# HELENA 4LB. METHYL PARATHION - EPA Reg No: **5905-528** - Registrant: HELENA AGRI-ENTERPRISES, LLC, D/B/A HELENA CHEMICAL COMP - Signal word: Danger - Active ingredients: Methyl parathion (45.11%) - Label accepted: 1997-06-03 - Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/005905-00528-19970603.pdf --- ) 5105-521 '.-3- 11 11 - . - - UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Judy Oldham Helena Chemical Company 6705 Poplar Avenue, Suite 500 Memphis, Tennessee 3,8119 Dear Ms. Oldham: .. Subject: Labeling Amendment 4 lb. Methyl Parathion EPA Reg. No. 5905-528 WASHINGTON, D.C. 20460 JUN 031997 . Your submission dated March 17, 1997 The labeling amendment referred to above submitted in connection with registration under the Federal Insecticide, Fungicide, and Rodenticide Act, as amended, has been received and reviewed, and the following are the Agency's comments: 1. All products distributed or sold under 4 lb. Methyl Parathion EC (EPA Reg. No.5905~528) must be packaged in labeled containers bearing a unique identification number that will remain on the label or container atall times. 2. The label you submitted is acceptable providing you make the following changes and/or address the followil)g comments: a .. Change the application rate for treatment of leafhoppers and armyworms (to 3rd instar) on . Rye and Wh~at.r~£m.~ y,.ts.» Y>.pints. ",.~._._. .._.,_.~_ ... -,'~-"~ , .. " 3. Submit three copies of the revised final printed label for the record. A stamped copy of the labeling is enclosed for your records. Enclosures Sincerely, ~M?~ Larry Fried . Insecticide-Rodenticide Branch Registration Divisi.on (7505C) " ) ) RESTRICTED USE PESTICIDE Due to Very High Acute Toxicity to Humans and Birds ForretaiJ sale to and u~-,~nl~Ey~ertified applicatorsotpersons under their direct supervision and only for those uses covered by the certified applicator's certification. Direct supervision for this product is defined as the certified applicator being physically present during application, mix iog, loading, repair and cleaning of application equipment. Commercial certified applicators must also ~nsure that aU persons involved in these activities are informed of the precautionary statements . 4 LB. METHYL PARATffi()N EMULSIFIABLE INSECTICIDE CONCENTRATE ACTIVE INGREDIENT: O,O-dimethyl O-p-nitrophenyl phosphorothioate* ..................................... . Related Compounds ............... : .... , ...................................................•.. INERT INGREDIENTS: ...................................................................•................. TOTAL ...................................................................................... . J gallon of 4 LB. METHYL PARATHION contains 4 pounds of Methyl Parathion. "'Methyl Parathion. ... -- 43.40% 1.71% 54.89% 100.00% DANGER POISON PELIGRO KEEP OUT OF REACH OF CHILDREN ORGANOPHOSPHATE - - CAN KILL YOU.lF SWALLOWED: This product can kill you if swallowed even in small amounts; spray mist may be fatal if swallowed. CAN KILL YOU BY SKIN CONTACT: This product can kill you if touched by hands or spilled or splashed on skin, in eyes or on clothing (liquid goes through clothes). CAN KILL YOU IF BREA TIlED: This product can kill you if vapor, spray mist are breathed. Si usted no entiende la etiqueta, busque a alquien para que se la explique a usted en detaIle. (lfyou do not understand the label, [md someone to explain it to you in detail.) SPECIAL INSTRtiCTIONS FOR RESTRICTEDtiSE PESTICIDE RETAILERS: In addition to any other required records, restricted use pesticide retailers must record at the time of sale the unique container identification number on this label or container and .the identity Of the purchaser of the container. EPA REG. NO . .1905:52"8 EPA EST. NO:: Firstletters of product· batch code indicate producing establishment~=~ AC{.