# SKIRMISH HERBICIDE - EPA Reg No: **279-3184** - Registrant: FMC CORPORATION - Signal word: Caution - Active ingredients: Chlorimuron (25%) - Label accepted: 1997-02-27 - Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/000279-03184-19970227.pdf --- (under FIFRA, as amended) U.S. ENVIRONMENTAL PROTECTION AGENCY Office of Pest;cfde Programs Registration Div!sion (75D5C) 401 "MM St~, s.w. Washington, D.C. 20460 NOTICE OF PESTICIDE: ~ Registration ____ Reregistration Name aOO Address of Reghtrant (include ZIP Code): DC Corporation Agricultural Products Group 1.735 Market street Philadelphia, PA 1.91.03 ATTN. : Dr. Callista O. chukwunenye fill 2.5 .27'1- 311f"f EPA Reg. NlMIber: Date of Issuance: 279-31.84 FEB 27_ Term of Issuance: Conditional Name of Pesticide Product: Skirmish h Herbicide T ~ongea fnlebellng differing !n albotancefithotaeeepted in conn.ctlonwith thiioreglsqatlonlllil(be .t.iJiII!fted t6' -­ _ .. _tedby the Registration Division prior to ...... Qfthe lebel In cOIIIIletce.ln.IKrf corr...,.,ndeni:eon thIs produCt·.lI .. ~ ~ff~[;;i~_.t~~~f1!.£PA regi~t".tlon ~.~i-~>, ......... ··.i. i'" .• >t ... r. '., ',> '. ,;",." . On the besil of inforMation furnfshed by the registrant, the above named pesticide is hereby registered/reregistered under the Federal Insecticide, FU'lgicide and Rodenticide Act. I Registration is In no way to be construed 8S an en:cJorsement or recomnendation of this product by the Agency. In order to protect health aOO the envirorment. the Acininistrator. on his motion, may at any time suspend or cancel the registratfon 011 • pesticide in accordance with the Act. The acceptance of any name 1n cornection with the registration of • product lIlder this Act fs not to be construed as giving the regfstrant a rfght to exclusive use of the name or to its use ff ft has been covel"eeI by others. This product is conditionally registered in accordance with FIFRA se(:. 3(C) (7)(A) provided that you: 1. Submit and/or cite all data required for registration of your producl: under FIFRA sec. 3(c)(5) when the Agency requires all registrants of similar products to submit such data; and submit acceptable responses ) required for reregistration of your product under FIFRA section 4. 2. Mak~ the following label changes: Revise the EPA Registration Number to read, "EPA Reg. No. 279-31.84". 3. Submit two copies of the revised final printed label for the record. If these conditions are not complied with, the registration will be ,subject to cancellation in accordance with FIFRA sec. 6(e). Your release for shipment of the product constitutes acceptance of these conditions. I A stamped copy of the label is enclosed for your records. '~S7i~~~tu~r~.-O~f~App-=r~O~V~i~~O~I~f7ic~i~.7l-:-------------------------------,r7oa~t~e~:----------------------------------~ -(JZ~~ It. ~ ~ Product Manager (25), Fungicide-Herbicide Branch, Registration Division (75'05C)_ ':"" torm o,"u-" \ J-/J-7/q 7 BEST AVAILABLE COPY ) ) - .. herb • J. C ide Dispersible Granules Active Ingredient By Weight Chlorimuron Ethyl Ethyl 2-[[[[( 4-chloro-6-methoxypyrimidin- 2- yl)amino )carbony I) amino )sulfonyl)benzoate 25.0% Inert Ingredients 75.0% Total 100.0% EPA Reg. No. 279-XXXX U.S. Patent No. 4,394,506 & 4,547,215 CCEPTED FEB 211991 Net Contents FMC Corporation Agricultural Products Group Philadelphia PA 19103 KEEP OUT OF REACH OF CHILDREN CAUTION PRECAUTIONARY STATEMENTS HAZARDS TO HUMANS AND DOMESTIC ANIMALS Cantlon! May irritate eyes, nose, throat and skin. May be harmful if absorbed through skin. A void breathing dnst or spray mist. Avoid contact with skin, eyes. and clothing. Get medical attention if irritation persists. STATEMENT OF PRACTICAL TREATMENT IF IN EYES: Flush eyes with plenty of water. Call a physician if irritation persists. IF ON SKIN: Wash with plenty of soap and water. Get medical attention if irritation persists. For medical emergencies Involving this product, call toll-free 1-800-331-3148. PERSONAL PROTECTIVE EQUIPMENT