crop-chem-docs/corpus/epa_ppls/19713-234.md

METHYL PARATHION 6E

• EPA Reg No: 19713-234
• Registrant: DREXEL CHEMICAL COMPANY
• Signal word: Danger
• Active ingredients: Methyl parathion (62.6%)
• Label accepted: 1994-04-01
• Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/019713-00234-19940401.pdf

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PI) I q UNITED STATES ENVIRONMENTAL PROTECTION AGENCY WASHINGTON. D.C. 20460 BARBARA BROWN DREXEL CHEMICAL COMPANY BOX 9306 MEMPHIS, TN 38109 OFFICE OF I'AEl/ENTIOH,I'EITICIlES AND TOXIC IUltTANCEI Subject: Label Amendment Submission of 11108/93 Response to PR Notice 93-7 EPA Reg. No. 19713-234 METHYL PARATHION 6E Dear Registrant: The labeling cited above and submitted in connection with tegistration under the Federal Insecticide, Fungicide, and Rodenticide Act (FIFRA), as amended, is accepted subject to the comments reflected on the enclosed sheet. A copy of your proposed labeling stamped -ACCEPTED WITH COMMENTS- is enclosed. WHAT THIS ACCEPTANCE MEANS: Based on your certification, the Agency has accepted the labeling changes that are necessary to comply with the Worker Protection Standard (WPS) labeling requirements of 40 CFR part lS6, subpart K, described in PR Notices 93-7 and 93-11. Any other labeling changes submitted in connection with this amendment application but not directly related to compliance with the WPS have not been reviewed or accepted by the Agency. If you wish to make such changes, you must submit a separate amendment application proposing them. If your product is currently suspended, the acceptance of this labeling amendment d\Jes nt affect the suspension in any way. WHAT YOU ·NEED TO DO NEXT: By the next label printing make all the specified changes to your labeling. Send to EPA one (1) copy of the fmal printed labeling: • BEFORE selling or distributing any product bearing the final printed labehn AND • WITHIN one year from date of this acceptance.

• Page 2 Submit the final printed labeling via the U.s. Postal Service to: Document Processing Desk (FIN-LABEL) Office of Pesticide Programs (7SOSC) U.s. Environmental Protection Agency 401 M Street, SW Washington, D.C, 20460-0001 Hand or courier deliveries of final printed labeling may be made to: Attachment Document Processing Desk (FIN-LABEL) Office of Pesticide Programs Room 266A, Crystal Mall 2 1921 Jeffeson Davis Highway Arlington, V A 22202 • /~~-, ..... Tompk' ,Depu Chief gistrati Support Branch /RegistratiOn Division (7S0SW)

ONITBD STATBS ENVIRONKBNTAL PROTECTION AGENCY Office of Pe.ticide Programs Registration Division Barbara Brown DREXEL CHEMICAL CO BOX 9306 MEMPHIS TN 38109 Comment for: BPA Reg Nr.19713-234 METHYL PARATHION 6E The following" specific comments pertain to your WPS labeling submission concerning the product cited above: The respirator requirement for "applicators and other handlers· in the Personal Protective Equipment· section on your proposed labeling is missing or incorrect. Remove the incorrect requirement (if any) and add "For exposures outdoors, dust/mist filtering respirator (MSHA/NIOSH approval number prefix TC-21C). For exposures in enclosed areas, a respirator with either an organic-vapor-/emoving cartridge with a prefilter approved for pesticides (MSHA/NIOSH approval number prefix TC-23C), or a canister approved for pesticides (MSHA/NIOSH approval number prefix TC-14G) .• The exact location is shown iI". Sections A and B on Part I of the pruduct Worksheet in Supplement Three-A to PR Notice 93-7. Add "Organophosphate" to your label in one of the locations shown in Section B on Part 2 of the Product Worksheet in Supplement Three-A to PR Notice 93-7. Remove the statement "Do not apply this product in a way that will contact workers or other persons, either directly or through drift." Only protected handlers may be in the area during application." from its current position within the Agricultural Use Box a~d place it above the Agricultural Use Box. Delete the 72-hour arid area REI statement and the notification· statement from your label. BPA has determined that they are not required for products containing methyl parathion as the sole active ingredient. Correct the typographical errors circled on your proposed label.

