crop-chem-docs/corpus/epa_ppls/1812-383.md

OXYCOP 53WP

• EPA Reg No: 1812-383
• Registrant: GRIFFIN L.L.C.
• Signal word: Danger
• Active ingredients: Copper oxychloride (Cu2Cl(OH)3) (92%)
• Label accepted: 1996-03-14
• Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/001812-00383-19960314.pdf

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) u.s. ENVIRONMENTAL PROTECTION AGENCY Office of Pesticide Programs Registration Division (750SC) 401 'N St., S."'. Washington, D.C. 20460 NOTICE OF PESTICIDE: X Registration Reregistration (Inler F I FAA, al _ndedoled" ) Naoe and Addres. of Registrant (Include ZIP Code): Griffin corporation P.O. Box 1847 Valdosta, GA 3160-1847 EPA Rog. NUIbor: Date of Issuance: 1812-383 MAR 1 4 1996 TeMlt of Issuance: Conditional Naoe of Pesticide Product: Oxycop 53WP On the basis of information furnished by the registrant, the above named pesticide II hereby registered/reregistered InIer the Federal Insecticide, Fungicide and Rodenticide Act. Registration is in no way to be construed as an endorsement or recommendation of this product by the Agency. In order to protect heal th and the environment, the Adninistrator, on his IAOtion, may at any th.e suspend or cancel the registration of 8 pesticide in accordance with the Act. The acceptance of any name in connection with the registration of 8 product under this Act is not to be construed 8S giving the registrant a right to exclusive use of the name or to its use if it has,been covered by others. This product is conditionally registered in accordance with FIFRA sec. 3(c) (7) (A) provided that you:

1. Submit and/or cite all data required for registration/ reregistration of your product under FIFRA sec. 3{c) (5) when the Agency requires all registrants of similar products to submit such data; and submit acceptable responses required for reregistration of your product under FIFRA section 4.
2. Svbmit by September 14, 1996 Product Chemistry Studies conducted ~n accordance with the Good Laboratory Practice Standards, 40 CFR Part 160 and appropriate test guidelines as referenced in EPA's Data Requirements for Registration Regulations, 40 CFR Part 158.
3. Add the phrase "EPA Registration No. 1812-383" to your label before you release the product for shipment.
4. Submit one (1) copy of your final printed labeling before you release the product for shipment. Refer to the A-79 enclosure for a further description of final printed labeling. Signatur.:- on Approving Offici8'.L--- I )<f;u""c-- (. ~J

) ) page 2 EPA Reg. No. 1812-383 If these conditions are not complied with, the registration will be subject to cancellation in accordance with FIFRA section 6 (e). Your release for shipmcalt of the product constitutes acceptance of these conditions. A stamped copy of the label is enclosed for your records. Enclosure Theresa A •. stowe Acti~g Team Leader Product Manager (22) Fungicide-Herbicide Branch Registration Division (7505C)

-' .... ,,. t 11'11-tj III LAB OO2l007 .. ) 3/14/96 Oxycop 53WP Active Ingredient Copper Oxychloride . ... 92% Inert h.gredients . ":Q'.:«' '.. . . .. ~ Total. ........ . . ... " ..... ... 100% (Metallic Copper Equivalent·53%) KEEP OUT OF REACH OF CHILDREN DAl"JGER - PELlGRO Si usted no entiende la etiqueta, busque a .algulen para que se la explique a usted ell d¢t'al!e. (If you do not understand the label, find someone to explain it to you in detail.) STATEMENT OF PRACTICAL TREATMENT IF IN EYES: Flush eyes immediately with plenty of water for at least 15 mll1utes Get medical attention if irritation persisils., IF ON SKIN: Wash skin immediately with soap and water Get medical attention if ) irritation persis its . IF SWALLOWED: Drink promptly a large quantity of milk, egg whIte, gelatin solution, or if these are not available, large quanttties of water. AVOId alcohol. Get medical attention. Note to physician: Probable mucosal damage may contraindicate use of gastric lavage. IF INHALED: Remove victim to fresh air. If not bleathmg, give artificial respiration, preferably mouth-to-mouth. ,see label.fnr,additional Preca1.ltloll! a Directions fOr Use. --'-----".:..;' '"",' .' . " .... . -' ------'-' _.. .. '--.;..-'----- Griffin Corporation EPA Reg. No. 1812-GIG 1 .··~7 /

) 'A,. ••• ' LI,f.V L..."'1.D ~ 003/007 Valdosta. Georgia 31601 EPA Est. No. 890!-TX-l PRECAUTIONARY STATEMENTS HAZARDS TO IWMANS (AND DOMESTIC ANIIVIALS) DANGER - PELIGRO Corrosive. Causes irreversible eye damageV:}Harmful if swallowed, inhaled, or adsorbed through the skin. May cause skin sensitization reactions ill certain individuals. Do not get in eyes, on skin, or clothing. Avoid breathing dust or spray mist. Wash thoroughly with soap and water after handling. PERSONAL PROTECTIVE EQUIPMENT (PPE) Applicators and other handlers must wear:

