crop-chem-docs/corpus/epa_ppls/19713-651.md

DREXEL DE-AMINE 6

• EPA Reg No: 19713-651
• Registrant: DREXEL CHEMICAL COMPANY
• Signal word: Danger
• Active ingredients: 2,4-D, dimethylamine salt (66.2%)
• Label accepted: 2020-08-05
• Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/019713-00651-20200805.pdf

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August 5, 2020 Subject: Dear Ms. Chan: Sincerely, Notification Label Acceptable v.20150904 The label submitted with the application has been stamped “Notification” and will be placed in our records. Mindy Ondish Product Manager 23 Herbicide Branch Registration Division (7505P) Office of Pesticide Programs OFFICE OF CHEMICAL SAFETY AND POLLUTION PREVENTION Should you wish to add/retain a reference to the company’s website on your label, then please be aware that the website becomes labeling under the Federal Insecticide, Fungicide, and Rodenticide Act (FIFRA) and is subject to review by the Agency. If the website is false or misleading, the product would be misbranded and unlawful to sell or distribute under FIFRA section 12(a)(1)(E). 40 CFR 156.10(a)(5) list examples of statements EPA may consider false or misleading. In addition, regardless of whether a website is referenced on your product’s label, claims made on the website may not substantially differ from those claims approved through the registration process. Therefore, should the Agency find or if it is brought to our attention that a website contains false or misleading statements or claims substantially differing from the EPA approved registration, the website will be referred to the EPA’s Office of Enforcement and Compliance. The Agency is in receipt of your Application for Pesticide Notification under Pesticide Registration Notice (PRN) 98-10 for the above referenced product. The Registration Division (RD) has conducted a review of this request for its applicability under PRN 98-10 and finds that the action requested falls within the scope of PRN 98-10. Luz G. Chan Registration Manager Drexel Chemical Company PO Box 13327 Memphis, TN 38113-0327 If you have any questions, you may contact Endia Blunt at 703-347-0788 or by email at Blunt.Endia@epa.gov. Notification per PRN 98-10 - Multiple label edits Product Name: Drexel De-Amine 6 EPA Registration Number: 19713-651 Application Date: May 20, 2020 Decision Number: 564266 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY WASHINGTON, DC 20460

2,4-D HERBICIDEGROUP Net Content: Gals. ( L) FIRST AID 651SP-0820P Page 1 of 32 4 Drexel EPA Reg. No. 19713-651 EPAEst. No. 19713-XX-XXX [See Container Labeling for Complete Directions for Use] [See (Attached) Booklet (Container Labeling) for Complete Directions for Use] For selective control of many broadleaf weeds in certain crops including Asparagus; Cereal grains (Barley, Millet, Oats, Rye, Triticale, and Wheat); Corn (Field corn. Popcorn and Sweet corn); Fallow land and Crop stubble. Hops; Orchard floors (Apple, Pear, Stone fruit and Nut); Rice; Sorghum (Grain and Forage Sorghum); Soybeans (Pre-plant burndown application only); Forests; Rangeland and established Grass pastures including Conservation Reserve Program (CRP) acres; Non­ cropland; Grasses grown for seed or sod; Ornamental turfgrass; and Aquatic areas. If In Eyes: . Hold eye open and rinse slowly and gently with water for 15 to 20 minutes. . Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. . Call a poison control center or doctor for treatment advice.____________________________________ If on Skin or Clothing: • Take off contaminated clothing. • Rinse skin immediately with plenty of water for 15 to 20 minutes. » Call a poison control center or doctor for treatment advice.____________________________________ If Swallowed: . Call a poison control center or doctor immediately for treatment advice. . Have person sip a glass of water if able to swallow. . Do not induce vomiting unless told to do so by the poison control center or doctor. . Do not give anything by mouth to an unconscious person._____________________________________ Have the product container or label with you when calling a poison control center or doctor, or going for treatment. For information on this pesticide product (including health concerns, medical emergencies or pesticide incidents), call the National P esticide Information Center at 1-800-858-7378. You may also call CHEMTREC at 800-424-9300 for emergency medical treatment information._______________________ Note to Physician: This product is a phenoxy type of herbicide. There is no specific antidote. Base all treatments on observed signs and symptoms of distress in the patient. Probable mucosal damage may contraindicate the use of gastric lavage. ACTiVE iNGREDiENT: 2,4-Dichlorophenoxyacetic acid, dimethylamine salt................. OTHER iNGREDiENTS: ............................................................... TOTAL: .................................................................................. ‘Equivalent to 55.1% of 2,4-Dichlorophenoxyacetic acid or 5.6 pounds per gallon. Isomer specific by AOAC Method 6.275, 13th Ed., 1980. 66.2% 33.8% 100.0% KEEP OUT OF REACH OF CHILDREN DANGER ZPELIGRO Si usted no intiende a la etiqueta, busque a alguien pars que se la explique a usted en detalle. (If you do not understand the label, find someone to explain it to you in detail.) labclinfT. tiw Afjency stcltnowlet^s this ncirjtitaiiiin by ttner dittd; ■ 08/05/2020 NOTIFICATION 19713-651 Thf applicani has certified ihat no cban^es, other than thtiM reported to the Agency hare been made t-.i the