RESTRICTED USE PESTICIDE Due to very high acute toxicity to Humans and Birds. For retail sale to and use only by certified applicators or persons under their direct supervision and only for those uses covered by the certified applicator's certification. Direct supervision for this product is defined as the certified applicator being physically present during application, mixing, loading, repair and cleaning of application equipment. Commercial certified applicators must also ensure that all persons involved in these activities are informed of the precautionary statements. Drexel Mathyl parathion 6B Emulsifiable insecticide for controlling certain listed field, forage, fruit and vegetable crops. ACTIVE INGREDIENTS: O,O-Dimethyl 0-4-nitrophenyl phosphorothioate • Related Compounds. . . • • . • • • . • • . • . • INERT INGREDIENTS*: • • • • • • • • • • • • • • ()J~ • • • • • • • • • *Equivalent to 6.0 lbs. of 100% methyl parathion **Contains Xylene range aromatic solvent. insects on the • • 60.3% • • 2.3% • • 37. 4t • .100.0% per gallon. KEEP OUT OF REACH OF CHILDREN DANGBRjPOISON PRBeAu%eN-A-USAR%e~-S*-sed-fte-%ee-ft~%es,-fte-se-ese STA'l'BMEl'4T OF PRACTICAL TREATMENT Call a doctor (physician), clinic or hospital immediately. Explain that the victim has been exposed to methyl parathion and describe his condition. ~ doctor cannot come, take victim to clinic or hospital. Move victim immediately from the area where methyl parathion is present. IF IHHALBD: Remove victim to fresh air. If not breathing, immediatey give artificial respiration, preferably mouth-to­ mouth. Get medical attention. IF IN BYES: Flush with plenty of water. Call a physician. %p-eN-SK%N-wash-wh-p%efty-e!-seap-aftd-waeerT-6ee-.edea% a~~eft*eftT IF SWALLOWED: Call a physician or Poison Control Center. Drink 1 or 2 glasses of water and induce vomiting by touching back of throat with finger. Do not induce vomiting or give anything by mouth to an unconscious person. , ItST aYllllBlE con)

EPA Reg. No. 19713-234 Net contents Manufactured By: EPA Est. No. DREXEL CHEMICAL COMPANY P.O. BOX 9306 MEMPHIS, TENN 38109-0306 FZRST AJ:D TREA'l'JIBN'l' NOTE TO PHYSICIAN Antidote-administer atropine sulfate in large doses, TWO to FOUR mg. intravenously or intamuscularly as soon as cyanosis is overcome. Repeat at 5 to 10 minute intervals until signs of atropinization appear. 2-PAM chloride is a pharmacologic antidote and may be administered as an adjunct to, but not a substitute for, atropine which is a symptomatic and often life-savinq antidote. DO NOT GIVE MORPHINE OR TRANQUILIZERS BECAUSE THESE ANTIDOTES MAY PRODUCE ADVERSE EFFECTS ACCEH'l'UATING THE PHARMACOLOGIC EFFECT OF THIS PRODUCT. This product is a strong cholinesterase inhibitor affecting the central and peripheral nervous systems and producing cardiac and respiratory depression. At first sign of pulmonary edema, the patient should be given supplemental oxygen and treated symptomatically. Continued absorption of the poison may occur and fatal relapses have been reported after initial improvements. VERY CLOSE SUPERVISION OF THE PATIENT IS INDICATED FOR AT LEAST 48 BOORS. ... ..., . ,.

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ENVIRONMENTAL HAZARDS " .• This pesticide is highly toxic to aquatic invertebrates and wildlife. Birds in treated areas may be killed. Shrimp and other aquatic organi;ms may be killed at recommended application rates. For terrestrial uses, do not apply directly to water or to areas where surf~ce water is present, or to intertidal areas below the mean high water mark. Runoff and drift from target areas may be hazardous to aquatic organisms in adjacent aquatic sites. Do not contaminate water by cleaning of equipment or disposal of wastes. This product is highly toxic to bees exposed to direct treatment or residues on blooming crops or weeds. Do not apply this product or allow it to drift to blooming crops or weeds if bees are visiting the treatment area. \ I£ST l1llll8lE ca" 1