Applicators and other handlers must wear: Long-sleeved shirt and long pants. Waterproof gloves. Shoes plus socks. Follow manufacturer's instructions for cleaning/maintaining PPE. If no such instructions for washables, use detergent and hot water. Keep and wash PPE separately from other laundry. ENGINEERING CONTROL STATEMENTS When handlers use closed systems, enclosed cabs or aircraft in a manner that meets the requirements listed in the Worker Protection Standard (WPS) for agricultural pesticides [40 CFR part 170 Section 170.240 (d)(4-6)). the handler PPE requirements may be reduced or modified as specified in the WPS. USER SAFETY RECOMMENDATIONS USERS SHOULD: Wash hands before eating. drinking. chewing gum, using tobacco or using the toilet. ENVIRONMENTAL HAZARDS Do not apply directly to water. or to areas where surface water is present, or to intertidal areas below the mean high water mark. Do not contaminate water when disposing of equipment washwaters. 2197 Oraft '. . BEST AVAILABLE C~py ) ) -' -DIRECTIONS FOR USE It is a violation of federal law to use this product in a manner inconsistent with its labeling. Do not apply this product in a way that will contact workers or other person,. either directly or L'>rough drifL Only protected handlers may be in the area during application. For any requirements specific to your State or Tn'be, consult the agency responsible for pesticide regulation. AGRICULTURAL USE REQUIREMENTS Use this product only in accordance with its labeling and with the Worlz <>f Matador per acre Grass Height (Inches) Giant Foxtail 2-8 Wild Proso Millet 2-6 \ BEST AVAILABLE Copy H 11I!l!l'1i1 ..... ' = ) ) ) SKIRMISH + 8 oz of MATADOR per acre Grass Height (Inches) Crowfoot Grass 2-6 Fall Panicum 2-6 Green Foxtail 2-4 Bristly Foxtail 2-4 Goosegrass 2-4 Itchgrass 2-8 Field Sandbur 2-6 Sprangletop 2-6 Volunteer Cereals 2-6 Wild Oats 2-6 Witchgrass 2-6 SKIRMISH + 10 oz of MATADOR per acre Grass Height (Inches) Junglerice 2-6 Jolmsongrass. Rhizome 10-24 For best results apply Skinnish 7 days before or 1 day after the grass herbicide. Refer to the grass herbicide label for precrutions and specific use information. Under certain conditions SKIRMISH may reduce the activity of the grass herbicide. The broadleaf activity of SKIRMISH will not be affected. .. . 4 SKIRMISH + Cobra' Waterhemp and Nightshade Prickly Sida and Hemp Sesbania For control of Prickly Sida and Hemp Sesbania use a tank mix at the rate of 112 oz SKIRMISH and 8.0 to 12.5 fl oz of "Cobra"per acre. Use the higher rate of "Cobra" when Prickly Sida and Hemp Sesbania are heavy or Prickly Sida and Hemp Sesbania approach the maximum size of I" or 4". Include a nonionic surfactant at I to 2 pt per 100 gal of spray solution (minimum of 0.125% v/v actual snrfactant). Do not use crop oil concentrate when tank mixing SKIRMISH + "Cobra" at these rates. • Tank mix applications of SKIRMISH + "Cobra" may not control weeds listed on the Skinnish label as completely as applications of Skinnish alone. Soybean Precautions • Temporary leaf yellowing andlor retardation of soybean growth may occur following application of SKIRMISH. These effects will generally be most evident 5-7 days after application to soybeans under stress. Under favorable soybean growing conditions, the crop will quickly recover. Do not graze treated fields or harvest for forage or hay. • SKIRMISH should not be used on soils with a history of nutrient deficiency (such as iron chlorosis). Crop injnry may occur. • Do not apply to land that has been or will be treated with DuPont GLEAN". ALL yo. or FINESSE" Herbicides in the states of Kansas, Nebraska, North Dakota, or South Dakota without carefully observing the rotational crop intervals for those products. Do not tank mix SKIRMISH with organophosphate insecticides or apply Skirmish within 14 days before or after an application of an organophosphate insecticide. as severe crop injnry may occur. MIXING INSTRUCTIONS FOR SOYBEANS The following steps should be followed when preparing to spray SKIRMISH: I. Fill the spray tank 114 to 1/3 full of water. 