# PRISTINE FUNGICIDE - EPA Reg No: **7969-199** - Registrant: BASF AGRICULTURAL SOLUTIONS US, LLC - Signal word: Caution - Active ingredients: Pyraclostrobin (12.8%); boscalid (25.2%) - Label accepted: 2022-11-30 - Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/007969-00199-20221130.pdf --- UNITED STATES ENVIRONMENTAL PROTECTION AGENCY WASHINGTON, DC 20460 OFFICE OF CHEMICAL SAFETY AND POLLUTION PREVENTION November 30, 2022 Quinn Peacock Product Registration Manager BASF Corporation P.O. Box 13528, 26 Davis Drive Research Triangle Park, NC 27709 Subject: Registration Review Label Mitigation for Boscalid and Pyraclostrobin Product Name: PRISTINE FUNGICIDE EPA Registration Number: 7969-199 Application Dates: 2/2/2021 and 12/15/2021 Decision Numbers: 570470 and 588850 Dear Quinn Peacock: The Agency, in accordance with the Federal Insecticide, Fungicide and Rodenticide Act (FIFRA), as amended, has completed reviewing all the information submitted with your application to support the Registration Review of the above referenced product in connection with the Boscalid and Pyraclostrobin Interim Decisions, and has concluded that your submission is acceptable. The label referred to above, submitted in connection with registration under FIFRA, as amended, is acceptable. Should you wish to add/retain a reference to the company’s website on your label, then please be aware that the website becomes labeling under the Federal Insecticide Fungicide and Rodenticide Act and is subject to review by the Agency. If the website is false or misleading, the product would be misbranded and unlawful to sell or distribute under FIFRA section 12(a)(1)(E). 40 CFR 156.10(a)(5) list examples of statements EPA may consider false or misleading. In addition, regardless of whether a website is referenced on your product’s label, claims made on the website may not substantially differ from those claims approved through the registration process. Therefore, should the Agency find or if it is brought to our attention that a website contains false or misleading statements or claims substantially differing from the EPA approved registration, the website will be referred to the EPA’s Office of Enforcement and Compliance. A stamped copy of your labeling is enclosed for your records. This labeling supersedes all previously accepted labeling. You must submit one copy of the final printed labeling before you release the product for shipment with the new labeling. In accordance with 40 CFR 152.130(c), you may distribute or sell this product under the previously approved labeling for 12 months from the date of this letter. After 12 months, you may only distribute or sell this product if it bears this new revised labeling or subsequently approved labeling. “To distribute or sell” is defined under FIFRA section 2(gg) and its implementing regulation at 40 CFR 152.3. Page 2 of 2 EPA Reg. No. 7969-199 Decision No. 570470 and 588850 If you have any questions about this letter, please contact Quinn Gavin via email at gavin.quinn@epa.gov. Sincerely, Linda Arrington, Branch Chief Risk Management and Implementation Branch 4 Pesticide Re-Evaluation Division Office of Pesticide Programs Enclosure Boscalid Group 7 Fungicide Pyraclostrobin Group 11 Fungicide For use in disease control and plant health in the following crops: alfalfa; avocado; Belgium endive; berries; Brassica, head and stem; Brassica, leafy greens (except watercress); bulb vegetables; carrot; celery; celtuce; citrus fruit; cotton; cucurbit vegetables; dill seed; Florence fennel; fruiting vegetables; globe artichoke; grape; herbs; hops; kohlrabi; leaf petiole vegetables; leafy greens; low growing berry (except cranberry); oilseed crops; pea and bean, dried shelled, except soybean, subgroup 6C; peanut; persimmon; pome fruit; root vegetables (except sugar beet); small fruit, vine climbing (except fuzzy kiwifruit); soybean; spinach; stone fruit; strawberry; tree nut; tropical fruits (listed); and turnip greens Active Ingredients: pyraclostrobin*: (carbamic acid, [2-[[[1-(4-chlorophenyl)- 1H-pyrazol-3-yl]oxy]methyl]phenyl]methoxy-, methyl ester) ................. 12.8% boscalid**: 3-pyridinecarboxamide,2-chloro-N-(4'-chloro(1,1'-biphenyl)-2-yl)- . . . 25.2% Other Ingredients:............................................... 62.0% Total: ......................................................... 100.0% * 0.128 oz (0.008 lb) of pyraclostrobin in 1 oz of product ** 0.252 oz (0.0158 lb) of boscalid in 1 oz of product EPA Reg. No. 7969-199 EPA Est. No. KEEP OUT OF REACH OF CHILDREN CAUTION/PRECAUCION Si usted no entiende la etiqueta, busque a alguien para que se la explique a usted en detalle. (If you do not understand the label, find someone to explain it to you in detail.) See full label for complete First Aid, Precautionary Statements, Directions For Use, Conditions of Sale and Warranty, and state-specific crop and/or use site restrictions. In case of an emergency endangering life or property involving this product, call day or night, 1-800-832-HELP (4357). Net Contents: BASF Corporation 26 Davis Drive, Research Triangle Park, NC 27709 Nov 30, 2022 7969-199 2 Precautionary Statements Hazards to Humans and Domestic Animals CAUTION. Harmful if swallowed or absorbed through skin. Causes moderate eye irritation. Avoid contact with skin, eyes or clothing. Prolonged or frequently repeated skin contact may cause allergic reaction in some individu- als. Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco or using the toilet. Personal Protective Equipment (PPE) Applicators and other handlers must wear: • Protective eyewear (goggles, face shield or safety glasses) • Long-sleeved shirt and long pants • Chemical-resistant gloves made of: barrier laminate, butyl rubber ≥ 14 mils, nitrile rubber ≥ 14 mils, neoprene rubber ≥ 14 mils, natural rubber ≥ 14 mils, polyethylene, polyvinyl chloride ≥ 14 mils, or viton ≥ 14 mils • Shoes plus socks User Safety Requirements Follow the manufacturer’s instructions for cleaning and maintaining PPE. If no such instructions for washables exist, use detergent and hot water. Keep and wash PPE separately from other laundry. Engineering Controls Statement When handlers use closed systems, enclosed cabs, or air- craft in a manner that meets the requirements listed in the Worker Protection Standard (WPS) for agricultural pesti- cides [40 CFR 170.240(d)(4-6)], the handler PPE requirements may be reduced or modified as specified in the WPS. USER SAFETY RECOMMENDATIONS Users should: • Remove clothing/PPE immediately if pesticide gets inside. Then wash thoroughly and put on clean clothing. • Remove clothing/PPE immediately after handling this product. Wash the outside of gloves before removing. As soon as possible, wash thoroughly and change into clean clothing. Environmental Hazards This pesticide is toxic to fish and aquatic invertebrates. Drift and runoff may be hazardous to aquatic organisms in water adjacent to treated areas. DO NOT apply directly to water, areas where surface water is present, or intertidal areas below the mean high water mark. DO NOT contami- nate water when disposing of equipment washwaters or rinsate. Groundwater Advisory Boscalid and pyraclostrobin are known to leach through soil into groundwater under certain conditions as a result of label use. These chemicals may leach into groundwater if used in areas where soils are permeable, particularly where the water table is shallow. Surface Water Advisory This product may impact surface water quality due to run- off of rain water. This is especially true for poorly draining soils and soils with shallow groundwater. This product is classified as having high potential for reaching surface water via runoff for several months or more after applica- tion. A level, well-maintained vegetative buffer strip between areas to which this product is applied and sur- face water features including ponds, streams, and springs will reduce the potential loading of boscalid and FIRST AID If on skin or clothing • Take off contaminated clothing. • Rinse skin immediately with plenty of water for 15 to 20 minutes. • Call a poison control center or doctor for treatment advice. If swallowed • Call a poison control center or doctor immediately for treatment advice. • Have person sip a glass of water if able to swallow. • DO NOT induce vomiting unless told to do so by a poison control center or doctor. • DO NOT give anything by mouth to an unconscious person. If in eyes • Hold eyes open and rinse slowly and gently with water for 15 to 20 minutes. • Remove contact lenses, if present, after first 5 minutes; then continue rinsing eyes. • Call a poison control center or doctor for treatment advice. If inhaled • Move person to fresh air. • If person is not breathing, call 911 or an ambulance; then give artificial respiration, prefer- ably by mouth to mouth, if possible. • Call a poison control center or doctor for further treatment advice. HOTLINE NUMBER Have the product container or label with you when calling a poison control center or doctor or going for treatment. You may also contact BASF Corporation for emergency medical treatment information: 1-800-832-HELP (4357). 3 pyraclostrobin from runoff water and sediment. Runoff of this product will be reduced by avoiding applications when rainfall or irrigation is expected to occur within 48 hours. Sound erosion control practices will reduce this product’s contribution to surface water contamination. Directions For Use It is a violation of federal law to use this product in a man- ner inconsistent with its labeling. DO NOT apply this product in a way that will contact workers or other per- sons, either directly or through drift. Only protected handlers may be in the area during application. For any requirements specific to your state or tribe, consult the agency responsible for pesticide regulation. AGRICULTURAL USE REQUIREMENTS Use this product only in accordance with its labeling and with the Worker Protection Standard, 40 CFR part 170. This standard contains requirements for the protection of agricultural workers on farms, forests, nurseries, and greenhouses, and handlers of agricultural pesticides. It contains requirements for training, decontamination, notification, and emergency assistance. It also contains specific instructions and exceptions pertaining to the statements on this label about personal protective equipment (PPE), notification to workers and restricted- entry interval. The requirements in this box only apply to uses of this product that are covered by the Worker Protection Standard. DO NOT enter or allow worker entry into treated areas during the restricted-entry interval (REI) of 12 hours. Exceptions: DO NOT allow workers to perform cane tying and leaf pulling tasks on grapes for 5 days after application. DO NOT allow workers to perform cane turning or cane girdling tasks on table grapes grown on T-trellis systems for 5 days after application. Notify work- ers of these prohibitions. PPE required for early entry to treated areas that is per- mitted under the Worker Protection Standard and that involves contact with anything that has been treated, including plants, soil, or water, is: • Protective eyewear (goggles, faceshield or safety glasses) • Coveralls • Chemical-resistant gloves made of: barrier laminate, butyl rubber ≥ 14 mils, nitrile rubber ≥ 14 mils, neoprene rubber ≥ 14 mils, natural rubber ≥ 14 mils, polyethylene, polyvinyl chloride ≥ 14 mils, or viton ≥ 14 mils • Shoes plus socks STORAGE AND DISPOSAL DO NOT contaminate water, food, or feed by storage or disposal. Pesticide Storage Store in original containers only. Keep container closed when not in use. DO NOT store near food or feed. Pesticide Disposal Wastes resulting from using this product may be dis- posed of on-site or at an approved waste disposal facility. If these wastes cannot be disposed of according to label instructions, contact your state pesticide agency or environmental control agency, or the Hazardous Waste representatives at the nearest EPA Regional Office for guidance. Container Handling Nonrefillable Container. DO NOT reuse or refill this container. Triple rinse or pressure rinse container (or equivalent) promptly after emptying; then offer for recy- cling, if available, or reconditioning, if appropriate, or puncture and dispose of in a sanitary landfill, or by incin- eration, or by other procedures approved by state and local authorities. Triple rinse containers small enough to shake (capacity ≤ 50 pounds) as follows: Empty the remaining contents into application equipment or a mix tank. Fill the container 1/4 full with water and recap. Shake for 10 seconds. Pour rinsate into application equipment or a mix tank, or store rinsate for later use or disposal. Drain for 10 seconds after the flow begins to drip. Repeat this procedure two more times. Triple rinse containers too large to shake (capacity > 50 pounds) as follows: Empty the remaining contents into application equipment or a mix tank. Fill the container 1/4 full with water. Replace and tighten closures. Tip container on its side and roll it back and forth, ensuring at least one complete revolution, for 30 seconds. Stand the container on its end and tip it back and forth several times. Turn the container over onto its other end and tip it back and forth several times. Empty the rinsate into application equipment or a mix tank, or store rinsate for later use or disposal. Repeat this procedure two more times. Pressure rinse as follows: Empty the remaining con- tents into application equipment or mix tank. Hold container upside down over application equipment or mix tank, or collect rinsate for later use or disposal. Insert pressure rinsing nozzle in the side of the container and rinse at about 40 PSI for at least 30 seconds. Drain for 10 seconds after the flow begins to drip. 4 In Case of Emergency In case of large-scale spillage regarding this product, call: • CHEMTREC 1-800-424-9300 • BASF Corporation 1-800-832-HELP (4357) In case of medical emergency regarding this product, call: • Your local doctor for immediate treatment • Your local poison control center (hospital) • BASF Corporation 1-800-832-HELP (4357) Steps to be taken in case material is released or spilled: • In case of spill on floor or paved surfaces, mop or sweep spill; then remove to chemical waste storage area until proper disposal can be made if product cannot be used according to label. • Dike and contain the spill with inert material (sand, earth, etc.) and transfer liquid and solid diking material to sepa- rate containers for disposal. • Remove contaminated clothing, and wash affected skin areas with soap and water. • Wash clothing before reuse. • Keep the spill out of all sewers and open bodies of water. Product Information This package contains Pristine® fungicide, a water dis- persible granule (WG). The active ingredients in Pristine belong to two classes of fungicides, the strobilurins and anilides. Preventive applications optimize disease control resulting in improved plant health. The increase in plant health comes from the combined effect of disease control (including fungal diseases listed in Crop-specific direc- tions), improved growth efficiency and improved stress response. Overall increased plant health may result in an improvement in crop growth and crop quality as well as increased crop yields. Pristine is effective against patho- gens resistant to other fungicides. Pristine has a protective effect because it inhibits spore germination. It also has a curative effect because it inhibits mycelial growth and sporulation of the fungus on the leaf surface. However, optimum disease control is achieved when Pristine is applied in a regularly scheduled protective spray program and is used in a rotation program with other fungicides. Because of its high specific activity and rain- fastness, Pristine has good residual activity against target fungi. Information regarding the contents and levels of metals in this product is available on the internet at http://www.aapfco.org/metals.htm. Pristine is not for use in greenhouse or transplant production. Sensitive Crop Precaution Grapes - DO NOT use on Concord or Noiret (NY73.0136.17) due to foliar injury. Possible foliar injury could occur to Worden, Fredonia, Niagara, Steuben, Rougeon or related grape varieties. Use special care when applying Pristine to prevent contact with these sensitive varieties. Not all varieties have been thoroughly tested. Consult a BASF representative for more information con- cerning these sensitive grape varieties. Thoroughly rinse spray equipment, including the inside of the tank, hoses and nozzles after and before using the same equipment on grape varieties sensitive to Pristine. Blueberry (highbush and lowbush) - DO NOT apply Pristine to blueberries as a tank mix with other pesticide products except fungicide products that contain captan (N-Trichloromethythio-4-cyclohexene-1,2-dicarboxamide) as the ONLY active ingredient. DO NOT apply Pristine as a tank mix with adjuvants, liquid fertilizers, nutrients or other additives. Only use water as the spray carrier. Modes of Action Pyraclostrobin and boscalid, the active ingredients of Pristine, belong to the groups of respiration inhibitors classified as target site of action Group 11 and Group 7 fungicides, respectively. Resistance Management For resistance management, please note that Pristine contains both a Group 7 (boscalid) and Group 11 (pyraclostrobin) fungicide. Any fungal population may con- tain individuals naturally resistant to Pristine and other Group 7 or Group 11 fungicides. A gradual or total loss of pest control may occur over time if fungicides from these groups are used repeatedly in the same fields. Appropriate resistance-management strategies must be followed. Pristine provides effective resistance management of most of its target pathogens because it is a premix of two fungicides with different modes of action. Pristine is effective against pathogens resistant to fungicides with modes of action different from those of target site Group 7 and Group 11, including dicarboximides, sterol inhibitors, benzimidazoles, or phenylamides. Pristine is also effec- tive against certain pathogens with resistance to Group 11 fungicides. However, fungal isolates resistant to Group 7 or Group 11 fungicides may eventually dominate the fun- gal population if Group 7 or Group 11 fungicides are used predominantly and repeatedly in the same field in succes- sive years as the primary method of control for the targeted pathogen species. This may result in reduction of disease control by Pristine or other Group 7 or Group 11 fungicides, especially if resistance to either Group 7 or Group 11 fungicides is already present in the pathogen population. To maintain the performance of Pristine in the field, DO NOT exceed the specified number of applica- tions of Pristine and the total number of applications of Pristine per year stated in Restrictions and Limitations and crop-specific use requirements. Adhere to the label instructions regarding the sequential use of Pristine or other target site of action Group 7 and Group 11 fungicides that have a similar site of action on the same pathogens. 