# DIAZINON 4AG - EPA Reg No: **9779-210** - Registrant: WINFIELD SOLUTIONS, LLC - Signal word: Caution - Active ingredients: Diazinon (48%) - Label accepted: 2001-09-27 - Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/009779-00210-20010927.pdf --- --------"""",.,,"""""'""" UNITED STATES ENVIRONMENTAL PROTECTION AGENCY WASHINGTON, D.C. 20460 OFFICE OF PREVENTION, PESTICIDES AND TOXIC SUBSTANCES Mr. steve Rogosheske Agriliance, LLC SEP 2 72001 P.O. Box 64089 st. Paul, MN 55164-0089 Dear Mr. Rogosheske: Subject: Amendment - Comply with 2000 Diazinon MOA, Update First Aid per PR Notice 2001-1, Delete Beans, Cucumbers, Parsley, Parsnips, Peas, Peppers, Irish Potatoes, Summer and winter Squash, Sweet Potatoes, Swiss Chard, Turnips, Lawns, and other outside (non-crop) Areas And Update CSF/replacement diazinon source Diazinon "'Aft EPA Registration ~umber 9779-210 Your submission dated May 31, 2001 The amendment referred to above, submitted in connection with registration under FIFRA section 3(C) (7) (a), is acceptable provided that you: 1. Submit and/or cite all data or other material required for registration/reregistration of your product under FIFRA section 3(c) (5) or FIFRA section 4 when the Agency requires all registrants of similar products to submit such data. 2. Make the labeling changes listed below before you release the product for shipment bearing the amended labeling: a. As agreed by telephone, your finished labeling for this amendment may include your previous directions for use on Cabbage which you inadvertently included in the listing of unsupported crops to be deleted. The agricultural use of diazinon on cabbage is supported under the diazinon MOA. 2 b. On page 3 under the heading General Information, revise the sentence "Do not use on food crops grown in greenhouses." to read "Do not apply this product in greenhouses.". c. On page 9, under the heading Vegetable crops, revise the sentence "Do not apply this product to food crops grown in greenhouses."to read "Do not apply this product in greenhouses.". d. As we discussed by telephone, on page 17 delete the heading Grassland Insects and its associated text. This is part of the unsupported outside non-crop areas which you requested to delete. Under the diazinon MOA, only crop uses may appear on agricultural use labels. 3. Submit three (3) copies of your final printed labeling before you release the product for shipment. If these conditions are not complied with, the registration will be subject to cancellation in accordance with FIFRA section 6(e). Your release for shipment of the product constitutes acceptance of these conditions. A stamped copy of the label is enclosed for your records. The Basic Confidential statement of Formula (CSF) dated May 30,2001, and which identifies your replacement diazinon source Manufacturing Use Product, is acceptable and has been added to this product's registration file. Sincerely, George T. LaRocca Product Manager 13 Insecticide Branch Registration Division (7505C) Page 1 of 17 RESTRICTED USE PESTICIDE DUE TO AVIAN AND AQUATIC TOXICITY FOR RETAIL SALE TO AND USE BY CERTIFIED APPLICATORS OR PERSONS UNDER THEIR DIRECT SUPERVISION AND ONLY FOR THOSE USES COVERED BY THE CERTIFIED APPLICATOR'S CERTIFICATION THIS PRODUCT MUST NOT BE USED ON GOLF COURSES AND SOD FARMS Diazinon 4AG For Control Of Certain Insects On Fruits, Nuts, Vegetables, Field Crops And Ornamentals ACTIVE INGREDIENT Diazinon (O,O-diethyl Q-(2-isopropyl-6-methyl-4-pyrimid'lnyl) phosphorothioate)* .. INERT INGREDIENTS". TOTAL. ·Contains 4 pounds of diazinen per gallon. ··Centains xylene range aromatic solvents. STOP - READ LABEL BEFORE USING KEEP OUT OF REACH OF CHILDREN CAUTION FIRST AID ...... 48.0% ..... 52.0% .. ... 100.0% ACCEPTED with C.i)MME~TS In EI'A Leae,," Dated: SEP 2 7 2001 Under tiw Fcd-:,:-cl Fmil't'ticirh:, Fungic:dc~ :mf', UoriemH"hlt' Act. Q!!I wnenned, 1-". th!! pt':sl.idde registel'ed ..mdf~r EPA He",. No. '117"1-2./0 This product contains diazinon and organophosphate insecticide that inhibits cholinesterase. IF SWALLOWED: • CaJl a poison control center or doctor immediately for treatment advice. · Have a person sip a glass of water if able to swallow. • 00 not induce vomiting unless told to do so by a poison control center or doctor. · 00 not give anything by mounth to an unconscious or convulsing person. IF IN EYES: • Hold eye open and rinse slowly and gently with water for 15·20 minules. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. • Call a Doison control center or doctor for treatment advice. IF INHALED: • Move person to fresh air. • If a person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably, mouth·to- mouth, if possible. • Call a Doison control center or doctor for treatment advice. IF ON SKIN OR COTHING: • Take off contaminated clothing. · Rinse skin immediately with plenty of water for 15-20 minutes. • Call a poison control center or doctor for treatment advice. Have product container or label with you when calling a poison control center or doctor, or going for treatment. NOTE TO PHYSICIAN: This product is an organophosphate insecticide. If symptoms of cholinesterase inhibition are present, atropine sulfate by injection is antidotal. 