# F4113 EW HERBICIDE - EPA Reg No: **279-3293** - Registrant: FMC CORPORATION - Signal word: Caution - Active ingredients: Glyphosate, isopropylamine salt (49.71%); Carfentrazone-ethyl (0.99%) - Label accepted: 2005-07-11 - Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/000279-03293-20050711.pdf --- ~::::::::::::~========U~.~S~.~ENV~'~R~ONM~E~NT~A:L~P~R~OT~E~C~T~'O~N~A~GE~N~C~Y======~~EP~A~R:eg:·=======r:D:a~te~O:f='~,:,~ua~n~c:e~,==~ Office of Pesticide Programs Number: Registration Division (H7505C) 401 hM" St., S.W. Washington, D.C. 20460 NOTICE OF PESTICIDE: ~ Registration -_'_ Reregistration (under FIFRA, as amended) Name and Address of Registrant (include ZIP Code) : FMC Corporation 1735 Market Street Philadelphia, P A 19103 279-3293 JUL 11 ?fXf5 Term of Issuance: Conditional Name of Pesticide Product: F4113 EW Herbicide Note: Changes in labeling differing in substance from that accepted in connection with this registration must be submitted to and accepted by the Registration Division prior to use of the label in commerce. In any correspondence on this product always refer to the above EPA registration number. On the basis of information furnished by the registrant. the above named pesticide is hereby registered/reregistered under the Federal Insecticide, Fungicide and Rodenticide Act. Registration is in no way to be construed as an endorsement or recommendation of this product by the Agency. In order to protect health and the environment. the Administrator, on his motIOn, may at any time suspend or cancel the registration ofa pesticide in accordance with the Act. The acceptance of any name in connection with the registration ofa product under this Act is not to be construed as giving the registrant a righllo exclusive use of the name or to its use ifit has been covered by others. This product is conditionally registered in accordance with FIFRA section 3(c)(7)(A) provided that you: I. Submit the result of the one-year storage stability (830,6317) and corrosion characteristics (830.5320) studies once they are available, 2, Submit/cite all data required for registration/reregistration of your product when the Agency requires all registrants of similar products to submit such data, 3, Make the labeling changes listed below before you release the product for shipment: a, Add the phrase "EPA Registration No,279-3293" b. On page 6, under Harvest Aid Treatment, delete "rice" from the list of crops in the first sentence, Glyphosate is not registered for preharvest on rice, c, On page 9, under Millet: Proso Millet, Pearl Millet, Spot Treatment, add the statement "Do not treat more than 10% of the total field to be harvested. d. On page 10, under Pastures, Spot Treatment, add the statements "For spot treatments using rates of 2.25 quarts per acre or less, the entire field or any portion of the field may be treated, When spot treatments are made above 2,25 quarts per acre, no more than 10 percent of the field may be treated at anY'One time, Date' 1')1 -2- 4. Submit two (2) copies of your final printed labeling before you release the product for shipment. Ifthese conditions are not complied with, the registration will be subject to cancellation in accordance with FIFRA section 6(e). Your release of this product for shipment constitutes acceptance of these conditions. A stamped copy of labeling is enclosed for your records. F4113 HERBICIDE For Agricultural, Aquatic or Commercial Non-Crop Use Only EPA Reg. No. 279-xxxx EPA Est. 279- Active Ingredient: By wt. Carfentrazone-€thyl-: Ethyl a,2-dichloro-5-[4- (difluoromethyl)-4,5-dihydro-3-methy~5-{)xcr 1 H-1 ,2.4- biazo~ 1-yl}4-ftuorobenzenepropanoate ..... 0.99% Glyphosate IPA .................................... .. 49.71% 49.30% 100.0% Inert Ingredients: .. .. *Contains 0.1 pounds Carfentrazone-ethyl per US gallon ··Contains 5.0 pounds Glyphosate, in the form of isopropylamine salt, per ~ gallon. (3.71 pounds per gallon glyphosate acid) Contains Petroleum Distillates U.S. Patent Pending KEEP OUT OF REACH OF CHILDREN CAUTION FIRST AID If Inhaled: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably by mouth-ta-mouth, if possible. Call a poison control center or doctor for further treatment advice. If on Skin or Clothing: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor for treatment advice. If In Eyes: Hold eye open and rinse Slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. If Swallowed: Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by the poison control center or doctor. Do not give anything by mouth to an unconscious person. HOTLINE NUMBER Have the product COntainer or label with you when calling a poison control center or doctor, or going for treatment. You may also contact 1-800-331-3148 for emergency medical treatment information. Note to Physician: F4113 is expected to have low oral and dermal toxicity, and moderate inhalation toxicity. It is expected to be slightly irritating to the skin and minimally irritating to the eyes. Treatment is otherwise controlled removal of exposure followed by symptomatic and supportive care. This product may pose an aspiration pneumonia hazard. See other panels for additional precautionary Information. THE ACTIVE INGREDIENT CARFENTRAZONE-ETHYL IS MADE IN CHINA. FORMULATED AND PACKAGED IN USA -FMC FMC Corporation A(~CEPTED wll.h COMMENTS In EPA Le~ter Datedt JUl 1 I 2005 Agricultural Products Group Under tIWJ PeGerd Insectfeid Philadelphia. PA 19103 F slcId :wi 11odad.w. .. ~": F4113_3_06-15-05 .. u':.... • ..l.i, for th. ~ restolered IIIUIu EPA ..... 