crop-chem-docs/corpus/epa_ppls/100-778.md

DIVIDEND 0.31 FS FUNGICIDE

• EPA Reg No: 100-778
• Registrant: SYNGENTA CROP PROTECTION, LLC
• Signal word: Caution
• Active ingredients: Difenoconazole (3.15%)
• Label accepted: 1997-05-27
• Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/000100-00778-19970527.pdf

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) 100-118 5 -2.1- '17 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY WASHINGTON, D.C. 20460 Dr. Gregory T . Peters' Ciba-Geigy Corporatiop P.O. Box 18300----- .. ---- ... - Greensboro, North Carolina Subject: Dividend O.lS FS MAY 27 1997 274l9-830a EPA Registration Number lOO-778 OFFICE OF PREVENTION, PESTICIDES AND TOXIC SUBSTANC"S Your letter diited January 3l, 1997 -amended label Dear Dr. Peters: The labe'ling referred to, abdve"submttted ~- connection with registrat:Con, uri4er '" the Fed.eral.insec,tic:jde ,fungicide, and Rodenticide Act:., asamendecCls' accept'able provided the following comments are incorporated, ' On the base label the Signal Wordc"CAUT:r:ON" shou;Ld immediately foTlow the-heading "Hazards to Hqmansand Domestic Anima'ls" ' ,-," On page"l,:oftheB.QQk:le,tlal::>el,under the "Note" section, delete the last sentence-sirrc'e-:the label and CSF indicates that the product already contains a dye. Submit one (l) copy of your final printe(i,labelpriOr to ) releasing the product for shipment. ' Sincerely, 6/ Cynthia Giles-Parker Product Manager (22) Fungicide Branch Registr<:l,tion Division (7S0SC)

) Dividend® 0.31 FS FUNGICIDE A seed treatment for control of diseases of wheat Active Ingre_dient [(2S.4R)/(2R.4S)]I[(2R.4R12S.4S)j 1-{2-[4-(4-chlorophenoxy)-2-chlorophenylj-4- methyl-1.3-dioxolan-2-yl-methyl}-1 H-1.2,4-triazole ........... 3.15% Inert Ingredients: 96.85% Total: 100.00% 212 Gallons U.S. Standard Measure 5 Gallons U. S. Standard Measure 15 Gallons U. S. Standard Measure EPA Reg. No. 100-778 EPA Est. 5905-GA-01 (21/z gals. & 5 gals.) KEEP OUT OF REACH OF CHILDREN .. CAUTION See additional precautionary statements and directions for use inside booklet. CGA CGA CGA (21/z gals.) (5 gals.) (15 gals.) ACCEPI'ED . with COMMENTS In EPA Leiter Dated MAY 27 1997 u~ the Federal Inse.t!dd ... ~m>dl!.! ''''MAd .. ~ed, for tlle ti<ide "'l!:l>tered:::, ... EPA<;t!. No. (£0- 2 '/ L

) ) -2- DIRECTIONS FOR USE AND CONDITIONS OF SALE AND WARRANTY IMPORTANT: Read the entire Directions for Use and the Conditions of Sale and Warranty before using this product. If terms are not accept­ able, retum the unopened product container at once. Conditions of Sale and Warranty The Directions for Use of this product reflect the opinion of experts based on field use and tests. The directions are believed to be reliable and should be followed carefully. However, it is impossible to eliminate all risks inherently associated with use of this product. Crop injury, ineffec­ tiveness, or other unintended consequences may result because of such factors as weather conditions, presence of other materials, or the manner of use or application, all of which are beyond the control of Ciba-Geigy or the Seller. All such risks shall be assumed by the Buyer. Ciba-Geigy warrants that this p"roduct conforms to the chemical descrip­ tion on the label and is reasonably fit for the purposes referred to in the Directions for Use subject to the inherent risks referred to above. Ciba­ Geigy makes no other express or implied warranty of Fitness or Merchantability or any other express or implied warranty. In no case shall Ciba-Geigy or the Seller be liable for consequential, special, or indirect damages resulting from the use or handling of this product. Ciba-Geigyand the Seller offer this product, and the Buyera.nd user accept it, subject to the foregoing Conditions of Sale and Warranty, which may be varied only by agreement in writing signed by a . duly authorized representative of Ciba-Geigy. . .. - - BEST AVAILABLE cOpy