5 To delay the development of fungicide resistance: • Rotate - Rotate the use of Pristine® fungicide or other Group 7 and Group 11 fungicides within a growing sea- son sequence with different mode of action groups that control the same pathogens. • Tank Mixtures - Use tank mixtures with fungicides from different target site of action groups that are registered/ permitted for the same use and that are effective against the pathogens of concern. Use at least the minimum labeled rates of each fungicide in the tank mix. • Integrated Pest Management (IPM) - Integrate Pristine into an overall disease and pest management program. Follow cultural practices known to reduce disease development. Consult your local extension spe- cialist, certified crop advisor and/or BASF representative for additional IPM strategies established for your area. Pristine may be used in Agricultural Extension advisory (disease forecasting) programs which base application timing on environmental factors favorable for disease development. • Monitoring - Monitor efficacy of all fungicides used in the disease management program against the targeted pathogen and record other factors that may influence fungicide performance and/or disease development. Monitor treated fungal populations for resistance development. • Reporting - If a Group 7 or Group 11 target site fungi- cide, including Pristine, appears to be less effective or no longer effective against a pathogen that it previously controlled or suppressed, contact a BASF representa- tive, local extension specialist, or certified crop advisor to assist in determining the cause of reduced performance. Cleaning Spray Equipment Clean spray equipment thoroughly before and after apply- ing this product, particularly if a product with the potential to injure crops was used prior to Pristine. Application Instructions Apply directed rates of Pristine as instructed by Table 3. Pristine® fungicide Crop-specific Requirements . Under low-level disease conditions, use the minimum application rates. Use maximum application rates and the shorter application interval for severe or threatening dis- ease conditions. Ground application is advised for thorough coverage. DO NOT apply by air to dill seed, herb, peanut, and turnip greens. For all other crops listed on this label, aerial application can be made, including conditions where applications are not possible using ground equipment. Pristine can be applied through sprin- kler irrigation equipment, except for use on dill seed, herb, and turnip greens. Check equipment frequently for calibration. Ground Application Apply Pristine in sufficient water to ensure thorough cov- erage of foliage, bloom, and fruit. Thorough coverage is required for optimum disease control. Directed or Banded Sprays The application rates on the Pristine label reflect the amount of product uniformly applied over an acre of ground on a broadcast basis. In some crops, apply Pristine as a directed or banded spray over the rows or plant beds with the alleys or row middles left unsprayed. For such uses, reduce the labeled Pristine rates in proportion to the area actually sprayed. This adjustment is necessary to avoid applying the product at use rates higher than permitted according to label directions. Use the following formula to determine the broadcast equivalent rate for doing directed or banded sprays: sprayed bed width + unsprayed row middles width = total row width sprayed bed width in inches x broadcast rate = band rate total row width in inches treated acre field acre Example: A directed spray application will be made to 45-inch plant beds that are separated by 15-inch unsprayed row middles. 45 inches sprayed bed width + 15 inches unsprayed row middles = 60 inches total row width The calculation to determine the appropriate equivalent rate of product to use for this situation based on a label broadcast rate of 12 ozs/acre follows: 45 inches sprayed bed width x 12 ozs Pristine = 9 ozs Pristine 60 inches total row width treated acre field acre Aerial Application For aerial application in New York State, DO NOT apply within 100 feet of aquatic habitats (including, but not limited to lakes, reservoirs, rivers, streams, mar shes, ponds, estuaries, and commercial fish ponds). DO NOT apply by air to dill seed, herb, peanut, and turnip greens. For all other crops listed on this label, aerial appli- cation can be made and thorough coverage is required to obtain optimum disease control. Avoid applications under conditions when uniform coverage cannot be obtained or when spray drift may occur. Use no less than 5 gallons of spray solution per acre. For aerial application to citrus fruit, grape, hops, pome fruit, stone fruit, and tree nut, use no less than 10 gallons of spray solution per acre. Thorough coverage is required for optimum disease control. 6 MANDATORY SPRAY DRIFT MANAGEMENT Aerial Applications • DO NOT release spray at a height greater than 10 ft above the ground or vegetative canopy, unless a great- er application height is necessary for pilot safety. • Applicators are required to select nozzle and pressure that deliver a medium or coarser droplet size (ASABE S641). • DO NOT apply when wind speeds exceed 15 miles per hour at the application site. If the windspeed is greater than 10 miles per hour, the boom length must be 65% or less of the wingspan for fixed-wing aircraft and 75% or less of the rotor diameter for helicopters. Otherwise, the boom length must be 75% or less of the wingspan for fixed-wing aircraft and 90% or less of the rotor diameter for helicopters. • If the windspeed is 10 miles per hour or less, applica- tors must use 1/2 swath displacement upwind at the downwind edge of the field. When the windspeed is between 11 to 15 miles per hour, applicators must use 3/4 swath displacement upwind at the downwind edge of the field. • DO NOT apply during temperature inversions. Airblast Applications • Sprays must be directed into the canopy. • DO NOT apply when wind speeds exceed 15 miles per hour at the application site. • User must turn off outward pointing nozzles at row ends and when spraying outer row. • DO NOT apply during temperature inversions. Ground Boom Applications • User must only apply with the release height recom- mended by the manufacturer, but no more than 4 ft above the ground or crop canopy. • Applicators are required to use nozzles and pressure that deliver a medium or coarser droplet size (ASABE S572.1). • DO NOT apply when wind speeds exceed 15 miles per hour at the application site. • DO NOT apply during temperature inversions. SPRAY DRIFT ADVISORIES THE APPLICATOR IS RESPONSIBLE FOR AVOIDING OFF- SITE SPRAY DRIFT. BE AWARE OF NEARBY NONTARGET SITES AND ENVI- RONMENTAL CONDITIONS. Boomless Ground Applications Setting nozzles at the lowest effective height will help to reduce the potential for spray drift. Handheld Technology Applications Take precautions to minimize spray drift. Importance of Droplet Size An effective way to reduce spray drift is to apply large droplets. Use the largest droplets that provide target pest control. While applying larger droplets will reduce spray drift, the potential for drift will be greater if applications are made improperly or under unfavorable environmental conditions. Controlling Droplet Size - Aircraft Adjust Nozzles - Follow nozzle manufacturers’ recom- mendations for setting up nozzles. Generally, to reduce fine droplets, nozzles should be oriented parallel with the airflow in flight. Controlling Droplet Size - Ground Boom • Volume - Increasing the spray volume so that larger droplets are produced will reduce spray drift. Use the highest practical spray volume for the application. If a greater spray volume is needed, consider using a nozzle with a higher flow rate. • Pressure - Use the lowest spray pressure recommend- ed for the nozzle to produce the target spray volume and droplet size. • Spray Nozzle - Use a spray nozzle that is designed for the intended application. Consider using nozzles designed to reduce drift. Release Height - Aircraft Higher release heights increase the potential for spray drift. Boom Height - Ground Boom For ground equipment, the boom should remain level with the crop and have minimal bounce. Shielded Sprayers Shielding the boom or individual nozzles can reduce spray drift. Consider using shielded sprayers. Verify that the shields are not interfering with the uniform deposition of the spray on the target area. Temperature and Humidity When making applications in hot and dry conditions, use larger droplets to reduce effects of evaporation. Temperature Inversions Drift potential is high during a temperature inversion. Temperature inversions are characterized by increasing temperature with altitude and are common on nights with limited cloud cover and light to no wind. The presence of an inversion can be indicated by ground fog or by the movement of smoke from a ground source or an aircraft smoke generator. Smoke that layers and moves laterally in a concentrated cloud (under low wind conditions) indicates an inversion, while smoke that moves upward and rapidly dissipates indicates good vertical air mixing. Avoid applica- tions during temperature inversions. Wind AVOID APPLICATIONS DURING GUSTY WIND CONDI- TIONS. Drift potential generally increases with wind speed. Applicators need to be familiar with local wind patterns and terrain that could affect spray drift. 7 Directions for Use Through Sprinkler Irrigation Systems Sprayer Preparation Clean chemical tank and injector system thoroughly. Flush system with clean water. Application Instructions Apply Pristine® fungicide at rates and timings as described in this label. Use Precautions for Sprinkler Irrigation Applications • DO NOT apply by sprinkler irrigation (chemigation) to dill seed, herb, and turnip greens. For all other crops, this product can be applied through sprinkler irrigation sys- tems including center pivot, lateral move, end tow, side (wheel) roll, traveler, big gun, solid set, or hand move irrigation systems. DO NOT apply this product through any other type of irrigation system. • Add this product to the pesticide supply tank containing sufficient water to maintain a continuous flow by the injection equipment. In continuous moving systems, inject this product-water mixture continuously, applying the labeled rate per acre for that crop. DO NOT exceed 1/2 inch (13,577 gallons) per acre. In stationary or non-continuous moving systems, inject the product- water mixture in the last 15 to 30 minutes of each set allowing sufficient time for all of the required pesticide to be applied by all the sprinkler heads and applying the labeled rate per acre for that crop. DO NOT apply when wind speed favors drift beyond the area intended for treatment. Crop injury, lack of effectiveness, or illegal pesticide residues in the crop can result from non uniform distribution of treated water. Thorough coverage of foli- age is required for good control. Maintain good agitation during the entire application period. • If you have questions about calibration, contact a state extension service specialist, equipment manufacturers or other experts. • The system must contain a functional check valve, vacu- um relief valve, and low pressure drain appropriately located on the irrigation pipeline to prevent water-source contamination from backflow. • The pesticide injection pipeline must contain a functional, automatic, quick-closing check valve to prevent the flow of fluid back toward the injection pump. • The pesticide injection pipeline must also contain a func- tional, normally closed, solenoid-operated valve located on the intake side of the injection pump and connected to the system interlock to prevent fluid from being with- drawn from the supply tank when the irrigation system is either automatically or manually shut down. • The system must contain functional interlocking controls to automatically shut off the pesticide injection pump when the water pump motor stops. • The irrigation line or water pump must include a function- al pressure switch, which will stop the water pump motor when the water pressure decreases to the point where pesticide distribution is adversely affected. • Systems must use a metering pump, including a positive displacement injection pump (e.g., diaphragm pump), effectively designed and constructed of materials that are compatible with pesticides and capable of being fitted with a system interlock. • Allow sufficient time for pesticide to be flushed through all lines and all nozzles before turning off irrigation water. A person knowledgeable of the chemigation system and responsible for its operation, or under the supervision of the responsible person, must shut the system down and make necessary adjustments when appropriate. • DO NOT connect an irrigation system used for pesticide application to a public water system unless the pesticide label-prescribed safety devices for public water systems are in place. Specific Instructions for Public Water Systems 1. Public water system means a system for the provision to the public of piped water for human consumption if such system has at least 15 service connections or regularly serves an average of at least 25 individuals daily at least 60 days out of the year. 2. Chemigation systems connected to public water sys- tems must contain a functional, reduced-pressure zone (RPZ) backflow preventer or the functional equivalent in the water supply line upstream from the point of pesti- cide introduction. As an option to the RPZ, discharge the water from the public water system into a reservoir tank prior to pesticide introduction. There must be a complete physical break (air gap) between the outlet end of the fill pipe and the top or overflow rim of the res- ervoir tank of at least twice the inside diameter of the fill pipe. 3. The pesticide injection pipeline must contain a function- al, automatic, quick-closing check valve to prevent the flow of fluid back toward the injection pump. 4. The pesticide injection pipeline must contain a function- al, normally closed, solenoid-operated valve located on the intake side of the injection pump and connected to the system interlock to prevent fluid from being with- drawn from the supply tank when the irrigation system is either automatically or manually shut down. 5. The system must contain functional interlocking controls to automatically shut off the pesticide injection pump when the water pump motor stops, or in cases where there is no water pump, when the water pressure decreases to the point where pesticide distribution is adversely affected. 6. Systems must use a metering pump, including a positive displacement injection pump (e.g., diaphragm pump), effectively designed and constructed of materials that are compatible with pesticides and capable of being fit- ted with a system interlock. 7. DO NOT apply when wind speed favors drift beyond the area intended for treatment. 