1.7 j-- ~}Ci } PRECAUTIONARY STATEMENTS Hazards to Humans (and Domestic Animals) Caution Harmful if swallowed, absorbed through the skin or inhaled. Causes moderate eye irritation. Avoid contact with eyes or clothing. Wash thoroughly with soap and water after handling. Personal Protective Equipment (PPE) If you want more options, follow the instructions for category A on the EPA chemical-resistance category selection chart. Applicators and other handlers must wear: long-sleeved shirt and long pants, chemical-resistant gloves made of waterproof material such as polyethylene or polyvinyl chloride, and shoes plus socks. Follow manufacturer's instructions for cleaning/maintaining PPE. If no such instructions for washables, use detergent and hot water. Keep and wash PPE separately from other laundry User Safety Recommendations: Users should: * Wash hands before eating, drinking, chewing gum, using tobacco or using the toilet. • Remove clothing immediately if pesticide gets inside. Then wash thoroughly and put on clean clothing. Environmental Hazards F4113 is very toxic to algae and moderately toxic to fish. Do not apply directly to water, to areas where surface water is present or to intertidal areas below the high water mark, except as speCified on this label. Do not contaminate water when cleaning of equipment or disposing of equipment wash-waters. Physical/Chemical Hazards Do not use or store near heat or open flame. Spray solutions of this product should be mixed, stored and applied using only stainless steel, aluminum, fiberglass, plastiC or plastic­ lined steel containers. DO NOT MIX. STORE OR APPLY THIS PRODUCT OR SPRAY SOLUTIONS OF THIS PRODUCT IN GALVANIZED STEEL OR UNLINED STEEL (EXCEPT STAINLESS STEEL) CONTAINERS OR SPRAY TANKS. This product or spray solutions of this product react with such containers and tanks to produce hydrogen gas, which may form a highly combUstible gas mixture. This gas mixture could flash or explode, causing serious personal injury, if ignited by open flame, spark, welder's torCh, lighted Cigarette or other ignition source. TABLE OF CONTENTS Section Active ingredient First Aid Instructions Precautionary Statements Environmental Hazards Physical/Chemical Hazards Directions for Use Agricultural Use Requirements Non-Agricultural Use Requirements Storage and Disposal General Information For Agricultural Use Application Information Spray Drift Management Allowable Use Information Preharvest Intervals Crop Rotation Restrictions Weeds Controlled In Agricultural Use Fallow Systems Preplant Bumdown Spot Treatment Hooded Sprayer Applications Harvest Aid Applications Com: Field, Seed, Popcorn, Sweet Corn Cotton Berry Page 1 1 1 1 1 , 2 '2 2 3 3 4 .' 4 4 S 5 5 5 6 6 7 8 overnight storage of F4113 spray mixtures. Premixing F4113 spray solutions in nurse tanks is not recommended. Maintain continuous spray solution agitation until all the spray solution has been used. Do not use with tank additives that alter the pH of the spray solution below pH 5 or above pH 8. Buffer spray solution to alter the pH range as appropriate. Spray equipment Clean-Out: Many new pesticides are very actl~e at low rates, especially to sensitive crops. Residues left In mixing equipment, spray tanks, hoses, spray booms and nozzles can cause crop effects if they are not properly cleaned. As soon as possible after spraying F4113 Herbicide and before using the sprayer equipment for any other applications, the sprayer equipment must be thoroughly cleaned using the following procedure. In addition, users must take appropriate steps to ensure proper equipment clean-cut for any other products mixed with F4113 Herbicide as required on the other product labels. More complete cleaning can be achieved If the spray system is cleaned Immediately following the application. 1. Drain sprayer tank, hoses, spray boom and spray nozzles. Use a high-pressure detergent wash to remove physical sediment and residues from the inside of the sprayer tank and thoroughly rinse. Then, thoroughly flush sprayer hoses, spray boom and spray nozzles with a clean water rinse. Remove and clean spray tips and all filters and screens (tank, spray hose and spray tips) separately in the ammonia solution of Step 2. 2. Next, prepare a sprayer cleaning solution by adding three gallons of ammonia (containing at least 3% active) per 100 gallons of clean water. Prepare sufficient cleaning solution to allow the operation of the spray system for a minimum of 15 minutes to thoroughly flush hoses, spray boom and spray nozzles. 