2. While agitating. add the required amount of SKIRJ,,!lSH. 3. Continue adequate agitation. 4;SKIRMISHsoouldbetliorotighly riiiXedwith 'watefiii· ! "~ thCs "'"tank befuCe addiii .. an otfiei-materialTm Oi-de.i:; ·7 •. ~::t:. .._ .,'" g, Y".," .. '. __ ~_, .. _ ...... 'I i@llc·~~~~ci'te~I~~A·~ !-:!?:°2i?~':"!'~.'!-~!'~,z~:c 'i ~\.i!ltrogen.:..oaseu 1e!'h lzer). g.!t?-'tlOIns.--~equ~(~u ltions below) Region A: The states ofIowa (Fields located within the boundaries ofthe Clarion-Nicollet-Webster and Hamburg­ Ida-Monona soil associations or fields located within the historic flood plain of the Missouri River.), Minnesota (Fields south of Route 27 or east of Route 71.), Nebraska (Fields north of Route 30 or west of Route 281.), New York, South Dakota, and Wisconsin. Region B: The states of Delaware, Illinois, Indiana, Iowa (Fields located outside the boundaries of the Clarion­ Nicollet-Webster and Hamburg-rda-Monona soil associations and fields located outside the historic flood plain of the Missouri River.), Kansas, Kentucky. Maryland, Michigan (Fields north of Interstate 96 or per supplemental labeling.), Missouri (Except the Bootheel), Nebraska (Fields south of Route 30 and east of Route 281.), New Jersey, Ohio, Pennsylvania, Virginia, and West Virginia. Region C: The states of Alabama (Except the ''Black Belt" where soil pH must be less than 7.0.), Arkansas, Florid., Georgia, Louisiana, Missouri (Bootheel region only), Mississippi (Except the "Black Belt" where soil pH must be less than 7.0.), North Carolina, Oklahoma, South Carolina, Tennessee, Texas (Fields east of Route 183.), , BEST AVAILABLE COpy . '\ , .... ) '.: .: ) . - . Follow Recrop Interval I if: • The field is located in a "Region A" state (all pH soils) AND • A single application of SKIRMISH with a total rate of no more than 1I3 ozJacre for the growing season applied. Follow Recrop Interval 2 if: • The field is located in a "Region B" state (all pH soils) AND, ElTIIER • A maximum of 2 applications of SKIRMISH with a total rate of no more than 1.0 ozJacre for the growing season are applied. Follow Recrop Interval 2 if: • The field is located in a "Region B" state with soil pH 7.0 or less AND, EITIIER A maximum of 2 applications of SKIRMISH with a total rate of no more than 1.5 ozJacre for the growing season are applied. Follow Recrop Interval 3 if: • The field is located in a "Region C' state (all pH soils except those with pH greater than 7.0 in the Black Belt region of Alabama and Mississippi) AND, EITIIER • A maximum of 2 applications of SKIRMISH with a total rate of no more than 1.5 ozJacre for the growing season are applied. .. 6 Crop Intervall Interval 2 lnterval'3 Soybeans Anytime Cereal Grains Pasture Grasses (such as Fescue and Ryegrass) Dry Beans Kidney Beans Peas Snap Reans Field Com (IR) Field Com" (States in Regions A and B) Field Corn" (States of AR, MO (Bootheel only), NC, OK, 1N, and TX) Field Corn" (States of AL, Fl., GA, LA, MS, and SC) Sweet Com+ (States in Region A) Popcorn Sorghum Tobacco (transplant) Tomato (transplant) Peanuts Rice Cotton Alfalfa Clover Cucumber Sunflower Watermelon Cabbage Canola (Rapeseed) Flax Lentils Mustard Pumpkins Carrots Onions Potatoes Sugar Beets Any crop not listed 3 9 8 9 9 15 6 9 9 9 9 18 30 Anytime Anytime 3 3 9 9 8 7 9 8 7 9 9 15 6 15 9 9 8 12 9 18 18 18 18 30 30 .. If SKlR.