8 Additives and Tank Mixing Information Under some conditions, the use of additives or adjuvants may improve the performance of Pristine® fungicide. However, all varieties and cultivars have not been tested with possible tank mix combinations. Local conditions can also influence crop response and may not match those under which BASF has conducted testing. Physical incom- patibility, reduced disease control, or crop injury may result from mixing Pristine with other products. Therefore, before using any tank mix (fungicides, insecticides, herbi- cides, liquid fertilizers, biological control products, adjuvants, and additives), test the combination on a small portion of the crop to be treated to ensure that a phytotox- ic response will not occur as a result of application. Consult a BASF representative or local agricultural authori- ties for more information concerning additives. If tank mixtures are used, it is the pesticide user’s respon- sibility to ensure that all products are registered for the intended use. Read and follow the applicable restrictions and limitations and directions for use on all product labels involved in tank mixing. Users must follow the most restric- tive directions for use and precautionary statements of each product in the tank mixture. Pristine can be tank mixed with most fungicides, insecti- cides, herbicides, liquid fertilizers, biological control products, adjuvants, and additives. See Table 3. Pristine ® fungicide Crop-specific Requirements for exceptions. Compatibility Test for Tank Mix Components Add components in the following sequence using 2 tea- spoons for each pound or 1 teaspoon for each pint of label rate per acre: 1. Water - For 100 gallons per acre spray volume, use 16 cups (1 gallon) of water. For other spray volumes, adjust rates accordingly. Use only water from the intend- ed source at the source temperature. 2. Water-dispersible products (dry flowables, wettable powders, suspension concentrates, or suspo- emulsions). Cap the jar and invert 10 cycles. 3. Water-soluble products - Cap the jar and invert 10 cycles. 4. Emulsifiable concentrates (oil concentrate or methyl- ated seed oil when applicable). Cap the jar and invert 10 cycles. 5. Water-soluble additives - Cap the jar and invert 10 cycles. 6. Let the solution stand for 15 minutes. 7. Evaluate the solution for uniformity and stability. The spray solution must not have free oil on the surface, nor fine particles that precipitate to the bottom, nor thick (clabbered) texture. DO NOT use any spray solution that could clog spray nozzles. Mixing Order 1. Water - Begin by filling a thoroughly clean sprayer tank 3/4 full of clean water. 2. Agitation - Maintain constant agitation throughout mix- ing and application. 3. Inductor - If an inductor is used, rinse it thoroughly after each component has been added. 4. Products in PVA bags - Place any product contained in water-soluble PVA bags into the mixing tank. Wait until all water-soluble PVA bags have fully dissolved and the product is evenly mixed in the spray tank before continuing. 5. Water-dispersible products (including Pristine, dry flowables, wettable powders, suspension concentrates, or suspo-emulsions) 6. Water-soluble products 7. Emulsifiable concentrates (including oil concentrates when applicable) 8. Water-soluble additives (including ammonium sulfate [AMS] or urea ammonium nitrate [UAN] when applicable) 9. Remaining quantity of water Make sure that each component is thoroughly mixed and suspended before adding tank mix partners. Maintain constant agitation during application. See Table 3. Pristine ® fungicide Crop-specific Requirements for more details. Restrictions and Limitations • DO NOT exceed the maximum product rate (ozs/A) per year, the maximum product rate per application, or the total number of applications of Pristine per year as stat- ed in Table 1. Pristine ® fungicide Restrictions and Limitations Overview and Table 3. Pristine® fungicide Crop-specific Requirements . Preharvest interval (PHI) restrictions are also included in these tables. • DO NOT apply more than the maximum annual use rate of ai/acre or ozs of product/acre for each specific crop from any combination of products containing pyraclostrobin or boscalid (including Pristine, Endura ® fungicide, Cabrio® EG fungicide, Headline® fungicide). To determine lbs of pyraclostrobin per acre, multiply ozs of product/acre by 0.008. To determine lbs of boscalid per acre, multiply ozs of product/acre by 0.0158. See Table 2. Pristine ® fungicide Rate Conversions for corresponding pounds active ingredi- ent per acre. • Pristine is not for use in greenhouse or transplant production. • Blueberry (highbush and lowbush) - DO NOT apply Pristine to blueberries as a tank mix with other pesticide products except fungicide products that contain captan (N-Trichloromethythio-4-cyclohexene-1,2-dicarboxamide) as the ONLY active ingredient. DO NOT apply Pristine as a tank mix with adjuvants, liquid fertilizers, nutrients, or other additives. Only use water as the spray carrier. 9 • Grape - DO NOT use on Concord or Noiret (NY73.0136.17) due to foliar injury. Possible foliar injury could occur to Worden, Fredonia, Niagara, Steuben, Rougeon or related grape varieties. Not all varieties have been thoroughly tested. • Aerial application in hops - DO NOT make more than one (1) aerial application of Pristine ® fungicide per year and include a myclobutanil product as a tank mix. • DO NOT apply by air to dill seed, herb, peanut, and tur- nip greens. • DO NOT apply through any type of irrigation system (chemigation) to dill seed, herb, and turnip greens. • For aerial application in New York State, DO NOT apply within 100 feet of aquatic habitats (including, but not limited to lakes, reservoirs, rivers, streams, marshes, ponds, estuaries, and commercial fish ponds). • DO NOT use on sugar beet. Crop Rotation Restriction Crops listed on the Pristine label may be planted immedi- ately following the last application. For all other crops, DO NOT plant sooner than 14 days after the last application. 10 Table 1. Pristine® fungicide Restrictions and Limitations Overview* Crop/Crop Group** Minimum Time from Application to Harvest (PHI) (days) Maximum Rate per Application (ozs product/A) Maximum Number of Applications per Year*** Maximum Rate per Year (ozs product/A) Alfalfa (including alfalfa grown for seed) 14 18 3 54 Avocado 01 2 . 5 2 2 5 Belgium endive 19 1.6 (cold storage) 1 3.4 1.8 (forcing) 1 Berry subgroups Bushberry [subgroup 13-07B] 02 3 4 9 2 Caneberry [subgroup 13-07A] 02 3 4 9 2 Low growing berry (except cranberry) [subgroup 13-07G] 02 3 5 1 1 5 Small fruit, vine climbing except fuzzy kiwifruit [subgroup 13-07F] 14 23 5 69 Brassica, head and stem [group 5-16] 02 5 2 5 0 Brassica, leafy greens (except watercress), [subgroup 4-16B] 14 25 2 50 Bulb vegetables [group 3-07] 7 18.5 6 111 Carrot 01 0 . 5 6 6 3 Celery 02 5 2 5 0 Celtuce 02 5 2 5 0 Citrus fruit [group 10-10] 01 8 . 5 4 7 4 Cotton 30 25 2 50 Cucurbit vegetables [group 9] 01 8 . 5 4 7 4 Dill seed**** 01 8 . 5 2 3 7 Florence fennel 02 5 2 5 0 Fruiting vegetables [group 8-10] 0 9.7 6 58.2 Tomato 25 2 69 Globe artichoke 02 3 3 6 9 Grape 14 23 3 69 Herb [subgroup 19A]**** 01 8 . 5 2 3 7 Hops**** 14 28 3 84 Kohlrabi 02 5 2 5 0 Leaf petiole vegetables [subgroup 22B] 02 5 2 5 0 Leafy greens [subgroup 4-16A] 14 25 2 50 Oilseed [group 20] 21 24.5 2 49 Pea and bean, dried shelled, except soybean, [subgroup 6C] 21 25 2 50 Peanut 14 28 3 84 Persimmon 02 3 3 6 9 Pome fruit [group 11-10] 01 8 . 5 4 7 4 (continued) 11 Table 1. Pristine® fungicide Restrictions and Limitations Overview* (continued) Crop/Crop Group** Minimum Time from Application to Harvest (PHI) (days) Maximum Rate per Application (ozs product/A) Maximum Number of Applications per Year*** Maximum Rate per Year (ozs product/A) Root vegetables (except sugar beet) [subgroup 1B] 01 0 . 5 6 6 3 Soybean 21 16 2 32 Spinach 14 25 2 50 Stone fruit [group 12-12] 01 4 . 5 5 7 2 . 5 Strawberry 02 3 5 1 1 5 Tree nut [group 14-12] 14 (for almond - 25 days) 14.5 4 58 Tropical fruits (listed in Table 3) 01 8 . 5 2 3 7 Turnip greens**** 14 25 2 50 * See Table 3. Pristine® fungicide Crop-specific Requirements for complete directions and exceptions, including restrictions and information regarding crop sensitivity and tank mixtures. ** For a complete list of crops labeled within a group, see Table 3. Pristine® fungicide Crop-specific Requirements . *** See Table 3. Pristine® fungicide Crop-specific Requirements for exceptions. **** For additional ground, aerial, and sprinkler irrigation (chemigation) application restrictions and limitations, see Table 3. Pristine® fungicide Crop-specific Requirements . 12 Table 2. Pristine® fungicide Rate Conversions* Product Use Rate (oz/A) lb ai boscalid lb ai pyraclostrobin 0.8 0.013 0.006 0.9 0.014 0.007 1.6 0.025 0.013 1.8 0.028 0.014 3.4 0.054 0.027 8 0.126 0.064 9.7 0.153 0.078 10 0.158 0.080 10.5 0.166 0.084 12 0.190 0.096 12.5 0.198 0.100 14 0.221 0.112 14.5 0.229 0.116 15 0.237 0.120 16 0.253 0.128 16.7 0.264 0.134 18 0.284 0.144 18.5 0.292 0.148 23 0.363 0.184 24.5 0.387 0.196 25 0.395 0.200 28 0.442 0.224 32 0.506 0.256 33.4 0.528 0.267 37 0.585 0.296 49 0.774 0.392 50 0.790 0.400 54 0.853 0.432 58 0.916 0.464 58.2 0.920 0.466 63 0.995 0.504 69 1.09 0.552 72.5 1.15 0.580 74 1.17 0.592 84 1.33 0.672 92 1.45 0.736 111 1.75 0.888 115 1.82 0.920 * Corresponding pounds active ingredient per acre for Product Use Rates (oz/A) in Table 3. Pristine® fungicide Crop-specific Requirements . Also see Table 3. Pristine® fungicide Crop-specific Requirements for the maxi- mum product use rate per year in ozs/A and lb ai. 13 Crop-specific Requirements Table 3. Pristine® fungicide Crop-specific Requirements Crop Target Disease Product Use Rate per Application (ozs/A) Maximum Number of Applications per Year Maximum Product Rate per Year (ozs/A) Minimum Time from Application to Harvest (PHI) (days) Alfalfa (including alfalfa grown for seed) Anthracnose Colletotrichum trifolii Common leaf spot Pseudopeziza medicaginis Downy mildew Peronospora trifoliorum Leaf spot Leptosphaerulina briosiani Powdery mildew Erysiphe pisi Rhizoctonia blight/ Black patch Rhizoctonis spp. Rust Uromyces spp. Spring black stem and Leaf spot Phoma medicaginis Stagonospora leaf spot Stagonospora meliloti Stemphyllium leaf spot Stemphyllium spp. Summer black stem and Leaf spot Cercospora medicaginis Yellow leaf blotch Leptotrichila medicaginis 12 to 18 2 per cutting or 3 total per year* 54 14 White mold/Sclerotinia crown and Stem rot Sclerotinia sclerotiorum, S. trifoliorum Suppression Only: Southern blight Sclerotium rolfsii 14 to 18 (continued) 14 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Alfalfa (including alfalfa grown for seed) (continued) Application Directions. Begin Pristine applications when conditions favorable for disease are expected, but prior to onset of disease development. For stand establishment of fall-seeded alfalfa, begin applications in fall through early winter prior to first snowfall or extended cool, wet conditions. For seed pod protection, begin applications at 10% to 30% bloom. Use the higher rate and shorter interval when disease pressure is high. Using higher rates may improve disease control performance as the crop canopy volume and density increases. Disease control can also be improved when application equipment and spray volume is adjusted to achieve thorough canopy penetration and coverage. Repeat application on a 14-day to 21-day interval if conditions are favorable for disease development. Under some conditions, additives or adjuvants may improve the performance of Pristine. No livestock feeding restrictions. Resistance Management. To limit development of resistance, DO NOT make more than two (2) sequential Pristine applications per cutting or three (3) Pristine applications per year. Alternate to a labeled non-Group 7 or non-Group 11 fungicide with different mode of action following two (2) sequential Pristine applications. Restrictions and Limitations * DO NOT make more than the Maximum Number of Applications per Year for applications made at the maximum Product Use Rate per Application (18 ozs/A contains 0.284 lb boscalid, 0.144 lb pyraclostrobin). Additional applications per year are permitted when a lower Product Use Rate per Application is used, as long as the Maximum Product Rate per Year (54 ozs/A contains 0.853 lb boscalid, 0.432 lb pyraclostrobin) is not exceeded. • Maximum single application rate is 18 ozs/A (0.284 lb boscalid, 0.144 lb pyraclostrobin). • Maximum annual application rate is 54 ozs/A (0.853 lb boscalid, 0.432 lb pyraclostrobin) per year. • DO NOT make more than two (2) Pristine applications per cutting or more than three (3) Pristine applications per year at the high application rate. • Minimum retreatment interval is 14 days. 15 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Use Rate per Application (ozs/A) Maximum Number of Applications per Year Maximum Product Rate per Year (ozs/A) Minimum Time from Application to Harvest (PHI) (days) Avocado[*] Anthracnose Colletotrichum gloeosporioides Scab Sphaceloma perseae 12.5 2 25 0 Application Directions. Begin application of Pristine prior to the onset of disease development and repeat application 7 days later, as needed, or alternate with another labeled fungicide having a different mode of action. Resistance Management. To limit the potential for development of resistance, DO NOT make more than two (2) sequential applications of Pristine or other Group 7 or Group 11 fungicides before alternating to a labeled fungicide with a different mode of action. Restrictions and Limitations • Maximum single application rate is 12.5 ozs/A (0.198 lb boscalid, 0.100 lb pyraclostrobin). • Maximum annual application rate is 25 ozs/A (0.395 lb boscalid, 0.200 lb pyraclostrobin). • DO NOT make more than two (2) applications of Pristine per year. • Minimum retreatment interval is 7 days. • DO NOT apply Pristine as a tank mix with any pesticide product (includes any fungicide, herbicide, or insecticide), fertilizer, nutrient or additive other than nonionic surfactant (NIS). NIS rate not to exceed 11 ozs/100 gallons (0.08% v/v). [Optional text: * Not registered for use in California.] 16 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Use Rate per Application Maximum Number of Applications per Year Maximum Product Rate per Crop per Year (ozs product per 1000 lbs roots) Minimum Time from Application to Harvest (PHI) (days) Belgium endive* Root and crown rot Sclerotinia sclerotiorum Prior to cold storage: 0.8 to 1.6 ozs per 1000 lbs roots 13 . 