~5-GA-I=CG.·5905=AR~r:::,WA.- . NET CQN1EN'T~: "lIh cO~~_r A-I=KC 5905-JA-I =DI in EPA Letbl't':D'lIiOd-" . ,JUl'! 031997 MANUFACTURED BY: Toder the Federal wseetielde, ~Ullt;iddc. and Rodenticide Act ~ nmended, for the peslid«le :egis,ered under EPA Reg. ~~ 5]O$"'":" $j..« HELENA CHEMICAL COMPANY MEMPHIS, TN 38119 Bar C".ktJr uniqL.() ldMtify­ ingnumber ) ) PRECAUTIONARY STATEMENTS HAZARDS TO HUMANS AND DOMESTIC ANIMALS DANGER WORKER SAFETY RULES 2 The National Pesticide T elecommunicationNetwork is available for recommendations regarding poisoning manags:ment, emergency treatment, and other information regarding the toxicity of methyl parathion. The toll free number for the National Pesticide Telecommunication Network is 1-800-858- 7378. Ifhandled indoors,provide mechanical exhaust ventilation. po notrub eyes or mouth with hands. If you feel sick in any way, STOP work arid get help right away. See First Aid Section. PERSONAL PROTECTIVE EQUIPMENT Some materials that are chemical-resistant to this product are listed below. If you want more options, follow the instructions for category G on an EPA chemical resistance category selection chart. Applicators and other handlers must wear: Coveralls over long-sleeved shirt and long pants Chemical-resistant gloves, such as Barrier Laminate or Viton2 14 mils Chemical-resistant footwear plus socks Protective eyewear Chemical-resistant headgear for overhead exposure Chemical-resistant aprortWhen cleaning equipment, mixing, or loading For exposure in enclosed areas, a respirator with either an organic vapor-removing cartridge with a prefilter approved for pesticides (MSHAJNIOSH approval number preflJ( TC-23C),or a canister approved for pesticides (MCHAJNIOSH llJ:>!lI"O"~I).llU1cberjrefix TC-14G) .,. For exposures outdoors, dtiStfffiistfIlteringrespirator (MSHAINIOSH approval number prefix TC- 21C. Discard clothing and other absorbent materials that have been drenched or heavily contaminated with this product's concentrate. Do not reuse them. Follow manufacturer's instructions for cleaning! maintairiing PPE. If rio stich instructions for washables, use detergentand hot water. Keep and wash PPE separately from other laundry. When handlers use closed systems, enclosed cabs, or aircraft in a manner that meets the requirements listed in the Worker Protection Standard (WPS) for agricultural pesticides [40 CFR 170.240 (d) (4- 6)], the handler PPE requirements may be redm:ec! oLmodified~ _~ecified in WPS. DURING AEIUA:LAPPLrCA rt6N HuMAN FLAGGERSARE PROHIBITED. USER SAFETY RECOMMENDATIONS Users should: Wash hands before eating, drinking, chewing gum, using tobacco or using the toi:el. Remove clothing immediately if pesticide gets inside. Then wash thoroughly and jlJ t vI', clem. lothing. ' Remove PPE immediately after handling this product. Wash the outside of glove~ lo>!f('lre removing. A.s soon as possible, was~thoroughly andchange into clean ~Iothing. _ ,', ., ) ) POISON SIGNS (SYMPTOMS): Methyl Parathion is a very dangerous poison. It rapidly enters 3 the body on contact with all skin surfaces and eyes. Exposed persons must receive prompt medical treatment or they may die. Some of the signs and symptoms of poisoning are: Headache, nausea, vomiting, cramps, weakness, blurred vision, pinpoint pupils, tightness in chest, labored breathing, nervousness, sweating, watering of eyes, drooling or frothing ofmQuth_and nose, muscle spasms and coma FIRST AID This product contains an organopbosphate and is a cholinesterase inhibitor. Call a doctor (physician), clinic or hospital immediately. EXplain that the victim has been exposed to methyl parathion and describe his condition. After fITst aid is given and if a doctor cannot come, take victim to clinic or hospital. F