3. Convenient and more thorough cleaning of the sprayer can be achieved if the ammonia solution or fresh water is left in the spray tank, hoses, spray booms and spray nozzles overnight or during storage. 4. Before using the sprayer, completely drain the sprayer system. Rinse the tank with clean water and flush through the hoses, spray boom, and spray nozzles with clean water. Remove and clean spray tips and all filters and screens (tank, spray hose and spray tip) separately in an ammonia solution. 5. Properly dispose of all cleaning solution and rinsate in accordance with Federal, Siale, and local regulations and guidelines. Do not apply sprayer cleaning solutions or rinsate to sensitive crops. Do not store the sprayer overnight or for any extended period of time with F4113 Herbicide spray solution remaining in the tank, spray lines, spray boom plumbing. spray nozzles or strainers. Ifthe sprayer has been stored or idle, purge the spray boom and nozzles with clean water before beginning any application. Should small quantities of F4113 Herbicide remain in inadequately cleaned mixing. loading andlor spray equipment, they may be released during subsequent applications potentially causing effects to certain crops and other vegetation. FMC accepts no liability for any effects due to inadequately cleaned equipment. APPLICATION INFORMATION GROUND APPLICATION Utilize ground sprayers designed, calibrated and operated to deliver uniform spray deposition to the target plant or plant parts. Be aware that ovenaps and slower ground speeds while starting, stopping or turning while spraying may result in higher application rates and possible crop response. Do not exceed 30 psi spray pressure unless otherwise required by the manufacturer of drift reducing nozzles. Apply a minimum of 10 gallons of finished spray per acre. Higher spray volumes are required when there is a dense weed population or crop canopy 3 Spray Buffer for Ground Application Spray buffer zones for ground applications, listed in chart below. are required where local indigenous endangered plant species are found Buffers to Indigenous EndanQared Plant Species F4113 USE RATE Low Spray Boom High Spray Boom {fluid ounces/acre) BUffe'lft.) Bufferlft.) 30 20 33 40 26 46 Conventional Boom and Nozzle Sprayers Utilize a boom and nozzle sprayer equipped with the appropriate nozzles, spray tips and screens and adjusted to provide optimum spray distribution and coverage at the appropriate operating pressures. Utilize nozzles, which produce minimal amounts of fine spray droplets. Do not exceed 30 psi spray pressure unless otherwise required by the manufacturer of drift reducing nozzles. Apply a minimum of 10 gallons of finished spray per acre. Higher spray volumes are required when there ;s a dense weed population or crop canopy. Sprayers should be adjusted to position spray tips a minimum of 18 inches above the crop and operated to avoid the application of excessive herbicide rates directly over the rows andlor into the whorl of treated crop plants. Directed Sprayers F4113 may be applied with drop nozzles or other type sprayer equipment capable of directing the spray to the target weeds and away from sensitive plant parts. F4113 may be used up to the maximum rate for the target crop for the control of larger weed sizes or additional weeds not controlled with lower use rates. Use appropriate rates of adjuvants such as non-ionic surfactant. crop oil concentrate or methylated seed oil. Hooded Sprayers Hooded sprayers may also be used to apply F4113. Refer to the Hooded Sprayer Section on page 5 for specific adjustment and operation instructions. AERIAL APPLICATION Use nozzle types and arrangements that wilt provide optimum coverage while producing a minimal amount of fine droplets. Apply at a minimum of 3 gallons of finished spray per acre. Higher aerial spray volumes are required for harvest aid/defoliation treatments. Higher spray volumes are required when there is a dense weed population or crop canopy. Read and follow all state and local regulations and restrictions regarding the aerial application of herbicides containing glyphosate. Spray Drift Management AVOIDING SPRAY DRIFT AT THE APPLICATION SITE IS THE RESPONSIBILITY OF THE APPLICATOR AND THE GROWER. The interaction of many equipment and weather related factors determine the potential for spray drift. The applicator and the grower are responsible for considering all these factors when making decisions. The following drift management requirements must be followed to avoid off-target movement from applications to agricultural field crops. These requirements do not apply to forestry applications, public health uses or to applications of dry materials. 1. The distance of the outer most nozzles on the boom must not exceed 3/4 the length of the wingspan or rotor. 