2·PAM is also antidotal and may be administered, but only in conjunction with atropine. This product contains a xylene range aromatic solvent which may present an aspiration hazard. Gastric lavage may be indicated if product was taken internally. Read Additional PRECAUTIONARY STATEMENTS. EPA REG NO. 9779-210 Distributed By: Agriliance, LLC P.O. Box 64089, SI. Paul, MN 55164-0089 0/E30/1 EPA EST. NO. Net Contents GALS PRECAUTIONARY STATEMENTS CAUTION HAZARDS TO HUMANS AND DOMESTIC ANIMALS Page 2 of 17 Harmful if swallowed, inhaled or absorbed through skin. Causes moderate eye injury. Avoid breathing vapor or spray mist. Avoid contamination of food and feed. Food utensils such as tablespoons and measuring cups should not be used for food purposes after use in measuring pesticides. Keep out of reach of domestic animals. Do not use on humans, household pets or livestock. Do not contaminate ornamental fish ponds. Personal Protective Equipment: Some materials that are chemical-resistant to this product are listed below. If you want more options follow the instructions for category F on an EPA chemical resistance category selection chart. Applicators and other handlers must wear long-sleeved shirt and long pants, chemical-resistant gloves, such as Barrier Laminate, Butyl Rubber, Nitrile Rubber, or Viton, shoes plus socks. Follow manufacturer's instructions for cleaning/maintaining PPE. If no such instructions for washables, use detergent and hot water. Keep and wash PPE separately from other laundry. USER SAFETY RECOMMENDATIONS Users should wash hands before eating, drinking, chewing gum, using tobacco or using the toilet. Remove clothing immediately if pesticide gets inside. Then wash thoroughly and put on clean clothing. Remove PPE immediately after handling this product. Wash the outside of gloves before removing. As soon as possible, wash thoroughly and change into clean clothing. . ENVIRONMENTAL HAZARDS This product is highly toxic to birds, fish and other wildlife. Birds, especially waterfowl, feeding or drinking on treated areas may be killed. Because of the migratory habits of Atlantic coast waterfowl, do not apply this product to lawns in Nassau County, New York, between November 1 and May 20. Do not exceed maximum permitted label rates. Rates above those recommended significantly increase potential hazards to birds, especially waterfowl. Avoid ovenapping of sprays. If watertowl (ducks or geese) can be expected in the treated area after treatment (except spot treatment), apply at least Y. inch of water immediately after spraying this product; however, stop watering before puddling occurs. Keep out of lakes, streams, ponds, tidal marshes and estuaries. Do not apply directly to water, to areas where surtace water is present, or to intertidal areas below the mean high water marie Drift and runoff may be hazardous to aquatic organisms in neighboring areas. Shrimp and crab may be killed at application rates recommended on this label. Do not apply where fish, shrimp, crab, and other aquatic life are important resources. Do not contaminate water by cleaning of equipment or disposal of equipment wash waters. This pesticide is highly toxic to bees exposed to direct treatment or to residues on blooming crops or weeds. Do not apply this pesticide or allow it to drift to blooming crops or weeds if bees are visiting the treatment area. PHYSICAL OR CHEMICAL HAZARDS Do not use, pour, spill, or store near heat or open flame. DIRECTIONS FOR USE It is a violation of Federal law to use this product in a manner inconsistent with its labeling. Reformulation or repackaging of this product is prohibited. Do not apply this product in a way that will contact workers or other persons, either directly or through drift. Only protected handlers may be in the area during application. FAILURE TO FOLLOW THE DIRECTIONS FOR USE AND PRECAUTIONS ON THIS LABEL MAY RESULT IN POOR INSECT CONTROL, CROP INJURY OR ILLEGAL RESIDUES. For any requirements specific to your State or Tribe, consult the agency responsible for pesticide regulation. AGRICULTURAL USE REQUIREMENTS Use this product only in accordance \Vith its labeling and with the Worker Protection Standard, 40 CFR part 170. This Standard contains requirements for the protection of agricultural worKers on farms, forests, nurseries, and greenhouses, and handlers of agricultural pesticides. It contains requirements for training, decontamination, notification, and emergency assistance. It also contains specific instructions and exceptions pertaining to the statements on this label about personal protective equipment (PPE), and restricted-entry interval. The requirements in this box only apply to uses of this product that are covered by the Worker Protection Standard. Do not enter or allow worKer entry into treated areas during the restricted entry interval (REI). Exception: If the product is soil­ injected or soil-incorporated, the WorKer Protection Standard, under certain circumstances, allows workers to enter the treated area if there will be no contact with anything that has been treated. PPE required for eany entry to treated areas that is permitted under the Worker Protection Standard and that involves contact with anything that has been treated, such as plants, soil, or water, is: coveralls, chemical-resistant gloves, such as Barrier Laminate, Butyl Rubber, Nitrile Rubber, & Viton, and shoes plus socks. Page 3 of 17 NON-AGRICULTURAL USE REQUIREMENTS The requirements in this box apply to uses of this product that are NOT within the scope of the Worker Protection Standard for agricultural pesticides (40 CFR Part 170). The WPS applies when this product is used to