crop-chem-docs/corpus/epa_ppls/10182-141.md

TORNADO HERBICIDE

• EPA Reg No: 10182-141
• Registrant: SYNGENTA CROP PROTECTION
• Signal word: Warning
• Active ingredients: Fluazifop-P-butyl (8.3%); Sodium salt of fomesafen (11.59%)
• Label accepted: 1997-08-07
• Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/010182-00141-19970807.pdf

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lolg-)-Jl/-I UNITED STATES ENVIRONMENTAL PROTfCnON AGENCY Mr. Wayne R. Hillebrecht Zeneca Inc., Zeneca Ag Products 1800 Concord Pike P.O. Box 15458 . Wilmington, DE 19850-5458 Dear Mr. Hillebrecht: AUG 7 1997 SUBJECT: Label Amendment Adding Agency-Required Groundwater Advisory Statement Tornado Herbicide . EPA File Symbol: 10182-141 Your Submission Dated May 30, 1997 The labeling referred to above, submitted in connection with registration under the Federal Insecticide, Fungicide, and Rodenticide Act, as amended, is acceptable, provided you make the following changes:

1. Delete the phrase "if irritation persists" from the dermal statement of practical treatment.
2. Add an inhalation statement of practical treatment as follows: "Iflnhaled: Remove victim to fresh air. If not breathing, give artificial respiration, preferably mouth-to-mouth. Get medical attention. 3 . Delete the product, "REFLEX"from the "Tankmix and Sequential Applications for Soybeans" section on page 15. Since both Tornado and Reflex contain~ the active ingredient, fomesafen, use of both products in a tankmix or sequentially could result in unacceptable residues offomesafen in or on soybeans.
3. Reduce the application rate for rhizome johnsongrass control from 1.6 to 1.5 quarts per acre. -5. Revise the statement under "General Use Precautions"xegarding the maximum amount of Tornado that may be applied per acre (1 qt) to allow the higher rate for-rhizome johnsongrass control. The following language is suggested: "A maximum of 1 quart (0.25 lb. activefomesafen + 0.188 lb. active fluazifop-P-butyl) per acre of TORNADO herbicide may be applied, except where higher rates are specifically recommended on this label. In the year of application, however, make only one application per growing season." RD:STANTON:PM Team 23:Rm: 237CM-2:305.-52l8:Disk #6:S524454.LET CONCURRENCES SYMBOL .. . ......... I~~9. ............................................................................... .._ ........................................................ _ ........................... _ .... .... ~ ............... . SURNAME· ... s.,.!l!!!n!.9~... ..... .... .... ..... .... ............... ... .... .. ........ ... ....... .. ........ ..... ............. .................. ...... .... . ................. _... ... . .... .... ..... ............ . ......... _ ......... . DATE ... AUQ 7. 1997 EPA Farm 132().1 (12-70) OFFICIAL FILE COPY

" . We note that several changes to this product's directions for use were made via the notification process on August 25, 1995. Please be aware that PR Notice 95-2 expressly prohibits registrants from making changes in the directions for use by notification, Such changes must be submitted as amendments for Agency review and approval. Enclosure , . Smcerely yours, ~/~fv Joanne I. Miller Product Manager (23) Herbicide Branch Registration Division (7505C)

TORNADO" Herbicide .3 Page 1 of6 TORNADO Container TORN141C.MAS 5119197 Grass and Broadleaf Weed Herbicide for Soybeans COMPLETE DIRECTIONS FOR USE ACTIVE INGREDIENTS: Fluazifop-P-butyl butyl (R)-2-[4[[5-(trifluoromethyl)-2-pyridinyl]oxy]phenoxy] propanoate . . . . . . . . . . . • . •. 8.30% Sodium salt of fomesafen 5-2[chlor0-4-(trifluoromethyl)phenoXY]N-(methylsulfonyl)-2-nitrobenzamide .......... 11.59% INERT INGREDIENTS ................................. : ............... 80.11% TOTAL ............................•..................••. 100.00% Contains 0.75 Ibs. (+) isomer of fluazifop-P-butyl and the equivalent of 11.0% foinesafen or 1 lb. fomesafen active ingredient per gallon. EPA Reg. No. 10182-141 KEEP OUT OF REACH OF CHILDREN WARNING - AVISO Si usted no entiende la etiqueta, busque a alguien para que se la explique a usted en detalle. (If you do not understand the label, find someone to explain it to you in detail.) SEE SIDE PANEL FOR STATEMENT OF PRACTICAL TREATMENT AND PRECAUTIONARY STATEMENTS ACCEPI'ED with COMMENTS In EPA Letter Dated AUG 11997 Under the Fecleral lau yeS lb, ,..,.,dI ..... , millS""""""'" Aet .. omeadcd, r_ the pectlcide regfotered aDd ... EPA R~. No. _-,/tt:?/ I:~-=.!':/L,,"· __ Made in U.S.A. ZENECA Ag Products ZENECAlnc. Wilmington, DE 19850-5458 , " " < , , ,', , < <, <" " ~ " ~ . .. " , < ~ r " •• " c " < • < ", , ..

