crop-chem-docs/corpus/epa_ppls/1381-215.md

2,4-DB 200

• EPA Reg No: 1381-215
• Registrant: WINFIELD SOLUTIONS, LLC
• Signal word: Danger
• Active ingredients: 2,4-DB, dimethylamine salt (25.9%)
• Label accepted: 2014-09-22
• Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/001381-00215-20140922.pdf

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C UNITED STATES ENVIRONMENTAL PROTECTION AGENCY ' ^ WASHINGTON, DC 20460 OFFICE OF CHEMICAL SAFETY AND POLLUTION PREVENTION SEP 2 2 2014 Danielle Erding Registration Specialist Winfield Solutions, LLC P.O. Box 64589 St. Paul, MN 55164-0589 Subject: Label Notification per PRN 98-10 - Adding MOA code and resistance management language Product Name: 2,4-DB 200 EPA Registration Number: 1381-215 Application Date: September 8, 2014 Decision Number: 495408 Dear Ms. Erding: The Agency is in receipt of your Application for Pesticide Notification under Pesticide Registration Notice (PRN) 98-10 for the above referenced product. The Registration Division (RD) has conducted a review of this request for its applicability under PRN 98-10 and finds that the action requested falls within the scope of PRN 98-10. The label submitted with the application has been stamped "Notification" and will be placed in our records. If you have any questions, you may contact Shanta Adeeb at 703-347-0502 or via .email at adeeb.shanta@epa.gov. Sincerely, Kathryn Montague, Product Manager 23 Herbicide Branch Registration Division (7505P) Office of Pesticide Programs

Please read instructions on reverse before cof "ting form. Form Approved. /"" *3 No. 2070-0060. Approval expires 2-28-95 EPA United States Environmental Protection Agency Washington, DC 20460 D Registration n Amendment El Other OPP Identifier Number Application for Pesticide -Section

1. Company/Product Number 1381-215
2. Company/Product (Name) 2,4-DB 200
3. EPA Product Manager Kathryn Montague PM# 23
4. Proposed Classification E) None D Restricted
5. Name and Address of Applicant (Include ZIP Code) Winfield Solutions, LLC P.O. Box64589 St. Paul, MN 55 164-0589 D Check if this is a new address
6. Expedited Review. In accordance with FIFRA Section 3(c)(3)(b)(i), my product is similar or identical in composition and labeling to: EPA Reg. No, Product Name: Section II D Amendment - Explain Below D Resubmission in response to Agency letter dated El Notification - Explain below D Final printed labels in response to Agency letter dated D "Me Too" Application D Other - explain below Explanation: Use additional page(s) if necessary. (For Section I and Section II). Notification of Addition of Resistance Management Recommendations and MOA code to label, consistent with PR Notice 2001-5. and per PR Notice 98-10. I believe this notification is consistent with the provisions of PR Notice 98-10 and EPA regulations at 40 CFR 152.46, and no other changes have been made to the labeling or the confidential statement of formula of this product. I understand that it is a violation of 18 U.S.C. Sec. 1001 to willfully make any false statement to EPA. I further understand that if this notification is not consistent with the terms of PR Notice 98-10 and 40 CFR 152.46, this product may be in violation of FIFRA and I may be subject to enforcement action and penalties under section 12 and 14 of FIFRA. Section I II 1 . Material This Product Will Be Packaged In: Child-Resistant Packaging D Yes* El No

• Certification must besubmitted. Unit Packaging D Yes El No If "Yes," No. Per Unit Package Wt. Container Water Soluble Packaging D Yes El No If "Yes," Package Wt. No. Per Container

2. Type of Container El Metal El Plastic D Glass D Paper D Other (Specify).
3. Location of Net Contents Information El Label D Container
4. Size(s) of Retail Container 1, 2.5, 30, 55 gallons
5. Location of Label Directions El On Label D On Labeling accompanying product
6. Manner In Which Label Is Affixed To Product D Lithograph D Paper Glued D Stenciled El Other Section IV 1 . Contact Point (Complete items directly below for identification of individual to be contacted, if necessary, to process this application) c Name Danielle Erding Title Registration Specialist Telephone No. (Include Area Code) c 651-375-7228 t <•<""•* cc Certification I certify that the statements I have made on this form and all attachments thereto are true, accurate and complete. I acknowledge that any knowingly false or misleading statement may be punishable by fine or imprisonment or both under applicable law.
7. Signature
8. Typed Name Danielle Erding
9. Title Registration Specialist
10. Date Septembers, 2014
11. D£tc Xpplicatiori ' J- Received l l <- < . c

• <- (Str.mped) EPA Form 8570-1 (Rev. 12-90) Previous editions are obsolete. White - EPA File Copy (original) Yellow - Applicant Copy

P 651 -375-5205 P.O. BOX 64589, MS 5705, ST PAUL MN 55164 F 651-375-1158 SHIP TO 1080 COUNTY ROAD F WEST, MS 5705, SHOREVIEW MN 55126-2910 Septembers, 2014 Ms. Kathryn Montague, PM 23 Document Processing Desk (NOTIF) Office of Pesticide Programs (7504P) U.S. Environmental Protection Agency 1200 Pennsylvania Ave., NW Washington, DC 20460-0001 Subject: EPA Reg. No. 1381-215, 2,4-DB 200 Notification of Label Amendment Addition of Resistance Management Recommendation and MOA Code per PR Notice 2001-5 Dear Ms. Montague: Enclosed are a Notification Application and five copies of amended labeling for the subject product. The labeling incorporates an herbicide resistance management recommendation and MOA code, consistent with the guidance provided in the Agency's PR Notice 2001-5. Please note that one copy of the enclosed labeling has been highlighted (in yellow), to point out the revisions. No other label changes are being made at this time. If there are questions concerning the enclosed, please do not hesitate to contact me. Sincerely, Danielle Erding Registration Specialist deerding@landolakes.com Enclosures c cc c c <- c ooc c c c i. c cc c t c c <- c t t <c c WINFIELD.COM WINFIELD SOLUTIONS, LLC A LAND O'LAKES COMPANY

