crop-chem-docs/corpus/epa_ppls/19713-509.md

KOP-AM COMPLEX LIQUID FUNGICIDE SPRAY

• EPA Reg No: 19713-509
• Registrant: DREXEL CHEMICAL COMPANY
• Signal word: Caution
• Active ingredients: Copper - ammonia complex (27.15%)
• Label accepted: 2011-07-05
• Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/019713-00509-20110705.pdf

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Luz Chan ( ( UNITED STATES ENVIRONMENTAL PROTECTION AGENCY WASHINGTON, D.C. 20460 OFFICE OF CHEMICAL SAFETY AND POLLUTION PREVENTION Drexel Chemical Company PO Box 13327 Memphis, TN 38113-0327 JUL 052011 Subject: KOP-AM Complex - Liquid Fungicide Spray EPA Registration No. 19713-509 Decision No. 446464 Submission Date: March 2, 2011 Labeling Amendment Dear Ms Chan: The labeling referred to above, submitted in connection with registration under the Federal Insecticide, Fungicide, and Rodenticide Act, as amended is acceptable provided you make the following changes:

1. For Commercial/Agricultural Crop Fungicide and Wood Treatment Use Label a. Environmental Hazards Statement
2. Pg 1 - Please update the statement to read: 1 : "This pesticide is toxic to fish and aquatic invertebrates and may contaminate water through runoff. This product has a potential for runoff for several months or more after application. Poorly draining soils and soils with shallow water tables are more prone to produce runoff that contains this product. Drift and runoff may be hazardous to aquatic organisms in water adjacent to treated areas. Do not apply directly to water, to areas where surface water is present, or to intertidal areas below the mean high water mark. Do not contaminate water when disposing of equipment washwater or rinsate." b. Fruit and Nut Crops table
3. Pg 4 - "Filberts" section;
4. Please revise the notice underneath the "Filberts" heading from "(OR and W A only)" to "(Permitted in OR and W A only)"
5. Intended for Home and Garden Use label a. Pg 12 - Before the "Environmental Hazards" section please insert the "User Safety Recommendations" box as seen on the "For hose end applicator" label b. Entry Restriction
6. Pg 12 - Please delete "Do not enter or allow others to enter the treated area until sprays have dried" and revise statement to read "Do not allow adults, children, or pets to enter the treated area until sprays have dried." 1

( 3. For Hose End Applicator label a. Entry Restriction

1. Pg 18 - Please delete "Do not enter or allow others to enter the treated area until sprays have dried" and revise statement to read "Do not allow adults, children, or pets to enter the treated area until sprays have dried." Submit one copy of your final printed labeling before you release the product for shipment. A copy of the labeling stamped "Accepted with Comments" is enclosed for your records. If you have any questions, please contact Dominic Schuler at (703) 347-0260 or via email at schuler.dominic@pa.gov. ;::' , '~ I . Ton~Kish Product 11anager (22) Fungicides Branch Registration Division (7504P) 2

( ( ACCEPlED with COMMENfS InEPALeaer~ MASTER LABEL JUL 052011 'UuderdleFedelai I~. pDngicide. aad Rodent •• At;;t as a""'Died, filr die peIticide resired UDd« EPA RIC. No. t C; 7/3'..- SoC) ACTIVE INGREDIENT: Copper diammonia diacetate complex [Bis(acetato-O)diamminecopper] .......... 27.15% OTHER INGREDIENTS: ................ .......................... 72.85% TOTAL: .............................................................. 100.0% • CAS No. 13822-80-5; Metallic copper equivalent, 8.0%. This product contains 0.784 pound of Copper per gallon. KEEP OUT OF REACH OF CHILDREN CAUTION See FIRST AID Below SHAKE WELL BEFORE USING EPA Reg. No. 19713-509 EPA Est. No. 19713-XX-XXX Net Content: ___ _ FIRST AID IFIN EYES: • Hold eye open and rinse slowly and gently with water for 15 to 20 minutes. • Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. • Call a poison control center or doctor for treatment advice. IF ON SKIN OR CLOTHING: • Take off contaminated clothing. • Rinse skin immediately with plenty of water for 15 to 20 minutes. • Call a poison control center or doctor for treatment advice. IF SWALLOWED: • Call a poison control center or doctor immediately for treatment advice. • Have person sip a glass of water if able to swallow. • Do not induce vomiting ,unless told to do so by a poison control center or doctor. • Do not give anything by mouth to an unconscious or convulsing person. Have the product container or label with you whim calling a poison control center or doctor, or going for treatment. For information on this pesticide product (including health concems, medical emergencies or pesticide inCiderits), call ~he Nati)nal Pesticide Information Center at 1-800-858-:'373. FOR COMMERCIAL/AGRICULTURAL CROP FUNGICIDE AND WOOD TREATMENT USE LABEL PRECAUTIONARY STATEMENTS Hazards to Humans and Domestic Animals CAUTION: Harmful if swallowed. Harmful if absorbed through skin. Causes moderate eye irritation. Avoid contact with skin, eyes or clothing. PERSONAL PROTECTNE EQUIPMENT (PPE) Some material that are chemical-resistant to this product are listed below. If you want more options, follow the instructions for Category G on an EPA chemical resistance category selection chart. Mixers, loaders, applicators, and other handlers must wear: Long-sleeved shirt and long pants, chemical-resistant gloves such as barrier laminate or viton, and shoes plus socks. Follow manufacturer's instructions for cleaning/maintaining PPE. If no such instructions for washables exist, use detergent and hot water. Keep and wash PPE separately from other laundry. Discard clothirig and other absorbent material that have been drenched or heavily con­ taminated with the product's concentrate. Do not reuse them. ENGINEERING CONTROLS When handlers use closed systems, enclosed cabs, or aircraft in a manner that meets the requirements listed in the Worker Protection Standard (WPS) for agricultural pesticide (140 CFR 170.240(d)(4- 6)], the handler PPE requirements may be reduced or modified as specified in the WPS. USER SAFETY RECOMMENDATIONS Users should: 1) Wash hands before eating, drinking, chewing gum, using tobacco or using the toilet. 2) Remove clothing/PPE im­ mediately if pesticide gets inside. Then wash thoroughly and put on clean clothing. 3) Remove PPE immediately after handling this prod­ uct. Wash the outside of gloves before removing. As.soon as pos­ sible, wash thoroughly and change into clean clothing. ENVIRONMENTAL HAZARDS Do not apply directly to water, or to areas where surface water is pres­ ent or to intertidal areas below the mean high water mark. Do not con­ taminate water when disposing of equipment washwaters or rinsate. This product may contaminate water through runoff. Poorly draining soils and soils with shallow water tables are more prone to produce runoff that contains this product. Drift and runoff may be hazardous to aquatic organisms in water adjacent to treated areas. Manufactured For: Drexel Chemical Company P.O. BOX 13327, MEMPHIS, TN 38113-0327 SINCE 1972 509MSP-0710' KOP-AM Complex Page 1 of 20

c DIRECTIONS FOR USE It is a violation of Federal law to use this product in a manner incon­ sistent with its labeling. Do not apply this product ina way that will contact workers or other persons, either directly or through drift. Only protected handlers may be in the area during application. For any re­ quirements specific to your State or Tribe, consult the agency re­ sponsible for pesticide regulation. AGRICULTURAL USE REQUIREMENTS Use this product only in accordance with its labeling and with the Worker Protection Standard, 40 CFR Part 170. This standard con- tains requirements for the protection of agricultural workers on farms, forests, nurseries, greenhouses and handlers of agricultural pesticides. It contains requirements for training, decontamination, notification and emergency assistance. It also contains specific in- structions and exceptions pertaining to the statements on this label about personal protective equipment (PPE) and restricted entry in- terval (REI). The requirements in this box only apply to uses of this product that are covered by the WPS. Do not enter or allow worker entry into treated areas during the REI of 48 hours. For greenhouse uses, do not enter or allow worker entry into treated areas during the REI of 24 hours. For at least seven days following the application of copper-contain- ing products in greenhouses: • at least one container or station designed specifically for flushing eyes is available in operating condition with the WPS-required de- contamination supplies for workers entering the area treated with copper-containing products, • workers are informed orally, in a manner they can understand:

• that residues in the treated area may be highly irritating to their eyes,
• that they should take precautions, such as refraining from rub- bing their eyes, to keep the residues out of their eyes,
• that if they do get residues in their eyes, they should immedi- ately flush their eyes with the eye flush container that is located with the decontaminated supplies and
• how to operate the eye flush container or eye flush station. PPE required for early entry to treated areas that is permitted under the WPS and that involves contact with anything that has been treated, such as plants, soil or water is: Coveralls over long-sleeved shirt and long pants, chemical-resistant gloves made of any water- proof material, chemical-resistant footwear plus socks, chemical-re- sistant headgear for overhead exposure and protective eyewear. Notify workers of the application by warning them orally and by post- ing warning signs at entrances to treated areas. NON-AGRICULTURAL USE REQUIREMENTS The requirements in this box apply to uses of the product that are NOT within the scope of the Worker Protection Standard for agri- cultural pesticides (40 CFR Part 170). The WPS applies when this product is used to produce agricultural plants on farms, forest, nurs- eries or greenhouses. Do not enter or allow others to enter the treated area until sprays have dried. SPRAY DRIFT MANAGEMENT A variety of factors, including weather conditions (e.g., wind direction, wind speed, temperature, relative humidity) and the method of appli­ cation (e.g., ground, aerial, airblast, chemigation), can influence pes­ ticide drift. The applicator must evaluate all factors and make appropriate adjustments when applying this product. Droplet Size Apply only as a medium or coarser spray (ASAE standard 572) or a volume mean diameter of 300 microns or greater for spinning atomizer nozzles. Wind Speed Do not apply at wind speeds greater than 15 mph. Only apply this product if the wind direction favor on-target deposition (approximately 3 to 10 mph), and there are no sensitive areas within 250 feet down­ wind. Temperature Inversions If applying at wind speeds less than 3 mph, the applicator must de­ termine if a) conditions of temperature inversion exist, or b) stable at­ mospheric conditions exist at or below nozzle height. Do not make applications into areas of temperature inversions or stable atmos­ pheric conditions. ( Other State and Local Requirements Applicators must follow all state and local pesticide drift requirements regarding application of copper compounds. Where states have more stringent regulations, they must be observed. Equipment All aerial and ground application equipment must be properly main­ tained and calibrated using appropriate carriers or surrogates. For aerial application: The boom length must not exceed 75% of the wingspan or 90% of the rotor blade diameter. Release spray at the lowest height consistent with efficacy and flight safety. Do not release spray at a height greater than 10 feet above the crop canopy unless a greater height is required for EPA aircraft safety. When applications are made with a crosswind, the swath must be dis­ placed downwind. The applicator must compensate for this displace­ ment at the up and downwind edge of the application area by adjusting the path of the aircraft upwind. For groundboom application: Do not apply with a nozzle height greater than 4 feet above the crop canopy. CHEMIGATION Do not apply this product through any irrigation system unless this sec­ tion on chemigation is followed . Apply this product only through center pivot, motorized lateral move or traveling gun sprinkler irrigation systems that do not contain aluminum components. Do not apply this product through any other type of irri­ gation system. Crop injury, lack of effectiveness or illegal pesticide residues in the crop can result from non-uniform distribution oftreated water. If you have questions about calibration, you should contact State Extension Service specialists, equipment manufacturers or other experts. Do not connect an irrigation system (including greenhouse systems) used for pesticide application to a public water system unless the pesticide label-prescribed safety devices for public water systems are in place. A person knowledgeable of the chemigation system and responsible for its operation or under the supervision of the responsi­ ble person, shall shut the system down and make the necessary ad­ justments should the need arise. Public water systems means a system for the provision to the public of piped water for human consumption if such system has at least 15 service connections or regularly serves an average of at least 25 in­ dividuals daily at least 60 days out of the year. Chemigation systems connected to public water systems must con­ tain a functional, reduced-pressure zone, backflow preventer (RPZ) or the functional equivalent in the water supply line upstream from the point of pesticide introduction. As an option to the RPZ, the water from the public water system should be discharged into a reservoir tank prior to pesticide introduction. There should be a complete physical break (air gap) between the outlet end of the fill pipe and the top or overflow rim of the reservoir tank of at least twice the inside diameter of the fill pipe. The system must contain a functional check valve, vacuum relief valve and low pressure drain appropriately located on the irrigation pipeline to prevent water source contamination from backflow. The pesticide injection pipeline must contain a functional, automatic, quick-closing check valve to prevent the flow of fluid back toward the injection pump. The pesticide injection pipeline must contain a functional, normally closed, solenoid-operated valve located on the intake side of the in­ jection pump and connected to the system interlock to prevent fluid from being withdrawn from the supply tank when the irrigation system is either automatically or manually shut down. The system must contain functional interlocking controls to automatically shut off the pesticide injection pump when the water pump motor stops or in cases where there is no water pump, when the water pressure de­ creases to the point where pesticide distribution is adversely affected. The irrigation line or water pump must include a functional pressure switch which will stop the water pump motor when the water pressure de­ creases to the point where pesticide distribution is adversely affected. Systems must use a metering pump, such as a positive displacement injection pump (e.g., diaphragm pump) effectively designed and con­ structed of materials that are compatible with pesticides and capable of being fitted with a system interlock. Do not apply when wind speed favors drift beyond the area intended for treatment. When mixing, fill the nurse tank half full with water. Add this product slowly to the tank while hydraulic or mechanical agitation is operating KOP-AM Complex Page 2 of 20