If 7 s Page 20f6 TORNADO Container TORN141C.MAS 5/19/97 STATEMENT OF PRACTICAL TREATMENT IF IN EYES: Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention if irritation persists. IF ON SKIN: Wash with plenty of soap and water. Get medical attention if irritation persists. FOR 24-HOUR EMERGENCY MEDICAL ASSISTANCE, CALL 1-800-F-A-8-T-M-E-D (327- 8633). FOR CHEMICAL EMERGENCY: Spill, leak, fire, exposure, or accident call CHEMTREC 1-800-424-9300. • PRECAUTIONARY STATEMENTS HAZARDS TO HUMANS AND DOMESTIC ANIMALS WARNING This product contains fomesafen which has been determined to cause tumors in laboratory ahimals (mice). Risks can be reduced by closely following use directions and precautions and by wearing the protective clothing specified elsewhere on this label. CAUSES SUBSTANTIAL, BUT TEMPORARY, EYE INJURY. HARMFUL IF ABSORBED THROUGH SKIN OR INHALED. MAY CAUSE ALLERGIC SKIN RESPONSE. Do not get in eyes or skin or clothing. Avoid breathing vapors or spray mist. PERSONAL PROTECTIVE EQUIPMENT Some materials that are chemical-resistant to this product are listed below. If you want mor options, follow the instructions for category C on an EPA chemical resistance category selection chart. Applicators and other handlers (other than mixers and loaders) must wear: • Long-sleeved shirt and long pants. • Chemical-resistant gloves, such as Barrier Laminate or Butyl Rubber or Nitrile Rubber or Neoprene Rubber or Polyvinyl Chloride (PVC) or Vlton. • Shoes plus socks. • Protective eyewear. ", f (I Mixers and Loaders must wear: < • . . . .. . ( f f • • Long-sleeved shirt and long pants. ' . : . , : ••• , • Chemical-resistant gloves, such as Barrier Laminate or Butyl Rubber or Nitrile 'Rubber'of •• Neoprene Rubber or Polyvinyl Chloride (PVC) or Viton. ' •• • Shoes plus socks. . . ' < < • Protective eyewear. < , ~ , , • Chemical-resistant apron when mixing or loading.

s 7~ Page 3 of6 TORNADO Container TORN141C.MAS 5/19/97 Discard clothing and other absorbent materials that have been drenched or heavily contaminated with this product's concentrate. Do not reuse them. Follow manufacturer's instructions for cleaning/maintaining PPE. If no such instructions for washables, use detergent and hot water. Keep and wash PPE separately from other laundry. When handlers use dosed systems, endosed cabs, or aircraft in a manner that meets the requirements listed in the Worker Protection Standard (WPS) for agricultural pesticides [40 CFR 170.240(d)(4-6)], the handler PPE requirements may be reduced or modified as specified in the WPS. User Safety Recommendations Users should: • Wash hands before eating, drinking, chewing gum, using tobacco or using the toilet. • Remove ciothing immediately if pesticide gets inside. Then wash thoroughly and put 0.0 clean clothing. • Remove PPE immediately after handling this product. Wash the outside of gloves before removing. As soon as possible, wash thoroughly and change into clean clothing. ENVIRONMENTAL HAZARDS This product is toxic to fish. Do not apply directly to water, or to areas where surface water is present, or to intertidal areas below the mean high water mark. Do not contaminate water when disposing of equipment washwaters. Do not apply when weather conditions favor drift from target area. This product contains the active ingredient fomesafen which is known to lea.ch through soil into ground water under certain conditions as a result of label use. Use of this product in areas where soils are permeable, particularly where the water table is shallow, may result in ground­ water contamination. • f ( ( ( .. . .. . " .. c ., • • ... ( ( ( . • , < , , , • ( ( c: C . . .. ,I" < . .. , [. " < • < . " . , •• I t .. " 4, t- • • ••

, CONDITIONS OF SALE t /- ~j Page 4 TORNADO Container TORN141C.MAS 5/19/97 AND LIMITATION OF WARRANTY AND LIABILITY The Directions for Use of this product should be followed carefully. It is impossible to eliminate all risks inherently associated with the use of this product. Crop injury, ineffectiveness or other unintended consequences may result because of such factors as manner of use or application, weather or crop conditions, presence of other materials or other influencing factors in the use of the product, which are beyond the control of ZENECA or Seller. All such risks shall be assumed by Buyer and User, and Buyer and User agree to hold ZENECA and. Seller harmless for any claims relating to such factors. ZENECA warrants that this product conforms to the chemical deSCription on the label and is reasonably fit for the purposes stated in the Directions for Use, subject to the inherent risks referred to above, when used in accordance with directions under normal use conditions. This warranty does not extend to the use of this product contrary to label instructions, or under abnormal conditions or under conditions not reasonably foreseeable to or beyond the control of Seller or ZENECA, and Buyer and User assume the risk of any such use. ZENECA MAKES NO WARRANTIES OF MERCHANTABILITY OR OF FITNESS FOR A PARTICULAR PURPOSE NOR ANY OTHER EXPRESS OR IMPLIED WARRANTY EXCEPT AS STATED ABOVE. In no event shall ZENECA or Seller be liable for any inCidental, consequential or special damages resulting from the use or handling of this product. THE.EXCLUSIVE REMEDY OF THE USER OR BUYER, AND THE EXCLUSIVE LIABILITY OF ZENECA AND SELLER FOR ANY AND ALL CLAIMS, LOSSES, INJURIES OR DAMAGES (INCLUDING CLAIMS BASED ON BREACH OF WARRANTY, CONTRACT, NEGLIGENCE, TORT, STRICT LIABILITY OR OTHERWISE) RESULTING FROM THE USE OR HANDLING OF THIS PRODUCT, SHALL BE THE RETURN OF THE PURCHASE PRICE OF THE PRODUCT OR, AT THE ELECTION OF ZENECA OR SELLER, THE REPLACEMENT OF THE PRODUCT. ZENECA and Seller offer this product, and Buyer and User accept it, subject to the foregOing conditions of sale and limitations of warranty and of liability, which may not be modified except by written agraement signed by a duly authorized representative of ZENECA. , , ,. <" ( , , , , (", , , <" •• « c ( , , " , I" , ,,< ( , , , , , , ~ ( . ,