2. Nozzles must always point backward parallel with the air stream and never be pointed downwards more than 45 degrees. Where states have more stringent regulations. they must be observed. The applicator should be familiar with and tak.e into account the information covered in the Aerial Drift Reduction Advisory. Grain Sorghum Soybeans VVheat, Barley and Oats Millet: Proso, Pearl Tree Fruits and Nuts Grape Pasture Aquatic, Site Preparation and Non-crop Use directions Non-crop Mixing and Application Non-crop Spray Equipment Cleanout Application Equipment and Techniques Annual Weed Control Perennial Weed Control Woody Brush and Trees Aquatic Site Preparation and Other Non-crop sites Wildlife Habitat Management Bermudagrass Release Bahiagrass Suppression Annual Grass Growth Suppression Warranty and Liability DIRECTIONS FOR USE 9 9 9 9 10 10 10 11 11 11 12 12 13 15 17 18 18 18 19 19 It is a violation of Federal law to use this product in a manner inconsistent with its labeling. Do not apply this product through any type of irrigation system. Do not apply this product in a way that win contact workers or other persons, either directly or through drift. Only protected handlers may be in the area during application. For any requirements specific to your State or Tribe, consult the agency responsible for pesticide regulation. AGRICULTURAL USE REQUIREMENTS Use this product only in accordance with its labeling and with the Worker Protect1On Standard. 40 CFR part 170 This Standard contains requirements for the protection of agricultural workers on farms, forests, nurseries, and greenhouses, and handlers of agricultural pest1cides. It contains requirements for tTaming. decontammatlon, notlficat1On, and emergency ass1stance It also contams spec1fic Instructions and exceptions penamlng to the statements on this label about personal protective eqll1pment (PPE), and restncted-entry interval. The requirements In this box only apply to uses of this product that are covered by the Worker Protection Standard Do not enter or allow worker entry into treated areas during the restricted entry interval (REI) of 12 hours. PPE required for early entry to treated areas that is permitted ut"der the Worker Protection Standard and that in'lol'les contact Wlli1 anything that has been treated, such as plants, soil, or water, is: Coveralls, chemical-resistant gloves made of any waterproof malenal and shoes plus socks NON-AGRICULTURAL USE REQUIREMENTS The requirements in this box apply to uses of this product that are not within the scope of the Worker Protection Standard for agricultural pesticides, 40 CFR part 170. The WPS applies when thiS product IS used to produce agricultural plants on farms, forests, nurseries, or greenhouses. Turf grasses on gOlf courses and other non-residential turf areas such as mdustnal parks, tank farms, profeSSionally managed college and profeSSional sports fields, commercial lawns and ornamental landscapes are not Within the scope of the Worker Protection Standard. Do not enter or allow others to enter the treated area until sprays ha'le dried. STORAGE AND DISPOSAL Do not contaminate water, food or feed by storage or disposal. Pesticide Storage Not for use or storage in or around the house. Keep out of reach of children and animals. Store in original containers only. Store in a cool, dry place and avoid excess heat. STORE ABOVE 10' F (-12' C) TO KEEP FROM CRYSTALLIZING. Crystals will settle to the bottom. If crystals form, allow product to warm above 500 F (100 C) and mix well or shake to redissolve. Carefully open containers. After partial use, replace lids and close tightly. Do not put concentrated or dilute material into food or drink containers. Do not contaminate other pesticides, or fertilizers, food, or feed by inappropriate storage or disposal. In case of spill, avoid contact, isolate area and keep out 2 unprotected persons and animals. Confine spills. Call FMC: (800) 331-3148. To confine spill: Dike surrounding area, sweep up spillage. Dispose of in accordance with information given under Pesticide Disposal. Wash spill area with water, absorb with sand, cat litter or commercial clay, sweep up and dispose of in an approved manner. Place damaged container in a larger holding container. Identify contents per required hazardous waste labeling regutations. Pesticide Disposal waste resulting from the use of this product may be disposed of at an approved waste disposal facility. Container Disposal Plastic containers: Triple rinse (or equivalent). Then offer for approved pesticide container recycling program, or puncture and dispose of in an approved waste disposal facility. Provided on site incineration is allowed by state and local authorities, stay out of smoke, GENERAL INFORMATION FOR AGRICULTURAL USE F4113 is a liquid suspension formulation. F4113 is to be mixed with water and applied to labeled crops for selective postemergence control of broadleaf weeds, Weed control is best when the product is applied to actively growing weeds up to 4 inches in height. F4113 is a contact and systemic herbicide. F4113 is rapidly absorbed through the foliage of plants. To avoid significant crop response, applications should not be made within 6 - 8 hours of either rain or irrigation. Within a few hours following application, the foliage of susceptible weeds show signs of