r Page 1 of 13 GROUP HERBICIDE 2,4-DB200 Broadleaf Herbicide Controls Broadleaf Weeds in Soybeans, Peanuts, Seedling and Established Alfalfa, and Seedling Birdsfoot Trefoil ACTIVE INGREDIENT: 4-(2,4-dichlorophenoxy)butyric acid, dimethylamine salt* 25.9% OTHER INGREDIENTS: 74.1% TOTAL 100.0% *4-(2,4-dichlorophenoxy)butyric acid equivalent 22.0% by weight or 2 pounds per gallon. KEEP OUT OF REACH OF CHILDREN DANGER/PELIGRO Si usted no entiende la etiqueta, busque a alguien para que se la explique a usted en detalle. (If you do not understand the label, find someone to explain it to you in detail.) FIRST AID IF IN EYES IF SWALLOWED IF ON SKIN OR CLOTHING IF INHALED Hold eye open and rinse slowly and gently with water for 1 5-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice Call poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by the poison control center or doctor. Do not give anything by mouth to an unconscious person. Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor for treatment advice. Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial preferably by mouth-to-mouth, if possible. • Call a poison control center or doctor for further treatment advice. respiration, HOT LINE NUMBER Have the product container or label with you when calling a poison control center or doctor or going for treatment. For additional information in case of medical emergency call toll free 1 -877-424-7452. NOTE TO PHYSICIAN Probable mucosal damage may contraindicate the use of gastric lavage. See booklet for additional PRECAUTIONARY STATEMENTS, COMPLETE DIRECTIONS FOR USE, WARRANTY DISCLAIMER AND LIMITATION OF LIABILITY. PRECAUTIONARY STATEMENTS HAZARDS TO HUMANS AND DOMESTIC ANIMALS DANGER: Corrosive. Causes irreversible eye damage. Harmful if swallowed. Do not get in eyes or on clothing. Avoid CGQtact with skin. t: C C c c L EPA Reg. No. 1381-215 Distributed By Winfield Solutions, LLC P.O. Box 64589, St. Paul, WIN 55164-0589 WlNFlELD <~ I- L c C C EPA Est. No. 42750-MO-1 NET CONTENTS J3ALS LOT NO. ,. 1 /03Q5/3 1/09084- *- *• *- c c AgrisoiutioNS

r Page 2 of 13 PERSONAL PROTECTIVE EQUIPMENT (PPE) Some materials that are chemical-resistant to this product are made of any waterproof material. If you want more options, follow the instructions for category A on the EPA chemical-resistance category selection chart. All mixers, loaders, applicators, and other handlers must wear: -long sleeved shirt and long pants, -shoes and socks, -chemical resistant gloves, -goggles or face shield, and -chemical-resistant apron when mixing, loading, cleaning up spills, cleaning equipment, or otherwise exposed to the concentrate. See engineering controls for additional requirements. USER SAFETY REQUIREMENTS Follow manufacturer's instructions for cleaning /maintaining PPE. If no such instructions for washables exist, use detergent and hot water. Keep and wash PPE separately from other laundry. Discard clothing and other absorbent materials that have been drenched or heavily contaminated with this product's concentrate. Do not reuse them. ENGINEERING CONTROL STATEMENTS Pilots must use an enclosed cockpit that meets the requirements listed in the WPS for agricultural pesticides [40 CFR 170.240(d)(6)]. Pilots must wear the PPE required on this labeling for applicators. When handlers use closed systems, enclosed cabs or aircraft in a manner that meets the requirements listed in the Worker Protection Standard (WPS) for agricultural pesticides [40 CFR 170.240 (d) (4-6)], the handler PPE requirements may be reduced or modified as specified in the WPS. USER SAFETY RECOMMENDATIONS Users should wash hands before eating, drinking, chewing gum, using tobacco or using the toilet. Users should remove clothing/PPE immediately if pesticide gets inside. Then wash thoroughly and put on clean clothing. Users should remove PPE immediately after handling this product. Wash the outside of gloves before removing. As soon as possible, wash thoroughly and change into clean clothing. ENVIRONMENTAL HAZARDS This product is toxic to fish. Do not apply directly to water, to areas where surface water is present, or to intertidal areas below the mean high water mark. Drift and runoff from treated areas may be hazardous to aquatic organisms in neighboring areas. Do not contaminate water when disposing of equipment wash waters. Do not contaminate water intended for irrigation or domestic purposes. Do not apply when weather conditions favor drift from target area. Groundwater Contamination: Most cases of ground water contamination involving phenoxy herbicides such as 2,4-DB have been associated with mixing/loading and disposal sites. Caution should be exercised when handling 2,4-DB pesticides at such sites to prevent contamination of ground water supplies. Use of closed systems for mixing or transferring this pesticide will reduce the probability of spills. Placement of the mixing/loading equipment on an impervious pad to contain spills will help prevent ground water contamination. This chemical has properties and characteristics associated with chemicals detected in groundwater. The use of this chemical in areas where soils are permeable, particularly where the water table is shallow, may result in groundwater contamination. Application around a cistern or well may result in contamination of drinking water or groundwater. Do not apply 2,4-DB 200 directly to or otherwise permit it to come in contact with cotton, okra, grapes, tomatoes, fruit trees, vegetables, flowers, or other desirable crop or ornamental plants. Do not permit spray mist to drift onto susceptible plants since very small quantities of the 2,4-DB 200 can cause severe injury during the growing or dormant periods. Use coarse sprays to minimize drift. Do not apply with nozzles that produce fine spray droplets. Drift from ground application may be reduced by: (1) keeping the spray boom as near to the crop as possible in order to obtcin complete coverage; (2) by applying 10 gallons or more of spray per acre; (3) by using no more than 20 pounds of pressure <3t-thpc nozzle tips; and (4) by not spraying when wind exceeds 5 miles per hour. c L c Drift from aerial application may be reduced by: (1) applying as near to the target as possible to obtain adequate coverage'; &)&f applying 5 or more gallons of spray per acre; (3) by using 20 pounds pressure or less at the nozzle tips; (4) by using nozzles which produce a coarse spray pattern; (5) by spraying when there is no possibility for a temperature inversion at time of spraying. Applications by aircraft, ground rig and hand sprayers should be carried out only when there is no hazard from spray drift. £ ° c c ° <= DIRECTIONS FOR USE It is a violation of Federal Law to use this product in a manner inconsistent with its labeling. Read entire label before using this product. L t C I. t. C (. L Do not apply this product in a way that will contact workers or other persons, either directly or through drift. Only protected handlers may be in the area during application. For any requirements specific to your State or Tribe, consult the agency responsible for pesticide regulations.