4 1 9 Prior to forcing: 0.9 to 1.8 ozs per 70 square feet of forcing tray 1 Application Directions. Dosage and frequency/timing of applications. Make one application to the roots when brought into cold storage prior to forcing. Apply again at the beginning of forcing after the roots have been packed in forcing trays. Prior to Cold Storage. Make one application as a spray to the roots as they move along a conveyor belt used to bring roots from field transportation into cold storage bins. Apply 0.8 to 1.6 ozs Pristine in 3.0 to 3.5 gals of water per 1000 lbs roots. Prior to Forcing. Make one application as a spray to the roots at the beginning of forcing, after they have been packed into forcing trays. Apply at the rate of 0.9 to 1.8 ozs of Pristine in approximately 100 fl ozs of water per 70 square feet of forcing tray. Approximately 1000 lbs of roots will fill 70 square feet of forcing tray. Restrictions and Limitations • Maximum single application rate is 1.6 ozs (0.025 lb boscalid, 0.013 lb pyraclostrobin) prior to cold storage and 1.8 ozs (0.028 lb boscalid, 0.014 lb pyraclostrobin) prior to forcing. • Maximum annual application rate is 3.4 ozs Pristine (0.054 lb boscalid, 0.027 lb pyraclostrobin) per 1000 lbs roots per crop per year. • DO NOT make more than two (2) Pristine applications per year, one (1) Pristine application prior to cold storage and one (1) Pristine application prior to forcing. • DO NOT apply after the beginning of forcing. • Minimum time from application to harvest (PHI) is 19 days. * For use in California only. 17 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Use Rate per Application (ozs/A) Maximum Number of Applications per Year Maximum Product Rate per Year (ozs/A) Minimum Time from Application to Harvest (PHI) (days) Berry subgroups Bushberry [subgroup 13-07B]* Aronia berry Black currant Blueberry** (highbush and lowbush) Buffalo currant Chilean guava Currant Elderberry European barberry Gooseberry Highbush cranberry Honeysuckle, edible Huckleberry Jostaberry Juneberry Lingonberry Native currant Red currant Salal Sea buckthorn Caneberry [subgroup 13-07A]* Blackberry (all varieties) Loganberry Raspberry (black and red) Wild raspberry Alternaria leaf spot and fruit rot Alternaria spp. Anthracnose Colletotrichum spp., Elsinoe spp. Botrytis gray mold Botrytis cinerea Leaf spot and blotch Mycosphaerella spp., Septoria spp. Monilinia blight and mummy berry Monilinia spp. Phomopsis leaf spot, twig blight, and fruit rot Phomopsis spp. Powdery mildew Microsphaera spp., Oidium spp., Sphaerotheca spp. Spur blight Didymella spp., Phoma spp. Suppression Only: Rust Arthuriomyces spp., Kuehneola spp., Phragmidium spp., Puccianiastrum spp. 18.5 to 23 4 92 0 (continued) 18 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Berry subgroups (continued) Application Directions. Begin applications of Pristine prior to onset of disease development and continue on a 7-day to 14-day interval. Use the shorter interval and/or the higher rate when disease pressure is high. * For the berries listed in this table (except blueberry), it is impossible for BASF to test all bushberry and caneberry crops for sensitivity to Pristine under all environments and all potential product mixture combinations. Local conditions can also influence crop response and may not match those under which BASF has conducted testing. Proceed with caution with regard to Pristine use, particularly in tank mixes and/or adjuvant combinations on bushberry and caneberry crops. To reduce the risk of berry crop injury, BASF advises testing Pristine or Pristine tank mixtures on a small portion of the crop before broad scale use. To the extent consistent with applicable law, the user assumes all risks associated with adding products to the Pristine spray solution. Refer also to the Conditions of Sale and Warranty section of this label. Resistance Management. To limit the potential for development of resistance, DO NOT make more than two (2) sequential applications of Pristine or other Group 7 or Group 11 fungicides before alternating to a labeled fungicide with a different mode of action. Restrictions and Limitations • Maximum single application rate is 23 ozs/A (0.363 lb boscalid, 0.184 lb pyraclostrobin). • Maximum annual application rate is 92 ozs/A (1.45 lbs boscalid, 0.736 lb pyraclostrobin) per year. • DO NOT make more than four (4) applications of Pristine per year. • Minimum retreatment interval is 7 days. ** Blueberry (highbush and lowbush) is not registered for use in California. For all other states, DO NOT apply Pristine to blueberries as a tank mix with other pesticide products except fungicide products that contain captan (N-Trichloromethythio-4-cyclohexene-1,2-dicarboxamide) as the ONLY active ingredient. DO NOT apply Pristine as a tank mix with adjuvants, liquid fertilizers, nutrients, or other additives. Only use water as the spray carrier. 19 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Use Rate per Application (ozs/A) Maximum Number of Applications per Year Maximum Product Rate per Year (ozs/A) Minimum Time from Application to Harvest (PHI) (days) Berry subgroups (continued) Low growing berry (except cranberry) [subgroup 13-07G]** Bearberry Bilberry Cloudberry Muntries Partridgeberry Anthracnose Colletotrichum spp. Botrytis gray mold Botrytis cinerea Leaf spot Mycosphaerella fragariae Powdery mildew Sphaerotheca macularis 18.5 to 23 5* 115 0 Application Directions. Begin applications of Pristine no later than 10% bloom, or prior to disease development, and continue on a 7-day to 14-day interval. Use the higher rate and the shorter interval when disease pressure is high. For the low growing berries listed in this table, it is impossible for BASF to test all low growing berry crops for sensitivity to Pristine under all environments and all potential product mixture combinations. Local conditions can also influence crop response and may not match those under which BASF has conducted testing. Proceed with caution with regard to Pristine use, particularly in tank mixes and/or adjuvant combinations on low growing berry crops. To reduce the risk of berry crop injury, BASF advises testing Pristine or Pristine tank mixtures on a small portion of the crop before broad scale use. To the extent consistent with applicable law, the user assumes all risks associated with adding products to the Pristine spray solution. Refer also to the Conditions of Sale and Warranty section of this label. Resistance Management. To limit the potential for development of resistance, DO NOT make more than two (2) sequential applications of Pristine or other Group 7 or Group 11 fungicides before alternating to a labeled fungicide with a different mode of action. Restrictions and Limitations * DO NOT make more than the Maximum Number of Applications per Year for applications made at the maximum Product Use Rate per Application (23 ozs/A contains 0.363 lb boscalid, 0.184 lb pyraclostrobin). Additional applications per year are permitted when a lower Product Use Rate per Application is used, as long as the Maximum Product Rate per Year (115 ozs/A contains 1.82 lbs boscalid, 0.920 lb pyraclostrobin) is not exceeded. • Maximum single application rate is 23 ozs/A (0.363 lb boscalid, 0.184 lb pyraclostrobin). • Maximum annual application rate is 115 ozs/A (1.82 lbs boscalid, 0.920 lb pyraclostrobin) per year. • Minimum retreatment interval is 7 days. ** See separate crop table for strawberry use rates and application directions. (continued) 20 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Use Rate per Application (ozs/A) Maximum Number of Applications per Year Maximum Product Rate per Year (ozs/A) Minimum Time from Application to Harvest (PHI) (days) Berry subgroups (continued) Small fruit, vine climbing except fuzzy kiwifruit [subgroup 13-07F]** Amur river grape Gooseberry Kiwifruit, hardy Maypop Schisandra berry Cultivars, varieties and/or hybrids of these Angular leaf spot Mycosphaerella angulata Anthracnose Elsinoe ampelina Black rot Guignardia bidwellii Downy mildew Plasmopara viticola Leaf blight Pseudocercospora vitis Phomopsis cane and leaf spot Phomopsis viticola Powdery mildew Uncinula necator Ripe rot Colletotrichum gloeosporioides Aids in Control Only: Summer bunch rot (Sour rot) Aspergillus spp. and Cladosporium spp. Suppression Only: Botrytis gray mold Botrytis cinerea 8 to 12.5 5* 69 14 Botrytis gray mold Botrytis cinerea 18.5 to 23 3 (continued) 21 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Berry subgroups (continued) Small fruit, vine climbing except fuzzy kiwifruit [subgroup13-07F]** (continued) Application Directions. For powdery mildew control, begin applications of Pristine as of bud break prior to onset of disease, using 8 ozs per acre on a 10-day to 14-day interval. Use 10 to 12.5 ozs per acre on a 14-day to 21-day interval. For black rot and downy mildew control, begin applications of Pristine as of pre-bloom prior to onset of disease and continue applications on a 10-day to 14-day interval. For all other diseases listed except for Botrytis gray mold, begin applications of Pristine prior to onset of disease and continue applications on a 10-day to 14-day interval. Pristine applied at rates of 8 to 12.5 ozs per acre for control of the listed diseases will also suppress Botrytis gray mold. For control of Botrytis gray mold, apply 18.5 to 23 ozs per acre of Pristine prior to onset of disease development when conditions favor disease development during early bloom, bunch pre-closure and veraison up to 14 days before harvest. Continue applications on a 10-day to 14-day interval. Use the higher rate and the shorter interval when disease pressure is high. For the small fruit, vine climbing berries listed in this table, it is impossible for BASF to test all small fruit, vine climbing berry crops for sensitivity to Pristine under all environments and all potential product mixture combinations. Local conditions can also influence crop response and may not match those under which BASF has conducted testing. Proceed with caution with regard to Pristine use, particularly in tank mixes and/or adjuvant combinations on small fruit, vine climbing berry crops. To reduce the risk of small fruit, vine climbing berry crop injury, BASF advises testing Pristine or Pristine tank mixtures on a small portion of the crop before broad scale use. To the extent consistent with applicable law, the user assumes all risks associated with adding products to the Pristine spray solution. Refer also to the Conditions of Sale and Warranty section of this label. Resistance Management. To limit the potential for development of resistance, DO NOT make more than two (2) sequential applications of Pristine or other Group 7 or Group 11 fungicides before alternating to a labeled fungicide with a different mode of action. Restrictions and Limitations * DO NOT make more than the Maximum Number of Applications per Year for applications made at the maximum Product Use Rate per Application (23 ozs/A contains 0.363 lb boscalid, 0.184 lb pyraclostrobin). Additional applications per year are permitted when a lower Product Use Rate per Application is used, as long as the Maximum Product Rate per Year (69 ozs/A contains 1.09 lbs boscalid, 0.552 lb pyraclostrobin) is not exceeded. • Maximum single application rate is 23 ozs/A (0.363 lb boscalid, 0.184 lb pyraclostrobin). • Maximum annual application rate is 69 ozs/A (1.09 lbs boscalid, 0.552 lb pyraclostrobin) per year. • Minimum retreatment interval is 10 days. • Minimum time from application to harvest (PHI) is 14 days. ** See separate crop table for grape use rates and application directions. 22 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Use Rate per Application (ozs/A) Maximum Number of Applications per Year Maximum Product Rate per Year (ozs/A) Minimum Time from Application to Harvest (PHI) (days) Brassica, head and stem [group 5-16]** Broccoli Brussels sprouts Cabbage Chinese cabbage (napa) Cauliflower Cultivars, varieties and/or hybrids of these Alternaria leaf spot Alternaria spp. Black leg Phoma lingam Cercospora leaf spot Cercospora spp. Powdery mildew Erysiphe spp. Ring spot Mycosphaerella spp. White leaf spot Pseudocercosporella spp. 10 to 15 2* 50 0 Anthracnose Colletotrichum spp. White rust Albugo spp. 15 to 20 Downy mildew Peronospora spp. Gray mold Botrytis spp. Sclerotinia stem rot Sclerotinia spp. Rhizoctonia bottom rot Rhizoctonia solani 15 to 25 Application Directions. Begin applications of Pristine prior to disease development and continue on a 7-day to 14-day interval. Use the higher rate and the shorter interval when disease pressure is high. Resistance Management. To limit the potential for development of resistance, DO NOT make more than two (2) sequential applications of Pristine before alternating to a labeled fungicide with a different mode of action. Restrictions and Limitations * DO NOT make more than the Maximum Number of Applications per Year for applications made at the maximum Product Use Rate per Application (25 ozs/A contains 0.395 lb boscalid, 0.200 lb pyraclostrobin). Additional applications per year are permitted when a lower Product Use Rate per Application is used, as long as the Maximum Product Rate per Year (50 ozs/A contains 0.790 lb boscalid and 0.400 lb pyraclostrobin) is not exceeded. • Maximum single application rate is 25 ozs/A (0.395 lb boscalid, 0.200 lb pyraclostrobin). • Maximum annual application rate is 50 ozs/A (0.790 lb boscalid and 0.400 lb pyraclostrobin) per year. • Minimum retreatment interval is 7 days. ** Not registered for use in California. 23 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Use Rate per Application (ozs/A) Maximum Number of Applications per Year Maximum Product Rate per Year (ozs/A) Minimum Time from Application to Harvest (PHI) (days) Brassica, leafy greens (except watercress) [subgroup 4-16B]** Arugula Broccoli, Chinese Broccoli raab Cabbage, abyssinian Cabbage, Chinese, bok choy Cabbage, seakale Collards Cress (garden and upland) Hanover salad Kale Maca, leaves Mizuna Mustard greens Radish, leaves Rape greens Rocket, wild Shepherd’s purse Cultivars, varieties and/or hybrids of these Alternaria leaf spot Alternaria spp. Anthracnose Colletotrichum spp. Ascochyta leaf spot Ascochyta spp. Cercospora leaf spot Cercospora spp. Downy mildew Peronospora spp. Phoma Phoma spp. Powdery mildew Erysiphe spp., Phyllactinia spp., Sphaerotheca spp. Rust Puccinia spp. Septoria leaf spot Septoria spp. White rust Albugo spp. 10 to 15 2* 50 14 Botrytis rot Botrytis spp. Sclerotinia rot and blight Sclerotinia spp. 15 to 25 Application Directions. Begin applications of Pristine prior to the onset of disease development and continue on a 7-day interval. Use the higher rate when disease pressure is high. Resistance Management. To limit the potential for development of resistance, DO NOT make more than one (1) application of Pristine before alternating to a labeled fungicide with a different mode of action for at least one (1) application. Restrictions and Limitations * DO NOT make more than the Maximum Number of Applications per Year for applications made at the maximum Product Use Rate per Application (25 ozs/A contains 0.395 lb boscalid, 0.200 lb pyraclostrobin). Additional applications per year are permitted when a lower Product Use Rate per Application is used, as long as the Maximum Product Rate per Year (50 ozs/A contains 0.790 lb boscalid, 0.400 lb pyraclostrobin) is not exceeded. • Maximum single application rate is 25 ozs/A (0.395 lb boscalid, 0.200 lb pyraclostrobin). • Maximum annual application rate is 50 ozs/A (0.790 lb boscalid and 0.400 lb pyraclostrobin) per year. • Minimum retreatment interval is 7 days. • Minimum time from application to harvest (PHI) is 14 days. ** Not registered for use in California. 24 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Use Rate per Application (ozs/A) Maximum Number of Applications per Year Maximum Product Rate per Year (ozs/A) Minimum Time from Application to Harvest (PHI) (days) Bulb vegetables [group 3-07] Chive, fresh leaves Chive, Chinese, fresh leaves Daylily, bulb Elegans hosta Fritillaria, bulb Fritillaria, leaves Garlic, bulb Garlic, great-headed, bulb Garlic, serpent, bulb Kurrat Lady’s leek Leek Leek, wild Lily, bulb Onion, Beltsville bunching Onion, bulb Onion, Chinese, bulb Onion, fresh Onion, green Onion, macrostem Onion, pearl Onion, potato, bulb Onion, tree, tops Onion, Welsh, tops Shallot, bulb Shallot, fresh leaves Cultivars, varieties and/or hybrids of these Botrytis leaf blight Botrytis spp. Botrytis neck rot** Botrytis spp. 14.5 to 18.5 6* 111 7 Purple blotch and leaf blight Alternaria porri Stemphylium leaf blight and stalk rot Stemphylium vesicarium 10.5 to 18.5 Suppression Only: Downy mildew Peronospora destructor 18.5 (continued) 25 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Bulb vegetables [group 3-07] (continued) Application Directions. For control of neck rot, purple blotch and leaf blight, begin applications of Pristine prior to onset of disease development and continue on a 14-day interval. If application intervals shorter than 14 days are needed, rotate to another fungicide with a different mode of action. Use the higher rate when disease pressure is high. Applications made to control purple blotch, leaf blight and stalk rot will also suppress downy mildew. If downy mildew occurs during a Pristine application for these diseases, immediately follow the Pristine application with a downy mildew fungicide with a different mode of action. For downy mildew, rotate each application of Pristine with an application of a labeled fungicide with a different mode of action. No restriction on livestock grazing or feeding. Resistance Management. To limit the potential for development of resistance, DO NOT make more than two (2) sequential applications of Pristine or other Group 7 or Group 11 fungicides before alternating to a labeled fungicide with a different mode of action. Restrictions and Limitations * DO NOT make more than the Maximum Number of Applications per Year for applications made at the maximum Product Use Rate per Application (18.5 ozs/A contains 0.292 lb boscalid, 0.148 lb pyraclostrobin). Additional applications per year are permitted when a lower Product Use Rate per Application is used, as long as the Maximum Product Rate per Year (111 ozs/A contains 1.75 lbs boscalid, 0.888 lb pyraclostrobin) is not exceeded. • Maximum single application rate is 18.5 ozs/A (0.292 lb boscalid, 0.148 lb pyraclostrobin). • Maximum annual application rate is 111 ozs/A (1.75 lbs boscalid, 0.888 lb pyraclostrobin) per year. • Minimum retreatment interval is 14 days. • Minimum time from application to harvest (PHI) is 7 days. ** Not registered for use in California. 