} -3- DIRECTIONS FOR USE 11 is a violation of federal law to use this product in a manner inconsistent with its labeling. Do not apply this product in a way that will contact workers or other per­ sons, either directly or through drift. Only protected handlers may be in the area during application. For any requirements specific to your State or Tribe, consult the agency responsible for pesticide regulation. AGRICULTURAL USE REQUIREMENTS Use this product only in accordance with its labeling and with the Worker Protection Standard, 40 CFR part 170. This Standard con­ tains requirements for the protection of agricultural workers on farms, forests, nurseries, and greenhouses, and handlers of agricul­ tural pesticides. It contains requirements for training, decontamina­ tion, notification, and emergency assistance. It also contains specif­ ic instructions and exceptions pertaining to the statements on this label about personal protective equipment (PPE) and restricted-entry interval. The requirements in this box only apply to uses of this product that are covered by the Worker Protection Standard. Do not enter or allow worker entry into treated areas during the restricted entry interval (REI) of 12 hours. Exception: If the seed is treated with the product and the treated seed is soil-injectea or soil-incorporated, the Worker Protection Standard, under certain cir­ cumstances, allows workers to enter the treated area if there will be no contact with anything that has been treated. PPE required for early entry to treated areas that is permitted under the Worker Protection Standard and that involves contact with any­ thing that has been treated, such as plants, soil, or water is: cover­ alls over long-sleeved shirt and long pants, socks and chemical resistant footwear and waterproof gloves. FAILURE TO FOLLOW THE DIRECTIONS FOR USE AND PRECAUTIONS ON THIS LABEL MAY RESULT IN CROP INJURY, POOR DISEASE CONTROL, ANDIOR ILLEGAL RESIDUES,

) ) -4- General Information Dividend 0.31 FS is a systemicseea dressingwhich controls or suppress­ es certain seed-borne, soil-borne, and fall season foliar diseases of wheat. An EPA-approved coloring agent. Pigment Red 48, has been added to the formulation. Mixing Procedures Dividend 0.31 FS is espeCially formulated for on-farm treatment using standard mechanical slurry or mist type seed treatment equipment which accurately meters and mixes a flowable seed treatment. The equipment must provide uniform coverage of Dividend 0.31 FS on the seed. Uneven seed coverage may not give the desired level of diseas,e control. This product does not require the addition of water for application. Consult the manufacturer of the application equipment ybuplan to use for suitabnity for this application and for instructions on operation and calibration of the equipment. Wheat Apply Dividend 0.31 FS to Wheat seed atthe ratesgiven iTl the following table for control of common bunt (seed-borne and soil-borne), dwarf bunt. loose smut, general seed rots, flag smut. seed-borne Septaria, and fall season powdery mildew, Septoria leaf blotch. and rust; and for partial control of take-all, Fusarium root and crown rot, and common root rot. For control of damping-off of wheat caused by Pythium spp., the recom­ mended rate of Dividend 0.31 FS may be tank mixed with Apron® flow­ able or wettable powder seed treatment products in accordance with the most restrictiVe of label limitations and precautions. No labeled dosage rates should be exceeded. Use the Apron product at a rate of 0.032 oz. active ingredient per 100 Ibs. of seed (2 9 active ingredient!100 kg of seed) tank mixed with the recommended rates of Dividend 0.31 FS. Follow application and other instructions found on the Apron product label. BeST AVAILABLE COpy

Rate/CWT Diseases Controlled 10 fl. oz. 5 II. oz. Common Bunt', Dwarf Bunt, Loose Smut, Flag Smut, Seed-borne Septoria, General Seed Rots', Fusarium Seed Scab Common Bunt', Dwali Bunt, . Flag Smut, Seed-borne Septoria, Loose 'S:mut, General Seed Rots', Fusarium Seed Scab 2,5 II. oz." Common Bunt, Loose Smut ......., DIVIDEND 0.31 FS Winter Wheat Fall Season Foliar Diseases Controlled' Fall Season Powdery Mildew, Fail Season Leaf Rust, Fall Season Septoriat.eal Blotch ;1, ...J Diseases Partially Controlled' Common Root Rot (Coch/lobolus spp.), Fusarium Root Rot, Fusarium Crown Rot, Take-AU, Common Root Rot (Cochliobolus spp.) 'Dividend 0.31 FS provides control of fall season powdery mildew,' fall seailon leaf rust, and fall season Septoria leaf blotch in winter wheat for the.lirst 6 weeks after pJanting. For f\111 season control of these foliar diseases, use nlt®. fungicide according to laber instructions. .! 'Partial control can either mean erratic contral from go;od to poor 6r consistent control at a level below that generally con- sidered acceptable for commercial disease control. . :Dividend 0.31 FS controls both seed-borne and soli-borne common bunt. 'General seed rots controlled include those caused by saprophytic organisms such as Penicillium and Aspergillus. "The 2.5 II. oz. rate should only be used in the followln'g states:· TX, OK, KS, CO, MO, NE, NO, SO, MN, MT. 'I' . i , U1 ~ ~ --......1