Page 3 of 13 AGRICULTURAL USE REQUIREMENTS Use this product only in accordance with its labeling and with the Worker Protection Standard, 40 CFR part 170. This standard contains requirements for the protection of agricultural workers on farms, forests, nurseries, and greenhouses, and handlers of agricultural pesticides. It contains requirements for training, decontamination, notification, and emergency assistance. It also contains specific instructions and exceptions pertaining to the statements on this label about personal protective equipment (PPE) and restricted-entry intervals. The requirements in this box only apply to uses of this product that are covered by the Worker Protection Standard. Do not enter or allow worker entry into treated areas during the restricted-entry interval (REI) of 48 hours. PPE required for early entry to treated areas that is permitted under the Worker Protection Standard and that involves contact with anything that has been treated such as plants, soil or water is coveralls, chemical resistant gloves, made of any waterproof material, shoes plus socks and protective eyewear. STORAGE AND DISPOSAL Do not contaminate water, food or feed by storage or disposal. PESTICIDE STORAGE Store in original container in a dry secured storage area. Keep container tightly closed when not in use. PESTICIDE DISPOSAL Pesticide wastes are acutely hazardous. Improper disposal of excess pesticide, spray mixture, or rinsate is a violation of Federal ' law. If these wastes cannot be disposed of by use according to label instructions, contact your State Pesticide or Environmental Control Agency, or the Hazardous Waste representative at the nearest EPA Regional Office for guidance. CONTAINER DISPOSAL: Use label language appropriate for container size and type. Nonrefillable containers. Do not reuse or refill this container. Clean container promptly after emptying. Nonrefillable container equal to or less than 5 gallons. Triple rinse as follows: Empty the remaining contents into application equipment or a mix tank and drain for 10 seconds after the flow begins to drip. Fill the container % full with water and recap. Shake for 10 seconds. Pour rinsate into application equipment or a mix tank or store rinsate for later use or disposal. Drain for 10 seconds after the flow begins to drip. Repeat this procedure two more times. Then offer for recycling or reconditioning, or puncture and dispose of in a sanitary landfill, or by incineration, or, if allowed by state and local authorities, by burning. If burned, stay out of smoke. Nonrefillable container greater than 5 gallons. Triple rinse as follows: Empty the remaining contents into application equipment or a mix tank. Fill the container % full with water. Replace and tighten closures. Tip container on its side and roll it back and forth, ensuring at least one complete revolution, for 30 seconds. Stand the container on its end and tip it back and forth several times. Turn the container over onto its other end and tip it back and forth several times. Empty the rinsate into application equipment or a mix tank or store rinsate for later use or disposal. Repeat this procedure two more times. Then offer for recycling or reconditioning, or puncture and dispose of in a sanitary landfill, or by incineration, or, if allowed by state and local authorities, by burning. If burned, stay out of smoke. Refillable container. Refill this container with pesticide only. Do not reuse this container for any other purpose. Cleaning the container before final disposal is the responsibility of the person disposing of the container. Cleaning before refilling is the responsibility of the refiller. To clean the container before final disposal, empty the remaining contents from this container into application equipment or mix tank. Fill the container about 10 percent full with water. Agitate vigorously or recirculate water with the pump for 2 minutes. Pour or pump rinsate into application equipment or rinsate collection system. Repeat this rinsing procedure two more times. Then offer for recycling or reconditioning, or puncture and dispose of in a sanitary landfill, or by incineration, or, if allowed by state and local authorities, by burning. If burned, stay out of smoke. FOR CHEMICAL EMERGENCY: Spill, leak, fire, exposure, or accident, call CHEMTREC 1-800-424-9300 CAUTIONS AND RESTRICTIONS Do not apply 2,4-DB 200 through any type of irrigation system. Do not use in or near a greenhouse. L L I. (, Do not feed/graze soybean forage or harvest hay for 60 days following any 2,4-DB 200 application. l, , , t L APPLICATION PROCEDURES i c c 2,4-DB 200 can be applied to registered use areas by ground and aerial application equipment. The following ip!rpyides recommended methods of application for each crop. c GROUND APPLICATION .. L Use a standard herbicide boom sprayer that provides uniform and accurate application. Sprayer should be equipped wch' screens no finer than 50 mesh in the nozzle tips and in-line strainers. c <. i t Select a spray volume and delivery system that will ensure thorough and uniform spray coverage. For optimum spray cK.striDuJjon and thorough coverage, use of flat fan nozzles (maximum tip size 8008) with a minimum spray pressure of 30 psi at the nozzle tips are recommended. Where the potential for drift is a problem, see the "Environmental Hazards" section for recommendations to reduce drift. Other nozzle types that produce course spray droplets may not provide adequate coverage of the weedG'ie or.r.ure optimum control. Raindrop nozzles are not recommended as weed control with 2,4-DB 200 may be reduced. In general a minimum spray volume of 10 gallons per acre (GPA) is recommended for optimum spray coverage. When using highw'-speed equipment, a maximum speed of 10 mph is suggested if field conditions cause excessive boom movement during appiiu-lbn and subsequent poor spray coverage. Ground applications made when dry, dusty field conditions exist may provide reduced weed control in wheel track areas.