DIRECTIONS FOR USE 7 1.),5 Page 5 TORNADO Container TORN141C.MAS 5/19/97 It is a violation of Federal law to use this product in a manner inconsistent with its labeling. Do not apply this product through any type of irrigation system. Do not apply this product in a way that will contact workers or other persons, either directly or through drift. Only protected handlers may be in the area during application. For any requirements specific to your State or Tribe, consult the agency responsible for pesticide regulation. AGRICULTURAL USE REQUIREMENTS Use this product only in accordance with its labeling and with the Worker Protection Standard, 40 CFR part 170. Refer to supplemental labeling (Le., attached booklet) under "AGRICULTURAL USE REQUIREMENTS" in the DIRECTIONS FOR USE section for information about this· standard. STORAGE AND DISPOSAL PROHIBITIONS: Do not contaminate water, food or feed by storage or disposal. Open dumping is prohibited. Do not reuse empty container. STORAGE: Store above 32°F in original containers only. If product freezes, return to room temperature and agitate to reconstitute. Keep container closed when not in use. Do not store near food or feed. In case of spill or leak on floor or paved surfaces, soak up with sand, earth or synthetiC absorbent. Remove to chemical waste area. PESTICIDE DISPOSAL: Pesticide wastes are toxic. Irnproper disposal of excess pesticide, spray mixture or rinsate is a violation of Federal law. If these wastes cannot be disposed of by use according to label instructions, contact your State Pesticide or Environmental Control Agency or the Hazardous Waste Representative at the nearest EPA Regional Office for guidance. • CONTAINER DISPOSAL: Metal Containers: Triple rinse (or equivalent). Then offer for recycling or reconditioning or puncture and dispose of in a sanitary landfill or by other procedures approved by state and local authorities. Plastic Containers: Triple rinse (or equivalent). Then offer for recycling or reconditioni"9:cir' : puncture and dispose of in a sanitary landfill by incineration or, if allowed by ~~ ,qnd local. authorities, by burning. If burned, stay out of smoke. . ': , , , • Glass Containers: Triple rinse (or equivalent). Then dispose of in a sanitary 1!!r.cf.1I or D¥o!her approved state and local procedures. . , . ' : < • ,,(, , "., [ , " , , , <,. , , .. t ~ . , ••

" FOR BULK AND MINI-BULK CONTAINERS: 8 7.;,f Page 6 TORNADO Container TORN141C.MAS Sf19f97 Container Disposal: Reseal container and offer for reconditioning, or triple rinse (or equivalent) and offer for recycling or reconditioning, or clean in accordance with manufacturer's instructions. Container Precautions: Before refilling, inspect thoroughly for damage, such as cracks, punctures, bulges, dents, abrasions and damaged or worn thread on closure devices. REFILL ONLY WITH TORNADO". The contents of this container cannot be completely removed by cleaning. Refilling with materials other than TORNADO herbicide will result in contamination and may weaken container. After filling and before transporting, check for leaks. Do not refill or transport damaged or leaking container. CONTAINER IS NOT SAFE FOR FOOD, FEED OR DRINKING WATER. TORNADO" is a trademark of a ZENECA Group Company. ",. <' . , .. ,,(, ( ( t " : , . .. . f' (, " . " .. , , t <I. < t , . "

TORNADO" Herbicide 1 Page 1 of 17 TORNADO Book/et TORN141B.RSF 5/19/97 Grass and Breadleaf Weed Herbicide for Soybeans COMPLETE DIRECTIONS FOR USE ACTIVE INGREDIENTS: Fluazifop-P-butyl butyl (R)-2-[4[[5-{trifluoromethyl)-2-pyridinyl]oxy]phenoxy] propanoate . . . . . . . . . . . • • •. 8.30% Sodium salt of fomesafen 5-2[chlor0-4-(trifIuoromethyl)phenoxy]N-(methyisulfonyl}-2-nitrobenzamide •...•..... 11.59% INERTINGREDIENTS ..... , ........................................... 80.11% TOTAL ..................••....•.•.•......•.............. 100.00% Contains 0.75 Ibs. (+) isomer of fluazifop-P-butyl and the equivalent of 11.0% fomesafen or 1 lb. fomesafen active ingredient per gallon. EPA Reg. No. 10182"141 KEEP OUT OF REACH OF CHILDREN WARNING - AVISO Si usted no entiende la etiqueta, busque a alguien para que se la explique a usted en detalle. (If you do not understand the label, find someone to explain it to you in detail.) Made in U.S.A. ZENECA Ag Products ZENECAlnc. Wilmington, DE 19850-5458 I [ ( r f , , " , , , ,. " , , Co C , ( , , " . , , , , " ., t' l C. , < • • ..

CONDITIONS OF SALE If} 7.)f Page 2 TORNADO Booklet TORN141B.RSF 5/19/97 AND LIMITATION OF WARRANTY AND LIABILITY The Directions for Use of this product should be foffowed carefuffy. It is impossible to eliminate aff risks inherently associated with the use of this product. Crop injury, ineffectiveness or other unintended consequences may result because of such factors as manner of use or application, weather or crop conditions, presence of other materials or other influencing factors in the use of the product, which are beyond the control of ZENECA or Seffer. Aff such risks shaff be assumed by Buyer and User, and Buyer and User agree to hold ZENECA and Seffer harmless for any claims relating to such factors. ZENECA warrants that this product conforms to the chemical description on the label and is reasonably fit for the purposes stated in the Directions for Use, subject to the inherent risks referred to above, when used in a=rdance with directions under normal use conditions. This warranty does not extend to the use of this product contrary to label instructions, or under abnormal conditions or under conditions not reasonably foreseeable to or beyond the control of Seffer or ZENECA, and Buyer and User assume the risk of any such use. ZENECA MAKES NO WARRANTIES OF MERCHANTABILITY OR OF FITNESS FOR A PARTICULAR PURPOSE NOR ANY OTHER EXPRESS OR IMPLIED WARRANTY EXCEPT AS STATED ABOVE. In no event shaff ZENECA or Seffer be liable for any incidental, consequential or special damages resulting from the use or handling of this product. THE EXCLUSIVE REMEDY OF THE USER OR BUYER, AND THE EXCLUSIVE LIABILITY OF ZENECA AND SELLER FOR ANY AND ALL CLAIMS, LOSSES, INJURIES OR DAMAGES (INCLUDING-CLAIMS BASED ON BREACH OF WARRANTY, CONTRACT, NEGLIGENCE, TORT, STRICT LIABILITY OR OTHERWISE) RESULTING FROM THE USE OR HANDLING OF THIS PRODUCT, SHALL BE THE RETURN OF THE PURCHASE PRICE OF THE PRODUCT OR, AT THE ELECTION Ot: ZENECA OR SELLER, THE REPLACEMENT OF THE PRODUCT. ZENECA and Seffer offer this product, and Buyer and User accept it, subject to the foregoing conditions of sale and limitations of warranty and of liability, which may not be modified except by written agreement Signed by a duly authorized representative of ZENECA. ((C((~ , .. , . . , ( . ( { , , " ", . " , . s ..: t c . , .. . • • .. c , " " \ <,' ' ''" It c-o , 0<

