MAKES NO OTHER
|
||||
EXPRESS OR IMPLIED WARRANTY OF FITNESS
|
||||
OR OF MERCHANTABILITY OR ANY OTHER
|
||||
EXPRESS OR IMPLIED WARRANTY. TO THE
|
||||
EXTENT CONSISTENT WITH APPLICABLE LAW,
|
||||
IN NO EVENT SHALL DUPONT OR SELLER BE
|
||||
LIABLE FOR ANY INCIDENTAL,
|
||||
CONSEQUENTIAL OR SPECIAL DAMAGES
|
||||
RESULTING FROM THE USE OR HANDLING OF
|
||||
THIS PRODUCT. BUYER'S OR USER'S
|
||||
BARGAINED-FOR EXPECTATION IS CROP
|
||||
PROTECTION. TO THE EXTENT CONSISTENT
|
||||
WITH APPLICABLE LAW, THE EXCLUSIVE
|
||||
REMEDY OF THE USER OR BUYER AND THE
|
||||
EXCLUSIVE LIABILITY OF DUPONT OR SELLER,
|
||||
FOR ANY AND ALL CLAIMS, LOSSES, INJURIES
|
||||
OR DAMAGES (INCLUDING CLAIMS BASED ON
|
||||
BREACH OF WARRANTY OR CONTRACT,
|
||||
NEGLIGENCE, TORT OR STRICT LIABILITY),
|
||||
WHETHER FROM FAILURE TO PERFORM OR
|
||||
INJURY TO CROPS OR OTHER PLANTS, AND
|
||||
RESULTING FROM THE USE OR HANDLING OF
|
||||
THIS PRODUCT, SHALL BE THE RETURN OF THE
|
||||
PURCHASE PRICE OF THE PRODUCT, OR AT THE
|
||||
ELECTION OF DUPONT OR SELLER, THE
|
||||
REPLACEMENT OF THE PRODUCT.
|
||||
To the extent consistent with applicable law that allows
|
||||
such requirement, DuPont or its Ag Retailer must have
|
||||
prompt notice of any claim so that an immediate
|
||||
inspection of buyer's or user's growing crops can be
|
||||
made. Buyer and all users shall promptly notify DuPont
|
||||
or a DuPont Ag Retailer of any claims, whether based
|
||||
on contract, negligence, strict liability, other tort or
|
||||
otherwise, or be barred from any remedy.
|
||||
This Limitation of Warranty and Liability may not be
|
||||
amended by any oral or written agreement.
|
||||
(
|
||||
For product information call: 1·888·6·DUPONT
|
||||
Internet address: http://cropprotection.dupont.com/
|
||||
© 2010 E. I. du Pont de Nemours and Company, 1007 Market Street, Wilmington, Delaware 19898.
|
||||
All rights reserved.
|
||||
9
|
||||
Reference in New Issue
Block a user