\I(ISH is .l~plied after August 1. extent! rotational crop intervals 2 months for J..!fuJ.fa. clover. com (non·1R), cotton. popcorn, rice, sorghum,. tobacco. and tomato. nThe term "Field Com" is defined to include only that corn grown for grain orsilag'! or for seed corn relative to the Rotiltiona! Crop Guidelines section of !his label. + Rotational crop intervals ilre for processing Sweet Com varieties only. The rotational crop interval for Olher Sweet Corn varieries is 1 S. months. \ BEST AVAILABLE Copy ) ' .. THE IMPORTANCE OF SOIL PH Soil pH varies greatly, even within the same field. pH variations as much as 2 pH units are common. Composite soil samples taken across an entire field. such as those samples taken for soil fertility recommendations, may not detect areas of high pH. Subsarnpling is recommended for areas likely to have pH values higher than the field average. The following is a non-inclusive list of potential high pH areas where subsampling is recommended. Where different soil types are evident within a field, sample soil types separately. • Where conditions vary within a field, sample areas separately, such as: areas bordered by limestone gravel roads, river bottoms subject to flooding, - low areas in hardpan soils where evaporative ponds may occur, - eroded hillsides, - along drain tile lines, and - areas where drainage ditch spoil has been spread. Where lime has not been deeply incorporated, soil may exhibit significantly higher pH values in the upper 3 inches of soil. Composite soil samples taken at a 6-8 inch depth may not reflect the elevated pH near the surface. In these cases shallow sampling, the upper 3 inches, is ad vised. Determine soil pH by laboratory analysis using a I: I soil:water suspension. SPRAYER PREPARATION AND CLEANUP Prior to application of SKIRMISH, start with clean, well maintained application equipment. Immediately following application, thoroughly clean all application equipment. Postponing action, even for a few hours, only makes effective cleanup more difficult. Failure to clean spraying equipment thoroughly may result in injury to subsequently sprayed crops. When spraying multiple loads of SKIRMISH over an extended period of time, rinse the equipment with clean water at the end of the day. Leave water in the equipment overnight to prevent deposits from drying on surfaces. When applications of SKIRMISH are completed and prior to ) using the sprayer and associated equipment for other products or for crops other th,n soybeans, thoroughly clean . the equipment using the procedure below. STEP I: Drain spray equipment. Thoroughly rinse sprayer, and.flush hoses, boom and nozzles with clean water. Loosen and physically remove visible deposits. STEP 2. Fill the sprayer with clean water and add household ammonia (one gallon of 3% active for every 100 gallons of water). Rush hoses, boom and nozzles. Tum off the boom and tOP off the~anK with clean water. Circulate through the sprayir.g system for 15 minutes. Rush the hoses. boom and nozzles with the cleaning solution. Drain the tank. STEP 3. Remove and clean nozzle. screens and strainers in a bucket of fresh cleaner and water. STEP 4. Repeat STEP 2. STEP 5. 'Thoroughly rinse the sprayer, hoses, boom and nozzles with clean water. several times. Clean all other associated application equipment. Take all necessary safety precautions when cleaning equipment. Do not clean near wells, water sources or near desirable vegetation. Dispose of waste rinse water in accordance"with local regulations. 1 SPRAY DRIFT MANAGEMENT The interaction of many equipment and weather-related factors determines the potential for spray drift. The applicator is responsible for considering all these factors when making appIication decisions. A VOlDll'150 - 200 microns). The hest drift management strategy is to apply the largest droplets that provide sufficient coverage and control. The presence of sensitive species nearby. the environmental conditions, and pest pressure may affect how an applicator balances drift control and coverage. APPLYING LARGER DROPLETS REDUCES DRlFT POTENTIAL, BUT WILL NOT PREVENT DRlFT IF APPUCA TrONS ARE MADE Th1PROPERL Y OR UNDER UNFAVORABLE ENVIRONMENTAL CONDmONS! See Wind, Temperature and Humidity, and Temperature Inversloru, sections of this label. Controlling Droplet Size - General Techniques • Volnme - Use high flow rate nozzles to apply the highest practical spray volume. Nozzles with higher rated flows produce larger droplets. Pressure - Use the