BREA TIllNG HAS STOPPED, start artificial respiration immediately and maintain until doctor eesvictim. E'SW ALLO\VED, drink 1 or 2 glasses of water and induce vomiting by touching back of throat witb '"mger. Do not induce vomiting or give anything by mouth to an unconscious person. Get medical ~ttention. , ,',' ., . ~ CASE OF CONTACT, inllnediately flush eyes or skin with plenty of water. See doctor immedi­ ~tely. ~OTE TO PHYSICIAN: Antidote - administer atropine sulfate in large doses, TWO to FOUR mg. ~travenously or intramuscularly as soon as cyanosis is overcome. Repeat at 5 to 10 minute intervals putil signs of atrcpinization appear. 2-P AM chloride is also antidotal and mllY be administered in Fonjunction with atropine. DQ NOTGIVE MORPHINE OR TRANQUILIZERS. Methyl parathion s a strong cholinesterase 'inhibitor affecting the central and peripheral nervous systems and producing pardiac and respiratory depression. At first sign of pulmonary edema, the patient should be given ~upplementa1 oxygen and treated symptomatically. Continued absorption of the poison may occur and Ifatal relapses have been reported after initial improvement. VERY CLOSE SUl'BRVISION OF THE PATIENT IS INDICATED FOR AT LEAST 48 HOURS. . . ' . ENVIRONMENTAL HAZARDS _' This pesticide is highly toxic to aquatic invertebrates and wildlife. Birds in treated areas may be killed. Shrimp and other aquatic organisms may be killed at recommended application rates. Do not apply directly to water, or to areas'where surface water is present or to iiltertidaI areas below the mean high water mark uuless otherwise permitted in Directions for Use. Runoff anddriftmay be hazardous to aquatic organisms in adjacent aquatic sites. Do not contaminate water by cleaning of equipment or disposal of equipment washwaters. This product is highly toxic to bees exposed to direct treatment or residues OP. bl'J'J'lling cro:ps or weeds. Do not apply this product or allow it to drift to blooming crops ?r wetds if Jees <.re visiting the treatment area. COMBUSTIBLE DO NOT USE OR STORE NEAR HEAT OR OPEN FLAME NOT FOR USE OR STORAGE IN OR AROUND THE HOME. ) 4 DIRECTIONS FOR USE It is a violation of Federal law to use this product in a marmer inconsistent with its labeling. Do not apply this product in a way that will contact workers or other persons, either directly or through drift. Only protected handlers may be in the area during application. For any requirement specific tc your State or Tribe, c'onsult the agency responsible for pesticide regulation. AGRICULTURAL USE REQUIREMENTS' Use this product only in accordance with its labeling and with the Worker Protection Standard, 40 CFR part 170. This Standard contains requirements for the protection Qfagricultural workers on farms, forests, nurseries,~and greenhouses, and handlers of agricultural pesticides. It contains require­ ments for training, decontamination, notification, and emergency assistance. It also contains specific instructions and exceptions pertaining to the statements on this label about personal protective equip­ ment"(pPE)and restricted-entry interval The requirements in this box only apply to uses of this product that are covered by the Worker Protection Standard. Do not enter or allow worker entry into treated areas during the restricted entry interval (REI) of 48 hours. PPE required for early entry to treated areas that is pennitted under the Worker Protection Standard and that involves contact with anything that has been treated, such as plants, soil, or water is : --Coveralls over long-sleeved shirt and long pants --Chemical-resistant gloves, such as Barrier Laminate or Viton:? 14 mils. --Chemical-resistant footwear plus socks --Protective eyewear --Chemical-resistant headgear for overhead exposure. Notify workers of the application by warning them orally and by posting warning signs a! e!ltrap.c~~!c treated areas.' . ..