# DREXEL METHYL PARATHION 4E - EPA Reg No: **19713-37** - Registrant: DREXEL CHEMICAL COMPANY - Signal word: Danger - Active ingredients: Methyl parathion (44.8%) - Label accepted: 1997-10-10 - Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/019713-00037-19971010.pdf --- )1713- 37 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY WASHINGTON, D.C. 20460 R. Franklin Handy Technical Director Drexel Chemical Company P.O. Box 13327 Memphis, T.N. 38113-0327 Dear Dr. Hand\': . '. October 10, 1997 Subject: Labeling i\mendment and Confidential Statement of Fonnula Methyl Parathion 4E EPA Reg. No. 19713-37 OFFICE OF PRE VENTION. PESTICIDES AND TOXIC SUBSTANCES Confidential Statement of Formula was received at EPA on February 26,1997 Resubmission of the amended label was received at EPA on July 31, 1997 The amended label and confidential statement offormula (CSF) referred to above submitted in connection with registration under the Federal Insecticide, Fungicide, and Rodenticide Act, as amended, have been received and reviewed, and the following are the Agency's comments. The confidential statement of formula dated February 26,1997 for the Methyl Parathion 4E formulation agrees with the label claim in compliance with PR Notice 91-2 and is acceptable. The amended label dated July 31, 1997 for the Methyl Parathion 4E is accepted pro\~ding you make the following change to your label: 1. Delete the Special Local Need on page one of your label identified as EPA Est. No. 19713-GA-J All products distributed or sold under Drexel Methyl Parathion 4 (EPA Reg. No. 19713-37) must be packaged in labeled containers bearing a unique identification number that will remain on the label or container at all times. Racycled/Recyclable • Printed with Vegetable Oil Basod Inks on 100% Recycled Paper (4CT'k Postconsume:) 'I S 2 The accepted label and confidential statement offonnula have been added to your file as part of the record. A stamped copy is enclosed for your records. Please submit one (1) final printed copy for the above mentioned label before releasing the product for shipment. Enclosures Larry Fried Insecticide-Rodenticide Branch Registration Division (7505C) -.. RESTRICTED USE PESTICIDE Due: 10 vcry h;gll acule ~cxicity to Humans and Birds For re:ail sa:e to and usc only by certified applicaloi or persons under their direct supervision and only for those uses covered by t'le ccni:icd 2Pi':ica:cr's certificatio~. Direct supervision for this product is defined as t..'le certified app:icatcr being physi~Uy prescr.: du:ing application. mixing, loading, repair and deaning of 3PpHcaiion equip:nent. Commc;-cia! certfied app:icators must ::lisa er,sure that all persons invo!ved in these aC'jvitics are infonTled of the prea:ui.ionmy s:a:ements. , ". - '- .' I ·.,!:;>~\-",ethyl Parathion 4E. : ',:t. .,' '". • " • Emulsifiable insecticide for controlling certain insects on the listed field and forage crops. ACTIVE INGREDIENTS: 0,0-Dimethyl-0-{4-nitrophenyl) phosphorothioate' Related Compounds ...... ___ ............ . INERTINGREDIENTS:- .. _ ... _ ............ _ TOTAL: ........................... _ ·O~t-.~:-,";'se ~nO'.·,,:-: as 'r:1c~hyl ;1Cl~a:~,:cn' "Cc:ll,<",,;\; DANGER .. PELIGRO Reo POISON .. 'ItfDtI~) VENENO ~ ~-.... ..-/ ,si us:ed no er:ticr:de la C'iC;t.!ctCl, ta:sc;:.:e a al;uie;) para c;ue se!a explique a usted en detal!e. (If you do ::ot ur.cefs1cflC the label, fir:d sorne~ne :0 explai:l it to you in detaili. EPA Reg_ No_ 19713-37 EPA Est. No. 19713-GA-1 STATEMENT OF PRACTICAL TREATMENT This product contains an organophosphate and is a cholinest­ erase inhibitor. IF SWALLOWED: Gail a physician or Poison Control Center. Drink 1 or 2 glasses of water and inducevcmi:.ing by touching back of throat with finser. or, if available, by administering syrup of ipecac. Do not induce vomiting crgive anything by mouth to an unconscious person. IF INHALED: Remove victim to fresh air. If not breathing, immedi­ ately give artificial respiration, preferably mouth-to-mouth. Getmedi­ cal attention, IF IN EYES: Flush with plenty of water. Call a physician. IF ON SKIN: If material has been spilled on the skin, immediately remove pat1ent from the vicinity of the methyl parathion and wash with plenty of soap and water. Get medical attention. CALL A PHYSICIAN IMMEDIATELY IN ALL CASES OF SUS­ PECTED POISONING. Note to Physician: Antidote: Administer atropine sulfate in large doses, two to four mg intrevenously or intramusculany as soon as cyanosis is overcome. Repeat at 5 to 15 minute intervals until signs of atropinization appear. 2-PAM chloride is also antidotal and may be administered in conjunction with atropine. Do not give morphine or tlC!nquilizers. Methyl parathion is 'a strong cholinesterase inhibitor affecting L"e central penphel'2l ner ... ous system and producing cardiac and respiratory depression, At first sign of pulmonary edema, the patient should be given supplemental oxygen and treatccl symptomatically, Continued absorption of the poison may occur and fatal relapses have been reported after initial improvement. Very close supervision of the patient is indicated fOf at least 48 hcurs, POISON SIGNS (Symptoms) Methyl parathion is a very dangerous poison. It rapidly enters the body cn contact with all skin surfaces arid eycs. Clothing wet with this ma:erial must be removed immediCllcly. Exposed persons must receive prompt medical treatment or they may die. Some of t.:'e signs and symptoms of poisoning are: headache, r:ausea, vomi:ing, cramps. weakness, blurred vision, pin-pci:1: puO)Hs. tigh;r.ess :n ches:, labored breat!ling, r.ervousness, sweating, watering of eyes. c'rccllng or fiothing of molt.h and nose, muscle spasms and coma. SPECIAL INSTRUCTIONS FOR RESTRICTED USE PESTICIDE R!:.TAIL· ERS In addit;on !o arlY other :equ:red rec~xc's, restricted L:se ;:>es!lcic:e re!.E.l~=rs must record .at !:-:e time of sa~e the uniq;.;e ccnt3:r.er idenUica:ion !lu..,tler cn tr,is !c.t:el cr. c~ntai;;.er and :r.e ic'emity cf the purcr.aser of the CC:lt::l.'"!er, PRECAUTIONARY STATEMENTS Hazards to Humans and Domestic Animals DANGER· POISON CAN Kill YOU IF SWALLOWED: This prod!.!·:: can ki!1 you if s' .... allcwed even in small amounts; spray mist may be fatal if swa:lcwed. CAN KILL YOU BY SKIN CONTACT: Tnis prodt.:C! can kill yo:..! i~ tOt.!c~.e-d by hands or spilled or splashe:d en skin, in eyes or en c!othi:lg (liq:..!id perle!; a:es clo:hing). CAN KILL YOU IF BREATHED: Thisprc-duct can kill you if vapors cr spray mist are breathed. See Antidote Statement arid O:her Warr:.ir:gs on Side Pa;-,el. DURING AERIAL APPLICATION, HU!>.1AN FLAGG:::RS ARE PROHIB­ ITED. The National Pesticide Telecommunication Networ'~ is available for recom­ mendations regarding po:so~ing managemen:, emergency treCltment ar.d ot.'ler jnformation regardir.g the toxicity of methyl parathion. Toe toll free number for the National Pes~c:dc Telccomml1nica~on Networkis 1-800-858- 7378. If handled indoors provide mechanical exhaust ventilation. Keep aU unpro­ tected persons. children, livestock and pets away from t.'-eated area orwhere there is danger of drift. Do net rub eyes or mouth with hands. If you feel sick in any way, STOP work and get help riGht away. See Rrst Aid (Practical Treatment) section. ACCEPTED willa COMMENTS III EPA Letter Dated (D - (0 -1:;-- , , , Uader doe Federallaa t lkide, FaaciitUe.1IIId ~ A.:t .. &meaded, for the pect!cide "'Pjred 1U>d ... EPA R"lI' No. 1/13-37 r/.a:'n.':~'<:::5. such 'us barrier laminate. bL:tyl rubber. nitrile rubber or Vi::m. chemr:ai­ resis:ar.t footwear plus secks. pratect:ve eyewear ane chcmical-res·:S'i:?;r.: apron when c!eaning equip:-:-.ent, mix:ng or !oacing. For ~xposure outdoors. dust-mist m~e;ing .espirator (MSHNNiOS:- =0- pravsl nt;:nber prefix TC-21C). For exposure in enclosed areas. a ~es;:l1ratcr wi:'" c-~ther an crganic v;o:r­ removing car.:idge with a pre;]I:!:: approved for po;,s,icice (MSHAlJ\.'