TABLE OF CONTENTS . 1/ 1 ,Js' Page 3 TORNADO Bookiet TORN1418.RSF 5/19/97 STATEMENT OF PRACTICAL TREATMENT ....................................... . PRECAUTIONARY STATEMENTS .............................................. . DIRECTIONS FOR USE ...................................... ~ •.. : ... _ ....... . Agricultural Use Requirements .....•..•.•..••.....•....••...••...•.....•.•... Storage and Disposal .......•..•••••.••....•......••...•.•.••.••........... General Information • . . . . • . . . • . • . • . . . • . . . . . . . . . . • • . . . . • . . • • . . .•..•.....•.... Application Directions ...........•................••.••..•.... ..•........... General Use Precautions .........•...•..•....................•........•..••. Rotational Crop Restrictions .......•..................•.......•.............. TORNADO Use Regions .......•..•..............•.....................•.... Tankmix and Sequential Applications for Soybeans ...........•..••............•... Rates and Weed Growth Stages .......................•.................• ' ... . Scientific Names of Weeds (Appendix) ............. _ .......................... . f, (i r r . ., , " .,' , , , " ", . { ( ~ < • , . . ., .. , . , . " I" , .. ~ " ~ • • ••

/~ 1 ,ls Page 4 TORNADO' Bookfet TORN141B.RSF 5/19/97 STATEMENT OF PRACTICAL TREATMENT IF IN EYES: Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention if irritation persists. IF ON SKIN: Wash with plenty of soap and water. Get medical attention if irritation persists. FOR 24-HOUR EMERGENCY MEDICAL ASSISTANCE, CALL 1-800-F-A-5-T -M-E-D (327- 8633). FOR CHEMICAL EMERGENCY: Spill, leak, fire, exposure, or accident call CHEMTREC 1-800-424-9300. PRECAUTIONARY STATEMENTS HAZARDS TO HUMANS AND DOMESTIC ANIMALS WARNING This product contains fomesafen which has been determined to cause tumors in laboratory animals (mice). Risks can be reduced by closely following use directions and precautions and by wearing the protective clothing specified elsewhere on this label. CAUSES SUBSTANTIAL, BVTTEMPORARY, EYE INJURY. HARMFUL IF ABSORBED THROUGH SKIN OR INHALED. MAY CAUSE ALLERGIC SKIN RESPONSE. Do not get in eyes or skin or clothing. Avoid breathing vapors or spray mist: PERSONAL PROTECTIVE EQUIPMENT Some materials that are chemical-resistant to this product are listed below. If you want more options, follow the instructions for category C on an EPA chemical resistance category selection chart. Applicators and other handlers (other than mixers and loaders) must wear: • Long-sleeved shirt and long pants. • Chemical-resistant gloves, such as Barrier Laminate or Butyl Rubber or Nitrile Rubber or Neoprene Rubber or Polyvinyl Chloride (PVC) or Vrton. • Shoes plus socks. • Protective eyewear. • c • ~ • • " . Mixers and Loaders must wear: c { • , • Long-sleeved shirt and long pants. . .. , , , , ••• • Chemical-resistant gloves, such as Barrier Laminate or Butyl Rubber or Nitrill::, Rllbber,«'r • Neoprene Rubber or Polyvinyl Chloride (PVC) or Viton. . , ' . . :' , , • • Shoes plus socks. ' , : , . ' • Protective eyewear. • Chemical-resistant apron when mixing or loading. '" , "' , Co , • • ..

/3 1,Kf PageS TORNADO Booklet TORN141B.RSF 5/19/97 Discard clothing and other absorbent materials that have been drenched or heavily contaminated with this product's concentrate. Do not reuse them. Follow manufacturer's instructions for cleaning/maintaining PPE. If no such instructions for washables, use detergent and hot water. Keep and wash PPE separately from other laundry. When handlers use closed systems, enclosed cabs, or aircraft in a manner that meets the reqUirements listed in the Worker Protection Standard (WPS) for agricultural pesticides [40 CFR 170.240(d)(4-6)], the handler PPE requirements may be reduced or modified as specified in the WPS. User Safety Recommendations Users should: • Wash hands before eating, drinking, chewing gum, using toba= or using the toilet. • Remove clothing immediately if pesticide gets inside. Then wash thoroughly and put on clean clothing. • Remove PPE immediately after handling this product. Wash the outside of gloves before removing. As soon as pOSSible, wash thoroughly and change into clean clothing. ENVIRONMENTAL HAZARDS This product is toxic to fish. Do not apply directly to water, or to areas where surface water is present, or to intertidal areas below the mean high water mark. Do not contaminate water when disposing of equipment washwaters. Do not apply when weather conditions favor drift from target area. < < f ( C C . " • " t ~ ,.. • c « • ( C • C • , , , ' , , C' ( •• , , , ", . , , « ( < • l • • ... c • • ••