( r Page 4 of 13 // AERIAL APPLICATION Use orifice discs, cores and nozzle types and arrangements that will provide for optimum spray distribution and maximum coverage. In general a minimum spray volume of 5 GPA and a maximum pressure of 40 psi are recommended. Where the potential for drift is a problem, see the "Environmental Hazards" section for recommendations to reduce drift. SPRAY DRIFT MANAGEMENT Avoiding spray drift at the application site is the responsibility of the applicator. The interaction of many equipment- and weather- related factors determine the potential for spray drift. The applicator and the grower are responsible for considering all these factors when making decisions. Apply only as a medium or coarser spray (ASAE standard 572) or a volume mean diameter of 300 microns or greater for spinning atomizer nozzles. Apply only when the wind speed is 2-10 mph at the application site. Additional requirements for aerial applications: The boom length must not exceed 75% of the wingspan or 90% of the rotor blade diameter. Release spray at the lowest height consistent with efficacy and flight safety. Do not release spray at a height greater than 10 feet above the crop canopy. When applications are made with a crosswind, the swath will be displaced downwind. The applicator must compensate for this displacement at the downwind edge of the application area by adjusting the path of the aircraft upwind. Do not make applications into temperature inversions. Additional requirements for ground boom application: Do not apply with a nozzle height greater than 4 feet above the crop canopy. MIXING INSTRUCTIONS 2,4-DB 200 ALONE: Fill the spray tank 1/2 to 3/4 full with clean water. Begin agitation and add the recommended amount of 2,4- DB 200. Add water to the spray tank to the desired level. Maintain sufficient agitation to ensure a uniform spray mixture during application. TANK MIXTURES: 2,4-DB 200 can be applied in tank mixture with other herbicides registered for use on approved crops. Refer to the specific crop section for rate directions and other restrictions. To apply 2,4-DB 200 in mixture with another product, fill the spray tank 1/2 to 3/4 full with clean water and begin agitation. If tankmixing with wettable powder, soluble powder, flowable or dry flowable products, add the powder or flowable product first. After the other herbicide is thoroughly mixed with water, add the recommended amount of 2,4-DB 200 and add water to the spray tank to the desired level. If tankmixing with other product types, add the 2,4-DB 200 first before adding the other product. Always mix one product in water thoroughly before adding another product or compatibility problems may occur. Never mix two products together without first mixing in water. Maintain sufficient agitation while mixing and during application to ensure a uniform spray mixture. If spray mixture is allowed to remain without agitation for short periods of time, be sure to agitate until uniformly mixed before application. COMPATIBILITY Evaluate tank mixtures not listed on this label for compatibility and crop safety on a small area before applying to the entire field. 2,4-DB 200 Broadleaf Herbicide may form an insoluble precipitate in very hard water. If you expect'to mix 2,4-DB 200 with very hard water, test compatibility by mixing a small amount of 2,4-DB 200 in the proposed dilution ratios, shake and observe. A compatibility agent approved for use on growing crops such as Complete Compatibility or E-Z MIX may be tested to reduce precipitation. Whenever hard water is used to dilute 2,4-DB 200, spray immediately and do not allow spray mixture to sit overnight. RESISTANCE MANAGEMENT RECOMMENDATIONS 2,4-DB 200 is a Group 4 herbicide. Any weed population may contain or develop plants naturally resistant to 2,4-DB 200 artdcd[r'i'erc Group 4 herbicides. Weed species with acquired resistance to Group 4 may eventually dominate the weed population if Group '4C c herbicides are used repeatedly in the same field or in successive years as the primary method of control for targeted species. Tfe may result in partial or total loss of control of those species by 2,4-DB 200 or other Group 4 herbicides. c <- c c. c To delay herbicide resistance consider: • Avoiding the consecutive use of 2,4-DB 200 or other target site of action Group 4 herbicides that have a similar targa* ci'3;C.f action, on the same weed species. *" • Using tank-mixtures or premixes with herbicides from different target site of action Groups as long as the involvedjiiooycts are all registered for the same use, have different sites of action, and are both effective at the tank mix or prepack rate on trio weed(s) of concern. L • Basing herbicide use on a comprehensive IPM program. c t • Monitoring treated weed populations for loss of field efficacy. c c '•c l c • Contacting your local extension specialist, certified crop advisors, and/or Winfield Solutions, LLC representative for herbicide resistance management and/or integrated weed management recommendations for specific crops and resistant weed biotypes. ' L c c L

Page 5 of 13 PRODUCT INFORMATION Spray tank residues of 2,4-D or MCPA mixed with 2,4-DB 200 can cause serious crop or ornamental plant injury. A sprayer previously used to apply these chemicals must be thoroughly cleaned with alkali and water before applying 2,4-DB 200. Be sure sprayer is clean before applying 2,4-DB 200. Local conditions may affect the use of herbicides. Consult your State Agricultural Experiment Station, Farm Advisors, or Extension Weed Specialists for advice in selecting treatments from this label to best fit local conditions. INJURY TO CROPS FROM THIS HERBICIDE MAY OCCUR. IF YOU ARE NOT PREPARED TO ACCEPT SOME DEGREE OF CROP INJURY, DO NOT USE THIS PRODUCT.. Crop varieties vary in response to 2,4-DB and some are easily injured. Apply 2,4-DB 200 only to varieties known to be tolerant to 2,4-DB. If you are uncertain concerning tolerant varieties or local use situations that may affect crop tolerance to 2,4-DB, consult your seed company, state Agricultural Extension Service or qualified crop consultant for advice. Be sure that use of this product conforms to all applicable laws, rules, and regulations. Certain states have restrictions pertaining to application distances from susceptible crops. The applicator should become familiar with these laws, rules, or regulations and follow them exactly. WEED LIST 2,4-DB 200 Broadleaf Herbicide alone will control or suppress the following weeds depending on weed size. COMMON NAME velvetleaf Virginia copperleaf prickly sida (teaweed) common ragweed threeseed croton (goatweed) lambsquarters wild mustard field pennycress jimsonweed devilsclaw pigweed morningglory cocklebur curled dock Russian thistle yellow rocket smartweed sicklepod** BOTANICAL NAME Abutilon theophrasti Acalypha virginica Sida spinosa Ambrosia artemisiifolia Croton lindheimeranus Chenopodium album Sinapsis arvensis Thlaspi arvense Datura stramonium Proboscidea louisianica Amaranthus spp. Ipomoea spp. Xanthium spp. Rumex crispus Salsola kali Barbarea vulgaris Polygonum spp. Cassia obtusifolia (L) MAXIMUM WEED HEIGHT* 1 inch 1 inch 1 inch 1 inch 1 inch 1 inch 1 inch 1 inch 1.5 inches 2 inches 3 inches 36 inches 36 inches 3 inches 3 inches 3 inches 3 inches 2 inches *Growth of larger weeds will be only suppressed. "Sicklepod may only be partially controlled. Repeat applications of 2,4-DB 200 may be necessary for control. SOYBEANS 2,4-DB 200 Broadleaf Herbicide Directions PRODUCT Preplan! through pre-emergence 2,4-DB 200 + Non-ionic surfactant RATE 0.7 - 0.9 pint/A + 0.5% V/V APPLICATION TIMING AND SPECIFIC COMMENTS CROP Apply to soybeans before planting or before crop emergence. WEEDS For control of emerged cocklebur, annual morningglories and other susceptible broadleaf weeds, apply when weeds are small and actively growing (see WEED LIST). 2,4-DB 200 may not give complete control of larger overwintered mustards. . Best results will be achieved by adding a non-ionic surfactant at a 0.5% V/V to the spray tank when making a preplant or preemergence application of 2,4-DB 200.