) ) Rate/CWT 10 II. oz. 5 II. oz. 2.5 II. oz.' -6- DIVIDEND 0.31 FS Spring Wheat Diseases Controlled -:.. Common Bunt', Seed-borne Septoria, Loose Smut, General Seed Rots', Fusarium Seed Scab Common Bunt, Loose Smut, Fusarium Seed .Scab Diseases Partially Controlled' Take-All. Common Root Rot, Common Root Rot (Cochliobolus spp.), 'Dividend 0.31 FS controls both seed-borne and soil-borne common bunt. 'General seed rots controlled include those causecj by saprophytic organ­ isms such as Penicillium and Aspergillus. 'The 2.5 II. oz. rate should only be used in the following states: TX, OK, KS, CO, MO, NE, NO, SO, MN, MT. . 'Partial control can either mean erratic control from good to poor or con­ sistent control at a level below that generally considered acceptable for commercial disease control. Important: (1) Do not use treated seed for feed, lood, or oil. (2) Green forage may not be grazed until 55 days after planting. (3) Do not plant any crop other than wheat within 30 days to fields in which treated seeds were planted. Note: Federal law requires that bags containing treated seeds shall be labeled with the lollowinginlormation: "This seed has been treated with difenoconazole fungiCide. Do not use for feed, lood, or oil purposes. Store away from leeds and loodstuffs." If necessary, use with an EPA­ approved dye or colorant that imparts an unnatural color to the seed. Storage and Disposal Pesticide Storage and Disposal Do not contaminate water, lood, or leed by storage, disposal, or cleaning 01 equipment. Wastes resulting Irom the use 01 this product may be dis­ posed 01 on site or at an approved waste disposal facility.

) -7- (For 2 hand 5 Gallons) Container Disposal Do not reuse empty container. Triple rinse (or eqhflialent), and offer for recycling or reconditioning, or puncture and dispose of In a sanitary land­ fill, or by incineration. or by openbuming,if allowed by state and local authorities. If burned, keep out of smoke. (For 15 gallons) Container Refilling and Disposal Refer to label on container for refilling and disposal instructions. For minor spills, leaks, etc., follow all precautions indicated on this label and clean up immediately. Take special care to avoid contamination of equipment arid facilities during cleanup and disposal of wastes. In the event of a major spill, fire, or other emergency, call 1-800-888-8372, day or night. Precautionary Statements Hazards to Humans and Domestic Animals CAUTION Harmful if absorbed through skin. Avoid contact with eyes, skin or cloth­ ing. Wear long-sleeved shirt and long pants, socks and shoes and water­ proof gloves. Wash thoroughly with soap and water after handling. Statement of Practical Treatment If on skin: Wash with plenty of soap and .water. Get medical attention if irritation persists. Note to Physician: If ingested, induce emesis or lavage stomach. Treat symptomatically. Personal Protective Equipment Applicators and other handlers must wear: • Long-sleeved shirt and long pants • Waterproof gloves • Shoes plus socks

) ) 8 Follow manufacturer s Instructions for cleaning/maintaining PPE If no such Instructions for washables use detergent and hot water Keep and wash PPE separately from other laundry Engineering Control Statements When handlers use closed systems or enclosed cabs In a manner that meets the reqUirements listed In the Worker Protection Standard (WPS) for agncultural pesticides [40 CFR 170 240(d) (4-6)] the handler PPE reqUirements may be reduced or modified as specified In the WPS User Safety Recommendations Users should: • Wash hands before eating dnnklng, chewing gum uSing tobacco, or uSing the toilet • Remove clothing Immediately If pesticide gets Inside Then wash thoroughly and put on clean clothing Environmental Hazards This product IS tOXIC to fish and aquatic Invertebrates Do not apply directly to water to areas where surface water IS present or to Intertidal areas below the mean high water mark Do not contaminate water when dispOSing of equipment wash vaters or nnsate If treated seed IS spilled outdoors or In areas accessible to birds promptly clean up or bury to prevent Ingestion Apron® Dlvldend® and Tilt® trademarks of Clba-Gelgy Corporation U S Patent No 5 266 585 ©1996 Clba Geigy CorporatIOn