• coveralls worn over long-sleeved shirt and long pants
• Waterproof gloves Shoes plus socks
• Protective eyewear Discard clothing and other absorbent materials that have een drenched or heavily comaminated with this product's concentrate. Do nOl ,use them. Follow manufacturer's instructions for cleaning and maintaining PPE. If no such instructions fCl washables, use detergent and hot water. Keep and wash PPE separately from other laundry. ENVmONMENT AL HAZARDS This pesticide is toxic to fish and aquatic organisms. Do not apply directly to water 01 !o areas where surface water is present or to intertidal areas below the mean high water mark. Do not apply when weather conditions favor drift from area treated. Do not apply when runoff is likely to occur. Drift and runoff from treated areas may be hazardous to fish and aquatic organisms in adjacent aquatic sites. Do not allow rinsate from cie:>.niog of equipment or disposed material to enter surface or ground water. Do not contaminate water by disposal of equipment washwaters. I>e Ret Bischarge effltte81 e@Blillniog IBis pfoollet iHlO 1<11(85, strea:ms, jloads, -estuaries, oceam. df allier wate,s unless ifliiEcof8M1ce with ifte reqIJifeRieRI:s ef Ii Natieo81 POilUlaI'll DiscBilfge EliHlimtioft System (NPDES) I'emlit aM llIe jleflftitling atitllority flas Be'!R Ratified in wriliog prier 16 filscaarge. Do Ret 8iscinuge effluellt eoftlainiHg llIis prsewer systems willlBlil jlre'ie\J91' ootifyiRg llIe 102111 sewage tfeatmenl ploot 8t1tfiority. f"erf,llidanee eOHtactf -W8fer BOilf8 or Regieft81 OHi£·the EPA-, --- --.----- 41 /

) ) GRIFFIN-BIO LAB ~ 0041007 4jr-' 5~, USER SAFETY RECOMMENDATIONS Users should:

• Wash hands before eating, drinking, chewing gum, using tobacco or using u:e toilet
• Remove clothing immediately if pesticide gets inside. en wash thc,roughly and put on clean clothing. I DIRECTIONS FOR USE It is a violation of Federal Law to use this product in a manner inconsistent with its labeling. Do not apply this product in a way that will contact workers or otlter persons, either directly or through drift. Only protected handlers may be in the area during application. For any requirements specific to your State or Tribe, consult the agency responsible for pesticide re gulatlOn. ,------------------------------------------------------------------- AGRICULTURAL USE REQUIREMENTS Use this product only in accordance with its labeling and with the Worker Protection Standard. 40 CFR part 170. This Standard contains requirements for protection of agricultural workers on farms, forests, nurseries, and greenhouses and handlers of agricultural pesticides. It contains requirements for training, decontamination, notification, and emergency assistance. It also contains specific instructiom and exceptions pertaining to the statements on this label about personal protective eqUipment (PPE) and restricted-entry intervals. The requirements in this box only apply to use of this product (bat are covered by the Worker Protection Standard. Do not enter or allow worker entry into treated areas during the restricted entry interval (REI) of 24 hours WIthout required PPE. PPE required for early entry to treated areas that IS permitted under the Worker Protection Standard and thaI involves contact with anything that has been treated. such as plants, soil, 'Jr water. is: . Coveralls worn over lone-sleeved shins and long pants
• Waterproof gloves .. Shoes plus socks
• Protective eyewear 3 ---------- ---~--- (

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) ) O~· 1~/96 16: 19 '6'912 2~~ 59;8 GRIFFI~-BIO LAB NON-AGRICULTURAL USE REQUIREMENTS The requirements in this box apply to uses of this product that are not within the scope of the Worker Protection Standard for agricultural pesticides 40 CFR pall 170. The WPS applies when this product is used to produce agricultural plants on farms. fo,-,slS, nurseries or greenhouses. STORAGE AND DISPOSAL Storage' Store in a cool, dry place. PESTICIDE DISPOSAL: Pesticide wast·es are acutely hazardous. Improper disposal of excess pesticide, spray mixture, or rinsate is a violation of Federal Law. If these wastes carmot be dispused of by use according to label instructions, contact your State Pesticide or Envirorunental Control Agency. or the Hazardous Waste representattve at the nearest EPA Regional Office for guidance. CONT AINER DISPOSAL: Completely empty bag into application equipment. Then dispose of empty bag in sa'1itary landfill, or by incineration, or if allowed by State and local authorities, by burning. If burned. stay out of smoke. GENERAL INSTRUCTIONS Use Oxycop WPS3 as noted below. Oxycop WP53 is adaptable to spraying from aircraft and ground spraying equipment or chemigation unless specifically directed otherwise in the specific crop use directions. The per acre use rate of Oxycop WP53 is applicable for both dilute and concentrate spraYIng lJepending upon the equipment used and the specific crop, the spray volume applied per acre will differ Refer to Reconunended Minimum Spray Volume Table below Complete spray coverage is essential to assure optimum performance from Oxycop WP53 When treating hy aerial application. or with low volume apphcation equipment. unless you have had speCific previous experience, it is ad\1sable to test for compatIbility and tolerance to crop injury prior to full srale commercial utilmltion " 4 /