desiccation, and in subsequent days necrosis and death of the plant occur. Due to environmental conditions and with certain spray tank additives, some herbicidal symptoms may appear on the crop. However, the crop recovers quickly with no loss in yield. Extremes in environmental conditions such as temperalure, moisture, soil conditions, and cultural practices may affect the activity of F4113. Under warm moist conditions, herbicide symptoms may be accelerated. While under very dry conditions, the expression of herbicide symptoms may be delayed. and weeds hardened off by drought are less susceptible to F4113. Tank Mixtures F4113 may be tank mixed with other herbicides to control weeds not listed on this label. Read and follow all manufacturers' label recommendations for the companion herbicide except for specific recommendations on this label. Tank mixtures of F4113 with EC formulations of other crop protection products, crop oil concentrate, methylated seed oil, silicone based adjuvant, 28% nitrogen or ammonium sulfate may increase crop response. Adjuvant Use Requirements Use a non-ionic surfactant (NISI having at least 80% active ingredient at 0,25% vtv (2 pints per 100 gallons of spray solution) or a 28% nitrogen (UAN) at 2 to 4 quarts per 100 gallons of spray solution. AmmoniUm sulfate (AMS) may be used at 2-4 pounds per acre where recommended by those companion herbicides listed on this label. In the latter case, the level of leaf speckling may be higher than with NIS alone. Crop oil (CDC) or crop oil piuS either 28% nitrogen or ammonium sulfate may be used with companion herbicides listed on this label and may be recommended in certain Situations. Mixing and Loading Instructions: Fill the spray tank 3/4 full with clean water. Make sure the agitation system is operating while adding the recommended amount of ingredients uSing the fo!lowmg order: dry formulations (e.g., wettable powders. dry flowables) firs!. liquid suspensions (e.g., flowables) next and finally liquids (e.g., EC's). Complete filling the spray lank to the desired level. The spray tank agitation should be suffiCient to ensure uniform spray mixture during application and until the spray tank has been emptied. VVhen tank mixing with other products. F4113 should be mixed in the spray tank after dry formulations. if used. After the F4113 is thoroughly mixed, add the other products as specified on their label. Ensure the compatibility of other prOducts with F4113 before mixing them together in the spray tank. AVOid the Information on Droplet Size The most effective way to reduce drift potential is to apply large droplets. The best drift management strategy is to apply the largest droplets that provide sufficient coverage and control. Applying larger droplets reduces drift potential. but will not prevent drift if applications are made improperly, or under unfavorable environmental conditions (See Wind, Temperature and Humidity, and Temperature Inversions). Controlling Spray Droplet Size·· Volume - Use high flow rate nozzles to apply the highest practical spray volume. Nozzles with higher rated flows produce larger droplets. Pressure - Do not exceed the nozzle manufacturer's recommended pressures. For many nozzle types lower pressure produces larger droplets. \Nhen higher flow rates are needed, use higher flow rate nozzles instead of increasing pressure. Number of nozzles - Use the minimum number of nozzles that provide uniform coverage. Nozzle Orientation - For aerial application, orient nozzles so that the spray is released parallel to the airstream produces larger droplets than other orientations and is the recommended practice. Significant deflection from horizontal will reduce droplet size and increase drift potential. Nozzle Type - Use a nozzle type that is designed for the intended application. With most nozzle types. narrower spray angles produce larger droplets. Consider using low drift nozzles. Solid stream nozzles oriented straight back produce the largest droplets and the lowest drift. Boom Length - For some aerial use patterns, reducing the effective boom length to less than 3/4 of the wingspan or rotor length may further reduce drift without reducing swath width. Application Height - Aerial applications should not be made at a height greater than 10 feet above the top of the target plants unless a greater height is required for aircraft safety. Making applications at the lowest height that is safe reduces exposure of droplets to evaporation and wind. Swath Adjustment - \JV'hen aerial applications are made with a crosswind, the swath will be displaced downwind. Therefore, on the upwind and downwind edges of the field, the applicator must compensate for this displacement by adjusting the path of the aircraft upwind. Swath adjustment distance should increase, with increasing drift polential (higher wind, smaller drops, etc.) Wind - Drift potential is lowest between winds speeds of 3-10 mph. However, many factors, including droplet size and equipment type determine drift potential at any given speed. Application should