!:~H approval r.umber prefix TC-23C). or a canis:er cPl=foved for pes:i=::es (MSHAlN!OSH app:-ovCl: numberTC-14G). Respirc.tc~ ffiustbe ceane: ::r.d filters replaced according to instruc:icns ir.c!l!ced w:til respirc!:.af aphids. Com rootworm ;;Cu/ts. Fall armyworms and Slink bugs. use Y.! pint ~er ac:e. Fer Grass;;~,..,€r.;,. use 1 pint per acre. Do no~ app\ywith:n 12 days of harvest. Do :1ot apply to ~m during the pcl:erl sr.ed period. RICE - Fa..-.~'ce stink tl .. !gs. use}S to "i pln: per ac:e. Fo: Grasshoppers. use 1 pin: per ac."e. C-o net apply wit!lin 15 days of harvest or within 14 days arte~ propar:i! has been a;::pli~-d. Shrimp. crabs ar.d c:ayfish may t:-e ki!:-ed. Do not apl=:!Y wh~:e ~I~ese ar-:: ir:-.pcrtar:t resources. SOYBEANS - For con~iO! of Climbing cutworms and Threo-cornered ;;lfaif;; ho.cp-s:rs.l.rSc :h :::: ~ pint per a.C:"e. For ccn~roi of Aphids, Bfis~er be€t!es, .'dcxiccm bsa.'1 b-s~t:-=.s, Senk. bugs. Two-sported mites and Ve!vat-been caterpiffars. use 1 pin: per ,:c~e. S-o not 2PP:Y ::::o:;;er tharl15 days be~o:e ha:vest or grazir:g. COTiON - :=or :::ontrol of Thn"ps, use X:o ~ plnt per 3c:e. Fer CoUon IOcracre. For Cui~"'or.ns. use 1 [0 2 ;::intS ~er acre. For Bcf/wcrms. Salt-marsh catt!tpillars, A .... my .. 'crms. Cotton feci perfo.'2tors and Stink bugs. use 1 c;~ar.. per acre. A~~!:cal'oc.s sr.ould be made at 4 to 5 day irrteiVals l!:11ii cO:"l:rd is obtained. AI above ccsc.o;es. app~ication may J::e made: up 10 !he day before har~esl. if harvest wil! be wtt mec.~anical pickers. r\lso see "Tar.~ Mbctures on Cot!on~. CAUTION: 00 not apply within 5 days of handpickir.g cotlO:1. TANK MlXTURES T.,is product may be tank mixed with o~her insecticices to provice control of 2dditior.zl insect speCies. Read Clnd carefu!ly observe the precautionary state­ ments and a1l otl1er information ap~aring on the labe!s of all the insect:cides used. When we::..able powder, water soluble or fic ..... able formulations me to be tank mixed wIih emulsifiable formulCltions: 1. PlaCE: 2 20 to 35 mesh screen or weUir:g basket over fi1ling port. 2. Through the screen. fill the sprayer tank or.e-half full with water and start agitatfon. 3. If a wettable powder is used. make a slurry with the water carrier. and add it SLOM Y through the screen inlo the tank. Continue agitation. 4. If a 1'Iow;;.!::le formulation is used. pre-mix one partflcwable with one part waler. Add cf:!c:.ed mixture SLOWLY through the screen ir.to the tClnk. Continue agitation. S. Ccn:irll!e filling L'1e sprnyer tank with water ar.d add any rcmainir.g arr:ounts of liquid insecticides near the er:d offilling process. Maintain good agitatior: at all times ~I the contents of the tank are sprayed. 6. r..W. com~incd Iclal a.i.fClcre. Methyl Paratt-:;on 4= Cotten BoHworm and To~cco Bud",yorm -.55 to 1.1 lb. combined total a.i.lac~e. lIIr.r.~l" is II regr..lor'OC IrXom3ri1; cr E.1. O\JPor..! Ce~O:TlO~:$."Y.Id Cor:>;::!:1y. Lc~b3R 1:5 II maisieroc:' Ir:w:Iol'!'l(lril; o~ccw e~~rco Or.her.o is II ~islorod ~emDrk ofVJ;Or.t u.s.A. Corpo",lior: FIELD AND FORAGE CROPS RATE/ACRE . 1 ql ~ p!us lb Lb.­ ('f2Ib. a.i.) 1 quart" ;;lus 1 pint" 1 t02 pints­ plus 1 to 1'/: quarts • 1 pt.to1 qt.- ALFALFA AND CLOVER - For con!ro! of Alfalfa wel3~';1 farvaF.:, Aphids (including spot:.ed alfellfa aphids), Clim!)ing cut.'IOrms, and Grasshoppers, use Y:: to 1 pint pcr acre. For Alialfa caterpil!ars, Adult alfalfa weewls, ArmYi"lOnns, Clover leaf weevils and Webwo!lTis, use 1 pin: pcr .::tere. Fe: ~yp:J~n aimlfa weevfls, Leafhoppers, Ly~us bugs, and Spidermi~-cs. use i to 2 ;lir.!s per acre. 00 r:ot tre2~ c:cser than 15 ca,'s befere har,'est. c;J:::ns cr £fez:rtg. In Caiiicrr:ia. do not use mcre than ~ p:nt per a:::re. Do not apply if L';e ~.-op 0: weeds ir. t.'1a tr~Cl:mer.: o:rea a.-e in bloem. GRASS (Forage) - For RC!r:~e caterpiiJar. I.:se , p~r.t per a:::re. For contro! of Annywcrms. Crcs:o:Jc! w,'Je