( and continue filling the tank with water. Stickers, spreaders, nutrients, insecticides, etc. should be added last. If the compatibility is ques­ tionable, ·use the compatibility jar test before mixing a whole tank. Be­ cause of the wide variety of possible combinations that can occur, observe all cautions and limitations on the labels of all the products used in mixtures. This product should be continuously added through a traveling irrigation system. Agitation is recommended. APPLICATION AND CALIBRATION TECHNIQUES FOR SPRINKLER IRRIGATION Center Pivot, Motorized Lateral Move and Traveling Gun Irriga­ tion Equipment: Operate system and injection equipment at normal pressures recommended by the manufacturer of the injection equip­ ment used. Fill tank of injection equipment with water. Operate sys­ tem for one complete circle for center pivot or one complete run for motorized lateral move or traveling gun equipment, measuring time required, amount of water injected and acreage contained in circle or run. Mix recommended amount of this product for acreage to be covered into the same amount of water used during calibration and inject into system continuously for one revolution or run. Shut off in­ jection equipment after one revolution or run, but continue to oper­ ate irrigation system until this product has been cleared from the last sprinkler head. USE INFORMATION The control of diseases with fungicides is based on PREVENTION: plant surfaces must be completely covered with the fungicide to suc­ cessfully prevent infection. Use the highest indicated rate per crop when disease incidence is high or expected to be, depending on rain­ fall and temperature. The lower rate is suitable for general and pre­ ventative sprays under normal conditions. Since the weather conditions and disease incidence vary, consult your Agricultural Ex­ tension Service for timing and initial application. USE INSTRUCTIONS Partially fill the spray tank with water, add the desired amount of this product and continue filling the tank. If applied with other products, add this product last. Use agitation during mixing and application, until tank is empty. Good bypass agitation is adequate. Observe all pre­ cautions and limitations on labeling of all products used in mixtures. In common with all good agricultural practice, start with clean equipment; equipment should be flushed well with water after use. Ground Application-Dilute Spraying: Apply specified rate in 10 to 100 gallons of water per acre. Orchard and Grove Spraying: Apply specified rate in 100 to 800 gallons of water per acre. Concentrate Spraying: On Vegetable crops use 5 to 25 gallons of spray mixture per acre; on Fruit and Nut trees use 20 to 250 gallons per acre. AIR APPLICATION: Apply specified rate in 3 to 20 gallons of water per acre. FRUIT AND NUT CROPS Crop Disease Controlled Rate of This Product per Acre Almonds Brown rot 8 to 12 qts. SPECIFIC DIRECTIONS: Apply at delayed-dor- mant bud swell stage Oust before blossom buds break open). Dormant oil may be used. Shot hole 8 to 12 qts. SPECIFIC DIRECTIONS: Apply at leaf fall to pro- tect buds and shoots from infection during rainy pe- riods. Reapply every 3 to 4 weeks up to late bud swell. Do not apply after full bloom. Use Restrictions: During the dormant or late dormant period, do not apply more than 8 Ibs. of copper (40.8 qts. of this product) per acre per application. Minimum retreatment interval is 7 days. During the bloom or growing period, do not apply more than 1.5Ibs. of cop- per (7.65 qts. of this product) per acre per application. Minimum re- treatment interval is 5 days. Do not apply more than 18 Ibs. of copper (91.8 qts. of this product) per acre per year. ( Crop Disease Controlled Rate of This Product per Acre Apples Anthracnose 8 to 10 qts. SPECIFIC DIRECTIONS: Apply to foliage after harvest annually. Apple scab (black spot), 8 to 12 qts. Bacterial canker, Blossom and Shoot blast SPECIFIC DIRECTIONS: Apply post-harvest be- fore Fall rains. Crown or Collar rot 4 qts. SPECIFIC DIRECTIONS: Mix in 100 gallons of water. Apply 4 gallons of suspension as a drench on the lower trunk area of each tree. Apply either in early Spring or in late Fall after harvest. Do not use if soil pH is below 5.5 since copper toxicity may re- sult. Fireblight 1 to 2 qts. SPECIFIC DIRECTIONS: Apply at 10% bloom and repeat at 5- to 7-day intervals during bloom period. Do not use on copper sensitive varieties. Fireblight 8 to 12 qts. SPECIFIC DIRECTIONS: Apply as a full cover spray between silver-tip and green-tip. Discontinue when green-tip reaches one-half inch as injuries may occur. Use Restrictions: During the Fall or late dormant period, do not apply more than 8 Ibs. of copper (40.8 qts. of this product) per acre per application. Only one application is permitted per season. Be- tween silver-tip and green-tip period, do not apply more than 6 Ibs. of copper (30.6 qts. of this product) per acre per application. Only one application per season is permitted. During the bloom or grow- ing period, do not apply more than 0.5 lb. of copper (2.5 qts. of this product) per acre per application. Minimum retreatment interval is 5 days. Do not apply more than 16 Ibs. of copper (81.6 qts. of this product) .Jl.er acre per year. Apricots Brown rot blossom blight 7.65 to 12 qts. SPECIFIC DIRECTIONS: Apply at red bud to jacket fall stage. Shot hole 7.65 to 12 qts. SPECIFIC DIRECTIONS: Apply at leaf fall to pro- tect buds and shoots from infection during rainy pe- riods. Reapply up to late bud swell. Do not apply after full bloom. Use Restrictions: During the dormant or late dormant period, do not apply more than 8 Ibs. of copper (40.8 qts. of this product) per acre per application. Minimum retreatment interval is 7 days. During the bloom or growing period, do not apply more than 1.5 Ibs. of cop- per (7.65 qts. of this product) per acre per application. Minimum re- treatment interval is 5 days. Do not apply more than 18 Ibs. of copper (91.8 qts. of this product) per acre per year. Avocados Anthracnose 1 8qts. SPECIFIC DIRECTIONS: Apply when the flower buds begin to swell and continue at monthly inter- vals until AUQust. Use Restrictions: Do not apply more than 3.15 Ibs. of copper (16 qts. of this product) per acre per application. Do not apply more than 18.9 Ibs. of copper (96.4 qts. of this product) per acre per year. Min- imum retreatment interval is 14 days. Bananas Sigatoka I 2 to 4 qts. SPECIFIC DIRECTIONS: Apply every 1 to 4 weeks. (Continued) KOP-AM Complex Page 3 of 20

( ( FRUIT AND NUT CROPS Crop Disease Controlled R.ate of This Product per Acre Crop Disease Controlled Rate of This Product per Acre Bananas Black pitting 5.3 qts. Citrus Greasy spot, Melanose, 0.75 to 2 qts. per (Cont) SPECIFIC DIRECTIONS: Mix in 100 gallons of Pink pitting, Scab 100 gals. of water water. Apply directly to the fruit stem and include Aerial Application: the basal portion of the leaf crown. Apply during the 6 to 8 qts. per 10 first and second weeks after fruit emergence. gals. of water Use Restrictions: Do not apply more than 1.05 Ibs. of copper (5.3 qts. of this product) per acre per application. Do not apply more than (Not to exceed the maximum allowable 18.9 Ibs. of copper (96.4 qts. of this product) per acre per year. Min- imum retreatment interval is 7 days. Blueberries Bacterial canker 8 to 10 qts. SPECIFIC DIRECTIONS: Apply with a spreader/sticker before Fall rains and again 4 weeks later. Cane canker 8 to 10 qts. SPECIFIC DIRECTIONS: Apply with a spreader/sticker before Fall rains and again 4 weeks later. In the Spring during wet weather, apply at 7- to 14-day intervals be- ginning at leaf emergence. Use Restrictions: Do not apply more than 2.1 Ibs. of copper (10.7 qts. of this product) per acre per application. Do not apply more than B.4lbs. of copper (42.8 qts. of this product) per acre per year. Min- imum retreatment interval is 7 days. Caneberries Anthracnose, Leaf and 2 to 4 qts. Cane spot, Purple blotch, Yellow rust SPECIFIC DIRECTIONS: Apply when leaf buds open. Repeat when flower buds show white and continue at 10- to 14-day intervals. Anthracnose, Bacterial 8 to 10.2 qts. blight, Leaf and Cane spot, Purple blotch, Yellow rust rate per acre per application specified under "Use Restrictions') SPECIFIC DIRECTIONS: Apply as pre-bloom and post-bloom sprays. May be used in concentrate sprays at equivalent rates. Brown rot 2 to 6 qts. SPECIFIC DIRECTIONS: Apply in the Fall before or just after heavy rains. In areas of skirt sprays, apply to a height of at least 4 feet. Use Restrictions: Do not apply more than 3.15 Ibs. of copper (16 qts. of this product) per acre per application. Do not apply more than 10 Ibs. of copper (51 qts. of this product) per acre per year. Minimum retreatment interval is 7 days. Cacao Black pod rot 2 to 4 qts. SPECIFIC DIRECTIONS: Apply on a 14- to 21- day schedule in high rainfall areas. Use Restrictions: Do not apply more than 2.25Ibs. of copper (11.5 qts. of this product) per acre per application. Do not apply more than 15.75 Ibs. of copper (80.3 qts. of this product) per acre per year. Minimum retreatment interval is 14 days. Coffee Iron spot, Pink disease 2 to 8 qts. SPECIFIC DIRECTION: Apply 3 applications at the SPECIFIC DIRECTIONS: Apply in the Fall after beginning of the wet season. harvest. Bacterial blight, Berry 3 to 8 qts. Use Restrictions: Do not apply more than 2 Ibs. of copper (10.2 spot, Leaf spot, Leaf rust qts. of this product) per acre per application. Do not apply more than SPECIFIC DIRECTIONS: Apply as locally recom- 10 Ibs. of copper (51 qts. of this product) per acre per year. Minimum mended, usually at 2- to 4-week intervals depend- retreatment interval is 10 days. ing upon disease severity and rainfall conditions. Cherries Deadbud, Coryneum 6 qts. per 100 gals. Use Restrictions: Do not apply more than 2.1 Ibs. of copper (10.7 blight of water qts. of this product) per acre per application. Do not apply more than (Not to exceed the 12.6 Ibs. of copper (61.2 qts. of this product) per acre per year. Min- maximum allowable imum retreatment interval is 14 days. rate per acre per Cranberries Fruit rot 8qts. application specified SPECIFIC DIRECTIONS: Apply beginning in late under "Use bloom. One or two additional applications made at Restrictions') 7- to 14-day intervals may be required depending SPECIFIC DIRECTIONS: Apply in October (before upon disease pressure. Follow the advice of the heavy Fall rains) and again in January. Where dis- State Agricultural Extension Service. ease is severe, another application should be ap- plied in August. Use Restrictions: Do not apply more than 2.1 Ibs. of copper (10.7 qts. of this product) per acre per application. Do not apply more than Brown rot blossom blight 2 to 3 qts. per 100 6.3 Ibs. of copper (32 Ibs. of this product) per acre per year. Mini- gals. of water mum retreatment interval is 7 days. (Not to exceed the maximum allowable Currants, Anthracnose, Leaf spot 5 to 10 qts. Gooseberries (cane blight) rate per acre per application specified under "Use SPECIFIC DIRECTIONS: Make 3 applications starting after harvest, before bloom and after petal fall. Restrictions') SPECIFIC DIRECTIONS: Apply as a full cover spray at popcorn stage and at full bloom. Use Restrictions: Do not apply more than 2.5Ibs. of copper (12.7 qts. of this product) per acre per application. Do not apply more than 10 Ibs. of copper (51 qts. of this product) per acre per year. Minimum Use Restrictions: During the dormant or late dormant period, do retreatment interval is 10 days. not apply more than 8 Ibs. of copper (40.8 qts. of this product) per acre per application. Minimum retreatment interval is 7 days. During the bloom or growing period, do not apply more than 1.5Ibs. of cop- per (7.65 qts. of this product) per acre per application. Minimum re- treatment interval is 5 days. Do not apply more than 18 Ibs. of copper (91.8 qts. of this product) Filberts Bacterial blight 10 to 12 qts. (ORand WA SPECIFIC DIRECTIONS: Apply after harvest. only) Under severe conditions, apply again when three- fourths of the leaves have dropped. (Continued) per acre per year. KOP-AM Complex Page 4 of 20