be avoided below 3 mph due to variable wind direction and high inversion potential. NOTE: Local terrain can influence wind patterns. Every applicator should be familiar with local wind patterns and how they affect spray drift. Temperature and Humidity - VVhen making applications in low relative humidity, set up equipment to produce larger droplets to compensate for evaporation. Droplet evaporation is most severe when conditions are both hot and dry. Temperature Inversions - Applications should not occur during a temperature inversion because drift potential is high. Temperature inversions restrict vertical air mixing, which causes small-suspended droplets to remain in a concentrated cloud. This cloud can move in unpredictable directions due to the light variable winds common during inversions. Temperature inversions are characterized by increasing temperatures with altitude and are common on nights with limited cloud cover and light to no wind. They begin to form as the sun sets and often continue into the morning. Their presence can be indicated by ground fog; however, if fog is not present, inversions can also be identified by the movement of smoke from a ground source or an aircraft smoke generator. Smoke that layers and moves laterally in a concentrated cloud (under low wind conditions) indicates an inversion, while smoke that moves upward and rapidly dissipates indicates good vertical air mixing. Sensitive Araas - The pesticide should only be applied when the wind is blowing away from adjacent sensitive areas (e.g. residential areas, bodies of water. known habitat for threatened or endangered species, non-target cropS). 4 PER ACRE PER SEASON Pear Berries and Small Fruit Cranberries Soybeans Ii F4113 3 day 3 day 3 day 14 days 30 days V10 Growth Stage (grazing or hay operations) CROP ROTATIONAL RESTRICTIONS Following applications of F4113. any reglltered crop may be planted at any time with the following exceptions. For treatments prior to planting. allow at least 3 days before planting the following crops: Cantaloupe, Casaba melon, Cucumber. Egg plant, Endive (elcarole). Garlic, Gourds, Groundcherry, Honeydew melon, Honeyball melons, Mango melons, Muskmelons, Persian melons, all melons, Pumpkin, Summer squash, Winter squash, Tomatlllo, Watermelon, Pepper. and Forage grasses. For all other crops, 12 months. WEEDS CONTROLLED VVhen applied according to directions F4113 will provide control of the following weeds. Optimum control may be achieved when small weeds are treated rather that when they are larger in size. When larger weeds are targeted. use higher rates. VVhen weed density is high, use higher rates. VVhen weeds are hardened off due to weather conditions, use higher rates and use more aggressive spray adjuvants. When weeds are nearing maturity, use higher rates and more aggressive spray adjuvants. When applied at 20 to 24 fluid ounces per acre, F4113 will Drovlde control of the followln n weeds: Amaranthus, Palmer Morninaalorv, oiUed Amaranthus, sr;mv- Momi~ smallflower Ammania, Durole Morninaalorv, scarlet Anoda, Snurred Morni~tall Bedstraw, catchweed Mustard, blue Bittercress Mustard, tansv Bluearass Mustard, tumble Brome, downv 'Mustard, wild Brome, Jananese Nlahtshade, black Burcucumber Niahtshade, Eastern black ButtercUn Nlohtshade, hairv Caroetweed Pennvcress, field Cocklebur Piaweed, Drostrate Corn(nonCiiVOhosate tolerant) P1Qweed, red root Cotton Piaweed, smooth CrabQrass Pinweed, tumble Dandelion, dwarf Poinsettia, wild Fleabane, annual Purslane. common Fleabane, hairv Rocket. London Foxtail Rocket. vellow Flixweed Sand bur, field Goatnrass, 'ointed Sesbania, hemo Groundcher;v: cutleaf Sheoard'sourse Groundcherrv. Wriaht's Smartweed, Pennsvlvania Kochia Snrannieton' Mominoolorv. entireleaf Stinkorass Morni~leaf Sunflower, wild Mominoolorv, Dalmleaf Velvetleaf When applied at 25 to 28 fluid ounces per acre, F4113 will provide control of the following weeds: All the weeds listed above nlus, Bermudaarass Mallow, Venice Cheeseweed Millet. wild oroso Chickweed Nettle, burn ina CUDorass, wooly Nettle, stinaina EcTInta Panicum, browntoo Fleabane, rouch Panicum, fall Goosenrass Panicum, Texas Henbit Radish, wild Itcharass Raoweed, common Johnsonnrass. seedlmn Shattercane Jointvetch. Indian Sou rae, nodding Jointvetch, Northern Soume,orostrate Jimsonweed 5Ou",e. spotted Knotweed, oro strate Source, uorioht Lambsnuarters, common Wallflower, bushy Lettuce~ricklV WitchQrass Mallow, common When applied at over 28 fluid ounces per acre, F4113 will provide control of the following weeds. All the weeds listed above nlus, Broad leaf sianalorass Filaree, broad leaf Burclover Filaree, redstem Cheat Filaree, whitestem Cannerleaf, honhornbeam Sowthistle FALLOW SYSTEMS Apply F4113 by ground or aerially alone or with other herbicides in the fallow period prior to planting or the emergence of any crop or rotational crop listed on this label to cOntrol or suppress annual broad leaf weeds. For best performance, make applications to young and actively growing weeds up to 4 inches high or rosettes