26 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Use Rate per Application (ozs/A) Maximum Number of Applications per Year Maximum Product Rate per Year (ozs/A) Minimum Time from Application to Harvest (PHI) (days) Carrot Alternaria leaf spot Alternaria spp. Cercospora leaf spot Cercospora spp. Powdery mildew Erysiphe spp. Suppression Only: Southern root rot Sclerotium rolfsii 8 to 10.5 6* 63 0 Application Directions. Begin applications of Pristine prior to onset of disease development and continue on a 7-day to 14-day interval. Use the higher rate and the shorter interval when disease pressure is high. No restriction on livestock grazing or feeding for carrot culls. Resistance Management. To limit the potential for development of resistance, DO NOT make more than two (2) sequential applications of Pristine or other Group 7 or Group 11 fungicides before alternating to a labeled fungicide with a different mode of action. Restrictions and Limitations * DO NOT make more than the Maximum Number of Applications per Year for applications made at the maximum Product Use Rate per Application (10.5 ozs/A contains 0.166 lb boscalid, 0.084 lb pyraclostrobin). Additional applications per year are permitted when a lower Product Use Rate per Application is used, as long as the Maximum Product Rate per Year (63 ozs/A contains 0.995 lb boscalid, 0.504 lb pyraclostrobin) is not exceeded. • Maximum single application rate is 10.5 ozs/A (0.166 lb boscalid, 0.084 lb pyraclostrobin). • Maximum annual application rate is 63 ozs/A (0.995 lb boscalid, 0.504 lb pyraclostrobin) per year. • Minimum retreatment interval is 7 days. 27 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Use Rate per Application (ozs/A) Maximum Number of Applications per Year Maximum Product Rate per Year (ozs/A) Minimum Time from Application to Harvest (PHI) (days) Celery** Celery (Chinese)** Alternaria leaf spot Alternaria spp. Anthracnose Colletotrichum spp. Ascochyta leaf spot Ascochyta spp. Cercospora leaf spot Cercospora spp. Downy mildew Bremia spp., Peronospora spp. Phoma Phoma spp. Powdery mildew Erysiphe spp. Rust Puccinia spp. Septoria leaf spot Septoria spp. White rust Albugo spp. 10 to 15 2* 50 0 Botrytis rot Botrytis spp. Sclerotinia rot and blight Sclerotinia spp. 25 Application Directions. Begin applications of Pristine prior to the onset of disease development and continue on a 7-day interval. Use the higher rate when disease pressure is high. Resistance Management. To limit the potential for development of resistance, DO NOT make more than one (1) application of Pristine before alternating to a labeled fungicide with a different mode of action for at least one (1) application. Restrictions and Limitations * DO NOT make more than the Maximum Number of Applications per Year for applications made at the maximum Product Use Rate per Application (25 ozs/A contains 0.395 lb boscalid, 0.200 lb pyraclostrobin). Additional applications per year are permitted when a lower Product Use Rate per Application is used, as long as the Maximum Product Rate per Year (50 ozs/A contains 0.790 lb boscalid, 0.400 lb pyraclostrobin) is not exceeded. • Maximum single application rate is 25 ozs/A (0.395 lb boscalid, 0.200 lb pyraclostrobin). • Maximum annual application rate is 50 ozs/A (0.790 lb boscalid, 0.400 lb pyraclostrobin) per year. • Minimum retreatment interval is 7 days. ** Not registered for use in California. 28 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Use Rate per Application (ozs/A) Maximum Number of Applications per Year Maximum Product Rate per Year (ozs/A) Minimum Time from Application to Harvest (PHI) (days) Celtuce** Alternaria leaf spot Alternaria spp. Anthracnose Colletotrichum spp. Ascochyta leaf spot Ascochyta spp. Cercospora leaf spot Cercospora spp. Downy mildew Bremia spp., Peronospora spp. Phoma Phoma spp. Powdery mildew Erysiphe spp. Rust Puccinia spp. Septoria leaf spot Septoria spp. White rust Albugo spp. 10 to 15 2* 50 0 Botrytis rot Botrytis spp. Sclerotinia rot and blight Sclerotinia spp. 15 to 25 Application Directions. Begin applications of Pristine prior to the onset of disease development and continue on a 7-day interval. Use the higher rate when disease pressure is high. Resistance Management. To limit the potential for development of resistance, DO NOT make more than one (1) application of Pristine before alternating to a labeled fungicide with a different mode of action for at least one (1) application. Restrictions and Limitations * DO NOT make more than the Maximum Number of Applications per Year for applications made at the maximum Product Use Rate per Application (25 ozs/A contains 0.395 lb boscalid, 0.200 lb pyraclostrobin). Additional applications per year are permitted when a lower Product Use Rate per Application is used, as long as the Maximum Product Rate per Year (50 ozs/A contains 0.790 lb boscalid, 0.400 lb pyraclostrobin) is not exceeded. • Maximum single application rate is 25 ozs/A (0.395 lb boscalid, 0.200 lb pyraclostrobin). • Maximum annual application rate is 50 ozs/A (0.790 lb boscalid, 0.400 lb pyraclostrobin) per year. • Minimum retreatment interval is 7 days. ** Not registered for use in California. 29 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Use Rate per Application (ozs/A) Maximum Number of Applications per Year Maximum Product Rate per Year (ozs/A) Minimum Time from Application to Harvest (PHI) (days) Citrus fruit [group 10-10] Australian desert lime Australian finger lime Australian round lime Brown River finger lime Calamondin Chironja Citron Citrus hybrids Grapefruit Japanese summer grapefruit Kumquat Lemon Lime Mediterranean mandarin Mount White lime New Guinea wild lime Orange, sour Orange, sweet Pummelo Russell River lime Satsuma mandarin Sweet lime Tachibana orange Tahiti lime Tangelo Tangerine (mandarin) Tangor Trifolate orange Uniq fruit Cultivars, varieties and/or hybrids of these Alternaria brown spot Alternaria alternata, Alternaria spp. Citrus black spot* Guignardia citricarpa Greasy spot Mycosphaerella citri Melanose Diaporthe citri Scab Elsinoe fawcettii 16 to 18.5 4 74 0 (continued) 30 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Citrus fruit [group 10-10] (continued) Application Directions. Apply Pristine in a regularly scheduled protective fungicide program. Begin Pristine applications prior to infection and continue on a 10-day to 21-day interval. Use the higher rate and shorter interval when disease pressure is high. Disease control from Pristine depends on disease pressure and various cultural practices that influence rind maturation and disease susceptibility. Improved disease performance may result when Pristine is used in a crop management program that minimizes rind overmaturity and rind damage. No livestock feeding restrictions. For aerial application to citrus fruit trees, use no less than 10 gallons of spray solution per acre. Resistance Management. To limit development of resistance, DO NOT make more than two (2) sequential applications of Pristine or other Group 7 or Group 11 fungicides before alternating to a labeled fungicide with different modes of action. Restrictions and Limitations • Maximum single application rate is 18.5 ozs/A (0.292 lb boscalid, 0.148 lb pyraclostrobin). • Maximum annual application rate is 74 ozs/A (1.17 lbs boscalid, 0.592 lb pyraclostrobin) per year. • DO NOT make more than four (4) applications of Pristine per year. • Minimum retreatment interval is 10 days. * Not registered for use in California. 31 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Use Rate per Application (ozs/A) Maximum Number of Applications per Year Maximum Product Rate per Year (ozs/A) Minimum Time from Application to Harvest (PHI) (days) Cotton** Alternaria leaf spot Alternaria spp. Anthracnose, boll rot Glomerella spp. Ascochyta blight, boll rot Ascochyta spp. Cercospora leaf spot Cercospora spp. Diplodia boll rot Diplodia spp. Hard lock, boll rot Fusarium spp. 12.5 to 25 2* 50 30 Application Directions. Begin applications of Pristine prior to the onset of disease development and continue on a 7-day to 14-day interval. Use the higher rate and the shorter interval when disease pressure is high. Feed containing commodities from cotton production and processing can be fed to livestock. Resistance Management. To limit the potential for development of resistance, DO NOT make more than one (1) application of Pristine before alternating to a labeled fungicide with a different mode of action for at least one (1) application. Restrictions and Limitations * DO NOT make more than the Maximum Number of Applications per Year for applications made at the maximum Product Use Rate per Application (25 ozs/A contains 0.395 lb boscalid, 0.200 lb pyraclostrobin). Additional applications per year are permitted when a lower Product Use Rate per Application is used, as long as the Maximum Product Rate per Year (50 ozs/A contains 0.790 lb boscalid, 0.400 lb pyraclostrobin) is not exceeded. • Maximum single application rate is 25 ozs/A (0.395 lb boscalid, 0.200 lb pyraclostrobin). • Maximum annual application rate is 50 ozs/A (0.790 lb boscalid, 0.400 lb pyraclostrobin) per year. • Minimum retreatment interval is 7 days. • Minimum time from application to harvest (PHI) is 30 days. ** Includes cottonseed tolerance. 32 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Use Rate per Application (ozs/A) Maximum Number of Applications per Year Maximum Product Rate per Year (ozs/A) Minimum Time from Application to Harvest (PHI) (days) Cucurbit vegetables [group 9] Chayote Chinese waxgourd Citron melon Cucumber Gherkin Pumpkin Watermelon Edible Gourd Chinese okra Cucuzza Hechima Hyotan Momordica spp. Balsam apple Balsam pear Bitter melon Chinese cucumber Muskmelon Cantaloupe Casaba Crenshaw melon Golden pershaw melon Honey balls Honeydew melon Mango melon Persian melon Pineapple melon Santa Claus melon Snake melon Summer Squash Crookneck squash Scallop squash Straightneck squash Vegetable marrow Zucchini Winter Squash Acorn squash Butternut squash Calabaza Hubbard squash Spaghetti squash Cultivars, varieties and/or hybrids of these Alternaria blight Alternaria cucumerina Cercospora leaf spot Cercospora citrulina Downy mildew Pseudoperonospora cubensis Gummy stem blight Didymella bryoniae Powdery mildew Erysiphe cichoracearum, Sphaerotheca fuliginea 12.5 to 18.5 4 74 0 Anthracnose Colletotrichum orbiculare 18.5 (continued) 33 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Cucurbit vegetables [group 9] (continued) Application Directions. Begin applications of Pristine prior to onset of disease development and continue on a 7-day to 14-day interval. Use the higher rate and the shorter interval when disease pressure is high. Use the highest labeled rate for anthracnose. Tank Mixes with Adjuvants and Other Products. BASF evaluations indicate that tank mixes of additives, adjuvants, and/or other products with Pristine may result in injury. This is particularly true for muskmelon crops including cantaloupe and honeydew. Users need to be aware of this, proceed with caution, and test for crop safety when tank mixing, as stated below. Applications of additives, adjuvants, and/or other products that increase penetration may cause injury when mixed with Pristine. Injury potential from these kinds of tank mixes may decrease with lower rates of the tank mix partner. Users are advised to test for crop safety, as stated below. BASF has not tested all varieties and cultivars with all possib le tank mix combinations and rates of additives, adjuvants, and/or other products. Local environmental conditions also influence crop response and may not match those under which BASF has conducted testing. Physical incompatibility, reduced disease control, or crop injury may result from mixing Pristine with other products. To minimize the likelihood of crop injury, BASF advises testing Pristine in combination with additives, adjuvants, and/ or other products for crop safety on a small portion of the crop. However, environmental variability precludes direct and consistent projection of small area test results to future use. Consult a BASF representative for more information concerning additives or adjuvants. Resistance Management. To limit the potential of development of resistance, DO NOT make more than one (1) application of Pristine before alternating to a labeled fungicide with a different mode of action for at least one (1) application. Restrictions and Limitations • Maximum single application rate is 18.5 ozs/A (0.292 lb boscalid, 0.148 lb pyraclostrobin). • Maximum annual application rate is 74 ozs/A (1.17 lbs boscalid, 0.592 lb pyraclostrobin) per year. • DO NOT make more than four (4) applications of Pristine per year. • DO NOT tank mix Pristine with chlorpyrifos, dicofol, endosulfan, malathion, methomyl, potassium salts of fatty acids, or dicloran as crop injury may result. • Minimum retreatment interval is 7 days. Crop Target Disease Product Use Rate per Application (ozs/A) Maximum Number of Applications per Year Maximum Product Rate per Year (ozs/A) Minimum Time from Application to Harvest (PHI) (days) Dill seed Phoma blight Cercosporidium spp. 18.5 2 37 0 Application Directions. Begin Pristine applications prior to the onset of disease development and repeat application 7 days later as needed or rotate to another fungicide with a different mode of action. Restrictions and Limitations • Maximum single application rate is 18.5 ozs/A (0.292 lb boscalid, 0.148 lb pyraclostrobin). • Maximum annual application rate is 37 ozs/A (0.585 lb boscalid, 0.296 lb pyraclostrobin) per year. • DO NOT make more than two (2) applications of Pristine per year. • DO NOT apply by air. • DO NOT apply through any type of irrigation system (chemigation). • Minimum retreatment interval is 7 days. 34 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Use Rate per Application (ozs/A) Maximum Number of Applications per Year Maximum Product Rate per Year (ozs/A) Minimum Time from Application to Harvest (PHI) (days) Fennel (Florence)** Alternaria leaf spot Alternaria spp. Anthracnose Colletotrichum spp. Ascochyta leaf spot Ascochyta spp. Cercospora leaf spot Cercospora spp. Downy mildew Bremia spp., Peronospora spp. Phoma Phoma spp. Powdery mildew Erysiphe spp. Rust Puccinia spp. Septoria leaf spot Septoria spp. White rust Albugo spp. 10 to 15 2* 50 0 Botrytis rot Botrytis spp. Sclerotinia rot and blight Sclerotinia spp. 15 to 25 Application Directions. Begin applications of Pristine prior to the onset of disease development and continue on a 7-day interval. Use the higher rate when disease pressure is high. Resistance Management. To limit the potential for development of resistance, DO NOT make more than one (1) application of Pristine before alternating to a labeled fungicide with a different mode of action for at least one (1) application. Restrictions and Limitations * DO NOT make more than the Maximum Number of Applications per Year for applications made at the maximum Product Use Rate per Application (25 ozs/A contains 0.395 lb boscalid, 0.200 lb pyraclostrobin). Additional applications per year are permitted when a lower Product Use Rate per Application is used, as long as the Maximum Product Rate per Year (50 ozs/A contains 0.790 lb boscalid, 0.400 lb pyraclostrobin) is not exceeded. • Maximum single application rate is 25 ozs/A (0.395 lb boscalid, 0.200 lb pyraclostrobin). • Maximum annual application rate is 50 ozs/A (0.790 lb boscalid, 0.400 lb pyraclostrobin) per year. • Minimum retreatment interval is 7 days. ** Not registered for use in California. 35 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Use Rate per Application (ozs/A) Maximum Number of Applications per Year Maximum Product Rate per Year (ozs/A) Minimum Time from Application to Harvest (PHI) (days) Fruiting vegetables [group 8-10] African eggplant Bell pepper Bush tomato Cocona Currant tomato Eggplant Garden huckleberry Goji berry Groundcherry Martynia Naranjilla Okra Pea eggplant Pepino Pepper (all varieties) Nonbell pepper Roselle Scarlet eggplant Sunberry Tomatillo Tree tomato Cultivars, varieties and/or hybrids of these Black mold Alternaria alternata Early blight Alternaria solani 9.7 or 9.7 ozs per 100 gal of spray volume (dilute)* 65 8 . 