/'1 'f..)-J Page 6 TORNADO Booklet TORN141B.RSF 5/19/97 DIRECTIONS FOR USE It is a violation of Federal law to use this product in a manner inconsistent with its labeling. Do not apply this product through any type of irrigation system. Do not apply this product in a way that will contact workers or other persons, either directly or through drift. Only protected handlers may be in the area during application. For any requirements specific to your State or Tribe, consult the agency responsible for pesticide regulation. AGRICULTURAL USE REQUIREMENTS Use this product only in accordance with its labeling and with the Worker Protection Standard, 40 CFR part 170. This Standard contains requirements for the protection of agricultural workers on fanns, forests, nurseries, and greenhouses, and handlers of agricultural pesticides. It contains requirements for training, decontamination, notification, and emergency assistance. It also contains specific instructions and exceptions pertaining to the statements on this label about personal protective equipment (PPE), and restricted-entry interval. The requirements in this box only apply to uses of this product that are covered by the Worker Protection Standard. Do not enter or allow worker entry into treated areas during the restricted·entry interval (REI) of 24 hours. PPE required for early entry to treated areas that is pennitted under the Worker Protection Standard and that involves contact with anything that has been treated, such as plants, soil, or water, is: • Coveralls. • Chemical-resistant gloves, such as Barrier Laminate or Butyl Rubber or Nitrile Rubber or Neoprene Rubber or Polyvinyl Chloride (PVC) or Viton. • Shoes plus socks. • Protective eyewear. STORAGE AND DISPOSAL PROHIBITIONS: Do not contaminate water, food or feed by storage or disposal. Open dumping is prohibited. Do not reuse empty container. ( ... STORAGE: Store above 32°F in Original containers only. If product freezes, return to roOm' : temperature and agitate to reconstitute. Keep container closed when not in U£E:.' ,00 not store near food or feed. In case of spill or leak on floor or paved surfaces, soak up With sand, ttl1' Qr synthetic absorbent. Remove to chemical waste area. . , : ' , : ' , , , , , , , PESTICIDE DISPOSAL: Pesticide wastes are toxic. Improper disposal of ex$ :oasticide,: ' spray mixture or rinsate is a violation of Federal law. If these wastes cannot be disposed of by use according to label instructions, contact your State Pesticide or Environmental Control' , : , , ' Agency or the Hazardous Waste Representative at the nearest EPA Regional Office for •••• : guidance. ••

/.> 1"'.f' Page 7 TORNADO Booklet TORN141B.RSF 5f19f97 CONTAINER DISPOSAL: Metal Containers: Triple rinse (or equivalent). Then offer for recycling or reconditioning or puncture and dispose of in a sanitary landfill or by other procedures approved by state and local authorities. Plastic Containers: Triple rinse (or equivalent). Then offer for recycling or reconditioning or puncture and dispose of in a sanitary landfill by incineration or, if allowed by state and local authorities, by burning. If burned, stay out of smoke. Glass Containers: Triple rinse (or equivalent). Then dispose of in a sanitary landfill or by other approved state and local procedures. FOR BULK AND MINI-BULK CONTAINERS: Container Disposal: Reseal container and offer for reconditioning, or triple rinse (or equivalent) and offer for recycling or reconditioning, or clean in accordance with manufacturer's instructions. Container Precautions: Before refilling, inspect thoroughly for damage, such as cracks, punctures, bulges, dents, abrasions and damaged or wom thread on closure devices. REFILL ONLY WITH TORNADO"'. The contents of this container cannot be completely removed by cleaning. Refilling with materials other than TORNADO herbicide will result in contamination and may weaken container. After filling and before transporting, check for leaks. Do not refill or transport damaged or leaking container. CONTAINER IS NOT SAFE FOR FOOD, FEED OR DRINKING WATER. GENERAL INFORMATION Read all label directions before using. TORNADO herbicide is a selective early postemergence herbicide for control of grass and broadleaf weeds in soybeans. - TORNADO herbicide has systemic activity moving from the treated foliage into the shoots, roots, rhizomes, stolons, and growing points (meristematic regions) of treated grass weeds and contact activity for broad leaf weeds. Thorough coverage of all weed plant foliage is important for goot! activity. Optimum weed control is achieved when young actively growing weeds are treated that are not under stress from moisture, temperature, low soil fertility, mechanical or chemical injury. Control Symptoms: Growth of treated grass weeds stops soon after application. Symptoms include loss of vigor, yellowing andfor reddening, and eventual death to the treated grass plant. Symptoms on grass weeds are generally observed within one week, depending on species and environmental conditions. , , , , Symptoms on broadleaf weeds occur within 3 days and appear as bl"O\i\ffling and crinkling. " < "", , Soybean plants are tolerant to TORNADO herbicide when it is applied at the rerrlended . There may be slight bronzing, crinkling or spotting of soybean leaves but soybean: 500n oVtgmw these effects and develop normally. , , , , '. ", , ,<" ' Information on Weed Resistance ,., . Naturally occurring biotypes of certain grass species with resistance to this herbicide and re)a products (same mode of action) are known to exist. Selection of resistant biotypes, through repeated use of these herbicides, may result in control failures.

