# TRI-4 HF HERBICIDE - EPA Reg No: **241-343** - Registrant: BASF AGRICULTURAL SOLUTIONS US LLC - Signal word: Warning - Active ingredients: Trifluralin (42.8%) - Label accepted: 2004-03-23 - Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/000241-00343-20040323.pdf --- Rodney C. Akers, Ph.D BASF Corporation P.O. Box 400 Princeton, NJ 08543-0400 Dear Dr. Akers: MAR 23 2004 SUBJECT: Label Amendment - Adding Rapeseed Use Back on Label Tri-4 HP Herbicide EPA Registration No. 241-343 Your Application Dated July 9, 2002 The label referred to above, submitted in connection with registration under the Federal Insecticide, Fungicide, and Rodenticide Act, as amended, is acceptable. The amended label supersedes all previously accepted labels. A stamped copy of the label is enclosed for your records. Please submit one copy of the final printed label before you release the product for shipment. Enclosure Sincerely yours, t S( Joanne I. Miller Product Manager (23) Herbicide Branch Registration Division (7505C) CONCURRENCES ')17 :::: 1 ~I~;;;:;~"'I""""""""""""""'I"'''''''''''' .. ·· .... ···· .. ·1 .............. · .... · ........ ·1 .. · .. ·· ............ ··· .. · .... 1 ...... · .. · ...... · .... · .... ·1 .. · ........ · .............. ·1· .. · ...... ·· .......... .. ..................... , .. "" ..... " .... ", ... "., .. ,.".,',., """.", .. ,.",.,."""", .... ,,",., ...................................................... , .. , ... ,., .. ,', .. ,', .. ,.,'" ... , .......... , ..... ' ..... ,." ........ ".,. DATE Mar 23 , 2004 ' EPA Form 1320-1 (12-70) OFFICIAL FILE COPY BASF EMULSIFIABLE CONCENTRATE • herbicide A CEPTED MAR 23 2004 SELECTIVE HERBICIOE FOR THE PRE-EMERGENCE CONTROL OF ANNUAL GRASSES ANO BROAOLEAF WEEDS ACTIVE INGREDIENT: TRIFLURALlN: a, a, a-trifluoro-2,6-dinitro-N,N-dipropyl-p-toluidine .................. . 42.8% INERT INGREDIENTS·: ... TOTAL ................ . 'Contains Petroleum Distillate Contains 4 pounds of active ingredient per gallon. EPA Reg. No. 241-343 KEEP OUT OF REACH OF CHILDREN WARNING!/AVISOI 57.2% ................. 100.0% EPA Est. No. ???-??-??? Si usted no entiende la etiqueta, busque a alguien para que se la explique a usted en detalle. (If you do not understand this label, find someone to explain it to you in detaiL) See Inside for Additional Precautionary Statements See Directions for Use In,side in case of an emergency endangering life or property involving this product, call day or night 800-832-HELP. Net Contents: 110 Gallons BASF Corporation 26 Davis Drive, Research Triangle Park, NC 27709 Precautionary Statements Generatlnformation Weeds and Grasses Controlled INDEX Soil Preparation ................... . Soil Texture Application Directions Ground Application Aerial Application Chemigation Incorporation Application with liquid Fertilizers .. Application with Dry Bulk Fertilizers Directions for Use Alfalfa Beans (Dry, Castor, Guar, Mungbeans, lima, Snap) Carrots . . . . . . . . . . . ............... . Celery , , , . , , , , , , , , . , , , . , , . , , , , , . , . , , , Cole Crops .. .. .. , .......... (Broccoli, Brussels Sprout, Cabbage, Cauliflower) Cotton ........ Cucurbits , ' . , , , , . , , , , , . , , , , , , , , , , , , , , , . , (Cantaloupes, Cucumbers, Watermelons) Field Corn, ' , , , , , , , , , Greens, . , ' , , , , , , . , . , , , , , , , , , (Turnip greens, Kale, Mustard greens) Grain Sorghum , Hops .. " .. , .. , .... , .... , ....... , .. Okra .. Peanuts. , Peas (English, Dry, Southern Peas) Peppers , , ' . . , . , , , , , , , , , , , , , . , . , . , , , , , , . Potatoes .. .. .. .. .... , .. Rapeseed (Canola) . . , , , , , , , . , Safflower ' , , , ' , ' Soybean, .. , Sugar beets ...... , ...... , .. Sugarcane ' , , . , , . , , , 3 3 5 5 5 5 5 6 6 6 7 7 .. .. , .. 7 8 8 8 9 9 9 9 9 .. ,10 .... 10 .. ,10 , .. ,10 , ' ,10 ...... 11 ...... 11 .... , ........ 11 """"""" ,13 .... 13 Sunflower .. ' .. . .. . .. .. , , .. ,13 ,13 .. 