Page 6 of 13 SOYBEANS 2,4-DB 200 Broadleaf Herbicide Directions PRODUCT RATE APPLICATION TIMING AND SPECIFIC COMMENTS CROP WEEDS Postemergence broadcast (over the top) 2,4-DB 200 Pre-bloom: 0.73 pint/A Bloom: 0.89 pint/A Apply to soybeans grown in the Southern states only from 7 to 10 days before bloom up to mid-bloom when soybeans are about knee-high and growing actively. Soybean foliage should be dark green indicating that nodulation and nitrification are under way. Postemergence broadcast application at these rates prior to or after this application timing is not to be used as reduced flowering and yield may result. DO NOT APPLY 2,4-DB 200 Postemergence broadcast to soybeans grown in the Midwest states of IA, IL, IN, KS, KY (except the Purchase area), MO (except the MO bootheel), Ml, MN, NE, ND, OH, SD and Wl. For control of emerged cocklebur, annual morningglories and other susceptible broadleaf weeds, apply when weeds are small and actively growing (see WEED LIST). Postemergence directed band 2,4-DB 200 0.7-1.6 pints/A Apply when soybeans are 8 or more inches tall with sprayer nozzles mounted to insure proper placement of spray on only the lower 1/3 of the soybean plants. Do not allow spray to contact growing terminals of beans as excessive crop injury will result. Do not mount nozzles on booms with drop pipes or on cultivators without gauge wheels. Use flat fan type nozzles, 8001 or larger or the equivalent with nozzle pressure less than 30 psi and at least 10 gallons of spray volume per acre. To control emerged cockleburs and annual morningglories up to 3 inches tall, apply 0.7 to 0.9 pint/A per broadcast acre as a directed band treatment. To control other susceptible broadleaf weeds up to 1 inch tall, apply 1.4 to 1.6 pints per broadcast acre as a directed band treatment. Apply no more than 2 higher rate applications per season to reduce the potential for crop stunting. TANK MIXTURES OF 2,4-DB 200 broadleaf herbicide AND OTHER HERBICIDES IN SOYBEANS Applying tank mixtures of 2,4-DB 200 Broadleaf Herbicide with other soybean herbicides as directed below can reduce competition from early weed populations and can improve weed control or control mid-to-late-season weed populations, thus minimizing the likelihood of yield reduction in soybean fields with heavy broadleaf weed infestations. However, treating soybeans under stress (as from drought or disease such as Phytophthora root rot) or in any other manner not directed on this label, can cause crop injury and yield reduction. The advantage of treating weeds with an appropriate tank mixture should be balanced against any potential for loss. Follow the local recommendations of your- state, Cooperative Extension Service, or other agricultural weed control authority. Always follow the recommendations of any product used in tank mixture with 2,4-DB 200 Broadleaf Herbicide.

Page 7 of 13 Vfe 1 PRODUCT 2,4-DB 200 + Gramoxone® Extra + Nonionic surfactant 2,4-DB 200 + Prowl® + Nonionic surfactant 2,4-DB 200 + Roundup® or Honcho® + Nonionic surfactant 2,4-DB 200 + Pursuit® Plus + Nonionic surfactant 2,4-DB 200 + Scepter®or Scepter 70DG + Nonionic surfactant RATE 0.5 - 0.75 pint/A + 1.5-5 pints/A + 0.5% V/V 0.7 - 0.9 pint/A + 1.0-3.0 pints/A + 0.5% MN 0.5 - 0.75 pint/A + 1 - 1.5 pints/A + 0.5 - 1 .0% VAX 0.5 - 0.75 pint/A + 2.5 pints/A + 0.25% V/V 0.5 - 0.75 pint/A + 0.66 pint/A or 2.8 oz./A + 0.25% V/V APPLICATION TIMING AND SPECIFIC COMMENTS CROP Apply before planting or before soybean emergence. Do not apply this tank mixture after crop emergence. Apply up to 45 days prior to soybean planting. Do not apply a 2,4-DB 200 + Prowl tank mixture at or after planting North of Interstate 80. Surface applications of Prowl tank mixtures North of Interstate 80 require at least 1 inch rainfall or mechanical incorporation prior to planting or crop injury may result. Do not apply this tank mixture after crop emergence. Apply before planting or before soybean emergence. Do not apply this tank mixture after crop emergence. Apply before planting or before soybean emergence. Do not apply this tank mixture after crop emergence. Apply before planting or before soybean emergence. Do not apply this tank mixture after crop emergence. WEEDS For improved control of emerged annual morningglory, common cocklebur, marestail and other problem weeds, apply to small actively growing weeds. Refer to the Gramoxone® Extra label for full list of weed species controlled and specific application stage and rate directions. For control of emerged cocklebur, annual morning- glories and other susceptible broadleaf weeds, apply when broadleaf weeds are actively growing and small (see WEED LIST). 2,4-DB 200 mixtures may not give complete control of larger overwintered mustards. Best results will be achieved by adding a non-ionic surfactant to the spray tank when making a preplant appli- cation. For improved control of emerged annual morning- glories, common cocklebur and other problem weeds, apply to small actively growing weeds. Refer to the Roundup or Honcho labels for specific rate directions, application stage and weed species controlled. For improved control of emerged mustards, field pennycress and other problem weeds, apply when broadleaf weeds are actively growing and small (see WEED LIST). For improved control of emerged mustards, field pennycress and other problem weeds, apply when broadleaf weeds are actively growing and small (see WEED LIST).