Aquatic Weed Control: Fish breathe dissolved oxygen in the water and decaying weeds also use oxygen. When treating continuous, dense weed masses, it may be appropriate to treat only part of the infestation at a time. For example, apply the product in lanes separated by untreated strips that can be treated after vegetation in treated lanes has disintegrated. During the growing season, weeds decompose in a 2 to 3 week period following treatment. Begin treatment along the shore and proceed outwards in bands to allow fish to move into untreated areas. Waters having limited and less dense weed infestations may not require partial treatments. USER SAFETY RECOMMENDATIONS Users should: 1) Wash hands thoroughly before eating, drinking, chewing gum, using tobacco, or using the toilet 2) Remove clothing/PPE immediately if pesticide gets inside. Then wash thoroughly and put on clean clothing. If pesticide gets on skin, wash immediately with soap and water. 3) Remove PPE immediately after handling this product. Wash the outside of gloves before removing. As soon as possible, wash thoroughly and change into clean clothing. ENVIRONMENTAL HAZARDS For terrestrial uses: This product is toxic to aquatic invertebrates and may be to toxic to fish. Do not apply directly to water, to areas where surface water is present, or to intertidal areas below the mean high water mark except as noted on appropriate labels. Drift and runoff may be hazardous to aquatic organisms in water adjacent to treated areas. Do not contaminate water when disposing of equipment wash waters or rinsate. This chemical has properties and characteristics associated with chemicals detected in groundwater. The use of this chemical in areas where soils are permeable, particularly where the water table is shallow, may result in groundwater contamination. Application around a cistern or well may result in contamination of drinking water or groundwater. PRECAUTIONARY STATEMENTS Hazards to Humans and Domestic Animals DANGER: Corrosive. Causes irreversible eye damage. May be fatal if absorbed through skin. Harmful if swallowed. Do not get in eyes, on skin, or on clothing. PERSONAL PROTECTIVE EQUIPMENT (PPE) Some materials that are chemical-resistant to this product are made of any waterproof material. If you want more options, follow the instructions for Category C on an EPA chemical-resistance category selection chart. All pilots must wear: Long-sleeved shirt, long pants, shoes and socks. All mixers, loaders, applicators, flaggers, and other handlers must wear: Coveralls over short- sleeved shirt and short pants, chemical-resistant footwear plus socks, chemical-resistant gloves, protective eyewear (goggles face shield, and safety glasses), chemical-resistant headgear for overhead exposure, and chemical-resistant apron when mixing or loading, cleaning up spills or equipment, or otherwise exposed to the concentrate. See “ENGINEERING CONTROLS ” for additional requirements. Discard clothing and other absorbent materials that have been drenched or heavily contaminated with this product's concentrate. Do not reuse them. Follow manufacturer's instructions for cleaning/maintaining PPE. If no such instructions for washables exist, use detergent and hot water. Keep and wash PPE separately from other laundry. Follow manufacturer’s instructions for cleaning/maintaining PPE. If no such instructions for washables exist, use detergent and hot water. Keep and wash PPE separately from other laundry. After each day of use, clothing or PPE must not be reused until it has been cleaned. ENGINEERING CONTROLS When handlers use enclosed cabs or aircraft in a manner that meets the requirements listed in the Worker Protection Standard (WPS) for agricultural pesticides [40 CFR 170.240(d)(4-6)], the handler PPE requirements may be reduced or modified as specified in the WPS. Pilots must use an enclosed cockpit that meets the requirements listed in the WPS for agricultural pesticides [40 CFR 170.240(d)(6)]. GROUNDWATER CONTAMINATION Most cases of groundwater contamination involving phenoxy herbicides such as 2,4-D have been associated with mixing/loading and disposal sites. Exercise precautions when handling 2,4-D pesticides at such sites to prevent contamination of groundwater supplies. Use of closed systems for mixing or transferring this pesticide Page 2 of 32