2 0 Tomato Cultivars, varieties and/or hybrids Anthracnose Colletotrichum spp. Black mold Alternaria alternata Botrytis gray mold Botrytis cinerea Early blight Alternaria solani Late blight Phytophthora infestans Powdery mildew Leveillula taurica Septoria leaf spot Septoria lycopersici Target spot Corynespora cassiicola 12.5 to 25 5 at 12.5 ozs/A 2 at 25 ozs/A 69 (continued) 36 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Fruiting vegetables [group 8-10] (continued) Application Directions. Begin Pristine applications prior to disease development and continue on a 7-day to 14-day interval for anthracnose, black mold, botrytis gray mold, early blight, powdery mildew, Septoria leaf spot, and target spot. For control of late blight, begin applications prior to disease development; then follow each Pristine application with a labeled fungicide with a different mode of action 5 to 7 days later. Use the higher rate and shorter interval when disease pressure is high. * For applications based on dilute volume, spray plants to runoff. Apply a minimum of 20 gallons of spray volume per acre, and increase the spray volume as the plants grow. Spray proportional volume to the amount of plant tissue to be covered such that 100 gallons of spray per acre is used on mature plants. Use of Adjuvants. Additive or adjuvant use may improve the performance of Pristine on fruiting vegetables. However, BASF evaluations also indicate that under some conditions (particularly high temperatures and/or high additive rates), Pristine application in combination with certain rates of silicone based or oil-containing (petroleum or crop) additives or adjuvants can cause injury. BASF has not tested all varieties and cultivars with all possible tank mix combinations and rates of additives or adjuvants. Local environmental conditions also influence crop response and may not match those under which BASF has conducted testing. Physical incompatibility, reduced disease control, or crop injury may result from mixing Pristine with other products. To the extent consistent with applicable law, the user assumes all risks associated with adding products to the Pristine spray solution. BASF cannot be held responsible for crop injury, reduced disease control or incompatibility because of additives, adjuvants or other products used in combination with Pristine (see Conditions of Sale and Warranty). To minimize the likelihood of crop injury, test Pristine in combination with other products for crop safety on a small portion of the crop. However, environmental variability precludes direct and consistent projection of small area test results to future use. Consult a BASF representative for more information concerning additives or adjuvants. Resistance Management. To limit development of resistance, DO NOT make more than two (2) sequential Pristine applications before alternating to a labeled non-Group 7 or non-Group 11 fungicide with a different mode of action. For additional resistance management information, see Resistance Management in the Product Information section. Restrictions and Limitations • DO NOT apply more than 58.2 ozs/A (0.920 lb boscalid, 0.466 lb pyraclostrobin) per year for fruiting vegetables, except Tomato. For Tomato, DO NOT apply more than 69 ozs/A (1.09 lbs boscalid, 0.552 lb pyraclostrobin) per year. • Maximum single application rate is 25 ozs/A (0.395 lb boscalid, 0.200 lb pyraclostrobin). • DO NOT make more than six (6) applications of Pristine per year for fruiting vegetables, except Tomato. For Tomato, DO NOT make more than five (5) applications of Pristine per year at 12.5 ozs/A or two (2) applications of Pristine per year at 25 ozs/A. • Minimum retreatment interval is 7 days. 37 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Use Rate per Application (ozs/A) Maximum Number of Applications per Year Maximum Product Rate per Year (ozs/A) Minimum Time from Application to Harvest (PHI) (days) Globe artichoke Bud rot Botrytis cinerea Ramularia leaf spot Ramularia spp. 18.5 to 23.0 3 69 0 Application Directions. Dosage and frequency/timing of applications. Begin applications of Pristine prior to onset of disease development and continue on a 7-day to 14-day interval. For artichoke bud rot, begin applications at the initiation of the bud protection phase when approximately 25% of the plants have bolted. Use the shorter interval and/or the higher rate when disease pressure is high. Resistance Management. To limit the potential for development of resistance, DO NOT exceed the specified number of applications of Pristine or other Group 7 or Group 11 fungicides per year. Adhere to the label instructions regarding the consecutive use of Pristine or other target site of action Group 7 and Group 11 fungicides that have a similar site of action on the same pathogens. Restrictions and Limitations • Maximum single application rate is 23 ozs/A (0.363 lb boscalid, 0.184 lb pyraclostrobin). • Maximum annual application rate is 69 ozs/A (1.09 lbs boscalid, 0.552 lb pyraclostrobin) per year. • DO NOT make more than three (3) applications of Pristine per year. • DO NOT apply Pristine to artichokes as a tank mix with any other pesticide products (including fungicides, insecticides, herbicides), adjuvants, liquid fertilizers, nutrients, any other additives or anything other than water. Mix Pristine with water only for applications to artichokes. • Minimum retreatment interval is 7 days. 38 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Use Rate per Application (ozs/A) Maximum Number of Applications per Year Maximum Product Rate per Year (ozs/A) Minimum Time from Application to Harvest (PHI) (days) Grape (except Concord or Noiret (NY73.0136.17) due to foliar injury. It is possible that foliar injury could occur on related grape varieties. See comments in the Application Directions for more information.) Angular leaf spot Mycosphaerella angulata Anthracnose Elsinoe ampelina Black rot Guignardia bidwellii Downy mildew Plasmopara viticola Leaf blight Pseudocercospora vitis Phomopsis cane and leaf spot Phomopsis viticola Powdery mildew Uncinula necator Ripe rot Colletotrichum gloeosporioides Aids in Control Only: Summer bunch rot (Sour rot) Aspergillus spp. and Cladosporium spp. Suppression Only: Botrytis gray mold Botrytis cinerea 8 to 12.5 5* 69 14 Botrytis gray mold Botrytis cinerea) 18.5 to 23 3 (continued) 39 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Grape (continued) Application Directions. For powdery mildew control, begin applications of Pristine as of bud break prior to onset of disease, using 8 ozs per acre on a 10-day to 14-day interval. Use 10 to 12.5 ozs per acre on a 14-day to 21-day interval. For black rot and downy mildew control, begin applications of Pristine as of pre-bloom prior to onset of disease and continue applications on a 10-day to 14-day interval. For all other diseases listed except for Botrytis gray mold, begin applications of Pristine prior to onset of disease and continue applications on a 10-day to 14-day interval. Pristine applied at rates of 8 to 12.5 ozs per acre for control of the listed diseases will also suppress Botrytis gray mold. For control of Botrytis gray mold, apply 18.5 to 23 ozs per acre of Pristine prior to onset of disease development when conditions favor disease development during early bloom, bunch pre-closure and veraison up to 14 days before harvest. Continue applications on a 10-day to 14-day interval. Use the higher rate and the shorter interval when disease pressure is high. For aerial application to grape, use no less than 10 gallons of spray solution per acre. Resistance Management. To limit the potential for development of resistance, DO NOT make more than five (5) applications of Pristine or other Group 7 or Group 11 fungicides per year. DO NOT make more than two (2) sequential applications of Pristine before alternating to a labeled fungicide with a different mode of action. Restrictions and Limitations * DO NOT make more than the Maximum Number of Applications per Year for applications made at the maximum Product Use Rate per Application (23 ozs/A contains 0.363 lb boscalid, 0.184 lb pyraclostrobin). Additional applications per year are permitted when a lower Product Use Rate per Application is used, as long as the Maximum Product Rate per Year (69 ozs/A contains 1.09 lbs boscalid, 0.552 lb pyraclostrobin) is not exceeded. • Maximum single application rate is 23 ozs/A (0.363 lb boscalid, 0.184 lb pyraclostrobin). • Maximum annual application rate is 69 ozs/A (1.09 lbs boscalid, 0.552 lb pyraclostrobin) per year. • DO NOT enter or allow worker entry into treated areas during the restricted-entry interval (REI) of 12 hours. Exceptions: DO NOT allow workers to perform cane tying and leaf pulling tasks on grapes for 5 days after application. DO NOT allow workers to perform cane turning or cane girdling tasks on table grapes grown on T-trellis systems for 5 days after application. Notify workers of these prohibitions. • DO NOT use on Concord or Noiret (NY73.0136.17) due to foliar injury. Possible foliar injury could occur to Worden, Fredonia, Niagara, Steuben, Rougeon or related grape varieties. Not all varieties have been thoroughly tested. Consult a BASF representative for more information concerning these sensitive grapes. • Minimum retreatment interval is 10 days. • Minimum time from application to harvest (PHI) is 14 days. 40 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Use Rate per Application (ozs/A) Maximum Number of Applications per Year Maximum Product Rate per Year (ozs/A) Minimum Time from Application to Harvest (PHI) (days) Herb [subgroup 19A] Angelica Balm Basil Borage Burnet Catnip Chamomile Chervil (dried) Chive Chive, Chinese Clary Coriander (leaf) Costmary Culantro (leaf) Curry (leaf) Dillweed Horehound Hyssop Lavender Lemongrass Lovage (leaf) Marigold Marjoram Nasturtium Parsley (dried) Pennyroyal Rosemary Rue Sage Savory, summer and winter Sweet bay Tansy Tarragon Thyme Wintergreen Woodruff Wormwood Phoma blight Cercosporidium spp. Powdery mildew Erysiphe spp., Sphaerotheca spp. Rust Puccinia spp. 18.5 2 37 0 Application Directions. Begin Pristine applications prior to the onset of disease development and repeat application 7 days later as needed or rotate to another fungicide with a different mode of action. Restrictions and Limitations • Maximum single application rate is 18.5 ozs/A (0.292 lb boscalid, 0.148 lb pyraclostrobin). • Maximum annual application rate is 37 ozs/A (0.585 lb boscalid, 0.296 lb pyraclostrobin) per year. • DO NOT make more than two (2) applications of Pristine per year. • DO NOT apply by air. • DO NOT apply through any type of irrigation system (chemigation). • Minimum retreatment interval is 7 days. 41 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Use Rate per Application Maximum Number of Ground Applications per Year Maximum Product Rate per Year (ozs/A) Minimum Time from Application to Harvest (PHI) (days) Hops (Ground Application) Powdery mildew Erysiphe cichoracearum, Sphaerotheca spp. Downy mildew Pseudoperonospora humuli 14 ozs per 100 gallons of dilute spray DO NOT use more than 28 ozs per acre. 3 (2 if one aerial application is made) 84 (70 ozs/A if one aerial application is made) 14 Application Directions. Begin applications of Pristine prior to disease development and continue on a 10-day to 21-day interval. Use the shorter interval when disease pressure is high. Application rates are based on 100 gallons of dilute spray applied to runoff. Adjust water volume to maintain thorough coverage. Use 25 to 50 gallons of dilute spray per acre prior to trellising and 100 to 200 gallons of dilute spray per acre thereafter. DO NOT use more than 200 gallons per acre of this mixture. If additional spray volume is needed for thorough coverage, use 28 ozs of Pristine per acre in the required spray volume. Resistance Management. To limit the potential for development of resistance, DO NOT make more than two (2) sequential applications of Pristine before alternating to a labeled fungicide with a different mode of action. Restrictions and Limitations • DO NOT apply more than 84 ozs/A (1.33 lbs boscalid, 0.672 lb pyraclostrobin) per year. If one aerial application is made, DO NOT apply more than 70 ozs/A (1.11 lbs boscalid, 0.560 lb pyraclostrobin) per year. • DO NOT make more than three (3) applications of Pristine per year (counting both ground and aerial applications). • DO NOT use more than 200 gallons per acre of this mixture. If additional spray volume is needed for thorough coverage, use 28 ozs of Pristine per acre in the required spray volume. • Maximum single application rate is 28 ozs/A (0.442 lb boscalid, 0.224 lb pyraclostrobin). • Minimum retreatment interval is 10 days. • Minimum time from application to harvest (PHI) is 14 days. 42 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Crop Target Disease Aerial Product Use Rate per Application Maximum Number of Aerial Applications per Year Aerial Application Timing Growth Stage Minimum Time from Aerial Application to Harvest (PHI) (days) Hops (Aerial Application) Powdery mildew Erysiphe cichoracearum, Sphaerotheca humuli, Sphaerotheca macularis, Sphaerotheca spp. 14 ozs/A as a tank mix with a myclobutanil fungicide product (see myclobutanil rate following) 1 Wire to 14 days preharvest 14 Application Directions. Aerial application may result in reduced control due to lack of canopy penetration and coverage. Use aerial application only when ground application is not possible. Apply a preventive spray of Pristine at 14 ozs (0.221 lb boscalid, 0.112 lb pyraclostrobin) as a tank mix with a myclobutanil fungicide product at a rate equivalent to 0.15 lb per acre of active ingredient for resistance management. Avoid applications under conditions when uniform coverage cannot be obtained or when spray drift may occur. Use a minimum of 10 gallons of water per acre when applying by air. Thorough coverage is essential. Because complete coverage is important for effective disease control, aerial application at low volumes may result in reduced control due to lack of canopy penetration and coverage . Mixing Pristine with surfactants or foliar fertilizers is not advised when applying by air. Similarly, adjuvants that enhance pesticide penetration may cause phytotoxicity when used with Pristine applied by air. Resistance Management. To limit the potential for development of resistance, DO NOT make more than one (1) aerial application of Pristine per year and include a myclobutanil product as a tank mix as described. Restrictions and Limitations • DO NOT apply more than 14 ozs/A (0.221 lb boscalid, 0.112 lb pyraclostrobin) per application • DO NOT make more than one (1) application of Pristine per year. • Minimum time from application to harvest (PHI) is 14 days. 43 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Use Rate per Application (ozs/A) Maximum Number of Applications per Year Maximum Product Rate per Year (ozs/A) Minimum Time from Application to Harvest (PHI) (days) Kohlrabi** Alternaria leaf spot Alternaria spp. Black leg Phoma lingam Cercospora leaf spot Cercospora spp. Powdery mildew Erysiphe spp. Ring spot Mycosphaerella spp. White leaf spot Pseudocercosporella spp. 10 to 15 2* 50 0 Anthracnose Colletotrichum spp. White rust Albugo spp. 15 to 20 Downy mildew Peronospora spp. Gray mold Botrytis spp. Sclerotinia stem rot Sclerotinia spp. Rhizoctonia bottom rot Rhizoctonia solani 15 to 25 Application Directions. Begin applications of Pristine prior to disease development and continue on a 7-day to 14-day interval. Use the higher rate and the shorter interval when disease pressure is high. Resistance Management. To limit the potential for development of resistance, DO NOT make more than two (2) sequential applications of Pristine before alternating to a labeled fungicide with a different mode of action. Restrictions and Limitations * DO NOT make more than the Maximum Number of Applications per Year for applications made at the maximum Product Use Rate per Application (25 ozs/A contains 0.395 lb boscalid, 0.200 lb pyraclostrobin). Additional applications per year are permitted when a lower Product Use Rate per Application is used, as long as the Maximum Product Rate per Year (50 ozs/A contains 0.790 lb boscalid and 0.400 lb pyraclostrobin) is not exceeded. • Maximum single application rate is 25 ozs/A (0.395 lb boscalid, 0.200 lb pyraclostrobin). • Maximum annual application rate is 50 ozs/A(0.790 lb boscalid, 0.400 lb pyraclostrobin) per year. • Minimum retreatment interval is 7 days. ** Not registered for use in California. 44 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Use Rate per Application (ozs/A) Maximum Number of Applications per Year Maximum Product Rate per Year (ozs/A) Minimum Time from Application to Harvest (PHI) (days) Leaf petiole vegetables [subgroup 22B]** Cardoon Fuki Rhubarb Udo Zuiki Cultivars, varieties and/or hybrids of these Alternaria leaf spot Alternaria spp. Anthracnose Colletotrichum spp. Ascochyta leaf spot Ascochyta spp. Cercospora leaf spot Cercospora spp. Downy mildew Bremia spp., Peronospora spp. Phoma Phoma spp. Powdery mildew Erysiphe spp. Rust Puccinia spp. Septoria leaf spot Septoria spp. White rust Albugo spp. 10 to 15 2* 50 0 Botrytis rot Botrytis spp. Sclerotinia rot and blight Sclerotinia spp. 15 to 25 Application Directions. Begin applications of Pristine prior to the onset of disease development and continue on a 7-day interval. Use the higher rate when disease pressure is high. Resistance Management. To limit the potential for development of resistance, DO NOT make more than one (1) application of Pristine before alternating to a labeled fungicide with a different mode of action for at least one (1) application. Restrictions and Limitations * DO NOT make more than the Maximum Number of Applications per Year for applications made at the maximum Product Use Rate per Application (25 ozs/A contains 0.395 lb boscalid, 0.200 lb pyraclostrobin). Additional applications per year are permitted when a lower Product Use Rate per Application is used, as long as the Maximum Product Rate per Year (50 ozs/A contains 0.790 lb boscalid, 0.400 lb pyraclostrobin) is not exceeded. • Maximum single application rate is 25 ozs/A (0.395 lb boscalid, 0.200 lb pyraclostrobin). • Maximum annual application rate is 50 ozs/A (0.790 lb boscalid, 0.400 lb pyraclostrobin) per year. • Minimum retreatment interval is 7 days. ** Not registered for use in California. See separate crop table for celery and Chinese celery use rates and application directions. 