- ............ ~ ..... ~ ....... ~... . - ......-..... -_ ...... ::-~ .. '-~-"'-. .. ) In case of accidental exposure: Call a doctor (physician), clinic or hospital immediately. Explain that . . the victim has been exposed to methyl parathion and describe his condition. For further information, see the FIRST AID portion of the pesticide labeL STORAGE AND DISPOSAL PROHIBITIONS: Do not contaminate water, food, or feed by storage o~ ·disposal. Do not store under com:!itions which might adversely affect the container or its ability to function properly. -~-.---- -.-.. _---- STORAGE: 06 not stOre1Je16w O°F. Store in a sareIIl~~r.Do·not use or store near heat, vp<:n flame or hot surfaces. Keep out of reach of children and animals. Store in original ,con1;a,iners only. Store in a cool, dry place and avoid excess heat. Reduce stacking height where lo-:;a\ conditkns C.1Jl affect package strength. Personnel should Use clothing andequipment listedunde. 'P:;U;CACTION­ AR Y STATEMENTS" when handling open containers. Carefully open containers. Do not put concentrate or dilute material into food or drink containers. SPILLED MATERIAL: Block or dike tc prevent spreading of spill. Cover with absorbent It\li\teri,al such as lime, clay or sawdust. Scoop and sweep into a disposable container. Wash area with strdI'{t lye solution, absorb and place intc a disposable container. ) PESTICIDE DISPOSAL Pesticide wastes are acutely hazardous. Improper disposal of excess pesticide, spray mixture, or rinsate is a violation of Federal Law. If these wastes cannot be disposed of by use according to label instructions, contact your State Pesticide or Environmental Control Agency, or the Ha2:ardollS Wastes representative at the nearest EPA Region Officeror guidance. CONTAINER DlSPOSAL RetumablelRefillable Seal Container: Do not break seals or add any material to the container. Do not rinse container or empty any residue from coIltainer. This container must be retiuned intact after use to the point of purchase. DIRECTIONS Be sure to read the precautionary statements before using! This product is designed for application after dilution with water and for use by trained operators using airplane or power ground equipment. The hazards and precautions for handling the product in this container are equally applicable to it after dilution with water for spray application. REMOVAL OF PRODUCT FROM CONTAINER This container is fitted with the :MICRO MATIC "DV" liqUid transfervaIve system._Toremove product, use the :MICRO MA TIC coupler attachment which is available from the seller of this con­ tainer. The directions below must be followed: To Connect Coupler: 1. Attach pump hose to chemical pump. 2. Attach pump hose to coupler. 3. With coupler handle in disengaged position, insert coupler straight down into the drum valve, ensuring that the pins on the coupler align with the slots on the valve. 4. Turn coupler handle clockwise a quarter tum, until it locks into place. ) 5. Push down coupler handle to engage, ensuring that the lock bar clicks into place. To Disconnect Coupler: 1. Press down on coupler and disconnect the lock bar. Allow coupler handle to raise to its disen­ gaged position. 