( ( FRUIT AND NUT CROPS Crop Disease Controlled Rate of This Product per Acre . Crop Disease Controlled Rate of This Product per Acre Filberts Eastern filbert blight 10 to 12 qts. Peaches, Bacterial spot 2 qts. per 100 gals. (ORand WA SPECIFIC DIRECTIONS: Make initial application Nectarines of water only) after harvest in October before heavy rains begin. (Not to exceed the (Con!.) The next application should be made in late Feb- maximum allowable ruary to early March followed by another applica- rate per acre per tion 1 month later. If desired, add 1 pint of a sticking application specified agent or superior type oil per 100 gallons of water. under "Use Use higher rate when rainfall is heavy and disease Restrictions', pressure is high. SPECIFIC DIRECTIONS: Apply as a dormant Use Restrictions: Do not apply more than 6 Ibs. of copper (30.6 spray. Make post-bloom application at 0.5 pt. per qts. of this product) per acre per application. Do not apply more than 100 gallons at first and second cover sprays. DO 24 Ibs. of copper (122.4 qts. of this product) per acre per year. Min- NOT spray later than 3 weeks prior to harvest. DO imum retreatment interval is 14 days. Permitted only in Oregon and NOT use at rates above those specified. Washington. Note: Slight defoliation and spotting of leaves may Grapes Anthracnose, Black rot, 2 qts. Downy mildew, Powdery occur from use in cover sprays. Blossom brown rot 8 to 12 qts. mildew SPECIFIC DIRECTIONS: Apply as dormant or de- SPECIFIC DIRECTIONS: Apply just before bud layed-dormant spray. Can use with dormant spray break, when the shoots are 6 to 8 inches long, just oil. DO NOT apply at or after full bloom. after bloom and every 3- to 10-days throughout Leaf curl, Shot hole 8 to 12 qts. season as needed. Foliar injury may occur on cop- per-sensitive varieties. Use Restrictions: Do not apply more than 3 Ibs. of copper (15.3 SPECIFIC DIRECTIONS: Apply at leaf fall to pro- tect buds and shoots from infection during rainy pe- riods. Reapply up until late bud swell. DO NOT qts. of this product) per acre per application. Do not apply more than apply after full bloom. 20 Ibs. of copper (102 qts. of this product) per acre per year. Mini- mum retreatment interval is 3 days. Hops Downy mildew 2 qts. Use Restrictions: During the dormant or late dormant period, do not apply more than 8 Ibs. of copper (40.8 qts. of this product) per acre per application. Minimum retreatment interval is 7 days. During SPECIFIC DIRECTIONS: Apply as needed at 10- the bloom or growing period, do not apply more than 1.5Ibs. of cop- day intervals. Begin with crown treatment (after per (7.65 qts. of this product) per acre per application. Minimum re- pruning but before training) and continue until 2 treatment interval is 5 days. weeks before harvest. Do not apply more than 18 Ibs. of copper (91.8 qts. of this product) Use Restrictions: Do not apply more than 0.53 lb. of copper (2.7 per acre per year. qts. of this product) per acre per application. Do not apply more than Pears, Quince Fire blight 1 to 2 qts. 2.65 Ibs. of copper (13.5 qts. of this product) per acre per year. Min- imum retreatment interval is 10 days. SPECIFIC DIRECTIONS: Apply at 10% bloom and repeat at 5- to 7 -day intervals throughout the bloom Kiwi Pseudomonas syringea, 8 qts. period. Do not use on copper-sensitive varieties. Erwinia herbicola, Blossom blast 8 to 12 qts. Pseudomonas f/uorescens SPECIFIC DIRECTIONS: Apply in 200 gallons of water per acre. Make applications on a monthly SPECIFIC DIRECTIONS: Apply as a dormant spray. Apply only at bud break to control primary infection. basis. A maximum of 3 applications may be made. Use Restrictions: During the Fall or late dormant period, do not Use Restrictions: Do not apply more than 2.1 Ibs. of copper (10.7 apply more than 8 Ibs. of copper (40.8 qts. of this product) per acre qts. of this product) per acre per application. Do not apply more than per application. Only one application is permitted per season. Dur- 6.3 Ibs. of copper (32 qts. of this product) per acre per year. Mini- ing the bloom or growing period, do not apply more than 0.5 lb. of mum retreatment interval is 30 days. copper (2.5 qts. of this product) per acre per application. Minimum Limes Greasy spot 8 qts. retreatment interval is 5 days. SPECIFIC DIRECTIONS: Apply in June and con- Do not apply more than 16 Ibs. of copper (81.6 qts. of this product) tinue at 7-day intervals through August. per acre per year. Use Restrictions: Do not apply more than 3.15 Ibs. of copper (16 Pecans Shuck and Kernel rot, 4 to 10 qts. qts. of this product) per acre per application. Do not apply more than Zonate leaf spot 10 Ibs. of copper (51 qts. of this product) per acre per year. Minimum SPECIFIC DIRECTIONS: For suppression, apply retreatment interval is 7 days. in sufficient water to ensure complete spray cover- Mangoes Anthracnose 8 qts. age at 2- to 4-week intervals starting at kernel (Not for Use SPECIFIC DIRECTIONS: Apply monthly from the inCA) time the panicles are 2 inches in length until all growth and continuing until shucks open. Use the higher rate and shorter interval if frequent rainfall fruits are set until August. Use Restrictions: Do not apply more than 2.6 Ibs. of copper (13.2 qts. of this product) per acre per application. Do not apply more than 18.2 Ibs. of copper (92.8 qts. of this product) per acre per year. Min- imum retreatment interval is 30 days. Olives Peacock spot 8 to 12 qts. OR occurs. Use Restrictions: Do not apply more than 2.1 Ibs. of copper (10.7 Ibs. ofthis product) per acre per application. Do not apply more than 8.4 Ibs. of copper (42.8 qts. of this product) per acre per year. Min- imum retreatment interval is 14 days. Pistachios Alternaria late blight 8 to 10.7 qts. SPECIFIC DIRECTIONS: Apply at 50% and full 2 to 3 qts. per 100 gals. of water bloom followed by up to 3 applications at 30-day intervals. SPECIFIC DIRECTIONS: Make first application be- (Continued) fore Winter rains fall. A second application should be made in early Spring if disease is severe. Use Restrictions: Do not apply more than 3.15 Ibs. of copper (16 qts. of this product) per acre per application. Do not apply more than 6.3 Ibs. of copper (32 qts. of this product) per acre per year. Mini- mum retreatment interval is 30 days. KOP-AM Complex Page 5 of 20

( " ( FRUIT AND NUT CROPS FIELD AND VEGETABLE CROPS Crop Disease Controlled Rate of This Product per Acre Rate of This Crop Disease Controlled Product per Pistachios Botrytis blight, 8 to 10,7 qts, Acre (Cont.) Botryosphaeria panicle, Shoot blight, Septoria leaf blight SPECIFIC DIRECTIONS: Make initial application at bud swell and repeat on a 14- to 28-day sched- ule as dictated by disease conditions, If disease conditions are severe, use the higher rate and shorter interval. Alfalfa Leaf spot 1 to 2 qts. SPECIFIC DIRECTIONS: Apply by ground or air 10 to 14 days prior to harvest. Slight injury may occur to sensitive varieties. Use Restrictions: Do not apply more than 0.53 Ibs. of copper (2.7 qts. of this product) per acre per application. Do not apply more than 1.12 Ibs. of copper (5.7 qts. of this product) per acre per year. Min- Use Restrictions: Do not apply more than 2,1 Ibs. of copper (10.7 Ibs, of this product) per acre per application. Do not apply more than 8.4 Ibs. of copper (42.8 qts. of this product) per acre per year. Min- imum retreatment interval is 14 days. Plums, Brown rot blossom blight, 8 to 12 qts. Prunes Coryneum blight (shot imum retreatment interval is 30 days. Beans, Lentils, Bacterial blight (halo and 1 to 3 qts. Peas common) (succulent and SPECIFIC DIRECTIONS: Apply when plants dry) are 3 to 5 inches high and before diseases ap- pear. Repeat at 7- to 10-day intervals. hole) Use Restrictions: Do not apply more than 0.79 Ibs. of copper (4 SPECIFIC DIRECTIONS: Apply as a dormant qts. of this product) per acre per application. Do not apply more than spray before heavy rains begin. For Brown rot, apply at early green bud to full popcorn stages. Bacterial blast, Bacterial 8 to 12 qts. canker 4.74 Ibs. of copper (24 qts. of this product) and 3.95 Ibs. of copper (20 qts. of this product) per acre per year for beans and peas, re- spectively. Minimum retreatment interval is 7 days. Beets, Sugar Cercospora leaf spot 1.5 to 3 qts. SPECIFIC DIRECTIONS: Apply at dormant to beets SPECIFIC DIRECTIONS: Apply when disease early pink stage. Where disease is severe, apply 1 quart at 2-week intervals post-bloom. Slight leaf in- jury may occur. appears making 3 to 6 sprays at 10- to 14-day intervals. Apply more frequently under severe disease pressure. Use Restrictions: During the dormant or late dormant period, do Use Restrictions: Do not apply more than 1.31 Ibs. of copper (6.6 not apply more than 8 Ibs. of copper (40.8 qts. of this product) per qts. of this product) per acre per application. Do not apply more than acre per application. Minimum retreatment interval is 7 days. During 7.86Ibs. of copper (40 qts. of this product) per acre per year. Mini- the bloom or growing period, do not apply more than 1.5Ibs. of cop- mum retreatment interval is 10 days, per (7.65 qts. of this product) per acre per application. Minimum re- Carrots Early and Late blight 2 to 3 qts, treatment interval is 5 days. Do not apply more than 18 Ibs. of copper (91.8 qts. of this product) SPECIFIC DIRECTIONS: Apply when plants are 6 inches high. Make 3 to 5 applications at per acre per year. 7- to 10-day intervals. Strawberries Leaf spot, Scorch 1.5 to 2 qts. (7.6 qts.- Severe disease) SPECIFIC DIRECTIONS: Apply at 7- to 10-day in- tervals from the time new growth starts until har- vest. Use Restrictions: Do not apply more than 1 lb. of copper (5 qts. of this product) per acre per application. For severe infection, do not apply more than 1.5 Ibs. of copper (7.6 qts. of this product) per acre per application. Do not apply more than 8.19 Ibs. of copper (41.7 qts. of this product) per acre per year. Minimum retreatment interval is 7 days. Walnuts Walnut blight I 8 to 12 qts, SPECIFIC DIRECTIONS: Make first application at early pre-bloom. Make second application at late pre-bloom. Make additional applications if disease conditions persist. Use Restrictions: Do not apply more than 3.15 Ibs. of copper (16 qts. of this product) per acre per application. Do not apply more than 25.2 Ibs, of copper (128.5 qts. of this product) per acre per year. Use Restrictions: Do not apply more than 1 lb. of copper (5 qts. of this product) per acre per application. Do not apply more than 5 Ibs. of copper (25.5 qts. of this product) per acre per year. Minimum re- treatment interval is 7 days. Celery Bacterial blight, Early and 2 to 3 qts. Late blight SPECIFIC DIRECTIONS: Apply as soon as plants are established in the field and repeat at 7 -day intervals. Use Restrictions: Do not apply more than 1 lb. of copper (5 qts. of this product) per acre per application. Do not apply more than 5.3 Ibs. of copper (27 qts. of this product) per acre per year. Minimum retreatment interval is 7 days. Corn Bacterial rot, Bacterial 2 qts. (field, pop, sweet) stripe, Bacterial wilt, Leaf blight, Stalk rot SPECIFIC DIRECTIONS: Apply when disease appears and repeat as necessary, Use Restrictions: Do not apply more than 1.05 Ibs. of copper (5.3 Minimum retreatment interval is 7 days. qts. of this product) per acre per application. Do not apply more than 4.2 Ibs. of copper (21.4 qts. of this product) per acre per year. Min- imum retreatment interval is 7 days. Crucifers Black leaf spot, Black rot 1 to 2.7 qts. [Broccoli, SPECIFIC DIRECTIONS: Apply by ground or Brussels sprouts, air when disease appears and repeat at 7- to Cabbage, 10-day intervals. Cauliflower, Downy mildew 0.5 to 1 qt. Greens SPECIFIC DIRECTIONS: Apply by ground or (collard, mustard, turnip)] air when disease appears and repeat at 7- to 10-day intervals. Use Restrictions: Do not apply more than 0.53 lb. of copper (2,7 qts. of this product) per acre per application. Do not apply more than 2.65Ibs. of copper (13.5 qts. of this product) per acre per year. Min- imum retreatment interval is 7 days. (Continued) KOP-AM Complex Page 6 of 20

( FIELD AND VEGETABLE CROPS Rate of This. Rate of This Crop Disease Controlled Product per Crop Disease Controlled Product per Acre Acre Cucurbits, Alternaria leaf spot, Angular 1.5 to 2 qts. Spinach Anthracnose, Cercospora 1.5 qts. (Cantaloupe, leaf spot, Anthracnose, leaf spot, Downy mildew Cucumber, Downy mildew, Powdery SPECIFIC DIRECTIONS: Apply on first ap- Honeydew, mildew, Gummy stem blight, pearance of disease and repeat at 7- to 10-day Muskmelon, Watermelon bacterial fruit intervals. Pumpkin, Squash, blotch Watermelon) SPECIFIC DIRECTIONS: Apply by ground or air when disease appears and repeat at 5- to 10-day intervals. Use Restrictions: Do not apply more than 1.05Ibs. of copper (5.3 qts. of this product) per acre per application. Do not apply more th~n 5.25 Ibs. of copper (26.7 qts. of this product) per acre per year. Min- imum retreatment interval is 5 days. Eggplant Alternaria blight, 2 qts. Anthracnose, Phomopsis SPECIFIC DIRECTIONS: Apply before dis- ease appears and repeat at 7- to 1 O-day inter- vals. Use Restrictions: Do not apply more than 0.79 lb. of copper (4 qts. of this product) per acre per application. Do not apply more than 3.95 Ibs. of copper (20 qts. of this product) per acre per year. Mini- mum retreatment interval is 7 days. Tobacco Angular leaf spot 4 to 5 qts. SPECIFIC DIRECTIONS: Apply on a 10-day basis when disease appears. Destroy all in- fected plants. Blue mold 2 qts. SPECIFIC DIRECTIONS: Apply every 10 days when disease appears. Brown spot 4 to 5 qts. Use Restrictions: Do not apply more than 0.79 lb. of copper (4 qts. SPECIFIC DIRECTIONS: Apply every 10 days of this product) per acre per application. Do not apply more than 7.9 when disease appears. Ibs. of copper (40.3 qts. of this product) per acre per year. Minimum Damping-off disease 5to 6 qts. retreatment interval is 7 days. SPECIFIC DIRECTIONS: Apply to the seed Onions Downy mildew, Purple 2 qts. bed after planting. Avoid overwatering. blotch Frog eye disease I 4 to 5 qts. SPECIFIC DIRECTIONS: Apply when plants are 4 to 6 inches high and repeat at 7- to 10- SPECIFIC DIRECTIONS: Apply just before transplanting and when topped. day intervals. Use Restrictions: Do not apply more than 1 lb. of copper (5 qts. of this product) per acre per application. Do not apply more than 6 Ibs. of copper (30.6 Ibs. of this product) per acre per year. Minimum re- treatment interval is 7 days. Peanuts Cercospora leaf spot I 1.5 to 3 qts. SPECIFIC DIRECTIONS: Apply on first ap- pearance of disease and repeat at 7- to 14-day intervals. Pod rot complex (Pythium I 4 qts. myriotylum, Rhizoctonia solani and Sclerotium ralfsii) SPECIFIC DIRECTIONS: Apply at pegging in a 12- to 15-inch band over the row. Use Restrictions: Do not apply more than 0.79Ib. of copper (4 qts. of this product) per acre per application. Do not apply more than 4.74 Ibs. of copper (24 qts. of this product) per acre per year. Mini- mum retreatment interval is 7 days. Wildfire 1 2 qts. SPECIFIC DIRECTIONS: Apply every 10 days from seeding to transplanting. Use Restrictions: Do not apply more than 2 Ibs. of copper (10.2 qts. of this product) per acre per application. Do not apply more than 8 Ibs. of copper (40.8 qts. of this product) per acre per year. Mini- mum retreatment interval is 10 days. Tomatoes Bacterial speck, Bacterial 11.5 to 2.7 qts. spot, Early and Late blight SPECIFIC DIRECTIONS: Make first applica- tion upon emergence of seedlings or immedi- ately after transplanting and repeat at 3- to 10-day intervals. When disease is severe, apply at 3- to 5-day intervals. Complete cover- age is essential for disease control. Note: While the labeled rate is particularly ef- fective against Bacterial spot, a tank mix with Maneb or Mancozeb used at the labeled rates Peppers Bacterial spot, Cercospora 11.5 to 3 qts. leaf spot SPECIFIC DIRECTIONS: Make first applica- tion upon emergence of seedlings or immedi- ately after transplanting and repeat at 7- to 10-day intervals. When disease is severe, apply at 4- to 5-day intervals. Note: Disease control is critical during fruiting. Use Restrictions: Do not apply more than 0.79 lb. of copper (4 qts. of this product) per acre per application. Do not apply more than 11.85 Ibs. of copper (60.5 qts. of this product) per acre per year. controls a broad range of diseases. Use Restrictions: Do not apply more than 0.53 lb. of copper (2.7 qts. of this product) per acre per application. Do not apply more than 17.4lbs. of copper (88.7 qts. ofthis product) per acre per year. Min- imum retreatment interval is 3 days. Wheat, Oats, Helminthosporium spot 1 1.5 to 2 qts. Barley blotch, Septoria leaf blotch SPECIFIC DIRECTIONS: Make first applica- tion at early heading and follow with second spray 10 days later. Use the higher rate when conditions favor disease. Minimum retreatment interval is 3 days. Potatoes Early and Late blight I 1.5 to 3 qts. SPECIFIC DIRECTIONS: Apply on first ap- pearance of disease and continue on 5- to 10- day intervals. Use Restrictions: Do not apply more than 2.5 Ibs. of copper (12.7 qts. of this product) per acre per application. Do not apply more than 25 Ibs. of copper (127.5 qts. of this product) per acre per year. Min- Bacterial wilt, Head scab I 2 qts. SPECIFIC DIRECTIONS: Apply when disease appears and repeat as necessary. Use Restrictions: Do not apply more than 0.53 lb. of copper (2.7 qts. of this product) per acre per application. Do not apply more than 1.06 Ibs. of copper (5.4 qts. of this product) per acre per year. Min- imum retreatment interval is 10 days. imum retreatment interval is 5 days. KOP-AM Complex Page 7 of 20