) UJ'I~'Ulj 11:19 \'912 2~~ 5978 GRI FFIN-BIO UB 'While volume is important in obtaining full spay coverage, often factors such as foliage density, environmental conditions and sprayer calibrations, have a greater impact. Always be sure that sprayers are calibrated to spray equipment manufacturer's specifications and environmental conditions are within those recommended by State and loc;al regulatory authorities. Consult the Oxycop WP53 label for specific rates ano timing of application by crop. When selecting a Oxycop WP53 use rate do not apply less than the label recommended minimum amount. Where application rates are provided in a range (6 - 16 #P), the higher rates are recommended when rainfall is heavy andlor disease pressure high. Under heavy disease pressure or when conditions favor such, use the higher rate and short spray intervals specified for each crop. In addition, use the higher rates for large mature tree crops. It must be determined in the selection prOcess if proper application equipment is available and if the waste associated with its use can be properly bandied. Materials used in the construction of application equipment is also an important factor as agricultural chemicals are often reactive with soft metals such as aluminum and even some synthetic materials such as plastics, rubbers, etc. Therefore it is necessary when working with equipment containing these materials that they are thoroughly flushed with clean water after each days use. When mixing, fill spray tank one-half full with water. Add Oxycop WP53 slowly to tank while hydrauhc or mechanical agitation is operating and continue filling with water Spreaders, stickers (cleared for application to growing crops). nutrients, etc. should be added last. If compatibility is in question, use the Compatibility Jar Test before mixing a whOle tank. l'iOTE: Oxycop WPS3 should not be applied in a spray solution having a pH ofless than 6.5 as phytotoxiCIty may occur CROP CLASSIFICATION ) CITRUS Grapefruit, Kumquat, Lemon, Lime, Orange, Tangelo and Tangerine FIELD CROPS' Barley. Oats, Peanut, Potato, Sugar Beet and Wheat. SMALL FRUITS Blackberry, Blueberry, Cranberry, Raspberry and Strawberry TREE CROPS. Almond, Apple. Apricot, Avocado, Banana, Cacao, Cherry, Coifee, Filbert, Mango, Nectarine, Olive, Papaya. Peach, Pecan. Plum, Prune, and Walnut VF.GETABLES Bean. Beet Greens, Broeeoli. Cantaloupe, Carrot. Celel)" Cucumber, Eggplant. Garlic, Honeydew, l.eeks, Muskmeloll, Omon. Pea. and Tomato GREENHOUSE AND SHADE HOUSE CROPS Pepper, and Tomato ~nSC[LLANEOUS Rice and to'{;acco

) ) Garlic, Honeydew, Leeks, Muskmelon, Onion, Pea, and Tomato. GREENHOUSE AND SHADE HOUSE CROPS Pepper, and Tomato MISCELLANEOUS: Rice and tobacco. ORNAMENTALS Species as listed. Minimum Recommended Spray Volume (Gallons) Per Acre When <\ppl)in!; Oxycop WP53 Aerial Ground Dilute Concentrate Vegetablc~ 3 100 20 Field Crops 3 100 20 Small Fruit 3 250 50 Tree Crops 10 250 SO Citrus 10 800 100 • (Florida) Miscellaneous 10 150 50 and Ornamentals • Pesticide application equipment such as Curtec® or other similar sllrayers which are capable of obtaining thorough coverage at low volumes may be used at as low as 20 gpa of spray volume For citrus decrease volume toward 100 g~ as tree size decreases. For small fruit and tree crop dilu,e ground spray use a minimum of 15 gpa. This product may be reactive on metal and masonry surfaces such as galvanized roofing. Avoid contact ',vith metal surfaces Do not spray on cars, houses, lawn furniture, etc The following specific instructions are based on general application procedures The recommendations of the State Agricultural Extension Service should be closely followed as to timing, frequency. and numher of sprays per season FROST IN.1I1RY PROTH:TION BACTERIAL ICE NUCLEATION INIIIBITOR :\ppllcatl(ln (1( o.xvCPP WI";} rnade to all crops listed Oil this label at rates and stages of growth sh{)\'Tl on thIS Llhel. at least 24 houls before antiCipated frost conditions. will afford control of ILT nucle;ltlnl( bacteria 1l';;eudcll11(lnas ,!yringae. Erwini;I herhicola. and Pseudomonas tlur1 [csccns) and rnav thc[cfnre p[m'id~ snmc prntection against light frost Not recommended

for those geographical areas where weather conditions favor severe frost CITRllS ,J Oxycop WP53 may be mixed with dry foliar nutritionals (micronutrients) to create "Shot Bag" mixes to meet the various nutritional requirements of citrus and provide disease protection as described on this label. Oxycop WPS3 per acre rates in these mixes must not exceed the maximum recommended labeled rates for disease control. NOTE Addi!1g foliar nutritionals to spray mixtur'!s containing Oxycop WPS3 or other products and applying to citrus during that post bloom period whet. young fruit is present may result in spray burn Disease Melanose, Scab Greasy ~pot, Pink Pitting I'hvtophthora Brown Kat Rate/Acre 6 - 12 Ibs 4 - 12 Ibs. 4 -12 Ibs. Use Instructions For Scab control make two applications, one ( just before trees t ~gin to flush and repeat at two-thirds petal fall. For Melanose control, apply I to 3 weeks after petal fall. Repeat 4 weeks later if necessary. Use higher rates when conditions favor disease Make a summer :;pray about July IS in Florida on expanded new flush and fruit. Repeat on / subsequent flushes if disease is severe Use higher rate wh(,11 conditions favor disease Apply to skirts of trees to a height of at least 4 fi and tu the bare ground under tree and one foot beyond the tree line before fall rains Reapply in January or February depending on the amount of rain during this period. Addition of a spreader-sticker adjuvant may increase the effectiveness of the treatment. NOTE: Do not use or apply in areas where copper injury is known to occur. ~e ficllHigAtiflA witA A)'t1rflgeA€'l'ftAide is prActice&-­ NOTE: California only. in areas subject to copper injul'. add 112 to I pound (lfhigh qualit' Innc per pound nf Oxvcop WI' q FJELD ('HOI'S I