PageS of 13 TANK MIXTURES OF 2,4-DB 200 AND OTHER HERBICIDES IN SOYBEANS PRODUCT 2,4-DB 200 + Squadron® + Nonionic surfactant 2,4-DB 200 + Basagran® 2,4-DB 200 + Blazer® 2,4-DB 200 Reflex® 2,4-DB 200 Lorox® RATE 0.5 - 0.75 pint/A + 3 pints/A + 0.25% V/V 2 f I oz/A + 1.5 -2 pints/A 2 fl oz/A + 1.5 -2 pints/A 2 - 3 fl oz/A + 1-1 1/2 pints/A 0.8 pint/A + 1 pint/A APPLICATION TIMING AND SPECIFIC COMMENTS CROP Apply before planting or before soybean emergence. Do not apply this tank mixture after crop emergence. Apply postemergence to soybeans. Under certain conditions soybean foliage may burn, crinkle and bronze following application. Apply postemergence to soybeans. Under certain conditions, soybean foliage may burn, crinkle and bronze following application. Soybean yield may be reduced. Do not add surfactant or crop oil to this mixture as increased crop injury may result. Apply postemergence to soybeans. Under certain conditions bronzing, crinkling or spotting of soybean foliage may occur. Apply to soybeans as a directed band treatment only when soybeans are at least 8 inches high. Do not spray higher than 3 inches on the soybean stem or unacceptable crop injury may result. Do not spray over the top of soybean plants. WEEDS For improved control of emerged mustards, field pennycress and other problem weeds, apply when broadleaf weeds are actively growing and small (see WEED LIST). To improve control of annual morningglories, apply to morningglory vines up to 6 inches long in the Southern states of AL, AR, FL, GA, LA, MS, NC, OK, SC, TN, TX and VA or a maximum of 10 inches long in all other states. To improve control of larger morningglories, cockleburs, common ragweed, jimson- weed and pigweed, apply when weeds are actively growing and before they are 12 inches tall or long. For improved control of annual morningglories, giant ragweed and cocklebur, apply to actively growing weeds in the seedling stage of growth. For postemergence control of annual morningglories, sic- klepod, teaweed, cocklebur and sesbania, apply when weeds do not exceed 4 inches in height. A second application may be neces- sary, but do not make more than 2 applications per season.

r Page 9 of 13 %TANK MIXTURES OF 2,4-DB 200 AND'OTHER HERBICIDES IN SOYBEANS PRODUCT 2,4-DB 200 + Sencor® DF 2,4-DB 200 + Pursuit 2,4-DB 200 + Classic® 2,4-DB 200 + Scepter® O.T. + Nonionic surfactant RATE 0.9 pint/A + 0.33 - 0.66 Ib/A 2 - 3 fl oz/A + 4 f I oz/A 1 -2'floz/A + 1/2 oz/A 1 - 2 f I oz/A + 1 .0 pint/A + 0.25% v/v APPLICATION TIMING AND SPECIFIC COMMENTS CROP Apply to soybeans as a directed band treatment only when soybeans are at least 8 inches high, with spray or nozzles mounted to insure proper placement of spray on no more than the lower 1/3 of the soybean plants. Do not apply directly to soybean plants or serious crop injury will occur. Soybean leaves contacted by spray will be killed. Follow all variety restrictions on the full Sencor® DF label. Apply postemergence to soybeans. Apply anytime after soybean emergence but no later than 85 days before soybean harvest. Apply postemergence to soybeans. Apply after first trifoliate has opened but no later than 60 days before soybean maturity. Apply postemergence to soybeans. Apply anytime after soybean emergence but no later than 90 days before soybean harvest. WEEDS For improved control of cocklebur, annual morning- glories and other broadleaf weeds, apply before weeds are 3 inches tall. A nonionic surfactant may be added to improve broadleaf weed control. To improve control of morningglories, common ragweed, and giant ragweed. See Pursuit label for weeds controlled, and use precautions. Provides improved control of most annual broadleaf weeds, including morning- glories, and common lambs- quarters, compared to Classic alone. See Classic label for weeds controlled and precautions. Provides improved control of morningglories compared to Scepter O.T. alone. Check Scepter O.T. label for weeds controlled and precautions. RESTRICTIONS AND LIMITATIONS FOR USE ON SOYBEANS Maximum single application rate for pre-plant through pre-emergence applications is 0.9 pint (0.225 Ib ae) per acre. Maximum single application rate for pre-bloom applications is 0.73 pint (0.182 Ib ae) acre. Maximum single application rate for applications made after bloom is 0.89 pint (0.222 Ib ae) per acre. Maximum single application rate for post-emergence applications through directed spray (band sprayer, low pressure ground sprayer) is 1.6 pints (0.4 Ib ae) per acre. Maximum single application rate for post-emergence applications through band treatment (sprayer) is 0.9 pint (0.225 Ib ae) per acre. Maximum of 2 post-emergence applications per year. Beans stressed by drought or other influences should not be sprayed. Do not use this product on soybeans that show symptoms of disease such as Phytophthora root rot. Do not graze or feed soybean hay within 60 days after application of 2,4-DB 200 Broadleaf Herbicide tank mix application. Do not harvest soybeans within 60 days after spray application. Do not treat soybeans with a tank mixture of 2,4-DB 200 and SEVIN® Carbaryl Insecticide as severe injury may result. When preplant through preemergence treatment is followed with a 2,4-DB 200 postemergence application, the cumulative rate should not exceed 1.6 pints per acre per season. Follow all restrictions and limitations of any product used in tank mixture with 2,4-DB 200. Do not use 2,4-DB 200 alone or in tank mixture as a preplant through preemergence application to soybeans in California.