45 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Use Rate per Application (ozs/A) Maximum Number of Applications per Year Maximum Product Rate per Year (ozs/A) Minimum Time from Application to Harvest (PHI) (days) Leafy greens [subgroup 4-16A]** Amaranth, Chinese Amaranth, leafy Aster, Indian Blackjack Cat’s whiskers Cham-chwi Cham-na-mul Chervil, fresh leaves Chipilin Chrysanthemum, garland Cilantro, fresh leaves Corn salad Cosmos Dandelion, leaves Dang-gwi, leaves Dillweed Dock Dol-nam-mul Ebolo Endive Escarole Fameflower Feather cockscomb Good King Henry Huauzontle Jute, leaves Lettuce, bitter Lettuce, head Lettuce, leaf Orach Parsley, fresh leaves Plantain, buckhorn Primrose, English Purslane, garden Purslane, winter Radicchio Swiss chard Violet, Chinese, leaves Cultivars, varieties, and/or hybrids of these Alternaria leaf spot Alternaria spp. Anthracnose Colletotrichum spp. Ascochyta leaf spot Ascochyta spp. Cercospora leaf spot Cercospora spp. Downy mildew Peronospora spp. Phoma Phoma spp. Powdery mildew Erysiphe spp., Phyllactinia spp., Sphaerotheca spp. Rust Puccinia spp. Septoria leaf spot Septoria spp. White rust Albugo spp. 10 to 15 2* 50 14 Botrytis rot Botrytis spp. Sclerotinia rot and blight Sclerotinia spp. 15 to 25 (continued) 46 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Leafy greens [subgroup 4-16A]** (continued) Application Directions. Begin applications of Pristine prior to the onset of disease development and continue on a 7-day interval. Use the higher rate when disease pressure is high. Resistance Management. To limit the potential for development of resistance, DO NOT make more than one (1) application of Pristine before alternating to a labeled fungicide with a different mode of action for at least one (1) application. Restrictions and Limitations * DO NOT make more than the Maximum Number of Applications per Year for applications made at the maximum Product Use Rate per Application (25 ozs/A contains 0.395 lb boscalid, 0.200 lb pyraclostrobin). Additional applications per year are permitted when a lower Product Use Rate per Application is used, as long as the Maximum Product Rate per Year (50 ozs/A contains 0.790 lb boscalid, 0.400 lb pyraclostrobin) is not exceeded. • Maximum single application rate is 25 ozs/A (0.395 lb boscalid, 0.200 lb pyraclostrobin). • Maximum annual application rate is 50 ozs/A (0.790 lb boscalid, 0.400 lb pyraclostrobin) per year. • Minimum retreatment interval is 7 days. • Minimum time from application to harvest (PHI) is 14 days. ** Not registered for use in California, except on radicchio for control of Sclerotinia rot and blight when applied at a rate of 25 ozs/A. 47 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Use Rate per Application (ozs/A) Maximum Number of Applications per Year Maximum Product Rate per Year (ozs/A) Minimum Time from Application to Harvest (PHI) (days) Oilseed [group 20] †* Flax Pasmo Septoria linicola 16.7 2 33.4 21 Rapeseed (canola varieties only) Blackleg Leptosphaeria maculans Blackspot Alternaria spp. Sclerotinia rot and blight Sclerotinia spp. Sunflower Alternaria leaf spot Alternaria spp. Cercospora leaf spot Cercospora helianthi Downy mildew Plasmopara halstedii Powdery mildew Erysiphe cichoracearum Rust Puccinia helianthi, Uromyces spp. Sclerotinia rot and blight Sclerotinia spp. Septoria leaf spot Septoria spp. White rust Albugo tragopogonis 24.5 2 49 21 (continued) 48 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Use Rate per Application (ozs/A) Maximum Number of Applications per Year Maximum Product Rate per Year (ozs/A) Minimum Time from Application to Harvest (PHI) (days) Oilseed [group 20] †* (continued) Borage Calendula Castor oil plant Chinese tallowtree Crambe Cuphea Echium Euphorbia Evening primrose Gold of pleasure Hare’s ear mustard Jojoba Lesquerella Lunaria Meadowfoam Milkweed Mustard seed Niger seed Oil radish Poppy seed Rose hip Safflower Sesame Stokes aster Sweet rocket Tallowwood Tea oil plant Vernonia Alternaria spp. Septoria spp. 16.7 2 33.4 21 (continued) 49 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Oilseed [group 20]†* (continued) Application Directions. For optimal disease control, begin applications of Pristine prior to disease development and continue on a 7-day to 14-day interval if conditions are conducive for disease development. Use the higher rate and shorter interval when disease pressure is high. Rapeseed. For control of blackleg, apply Pristine at 2- to 4-leaf stage. For optimal control of blackspot, apply Pristine at early pod development. A second application 7 to 10 days later may be made if disease persists or if weather conditions are favorable for disease development. Flax. Apply Pristine at mid-flowering (7 to 10 days after flower initiation). Make a second application 7 to 10 days later if disease persists or if weather conditions are favorable for disease development. † See separate crop table for cotton/cottonseed use rates and application directions. Pristine may be used with adjuvants. No livestock feeding restrictions. Resistance Management. To limit the potential for development of resistance, DO NOT make more than two (2) sequential applications of Pristine or other Group 7 or Group 11 fungicides before alternating to a labeled fungicide with a different mode of action. Restrictions and Limitations • DO NOT apply more than 33.4 ozs/A (0.528 lb boscalid, 0.267 lb pyraclostrobin) per year for oilseed crop, except sunflower. DO NOT apply more than 49 ozs/A (0.774 lb boscalid, 0.392 lb pyraclostrobin) per year for sunflower. • Maximum single application rate is 24.5 ozs/A (0.381 lb boscalid, 0.196 lb pyraclostrobin). • DO NOT make more than two (2) applications of Pristine per year. • Minimum retreatment interval is 7 days. • Minimum time from application to harvest (PHI) is 21 days. * Not registered for use in California. 50 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Use Rate per Application (ozs/A) Maximum Number of Applications per Year Maximum Product Rate per Year (ozs/A) Minimum Time from Application to Harvest (PHI) (days) Pea and bean, dried shelled, except soybean, subgroup 6C** Lupinus spp. Grain lupin Sweet lupin White lupin White sweet lupin Phaseolus spp. Field bean Kidney bean Lima bean (dry) Navy bean Pink bean Pinto bean Tepary bean Pisum spp. Field pea Vigna spp. Adjuki bean Blackeyed pea Catjang Cowpea Crowder pea Moth bean Mung bean Rice bean Southern pea Urd bean Alternaria leaf and pod spot Alternaria spp. Ascochyta blight Ascochyta spp., Phoma exigua Cercospora leaf spot Cercospora spp. Downy mildew Phytophthora nicotianae Mycosphaerella blight Mycosphaerella spp. Powdery mildew Erysiphe polygoni Rust Uromyces appendiculatus Septoria leaf spot Septoria spp. 10 to 15 2* 50 21 Anthracnose Colletotrichum spp. Botrytis gray mold Botrytis cinerea White mold Sclerotinia sclerotiorum 15 to 25 Application Directions. For optimal disease control, begin applications of Pristine prior to onset of disease development or at the beginning of flowering and repeat on a 5-day to 14-day interval if conditions are conducive for disease development. Use the higher rate and shorter interval when disease pressure is high. Resistance Management. DO NOT make more than one (1) application of Pristine before alternating to a labeled fungicide with a different mode of action for at least one (1) application. Restrictions and Limitations * DO NOT make more than the Maximum Number of Applications per Year for applications made at the maximum Product Use Rate per Application (25 ozs/A contains 0.395 lb boscalid, 0.200 lb pyraclostrobin). Additional applications per year are permitted when a lower Product Use Rate per Application is used, as long as the Maximum Product Rate per Year (50 ozs/A contains 0.790 lb boscalid, 0.400 lb pyraclostrobin) is not exceeded. • Maximum single application rate is 25 ozs/A (0.395 lb boscalid, 0.200 lb pyraclostrobin). • Maximum annual application rate is 50 ozs/A (0.790 lb boscalid, 0.400 lb pyraclostrobin) per year. • Minimum retreatment interval is 5 days. • Minimum time from application to harvest (PHI) is 21 days. • DO NOT feed treated pea commodities to livestock. ** Not registered for use in California. 51 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Use Rate per Application (ozs/A) Maximum Number of Applications per Year Maximum Product Rate per Year (ozs/A) Minimum Time from Application to Harvest (PHI) (days) Peanut** Early leaf spot Cercospora arachidicola Late leaf spot Cercosporidium personatum Pepperspot Leptosphaerulina crassiasca Rust Puccinia arachidis Web blotch Phoma arachidicola 12.5 to 18.5 3* 84 14 Rhizoctonia limb rot, peg rot, and pod rot Rhizoctonia solani Sclerotinia blight Sclerotinia minor Sclerotium rot, Southern blight, Southern stem rot, and White mold Sclerotium rolfsii 18.5 to 28 (continued) 52 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Peanut** (continued) Application Directions. For control of pepperspot, rust, web blotch, early and late leaf spot, begin applications of Pristine prior to onset of disease development and continue on a 14-day interval. For control of Rhizoctonia and Sclerotium rot, begin applications of Pristine prior to onset of disease development and continue on a 14-day interval. For control of Sclerotinia blight, begin applications of Pristine prior to onset of disease development or 45 to 60 days after planting. Make a second application 14 to 21 days later. Use the higher rate and/or shorter spray interval when disease pressure is high or in fields with a history of disease. Resistance Management. To limit the potential for development of resistance, DO NOT make more than two (2) sequential applications of Pristine or other Group 7 or Group 11 fungicides before alternating to a labeled fungicide with a different mode of action. Restrictions and Limitations * DO NOT make more than the Maximum Number of Applications per Year for applications made at the maximum Product Use Rate per Application (28 ozs/A contains 0.442 lb boscalid, 0.224 lb pyraclostrobin). Additional applications per year are permitted when a lower Product Use Rate per Application is used, as long as the Maximum Product Rate per Year (84 ozs/A contains 1.33 lbs boscalid, 0.672 lb pyraclostrobin) is not exceeded. • Maximum single application rate is 28 ozs/A (0.442 lb boscalid, 0.224 lb pyraclostrobin). • Maximum annual application rate is 84 ozs/A (1.33 lbs boscalid, 0.672 lb pyraclostrobin) per year. • Use of Pristine with silicone-based adjuvants may cause crop injury. • DO NOT apply by air. • DO NOT feed treated peanut hay to livestock. • DO NOT graze livestock or harvest for forage use. • Minimum retreatment interval is 14 days. • Minimum time from application to harvest (PHI) is 14 days. ** Not registered for use in California. Crop Target Disease Product Use Rate per Application (ozs/A) Maximum Number of Applications per Year Maximum Product Rate per Year (ozs/A) Minimum Time from Application to Harvest (PHI) (days) Persimmon Cercospora leaf spot Cercospora spp. 18.5 to 23.0 3 69 0 Application Directions. Dosage and frequency/timing of applications. Begin applications of Pristine prior to the onset of disease development and continue on a 7-day to 14-day interval. Use the shorter interval and/or higher rate when disease pressure is high. Resistance Management. To limit the potential for development of resistance, DO NOT exceed the specified number of applications of Pristine or other Group 7 or Group 11 fungicides per year. Adhere to the label instructions regarding the consecutive use of Pristine or other target site of action Group 7 and Group 11 fungicides that have a similar site of action on the same pathogens. Restrictions and Limitations • Maximum single application rate is 23 ozs/A (0.363 lb boscalid, 0.184 lb pyraclostrobin). • Maximum annual application rate is 69 ozs/A (1.09 lbs boscalid, 0.552 lb pyraclostrobin) per year. • DO NOT make more than three (3) applications of Pristine per year. • Minimum retreatment interval is 7 days. 53 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Use Rate per Application (ozs/A) Maximum Number of Applications per Year Maximum Product Rate per Year (ozs/A) Minimum Time from Application to Harvest (PHI) (days) Pome fruit [group 11-10] Apple Azarole Crabapple Loquat Mayhaw Medlar Pear Pear, Asian Pear, Oriental Quince Quince, Chinese Quince, Japanese Tejocote Cultivars, varieties and/or hybrids of these Alternaria blotch Alternaria mali Apple scab Venturia inaequalis Bitter rot Colletotrichum spp. Black rot/Frogeye leaf spot Botryosphaeria obtusa Blue mold** Penicillium spp. Brooks spot Mycosphaerella pomi Flyspeck Zygophiala jamaicensis Gray mold** Botrytis spp. Pear scab Venturia pirina Powdery mildew Podosphaera leucotricha Sooty blotch (disease complex) White rot Botryosphaeria dothidea Suppression Only: Cedar apple rust Gymnosporangium juniperi-virginianae Quince rust Gymnosporangium clavipes 14.5 to 18.5 4* 74 0 (continued) 54 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Pome fruit [group 11-10] (continued) Application Directions for scab, powdery mildew, frogeye leaf spot and rust. Begin applications of Pristine prior to disease development and continue on a 7-day to 10-day interval. Application Directions for blue mold, gray mold, sooty blotch, flyspeck, white rot, black rot, bitter rot and Alternaria blotch. Begin applications of Pristine prior to disease development and continue on a 7-day to 14-day interval. Use the higher rate and shorter interval when disease pressure is high. No restriction on livestock grazing or feeding for pome fruit feed items. For aerial application to pome fruit trees, use no less than 10 gallons of spray solution per acre. Resistance Management. To limit the potential for development of resistance, DO NOT make more than four (4) applications of Pristine or other Group 7 or Group 11 fungicides per year. DO NOT make more than two (2) sequential applications of Pristine before alternating to a labeled fungicide with a different mode of action. Restrictions and Limitations * DO NOT make more than the Maximum Number of Applications per Year for applications made at the maximum Product Use Rate per Application (18.5 ozs/A contains 0.292 lb boscalid, 0.148 lb pyraclostrobin). Additional applications per year are permitted when a lower Product Use Rate per Application is used, as long as the Maximum Product Rate per Year (74 ozs/A contains 1.17 lbs boscalid, 0.592 lb pyraclostrobin) is not exceeded. • Maximum single application rate is 18.5 ozs/A (0.292 lb boscalid, 0.148 lb pyraclostrobin). • Maximum annual application rate is 74 ozs/A (1.17 lbs boscalid, 0.592 lb pyraclostrobin) per year. • For pears, DO NOT use Pristine with a horticultural mineral oil as crop response to foliage and/or fruit can occur under certain conditions. • Minimum retreatment interval is 7 days. ** Not registered for use in California. 55 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Use Rate per Application (ozs/A) Maximum Number of Applications per Year Maximum Product Rate per Year (ozs/A) Minimum Time from Application to Harvest (PHI) (days) Root vegetables (except sugar beet) [subgroup 1B]** Beet, garden Burdock, edible Celeriac Chervil, turnip-rooted Chicory Ginseng Horseradish Parsley, turnip-rooted Parsnip Radish Radish, oriental Rutabaga Salsify Salsify, black Salsify, Spanish Skirret Turnip Alternaria leaf spot Alternaria spp. Cercospora leaf spot Cercospora spp. Powdery mildew Erysiphe spp. Suppression Only: Southern root rot Sclerotium rolfsii 8 to 10.5 6* 63 0 Application Directions. Begin applications of Pristine prior to onset of disease development and continue on a 7-day to 14-day interval. Use the higher rate and the shorter interval when disease pressure is high. Resistance Management. To limit the potential for development of resistance, DO NOT make more than one (1) application of Pristine before alternating to a labeled fungicide with a different mode of action for at least one application. Restrictions and Limitations * DO NOT make more than the Maximum Number of Applications per Year for applications made at the maximum Product Use Rate per Application (10.5 ozs/A contains 0.166 lb boscalid, 0.084 lb pyraclostrobin). Additional applications per year are permitted when a lower Product Use Rate per Application is used, as long as the Maximum Product Rate per Year (63 ozs/A contains 0.995 lb boscalid, 0.504 lb pyraclostrobin) is not exceeded. • Maximum single application rate is 10.5 ozs/A (0.166 lb boscalid, 0.084 lb pyraclostrobin). • Maximum annual application rate is 63 ozs/A (0.995 lb boscalid, 0.504 lb pyraclostrobin) per year. • Minimum retreatment interval is 7 days. ** Not registered for use in California. 