/o0f2i Crop Disease Rate/Acre Use Instructions Peanut Cercospo:a Leaf 2 - 3 Ibs. Use in ground, chemigation or Spot aerial application. Make first application before first disease symptoms appear or are reported in area (usually 25-40 days after planting). Thorough canopy penetrating coverage is required for good control. For best ground spray, use as much water as practically possible and a spray pressure of at least 60 psi or more. With aerial application use 3 -5 gallons per acre. Continue sprays at 1 (1-14 day intervals preferably up to harvest. Use shorter interval and higher rates when disease pressure is high and when late Leaf Spot is expected, May be tank mixed with a sulfur formulation or other compatible fungicides at labeled rates. Potato Early Blight, Late 3 - 4 Ibs. Usc in 25 or more gallons of I Blight water per acre. Begin applications when plants arc 4-6 inches high or when disease first ) appears 111 area Repeat at 4-10 day intervals to harvest or as needed. If Late Blight is a problem, apply before digging or in vine kill spray. Use higher rates when conditions favor disease. Sugar Beet Cercospora Leaf :l - 5 IDS. Begin applications when disease SpIlt first appears and repeat as needed lise the higher rates when conditions Ln-or dlSCISC Wheat. (bh Scpt(lfl:l I caf Blotch :' -, Ihs l\fake fir'! aPl'ircltlon at cail,. <Inti H.lI k" (11 (iluIIll' II 1 (ltc fi". hcadllH. alld fllll(,," with sec'llnd fl

Crop Berries (Blackberry Boysenberry, Dewberry, Loganberry, Raspberry) Strawberry Crop Aln10nd Hclminthosporium Leaf or Spot Blotch SMALL FRUITS Disease Rate/Acre Anthracnose 4-5 Ibs. Leaf and Cane Spot, 4-5 Ibs. Yellow Rust 12-15Ibs. Downy j\1ildew, 2 - 3 Ibs Leaf Spot TREE CR(lPS Disease Ratr.! Acrr Corynillm Blight R - 12 Ihs (Shot Hole), Brown Rot BlossOIll Blight, Twig Blight 'J spray 10 days later. Use the higher rates when conditions " favor disease. Use Instructions Begin spray when leaf buds begin to open. Repeat when flower buds show white and continue at 10-14 day intervals. Use higher rates when conditions favor disease. In spring sprays apply when leaf buds begin to open and repeat when flower buds show white. Use higher rates when conditions favor disease. Make a post-harvest spray after pruning but before rains begin. Combine with a spreader-sticker. Use higher rates when conditions favor disease. Begin application after leaves form. Repeat at 10-14 day intervals. Use the higher rates when conditions favor disease. Use Instructions Apply as a rlorrnant spra' before buds begin to swell esc highel rates during wet seasons or when dISease pressure is high JI~7 ( /'

) 6-8Ibs. Apply at early bloom (popcorn) to full bloom stage NOTE: to avoid plant injury, do not use above rate after full bloom. Apple Anthracnose, 12-16Ibs. Apply at 10% to 60% leaffall European Canker, . but before fall rains. Repeat Blossom and Shoot before winter pruniilg. Blast reseudomonas) NOTE: If Fire Blight spray is not made, repeat between silver- tip and green-tip, but do not use after green tip exceeds 1/2 inch. ) NOTE: Use on yellow varieties may cause russeting. To avoid discoloration, pick before spraying Non-yellow varieti,~s may differ in susceptibility to copper resulting in russeting or injury / Fireblight 8-16 Ibs. Make application between silver- tip and green-tip but do not usc after gr ~en tip reaches 112 inch as phytotoxicity may occur. \ I -I 1/2 Ibs. During bloom apply as a dilute I cover spray. Begin spray at 10% bloom and repeat at 5 day intervals until bloom is over. / NO'IF: In California use only I lb. during bloom period and follow directions for application above ..\l'riu1t C(lryncuill Blil:ht (,- 12 Ihs Apply in fall d(lrrnant sprav and (Sh,l{ Hole), Brown repeat at popcorn (l \]11 bl[)(ll11 Rot BI(lS>(lm Blight, \vil: 1l11l:l1t ,. 1 ()

Avocado Scab Banana Sigatoka Black Pitting Cacao Black Pod Cherry BI(lS,(1f11 Blil(ht , ' Br(mn Rot, TWig Blight, l.caf Spot l.raf Rust (llemi1cla 6-12 Ibs. 3-4 Ibs. 4-6 Ibs. 3-6Iho. 8-10Ibs. 1 1 Begin spray when bloom buds begin to swell and continue at "-monthly intervals for 5 to 6 applications or as needed. Use higher rate when conditions favor disease. Addition of spreader-sticker is recommended especially when rainfall is heavy and frequent. Apply in 3 gallons water containing 0.5 gallons agricultufal oiL Apply on a 14 day schedule throughout the wet season. Apply at 21 day intervals during dry periods. Apply in 100 gallons directly to the fiuit stem and include the basal portion of the leaf crown. Apply during the first and second week after fruit emergence. Begin applications at the start of the rainy season and continue while infection conditions persist Applications should be made at ! 4 to 21 days in high rai~ltall "reas. F or drier areas, 2 to 4 applications are recommended during critical infection periods and at the longer intervals. Use higher application rates and shorter intervals according to disease pressure and planting density Apply at popcorn. full hloom and again at petal fall Do not applY after petal fall sta),!c i\vrra[!c lknsitv Plant at inns /

) i vastatrix) 6-12Ibs. High Density Plantations. Make applications before onset of rainy season alld when disease is expected for that area. Follow local recommendations for number and timing of sprays. Iron Spot (Cer- 3-4 Ibs. Use as concentrate or dilute cosllora coffeicola), spray. Begin treatment at the Pink Disease start of wet season and continue (Corticium at monthly intervals for 3 salm,;macolor) applications. ) Filbert Bacterial Blight 16 -24 Ibs. Apply as a post harvest spray in late August or early September before heavy rainfall. Ifheavy fall rains occur, reveat application when three-fourths of the leaves have dropped. If weather conditions requIre, a spreader-sticker may be added. Use higher rates when conditions favor disease. \fango Antr.racnose 12-15Ibs. Begin applications when panicles . (Except are about 2 inchl!S long. Repeat ~ California) weekly until fruit set and then ) continue sprays monthly through September for a total of 5-12 applications depending upon area. Add suitable spreader- sticker. OliVl~ Leaf Spot (Peacock) 8-121bs Apply before fall rains begin. NOTE: In areas with 10 inches or less of rainfall per year, usc 4- 8 Ihs. per acre I' ,Ipaya t\nthracnose '-1 () Ills Begin application hefore rains (Except California) when disease is suspected ,.. R 'peat at 10-14 day intervals 1 ., ..