) ) Ciba Crop Protection Seed Treatmenf Products Ciba-Geigy Corporation Greensboro, North Carolina 27419 CGA CGA· CGA (2 '12 gals.) (5 gals.) (15 gals.) -9- [QUARK\DIVIDEND 0.31 FS - DIVO.31FS-BKLTML-A]- ccg - 1/30/97

) Dlvldend® 0 31 FS FUNGICIDE 10- Base Label (For 21z and 5 Gallons) A seed treatment for control of diseases of wheat Active Ingredient [(2S,4R)/(2R 4S)]/[(2R,4R/2S 4S)] 1 {2-[4-(4-chlorophenoxy)-2-chlorophenyl] 4 methyl-1 3-dloxolan-2-yl-methyl}-1 H-1 2 4-tnazole Inert Ingredients Total See directions for use In attached booklet AGRICULTURAL USE REQUIREMENTS 315% 9685% 10000% Use this product only In accordance with ItS labeling and with the Worker ProtectIOn Standard, 40 CFR part 170 Refer to sup­ plementallabehng under "Agricultural Use Requirements" In the Directions for Use section for information about this standard_ EPA Reg No 100-778 EPA Est 5905 GA 01 212 Gallons U S Standard Measure 5 Gallons U S Standard Measure KEEP OUT OF REACH OF CHILDREN_ CAUTION Precautionary Statements Hazards to Humans and Domestic Anrmals Harmful If absorbed through skin Avoid contact with eyes skin or cloth tng Wear long sleeved shirt and long pants socks and shoes and water proof gloves Wash thoroughly with soap and water after handling •

-11 - Statement of Practical Treatment If on skin: Wash with plenty of soap and water. Get medical attention if irritation persists. Note to Physician: If ingested, induce emesis or lavage stomach. Treat symptomatically. Personal Protective Equipment Applicators and other handlers must wear: • Long-sleeved shirt and long pants • Waterproof gloves • Shoes plus socks Follow manufacturer's instructions for cleaning/maintaining PPE. If no such instructions for washables, use detergent and hot water. Keep and wash PPE separately from other laundry. Environmental Hazards This product is toxic to fish and aquatic invertebrates. Do not apply directly to water, to areas where surface water is present, or to intertidal areas below the mean high water mark. Do not contaminate water when disposing of equipment wash waters or rinsate. If treated seed is spilled outdoors or in areas accessible to birds, promptly clean up or bury to prevent ingestion. Container Disposal Do not reuse empty container. Triple rinse (or equivalent), and offer for recycling or reconditioning; or puncture and dispose of in a sanitary land­ fill, or by incineration, or by open burning, if allowed by state and local authorities. If burned, keep out of smoke. For minor spills, leaks, etc., follow all precautions indicated on this label and clean up immediately. Take special care to avoid contamination of equipment and facilities during cleanup and disposalof wastes. In the event of a major spill, fire, or other emergency, call 1-800-888-8372, day or night. . Dividend® trademark of Ciba-Geigy Corporation U.S. Patent No. 5.266,585 ©1996 Ciba-Geigy Corporation

) Ciba Crop Protection Seed Treatment Products Ciba-Geigy Corporation Greensboro. North Carolina 27419 -12- CGA CGA (2'12 gals.) (5 gals.) Product 10.: 52141 Product 10.: January 19. 1995 - Initial label for 0.31 FS on-farm formulation February 19. 1996 - Reduced rotational crop restriction to 30 days April 22. 1996 - Added Kamal Bunt to list of diseases partially controlled [QUARK\DIVIDEND 0.31 FS/DIVO.31FS-BKLTML-Aj- ccg - 10/30/97 /3-117

) ) Revised Draft , ____ n R'::::e-'-'fil:;:;'la'--b-le-) c...c.c:2 Pressure-Sensitive Label Dividend® 0.31 FS FUNGICIDE - ", ':;.- A seed treatment for control of diseases of wheat Active Ingredient: [(2S,4R)/(2R,4S)]1I(2R,4R12S,4S)] 1-{2-[4-(4-chlorophenoxy)-2-chlorophenyl]-4- methyl-1 ,3-dioxolan-2-yl-methyl}-1 H-1 ,2,4-triazole ........... 3.15% Inert Ingredients: . .. 96.85% Total: 100.00% EPA Reg. No.1 00-778 . EPA Est. S905-GA-01 15 Gallons U. S. Standard Measure KEEP OUT OF REACH OF CHILDREN. CAUTION See additional precautionary statements at end of label. ACCEPI'ED with COMMENTS In EPA Letter Dated MAY 27 1997 ,-,.-.......,.,.---, .. "...,"-