produce agricultural plants on farms, forests, nurseries, or greenhouses. Keep unprotected persons or pets out of treated areas until sprays have dried. Note: The California Department of Agriculture has set a 5-day reentry period for diazinon on grapes, peaches, and nectarines. Five days should elapse between the time of application and the time a worker may enter the field to engage in any activity requiring substantial contact with treated foliage. When a mixture of two or more organophosphate pesticides are applied in combination, the interval should be prolonged by adding to the largest applicable interval an additional 50% of that interval. STORAGE AND DISPOSAL Do not contaminate water, food, or feed by storage or disposal. Open dumping is prohibited. Pesticide Pesticide wastes are toxic, improper disposal of excess pesticide, spray mixture, or rinsate is a violation of Federal law. If pesticide, spray mixture or rinsate cannot be disposed of by use according to label instructions, contact your State Pesticide or Environmental Control Agency, or the Hazardous Waste representative at the nearest EPA Regional Office for guidance. Container Triple rinse (or equivalent). Then puncture and dispose of in a sanital)' landfill, or incinerate, or burn, jf allowed by state and local authorities. Stay out of smoke from burning container. For minor spills, leaks, etc., follow all precautions indicated on this label and clean up immediately. Take special care to avoid contamination of equipment and facilities during cleanup and disposal of wastes. In the event of a major spill, fire or other emergency, call 1-800-424-9300 (CHEM TREC) day or night. GENERAL INFORMATION DIAZINON 4AG is an emulsifiable solution which, when diluted with water according to the directions, is intended for the control of insect pests of agricultural crops and other plants. Do not use on food crops grown in greenhouses. Do not use in barns or dwellings. Do not use on livestock. In the directions for use which follow, best control is obtained when application is made at first sign of pests. Application should be repeated only as directed to maintain control. To avoid spray drift, do not apply under windy conditions. Avoid spray overlap, since crop or plant injury may result. Work Safety Rules REPEATED EXPOSURES TO CHOLINESTERASE INHIBITORS SUCH AS ARE CONTAINED IN THIS PRODUCT MAY, WITHOUT WARNING, CAUSE PROLONGED SUSCEPTIBILITY TO VERY SMAll DOSES OF ANY CHOLINESTERASE INHIBITOR. When handling DIAZINON 4AG, do not rub eyes or mouth with hands. If you feel sick in any way, STOP work and get help right away .. See Practical Treatment section of this label. CHEMIGATION APPLICATION THROUGH AN IRRIGATION SYSTEM (CHEMIGATION) - CRANBERRIES ONLY DIAZINON 4AG may be applied alone or in combination with other pesticides registered for application through sprinkler irrigation systems to cranberries. To insure compatibility, pour the products into a small container of water in the correct proportions. After thorough mixing, let stand for five minutes. If the combination remains mixed, or can be remixed readily, the mixture is compatible. Do not apply this product through any type of irrigation system to other crops. For chemigation, apply this product to cranberries only through sprinkler irrigation systems. Do not apply this product to cranberries through any other type of irrigation system. Crop injury, lack of effectiveness. or illegal pesticide residues in the crop can result from non-uniform distribution of treated water. If you have questions about calibration, you should contact State Extension Service specialists, equipment manufacturers or other experts. Do not connect the irrigation system used for pesticide application to a public water system unless the pesticide Jabel-prescribed safety devices for public water systems are in place. A person knowledgeable of the chemigation system and responsible for its operation, or under the supervision of the responsible person. shall shut the system down and make necessal)' adjustments, if the need arises. Chemigation System Connected to Public Water Systems 1. PubliC water system means a system for the provision to the public of piped water for human consumption if such system has at least 15 service connections or regularly serves an average of at least 25 individuals daily at least 60 days out of the year. 2. Chemigation systems connected to public water systems must contain a functional, reduced-pressure zone, backflow preventer (RPZ) or the functional equivalent in the water supply line upstream from the point of pesticide introduction. As an option to the RPZ, the water from the public water system should be discharged into a reservoir tank prior to pesticide introduction. There shall be a complete physical break (air gap) between the outlet end of the fill pipe and the top or overflow rim of the reservoir tank of at least twice the inside diameter of the fill pipe. Sprinkler Chemigation 1. The system must contain a functional check valve, a vacuum relief valve, and low pressure drain appropriately located on the irrigation pipeline to prevent water source contamination from backflow. page 4 of 17 2. The pesticide injection pipeline must contain a functional, automatic, quick-closing check valve to prevent the flow of fluid back toward the injection pump. 3. The pesticide injection pipeline must also contain a functional, normally dosed, solenoid-