2. TiJrn Coupler handle counter clockwise and quarter tum. Lift coupler straight up. If you have any questions Of need assistance, please call your Distributor or 1-800-548-6113. Add the concentrate to the spray tank while filling with water, and mix thorovgr ly ~ither by 'lleansof a tank agitator or pump by-pass. For best results,-thoroughly coverall surfac<-s to]:,e treated with spray. Rates of application given below should not be exceeded. Never apply la:er than indicated to assure residue levels at harvest are below tolerance established by the Envirol'ro~ptal Protecli0fl Agency. - -- -'-----, - ----'------------ - ------ Consult the StaieAgilcultlirafExtension Service or Experiment Station for specific recoro~~~dations regardingapplication, dosage and timing of spray. For application by ground equipment, add t:ie ) ) desired amount of concentrate to sufficient water to apply at least 3 gallons of water per acre. For 6 application by aircraft, add the atnount of concentrate desired per acre to 1 to 3 gallons of water consistent with crop growth and good coverage. Do not use in undiluted form. DO NOT APPLY 'tHIS PRODUCT THROUGH ANY TYPE OF IRRIGATION SYSTEM. COMPATIBILITY - A void combinations containing highly alkaline materials such as lime-sulfur solutions or lime. Alkaline compounds will reduce the effectiveness of methyl parathion. ALFALFA: Flea Beetles, Climbing Cutworms, - Apply \12-I pint per acre. Aphids (including Pea Aphids and Spotted Alfalfa Aphid) - Apply \12-I pint per acre. For Spotted Alfalfa Aphid, apply early in spring. Alfalfa Weevil (larvae)- Apply \12-1 pint per acre. Apply when 75% terminals show feeding, when buds and shoots appear ragged, or when the larval count reaches 25 per sweep. Web­ worms, Clover Leaf Weevil, Alfalfa Caterpillar, Armyworms, Alfalfa Weevil (adult) (Refer also to Egyptian Weevil) Thrips and Grasshoppers - Apply I pint per acre. Egyptian Alfalfa Weevil, Leafhoppers, LygusBugs, Mites, Stink Bugs, and Spider Mites - Apply 1-2 pints per acre. Do not apply within 15 days of harvest. Alfalfa Seed Chalid - Apply I \12-2\12 pints per acre. Plant Bugs (for use on seed crops only) - Apply \12-1 pint per acre. Do not apply within 15 days of harvest, cutting or grazing. In California and Nevada, do not usemore than Y. pint per acre. Do not apply if the crops or weeds in the treatment area are in bloom. BARLEY: Thrips - Apply \12-1 \12 pints per acre. Leafhopper, Cutworms (Climbing) - Apply Y. to 1 pint per acre. Stink Bugs, Armyworm (to 3r;:3J.. Cutworm (inclllding Climbing Cutworms), Flea Beetles, Grasshoppers, Leaiboppers, Sugar Beet Webworms, Mites - Apply Yo-l4 pint per acre. Lygus Bugs, Stink Bugs, Webworms - l4 pints per acre. ) Aphids - Apply l4 pints per acre. Do not apply within 20 days of harvest; 60 days iftops are to be fed to animals. SUNFLOWERS;·Sunfl01ver Moth, Sunflower Maggot, Sunflower Seed Weevil - Apply 2 pints per acre. Donotapply within 30 days of harvest. Do not apply more than 3 times at 5-day intervals per season. Do not feed seeds to birds. SWEET POTATOES: Aphids, Armyworm (to 3rd instar), Cutworms (including climbing and surface feeding species,) Flea Beetles, Leaiboppers, Cabbage Looper, Spider Mites - Apply 1 Yo pints per acre. Do nOt apply within 6 days of harvest. TURNIPS: Aphids (including Cabbage Aphid), Armyworms (to 3rd instar), Flea Beetles, Leaiboppers, Leafminer, Mites - Apply 1-1 Yo pints per acre. Imported Cabbage Worm, Cabbage Looper, Plant Bugs - Apply I Yo pints per acre. Do not apply within 10 days of harvest through Yo pint (roots). Do not apply within 21 days of harvest from 1 to 1 Yo pints (roots). Do not apply within 21 days of harvest if tops are to be used as food or feed. VETCH: Alfalfa Weevil (larvae) - Apply ~-1 pint per acre. Apply when 75% ofteoninals show feeding, when budS and shoots appear ragged, or when the larval count reaches 25 per sweep. Aphids, Leaiboppers, Mites - Yo-I pint per acre. Climbing Cutworms, Lygus Bugs, Vetch Bruchid - I pint per acre. Armyworm - YO-2YO pints per acre. Do not apply within 15 days of harvest through 2 pints. Do np! apply within 20 days of harvest from 2 pints through 2Yo pints. WHEAT: Brown Wheat Mites, Western Wheat Mites - Apply 1 pin! per acre . .B::rley Thrips­ Apply Yz-l4 pints per acre. Leallioppers, ArmyworJll (to 3r