/6 7).J' Page 8 TORNADO Booklet TORN141B.RSF 5/19/97 If poor performance cannot be attributed to adverse weather conditions or improper application methods, a resistant biotype may be present. In such a case, additional treatments with this herbicide or related products is not recommended. Consult your local company representative or agricultural advisor for assistance. APPLICATION DIRECTIONS Timing - Best control of susceptible weeds is obtained when TORNADO herbicide is applied to actively growing young weeds before they exceed the recommended growth stages shown on this label. Refer to the weed tables for specific recommendations on weed growth stages. Generally, the application should occur 10 to 21 days after soybean emergence. Spray Additives - Only spray additives cleared for use on growing crops under 40 CFR 180.1001 may be used in spray mixture. ALWAYS ADD ONE OF THE FOLLOWING: Crop Oil Concentrate - Add a nonphytotoxic crop oil concentrate at 0.5-1% (1 quart per 25 gallons) of the finished spray volume for ground sprays. For aerial applications, add 1 pint of crop oil concentrate per acre. crop oil concentrate can improve weed control but may Slightly reduce crop tolerance. Nonionic Surfactant - Add nonionic surfactant containing at least 75% surface active agent, at 0.25 - 0.5% (1/2 - 1 pint per 25 gallons) of the finished spray volume for ground sprays. For aerial applications, add v.z pint nonionic surfactant per acre. Other Adjuvants - Adjuvants other than COC or NIS may be used providing the product meets the following criteria:

1. Contains only EPA exempt ingredients.
2. Is non phytotOXiC to the target crop.
3. Is compatible in mixture. (May be established through a jar test).
4. Is supported locally for use with TORNADO on the target crop through proven field trials and through university and extension recommendations. Always refer to the product label and follow recommendations concerning rates, target crops, . environmental effect such as drought or weed stress, and use in tankmix with other labeled pesticides. In addition to crop oil concentrate or nonionic surfactant, diammonium phosphate (aqueous ammonium polyphosphate) commonly sold as a solution (10-34-0) can be added to the spray mixture. This water soluble material should be used at a rate of 2 pints per acre. Diammoflivrn phosphate should not be used as a substitute for crop oil concentrate or nonionic surfactantm : the spray mixture. Liquid nitrogen fertilizer (28% or similar) can also be added til' 5;:l'"8y mixture. Liquid nitrogen fertilizers are completely water soluble and should be used at e. rate of on~ 'galtqn per acre. Liquid nitrogen fertilizers should not be used as a substitute for crop 0; 'C4ocentrare br nonionic surfactant in the spray mixture. . . , , • " , ' "" \ MIXING - Fill a clean sprayer tank 1/2 full with clean water. Begin agitation and add the , " recommended rate of TORNADO. Add the appropriate amount of nonionic surfactant or crop cdl concentrate to be used. Finish filling the tank with water to the needed volume. Allow the< s(!l[a~ mixture to agitate and recycle 5-10 minutes before application. ••

: 17 r.l-f Page 9 TORNADO Booklet TORN141B.RSF 5/19/97 GROUND APPLICATION: Use sufficient spray volume and pressure to ensure complete coverage of the target weeds. A spray volume of 10-20 gallons per acre at 30-60 psi at the nozzle tip is recommended. When weed foliage is dense, use 60 psi and a minimum of 20 gallons per acre to ensure coverage of weed foliage. Use only hollow cone or flat fan nozzles. The sprayer must be calibrated to provide the proper volume and rate per acre. In addition, the boom and nozzle height must be adjusted to provide complete coverage of all weeds. DO NOT USE FLOOD TYPE OR OTHER SPRAY NOZZLE TIPS WHICH DELIVER COARSE, LARGE DROPLET SPRAYS. DO NOT APPLY TORNADO WITH RECIRCULATING SPRAYERS, ROPEWICK APPLICATORS, CONTROLLED DROPLET APPLICATORS {COAl OR ANY SIMILAR DEVICE. DO NOT APPLY THIS PRODUCT THROUGH ANY TYPE OF IRRIGATION SYSTEM. BAND APPLICATION - Adjust band application equipment to provide thorough weed coverage. Best coverage is obtained by using a minimum of two nozzles, one directed to each side of the planted row. A single nozzle directed over the top of the row will not provide adequate coverage and is not recommended. Cultivation of untreated areas may be needed following band applications. When making band applications and cultivating in the same operation, position nozzles in advance of the cultivation device. This will reduce dust in the spray area. Dust can intercept the spray, reducing weed coverage resulting in less than adequate weed control. Calculate the amount of herbicide and water volume needed for band treatment by the following formulas: BlaOd width in ioches X broadcast rate = Band herbicide rate row width in inches per acre per acre Band widtb in inches X broadcast volume = Band water volume row width in inches . per acre per acre AERIAL APPLICATION - Use sufficient spray volume and pressure to ensure complete coverage of the target weeds. A minimum of 5 gallons per acre of spray mixture should be­ applied with a maximum of 40 PSI pressure. When broadleaf weed or grass foliage is dense, use a minimum of 10 gallons per acre to ensure coverage of weed foliage. Add 1 pintlA of crop oil concentrate or 1/2 pintlA nonionic surfactant in the spray mixture. When making aerial applications, care should be taken to avoid drift to crops other than soybeans or to other non-target areas. Do not spray when conditions are favorable for drjft'qr • when wind velocity exceeds 10 mph. • , • •• (. (C CULTIVATION - Cultivation within 7 days prior to or within 7 days after applitio i~ not •••••• recommended as weeds may be put under stress reducing weed control. Timel)· :ciu:tivatipI' 1~3 weeks after applying TORNADO may assist weed control. : ', •• , , ,., . ...... (. • • ..

