crop-chem-docs/corpus/epa_ppls/19713-145.md

DREXEL D-264 PLUS CAPTAN SEED PROTECTANT

• EPA Reg No: 19713-145
• Registrant: DREXEL CHEMICAL COMPANY
• Signal word: Danger
• Active ingredients: Diazinon (25%); Captan (24.44%)
• Label accepted: 2002-04-30
• Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/019713-00145-20020430.pdf

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'if/.38/~ UNITED STATES ENVIRONMENTAL PROTECTION AGENCY WASHINGTON, D.C. 20460 Ms. Luz Piwonka Drexel Chemical Company P.O. Box 13327 Memphis, TN 38113-0327 Dear Ms. Piwonka: Subject: Amendment - Comply with 2000 Diazinon MOA; Delete Soybeans OFFICE OF PREVENTION, PESTICIDES AND TOXIC SUBSTANCES APR 3 02002 Update First Aid per PR Notice 2001-1; and Update CSF/replacement diazinon source Drexel D-264-Captan Seed Protectant EPA Registration Number 19713-145 Your submissions dated May 8, 2001, May 17, 2001, November 19, 2001, and associated submission dated April 16, 2002 The anlendment referred to above, submitted in connection with registraL.on under FIFRA section 3 (c) (7) (a), is acceptable provided that you:

1. Submit and/or cite all data or other material required for registration/reregistration of your product under FIFRA sectior 3(c) (5) or FIFRA section 4 when the Agency requires all registrants of similar products to submit such data.
2. Make the labeling changes listed bel.ow before you release the prccJuct for shipment bearing the amended labeling: a. In the FIRST AID section, after the "If on skin or clothing" advice add an "If Inhaled" section with appropriate text per PR Notice 2001-1. b. In the first sentence of the Environmental Hazards, add "highly" before "toxic". c. Under the heading DIRECTIONS FOR USE, relocate "Reformulation or repackaging of this product is prohibited." to appear directly after "It is a violation of Federal ).aw to use this product in a manner inconsistent with its labeling.".
3. Submit three (3) copies of your final printed labeling before you release the product for shipment.

2 If these conditions are not complied with, the registration will be subject to cancellation in accordance with FIFRA section 6(e). Your release for shipment of the product constitutes acceptance of these conditions. A stamped copy of the label is enclosed for your records. The Basic Confidential statement of Formula (CSF) dated November 19, 2001 which identifies a replacement diazinon source Manufacturing Use Product is acceptable and has been added to this product's registration file. Sincerely, George T. LaRocca Product Manager 13 Insecticide Branch Registratiop Division (7505C)