Page 3 of 32 will reduce the probability of spills. Placement of the mixing/loading equipment on an impervious pad to contain spills will help prevent groundwater contamination. DIRECTIONS FOR USE It is a violation of Federal law to use this product in a manner inconsistent with its labeling. Read all directions for use carefully before applying. Do not apply this product in a way that will contact workers or other person, either directly or through drift. Only protected handlers may be in the area during application. For any requirements specific to your State or Tribe, consult the agency responsible for pesticide regulation. WEED RESISTANCE MANAGEMENT I 2,4-D I GRdUPMM~~HERBiciD^ This product is a Group d herbicide. Any weed population may contain or develop plants naturally resistant to this product and other Group d herbicides. Weed species with acquired resistance to Group d may eventually dominate the weed population if Group d herbicides are used repeatedly in the same field or in successive years as primary method of control for targeted species. This may result in partial or total loss of control of those species by this product or other Group d herbicides. To delay herbicide resistance, consider: «--------Avoiding the consecutive use of this product or other target site of action Group d herbicides that have a similar target site of action on the same weed species. «--------Using tank-mixtures or premixes with herbicides from different target site of action Groups as long as the involved products are all registered for the same use. have different sites of action, and are both effective at the tank mix or prepack rate on the weed(s) of concern. «--------Basing herbicide use-OR-a-eemprehensive IPM pr-egramr •--------Monitoring treated weed populations for loss of field efficacy. «--------Contacting your local extension specialist, certified crop advisors and/or manufacturer for herbicide resistance management and/or integrated weed management recommendations for specific crops and resistant weed biotypes. For resistance management, this product is a Group 4 mode of action herbicide. Any weed population may contain or develop plants naturally resistant to this product and other Group 4 mode of action herbicides. The resistant biotypes may dominate the weed population if these herbicides are used repeatedly in the same field. Appropriate resistance management strategies should be followed. To delay herbicide resistance, take one or more of the following steps: • Rotate the use of this product or other Group 4 herbicides within a growing season sequence or among growing seasons with different herbicide groups that control the same weeds in a field. • Use tank-mixtures with herbicides from a different group if such use is permitted; where information on resistance in target weed species is available, use the less resistance-prone partner at a rate that will control the target weed(s) equally as well as the more resistance-prone partner. Consult your local extension sen/ice or certified crop advisor if you are unsure as to which active ingredient is currently less prone to resistance. • Adopt an integrated weed-management program for herbicide use that includes scouting and uses historical information related to herbicide use and crop rotation, and that considers tillage (or other mechanical control methods), cultural (e.g., higher crop seeding rates; precision fertilizer application method and timing to favor the crop and not the weeds), biological (weed-competitive crops or varieties) and other management practices. • Scout after herbicide application to monitor weed populations for early signs of resistance development. Indicators of possible herbicide resistance include: (1) failure to control a weed species normally controlled by the herbicide at the dose applied, especially if control is achieved on adjacent weeds; (2) a spreading patch of non-controlled plants of a particular weed species; (3) surviving plants mixed with controlled individuals of the same species. If resistance is suspected, prevent weed seed production in the affected area by an alternative herbicide from a different group or by a mechanical method such as hoeing or tillage. Prevent movement of resistant weed seeds to other fields by cleaning harvesting and tillage equipment when moving between fields, and planting clean seed. • If a weed pest population continues to progress after treatment with this product, discontinue use of this product, and switch to another management strategy or herbicide with a different mode of action, if available. • Contact your local extension specialist or certified crop advisors for additional pesticide resistance-management and/or integrated weed-management recommendations for specific crops and weed biotypes. • For further information or to report suspected resistance, contact Drexel Chemical Company representatives at (901) 774-4370.