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reeeS-wift-fts-preS.eT-tiftdieee-8peei!ie-ere-warftifts-Wftieft ft!era-werkers-e!-eree8-er-!iess-fte-.ey-fte-be-eftered-wifte.~ speei!ie-preeeive-eeftift7-peried-e!-iae-!ied-a.se -be veeaed-eftd-apprepriee-eeieft8-e-aka-ift-ee8e-e!-eeeidefta eHpe8.reTt-Wheft-ere~-warftfts-ere-iveft7-Werftifts-sfta~~-be-iveft ift-a-aft.ee-e.seaeriy-derseed-by-werker8T-ere~-warftift8 a.s-be-vaft-if-~ftere-i8-ree8eft-~e-beiieve-fte-vrieft-werftift8 eaftfte-be-~ •• r.ed-by-werk.r.T-Wri~.ft-warftift9·-•• ·-iftei ••• .-feiewift9-iftferae.ieftT-BAN8BR+-Ar.a-r.a.d-wi-.. yi paraftieft-eft-t.e.e-ef-appiieeiefttT-Be-fte-efter-vie.~ apprepriae-pre.eive-eeftift9-fer-4e-fte.r8T-ift-ea •• -.f aeeisefta~-.xpe •• r.7-r.fer-e-Saea.fte-ef-Praeieai-ree.ft~-eft freft~-paftei-.f-is-pr ••• ea-%ebeT e-pRBYB-PBRSeHA-iH~¥-AKB-peSSiBne-PAiiBB--He.p-ai persefts-efts-afti.es-e.-ef-r.aes-ar.as-fe~-4e-fte.rsT Werk.rs-.ft~erift9-~r.a ••• -fi.S8-wiift-4e-he.r8-.-w.er preeeiv.-eeftift9T . Do not· use in a manner other than recommended on this label. To avoid excessive residues of methyl parathion on food or forage crops always observe the statements found under "Directions For Use," limiting the time before harvest when methyl parathion may be applied. Because this material is poisonous by skin contact, inhalation or swallowing, it should nee be used in such a manner or under weather conditions as will permit drift of the spray into areas not intended to be sprayed. Do not apply or allow drift to areas occupied by unprotected humans or beneficial animals. This product is designed for application after dilution with water and for use by trained operators using airplanes or power ground equipment. The hazards and precautions for handling the product in this container are equally applicable to it after dilution with water for spray application. Add the concentrate to the spray tank while filling with water, and mix thoroughly either by means of a tank agitator or pump by-pass. For best results, thoroughly cover all" 'surfaces to be treated with spray. Rates of application given below should not be exceeded. Never apply later than indicated to assure residue levels at harvest are below tolerances established by the Food and Drug Administration. Consult the state Agriculture Extension Service or Experiment Station for specific recommendations regarding application, dosage and time of sprays. For application by ground equipment, add the desired amount of concentrate to SUfficient water to apply at least 3 gallons of water per acre. For application by aircraft, add the amount of concentrate desire per acre to 1/2 to 3 gallons of water consistent with crop growth and good coverage. Greater quantities of water may be required to give SUfficient coverage of orchard trees.

FIELD AND FORAGE CROPS ALFALFA AND CLOVER - For control of alfalfa weevil larvae aphids (including spotted alfalfa aphids) and climbing cutworms, use 1/3 to 2/3 pint per acre. Apply when 75 percent of the terminals show feeding damage or when larvae inert equals 25 larvae per sweep. For 8.lfalfa caterpillars, armyworms up to third instar, clover leaf weevils and webworDS, use 2/3 pint per acre. For Egyptian alfalfa weevils, leafhoppers, Lyqus bugs and spider mites, use 2/3 to 1-1/3 pints per acre. Do not treat closer than 15 days before harvest, cutting or grazing. Do not apply if the crop or weeds in the treatment area are in bloom. In California and Nevada do not use more than 1/2 pint per acre. COTTON - For control of thrips, use 1/6 to 1/3 pint per acre. For cotton leafworms, use 1/6 to 1/2 pint per acre. For grasshoppers and fall armyworms up to third instar, use 1/3 pint per acre. For spider mites (does not control all species), use 1/3 to 1/2 pint per acre. For control of fleahoppers, Lyqus and other mirids, use 1/6 pint to 2/3 quart per acre. For boll weevils, aphids, and garden webworms, use 1/3 to 2/3 pint per acre. For false chinch bugs, use 2/3 pint per acre. For cabbage loopers and cutworms, use 2/3 to 1-1/3 pints per acre. For bollworms, salt-marsh caterpillars, armyworms up to third instar, cotton leaf perforators and stink bugs, use 2/3 quart per acre. Application should be made at 4 to 5 day intervals until control is obtained. At above dosages, application may be made up to the day before harvest, if harvest will be with mechanical pickers. CAUTION - When necessary to enter treated cotton fields within 48 hours after application, protective clothing should be worn. Do not apply within 5 days of handpicking cotton. GRASS (FORAGE) - For control of armyworms up to third instar, crested wheat bugs, false chinch bugs, grasshoppers and leafhoppers, use 1 pint per"acre. Do not apply within 15 days of harvest or grazing., SOYBEANS - For control of climbing cutworms and three-cornered alfalfa hoppers, use 1/3 pint per acre. For control of garden webworms, Use 1/3 to 2/3 pint per acre. For control of aphids, blister beetles, Mexican bean beetles, stink bugs, two-spotted mites and velvet bean caterpillars, use 2/3 pint per acre. For bollworms, cabbage loopers, fall armyworms up to third ins tar and green cloverworms, use 2/3 quart per acre. Do not apply closer than 20 days before harvest or grazing. SUGAR BEETS - For aphids, armyworms up to third instar, flea beetles, leafhoppers, Lygus bugs, stink bugs and webworms, use 1/2 pint per acre. Do not treat closer than 20 days before harvest, 60 days if tops are to be fed to livestock.