. . IS- Page 10 TORNADO Booklet TORN141B.RSF 5119/97 GENERAL USE PRECAUTIONS TORNADO herbicide can be applied only in the states or part of states included in Region 1 and Region 2. See the TORNADO regional use map for a list of states included in Region 1 and Region 2. In Region 1, TORNADO herbicide may be applied to soybeans once per growing season. Make only one application of TORNADO herbicide, or other fomesafen containing product, per growing season. In Region 2, TORNADO herbicide may be applied to soybeans in alternate years. In the year of application, make only one application of TORNADO herbicide per growing season. Do not apply TORNADO herbicide, or other fomesafen containing product, to any field in Region 2 more than once every two years. Apply TORNADO herbicide before soybeans bloom. A maximum of 1 quart (0.25 lb. active fomesafen + 0.188 lb. active fluazifop-P-butyt) per acre of TORNADO herbicide may be applied. In the year of application, however, make only one application per growing season. Apply to actively growing weeds. Avoid applying TORNADO to weeds or soybeans which are under stress from moisture, temperature, low soil fertility, meichanical or chemical injury, as reduced weed control and/or increased crop injury may result. For mixed weed populations, apply when the first weed species reaches the recommended growth stage for treatment. Where irrigation is used as part of normal cropping practice, best results are usually obtained when TORNADO herbicide is applied within 7 days after irrigation. Thoroughly clean spray tank with water and a commercial tank cleaner before and after each use. TORNADO herbicide should not be mixed with fertilizers or pesticides unless specifically recommended on this label or on other approved ZENECA supplemental labeling. TORNADO herbicide requires a 4-hour rain-free period for best results. Avoid overlapping spray swaths. Avoid drift to all other crops and nontarget areas. Crops other than soybeans may be sev~~~ly injured by drift. • •• ' : Do not graze treated areas or harvest for forage or hay. ( ( ( t { 'I: , " , , "" <, , , .,', , , ,." , • , , , , • ' I e. t. ( (. • • ..

I'll >r Page 11 TORNADO Booklet TORN141B.RSF 5/19/97 ROTATIONAL CROP RESTRICTIONS The following rotational crops may be planted after applying TORNADO herbicide at recommended rates in soybeans: Crops To Be Planted Minimum Rotational Interval (Months After Last TORNAPO Application) Small grains such as wheat, barley, rye . . . . . . . . . • . . . . . • . . . . 4 Alfalfa, beans & peas, com, cotton, peanuts, rice, sorghum .... 10 To avoid crop injury do not plant sunflowers, sugar beets, or any other crop within . . . . . . . . • . . . . . . . . . . . . .. . . . . . . • • • 18 Do not graze rotated small grain crops or harvest for livestock forage or straw. In the event of a crop loss due to weather conditions soybeans can be replanted. TORNADO USE REGIONS Region 1: Includes the following states where TORNADO may be applied: Alabama, Arkansas, Florida, Georgia, Louisiana, MiSSissippi, North Carolina, South carolina, Tennessee,--and Texas (counties of Austin, Brazoria, Chambers, Colorado, Fort Bend, Galveston, Hardin, Harris, Jefferson, Liberty, Matagorda, Orange, Waller, Wharton). Region 2: Includes the following states where TORNADO may be applied: Connecticut, Delaware, Illinois, Indiana, Iowa, Kentucky, Maine, Maryland, Massachusetts, Missouri, New Hampshire, New Jersey, New York, Ohio, Pennsylvania, Rhode Island, Vermont, Virginia, and West Virginia. ,,', ' < " '(' ~ , C 1 • • .. . < < < < , < • I( 11. I( t. < • ••

~o '(.)..J Page 12 TORNADO Booklet TORN141B.RSF 5119197 RATES AND WEED GROWTH STAGES TORNADO USE RATE -1 QUARTIACRE"-b WEEDS CONTROLLED c BROAD LEAF WEEDS Carpetweed Cretalaria, Showy Cucumber, Volunteer Jimsonweed ladysthumb lambsquarters, Common MominQQlorv Entireleaf var. integriuscula Ivyleaf var. hederacea Purple Moonflower Smallwhite (pitted) Tall (Common) Mustard, Wild NiQhtshade, Black PiQweed, Redroot PiQweed, Smooth Purslane, Common Ragweed, Common Ragweed, Giant Smartweed, Pennsylvania Venice Mallow Yellow Rocket MAXIMUM GROWTH STAGE (NO. OF LEAVES) 6" diameter 4 4 4 2 2 (Suppression Onillt 2 (Suppression Only) 2 (Suppression Only) 2 2 2 (Suppression Only) 4 .. 4 4 4 6"diameter . 4 2 (Suppression Onlyt 4 4 4 , " , , . " , ,( " , , , ~ , , , , < <'"

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. . c?t Page 13 TORNADO Booklet TORN141B.RSF 5/19/97 TORNADO USE RATE -1 QUART/ACRE MAXIMUM HEIGHT MAXIMUM GROWTH STAGE WEEDS CONTROLLED" (INCHES) (NO. OF LEAVES)· ANNUAL GRASSES Bamyardgrass 2-3 3 Broadleaf signalgrass 2-4 5 Crabgrass large crabgrass 1-2 4 Smooth crabgrass 1-2 4 Southern crabgrass 1-2 4 Tropical crabQrass 1-2 4 Downy Brome 2~ 4 Fall panicum 2~ 6 Field Sandbur 2-4 4 Foxtails Giant foxtail 2~ 4 Green foxtail 2-4 4 Yellow foxtail 2-4 4 GooseQrass 2-4 -6 Italian Ryegrass 2-4 .. 4 Itch.grass 4-24 6 . Johnsongrass, Seedling 2-8 4 Junglerice 2-3 . 3 - .. Shattercane 6-12 8 Sorghum 6-12 8 , - . Southern sandbur 2~ 6 Texas panicum 2-8 6-12 c , ( If < < • .-,--<- Volunteer cereals ' , , < ( ~ < , ..... V.Barley 2~ 6"" , , • ( . ( . - , , , , , V.Com 12-24 19, " , , , , , , , , V.Milo 6-12 4"" , , , , V.Oats 2~ 6 { "- , I V. RYe 2~ 6 < • c.