Do not apply this product in less than 2 gallons of total spray volume per acre. Chemigation: Do not apply this product through any type of irrigation system. Page 4 of 32 Precautions and Restrictions: Use of this product in certain portions of California, Oregon, and Washington is subject to the January 22, 2004 Order for injunctive relief in Washington Toxics Coalition et al. v. EPA. C01-0132C, (W.D. W. A.). For further information, please refer to EPA website: http://www.epa.qov/espp/litstatus/wtc/index.htm. Apply this product as a water or oil-water spray during warm weather when weeds or woody plants are actively growing. Application under drought conditions will often give poor results. Use low spray pressure to minimize drift. Generally, the lower dosages specified on this label will be satisfactory for young, succulent growth of susceptible weed species. For less susceptible species and under conditions where control is more difficult, use higher specified rates. Deep-rooted perennial weeds such as Canada thistle and field bindweed and many woody plants usually require repeated applications for satisfactory control. Consult your State Agricultural Experiment stations or Extension Service Weed Specialists for recommendations from this label that best fit local conditions. Do not contaminate irrigation ditches or water used for domestic purposes. Residues of 2,4- dichlorophenoxyacetic acid in the soil may temporarily inhibit seed germination or plant growth. Be sure that use of this product conforms to all applicable regulations. There may be state or local regulations affecting the use of 2,4-D herbicides in your area. Consult state agricultural experiment station or local extension service weed specialists regarding regulations applicable to your area or specific local weed control recommendations. PRODUCT INFORMATION DE-AMINE 6 is a herbicide intended for selective control of many broadleaf weeds in certain crops, including, cereal grains {Barley, Millet, Oats, Rye, Triticale, and Wheat), Corn (field Corn, Popcorn and Sweet Corn), fallow land and crop stubble, orchard floors (Apple, Pear, stone fruit and nut). Rice, Sorghum (grain and forage Sorghum), Soybeans (pre-plant burndown application only); forests; rangeland and established grass pastures, including Conservation Reserve Program (CRP) acres; non-cropland areas; grasses grown for seed or sod, ornamental turfgrass; and aquatic areas. NON-AGRICULTURAL USE REQUIREMENTS The requirements in this box apply to uses of this product that are not within the scope of the Worker Protection Standard (WPS) for agricultural pesticides (40 CFR Part 170). The WPS applies when this product is used to produce agricultural plants on farms, forests, nurseries or greenhouses. Entry Restrictions for Non-WPS Uses: Do not enter or allow people (or pets) to enter treatment areas during application. For terrestrial uses: Do not enter or allow people (or pets) to enter the treatment area until sprays have dried. AGRICULTURAL USE REQUIREMENTS Use this product only in accordance with its labeling and with the Worker Protection Standard (WPS), 40 CFR Part 170. This standard contains the requirements for the protection of agricultural workers on farms, forests, nurseries, and greenhouses, and handlers or agricultural pesticides. It contains requirements for training, decontamination, notification, and emergency assistance. It also contains specific instructions and exceptions pertaining to the statements on this label about personal protective equipment (PPE) and restricted-entry interval. The requirements in this box only apply to uses of this product that are covered in the WPS. Do not enter or allow worker entry into treated areas during the restricted entry interval (REI) of 48 hours. PPE required for early entry to treated areas that is permitted under the WPS and that involves contact with anything that has been treated such as plants, soil, or water is: Coveralls over short-sleeved shirt and short pants, chemical-resistant gloves made of any waterproof material, chemical-resistant footwear plus socks, and protective eyewear (goggles, face shield, safety glasses).