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) Brown Rot Blossom 4-6Ibs. Apply in full cover spray at Blight (Suppression) green bud and at early pink to white bud stage. NOTE: Limit 6 :os. per acre and do not apply more than 500 gallons per acre. Walnut Bacterial Blight 8 - 14 Ibs. Apply at early pre-bloom. Repeat applications every 7-10 days as needed during bloom and early nutlet development. Use higher rates when conditions favor disease. ) VEGETABLES Crop Disease Rate/Acre Use Instructions Bean (Green Angular Leaf Spot 2-4Ibs. Begin application when plants and Dry) Anthracnose, have second trifoliate leaf set Bacterial Blight, (v. hen plants are about 5 inches Downy Mildew tall), or before disease first appears. Repeat ill 5-\ 0 day / intervals as needed. Use higher rates when conditions favor disease. ) Beets Downy Mildew, 2 - 4 Ibs. Begin applications when disease LeafBlight, Leaf first appears. Repeat at 7-10 day Spot intervals as needed. Use higher rates when conditions favor disease. Canl<!loupc. Anthracnose, 3-41bs Begin applications before disease Iionevdew. Angular Leaf Spot. first appears Reapply weekly \uokilleion, Scab, Downy while conditions favor disease i\ lildew Usc higher rates when conditions favor disease (Mr"t I eaf Blight, Leaf 1- (, Ihs 1 Isc in 2"-100 t!allons of water :---; {)1 ,. per acre Bcglll applicatloll.s bd('rc llisca;;c ilppcars ;lJId repeat 1 ,1

Celery Cucumber Eggplant ( except California) Onion, Garlic, Leeks Pea Pepper Early Blight, Late Blight, Bacterial Blight Angular Leaf Spot, Anthracnose, Downy Mildew, Cercospora Leaf Spot, Scab Alternaria Blight, Anthracnose, Phomopsis Purple Blotch, Downy Mildew Powdery Mildew, Bacterial Blight Bacterial Spot Damping off (cold frames, greenhouses) 3-6Ibs. 3 -4 Ibs 3-4Ibs. 3-4 Ibs. I 1/2-, Ibs 3-4 Ibs. 4-<; Ills 1 " at 7-\ 0 day intervals. ~ Use in 25-\ 00 gallons of water per acre. Begin when plants are set in field or when diseases are first reported in area. Repeat as 5 - I 0 day intervals. Apply weekly once the plants begin to vine Use shorter intervals and higher rates when conditions favor disease. Begin applications before disease appears. Repeat sprays at 7-10 day intervals or as needed depending on disease severity. Begin when plants are 4-6 inches high and repeat at 7-10 day intervals as needed depending upon disease pressure. A spreader-sticker may be adJed to better wet the foliage Begin applications when disease symptoms first appear and repeat at weekly :ntervals as needed. Use higher rates when conditions favor disease. Start sprays in seedbed or !idd before disease first appears and usually right after transplanting Repeat at 5-10 dav intervals especially during fruiting stages Use in \ 01) gallons of water or 2 07. in 1 gallons Applv as a light sprav to soil slIrface around plant' Begin when plants ('merge and rel'C3t at ·1-7 day inll'rvah tlntil tran'p;lI1tirH! time ( /

Spray plants thoroughly. Keep suspension well agitated. N9lE: De ftet use eft eebbege t1:116 related ereps fur the eefttrel efDafflpiflg 91f Tomato Gray LeafMold, 3-4 Ibs. Apply in sufficient water for Early Blight, Late thorough coverage. Begin in Blight, Septoria Leaf seedbed and repeat at 5-7 day Spot, Anthracnose, intervals after first leaves appear. Bacterial Speck, Bacterial Spot In the field, especially where Racterial Spot or Speck infections are uSl1ally heavy, ) begin spray ail r transplanting or when disease iJ first expected lnd repeat at 4-7 day intervals. Oxycop WP53 may be applied up to day of harvest Damping Off (Cold 4-5 lbs. Use in 100 gallons of water or 2 Frames, Green- oz. in 3 gallons. Apply as a light houses, etc.) spray to soil surface around plants Begin when plants emerge and repeat at 4- 7 day intervals until transplanting time I Spray plants thoroughly. Keep suspension well agitated ) NHlt: De flet use eft eabbage eftd related ereps fer the eentrel of D8ff1l"iflg mr 1\1ISCF:LIt\ "iEOUS Crop [)isl'asl' Rate/Acre Use Instructions Rice ,\Ig~c Control in 3-5 Ins Application oy dusting or Flooded Rice Fields spraying the flooded rice fields as needed to cnntH)1 algae is preferred and repeat as needed Use the higher rate as water , depth Increases fiom '1-(, inches 1 ()