tJ;). r ~ Page 14 TORNADO 800klet TORN1418.RSF 5/19i97 TORNADO USE RATE -1 QUART/ACRE MAXIMUM HEIGHT MAXIMUM GROWTH STAGE WEEDS CONTROLLED· (INCHES) (NO. OF LEAVES)· V. Wheat 2-6 6 Wild Oats 2-6 6 Wild Proso Millet 4-8 6 Witchorass 2-4 6 Woolv cuporass 2-4 6 • In Region 1, make only one application of TORNADO herbicide, or other fomesafen containing product, per growing season. In Region 2, do not apply TORNADO herbicide, or other fomesafen containing product, to any field more than once every two years. b It is necessary to use 0.25-0.5% non ionic surfactant or 0.5% to 1 % crop oil concentrate for ground applications. For aerial applications, use 1 pint of crop oil concentrate or 16 pint non ionic surfactant per acre. • Scientific names for weeds are listed in the Appendix (Page ). TORNADO can be used for the control of rhizome johnsongrass (height 8-18 inches) and bermudagrass (runner length 4-8 inches) and should be used at a rate of 1.6 quarts per acre. In case a second application needs to be made, use FUSILADE DX at a rate of 8 oz per acre and apply before johnsongrass reaches a height of 12 inches or before bermudagrass reaches a runner length of 8 inches. ,. "" , " , , <" (, • < < ~ , , , , , ~ < ( , {" , . , " , <" • ,<, , , ' < < , < •• , . . ••

~3 '( ~S"' Page 15 TORNADO Booklet TORN141B.RSF 5119197 TANKMIX AND SEQUENTIAL APPLICATIONS FOR l30YBEANS TORNADO can be used sequentially or in tankmix with one or more of the following products: Basagran"', Butyrac"', Pinnacle"', or REFLEX"'. • Under certain conditions, the mixture of TORNADO with one of the above mentioned broadleaf herbicides may cause a reduction in activity of any postemergence grass herbicide in the mixture. For sequential applications allow 2-3 days after the application of the grass herbicide before applying TORNADO or TORNADO mixtures. In case TORNADO or the TORNADO mixture is applied first apply the grass herbicide when the grass weeds begin to develop new leaves (generally around 7 days). Always read and follow the restrictions and limitations for all products whether used alone, sequentially or in a tankmix. The most restrictive labelling of any product used applies. TANKMIX APPLICATION Fill the spray tank with half the amount of required water and add the recommended amounts of TORNADO, the selected tankmix herbicide, and proper rate of approved adjuvant while the agitator is running and then add the remaining quantity of water. Allow the spray mixture to agitate and recycle 5-10 minutes before application. . NOTE: Tankmix applications can result in increases in crop injury as compared to either product used alone. NOTE: Tankmix applications sometimes have resulted in reduced grass weed control. A tankmix application is not recommended if perennial grass weeds are the predominant grasses to be controlled. If grass regrowth occurs following an application of the tankmix or an additional flush of grasses emerges, make an application of FUSILADE DX herbicide to actively growing grass weeds according to label recommendations. . (", ( , , . .. , < , , • < ,. (. , , '(, , < < < "

• APPENDIX ;:; Cf 1.)~ Page 16 TORNADO Booklet TORN141B.RSF Sf19f97 Scientific names are listed for annual grass and broadleaf weeds referred to in the TORNADO label. COMMON NAME SCIENTIFIC NAME BROADLEAF WEEDS carpetweed Mollugo verticil/ata Crotalaria, Showy Crota/aria s@ctabilis Cucumber, Volunteer Cucumis sativas Jimsonweed Datura stramonium Ladysthumb Polygonum persicaria Lambsquarters, Common Chenopodium album MorninQQlorv Entireleaf Ipomoea hederacea, var. integriuscula Ivyleaf Ipomoea hederacea, var. hederacea Purple Moonflower Ipomoea turbinata Smallwhite (pitted) Ipomoea lacunosa Tall (Common) Ipomoea purpurea Mustard, Wild Brassica kaber Nightshade, Black Solanum nigrum - Pigweed, Redroot Amaranthus retroflexus Pigweed, Smooth Amaranthus hybridus . Purslane, Common Portulaca oleracea - Ragweed, Common Ambrosia artemisiifolia - Ragweed, Giant Ambrosia trifida Smartweed, Pennsylvania Polygonum pensylvanicum Venice Mallow Hibiscus trionum Yellow Rocket Barbarea vulgaris ~ ( . , ---ANNUAL GRASS WEeDS " , , , Barnyard grass Echinochloa crus-gal/i , .' .' , ' ,."",.., __ ..J-c Broadleaf signalgrass Brachiaria platyphylla ' , , , , . , , , , . , .. · , Crabgrass .,., , · . Large Digitaria sanguina/is , , {' , Smooth Digitaria ischaemum .. , , • • Southem Diaitaria cifiaris

( ( ;:;s- 7 ;rs- Page 17 TORNADO Booklet TORN141B.RSF 5119/97 COMMON NAME SCIENTIFIC NAME Tropical Digitaria bicomis Downy Brome Bromus tectorum Fall Pa.nicum Panicum dichotomifiorum Field Sandbur Cenchrus incertus Foxtails Giant Setaria faberi Green Setaria viridis Yellow Setaria lutescens Goosegrass Eleusine indica Italian Ryegrass Lolium multifiorum Itchgrass Rottboellia axaltata Johnsongrass, seedling Sorahum ha/eJ)ense Junglerice Echinoch/oa colonum Shattercane Sorghum bicolor Sorghum Sorghum almum Southern sandbur Cenchrus echinatus Texas panicum Panicum texanum Volunteer Cereals V. Barley Hordeum vulgare V.Com Zeamavs V.Milo Sorghum bicolor V. Oats Avena sativa V. Rye Secale cereale V. Wheat Triticum aestivum Wild Oats Avena fatua Wild Proso Millet Panicum miliaceum Witchgrass Panicum capillare " ,,!, Wooly cupgrass Eriochloa villosa , TORNADO" and FUSILADE" are trademarks of a ZENECA Group Company. Basagran" is a trademark of BASF Corporation. : : : : : Butyrac" is a trademark of Rhone Poulenc Ag Company. Pinnacle" is a trademark of EL duPont de Nemours & Co., Inc. , , ,

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