lower spray pressures recommended for the nozzle. Higher pressure reduces droplet size and does not improve canopy penetration. WHEN HIGHER FLOW RATES ARE NEEDED, USE A HIGHER­ CAPACITY NOZZLE INSTEAD OF INCREASING PRESSURE. • Nozzle Type - Use a nozzle type that is designed for the intended application. With most nozzle types, narrower spray angles produce larger droplets. Consider using low­ drift nozzles. , BEST AVAILABLE Copy ) ... Controlling Droplet Size - Aircraft .. Number of Nozzles - Use the minimum number of nozzles with the highest flow rate that provide uniform coverage. Nozzle Orientation - Orienting nozzles so that t;"e spray is emitted backwards, parallel to the airstream will produce larger droplets than other orientations. Nozzle Type - Solid slream nozzles (such as disc and core with swirl plate removed) oriented straight back produce larger droplets than other nozzle types. • Boom Length - The boom length should not exceed 3/4 of the wing or rotor length - longer booms increase drift potential. • Application Height - Application more than 10 ft above the canopy increases the potential for spray drift. BOOM HEIGHT Setting the boom at the lowest labeled beight (if specified) which provides uniform coverage reduces the exposure of droplets to evaporation and wind. For ground equipment, the boom should remain level with the crop and have minimal bounce. WIND Drift potential increases at wind speeds ofless than 3 mph (due to inversion potential) or more than 10 mph. However, many factors, including droplet size and equipment type determine drift potential at any given wind speed. AVOID GUSTY OR WINDLESS CONDmONS. Note: Local terrain can influence wind patterns. Every applicator should be familiar with local wind patterns and how they affect spray drift. . TEMPERATURE AND HUMIDITY When making applications in hot and dry conditions, set up equipment to produce larger droplets to reduce effects of evaporation. TEMPERATURE INVERSIONS Drift potential is high during a temperature inversion. Temperature inversions restrict vertical air mixing. which causes small suspended droplets to remain close to the ground and move laterally in a concentrated cloud. Temperature inversions are characterized by increasing temperature with altitude and are common on nights with \ limited cloud cover and light to no wind. They begin to ,/ form as the sun sets and often continue into the morning. ) Their presence can be indicated by ground fog; however, if fog is oot present, inversions can also be identified by the movement of smoke from a ground source or an aircraft smoke generator. Smoke that layers and moves laterally in a concentrated doud (under low wind conditions) indicates an inversion, while smoke that moves upward and rapidly dissipates indicates good vertical air mixing. SHIELDED SPRAYERS Shielding rhe boom or individual nozzle:>. can reduce the df~cts of wind. However, it is the responsibility r:-f the applicator to verify that the shields are preventing drift and not interfering with uniform deposition of the product. '. . II AIR ASSISTED (AIR BLAST) FIELD CROP SPRAYERS Air assisted field crop sprayers carry droplets to the target via a downward directed air stream.. Some may reduce the potential for drift, but if a sprayer is unsuitable for the application andlor set up improperly, high drift potential can result. It is the responsibility of the applicator to. determine that a sprayer is suitable fo.r the intended application, is configured properly, and that drift is not occurring. Note: Air assisted field sprayers can affect product perfo.rmance by affecting spray co.verage and canopy penetration. Consult the application equipment section of this label to determine if use of an air assisted sprayer is recommended. IMPORTANT PRECAUTIONS Do not apply this product through any type of irrigation system. Injmy to or loss of desirable trees or vegetatio.n may result from failure to. observe the follo.wing: • Do no.t