( ( MISCELLANEOUS Rate of Rate of Crop Disease Controlled This Product Crop Disease Controlled This Product per Acre per Acre Atemoya, Anthracnose 3 qts. Guava Anthracnose, Red algae 3 qts. Carambola SPECIFIC DIRECTIONS: Make initial application SPECIFIC DIRECTION: Make initial application just before flowering and repeat on a weekly just before flowering and repeat on a weekly schedule until just before harvest. Apply in suffi- schedule until just before harvest. Apply in suffi- cient water for thorough coverage. cient water for thorough coverage. Use Restrictions: Do not apply more than 3.15 Ibs. of copper (16 Use Restrictions: Do not apply more than 1.23 Ibs. of copper (6.2 qts. of this product) for Atemoya and 2.1 Ibs. of copper (10.7 qts. of qts. of this product) per acre per application. Do not apply more than this product) for Carambola per acre per application. Do not apply 4.92 Ibs. of copper (25 qts. of this product) per acre per year. Mini- more than 12.6 Ibs. of copper (64.2 qts. of this product) and 10.5 Ibs. mum retreatment interval is 7 days. of copper (53.5 qts. of this product) per acre per year for Atemoya and Carambola, respectively. Minimum retreatment interval is 7 days. Chives Downy mildew 2 qts. Litchi Anthracnose 3 qts. SPECIFIC DIRECTION: Make initial application just before flowering and repeat on a weekly schedule until just before harvest. Apply in suffi- SPECIFIC DIRECTION: Begin applications when cient water for thorough coverage. plants are first established in the field. Repeat ap- plications every 7 to 10 days as dictated by dis- ease conditions. If disease pressure is high, use the shorter spray interval. Use Restrictions: Do not apply more than 1.23 Ibs. of copper (6.2 qts. of this product) per acre per application. Do not apply more than 4.92 Ibs. of copper (25 qts. of this product) per acre per year. Mini- mum retreatment interval is 7 days. Use Restrictions: Do not apply more than 0.53 lb. of copper (2.7 qts. of this product) per acre per application. Do not apply more than 2.65 Ibs. of copper (13.5 qts. of this product) per acre per year. Min- imum retreatment interval is 7 days. Dill Phoma leaf spot, Rhizoctonia 3 qts. foliage blight Live Oak Ball moss 6 qts. SPECIFIC DIRECTIONS: Apply in the Spring when Ball moss is actively growing, using 1.5 gal- lons of spray per foot of tree height. Make sure to wet Ball moss tufts throrughly. A second applica- tion may be required after 12 months. SPECIFIC DIRECTIONS: Begin applications Note: This product may be injurious to ornamen- when plants are first established in the field and tals grown under Live oaks. This product may be repeat at 7- to 10-day intervals depending upon reactive on metal and masonry surfaces such as disease severity and environmental conditions. If galvanized roofing. Avoid contact with metal sur- disease pressure is high, use the shorter spray faces. Do not spray on cars, houses, lawn furni- interval. ture, etc. Use Restrictions: Do not apply more than 0.79 lb. of copper (4 qts. Use Restrictions: Do not apply more than 2 Ibs. of copper (10.2 of this product) per acre per application. Do not apply more than qts. of this product) per acre per application. Do not apply more than 3.95 Ibs. of copper (20 qts. of this product) per acre per year. Mini- 20 Ibs. of copper (102 qts. of this product) per acre per year. Mini- mum retreatment interval is 7 days. mum retreatment interval is 7 days. Douglas fir Rhabdocline needlecast 2 qts. Macadamia Anthracnose 6 qts. SPECIFIC DIRECTIONS: Begin applications at SPECIFIC DIRECTIONS: Initiate spray at first bud break and repeat at 1- to 4-week intervals. sign of flowering and repeat on a weekly sched- Apply in a tank mix with another registered pesti- ule until just before harvest. Apply in sufficient cide if moderate to severe disease pressure is water for thorough coverage. present. Use Restrictions: Do not apply more than 2 Ibs. of copper (10.2 qts. of this product) per acre per application. Do not apply more than 20 Ibs. of copper (102 qts. of this product) per acre per year. Mini- mum retreatment interval is 7 days. Ginseng Alternaria leaf and stem blight I 3.5 qts. SPECIFIC DIRECTIONS: Use as a tank mix with 2 pounds Rovral 50W in 100 gallons of water. Begin applications of this tank mix as soon as plants have emerged in Spring. Applications should be repeated every 7 days until plants be- come dormant in Fall. If scheduled application is to be before a rain shower, apply fungicides at least 8 hours before the rain, giving the fungicides time to dry on the plants. Use of a spreader- Phytophthora blight, Raceme 4 to 6 qts. blight SPECIFIC DIRECTIONS: Apply during raceme development and bloom periods. Apply in suffi- cient water for thorough coverage. Use Restrictions: Do not apply more than 2.36 Ibs. of copper (12 qts. of this product) per acre per application. Do not apply more than 9.44 Ibs. of copper (48 qts. of this product) per acre per year. Mini- mum retreatment interval is 7 days. Mamey sapote Anthracnose, Algal leaf spot 6 to 8 qts. SPECIFIC DIRECTIONS: Apply when conditions favor disease. Repeat on 14- to 30- day schedule as disease severity and environmental conditions dictate. sticker is advised. Use Restrictions: Do not apply more than 2.1 Ibs. of copper (10.7 Note: Alternaria leaf and stem blight are most se- qts. of this product) per acre per application. Do not apply more than vere in humid conditions such as those found in 8.4 Ibs. of copper (42.8 qts. of this product) per acre per year. Min- the dense canopies of 2-, 3- and 4-year old Gin- imum retreatment interval is 14 days. seng. It is very important that the stems be thor- Papaya Anthracnose I 4 to 10 qts. oughly covered with fungicide; therefore, use a spray apparatus which distributes the fungicide throuqhout the canODV. Use Restrictions: Do not apply more than 1.05 Ibs. of copper (5.3 SPECIFIC DIRECTIONS: Begin applications be- fore disease appears and repeat at 14-day inter- vals. Use higher rates when conditions favor disease. qts. of this product) per acre per application. Do not apply more than 5.25Ibs. of copper (26.7 qts. of this product) per acre per year. Min- imum retreatment interval is 7 days. Use Restrictions: Do not apply more than 2.63 Ibs. of copper (13.4 qts. of this product) per acre per application. Do not apply more than 21.2 Ibs. of copper (108 qts. of this product) per acre per year. Min- imum retreatment interval is 14 days. (Continued) KOP-AM Complex Page 8 of 20

(' \ MISCELLANEOUS Rate of Crop Disease Controlled This Product per Acre Parsley Bacterial blight 3 qts. SPECIFIC DIRECTIONS: Begin applications when plants are first established in the field and repeat at 10 day intervals depending upon dis- ease severity and environmental conditions. Use Restrictions: Do not apply more than 1 lb. of copper (5 qts. of this product) per acre per application. Do not apply more than 2 Ibs. of copper (10 qts. of this product) per acre per year. Minimum re- treatment interval is 10 days. Passion fruit Anthracnose 6 qts. SPECIFIC DIRECTIONS: Make initial application just before flowering and repeat on a weekly schedule until just before harvest. Apply in suffi- cient water for thorough coverage. Use Restrictions: Do not apply more than 2.36 Ibs. of copper (12 qts. of this product) per acre per application. Do not apply more than 9.44 Ibs. of copper (48 qts. of this product) per acre per year. Mini- mum retreatment interval is 7 days. Sugar apples Anthracnose 8 to 12 qts. (Annona) SPECIFIC DIRECTIONS: Make initial application just before flowering and repeat on a weekly schedule until just before harvest. Apply in suffi- cient water for thorough coverage. Use Restrictions: Do not apply more than 3.15 Ibs. of copper (16 qts. of this product) per acre per application. Do not apply more than 12.6 Ibs. of copper (64.2 qts. of this product) per acre per year. Min- imum retreatment interval is 7.days. Sycamore Anthracnose 2 to 3 qts. SPECIFIC DIRECTIONS: Apply as a full cover- age spray. Apply in 100 gallons of water or suffi- cient volume for thorough coverage. Make first application at bud crack and second application 7 to 10 days later at 10% leaf expansion. Use Restrictions: Do not apply more than 2 Ibs. of copper (10.2 qts. of this product) per acre per application. Do not apply more than 20 Ibs. of copper (102 qts. of this product) per acre per year. Mini- mum retreatment interval is 7 days. CITRUS (Field Nursery Grown) To control Brown rot, Citrus canker (suppression only), Greasy spot, Melanose, Pink pitting and Scab, apply 2 quarts of this product per 100 gallons of water (4 to 8 qts'/A). Apply this product at minimum 7- day intervals depending on disease severity. Use Restrictions: Do not apply more than 3.15 Ibs. of copper (16 qts. of this product) per acre per application. Do not apply more than 10 Ibs. of copper (51 qts. of this product) per acre per year. Minimum re­ treatment interval is 7 days. TURFGRASS To control Algae in Turfgrass, apply 0.7 pint of this product per 1,000 square feet in 5 gallons of water. This product may be used alone or in combination with other registered fungicides as a maintenance spray. Observe all precautions and limitations on the label of each product used in tank mixes. Use Restrictions: Do not apply more than 3 Ibs. of copper (30.6 pts. of this product) per acre (0.7 pt. per 1,000 sq. ft.) per application. Do not apply more than 9 Ibs. of copper (91.8 pts. of this product) per acre (2.1 pts. per 1,000 sq. ft.) per year. Minimum retreatment interval is 10 days. Note: Phytotoxicity may occur depending upon varietal differences. Apply the specified rate to a small area and observe for 7 to 10 days for signs of injury. If phytotoxicity occurs, discontinue use. Do not apply in a spray solution with a pH of less than 6.5. GREENHOUSE AND SHADE HOUSE CROPS Notice to User: This product may be used in greenhouses and shade houses to control diseases on some crops which appear on this label. The grower should bear in mind that the sensitivity of crops grown in greenhouses and shade houses differ greatly from crops grown under· field conditions. Neither the Manufacturer nor the Seller has deter­ mined whether or not this product can be used safely on all green- ( house and shade house-grown crops. The user should determine if this product can be used safely prior to commercial use. In a small area, apply the specified riltes to tlie plants in question, i.e., foliage, fruit, etc., and observe for 7 to 10 days for symptoms of phytotoxicity prior to commercial use Crop Diseases Rate of Application Eggplant Alternaria blight, 4 tbsps. per Anthracnose, Phomopsis 1,000 sq. ft. SPECIFIC DIRECTIONS: Begin applications prior to development of disease symptoms. Re- peat spray at 7- to 10-day intervals. Use Restrictions: Do not apply more than 3 fl. ozs. (6 tbsps.) of this product per 1,000 sq. ft. per application. Do not apply more than 29.6 fl. ozs. (59 tbsps.) of this product per 1,000 sq. ft. per year. Min- imum retreatment interval is 7 days. Peppers Bacterial spot 4 to 6 tbsps. per 1,000 sq. ft. SPECIFIC DIRECTIONS: Begin applications when conditions first favor disease development and repeat at 3- to 10-day intervals as needed depending on disease severity. Use higher rate for severe disease. Use Restrictions: Do not apply more than 3 fl. ozs. (6 tbsps.) of this product per 1,000 sq. ft. per application. Do not apply more than 44.4 fl. ozs. (88.8 tbsps.) of this product per 1,000 sq. ft. per year. Minimum retreatment interval is 3 days. Tomatoes Early and Late blight, 4 tbsps. per Bacterial speck, Anthracnose, 1,000 sq. ft. Bacterial spot, Gray leaf mold, Septoria leaf spot SPECIFIC DIRECTIONS: Begin applications when disease first threatens and repeat at 3 to 10-day intervals depending on disease severity. Use Restrictions: Do not apply more than 2 fl. ozs. (4 tbsps.) of this product per 1,000 sq. ft. per application. Do not apply more than 65.2 fl. ozs. (130 tbsps.) of this product per 1,000 sq. ft. per year. Minimum retreatment interval is 3 days. Citrus Brown rot, Citrus canker, 6 tbsps. per (non-bearing Greasy spot, Melanose, Pink 1,000 sq. ft. nursery) pitting, Scab SPECIFIC DIRECTIONS: Begin applications when disease threatens. Repeat at 7 to 30-day intervals depending on disease severity. Use Restrictions: Do not apply more than 11.8 fl. ozs. (23.6 tbsps.) of this product per 1,000 sq. ft. per application. Do not apply more than 47.2 fl. ozs. (94.5 tbsps.) of this product per 1,000 sq. ft. per year. Minimum retreatment interval is 7 days. 1 fl. oz. = 2 tablespoonsful ORNAMENTALS Notice to User: Plant sensitivities to this product have been found to be acceptable in specific genera and species listed on this label; how­ ever, it is impossible to know sensitivities under all conditions and phy­ totoxicity may occur. Due to the large number of species and varieties of ornamentals and nursery plants, it is impossible to test every one for sensitivity to this product. Neither the Manufacturer nor Seller recom­ mends use upon species not listed on the label, nor has it been de­ termined that this product can be safely used on omamental or nursery plants not listed on this label. The user should determine if this prod­ uct can be used safely prior to commercial use. Use this product on container, bench or bed-grown ornamentals in greenhouses, shade houses or outdoor nurseries, for professional use on ornamentals grown in indoor and outdoor landscaping and for con­ trol of bacterial and fungal diseases of foliage, flowers and stems. Apply as a thorough coverage spray using sufficient water and rate not exceeding the maximum allowable per acre per application stated below under "Use Restrictions'. Begin application at first sign of dis­ ease and repeat at 7- to 14-day intervals as needed. Use shorter in­ terval during periods of frequent rains or when severe disease conditions persist. This product may be used alone or in combination with other regis­ tered fungicides as a maintenance spray. Observe all precautions and limitations on the label of each product used in tank mixes. KOP-AM Complex Page 9 of 20 \ ~ 2l,r.