13 .. ,14 Tomatoes, , . , , , , , , , , , . , , , ' , , , , , , , , , , , , , , , , , , , , ' , , Trees and Vineyards , , .. , , , , , , , , , , , , , , , , , , , , Wheat """"""""""""'", .. """",,' , (Winter, Spring, Durum) SpeCial Precautions , Disclaimer "" 2 .. ,14 , , , ' ,14 3/17 PRECAUTIONARY STATEMENTS HAZARDS TO HUMANS AND DOMESTIC ANIMALS WARNING Causes substantial but temporary eye injury. Harmful if swallowed or absorbed through the skin. Do not get in eyes or on clothing. Avoid contact with skin. Prolonged or fre­ quently repeated skin contact may cause allergic reaction in some individuals. FIRST AID IF IN EYES: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing. Call a poison control center or doctor for treatment advice. IF ON SKIN OR CLOTHING: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor feftreat­ ment advice. IF SWAllOWED: Gall a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by the poison control center or doctor. IF INHALED: Move person to fresh air. If person is not breathing, call 911 or an ambu" lance, then give artificial respiration, preferably by mouth-to· mouth, if possible. Call a poison control center or doctor for further treatment advice. Have the product container or label with you when calling a poison control center or doctor, or going tor treabnent. NOTE TO PHYSICIAN: Because of increased risk of chemical pneumonia or pulmonary edema caused by aspiration of the hydrocarbon solvent. vomiting should be Induced only under professional supervision. Personal Protective Equipment (PPE): Some materials that are chemical-resistant to this product are made of any barrier laminate, butyl rubber, nitrile rubber or viton. If you want more options, lollow the instructions for category F on an EPA chemical resistance category selection chart. Mixers, loaders, applicator and all other handlers must wear: • long·sleeved shirt and long pants, • socks and shoes, goggles or face shield, and chemical resistant gloves Discard clothing and other absorbent materials that have been drenched or heavily contaminated with this product's concentrate. DO NOT reuse them. Follow manufac­ turer's instructioos for cleaning and maintaining PPE. If no such instructions for wash· ables, use detergent and hot water. Keep and wash PPE separately from other laundry. When handlers use closed systems, enclosed cabs, or aircraft in a manner that meets the requirements listed in the WOO;er Protection Standard (WPS) for agricultural pes· ticides [40 CFR 170.240 (d) (4-6)), ttle handler PPE requirements may be reduced or modified as specified in the 'NPS. User Safety Recommendations: Users should: Wash hands before eating, drinking, chewing gum, using tobacco or using the toilet. Remove clothing immediately If pesticide gets inside. Then wash thoroughly alld put on clean clothing. Remove PPE immediately after handling this product. Wash the outside of gloves before removing. As soon as possible, wash thoroughly and change into clean clothing, EtJVIRONr,1ENTAL HAZARDS This pesticide is extremely toxic to freshwater marine, and estuarine fish and aquat­ ic invertebrates including shrimp and oyster. DO NOT apply in a manner which will directly expose canals, Jakes, streams, ponds, marshes or estuaries to aerial drift. Do not contaminate water when disposing of equipment washwaters. DO NOT apply directly to water, or to areas where surface water is present or to inter­ tidal areas below the mean high water mark. PHYSICAL AND CHEMICAL HAZARDS DO NOT use or store near heat or open flame. This product is a mild reducing agent. DIRECTIONS FOR USE It is a violation of Federal law to use this proooct in a manner inconsistent with its labeling. DO NOT apply this product in a way that will contact workers or other per­ sons, either directly or through drift. Only protected handlers may be in the area dur­ ing application. For any requirements specific to your State or Tribe, consult the agency responsible lor pesticide regulation. 3 DO NOT apply this producllhrough any type of irrigation system unless the label instruc­ tions on chemigation are followed. AGRICULTURAL USE REQUIREMENTS Use this product only In accordance with jts labeling and with the Worker Protection Standard, 40 CFR part 170. This Standard contains requirements lor the protec­ tion of agricultural workers on farms, forests, nurseries, and greenhouses, and handlers of agricultural pesticides. It contains requirements for training, decon­ tamination, notification, and emergency assistance. It also contains specific instructions and exceptions pertaining to the statements on this label about per­ sona protective equipment (PPE) and restricted-entry interval. The requirements in this box only apply to uses of this product that are covered by the Worker Pro1ectioo Standard. DO NOT enter or allow WOfker entry into treated areas during the restricted entry interval (REI) of 12 hours. Exception: if the product is soil-injected or soil­ incorporated, the Worker Protection Standard, under certain Circumstances, allows workers to enter the treated area If