Tobacco Angular Leaf Spot, Root Rot, Damping Off( Cold Frames, Green-houses, etc.) 1/4 to 2/3 lb. (15 square yanfsof bed) 1 ; and as algae infestation level Increases. '" Use in 10 gallons of water and apply as spray to each 15 square yards of bed and repeat eve!), 10- 14 days. Begin at plant emergence and use the lower rate on smaller plants and increase as the seedlings grow. ( \

) ORNAMENTALS For control of disease on ornamentals in Greenhouses, Field and Nurseries: Use Oxycop WPS3 on container, bench or bed-grown ornamentals in greenhouses or outdoor nurseries, for professional use on ornamentals grown for indoor and outdoor landscaping, and for control of bacterial and fungal diseases of foliage, flowers and stems. Apply as a thorough coverage spray using 4 lbs. ofOxycop WPS3 per 100 gallons of water. Begin applicatioll at first sign of disease and repeat at 7-10 day intervals as needed and after each rain. Use the shorter interval during periods offrequent rains or when severe disease conditions persist. Use equivalent rates when applied by chemigation Notice to User: Plant sensitivities to Oxycop WPS3 have been found to be acceptable in specific genera and species listed on this label under conditions tested, however, phytotoxicity may occur with varying conditions. Due to the large number of species and varieties of ornamentals and nursery plants, it is impossible to test every one for sensitivity to Oxycop WPS3. Neither the manufacturer nor seller has determined whether or not Oxycop WPS3 can be safely used on ornamental or nursery plants not listed on this label. The user should determine if Oxycop WPS3 can be used safely prior to commercial use. In a small area, apply the / recommended rates to the plants in question, i. e. bedding plants, foliage, etc., and observe for 7- 1 0 day~ for symptoms of phytotoxicity before commercial use. Latin Name Arbor Vitae Thuja occidentalis :,ters Aster sp. Azalea Rhododendron sp Begonia Begonia semperflorens Didnth"s 'P Disease Anthracnose, Blights, Leaf Spots Anthracnose, Botrytis Blight, Leaf Spot, Downy Mildew, Powdery Mildew Anthracnose, Blights, Leaf Spots, Bud Blight, Twig Bligl it Anthracnose, Botrytis Blight, Leaf Spot, Downy Mildew, Powdery Mildew Anthracnose, Blrghts, Leaf Sp(lts Anthracnose, Botry.'is B1il:ht, !'eaf Spot. Down:,

( , Chrysanthemum Dahlia Dogwood Gardenia Geranium Gladiolus Hollyhock Ivy (English, Algerian) Lilac Lilies 1'.lallg(lld Chrysanthemum IDorifoliuID Dahlia pinnata Comus florida Gardenia jasminoides Pelargonium sp. Gladiolus sp. Alcea sp. Hendera helix, H. cananensls Syringa sp. Liliulll sp. 8cer sp. 1 ') f \ \ Mildew, Powdery¥lew Anthracnose, Botrytis Blight. Leaf Spot, Downy Mildew, P6wd" Mildew ........ ~ ......... , ........ . Anthracnose, Botrytis Blight, Leaf Spot, Downy Mildew, Powd!YMiI4ew Anthracnose, Blights, Leaf Spots Anthracnose, Botrytis Blight, Leaf Spot, Downy Mildew, §!'ygl!'41~~ew Anthracnose, Botrytis Blight, Leaf Spot, Downy Mildew, Ppwd~!y~14ew Anthracnose, Botrytis Blight, Leaf Spot, Downy Mildew, PowMijMild ew Anthracnose, Botrytis Blight, Leaf Spot, Downy Mildew, Powdery Mildc'''' Anthracnose, Blights, Leaf Spots Anthracnose, Blig'lts, Leaf Spots Anthracnose, Botrytis Blight, Leaf Spot, Downy Mildew, Powdery Mildew Anthracnose. Blights, Leaf SP0ts Anthracnose, Botrytis Blight. leaf Spot, Downy Mildew, Pl1wdery Mildew I , ./

) Naslurtiu.ll TrOp~0ilJfT] sp Anthracnose, l30trytis Blight, Leaf Spot, Downy Mildew, Powdery Mildew Oak Quercus sp. Anthracnose, Blights, Leaf Spots Palm Palm;le sp. Anthracnose, Blights, Leaf Spots, Smuts Pine Pinus sp. Anthracnose, Blights, Leaf Spots Pansy Viola SIL Anthracnose, Botrytis Blight, Leaf Spot, Downy Mildew, Powdery Mitdev.( Peony Paeonia spp. Anthracnose, Botrytis Blight, Leaf Spot, DO'\llY Mildew, Powdery Mildew Phlox Phlox sp Anthracnose, Botrytis Blight, Leaf Spct, Downy Mildew, Powdery Mildew / Rhododendron KhQdodendron sp AnthracnGS<', Blights, Leaf Spots Rose Ros,! sp Anthracnose, BJtrytis ) Blight, Leaf Spot, Downy Mildew, Powdery Mildew Snapdragon Antirrhinun) sp. Anthracnose, BOlrytis Blight. Leaf Spot, DO'\llY Mildew, Powdel)' Mildew .~wcet Pea l.athyn.lsodllratus Anthracn()sc, Botlytls Blight. Leaf Sr('t. 1>,,\I1V ~1i1dew. Powdery lildew 11I1,!', lull!"l "I' ,\ntlll aUII.''''. ll"ll vII.; IIItht. I l',lf SI'''1. il(l\m ,.. ~ Itldcw. P(l'\ltcry ~ hldew )()