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VETCH - For control of aphids, armyworms up to third instar, climbing cutworms, leafhoppers, Lyqus bugs, spider mites and vetch bruchids, use 2/3 to 1-2/3 pints per acre. Do not treat closer than 15 days before harvest or grazing. VEGETABLES POTATOES - For control of aphids, armyworms up to third instar, cabbage loopers, false chinch bugs, flea beetles, leafhoppers, mites and shield bugs, use 1 quart per acre. Do not apply within 5 days of harvest. SWEET POTATOES - For control of aphids, armyworms up to third instar, surface feeding and climbing cutworms, flea beetles, leafhoppers and mites, use 1/2 quart per acre. Do not apply within 5 days of harvest. BROCCOLI - For control of aphids, armyworms up to third instar, flea beetles, leafhoppers and mites, use 2/3 to 2 pints per acre. For cabbage loopers and stink bugs, use 1-1/3 to 2 pints per acre. Rates above 2/3 pints should not be applied closer than 21 days before harvest. BRUSSEL SPROUTS - For control of aphids, armyworms up to third instar, flea beetles, leafhoppers and mites, use 2/3 to 2 pints per acre. For cabbage loopers and stink bugs, use 1-1/3 to 2 pints per acre. Rates above 2/3 pints should not be applied closer than 21 days before harvest. RUTABAGAS - For control of aphids, armyworms up to third instar, flea beetles, leafhoppers and mites, use 2/3 to 2 pints per acre. For cabbage loopers and stink bugs, use 1-1/3 to 2 pints per acre. Rates above 2/3 pints should not be applied closer than 21 days before harvest. ~. ., CABBAGE - For control of aphids, armyworms up to third instar, flea beetles, leafhoppers and mites, use 2/3 to 2 pints per acre. For cabbage loopers and stink bugs, use 1-1/3 to 2 pints per acre. Rates above 2/3 pints should not be applied closer than 21 days before harvest. COLLARDS, KALE AND MUSTARD GREENS - For control of aphids, armyworms up to third instar, flea beetles, leafhoppers and mites, use 2/3 to 2 pints per acre. For cabbage loopers and stink bugs, use 1-1/3 to 2 pints per acre. Rates above 2/3 pints should not be applied closer than 21 days before harvest.

-- ----------. PEAS - For control of aphids, armyworms up to third instar, flea beetles, leafhoppers, Lygus bugs and mites, use 2/3 to 1-1/3 pints per acre. For cabbage loopers, cowpea curculio, surface feeding and climbing cutworms and stink bugs, use 1-1/3 pints per acre. Rates above 2/3 pints should not be applied closer than 15 days before harvest. Do not apply if the crop or weeds in the treatment area are in bloom. TURNIPS - For control of aphids, armyworms up to third instar, flea beetles, leafhoppers, leaf miners and mites, use 2/3 to 1 pint per acre. For cabbage loopers us. 1 pint per acre. Rat.s above 2/3 pints should not be applied closer than 15 days before harvest. If tops are to be used for food or feed do not apply closer than 21 days before harvest. BEANS (Dry and Green) - For control of aphids, armyworms up to third instar, flea beetles, leafhoppers, Lygus bugs and mites, use 2/3 to 2 pints per acre. For cowpea curculio, surface feeding and climbing cutworms and stink bugs, use 1-1/3 to 2 pints per acre. Rates above 2/3 pints should not be applied closer than 15 days before harvest. Do not apply if the crop or weeds in the treatment area are in bloom. BEETS (Red) - For control of aphids, armyworms up to third ins tar , cabhage loopers, flea beetles, leafhoppers, Lygus bugs, mites and stink bugs, use 2/3 quart per acre. Do not apply closer than 21 days before harvest. CARROTS - For control of aphids, armyworms up to third instar, surface feeding and climbing cutworms, flea beetles, leafhoppers and mites, use 2/3 quart per acre. Do not feed tops. Do not apply closer than 15 days before harvest. CELERY - For control of aphids, armyworms up to third instar, cabbage loopers, flea beetles,' leafhoppers, Lygus bugs, mites and stink bugs, use 2/3 quart per acre. Do not apply closer than 15 days before harvest. ONIONS - For control of thrips, use 1/3 pint per acre. Do not apply closer than 15 days before harvest. SPINACH - For control of aphids, armyworms up to third instar, flea beetles, leafhoppers, mites, seed corn maggots in crown and crown mites, use 2/3 to 1-2/3 pints per aero. For cabbage loopers, use 1-1/3 pints per acre. Rates above 2/3 pint should not be applied closer than 21 days before harvest. LETTUCE - For control of aphids, armyworms up to third instar, cabbage loopers, flea beetles, leafhoppers and mites, use 2/3 quart per acre. Do not apply closer than 21 days before harvest.