c Note: Do not lank-mix this product with Aliette fungicide unless ap­ propriate precautions have been taken to buffer the spray solution. Severe phytotoxiCity may result if adequate precautions are hot taken. Use Restrictions: On Easter Lily, do not apply more than 2.5 Ibs. of copper (12.7 qls. of this product) per acre (9.3 fl. ozs. per 1,000 sq. ft.) per application. On other ornamentals, do not apply more than 2 Ibs. of copper (10.2 qls. of this product) per acre (7.5 fl. ozs. per 1,000 sq. ft.) per application. Do not apply more than 20 Ibs. of copper (102 qts. of this product) per acre (75 fl. ozs. per 1,000 sq. ft.) per year. Minimum retreatment interval is 7 days. Crop Latin name Disease Althaea Hibiscus syriacus Bacterial leaf spot (Rose of Sharon) Aralia Dizygotheca Alternaria, elegantissima Cercospora leaf spot, Xanthomonas leaf spot Arborvitae Thuja spp. Alternaria twig blight, Cercospora leaf blight Azalea' Rhododendron Botrytis blight, spp. Cercospora leaf spot, Phytophthora dieback, Powdery mildew Begonia Begonia Bacterial leaf spot semperf/orens (Emina sp., Pseudomonas sp., Xanthomonas spp.) Bougainvillea Bougainvillea Anthracnose, Bacterial spectabilis leaf spot Bulbs - Anthracnose, Botrytis (Tulip, Gladiolus) blight Camellia Camellia japonica, Anthracnose, Bacterial C. sasanqua leaf spot Camphor tree Cinnamomum Pseudomonas leaf camphora spot Canna Canna spp. Pseudomonas leaf spot Carnation' Dianthus spp. Alternaria blight, Botrytis blight, Pseudomonas leaf spot Chinese tallow tree Sapium sebiferum Bacterial leaf spot (Pseudomonas spp., Xanthomonas spp.) Chrysanthemum' Chrysanthemum Botrytis blight, morifolium Septoria leaf spot Cotoneaster Cotoneaster spp. Botrytis blight Dahlia Dahlia pinnata Alternaria leaf spot, Botrytis gray mold, Cercospora leaf spot Date palm Phoenix Pestalotia leaf spot canariensis Dianthus Dianthus spp. Bacterial soft rot, Bacterial spot Dogwood Comus florida Anthracnose Dusty miller Senecio cineraria Bacterial leaf spot (Pseudomonas cichorii) Easter lily2 . Ulium longiflorum Botrytis blight Echinacea Echinacea spp. Bacterial leaf spot (Pseudomonas cichorii) Elm "Drake" Ulmus parvifolia Xanthomonas leaf spot Euonymus Euonymus spp. Anthracnose, Botrytis blight European fan palm Chamaerops Pestalotia leaf spot humilis Gardenia Gardenia Alternaria leaf spot, jasminoides Botrytis bud rot, Cercosoora leaf sj)ot ( Crop Latin name Disease Geranium Pelargonium spp. Alternaria leaf spot, Botrytis gray mold, Cercospora leaf spot Gladiolus Gladiolus spp. Alternaria leaf spot, Bacterial leaf blight, Botrytis gray mold Goldenrain tree Koelreuteria Bacterial leaf spot paniculata Hibiscus Hibiscus Bacterial leaf spot rosa-sinensis Holly fern Cyrtomium Pseudomonas leaf falcatum spot Impatiens Impatiens Bacterial leaf spot sallerana India hawthorn 3 Rhaphiolepis Anthracnose, indica Entomosporium leaf spot Ivy Hedera helix, Xanthomonas leaf spot (English, Algerian)' H. canariensis Ixora Ixora coccinea Xanthomonas leaf spot Juniper Juniperus Anthracnose (Eastern red cedar) virginiana Lantana Lantana camara Bacterial leaf spot Lilac Syringa spp. Cercospora leaf spot Loblolly bay Gordonia Anthracnose lasianthus Loquat Eriobotrya Colletotrichum spp., japonica Entomosporium maculata Magnolia (Saucer) Magnolia Bacterial leaf spot soulangiana Magnolia Magnolia Algal leaf spot, (Southern) grandiflora Anthracnose, Bacterial leaf spot Magnolia Magnolia Anthracnose (Sweet bay) virginiana Mandevillas Mandevilla spp. Anthracnose Marigold Tagetes spp. Alternaria leaf spot, Botrytis leaf and flower rot, Cercospora leaf spot Mulberry, weeping Morusalba Bacterial leaf spot Oak, Laurel Quercus laurifolia Algal leaf spot (Cephaleuros virescens) Oleander Nerium oleander Bacterial leaf spot, Fungal leaf spot Pachysandra Pachysandra Volutella leaf blight procumbens Pansy Viola spp. Downy mildew Pear (Flowering) Pyrus calleryana Fireblight, Leaf spot Pentas Pentas spp. Bacterial leaf spot (Egyptian star) (Xanthomonas sp.) Peony Paeonia spp. Botrytis blight Periwinkle Catharanthus Phomopsis stem blight roseus, Vinca spp. Philodendron Philodendron Bacterial leaf spot. selloum Phlox Phlox spp. Alternaria leaf spot Photinia Photinia fraseri, Anthracnose, P. glabra Entomosporium Pistachio Pistacia chinen sis Anthracnose Plantain lily Hosta spp. Bacterial leaf spot Powder puff plant Calliandra spp. Bacterial leaf spot Pyracantha Pyracantha spp. Fireblight, scab Queen palm Syagrus Exosporium leaf spot, romanzoffianum Phytophthora bud rot (Continued) KOP-AM Complex Page 10 of 20

( ORNAMENTALS Crop Latin name Disease Rhododendron Rhododendron Alternaria flower spot spp. Rose' Rosa spp. Powdery mildew, Black spot Verbena Verbena spp. Xanthomonas leaf spot Viburnum Viburnum Anthracnose odoratissimum, V. suspensum Washingtonia palm Washingtonia Pestalotia leaf spot robusta Weeping willow Salix baby/onica Anthracnose Yucca Yucca spp. Cercospora leaf spot, (Adam's needle) Septoria leaf spot Note: , Discoloration of foliage and/or blooms has been noted on some varieties. To prevent residues on commercial plants, do not spray just before selling season. 2 Apply this product at 3 to 5 quarts in 20 to 100 gallons of water per acre. Also, see "Use Restrictions". 3 For India Hawthorn, use 2 to 4 quarts per 100 gallons of water or 2 to 4 level tablespoons per 3 gallons of water. FROST INJURY PROTECTION Bacterial Ice Nucleation Inhibitor - Application of this product made to all crops listed on this label at rates indicated on this label, just prior to anticipated frost conditions, will sustain control of ice nucleating bac­ teria (Pseudomonas syringae, Erwina herbico/a and Pseudomonas f1uorescens) and may therefore provide protection against light frost. Not recommended for those geographic areas where weather condi­ tions favor severe frost. TREATMENT OF WOOD BASED COMPOSITES (Except California) For treatment of composite wood products for protection from fungal decay and termite attack, this product can be applied to the furnish (fiber, flakes, chips, particles or strands) either as a solution concentrate or, al­ ternately, diluted with water. The weight percent loading on the furnish should range from 1.0% wlw to 4.0% w/w as copper ammonium acetate complex (0.26 to 1.1 % copper metal). The actual amount of copper am­ monium acetate complex to make the composite, the desired distribu­ tion of this product in the composite, and the anticipated exposure conditions end use of the composite wood product. Consult manufac­ turer for recommendations on specific products and applications. Apply the treatment solution by spraying the composite wood compo­ nent with a low-pressure sprayer. A moderately fine spray, not an aerosol or fog, generally provides the best coverage. Apply in a com­ mercial spray booth. Treatment solution may also be applied by im­ mersing the composite wood components. Immersion systems should be fully contained to recycle any excess solution. ( STORAGE AND DISPOSAL Do not contaminate water, food or feed by storage and disposal. PESTICIDE STORAGE: Store in original containers only. PESTICIDE DISPOSAL: Wastes resulting from the use of this prod­ uct may be disposed of on site or at an approved waste disposal fa­ cility. CONTAINER DISPOSAL: For liquid dilutable formulations in 5 gallon or larger nonrefill­ able containers: Nonrefillable container. Do not reuse or refill this container. Triple rinse container (or equivalent) promptly after emp­ tying. Triple rinse as follows: Empty the remaining contents into ap­ plication equipment or a mix tank. Fill the container one-quarter full with water. Replace and tighten closures. Tip container on its side and roll it back and forth, ensuring at least one complete revolution, for 30 seconds. Stand the container on its end and tip it back and forth several times. Empty the rinsate into application equipment or a mix tank or store rinsate for later use use or disposal. Repeat this procedure 2 or more times. Offer for recycling or reconditioning if available, or puncture and dispose of in a sanitary landfill, or by in­ cineration, or if allowed by State and Local authorities, by burning. If burned, stay out of smoke. For liquid dilutable formulations in nonrefillable containers smaller enough to shake (i.e., with capacities equal to or less than 5 gallons): Nonrefillable container. Do not reuse or refill this container. Triple rinse container (or equivalent) promptly after emp­ tying. Triple rinse as follows: Empty the remaining contents into ap­ plication equipment or a mix tank and drain for 10 seconds after the flow begins to drip. Fill the container one-half full with water and recap. Shake for 10 seconds. Pour rinsate into application equip­ ment or a mix tank or store rinsate for later use or disposal. Drain for 10 seconds after the flow begins to drip. Repeat this procedure two more times. Refillable Containers: Refillable container. Refill this container with pesticide only. Do not reuse this container for any other purpose. Cleaning the container before final disposal is the responsibility of the person disposing of the container. Cleaning before refilling is the responsibility of the refiller. To clean the container before final dis­ posal, empty the remaining contents from this container into appli­ cation equipment or mix tank. Fill the container about 10% full with water. Agitate vigorously or recirculate water with the pump for 2 minutes. Pour or pump rinsate into application equipment or rinsate collection system. Repeat this rinsing procedure two more times. WARRANTY- CONDITIONS OF SALE OUR DIRECTIONS FOR USE of this product are based upon tests believed reliable. Follow directions carefully. Timing and method of ap­ plication, weather and crop conditions, mixtures with other chemicals not specifically recommended and other influencing factors in the use of this product are beyond the control of the Seller. To the extent con­ sistent with applicable law, Buyer assumes all risks of use, storage and handling of this material not in strict accordance with directions given herewith. To the extent consistent with applicable law, in no case shall the Man­ ufacturer or the Seller be liable for consequential, special or indirect damages resulting from the use or handling of this product when such use and/or handling is not in strict accordance with directions given herewith. The foregoing is a condition of sale by the Seller and is ac­ cepted as such by the Buyer. KOP-AM Complex Page 11 of 20