less than 3 inches across. Coverage is essential for good weed control. Apply F4113 at 16 to 40 fluid ounces per acre in fallow systems. A non ionic surfactant or crop oii concentrate must be used to enhance activity of F4113 in fallow systems. Use a nonionic suriactant at 0.25% vlv (2 pints per 100 gallons of spray solution) having at least 80% active ingredient or a petroleum or vegetable seed based crop oil concentrate at 1.5 to 2.0 pints per acre. 5 lJIJhen tank mixing F4113 with other products, be sure the F4113 is mixed in the spray tank water after dry formulations, if used. For specific mixing instructions, refer to the Mixing and Loading Instructions under the GENERAL INFORMATION section. For all products used in tank mixes, refer to the specific product labels for all restrictions on tank mixing and observe all label precautions, instructions and rotational cropping restrictions. BURNDOWN (PREPLANT, PREEMERGENCE and AT-PLANT) Apply F4113 alone or with other herbicides or liquid fertilizers as a burn-down treatment pnor to planting or emergence of labeled crops to control or suppress grass and broadleaf weeds. For best periormance, make applications to actively growing weeds up to 4 inches high or rosettes less than 3 inches across. Coverage is essential for good control. Use a non ionic suriactant at 0,25% vlv (2 pints per 100 gallons of spray solution) having at least 80% active ingredient or a petroleum or vegetable seed based crop oil concentrate at 1.5 to 2.0 pints per acre. lJIJhen tank mixing F4113 with other products, be sure the F4113 is mixed in the spray tank water after dry formulations, if used. lfoIhen tank mixing with fertilizer solutions be sure to use an F4113 slurry mixture. For specific mixing instructions, refer to the Mixing and Loading instructions under the GENERAL INFORMATION section. For all products used in tank mixes, refer to the speCific product labels for all restrictions on tank mixing and observe all label precautions, instructions and rotational CropplOg restrictions. Precautions: VVhen applying F4113 prior to transplanting crops into plastiC mulch, care must be taken to remove residues of F4113 from the plastic prior to transplanting. SPOT TREATMENT F4113 may be applied as a spot treatment for the control of weeds in the following crops: corn, cotton, sorghum, soybeans. barley, buckwheat, millet, rye, triticale and wheal. Refer to the "HAND-HELD and HIGH-VOLUME EQU1PMENr section for additional information and dilution charts. Restrictions Treatments must be made prior to: Seed head formation in grains pod set in soybeans boll opening in cotton. HOODED SPRAYER APPLICATIONS F4113 may be applied to the following crops using hooded sprayers in accordance with specific use directions as staled in the following Directions for Use section. Corn, Cotton, Peanuts, Sugarcane, Barley, Buckwheat, Millet. Rye, Oats, Triticale. VVileat, Calamondin, Chironja, Citron, Grapefruit, Kumquat, Lemon, Lime, Mandarin Orange, Orange, Pummelo, Tangelo, Tangors, Almond, Beechnut, Brazil nut, Butternut, Cashew, Chestnut, Chinquapin, Filbert, Hickory nut, Macadamia, Pecan, Walnut, Grapes, Kiwi, Apple, Apricot, Cherry (sweet and sour). Loquat, Mayhaw, Nectarine, Olive. Peach, Pear, Plum, Prune, Quince, Artichoke(Jerusalem), Beans, Beet greens, Beets(red and sugar), Broccoli, Brussels sprouts, Cabbage, Chinese cabbage, Cantaloupe, Carrot. Cauliflower, Casaba melon, Celeriac, Celery, Chard(Swiss), Chicory, Collards, Crenshaw melon, Cucumber. Egg plant, Endive (escarole), Garlic, Gourds, Groundcherry, Melon (honeydew and honeybatl), Horseradish, Kale, Kohlrabi, Leek, Lentils, Lettuce, Mango melon, Melons (all), Muskmelon, Mustard greens, Okra, Onion, Parsley, Parsnips, Peas, Pepper. Persian melon, Potato(lrish and sweet), Pumpkin, Radish, Rape greens, Rhubarb, Shallot, Spinach, Squash(summer and winter), Tomatillo, Tomato, Turnip, Turnip. Watermelon, Yams, Blackberry, Boysenberry, Cranberry, Currant, Elderberry, Gooseberry, Huckleberry, Raspberry(red and blaCk), Forage grasses, Acerola, Atemoye, Avocado, Banana, Canistel, Cherimoya, Cocoa beans, Coffee, Dates, Figs, Guava, Jaboticaba, Longan, Luchee, Mango, Papaya, Passion fruit, Persimmons. Pomegranate. Sapodilla, Sapote(black, mamey) Sugar apple. Tea Directions for Use: F4113 may be applied with hooded sprayers to control labeled weeds between the rows of the above listed crops. This treatment may be made to crops grown in rows, and includes crops grown in rows where mulch or plastic barriers are used as a weed control tool in the drill or plant line. F4113 may be applied at rates up to 40 ounces per broadcast acre not to exceed the amount listed In the Maximum Allowable F4113 Use Table above, in a minimum of 10 gallons per acre of finished spray. F4113 may be tankmixed with other pesticides registered for this treatment pattern. For best performance. make application to actively growing weeds up to 4 inches tall and rosettes less than 3 inches across. Coverage is essential for good control. Use a nonionic surfactant