I I' I to' I lJ I) ) I BARLEY, OATS, RYE AND WHEAT - For barley thrips, use 1/3 to 1/2 pint per acre. For aphids, armyworms up to third instar, leafhoppers and winter grain mites, use 1/3 to 1 pint per acre. For cutworms use 1/2 to 2/3 pint per acre. For chinch bugs, false chinch bugs and say's plant bugs, use 1 pint per acre. For western or brown wheat mites, use 2/3 pint per acre. Do not us. more than 1/3 pint per acre within 15 days of harvest. CORN - For control of armyworms up to third instar, climbing cutworms, corn leaf aphids, corn rootworm adults, fall armyworms up to third instar and stink bugs, use 1/3 pint per acre. Do not apply within 13 days of harvest. Do not apply to corn during the pollen shed period. RICE - For rice stink bugs, use 1/3 to 2/3 pint per acre. Do not apply within 15 days of harvest. Shrimp, crabs and crayfish may be killed. Do not apply where these are important resources. Do not apply within 14 days of Propanil application. SORGHUM - For corn leaf aphids and mites, use 2/3 pint per acre. For sorghum midges, use 2/3 pint to 2/3 quart per acre, 2 applications, 3 to 5 days apart when approximately 90% of the heads have completely emerged from the boot or not later than start of blooming. Do not apply closer than 21 days before harvest. Leaf injury may occur on some hybrid varieties of sorghum. Spray a few rows a week or so before booting to test effects upon plants. OIL SEED CROPS SUNFLOWERS - For control of sunflower moth, use 1-1/4 pints per acre. Make no more than 3 applications at S-day intervals'. Do not apply within 30 days of harvest. .. .. STORAGE AND DISPOSAL Do not contaminate water, food, or feed by storage, disposal. STORAGE AND HANDLING:

1. Handle container carefully so as to avoid damage and prevent leakage.
2. Do not use or store in or around the home.
3. Store container in a well-ventilat~d place.
4. Empty container retains vapor and product residue. Observe all labeled safeguards until container is cleaned, reconditioned or destroyed. Pesticide Disposal: Pesticide wastes are acutely hazardous. Improper dil!,posal of excess pesticide, spray mixture, or rinsate is a violation of federal law. If these wastes cannot be disposed of by use according to label instructions, contact your State Pesticide or Environmental Protection Agency, or the Hazardous Waste repr'asentative at the nearest EPA Regional Office for guidance.

L I !\o '''' l ---------.,. container Disposal: Triple rinse (or equivalent) and offer for recycling or reconditioning, or dispose of in a sanitary landfill or by other approved state or local procedures. WARRANTY - CONDITION OF SALE OUR RECOMMENDATIONS FOR USE of this product are based upon tests believed reliable. Follow directions carefully. Timing and method of application, weather and crop conditions, mixtures with other chemicals not specifically recommended, and other· influencing factors in the use of this product are beyond the control of the seller. Buyer assumes all risks of use, storage and handling of this material not in strict accordance with directions giyen herewith. In no case shall Drexel or the Seller be liable for conseqUential, special or indirect damages resulting from the use or handling of this product when such use and/or handling is not in strict accordance with directions given herewith. The foregoing is a condition of sale by Drexel Chemical Company and is accepted as such by the Buyer. I , ... .,