r Page 10 of 13 PEANUTS 2,4-DB 200 Broadleaf Herbicide Directions PRODUCT 2,4-DB 200 2,4-DB 200 RATE 0.8- 1.0 pint/A 0.8- 1.6 pints/A APPLICATION TIMING AND SPECIFIC COMMENTS CROP Apply to peanuts 2 to 12 weeks after planting in the states of AL, AR, FL, GA, LA, NC, MS, SC, TN and VA. Do not apply to peanuts within 60 days of harvest. Apply to peanuts 2 to 12 weeks after planting in the states of OK, TX and NM only. Do not apply later than 100 days after planting or 60 days before harvest. WEEDS For control of annual morningglories, cocklebur and other broadleaf weeds, apply when these weeds are small and actively growing (see WEED LIST). A second application may be made for late germinating cocklebur and morningglories. For control of annual morningglories and cocklebur, apply 0.8 - 1 .0 pint/A of 2,4-DB 200 when these weeds are actively growing and before they are 3 inches tall. For optimum control of other susceptible broadleaf weeds (see WEED LIST), apply 2,4- DB 200 at 1.6 pints/A. For optimum prickly sida suppression, make a second application 14 days later. TANK MIXTURES OF 2,4-DB 200 BROADLEAF HERBICIDE AND OTHER HERBICIDES IN PEANUTS PRODUCT 2,4-DB 200 + Pursuit + Nonionic surfactant 2,4-DB 200 + Classic 4- Nonionic surfactant 2,4-DB 200 + Starfire® RATE 0.8 -1.6 pints/A + 2 - 4 fl oz/A + 0.25% VA/ 0.8 pints/A + 1/2 oz/A + 0.25% VA/ 0.5 - 1 .0 pint/A + 1 1 fl oz/A APPLICATION TIMING AND SPECIFIC COMMENTS CROP Apply postemergence to peanuts. Follow restrictions listed above depending on the state. Apply postemergence not less than 60 days after peanuts emerge to within 60 days of peanut harvest. See Classic label for additional restrictions and precautions. Apply at ground crack. A second application may be made up to 28 days after ground crack. WEEDS Will provide enhanced control of morningglories, prickly sida, common and giant ragweed and suppression of 1" tall sicklepod. For late season control of Florida beggarweed, plus morningglories, lambsquarters, and other weeds on the 2,4-DB 200 label. Controls or suppresses many annual weeds < 6" tall, and provides improved control of cocklebur, sicklepod, and morningglory compared to Starfire alone. RESTRICTIONS AND LIMITATIONS FOR USE ON PEANUTS Maximum single application rate for spray (aircraft, boom sprayer) is 1 pint/A (0.25 Ib ae/A). Maximum single application rate for broadcast (aircraft, boom sprayer) is 1.6 pints/A (0.4 Ib ae/A). Maximum two applications per year. Do not apply to peanuts within 60 days of harvest. Do not feed treated peanut vines or peanut hay to livestock. Do not apply 2,4-DB 200 Broadleaf Herbicide if peanut plants are under stress from drought as injury may occur.

r Page 11 of 13 'it.FORAGE LEGUMES (SEEDLING AND ESTABLISHED ALFALFA, SEEDLING BIRDSFOOT TREFOIL) 2,4-DB 200 Broadleaf Herbicide Directions PRODUCT 2,4-DB 200 RATE 1-3 quarts/A APPLICATION TIMING AND SPECIFIC COMMENTS CROP Apply . postemergence to seedling forage legumes and seedling or established alfalfa. Forage legumes should be healthy and actively growing for greatest selectivity. In established alfalfa, twisting of stems and malformation of leaves may occur. Under most conditions this response is usually outgrown. A non-ionic surfactant at 0.25% V/V may be included in seedling alfalfa grown in dry, low humidity areas only. Non-ionic surfactant may cause some twisting of stems and malformation of leaves. This response is usually outgrown under most conditions. WEEDS For control of emerged lambsquarters, pigweed, field pennycress, wild mustard, common ragweed, cocklebur, yellow rocket, Russian thistle and annual morningglory species less than 1 inch high, apply 2,4- DB 200 at 1 to 2 quarts/A. For control of these weeds up to 3 inches tall, apply 2,4- DB 200 at 2-3 quarts/A. Use the higher rates in dry, low humidity growing areas. For control or suppression of smartweed and curled dock up to 3 inches tall, apply 2,4- DB 200 at 3 quarts/A. In seedling alfalfa only, the addition of an non-ionic surfactant at 0.25% V/V may improve broadleaf weed control under dry, low humidity conditions. 2,4-DB 200 may not adequately control overwintered broadleaf weeds including field pennycress and mustards. FORAGE LEGUMES (SEEDLING AND ESTABLISHED ALFALFA ONLY) 2,4-DB 200 Broadleaf Herbicide Tank Mixture Directions PRODUCT RATE APPLICATION TIMING AND SPECIFIC COMMENTS CROP WEEDS 2,4-DB 200 ®Poasf Crop Oil Concentrate 1 - 3 quarts + 1 - 2.5 pints ' + 2 pints/A Apply this tank mix postemergence to seedling and established alfalfa only. Alfalfa should be healthy and actively growing for greatest crop tolerance. Established alfalfa is less tolerant to 2,4- DB 200 than in the seedling stage of growth. Some yellowing and burning of alfalfa foliage, stem and leaf malformation may occur with this tank mixture. Alfalfa will generally outgrow this response. Balance the severity of your grass and broadleaf weed problem with the potential for crop injury. Do not add non-ionic surfactant, Dash®, UAN solution or ammonium sulfate to this tank mixture. For control of emerged susceptible broadleaf and grass weed that are actively growing, refer to the 2,4-DB 200 forage legume directions above and the Poast label for weeds controlled and application timing for full use directions.