there will be no contact with anything thai has been treated. PPE required for early entry to treated areas that is permitled under the Worker Protection Standard and that involves contact with anything that has been treated, such as plants, sOit, or water, Is: • coveralls • chemical-resistant gloves • socks plus shoes STORAGE AND DISPOSAL DO NOT contaminate water, food or feed by storage or disposal. STORAGE, Avoid freezing. Store above 40°F. If frozen, poor weed control may result DO NOT store near heat Of open flame. PESTICIDE DISPOSAL. Wastes resulting from the use of this product maybe disposed of on site or at an approved waste disposal facility. CONTAINER DISPOSAL FOR 2,5 GALLON, DO NOT reuse empty containers. Triple rinse (or equivalent). Then offer for recycling or reconditioning, or puncture and dis­ pose of in a sanitary landfill, or Incineration, or if allowed by state and local authori­ ties, by burning. If burned, stay out of smoke. CONTAINER DISPOSAL FOR BULK. Return empty container to point of purchase. GENERAL INFORMATlOIJ TRI-4 HF Is a herbiCide which when incorporated Into the soil provides Iong·lasting control of annual grasses and broad leaf weeds; it controls weeds by killing their seeds as they germinate, It does not control established weeds. incorporation of TRI·4 HF assures effective control regardless of weather conditions and permits shallow culti­ vation, rotary hoeing and hand hoeing without reducing its weed control activity. Following the use of this product and chemically related products with the same mode of action, naturally occurring biotypes· of some of the weeds listed on this label can­ not be effectively controlled by this and related products. This product should betank­ mixed or applied sequentially with an appropriate registered herbicide having a different mode of action to ensure control of resistant biotypes. "A weed biotype is a naturally occurring individual within a given species that has a slightly different, but distinct genetic makeup from other individUals. See your BASF representative for additional information, WEEDS AND GRASSES COtJTRIJLLED ·11 :"l,l'4 Ii "' iiIi:".' "",' ~~ ~j~~'" '~:" '" \ """,7 Annual bluegrass Barnyardgrass (Watergrass) Brachiaria (Signalgrass) Bromegrass (Cheatgrass, Downy brome) Cheal (Chess) Crabgrass (Large crabgrass, Smooth crabgrass) Fall panicum Foxtails (Bottlegrass, Bristlegrass, Giant foxtail, Green foxtail, Pigeon grass, Robust foxtail, Yellow foxtai~ Goosegrass (Silver crabgrass, Silvergrass, Wlregrass, Yardgrass) Guineagrass Johnsongrass (Seedling and Rhizome) Junglerice R.oulgrass (llchgrassl Sandbur (Burgrass) Sprangletop Stinkgrass (Lovegrass) Poaannua £Chinochloa sp. Brach/a!fa sp. Bromus tectorum Bromus secallnus Digitaria sp. Panicum dichotom. Setaria sp. 8eusine indica Panicum maximum SOIf1 OTHER WARRANTIES, EXPRESS OR IMPLIED AND EXPRESSLY EXCLUDES AND DIS­ ClAIMS All IMPLIED WARRANTIES OF MERCHANTABllllY OR FITNESS FOR A PAR­ TICUlAR PURPOSE. BUYER'S EXClUSWE REMEDY AND BASF'S EXCLUSIVE ll4BllllY, WHETHER IN CON­ TRACT, TORT, NEGLIGENCE, STRICT ll4BILITY OR OTHERWISE, SHAll BE LIMITED TO REPAYMENT OF THE PURCHASE PRICE OF TRI-4 HF. In no case shall BASf or the seller be liable for conseQuentlal, special or indirect damages resulting from the use Of handling of this product. USES WITH OTHER PRODUCTS (TANK-MIXES) If this product is used In combination with any other product except as specifically recommended in writing by BASF, then BASF (and any other seller) shall have no lia­ bility for any loss, damage, or Injury arising rut of its use in any such combination not so specifically recommended. If used in a combination recommended by BASF, the liability of BASF (and any other seller) shall in no manner extend to any damage, loss or injury not directly caused by the inclusion of the BASF product in such combina­ tion use, and in any event shall be limited to return of the amount of the purchase price of the product. ® Registered Trademarks of BASF lSencor is a trademark of Farbenfabnken Bayer GmbH, Leverkusen 2Karmex aoo Lexone are trademarks of EJ. DuPont de Nemours and Company, Inc. JEptam and Vernam are trademarks of lenees Group Companies. ~Cotoran and Caparoi are trademarks of Clba-Geigy Corporation 5Avadex and Roundup are trademarks of tOOnsanto Company 6Butyrac Is a trademark of Rhone Poulenc Company All rights reserved NOTES 15 © 2001 BASF Corporation NVA 2002-04-147-0087 BASF Corporation 26 Davis Drive Research Triangle Park, NC 27709 BASF