) -2- DIRECTIONS FOR USE AND CONDITIONS OF SALE AND WARRANTY IMPORTANT: Read the entire Directions for Use and the Conditions of Sale and Warranty before using this product. If terms are not accept­ able, retum the unopened product container at once. Conditions of Sale and Warranty The Directions for Use of this product reflect the opinion of experts based on field use and tests. The directions are believed to be reliable and should be followed carefully. However, it is impossible to eliminate all risks inherently associated with use of this product. Crop injury, ineffec­ tiveness, or other unintended consequences may result because of such factors as weather conditions, presence of other materials, or the manner of use or application, all of which are beyond the control of Ciba-Geigy or the Seller. All such risks shall be assumed by the Buyer. Ciba-Geigy warrants that this product conforms to the chemical descrip­ tion on the label and is reasonably fit for the purposes referred to in the Directions for Use subject to the inherent risks referred to above. Ciba­ Geigy makes no other express or implied warranty of Fitness or Merchantability or any other express or implied warranty. In no case shall Ciba-Geigy or the Seller be liable for consequential, special, or indirect damages resulting from the use or handling of this product. Ciba-Geigy and the Seller offer this product, and the Buyer and user accept it, subject to the foregoing Conditions of Sale and Warranty, which may be varied only by agreement in writing signed by a duly authorized representative of Ciba-Geigy. Precautionary Statements Hazards to Humans and Domestic Animals CAUTION Harmful if absorbed through skin. Avoid contact with eyes, skin ·or cloth­ ing. Wear long-sleeved shirt and long pants, socks and shoes and water­ proof gloves. Wash thoroughly with soap and water after handling. Statement of Practical Treatment If on skin: Wash with plenty of soap and water. Get medical attention if irritation persists. Note to Physician: If ingested, induce emesis or lavage stomach. Treat symptomatically.

) ) -3- Personal Protective Equipment Applicators and other handlers must wear: • Long-sleeved shirt and long pants • Waterproof gloves • Shoes plus socks Follow manufacturer's instructions for cleaning/maintaining PPE. If no such instructions for washables, use detergent and hot water. Keep and wash PPE separately from other laundry. Environmental Hazards This product is toxic to fish and aquatic invertebrates. Do not apply directly to water, to areas where surtace water is present, or to intertidal areas below the mean high water mark. Do not contaminate water when ·disposing of equipment wash waters or rinsates. If treated seed is spilled outdoors or in areas accessible to birds, promptly clean up or bury to prevent ingestion. - Container Refilling and Disposal This is a refillable container. If the container is to be refilled, do not rinse with any material or introduce any pesticide other than Dividend 0.31 FS. Reseal and return the container to an authorized Ciba-Geigy refilling facil­ ity. If the container is not tobe rejilled, triple rinse (or equivalent) and offer for recycling or reconditioning, or puncture and dispose of in a sani­ tary landfill, or by incineration, or by open burning, if allowed by state and local authorities. If burned, keep out of smoke. To be used in accordance with directions for use in the Dividend 0.31 FS label booklet. See Dividend 0.31 FS label booklet for pesticide disposal instructions. AGRICULTURAL USE REQUIREMENTS Use this product only in accordance with its labeling and with the Worker Protection Standara, 40 CFR part 170. Refer to supplemen­ tal labeling under "Agricultural Use Requirements" in the Directions for Use section for information about this standard.

) -4- For minor spills, leaks, etc., follow all precautions indicated on this label and clean up immediately. Take special care to avoid contamination of equipment and facilities during cleanup and disposal of wastes. In the event of a major spill, fire, or other emergency, call 1-800-888-8372, day or night. Dividend® trademark of Ciba-Geigy Corporation U.S. Patent No. 5,266,585 ©1996 Ciba-Geigy Corporation Ciba Crop Protection Seed Treatment Products Ciba-Geigy Corporation Greensboro, North Carolina 27419 CGA (1!'i gals.) Product 10.: 51881 January 19, 1995 - Initial label for 0.31 FS on-farm formulation [QUARK/DIVIDEND 0.31 FS/DIVID 0.31 FS-PSL-AJ - ccg - 9/5/96 ___ I 7 1'17