apply SKIRMlSH or drain or flush equipment on or near desirable trees or other plants, on areas where their roots may extend, or in locations where the chemical may be washed or moved into contact with their roots. • Do not use on lawns, walks, driveways. tennis courts, or similar areas. • Prevent spray drift to. desirable plants. • Do not contaminate any body of water. • Do not mixIIoad, or use within 50 feet of all wells including abandoned wells, drainage wells, and sink holes . • Avo.id storage o.f pesticides near well sites. • Keep SKIRMISH from coming in contact with fertilizers, insecticides, fungicides, and seeds during sto.rage. • Thoroughly clean all application equipment immediately after use and prior to spraying crops other than soybeans or peanuts. • Calibrate sprayers only with clean water away from the well site. INFORMATION ON RESISTANT WEEDS When herbicides with the same mode of action are used repeatedly over several years to control the same weed species in the same field, naturally-occurring resistant weed bio.types may survive a correctly applied herbicide Ireatment, propagate, and become dominant in that field. These resistant weed biotypes may not be adequately controlled. Cultural practices such as tillage, preventing weed escapes from going to seed, and using herbicides with different modes of action within and between crop seasons can aid in delaying the proliferation and possible dominance of he:bicide resistant weed biotypes. \ BEST AVAILABLE Copy -------------------------------------------------------------------------------------------------------~-~~~--~---, I().rf.c ) ) , .. STORAGE AND DISPOSAL Storage: Store product in original container only. Do not contaminate water, other pesticides, fertilizer. food or feed in storage. Product Disposal: Do not contaminate water, food or feed by disposal. Wastes resulting from the use of this product may be disposed of on site or at an approved waste disposal facility. Container Disposal: Triple rinse (or equivalent). Then offer the container for recycling or reconditioning. or puncture and dispose of in a sanitary landfill, or incinerator. Or, if allowed by state and local authorities, the container can be burned on site. If burned, stay out of smoke. Notice to Buyer: Purchase of this material does not confer any rights under patents of countries outside of the United States. Use of this quantity of purchased Skirmish herbicide is permitted under claim 24 of U.S. Patent 5,084,082. Registered trademark of Valent USA Corporation Registered trademark of DuPont '. . Dealers Should Sell in Original Packages Only. Terms of Sale or Use: On purchase of this product buyer and user agree to the following conditions: \Varranty: FMC makes no warranty, expressed or implied. concerning the use of this product other than indicated on the label. Except as so warranted the product is sold as is. Buyer and user assume all risk of use andlor handli ng and/or storage of this material when such use andJ or handling and/or storage is contrary to label instructions. Directions and Recommendations: Follow directions carefully. Timing and method of application, weather and crop conditions, mixture with other chemicals not specifically recommended and other influencing factors in the use of this product are beyond the control of the seller and are assumed by the buyer at his own risk. Use of Prodnct: FMC's recommendations for the use of this product are based upon tests believed to be reliable. The use of this product being beyond the control of the manufacturer, no guarantee, expressed or implied is made as to the effects of such or the results to be obtained if not used in accordance with directions or established safe practice. Damages: Buyer's or user~s exclusive remedy for damages for breach of warranty or negligence shall be limited to direct damages not exceeding the purchase price paid and shall not include incidental or consequential damages. BEST AVAILABLE Copy