RESTRICTED USE PESTICIDE Due to Avian and Aquatic Toxicity For retail to and use only by Certified Applicators or persons under their direct su!)ervision and only for those uses covered by the Cenified Apphcator's Certification. ACTIVE INGREDIENTS: Diazinon: O,O-Diethyl O-(2-isopropyl-6- methyl-4-pyrimidinyl) phosphorothioate Captan· ............................. . Related Derivatives .................... . OTHER INGREDIENTS: ................... . TOTAL: ......................... . ~ N-Trich loro m eth yl1 h iO-4-cyclo hexene-' .2-dica rbox im id e 25.00% 24.44% 0.56% 50.00% 100.00% KEEP OUT OF REACH OF CHILDREN DANGER I PELIGRO Si usted no entiende Ia etiqueta. busque a alguien para que se la explique a usted en detalle. (If you do not understand the label. find someone ;0 explain it to you in detail.) EPA REG. NO. 19713-145 ;:PA EST. NO. 19713-MS·1 FIRST AID Net Contents: WED; Drink !)romptly a large quantity of gelatin solu s or if these are not available. d of water, Avoid hoI. IF INHALED: Remov 'ctim to f artifiCial respiration. preferat:"~~ IF IN EVES: Flush wit Diazinon is an or on this pesticide product (including th concerns, mergencies or pesticide incidents), call the Natl elecommunications Network aI1-800-858-7378. PRECAUTIONARY STATEMENTS Hazards to Humans and Domestic Animals DANGER: Cr.rosve. Causs irreversible eye damage. May cause contact senSitization following repeated contact with skin in suS­ ceptible individuals. If sensitization reactions result, consult 8 physician. Harmful if swallowed or inhaled. PERSONAL PROTECTIVE EQUIPMENT (PPE) Applicators and other handl.rs (other than mixers and load­ ers) must wear: long-sleeved shirt and long pants, water!)roof gloves. shoes piuS socks and protective eyewear. Mixers and loaders must wear: long-sleeved shirt and long pants, waterproof gloves, shoes plus socks, protective eyewear. chemi­ cal-resistant apron when mixing or loading and dust/mist filtering respIrator (MSHA/NIOSH a!)proval number prefix TC-21 C) or a NIOSH approved res!)irator with any R. P or HE filter. Discard clothing and other absorbent materials that have been drenched or heavily contaminated with this product'S concentrate. Do not reuse them. Follow manufacturer's instructions for Cleaning/maintaining PPE. if no such instructions for washables, use detergent and hot water. Kee!) and wash PPE se!)arately from other laundry USER SAFETY RECOMMENDATIONS User should: 1) Wash hands before eating. drinking, Chewing gum, using tob",cco or using the loilet. 2) Remove clothing Immediately if pesticid~ gets inside. 3) Then wash thoroughly and put on clean clothing. i1emove PPE immediately after handling this product. Wash thc' outside of gloves before removing. As soon as pos­ sible, wash thoroughly and change into clean Clothing. ENVIRONME:NTAL HAZARDS This pesticide product is to toxic to birds, fish and other wildlife including waterfowl. Exposed treated seed may be hazardous to birds and other wildlife. Collect or incorporate treated seeds that are spilled during loading or are visible on soil surface in turn areas. Dispose of all excess treated seed and seed packaging by burial away from bodies of water. Keep out of lakes, streams, ponds, tidal marshes and estuaries. Do not contaminate water by cleaning of equipment or disposal of equipment washwaters. DIRECTIONS FOR USE It is a violatlolJ of Federal law to use this product in a manner incon· sislent with its labeling. 00 NOT APPLY THIS PROOUCT THROUGH ANY TYPE OF IRRIGATION SVSTEM. For any reQuirements specific to your Statf!' or Tribe, consult the agency responsible for pesticide regulation. Reformulation or repackaging of ttll, produc:t is prohil<)rt ..... AGRICULTURAL USE REClUIREMEM" Use this !)roduct only in accordanc} v it., It'l labeling arj with the Worker Protection Standard, 40 CFr{ Part '170. This tandard con­ tains requirements for the protection of agricultural we rk("'$ Ot farms, forests, nurseries, greenhouses and t,a'llth::r vf agricUilural !>tlsticides. II contains requirements for training, deco~t;minalion. no"f:~t::ln and emergency 3ssistance.1I also conlains specific instructions '!I,d exceptions pertaining to the stalements on this larel at-out personal protective equipment (PPE) and restricted entry i"t<:ll lal (REI). The re4uirements 10 this box ooly apply to usas of this product that ar, ""ered by I the Worker Protection Standard. (Conf/nued) Manufactured By: Drexel Chemical Company P.O. BOX 13327. MEMPHIS, TN38"3-Q327 ,1U14+,i" '1EGP'" O':,64-CAPTAN Page 1 013

AGRICULTURAL USE REQUIREMENTS (ConOnuedl Do nol apply this product in a way that will conlact workers or other persons, either directly or through drift. Only protected handlers may be in the area during application. Do nol enter or allow worker entry into treated areas during the restricted entry interval of 46 hours. PPE required for early entry to treated areas that is permitted under the Worker Protection Standard and that involves contact with anything that has been treated. such as plants, soil or water is: Coveralls. waterproof gloves, shoes plus 50cks and protective eyewear. NON-AGRICULTURAL USE REQUIREMENTS: Do nOI use on humans or permit children 10 go into treated areas until spray has completely dried. Keep out of reach of domestic animals. Do not permit pets to go into treated areas until spray has completely dried, WORK SAFETY RULES REPEATED EXPOSURES TO CHOLINESTERASE INHIBITORS SUCH AS ARE CONTAINED IN THIS PRODUCT MAY. WITHOUT WARNING, CAUSE PROLONGED SUSCEPTIBILITY TO VERY SMALL DOSES OF ANY CHOLINESTERASE INHIBITOR. Do not rub eyes or mouth with hands. If you feel sick in any way STOP work and get help right away. See -FIRST AID- section of this label. This product gives temporary protection of germinating seed and seedlings of Corn 810UI 6e;eu e from injury by Seed corn maggots and Seed corn beeUes and gives temporary protection to seed from seed-borne and soilborne fungi which cause seed decay and seedling blights. This product contains graphite to assist in accurate planting. Under some circumstances this prOduct may affect the rate of seed­ ing. It is necessary for the user to check planling rate frequenlly to assure himself that the desired planting rate is being obtained. MEASURING CUP ENCLOSED. SPECIFIC DIRECTIONS CORN: Use 5 ounces (3 level measuring cups) per bushel of Corn seed. APply 10 seed as planter box is being filled. Stir with paddle or lathe so that each seed is coated With seed protectant. If temperature is high and soil mOisture is low reduce dosage to one-half. especially for mId-season planting. DO NOT use BARE HANDS. Excess product flows with the seed into the furrow giving additional protection against soilborne diseases_ ounces eed in the planter box a ~ eve measurin e 0 to lanting. Folio STORAGE AND DISPOSAL 00 not contaminate water, food or feed by storage. disposal or cieaning of equipment. PESTICIDE STORAGE: Storage shOuld be under lock and key and secure from access by unauthorized persons and children. Storage should be in a cool, dry area away from any heat or ignition source. Do not allow storage in a damp or humid area. Do not stack bags over 2 pallets high. Move bags carefUlly so as not to tear or punc­ ture. 00 not move from one area to another unless they are se­ curely sealed to prevent dust from escaping. Keep container tightly sealed when nol in use. Keep away from any puncture source. Avoid storage near water supplies, food, feed and fertilizer to avoid con­ tamination. Avoid contamination wtth acids and alkalies. Store in original containers only. If the contents are leaking or material is spilled follow these steps:

1. Collect and place in suitable containers for disposal.
2. Wash area wHh soap and water to remove remaining pesticide.
3. Follow washing with clear water rinse.
4. 00 not allow /1,Inoff to enter sewer or conlaminate water sup- plies.
5. Dispose of waste as Indicated below: PESTICIDE DISPOSAL: f"esticide wlStes are toxic. Improper djs~ ponl of excelS pesticide, spray mixture or rinsale is a violation of Federal Law. If these wastes cannot be disposed of by use ac­ cording to label instructions, contact your State Pesticide or Envi­ ronmental Control Agency or the Hazardous Waste representative at the nearest EPA Regional Office for guidance. CONTAINER DISPOSAL: Completely empty bag into application equipment. Then dispose of empty bag in a sanitary landfill or by ino;:ineration, or, if allowed by State and Local authorities, by burn­ ing. If burned, stay oul of smoke. WARRANTY-CONDITION OF SALE OUR RECOMMENDATIONS FOR USE of this product ate based upon tests believed reliable, Follow directions carefully. Timing and method of application, weather and crop conditIOns, mixtures with other chemicals not ~pecificaUy recommended and other influencing factors in the use of this product are beyond the control of the Seller. Buyer assumes all dsks of use, storage and handling of this malerlal nol in strict accordance with directions given herewith. In no case shall the Manufacturer or the Seller be liable for consequen­ tial, special or indirect damages resulting from Ihe lise or handling of this product when such use and/or handling is not In strict accoraance with :jirections given herewith. The foregoing is a condition of sale by the Seller and is accepted as such by the buyer. 0-264·CAPTAN Page 2013

FIRST AID 0- This product contains diazinon, an organophosphate insecticide that inhibits cholinesterase. If swallowed • Call a polson control center or doctor immediately for treatment advice. • Have a person sip a glass of water if able to swallow. • Do not Induce vomiUng unless told to do so by a poI- son control center or doctor. • Do not give anything by mouth to an unconscious or convulsing person. If In eyes • Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, If present, after the first 5 minutes, then continue rinsing eye. If on skin or clothing • Take off contaminated clothing. • Rinse skin immediately with plenty of water for 15-20 minutes . . . .. Cal a. poison control cenler or doctor for trealment advice.liaw the produd . UI Iduel wnn you When C8RU19 a pOison COmrol center or doctor, or gOln9 for treaIDlent. FQr infQrmtiQn Qn Ihili QIiU!Oi!!1l Q[l!!!Y!OI !illlO!!!Qi!!ll !lU!!!! oncems, mlldlcal Ilm!:[lIencles or I1!!sUcidll iD!Oi!!l:ll!!il, COli l!!!! !!Ii!!nal P!:tiidll T!!:s;Qmmyni!<!!tiQ Networ1c iI! 3~OO::!!§S-Z37§. NOTE TO PHYSICIAN • This product contains diazinon, an organophosphate that inhibits cholinesterase. If symptoms of cholinesterase inhibition are present, , , atropine sulfate by Injection Is antidotal. 2-PAM is also antidotal, but , should be administered only in conjunction with atropine. • f .: , ( ( , I • , , • . .. . ,' .,