Vinca Violets Virginia Creeper Zinnia Species Pine' ) Vinca sp. Voila sp. Panthenocissus WIlquelQJjil Canker, Dieback Anthracnose, Botrytis Blight, Leaf Spot, Downy Mildew, Powdery Mildew Anthracnose, Blights, Leaf Spots Anthracnose, Botrytis Blight, Leaf Spot, Downy Mildew, Powdery lvfildew FOREST TREES AND SHRUBS Disease Needle Blight (including Dothistroma Neec:~ Blight) Rate/Acre I !I .. -3Ihs. 2 1/2-3 112 Ihs " I Use Instructions In forests, hedges and \;ndbreaks, apply in sufficient water for good coverage. If applied by aircraft equipment ~th low volume sprayers adjust the droplet size to apply 4 pints per acre or more. Apply I 1/2 Ibs in 1 3/4 pint medium crop oil and add sutlicicnt water to give thorollgh cover f(lr disease control Make applications as needles arc emerging When disease potential IS heavy, repeat about 3 weeks later. Repeat at yearly intervals as needed In nurseries anu ornamentals, apply bv dilute spray to point of nm off, applying in 1 00 gallon~ of water using above timings and fepeat as needed tn (')l1t[(11 disease Applv 111 !HI pll()l1s water lal(' firq spral ,It the fllst ,11:11 ()f nrq I'lrstulcs R"I'l',1t rn'TI ·1 w('(' s as l1('cdcd til (ilflil "I ( /'

disease. GENERAL CIIEMIGA nON INSTRUCTIONS Apply this product only through one or more of the following types of systems: sprinkler including center pivot, lateral move, erid tow, side (wheel) roll, travder, big gun, solid set, or hand move irrigation system(s). Do not apply this product through any other type of irrigation system Cop injury or lack of effectiveness can result from nonuniform distribution of treated water. If you have questions about calibration, you should contact State Ex.ension Service specialists, equipment manufacturers or other experts. ) Do not connect an nrigation system (inclur''lg greenhouse systems) used for pesticide application to a public water system unless Ie pesticide label-prescribed safety devices for public water systems are In place. A person knowledgeable of the chemigation system and responsible for its operation or under the supervision of the responsible person, shall shut the system down and make necessary adjustments should the need arise / Posting of areas to be chemigated is required wi.en I) any part of a treated area is within 300 feet of sensitive areas slIch a<; residential areas, labor camps, businesses, day care centrs, hospitals, in-patient c1lnil·s, nursing hrlnleS or any puhlic areas such as schools, parks, playgl ounds, or other public Llcilities not Including public wads, or 2) when the chemigated area is open to the public such <IS golf C()IIfSCS r,r retail greenhouses ) Posting must conform to the following requirements Treated areas shall be posted with signs at all usual pomts of cntry and along likely routes of approach from the listed sensitive areas. When there arc nr, lIslIal POlTlts of entry, signs must be posted in the corners of the treated areas and In any location alT"rriing ma'(imum visihility to sensiti(: areas. The printed side of the sign ,h(lliid face away frPIll the treated are,1 toward the stnsitlye area. The sIgns shall he printed in Fnglish Signs must Pc po,ted prior to application and mllst remain until foliage has dried and s,,11 SUI face water has disappeared Signs may remain in place indefinitely as long as they arc C(lIllP"'CJ "f mate'lais t(l prevent deterioration amimaintallliegihility lilT the duration of the I""tlng I'l'l1<,d .·\11."",,1, ,Iuil '(llhl,t "I ktt"ls at least 2 12 Inches 1;111, and all kttt'rs ,lI1d the' ,vlllb,,1 ,I'all he ,I ,,,1"1 th.,t ,h,lfl'lv" 'Iltt..,h With thc·lr 1ITl1ll'dl;lll' ba'kI~l(lund At til<' t{,P pI the 'i1'1l shall he till' ",,,ds KI·I·, ()I'I, bdl"'.'ed hv an {'CLlg{"!,ll st,,1' sign symhol at \c;l,t X Imh.", In d:dllll'lcr ,,,nl,llI11111: the w, 'Id S I ()j' Ilt-I"" the Wlllh{,1 ,hall be the words 1'1· S II' II )1· <; I" IIUU< i\ II( )'; \' \ II H r

I Shutoff injection equipment after treatment and continue to operate irrigation system until Oxycop WI'53 has been cleared from the last sprinkler head. " It must be determined in the selection process it proper application equipment is available and if the waste associated with its use can be properly handled. MateriaIs used in :i1e construction of application equipment is also an important factor as agricultural chemicals are often reactive with soft metals such as aluminum and even some synthetic materials such as plastics, rubbers, etc. Therefore it is necessary when working with equipment containing these materials that they are thoroughly flushed with clean water after each days use. CHEMIGATION SYSTEMS CONNECTED TO PUBLIC WATER SYSTEMS Public watcr system means a system for the provision to the public of piped water for human consumption if such systcm has at least 15 service connections or regularly serves an average of at least 25 individuals daily at least 60 days out of the year. Chemigation systems connected to public water systems must contain a functional, reduced- pI (',surc zonc, back flow preventer (RPZ) or thc functional equivalcnt in :hc watcr supply line upstrcam from thc point of pcsticidc introduction As an option to the RPZ, thc water from the publIc water system should be discharged into the reservoir tank prior to pesticide introduction There shall be a complete physical break (air gap) bctween the outlet end of the fill pipe 1nd the top or overflow rim of the reservoir tank of at least twice the inside diameter of the fill pIpe The pestiCIde injection pipeline must contain a functional, automatic, quick·c1osing check valve tn prcvent Ihe fl(lw ofthlid hack tnwarci the inj('clion pump The pestiCide injection pipeline must contain a functional, normally closed, solenoid-operated valve located on the intake side of the injection pump and connected to the system interlock to prevent fluid from being withdrawn from the supply tank when the irrigation systcm is either automatically or manually shut down The system must contain functional interlocking controls to automatically shtlt off the pesticide Injection pump when the water pump motor stops, or in cases where there is no water pump, when the water pres.urc decreases to the point where peJticide distrihution is adversely affected S,lclm I11Uq lise a nlt'kIHH! PtllTlP, stich as a I'mltl\T displcement injeclfI'rl pump It' g, dlal,hrWITlI'lIl11p) clleCllvc1\ deslI!Tlcd and c<'nstrtlcted (lfmatenals that arc c(ll11l'atlhle wllh I'l'''lll l ,'' .1nd capahle "flwlnl~ titled Wllh a S\SI(,lTllnt('r1(ll~ \hen 1111\1;,', till nlllSl' lank halffirll with W;]tt'f <\dd OWenI' WI' ~1(l\I\ t(1 LlIlk whIlr (