56 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Use Rate per Application (ozs/A) Maximum Number of Applications per Year Maximum Product Rate per Year (ozs/A) Minimum Time from Application to Harvest (PHI) (days) Soybean** Alternaria leaf spot Alternaria spp. Anthracnose Colletotrichum truncatum Brown spot Septoria glycines Cercospora blight Cercospora kikuchii Frogeye leaf spot Cercospora sojina Pod and stem blight Diaporthe phaseolorum Rhizoctonia aerial blight Rhizoctonia solani 8 to 16 2* 32 21 Asian soybean rust Phakopsora pachyrhizi 12.5 to 16 Southern blight Sclerotium rolfsii White mold Sclerotinia sclerotiorum 16 Application Directions. For optimal disease control, apply Pristine at early flowering (R1 to R3 growth stage) or prior to disease development, whichever is earlier. Make a second application 7 to 21 days later if monitoring shows disease development or if conditions are conducive for disease infection. Use the higher labeled rate and shorter interval when disease pressure is high. Pristine may be applied with adjuvants. Resistance Management. To limit the potential for development of resistance, DO NOT make more than one (1) application of Pristine before alternating to a labeled fungicide with a different mode of action for at least one (1) application. Restrictions and Limitations * DO NOT make more than the Maximum Number of Applications per Year for applications made at the maximum Product Use Rate per Application (16 ozs/A contains 0.253 lb boscalid, 0.128 lb pyraclostrobin). Additional applications per year are permitted when a lower Product Use Rate per Application is used, as long as the Maximum Product Rate per Year (32 ozs/A contains 0.506 lb boscalid, 0.256 lb pyraclostrobin) is not exceeded. • Maximum single application rate is 16 ozs/A (0.253 lb boscalid, 0.128 lb pyraclostrobin). • Maximum annual application rate is 32 ozs/A (0.506 lb boscalid, 0.256 lb pyraclostrobin) per year. • Minimum retreatment interval is 7 days. • DO NOT use soybean forage as feed earlier than 14 days after last application. • DO NOT use soybean hay as feed earlier than 21 days after last application. • Minimum time from application to harvest (PHI) is 21 days. ** Not registered for use in California. 57 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Use Rate per Application (ozs/A) Maximum Number of Applications per Year Maximum Product Rate per Year (ozs/A) Minimum Time from Application to Harvest (PHI) (days) Spinach Spinach (Malabar, New Zealand, and tanier) Alternaria leaf spot Alternaria spp. Anthracnose Colletotrichum spp. Ascochyta leaf spot Ascochyta spp. Cercospora leaf spot Cercospora spp. Downy mildew Peronospora spp. Phoma Phoma spp. Powdery mildew Erysiphe spp., Phyllactinia spp., Sphaerotheca spp. Rust Puccinia spp. Septoria leaf spot Septoria spp. White rust Albugo spp. 10 to 15 2* 50 14 Botrytis rot Botrytis spp. Sclerotinia rot and blight Sclerotinia spp. 25 Application Directions. Begin applications of Pristine prior to the onset of disease development and continue on a 7-day interval. Use the higher rate when disease pressure is high. Resistance Management. To limit the potential for development of resistance, DO NOT make more than one (1) application of Pristine before alternating to a labeled fungicide with a different mode of action for at least one (1) application. Restrictions and Limitations * DO NOT make more than the Maximum Number of Applications per Year for applications made at the maximum Product Use Rate per Application (25 ozs/A contains 0.395 lb boscalid, 0.200 lb pyraclostrobin). Additional applications per year are permitted when a lower Product Use Rate per Application is used, as long as the Maximum Product Rate per Year (50 ozs/A contains 0.790 lb boscalid, 0.400 lb pyraclostrobin) is not exceeded. • Maximum single application rate is 25 ozs/A (0.395 lb boscalid, 0.200 lb pyraclostrobin). • Maximum annual application rate is 50 ozs/A (0.790 lb boscalid, 0.400 lb pyraclostrobin) per year. • Minimum retreatment interval is 7 days. • Minimum time from application to harvest (PHI) is 14 days. 58 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Use Rate per Application (ozs/A) Maximum Number of Applications per Year Maximum Product Rate per Year (ozs/A) Minimum Time from Application to Harvest (PHI) (days) Stone fruit [group 12-12] Apricot Apricot, Japanese Capulin Cherry, black Cherry, Nanking Cherry, sweet Cherry, tart Jujube, Chinese Nectarine Peach Plum Plum, American Plum, beach Plum, Canada Plum, cherry Plum, Chickasaw Plum, Damson Plum, Japanese Plum, Klamath Plum, prune Plumcot Sloe Cultivars, varieties, and/or hybrids of these Alternaria leaf spot Alternaria spp. Anthracnose Colletotrichum spp. Blossom blight Monilinia spp. Brown rot Monilinia spp. Leaf spot Blumeriella jaapii Powdery mildew Podosphaera spp., Sphaerotheca spp. Ripe fruit rot Botrytis cinerea, Monilinia fructicola, Monilinia laxa, Rhizopus spp. Rust Tranzschelia discolor Scab Cladosporium carpophilum Shothole Wilsonomyces carpophilus 10.5 to 14.5 5* 72.5 0 Nectarine Peach Suppression Only: Leaf curl** Taphrina deformans Application Directions. Begin application of Pristine at pink bud or prior to onset of disease development and continue on a 7-day to 14-day interval. Use the shorter interval and/or the higher rate when disease pressure is high. For aerial application to stone fruit trees, use no less than 10 gallons of spray solution per acre. Resistance Management. To limit the potential for development of resistance, DO NOT make more than two (2) sequential applications of Pristine or other Group 7 or Group 11 fungicides before alternating to a labeled fungicide with a different mode of action. Restrictions and Limitations * DO NOT make more than the Maximum Number of Applications per Year for applications made at the maximum Product Use Rate per Application (14.5 ozs/A contains 0.229 lb boscalid, 0.116 lb pyraclostrobin). Additional applications per year are permitted when a lower Product Use Rate per Application is used, as long as the Maximum Product Rate per Year (72.5 ozs/A contains 1.15 lbs boscalid, 0.580 lb pyraclostrobin) is not exceeded. • Maximum single application rate is 14.5 ozs/A (0.229 lb boscalid, 0.116 lb pyraclostrobin.) • Maximum annual application rate is 72.5 ozs/A (1.15 lbs boscalid, 0.580 lb pyraclostrobin) per year. • Minimum retreatment interval is 7 days. ** Not registered for use in California. 59 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Use Rate per Application (ozs/A) Maximum Number of Applications per Year Maximum Product Rate per Year (ozs/A) Minimum Time from Application to Harvest (PHI) (days) Strawberry Anthracnose Colletotrichum spp. Botrytis gray mold Botrytis cinerea Leaf spot Mycosphaerella fragariae Powdery mildew Sphaerotheca macularis 18.5 to 23 5* 115 0 Application Directions. Begin applications of Pristine no later than 10% bloom, or prior to disease development, and continue on a 7-day to 14-day interval. Use the higher rate and the shorter interval when disease pressure is high. It is impossible for BASF to test strawberry sensitivity to Pristine under all environments and all potential product mixture combinations. Local conditions can also influence crop response and may not match those under which BASF has conducted testing. Proceed with caution with regard to Pristine use, particularly in tank mixes and/or adjuvant combinations on strawberry crops. To reduce the risk of strawberry crop injury, BASF advises testing Pristine or Pristine tank mixtures on a small portion of the crop before broad scale use. To the extent consistent with applicable law, the user assumes all risks associated with adding products to the Pristine spray solution. Refer also to the Conditions of Sale and Warranty section of this label. Resistance Management. To limit the potential for development of resistance, DO NOT make more than two (2) sequential applications of Pristine or other Group 7 or Group 11 fungicides before alternating to a labeled fungicide with a different mode of action. Restrictions and Limitations * DO NOT make more than the Maximum Number of Applications per Year for applications made at the maximum Product Use Rate per Application (23 ozs/A contains 0.363 lb boscalid, 0.184 lb pyraclostrobin). Additional applications per year are permitted when a lower Product Use Rate per Application is used, as long as the Maximum Product Rate per Year (115 ozs/A contains 1.82 lbs boscalid, 0.920 lb pyraclostrobin) is not exceeded. • Maximum single application rate is 23 ozs/A (0.363 lb boscalid, 0.184 lb pyraclostrobin). • Maximum annual application rate is 115 ozs/A (1.82 lbs boscalid, 0.920 lb pyraclostrobin) per year. • Minimum retreatment interval is 7 days. 60 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Use Rate per Application (ozs/A) Maximum Number of Applications per Year Maximum Product Rate per Year (ozs/A) Minimum Time from Application to Harvest (PHI) (days) Tree nut [group 14-12] African nut-tree Almond Beechnut Brazil nut Brazilian pine Bunya Bur oak Butternut Cajou nut Candlenut Cashew Chestnut Chinquapin Coconut Coquito nut Dika nut Ginkgo Guiana chestnut Hazelnut (Filbert) Heartnut Hickory nut Japanese horse-chestnut Macadamia nut Mongongo nut Monkey-pot Monkey puzzle nut Okari nut Pachira nut Peach palm nut Pecan Pequi Pili nut Pine nut Pistachio Sapucaia nut Tropical almond Walnut, black Walnut, English Yellowhorn Cultivars, varieties, and/or hybrids of these Alternaria leaf spot Alternaria spp. Anthracnose Colletotrichum spp., Marossonina juglandis Blossom blight Monilinia spp. Botrytis blossom and shoot blight/Green fruit rot Botrytis cinerea Eastern filbert blight Anisogramma anomala Leaf rust Tranzschelia discolor Panicle and shoot blight Botryosphaeria spp. Scab Cladosporium spp. Shothole Wilsonomyces carpophilus 10.5 to 14.5 4* 58 14 (for almond - 25 days) (continued) 61 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Tree nut [group 14-12] (continued) Application Directions. In almond, begin applications of Pristine at pink bud and continue on a 7-day to 14-day interval up to 25 days before harvest. In filbert, begin applications at budswell to budbreak, prior to infection and onset of disease development. Continue on a 7-day to 14-day interval to cover and protect new growth. In pecan, begin applications of Pristine prior to onset of disease development and continue on a 7-day to 21-day interval for the control of scab. In pistachio, begin applications prior to the onset of disease development and continue on a 10-day to 30-day interval. For all other crops listed above, apply Pristine prior to disease development and continue on a 7-day to 28-day interval. In all cases, use the shorter interval when shoot growth is very rapid. Use the shorter interval and/or the higher rate when disease pressure is high. No restriction on livestock feeding for almond hulls. For aerial application to tree nuts, use no less than 10 gallons of spray solution per acre. Resistance Management. To limit the potential for development of resistance, DO NOT make more than two (2) sequential applications of Pristine or other Group 7 or Group 11 fungicides before alternating to a labeled fungicide with a different mode of action. Restrictions and Limitations * DO NOT make more than the Maximum Number of Applications per Year for applications made at the maximum Product Use Rate per Application (14.5 ozs/A contains 0.229 lb boscalid, 0.116 lb pyraclostrobin). Additional applications per year are permitted when a lower Product Use Rate per Application is used, as long as the Maximum Product Rate per Year (58 ozs/A contains 0.916 lb boscalid, 0.464 lb pyraclostrobin) is not exceeded. • Maximum single application rate is 14.5 ozs/A (0.229 lb boscalid, 0.116 lb pyraclostrobin). • Maximum annual application rate is 58 ozs/A (0.916 lb boscalid, 0.464 lb pyraclostrobin) per year. • Minimum retreatment interval is 7 days. • Minimum time from application to harvest (PHI) is 14 days. (for almond - 25 days) 62 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Use Rate per Application (ozs/A) Maximum Number of Applications per Year Maximum Product Rate per Year (ozs/A) Minimum Time from Application to Harvest (PHI) (days) Tropical fruits[*] (listed) Black sapote Canistel Mamey sapote Mango Papaya Sapodilla Star apple Anthracnose Colletotrichum gloeosporioides Black spot Alternaria alternata, Asperisporium caricae, Cercospora papayae Dry rot Mycosphaerella spp. Powdery mildew Erysiphe spp., Oidium spp. Pseudocercospora spot/blotch Cercospora spp., Pseudocercospora purpurea Scab Elsinoe mangiferae 18.5 2 37 0 Application Directions. Begin application of Pristine prior to the onset of disease development and repeat application 7 days later, as needed, or alternate with another labeled fungicide having a different mode of action. Resistance Management. To limit the potential for development of resistance, DO NOT make more than two (2) sequential applications of Pristine or other Group 7 or Group 11 fungicides before alternating to a labeled fungicide with a different mode of action. Restrictions and Limitations • Maximum single application rate is 18.5 ozs/A (0.292 lb boscalid, 0.148 lb pyraclostrobin). • Maximum annual application rate is 37 ozs/A (0.585 lb boscalid, 0.296 lb pyraclostrobin) per year. • DO NOT make more than two (2) applications of Pristine per year. • Minimum retreatment interval is 7 days. • DO NOT apply Pristine as a tank mix with any pesticide product (includes any fungicide, herbicide, or insecticide), fertilizer, nutrient or additive other than nonionic surfactant (NIS). NIS rate not to exceed 11 ozs/100 gallons (0.08% v/v). [Optional text: * Not registered for use in California.] 63 Table 3. Pristine® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Use Rate per Application (ozs/A) Maximum Number of Applications per Year Maximum Product Rate per Year (ozs/A) Minimum Time from Application to Harvest (PHI) (days) Turnip greens Alternaria leaf spot and blight Alternaria spp. Anthracnose Colletotrichum spp. Cercospora leaf spot Cercospora brassicicola Downy mildew Peronospora parasitica Gray mold Botrytis cinerea Powdery mildew Erysiphe polygoni Rhizoctonia stem rot and Bottom rot Rhizoctonia solani Ring spot Mycosphaerella brassicicola Sclerotinia stem rot Sclerotinia minor, S. sclerotiorum Southern blight Sclerotium rolfsii White rust Albugo candida 18.8 to 25 2 50 14 Application Directions. Begin Pristine applications prior to disease development and continue on a 7-day to 10-day interval. Use the higher rate and shorter interval when disease pressure is high. Resistance Management. To limit development of resistance, DO NOT make more than two (2) sequential applications of Pristine or other Group 7 or Group 11 fungicides before alternating to a labeled fungicide with a different mode of action. Restrictions and Limitations • Maximum single application rate is 25 ozs/A (0.395 lb boscalid, 0.200 lb pyraclostrobin). • Maximum annual application rate is 50 ozs/A (0.790 lb boscalid, 0.400 lb pyraclostrobin) per year. • DO NOT make more than two (2) applications of Pristine per year. • Minimum retreatment interval is 7 days. • Minimum time from application to harvest (PHI) is 14 days. • DO NOT apply by air. • DO NOT apply through any type of irrigation system (chemigation). 64 © 2022 BASF Corporation All rights reserved. 007969-00199.20220801.NVA 2022-04-0156-0149 Supersedes: NVA 2022-04-0156-0113 BASF Corporation 26 Davis Drive Research Triangle Park, NC 27709 Cabrio, Endura, Headline and Pristine are registered trademarks of BASF. Conditions of Sale and Warranty The Directions For Use of this product reflect the opinion of experts based on field use and tests. The directions are believed to be reliable and must be followed carefully. However, it is impossible to eliminate all risks inherently associated with the use of this product. Crop injury, ineffectiveness or other unintended consequences may result because of such factors as weather conditions, presence of other materials, or use of the product in a manner inconsistent with its labeling, all of which are beyond the control of BASF CORPORATION (“BASF”) or the Seller. To the extent consistent with applicable law, all such risks shall be assumed by the Buyer. BASF warrants that this product conforms to the chemical description on the label and is reasonably fit for the purposes referred to in the Directions For Use , subject to the inherent risks, referred to above. TO THE EXTENT CONSISTENT WITH APPLICABLE LAW, BASF MAKES NO OTHER EXPRESS OR IMPLIED WARRANTY OF FITNESS OR MERCHANTABILITY OR ANY OTHER EXPRESS OR IMPLIED WARRANTY. TO THE EXTENT CONSISTENT WITH APPLICABLE LAW, BUYER’S EXCLUSIVE REMEDY AND BASF’S EXCLUSIVE LIABILITY, WHETHER IN CONTRACT, TORT, NEGLIGENCE, STRICT LIABILITY, OR OTHERWISE, SHALL BE LIMITED TO REPAYMENT OF THE PURCHASE PRICE OF THE PRODUCT. TO THE EXTENT CONSISTENT WITH APPLICABLE LAW, BASF AND THE SELLER DISCLAIM ANY LIABILITY FOR CONSEQUENTIAL, EXEMPLARY, SPECIAL OR INDIRECT DAMAGES RESULTING FROM THE USE OR HANDLING OF THIS PRODUCT. BASF and the Seller offer this product, and the Buyer and User accept it, subject to the foregoing Conditions of Sale and Warranty which may be varied only by agreement in writing signed by a duly authorized representative of BASF. 1108