f Page 12 of 13 FORAGE LEGUMES (SEEDLING ALFALFA ONLY) 2,4-DB 200 Broadleaf Herbicide Tank Mixture Directions PRODUCT 2,4-DB 200 + BUCTRIL RATE 1 quart/A + 1 pint/A APPLICATION TIMING AND SPECIFIC COMMENTS CROP Apply in the fall or spring to seedling alfalfa when the majority of the field has a minimum of 4 trifoliate leaves. This tank mixture may result in unacceptable crop leaf burn, especially under warm, humid weather conditions. See 2,4-DB 200 label for additional precautions and restrictions. Do not use this tank mix on established alfalfa. WEEDS This tank mix provides improved control of pigweed, kochia and tansy mustard compared to 2,4-DB 200 or BUCTRIL alone. Apply when weeds do not exceed the 4- leaf stage, 2 inches in height or 1 inch in diameter, whichever comes first. 2,4- DB 200 + BUCTRIL tank mixtures will not adequately control overwintered pennycress, henbit and mustards. RESTRICTIONS AND LIMITATIONS FOR USE ON FORAGE LEGUMES Maximum single application rate of 3 quarts/A (1.5 Ib ae/A). Do not graze established alfalfa or feed straw or hay from treated established alfalfa to livestock within 30-60 days after application. Do not graze or feed seedling alfalfa, or seedling birdsfoot trefoil within 30-60 days after application. Do not use on clover, peas or other legumes not mentioned above. Do not apply when crop is stressed from lack of moisture. Do not spray when the temperature exceeds 90°F and/or is predicted to exceed 90°F during the three days following application. Do not add any wetting agents or detergents to the spray solution unless as specified on this label. Rainfall or overhead irrigation within 7-10 days following a 2,4-DB 200 application can cause unacceptable crop injury. For irrigated crops, apply 2,4-DB 200 as soon as possible after irrigation. Delay the next irrigation for 7-10 days after spraying. Follow all restrictions and precautions of any product used in tank mixture with 2,4-DB 200. CONSERVATION RESERVE PROGRAM AREAS 2,4-DB 200 Broadleaf Herbicide Directions PRODUCT 2,4-DB 200 RATE 1 - 3 quarts/A APPLICATION TIMING AND SPECIFIC COMMENTS CROP Apply postemergence to Conservation Reserve Program areas containing grasses which are tillering or have a minimum of 6 leaves and forage legumes (seedling or established alfalfa, and seedling birdsfoot trefoil, which are emerged, healthy and actively growing. Temporary twisting of stems and malformation of forage legume leaves may occur following treatment. WEEDS For control of lambsquarters, pigweed, field pennycress, wild mustard, common ragweed, cocklebur, yellow rocket, Russian thistle, and annual morningglory species less than 1 inch tall, apply 2,4-DB 200 at 1 to 2 quarts/A. For control of these weeds up to 3 inches tall, apply 2,4-DB 200 at 2 - 3 quarts/A. Use the higher rates in dry, low humidity areas. For control or suppression of smartweed and curled dock up to 3 inches tall, apply 2,4- DB 200 at 3 quarts/A.

c r /</ Page 13 of 13 //(, RESTRICTIONS AND LIMITATIONS FOR USE ON CONSERVATION RESERVE PROGRAM (CRP) Do not graze or harvest treated CRP areas. Do not use on clover, peas or other legumes not mentioned above. Do not apply when cover crop is stressed from lack of moisture. Do not spray when the temperature exceeds 90°F and/or is predicted to exceed 90°F during the three days following application. Do not add any wetting agents or detergents to the spray solution. Rainfall or overhead irrigation within 10 days following a 2,4-DB 200 application can cause unacceptable legume injury. WARRANTY DISCLAIMER The directions for use of this product must be followed carefully. TO THE EXTENT CONSISTENT WITH APPLICABLE LAW, (1) THE GOODS DELIVERED TO YOU ARE FURNISHED "AS IS" BY MANUFACTURER OR SELLER AND (2) MANUFACTURER AND SELLER MAKE NO WARRANTIES, GUARANTEES, OR REPRESENTATIONS OF ANY KIND to BUYER OR USER EITHER'EXPRESS OR IMPLIED, OR BY USAGE OF TRADE, STATUTORY OR OTHERWISE, WITH REGARD TO THE PRODUCT SOLD, INCLUDING, BUT NOT LIMITED TO MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE, USE, OR ELIGIBILITY OF THE PRODUCT FOR ANY PARTICULAR TRADE USAGE. UNINTENDED CONSEQUENCES, INCLUDING BUT NOT LIMITED TO INEFFECTIVENESS, MAY RESULT BECAUSE OF SUCH FACTORS AS THE PRESENCE OR ABSENCE OF OTHER MATERIALS USED IN COMBINATION WITH THE GOODS, OR THE MANNER OF USE OR APPLICATION, INCLUDING WEATHER, ALL OF WHICH ARE BEYOND THE CONTROL OF MANUFACTURER OR SELLER AND ASSUMED BY BUYER OR USER. THIS WRITING CONTAINS ALL OF THE REPRESENTATIONS AND AGREEMENTS BETWEEN BUYER, MANUFACTURER AND SELLER, AND NO PERSON OR AGENT OF MANUFACTURER OR SELLER HAS ANY AUTHORITY TO MAKE ANY REPRESENTATION OR WARRANTY OR AGREEMENT RELATING IN ANY WAY TO THESE GOODS. LIMITATION OF LIABILITY TO THE EXTENT CONSISTENT WITH APPLICABLE LAW, IN NO EVENT SHALL MANUFACTURER OR SELLER BE LIABLE FOR SPECIAL, INCIDENTAL, OR CONSEQUENTIAL DAMAGES, OR FOR DAMAGES IN THE NATURE OF PENALTIES RELATING TO THE GOODS SOLD, INCLUDING USE, APPLICATION, HANDLING, AND DISPOSAL. MANUFACTURER OR SELLER SHALL NOT BE LIABLE TO BUYER OR USER BY WAY OF INDEMNIFICATION TO BUYER OR TO CUSTOMERS OF BUYER, IF ANY, OR FOR ANY DAMAGES OR SUMS OF MONEY, CLAIMS OR DEMANDS WHATSOEVER, RESULTING FROM OR BY REASON OF, OR RISING OUT OF THE MISUSE, OR FAILURE TO FOLLOW LABEL WARNINGS OR INSTRUCTIONS FOR USE, OF THE GOODS SOLD BY MANUFACTURER OR SELLER TO BUYER. ALL SUCH RISKS SHALL BE ASSUMED BY THE BUYER, USER, OR ITS CUSTOMERS. BUYER'S OR USER'S EXCLUSIVE REMEDY, AND MANUFACTURER'S OR SELLER'S TOTAL LIABILITY SHALL BE FOR DAMAGES NOT EXCEEDING THE COST OF THE PRODUCT. If you do not agree with or do not accept any of directions for use, the warranty disclaimers, or limitations on liability, do not use the product, and return it unopened to the Seller, and the purchase price will be refunded. Buctril and Sevin are registered trademarks of Aventis Crop Science. Gramoxone , Reflex , and Starfire are registered trademarks of Syngenta Crop Protection, Inc. Basagran, Blazer, Poast, Dash, Prowl, Pursuit Plus, Scepter, and Squadron are registered trademarks of BASF AG PRODUCTS. Roundup and Honcho are registered trademarks of Monsanto Company. Classic is a registered trademark of E.I. DuPont de Nemours Co., Inc. Lorox is a registered trademark of Griffin, LLC Sencor DF is a registered trademark of Bayer Crop Protection. AgriSolutions™ is a trademark of Winfield Solutions, LLC.