( ( INTENDED FOR HOME AND GARDEN USE Drexet KOP·AM Complex Liquid Fungicide Spray ACTIVE INGREDIENT: Copper diammonia diacetate complex [Bis(acetato-O )diamminecopperj* 27.15% OTHER INGREDIENTS: .......................................... 72.85% TOTAL: .............................................................. 100.0% • CAS No. 13822-80-5; Metallic copper equivalent, 8.0%. This product contains 0.784 pound of Copper per gallon. KEEP OUT OF REACH OF CHILDREN CAUTION See FIRST AID Below SHAKE WELL BEFORE USING EPA Reg. No. 19713-509 EPA Est. No. 19713-XX-XXX Net Content: ___ _ FIRST AID IF IN EYES: • Hold eye open and rinse slowly and gently with water for 15 to 20 minutes. • Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. • Call a poison control center or doctor for treatment advice. IF ON SKIN OR CLOTHING: • Take off contaminated clothing. • Rinse skin immediately with plenty of water for 15 to 20 minutes. • Call a poison control center or doctor for treatment advice. IF SWALLOWED: • Call a poison control center or doctor immediately for treatment advice. • Have person sip a glass of water if able to swallow. • Do not induce vomiting unless told to do so by a poison control center or doctor. • Do not give anything by mouth to an unconscious or convulsing person. Have the product container or label with you when calling a poison control center or doctor, or going for treatment. For information on this pesticide product (including health concerns, medical emergencies or pesticide incidents), call the National Pesticide Information Center at 1-800-858-7378. PRECAUTIONARY STATEMENTS Hazards to Humans and Domestic Animals CAUTION: Harmful if swallowed. Harmful if absorbed through skin. Causes moderate eye irritation. Avoid contact with skin, eyes or clothing. Wear protective eyewear (goggles, face shield or safety glasses), clothing and chemical-resistant gloves when handling this product. Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco, or using the toilet. Remove contaminated clothing and wash clothing before reuse. Do not use food utensils such as teaspoons or tablespoons for food purposes after use with pesticides. ENVIRONMENTAL HAZARDS This pesticide is toxic to fish and aquatic invertebrates and may con­ taminate water through runoff. Do not apply directly to water. Do not contaminate water when disposing of equipment washwaters or rin­ sate. To protect the environment, do not allow pesticide to enter or run off into storm drains, drainage ditches, gutters or surface waters. Apply­ ing this product in calm weather when rain is predicted for the next 24 hours will help to ensure that wind or rain does not blow or wash pes­ ticide off the treatment area. Rinsing application over the treated area will help avoid runoff to bodies of water or drainage systems. DIRECTIONS FOR USE I! is a violation of Federal law to use this product in a manner incon­ sistent with its labeling. Do not apply this product in a way that will contact adults, children or pets, either directly or through drift. Only protected users may be in the area during application. For any re­ quirements specific to your State or Tribe, consul! the agency re­ sponsible for pesticide regulation. ENTRY RESTRICTION Do not enter or allow others to enter the treated area until sprays have dried. USE INFORMATION The control of diseases with fungicides is based on PREVENTION: plant surfaces must be completely covered with the fungicide to suc­ cessfully prevent infection. Copper pesticides are considered preven­ tative, not curative. Use the highest indicated rate per crop when disease incidence is high or expected to be, depending on rainfall and temperature. The lower rate is suitable for general and preventative sprays under normal conditions. Since the weather conditions and dis­ ease incidence vary, consult your Agricultural Extension Service for timing and initial application. Seek advice on identifying specific dis­ ease problems and solutions from your local agricultural extension agent or other knowledgeable persons. USE INSTRUCTIONS Partially fill the spray tank with water, add the desired amount of this product and continue filling the tank. If applied with other products, add this product last. Use agitation during mixing and application, until tank is empty. Good bypass agitation is adequate. Observe all pre­ cautions and limitations on labeling of all products used in mixtures. In common with all good agricultural practice, start with clean equipment; equipment should be flushed well with water after use. Note: This product may be reactive on metal and masonry surfaces such as galvanized roofing. AVOID CONTACT with metal surfaces. Do not spray on cars, houses, lawn furniture, etc. Manufactured For: Drexel Chemical Company P.O. sox 13327, MEMPHIS, TN 38113-0327 SINCE 1972 509MSP-0710' KOP-AM Complex Page 12 of 20

( FRUITS AND NUTS Mix specified rate in 1 gallon of water and apply to 500 sq. ft. Apply 3 gallons of mixed solution to a small tree or bush, 6 gallons of mixed so­ lution to a medium size tree, or 9 gallons of mixed solution to a large tree. Thoroughly spray tree to point of runoff, including upper and lower surfaces of foliage. Do not overspray. Do not mix more spray solution than needed Fruits and Rate per Disease Controlled Gallon of Nuts Water Almonds Brown rot 4 to 6 tsps. SPECIFIC DIRECTIONS: Apply at delayed- dormant' bud swell stage. Dormant oil may be used. Shot hole 4 to 6 tsps. SPECIFIC DIRECTIONS: Apply at leaf fall to protect buds and shoots from infection during rainy periods. Reapply every 3 to 4 weeks up to late bud swell. Do not apply after full bloom. Apples Anthracnose 4 to 5 tsps. SPECIFIC DIRECTIONS: Apply to foliage after harvest, annually. Apple scab (black spot), 4 to 6 tsps. Bacterial canker, Blossom and Shoot blast SPECIFIC DIRECTIONS: Apply post-harvest before Fall rains. Fireblight 0.5 to 1 tsp. SPECIFIC DIRECTIONS: Apply at 10% bloom and repeat at 5- to 7 -day intervals during bloom period. Do not use on copper sensitive vari- eties. Fireblight 4 to 6 tsps. SPECIFIC DIRECTIONS: Apply as a full cover spray between silver-tip and green-tip. Discon- tinue when green-tip reaches one-half inch as injuries may occur. Apricots Brown rot blossom blight 4 to 6 tsps. SPECIFIC DIRECTIONS: Apply at red bud to jacket fall stage. Shot hole 4 to 6 tsps. SPECIFIC DIRECTIONS: Apply at leaf fall to protect buds and shoots from infection during rainy periods. Reapply up to late bud swell. Do not apply after full bloom. Avocados Anthracnose I 4 tsps. SPECIFIC DIRECTIONS: Apply when the flower buds begin to swell and continue at monthly intervals until August. Bananas Sigatoka 1 to 2 tsps. SPECIFIC DIRECTIONS: Apply every 1 to 4 weeks. Black pitting 2.5 flo ozs. SPECIFIC DIRECTIONS: Apply directly to the fruit stem and include the basal portion of the leaf crown. Apply during the first and second weeks after fruit emergence. Blueberries Bacterial canker I 4 to 5 tsps. SPECIFIC DIRECTIONS: Apply with a spreader/sticker before Fall rains and again 4 weeks later. Cane canker I 4 to 5 tsps. SPECIFIC DIRECTIONS: Apply with a spreader/sticker before Fall rains and again 4 weeks later. In the Spring during wet weather, apply at 7- to 14-day intervals beginning at leaf emergence. ( Fruits and Rate per Disease Controlled Gallon of Nuts Water Cane berries Anthracnose, Leaf and Cane 1 to 2 tsps. spot, Purple blotch, Yellow rust SPECIFIC DIRECTIONS: Apply when leaf buds open. Repeat when flower buds show white and continue at 10- to 14-day intervals. Anthracnose, Bacterial blight, 4 to 6 tsps. Leaf and Cane spot, Purple blotch, Yellow rust SPECIFIC DIRECTIONS: Apply in the Fall after harvest. Cherries Deadbud, Coryneum blight 2 fl. ozs. SPECIFIC DIRECTIONS: Apply in October (be- fore heavy Fall rains) and again in January. Where disease is severe, another application should be applied in August. Brown rot blossom blight 4 to 6 tsps. SPECIFIC DIRECTIONS: Apply as a full cover spray at popcorn stage and at full bloom. Citrus Greasy spot, Melanose, Pink 2 to 4 tsps. pitting, Scab SPECIFIC DIRECTIONS: Apply as pre-bloom and post-bloom sprays. May be used in con- centrate sprays at equivalent rates. Brown rot 1 to 3 tsps. SPECIFIC DIRECTIONS: Apply in the Fall be- fore or just after heavy rains. In areas of skirt sprays, apply to a height of at least 4 feet. Currants, Anthracnose, Leaf spot (cane 3 to 5 tsps. Gooseberries blight) SPECIFIC DIRECTIONS: Make 3 applications starting after harvest, before bloom and after petal fall. Filberts Bacterial blight 5 to 6 tsps. SPECIFIC DIRECTIONS: Apply after harvest. Under severe conditions, apply again when three-fourths of the leaves have dropped. Eastern filbert blight 5 to 6 tsps. SPECIFIC DIRECTIONS: Make initial applica- tion after harvest in October before heavy rains begin. The next application should be made in late February to early March followed by an- other application 1 month later. If desired, add 1 pint of a sticking agent or superior type oil per 100 gallons of water. Use higher rate when rainfall is heavy and disease pressure is high. Grapes Anthracnose, Black rot, Downy 1 tsp. mildew, Powdery mildew SPECIFIC DIRECTIONS: Apply just before bud break, when the shoots are 6 to 8 inches long, just after bloom and every 3- to 10-days throughout season as needed. Foliar injury may occur on copper-sensitive varieties. Kiwi Pseudomonas syringea, 4 tsps. Erwinia herbico/a, Pseudomonas fluorescens SPECIFIC DIRECTIONS: Apply in 200 gallons of water per acre. Make applications on a monthly basis. A maximum of 3 applications may be made. Limes Greasy spot 4 tsps. SPECIFIC DIRECTIONS: Apply in June and continue at monthly intervals through August. (Continued) KOP-AM Complex Page 13 of 20

( FRUITS AND NUTS Fruits and Rate per Nuts Disease Controlled Gallon of Water Mangoes Anthracnose 4 tsps. (Not for Use in SPECIFIC DIRECTIONS: Apply monthly from CAl the time the panicles are 2 inches in length until all fruits are set until August. Olives Peacock spot 2 to 4 tsps. SPECIFIC DIRECTIONS: Make first application before Winter rains fall. A second application should be made in early Spring if disease is se- vere. Peaches, Bacterial spot 4 tsps. Nectarines SPECIFIC DIRECTIONS: Apply as a dormant spray. Make post-bloom application at 0.5 tsp. per gallon at first and second cover sprays. DO NOT spray later than 3 weeks prior to harvest. DO NOT use at rates above those specified. Note: Slight defoliation and spotting of leaves may occur from use in cover sprays. Blossom brown rot 4 to 6 tsps. SPECIFIC DIRECTIONS: Apply as dormant or delayed-dormant' spray. Can use with dormant spray oil. DO NOT apply at or after full bloom. Leaf curl, Shot hole 4 to 6 tsps. SPECIFIC DIRECTIONS: Apply at leaf fall to protect buds and shoots from infection during rainy periods. Reapply up until late bud swell. DO NOT apply after full bloom. Pears, Quince Fire blight 0.5 to 1 tsp. SPECIFIC DIRECTIONS: Apply at 10% bloom and repeat at 5- to 7 -day intervals throughout the bloom period. Do not use on copper-sensi- tive varieties. Blossom blast 4 to 6 tsps. SPECIFIC DIRECTIONS: Apply as a dormant spray. Apply only at bud break to control pri- mary infection. Pecans Shuck and Kernel rot, Zonate 2 to 5 tsps. leaf spot SPECIFIC DIRECTIONS: For suppression, apply in sufficient water to ensure complete spray coverage at 2- to 4-week intervals start- ing at kernel growth and continuing until shucks open. Use the higher rate and shorter interval if frequent rainfall occurs. Pistachios Alternaria late blight 4 to 6 tsps. SPECIFIC DIRECTIONS: Apply at 50% and full bloom followed by up to 3 applications at 30- day intervals. Botrytis blight, Botryosphaeria 4 to 6 tsps. panicle, Shoot blight, Septoria leaf blight SPECIFIC DIRECTIONS: Make initial applica- tion at bud swell and repeat on a 14- to 28-day schedule as dictated by disease conditions. If disease conditions are severe, use the higher rate and shorter interval. Plums, Prunes Brown rot blossom blight, 4 to 6 tsps. Coryneum blight (shot hole) SPECIFIC DIRECTIONS: Apply as a dormant spray before heavy rains begin. For Brown rot, apply at early green bud to full popcorn stages. Bacterial blast, Bacterial canker 4 to 6 tsps. SPECIFIC DIRECTIONS: Apply at dormant to early pink stage. ( Fruits and Rate per Nuts Disease Controlled Gallon of Water Strawberries Leaf spot, Scorch 3 to 4 tsps. SPECIFIC DIRECTIONS: Apply at 7- to 1 a-day intervals from the time new growth starts until harvest. Walnuts Walnut blight 4 to 6 tsps. SPECIFIC DIRECTIONS: Make first application at early pre-bloom. Make second application at late pre-bloom. Make additional applications if disease conditions persist. • Delayed-dormant - The period just before blossom buds break open. VEGETABLES Mix specified rate in 1 gallon of water and apply 2 gallons of mixed solution per 1,000 sq. ft. (1 gallon of mixed solution per 500 sq. ft.). Rate per Vegetables Disease Controlled Gallon of Water Beans, Lentils, Peas Bacterial blight (halo and 2 to 6 tsps. (succulent and dry) common) SPECIFIC DIRECTIONS: Apply when plants are 3 to 5 inches high and before diseases appear. Repeat at 7- to 1 a-day intervals. Beets Cercospora leaf spot 3 to 6 tsps. SPECIFIC DIRECTIONS: Apply when dis- ease appears making 3 to 6 sprays at 10- to 14-day intervals. Apply more frequently under severe disease pressure. Carrots Early and Late blight 4 to 6 tsps. SPECIFIC DIRECTIONS: Apply when plants are 6 inches high. Make 3 to 5 applications at 7- to 10-day intervals. Celery Bacterial blight, Early and 4 to 6 tsps. Late blight SPECIFIC DIRECTIONS: Apply as soon as plants are established in the field and repeat at 7 -day intervals. Corn Bacterial rot, Bacterial stripe, 4 tsps. (pop, sweet) Bacterial wilt, Leaf blight, Stalk rot SPECIFIC DIRECTIONS: Apply when dis- ease appears and repeat as necessary. Crucifers Black leaf spot, Black rot 2 to 6 tsps. [Broccoli, Brussels SPECIFIC DIRECTIONS: Apply when dis- sprouts, Cabbage, ease appears and repeat at 7- to 10-day in- Cauliflower, Greens tervals. (collard, mustard, Downy mildew 1 to 2 tsps. turnip)) SPECIFIC DIRECTIONS: Apply when dis- ease appears and repeat at 7- to 1 a-day in- tervals. Cucurbits, Alternaria leaf spot, Angular 3 to 4 tsps. (Cantaloupe, leaf spot, Anthracnose, Cucumber, Downy mildew, Powdery Honeydew, mildew, Gummy stem blight, Muskmelon, Watermelon bacterial fruit Pumpkin, Squash, blotch Watermelon) SPECIFIC DIRECTIONS: Apply when dis- ease appears and repeat at 5- to 10-day in- tervals. Eggplant Alternaria blight, 4 tsps. Anthracnose, Phomopsis SPECIFIC DIRECTIONS: Apply before dis- ease appears and repeat at 7- to 10-day in- tervals. (Continued) KOP-AM Complex Page 14 of 20