at 0.25% v/v (2 pints per 100 gallons of spray solution) having at least 80% active ingredient or a petroleum or vegetable seed based crop oil concentrate at 1.5 to 2.0 pints per acre. Hooded sprayers must be designed, adjusted and operated in such a manner as to prevent any spray deposition to green stem, leaf tissue, flowers or fruit of the crop. The hooded sprayer should be designed and operated so as to totally enclose the spray pattern. Sprayers should be operated in such a manner as to minimize vertical movement such as bouncing or the raising of the equipment during application. Sprayers should not be operated in excess of five (5) miles per hour to minimize such bouncing. Extreme care must be taken during operations in fields where there is undulation of the soil surface, deep furrows, drains or other contours which would disturb the adjustment and positioning of the spray equipment and/or the spray pattern. Applications must not be made when wind conditions are such that spray patterns may be disturbed and result in spray deposition to sensitive planls or plant parts. Precautions: Crop injury will occur when spray is allowed to come in contact with the leaves, green stem tissue. flowers or fruit of the crop. Restrictions: Do not apply more than 40 fluid ounces during the preplant timing and no more than 80 fluid ounces in season as a row middle application. Do not apply more than 120 flUid ounces per crop season as a hooded sprayer application. Do not apply within 14 days of harvest. HARVEST AID TREATMENT F4113 may be applied to soybeans and the cereal grain crops (corn, rice, grain sorghum. wheat) to defoliate and/or desiccate troublesome grass and broadleaf weeds such as morninggJories, pigweeds, velvetleaf and others that may be present at harvest. F4113 may be used alone or as a tank mixture with other harvest aids. Applications should be made when the crop is mature and the grain has begun to dry down, or according to Extension Service recommendations in the use area. Apply F4113 as a broadcast spray at rates not to exceed the amount as listed in the MAXIMUM ALLOWABLE F4113 USE TABLE above. If treatments of F4113 have been made to the crop eanier, that volume must be considered in determining the maximum use rate as a harvest aid treatment. Applications should be made in spray volume sufficient to provide complete coverage of fOliage. Use a minimum of 10 gallons of finished spray per acre for ground application and 5 gallons per acre for aerial application. Use a nonionic surfactant at 0.25% v/v (2 pints per 100 gallons of spray solution) having at least 80% active ingredient or a petroleum or vegetable seed based crop oil concentrate at 1.5 to 2.0 pints per acre. Do not apply more than 26 fluid ounces of this product per acre to wheat. Do not apply within 7 days of harvest. Coverage is essential for satisfactory performance. Repeat application If necessary. If applied as a tank mixture, refer to the other product's label for restrictions on tank mixing, and observe all label precautions, instructions and rotational cropping restrictions. 6 CORN Field Corn, Seed Corn, Popcorn, Corn Silage, and Sweet Corn (Processing and Fresh Market) Apply F4113 alone or as a tank mixture with other herbicides to emerged and actively growing weeds. Apply to corn in all tillage systems from 30 days before planting up to 8 leaf collar growth stage. Do not apply when conditions favoring drift exist or wind is above 10 mph. Restriction: 00 not apply F4113 as a banded or broadcast treatment over the top of corn varieties not genetically tolerant to glyphosate herbicide. For best periormance, make application to actively growing weeds up to 4 inches high and rosettes less than 3 inches across. Coverage Is essential for good control. Use a nonionic surfactant at 0.25% v/v (2 pints per 100 gallons of spray solution) having at least 80% active ingredient. Under dry conditions the use of a crop oil concentrate may improve weed control. The use of a crop oil concentrate may increase Jeaf speckling on the treated corn leaves. To control weeds not listed on this label, F4113 may be tank mixed with other herbicides registered for use in corn. lJ\Itlen tank mixing F4113 with other products, be sure the F 4113 is mixed in the spray tank water first. For specific mixing instructions. refer to the Mixing and Loading Instructions under the GENERAL INFORMATION section. Refer to the other product's label for restrictions on tank mixing, and observe all label precautions, instructions. and rotational cropping restrictions. Sprayers should be adjusted to position spray tips a minimum of 18 inches above the crop and operated to aVOid the application of excessive herbicide rates directly over the rows and/or into the whorl of the corn plant. Be aware that overlaps and slower ground speeds while starting, stopping or turning while spraying may result in higher application rates and possible crop response. Preplant. Preemergence and At~Plant Apply F4113 alone or with other herbicides or liquid fertilizers as a burn-