hydraulic or mechanical agitation is operating and continue filling with water Stickers, spreaders, insecticide<" nutrients, etc. should be added last. If compatibility is in question, use the compatibility jar test before mixing a whole tank. Because of the wide variety of possible combinations that can be encountered, observe all cautions and limitations on the label of all products used in mixtures Oxycop WP53 should be added through a traveling irrigation system continuously or at the last 30 minutes of solid set or hand moved irrigation systems. Agitation of the mixture in the nurse tank is recommended Shut otT injection equipment after treatment and continue to operate irrigation system until Oxycop WP53 has been cleared from the last sprinkler head. SPRINKLER CHEMIGA nON The system must contain a functional check valve, vacuum relief valve, and low pressure drain appropriately located on the irrigation pipeline to prevent water sv .. ce contamination from backflow. The pesticide injection pipeline mllst also contain a functional, automatic, quick-closing check valve to prevent the flow of fluid back toward the injection pump. The pesticide injection pipeline must contain a functional, nomlally closed, solenoid-operated valve I(\eated on the intake side of the injection pump and connected to the system interlock to prewnt fluid frolll being withdrawn froll1 the supply tank when the irrigation svstem is either alJtol1lz\tkaliv or rnJnualiv shut down TIl(' ",tern I"ust wnt,lIn IllTlctionallnll'rincking cuntrols to automatic?lIy shut otT the pestiClCic ITljectlon pump when the water plI'np mnt()r stops rhe irrigation line or wiltcr pump must include a functional pressure switch that will stop the water pump motor when the water pressuTe decreases to the point where pesticide lhstnhution is adv('fsclvallccted SvstClllS must use a metering pump, ,ueh as a po'ltive displacement injection pUI11P leg, ,llal'hrarn pump) c!1i-cti\ r1v dl'signed and constn.lcted of matenals that arc compatible with I,,",tludl's ;lIld l·;lp;lhle "fklng fitted w"h Zl sv:;tCI1l intcri()ck \ 1i,'11 1Ii1\1TH~. f"IIIIIT, .. I.IIl~ Ii,tillllil "lib ",lleT,<I" ()\["I' WI' slowlv III tallk "hlle lr .. dl.11I1" "I ITI,·, fr,ITII'" I .1,'.1"'11,'111' "1,,·1,111111' ,ITI" U'IlIITllI(' tilllllg witlt w;lll'r Slll·k"TS, ,!'''',l<kl '. IT",',. II' Id,' '. 1,IIITWllls. l'k ,h, 'III" he ,Illded Llq If ll'llll'allhtlltv IS ITl qlll'ql"Tl. I"" lilt' ,"!l'I',II"<ll<l\ 1.11 1,',11"'1,,,,' 111IXIfl(,1 '.',fr"I,' l'ITlk II(,'·;IIIS[' "fllte wltk ,1nl'l\ ,>fI""'lhle !

{ combinations that can be encountered, observe all cautions and limitations on the label of all products used in mixtures '" Oxycop WI'53 should be added through a traveling irrigation system continuously or at the last 30 minutes of solid set or hand moved inigation systems_ Agitation is recommendeo. Shutoff injection equipment after treatment and continue to operate irrigation system until Oxycop WI'S3 has been cleared from the last sprinkler head. WARRAN1Y STATEMENT GRifFIN warrants that this product conforms to the chemical description on the I,.bel thereof and is reasonably fit for purposes stated on such label only when used in accordance with directions lInder normal use conditions. It is impossible to eliminate all risks inherently associated with use of this product. Crop injury, ineffectiveness or other unintended consequences may result because of such factors as weather conditions, presence of other ( materials, or the manner of usc or application, all of which are beyond the control of GRIFFIN. In no case shall GRIFFIN be liable for consequential, special or indirect damages resulting from the use or handling of this product. All such risks shall be assumed by the Bu;,er. The exclu~ive remedy of any buyer or user of this product for any and a:1 losses, injuries, or damages resulting from or in any way arising from the use, handling, or application ,f this product, whether in contract, warranty, tort, negliger>-::<:, strict liability, or otherwise, shall not exceed the purchase price paid for this product or at Griffll1 / Corporation's election, the replacement of this product. GRIFFIN MAKES NO WARRANTIES OF MERrI-fANTABlLlTY OR FITNESS FOR A PARTICULAR 1'1IRI'OSF NOR ANY OTHER EXl'RE'';S OR IMPLIED WARRANTY EXCEPT AS SIAITll AB()'F. --_. - -------------------- t ..