c VEGETABLES Rate per Vegetables Disease Controlled Gallon of Water Onions Downy mildew, Purple blotch 4 tsps. SPECIFIC DIRECTIONS: Apply when plants are 4 to 6 inches high and repeat at 7 -to 10- day intervals. Peanuts Cercospora leaf spot 3 to 6 tsps. SPECIFIC DIRECTIONS: Apply on first ap- pearance of disease and repeat at 7- to 14- day intervals. Pod rot complex (Pythium 3 fl. ozs. myriotylum, Rhizoctonia solani and Sclerotium rolfsit) SPECIFIC DIRECTIONS: Apply at pegging in a 12- to 15-inch band over the row. Peppers Bacterial spot, Cercospora 3 to 6 tsps. leaf spot SPECIFIC DIRECTIONS: Make first appli- cation upon emergence of seedlings or im- mediately after transplanting and repeat at 7- to 10-day intervals. When disease is se- vere, apply at 4- to 5-day intervals. Note: Disease control is critical during fruiting. Potatoes Early and Late blight 3 to 6 tsps. SPECIFIC DIRECTIONS: Apply on first ap- pearance of disease and continue on 5- to 10-day intervals. Spinach Anthracnose, Cercospora leaf 3 tsps. spot, Downy mildew SPECIFIC DIRECTIONS: Apply on first ap- pearance of disease and repeat at 7- to 10- day intervals. Tomatoes Bacterial speck, Bacterial 3 tsps. spot, Early and Late blight SPECIFIC DIRECTIONS: Make first appli- cation upon emergence of seedlings or im- mediately after transplanting and repeat at 3- to 10-day intervals. When disease is se- vere, apply at 3- to 5-day intervals. Com- plete coverage is essential for disease control. Note: While the labeled rate is par- ticularly effective against Bacterial spot, a tank mix with Maneb or Mancozeb used at the labeled rates controls a broad range of diseases. MISCELLANEOUS For Herbs: Mix specified rate in 1 gallon of water and apply 2 gallons of mixed solution per 1,000 sq. ft. (0.5 gallon of solution per 250 sq. ft.). For Trees: Mix specified rate in 1 gallon of water and apply to 500 sq. ft. Apply 3 gallons of mixed solution to a small tree, 6 gallons to a medium size tree, or 9 gallons of mixed solution to a large tree. Thor­ oughly spray tree to point of runoff, including upper and lower surfaces of foliage. Do not overspray. Do not mix more spray solution than needed. Rate per Crop Disease Controlled Gallon of Water Carambolas Anthracnose 6 tsps. SPECIFIC DIRECTIONS: Make initial application just before flowering and repeat on a weekly sched- ule until just before harvest. Apply in sufficient water for thorough coverage. Chives Downy mildew 4 tsps. SPECIFIC DIRECTION: Begin applications when plants are first established in the field. Repeat ap- plications every 7 to 10 days as dictated by disease conditions. If disease pressure is high, use the shorter spray interval. ( MISCELLANEOUS Rate per· Crop Disease Controlled Gallon of Water Dill Phoma leaf spot, Rhizoctonia 6 tsps. foliage blight SPECIFIC DIRECTIONS: Begin applications when plants are first established in the field and repeat at 7- to 10-day intervals depending upon disease severity and environmental conditions. If disease pressure is high, use the shorter spray interval. Douglas fir Rhabdocline needlecast 4 tsps. SPECIFIC DIRECTIONS: Begin applications at bud break and repeat at 1- to 4-week intervals. Apply in a tank mix with another registered pesticide if mod- erate to severe disease pressure is present. Guava Anthracnose, Red algae 6 tsps. SPECIFIC DIRECTION: Make initial application just before flowering and repeat on a weekly schedule until just before harvest. Apply in sufficient water for thorough coverage. Litchi Anthracnose 6 tsps. SPECIFIC DIRECTION: Make initial application just before flowering and repeat on a weekly schedule until just before harvest. Apply in sufficient water for thorough coverage. Live Oak Ball moss 2 fl. ozs. SPECIFIC DIRECTIONS: Apply in the Spring when Ball moss is actively growing, using 1.5 gallons of spray per foot of tree height. Make sure to wet Ball moss tufts thoroughly. A second application may be required after 12 months. Note: This product may be injurious to ornamentals grown under Live oaks. This product may be reactive on metal and masonry surfaces such as galvanized roofing. Avoid contact with metal surfaces. Do not spray on cars, houses, lawn furniture, etc. Macadamia Anthracnose 3 tsps. SPECIFIC DIRECTIONS: Initiate spray at first sign of flowering and repeat on a weekly schedule until just before harvest. Apply in sufficient water for thor- ough coverage. Phytophthora blight, Raceme blight 2 to 3 tsps. SPECIFIC DIRECTIONS: Apply during raceme de- velopment and bloom periods. Apply in sufficient water for thorough coverage. Papaya Anthracnose 2 to 5 tsps. SPECIFIC DIRECTIONS: Begin applications be- fore disease appears and repeat at 14-day inter- vals. Use higher rates when conditions favor disease. Parsley Bacterial blight 6 tsps. SPECIFIC DIRECTIONS: Begin applications when plants are first established in the field and repeat at 10 day intervals depending upon disease severity and environmental conditions. Passion fruit Anthracnose 3 tsps. SPECIFIC DIRECTIONS: Make initial application just before flowering and repeat on a weekly sched- ule until just before harvest. Apply in sufficient water for thorough coverage. Sugar apples Anthracnose 4 to 6 tsps. (Annona) SPECIFIC DIRECTIONS: Make initial application just before flowering and repeat on a weekly sched- ule until just before harvest. Apply in sufficient water for thorough coverage. Sycamore Anthracnose 4 to 6 tsps. SPECIFIC DIRECTIONS: Apply as a full coverage spray. Apply in 1 gallon of water or sufficient vol- ume for thorough coverage. Make first application at bud crack and second application 7 to 10 days later at 10% leaf expansion. KOP-AM Complex Page 15 of 20

( TURFGRASS To control Algae in Ornamental lawns and Turfgrass, apply 0.7 pint of this product per 1,000 square feet in 5 gallons of water. This product rnay be used alone or in cornbination with other registered fungicides as a maintenance spray. Observe all precautions and limitations on the label of each product used in tank mixes. Use Restrictions: Do not apply more than 3 Ibs. of copper (30.6 pts. ofthis product) per acre (0.7 pt. per 1,000 sq. ft.) per application. Do not apply more than 9 Ibs. of copper (91.8 pts. of this product) per acre (2.1 pts. per 1,000 sq. ft.) per year. Minimum retreatment interval is 10 days. Note: Phytotoxicity may occur depending upon varietal differences. Apply the specified rate to a small area and observe for 7 to 10 days for signs of injury. If phytotoxicity occurs, discontinue use. Do not apply in a spray solution with a pH of less than 6.5. ORNAMENTALS Notice to User: Plant sensitivities to this product have been found to be acceptable in specific genera and species listed on this label; how­ ever, it is impossible to know sensitivities under all conditions and phy­ totoxicity may occur. Due to the large number of species and varieties of ornamentals and nursery plants, it is impossible to test every one for sensitivity to this product. Neither the Manufacturer nor Seller recom­ mends use upon species not listed on the label, nor has it been de­ termined that this product can be safely used on omamental or nursery plants not listed on this label. The user should determine if this prod­ uct can be used safely prior to use. Apply as a thorough coverage spray using 2 teaspoonfuls of this prod­ uct per gallon of water. Apply at the rate of one gallon mixed spray to 500 sq. ft. For trees or bushes, apply 3 gallons of mixed solution to a small tree or bush, 6 gallons of mixed solution to a medium-sized tree, or 9 gallons of mixed solution to a large tree. Begin application at first sign of disease and repeat at 7- to 14-day intervals as needed. Use shorter interval during periods of frequent rains or when severe dis­ ease conditions persist. Do not apply more than 2 Ibs. of copper (7.5 fl. ozs. per 1,000 sq. ft.) per application. Do not apply more than 20 Ibs. of copper (75 fl. ozs. per 1,000 sq. ft.) per year. This product may be used alone or in combination with other regis­ tered fungicides as a maintenance spray. Observe all precautions and limitations on the label of each product used in tank mixes. Note: Do not tank-mix this product with Aliette fungicide unless appropriate pre­ cautions have been taken to buffer the spray solution. Severe phyto­ toxicity may result if adequate precautions are not taken. Ornamental Latin name Disease Althaea Hibiscus syriacus Bacterial leaf spot (Rose of Sharon) Aralia Dizygotheca Alternaria, elegantissima Cercospora leaf spot, Xanthomonas leaf spot Arborvitae Thuja spp. Alternaria twig blight, Cercospora leaf blight Azalea' Rhododendron spp. Botrytis blight, Cercospora leaf spot, Phytophthora dieback, Powdery mildew Begonia Begonia Bacterial leaf spot semperfiorens (Erwina sp., Pseudomonas sp., Xanthomonas spp.,) Bougainvillea Bougainvillea Anthracnose, Bacterial spectabilis leaf spot Bulbs - Anthracnose, Botrytis (Tulip, Gladiolus) blight Camellia Camellia japonica, Anthracnose, Bacterial C. sasanqua leaf spot Camphor tree Cinnamomum Pseudomonas leaf spot camphora Canna Canna spp. Pseudomonas leaf spot Carnation' Dianthus spp. Alternaria blight, Botrytis blight, Pseudomonas leaf spot Chinese tallow Sapium sebiferum Bacterial leaf spot tree (Pseudomonas spp., Xanthomonas spp.) Chrysanthemum' Chrysanthemum Botrytis blight, morifolium Septoria leaf spot Ornamental Cotoneaster Dahlia Date palm Dianthus Dogwood Dusty miller Echinacea Elm "Drake" Euonymus European fan palm Gardenia Geranium Gladiolus Goldenrain tree Hibiscus Holly fern Impatiens India hawthorn 2 Ivy (English, Algerian)' Ixora Juniper (Eastern red cedar) Lantana Lilac Loblolly bay Loquat Magnolia (Saucer) Magnolia (Southern) Magnolia (Sweet bay) Mandevillas Marigold Mulberry, weeping Oak, Laurel Oleander ( Latin name Disease Cotoneaster spp. . Botrytis blight Dahlia pinnata Alternaria leaf spot, Botrytis gray mold, Cercospora leaf spot Phoenix canariensis Pestalotia leaf spot Dianthus spp. Bacterial soft rot, Bacterial spot Comus florida Anthracnose Senecio cineraria Bacterial leaf spot (Pseudomonas cichorii) Echinacea spp. Bacterial leaf spot (Pseudomonas cichorii) Ulmus parvifolia Xanthomonas leaf spot Euonymus spp. Anthracnose, Botrytis blight Chamaerops humilis Pesta loti a leaf spot Gardenia Alternaria leaf spot, jasminoides Botrytis bud rot, Cercospora leaf spot Pelargonium spp. Alternaria leaf spot, Botrytis gray mold, Cercospora leaf spot Gladiolus spp. Alternaria leaf spot, Bacterial leaf blight, Botrytis gray mold Koelreuteria Bacterial leaf spot paniculata Hibiscus Bacterial leaf spot rosa-sinensis Cyrtomium falcatum Pseudomonas leaf spot Impatiens sallerana Bacterial leaf spot Rhaphiolepis indica Anthracnose, Entomosporium leaf spot Hedera helix, Xanthomonas leaf spot H. canariensis Ixora coccinea Xanthomonas leaf spot Juniperus virginian a Anthracnose Lantana camara Bacterial leaf spot Syringa spp. Cercospora leaf spot Gordonia lasianthus Anthracnose Eriobotrya japonica Colletotrichum spp., Entomosporium maculata Magnolia Bacterial leaf spot soulangiana Magnolia grandiflora Algal leaf spot, Anthracnose, Bacterial leaf spot Magnolia virginiana Anthracnose Mandevilla spp. Anthracnose Tagetes spp. Alternaria leaf spot, Botrytis leaf and flower rot, Cercospora leaf spot Morus alba Bacterial leaf spot Quercus laurifolia Algal leaf spot (Cephaleuros virescens) Nerium oleander Bacterial leaf spot, Fungal leaf spot (Continued) KOP-AM Complex Page 16 of 20

( , ORNAMENTALS Ornamental Latin name Disease Pachysandra Pachysandra Volutella leaf blight procumbens Pansy Viola spp. Downy mildew Pear (Flowering) Pyrus calleryana Fireblight, Leaf spot Pentas Pentas spp. Bacterial leaf spot (Egyptian star) (Xanthomonas sp.) Peony Paeonia spp. Botrytis blight Periwinkle Catharanthus Phomopsis stem blight roseus, Vinca spp. Philodendron Philodendron Bacterial leaf spot sel/oum Phlox Phloxspp. Alternaria leaf spot Photinia Photinia fraseri, Anthracnose, P glabra Entomosporium Pistachio Pistacia chinensis Anthracnose Plantain lily Hosta spp. Bacterial leaf spot Powder puff plant Cal/iandra spp. Bacterial leaf spot Pyracantha Pyracantha spp. Fireblight, scab Queen palm Syagrus Exosporium leaf spot, romanzoffianum Phytophthora bud rot Rhododendron Rhododendron spp. Alternaria flower spot Rose' Rosa spp. Powdery mildew, Black spot Verbena Verbena spp. Xanthomonas leaf spot Viburnum Viburnum Anthracnose odoratissimum, V. suspensum Washingtonia Washingtonia Pestalotia leaf spot palm robusta Weeping willow Salix babylonica Anthracnose Yucca Yucca spp. Cercospora leaf spot, (Adam's needle) Septoria leaf spot Note: , Discoloration of foliage and/or blooms has been noted on some varieties. To prevent residues on commercial plants, do not spray just before selling season. 2 For India Hawthorn, use 2 to 4 level tablespoons per gallon of water. FROST INJURY PROTECTION Bacterial Ice Nucleation Inhibitor - Application of this product made to all crops listed on this label at rates indicated on this label, just prior to anticipated frost conditions, will sustain control of ice nucleating bac­ teria (Pseudomonas syringae, Erwina herbicola and Pseudomonas f/uorescens) and may therefore provide protection against light frost. Not recommended for those geographic areas where weather condi­ tions favor severe frost. ( STORAGE AND DISPOSAL Do not contaminate water, food or feed by storage and disposal. PESTICIDE STORAGE: Store in secure, locked area away from pets and out of the reach of children. Store only in original container and place in a locked storage area. PESTICIDE DISPOSAL: Call you local solid waste agency for dis­ posal instructions. Never place unused product down any indoor or outdoor drain. CONTAINER DISPOSAL: Nonrefillable container. Do not reuse or refill this container. Place in trash or offer for recycling, if available. If partly filled, call you local solid waste agency for disposal instruc­ tions. Never place unused product down any indoor or outdoor drain. WARRANTY- CONDITIONS OF SALE OUR DIRECTIONS FOR USE of this product are based upon tests believed reliable. Follow directions carefully. nming and method of ap­ plication, weather and crop conditions, mixtures with other chemicals not specifically recommended and other influencing factors in the use of this product are beyond the control of the Seller. To the extent con­ sistent with applicable law, Buyer assumes all risks of use, storage and handling of this material not in strict accordance with directions given herewith. To the extent consistent with applicable law, in no case shall the Man­ ufacturer or the Seller be liable for consequential, special or indirect damages resulting from the use or handling of this product when such use and/or handling is not in strict accordance with directions given herewith. The foregoing is a condition of sale by the Seller and is ac­ cepted as such by the Buyer. Optional Marketing Statements: Ready-to-spray bottle Intended for Home and Garden Use Controls many diseases listed, attacking Citrus, Fruits, Nuts, Veg­ etables and Ornamentals. Intended for Residential Use only. KOP-AM Complex Page 17 of 20

( ( FOR HOSE-END APPLICATOR Drexet' KOP·AM Complex Liquid Fungicide Spray ACTIVE INGREDIENT: Copper diammonia diacetate complex [Bis(acetato-O)diamminecopper]* OTHER INGREDIENTS: ......................................... . TOTAL: ............................................................. . • CAS No. 13822-80-5; Metallic copper equivalent, 8.0%. 27.15% 72.85% 100.0% This product contains 0.784 pound of Copper per gallon. (One quart of this product contains 0.196 pound of copper) KEEP OUT OF REACH OF CHILDREN CAUTION See FIRST AID Below SHAKE WELL BEFORE USING EPA Reg. No. 19713-509 EPA Est. No. 19713-XX-XXX FIRST AID IF IN EYES: Net Content: 1 Quart • Hold eye open and rinse slowly and gently with water for 15 to 20 minutes. • Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. • Call a poison control center or doctor for treatment advice. IF ON SKIN OR CLOTHING: • Take off contaminated clothing. • Rinse skin immediately with plenty of water for 15 to 20 minutes. • Call a poison control center or doctor for treatment advice. IF SWALLOWED: • Call a poison control center or doctor immediately for treatment advice. • Have person sip a glass of water if able to swallow. • Do not induce vomiting unless told to do so by a poison control center or doctor. • Do not give anything by mouth to an unconscious or convulsing person. Have the product container or label with you when calling a poison control center or doctor, or going for treatment. For information on this pesticide product (including health concerns, medical emergencies or pesticide incidents), call the National Pesticide Information Center at 1·800-858-7378. PRECAUTIONARY STATEMENTS Hazards to Humans and Domestic Animals CAUTION: Harmful if swallowed. Harmful if absorbed through skin. Causes moderate eye irritation. Avoid contact with skin, eyes or clothing. Wear protective eyewear (goggles, face shield or safety glasses), clothing and chemical-resistant gloves when handling this product. Wash thoroughly with soap and water after handling and before eating, drinking or using tobacco. Remove contaminated clothing and wash clothing before reuse. Do not use food utensils such as teaspoons or tablespoons for food purposes after use with pesticides. USER SAFETY RECOMMENDATIONS Users should: 1) Wash hands before eating, drinking, chewing gum, using tobacco or using the toilet. 2) Remove clothing/PPE im­ mediately if pesticide gets inside. Then wash thoroughly and put on clean clothing. 3) Remove PPE immediately after handling this prod­ uct. Wash the outside of gloves before removing. As soon as pos­ sible, wash thoroughly and change into clean clothing. ENVIRONMENTAL HAZARDS This pesticide is toxic to fish and aquatic invertebrates and may con­ taminate water through runoff. Do not contaminate water when dis­ posing of equipment washwaters or rinsate. To protect the environment, do not allow pesticide to enter or run off into storm drains, drainage ditches, gutters or surface waters. Apply­ ing this product in calm weather when rain is predicted for the next 24 hours will help to ensure that wind or rain does not blow or wash pes­ ticide off the treatment area. Rinsing application over the treated area will help avoid runoff to bodies of water or drainage systems. DIRECTIONS FOR USE It is a violation of Federal law to use this product in a manner incon­ sistent with its labeling. Do not apply this product in a way that will contact adults, children or pets, either directly or through drift. Only protected users may be in the area during application. For any re­ quirements specific to your State or Tribe, consult the agency re­ sponsible for pesticide regulation. ENTRY RESTRICTION Do not enter or allow others to enter the treated area until sprays have dried. USE INFORMATION The control of diseases with fungicides is based on PREVENTION: plant surfaces must be completely covered with the fungicide to suc­ cessfully prevent infection. Copper pesticides are considered preven­ tative, not curative. Seek advice on identifying specific disease problems and solutions from your local agricultural extension agent or other knowledgeable persons. Manufactured For: Drexel Chemical Company P.O. BOX 13327, MEMPHIS, TN 38113-0327 SINCE 1972 509MSP-0710' KOP-AM Complex Page 18 of 20

USE INSTRUCTIONS APPLICATION: Thoroughly spray tree or bush to the point of runoff, includi'ng upper and lower surfaces of any foliage. Do not overspray. Note: This product may be reactive on metal and masonry surfaces such as galvanized roofing. AVOID CONTACT with metal surfaces. Do not spray on cars, houses, lawn furniture, etc. One quart of this product makes up to 48 gallons of spray solution and may be applied to 16 small trees or 8 medium-sized trees or 5 large trees. HOW TO USE THIS SPRAYER: Shake container well before getting started.

1. Before you start, the blue top water flow valve should be in the "OFF" position, and the red product flow valve should be in the up "OFF" position.
2. Shake container well and attach it to your garden hose.
3. Turn on the water from the faucet.
4. To apply, remove side pin (label "PULL OUr) and rotate red prod­ uct flow valve to "ON"; then, while holding sprayer at waist level and poiting in a direction away from face and body, push blue water flow valve forward to activate water.
5. When you are finished spraying, or if you have to stop spraying at any time, press blue water flow valve with thumb to the rear to shut off water and return red valve to the upright "OFF" position and re­ place side pin.
6. Turn off the water at the faucet.
7. Remove the container from the garden hose. Then rinse thor­ oughly and store according to storage instructions. FRUITS AND NUTS Fruits and Disease Controlled Nuts Almonds Brown rot SPECIFIC DIRECTIONS: Apply at delayed-dor- mant' bud swell stage, just before blossom buds break open. Shot hole SPECIFIC DIRECTIONS: Apply at leaf fall to pro- tect buds and shoots from infection during rainy pe- riods. Reapply every 3 to 4 weeks up to late bud swell (the period in Spring before buds begin to open). Do not apply after full bloom. Apples Apple scab (black spot), Bacterial canker, Blossom and Shoot blast SPECIFIC DIRECTIONS: Apply post-harvest be- fore Fall rains. Apricots Brown rot blossom blight SPECIFIC DIRECTIONS: Apply when buds show red in color until brown bud jackets have fallen. Shot hole SPECIFIC DIRECTIONS: Apply in late Fall or early Winter, before winter rains or snow. Repeat in late Winter or early Spring before buds break. Do not apply after full bloom. Avocados Anthracnose SPECIFIC DIRECTIONS: Begin application when the flower buds begin to swell and continue at monthly intervals until August. Blueberries Bacterial canker (Not for Use SPECIFIC DIRECTIONS: Apply before Fall rains in CAl and again 4 weeks later. Cane canker SPECIFIC DIRECTIONS: Apply before Fall rains and again 4 weeks later. In the Spring during wet weather, apply at 7- to 14-day intervals beginning at leaf emergence. Fruits and Disease Controlled Nuts Caneberries Anthracnose, Bacterial blight, Leaf and Cane spot, Purple blotch, Yellow rust SPECIFIC DIRECTIONS: Apply in the Fall after har- vest. Cherries Brown rot blossom blight SPECIFIC DIRECTIONS: Apply as a full cover spray at popcorn stage and at full bloom. Citrus Greasy spot, Melanose, Pink pitting, Scab SPECIFIC DIRECTIONS: Apply as pre-bloom and post-bloom sprays. Currants, Anthracnose, Leaf spot (cane blight) Gooseberries SPECIFIC DIRECTIONS: Make 3 applications start- ing after harvest, before bloom and after petal fall. Limes Greasy spot SPECIFIC DIRECTIONS: Apply in June and con- tinue at monthly intervals through August. Mangoes Anthracnose (Not for use SPECIFIC DIRECTIONS: Apply monthly from the inCA) time the panicles are 2 inches in length until all fruits are set until August. Olives Peacock spot SPECIFIC DIRECTIONS: Make first application be- fore Winter rains fall. A second application should be made in early Spring if disease is severe. Peaches, Bacterial spot Nectarines SPECIFIC DIRECTIONS: Apply as a dormant spray. Blossom brown rot SPECIFIC DIRECTIONS: Apply as dormant or delayed-dormant' spray. DO NOT apply at or after full bloom. Leaf curl, Shot hole SPECIFIC DIRECTIONS: Apply at leaf fall to pro- tect buds and shoots from infection during rainy pe- riods. Reapply up until late bud swell. DO NOT apply after full bloom. Pears Blossom blast SPECIFIC DIRECTIONS: Apply as a dormant spray. Apply only at bud break to control primary in- fection. Pecans Shuck and Kernel rot, Zonate leaf spot SPECIFIC DIRECTIONS: For suppression, apply at 2- to 4-week intervals starting at kernel growth and continuing until shucks open. Use shorter in- terval if frequent rainfall occurs. Pistachios Alternaria late blight SPECIFIC DIRECTIONS: Apply at 50% and full bloom followed by up to 3 applications at 30-day in- tervals. Botrytis blight, Botryosphaeria panicle, Shoot blight, Septoria leaf blight SPECIFIC DIRECTIONS: Make initial application at bud swell and repeat on a 14- to 28-day schedule as dictated by disease conditions. If disease condi- tions are severe, use the shorter interval. Plums, Coryneum blight (shot hole) Prunes SPECIFIC DIRECTIONS: Apply as a dormant spray before heavy rains begin. Bacterial blast, Bacterial canker SPECIFIC DIRECTIONS: Apply at dormant to early pink stage. Walnuts Walnut blight SPECIFIC DIRECTIONS: Make first application at early pre-bloom. Make second application at late pre-bloom. Make additional applications if disease conditions persist. , Delayed-dormant - The· period just before blossom buds break open. KOP-AM Complex Page 19 of 20

( STORAGE AND DISPOSAL Do not contaminate water, food or feed by storage and disposal. PESTICIDE STORAGE: Store in secure, locked area away from pets and out of the reach of children. Store only in original container and place in a locked storage area. PESTICIDE DISPOSAL: Call you local solid waste agency for dis­ posal instructions. Never place unused product down any indoor or outdoor drain. CONTAINER DISPOSAL: Nonrefillable container. Do not reuse or refill this container. Place in trash or offer for recycling, if available. If partly filled, call you local solid waste agency for disposal instruc­ tions. Never place unused product down any indoor or outdoor drain. ( , WARRANTY- CONDITIONS OF SALE OUR DIRECTIONS FOR USE of this product are based upon tests believed reliable. Follow directions carefully. Timing and method of ap­ plication, weather and crop conditions, mixtures with other chemicals not specifically recommended and other influencing factors in the use of this product are beyond the control of the Seller. To the extent con­ sistent with applicable law, Buyer assumes all risks of use, storage and handling of this material not in strict accordance with directions given herewith. To the extent consistent with applicable law, in no case shall the Man­ ufacturer or the Seller be liable for consequential, special or indirect damages resulting from the use or handling of this product when such use and/or handling is not in strict accordance with directions given herewith. The foregoing is a condition of sale by the Seller and is ac­ cepted as such by the Buyer. Optional Marketing Statements: Ready-to-spray bottle Just attach to garden hose and spray Intended for Home and Garden Use Intended for Residential Use Only Controls many listed diseases attacking Citrus and Fruit and Nut Trees KOP-AM Complex Page 20 of 20