Page 5 of 32 Wind Speed Do not apply at wind speeds greater than 15 mph. Only apply this product if the wind direction favors on- target deposition and there are not sensitive areas (including, but not limited to, residential areas, bodies of water, known habitat for nontarget species, nontarget crops) within 250 feet downwind. If applying a Medium spray, leave one swath unsprayed at the downwind edge of the treated field. Equipment All aerial and ground application equipment must be properly maintained and calibrated using appropriate carriers or surrogates. Aerial Application The boom length must not exceed 75% of the wingspan or 90% of the rotor blade diameter. When applications are made with a crosswind, the swath will be displaced downwind. The applicator must compensate for this by adjusting the path of the aircraft upwind. Droplet Size When applying sprays that contain 2,4-D as the sole active ingredient, or when applying sprays that contain 2,4-D mixed with active ingredients that require a coarse or coarser spray, apply only as a coarse or coarser spray (ASAE standard 572) or volume mean diameter of 385 microns or greater for spinning atomizer nozzles. When applying sprays that contain 2,4-D mixed with other active ingredients that require a Medium or more fine spray, apply only as a Medium or coarser spray (ASAE standard 572) or a volume mean diameter of 300 microns or greater for spinning atomizer nozzles. Temperature Inversions If applying at wind speeds less than 3 mph, the applicator must determine if: a) conditions of temperature inversion exist, or b) stable atmospheric conditions exist at or below nozzle height. Do not make applications into areas of temperature inversions or stable atmospheric conditions. Release spray at the lowest height consistent with efficacy and flight safety. Do not release spray at a height greater than 10 feet above the crop canopy unless a greater height is required for aircraft safety. This requirement does not apply to forestry or rights-of-way applications. Susceptible Plants Do not apply under circumstances where spray drift may occur to food, forage, or other plantings that might be damaged or crops thereof rendered unfit for sale, use or consumption. Susceptible crops include, but are not limited to, cotton, okra, flowers, grapes (in growing stage), fruit trees (foliage), Soybeans (vegetable stage), ornamentals, sunflowers, tomatoes, beans, and other vegetables, or tobacco. Small amounts of spray drift that might not be visible may injure susceptible broadleaf plants. Crop Injury: Injury to crops may occur when this herbicide is used as specified. If you are not prepared to accept some degree of crop injury, do not use this product. Certain crop varieties may be more susceptible to 2,4-D injury. Apply this product only to crop varieties known to be tolerant to 2,4-D. If you are uncertain concerning tolerant varieties or local use situations that may affect crop tolerance to 2,4-D, consult your seed company, state agricultural extension service or qualified crop consultant for advice. Other State and Local Requirements Applicators must follow all state and local pesticide drift requirements regarding application of 2,4-D herbicides. Where states have more stringent regulations, they must be observed. SPRAY DRIFT MANAGEMENT A variety of factors including weather conditions (e.g., wind direction, wind speed, temperature, relative humidity) and method of application (e.g., ground, aerial, airblast) can influence pesticide drift. The applicator must evaluate all factors and make appropriate adjustments when applying this product.

Page 6 of 32 Precaution; Adding oil, wetting agent or other surfactant to the spray may increase effectiveness on weeds, but also may reduce selectivity to crops resulting in crop injury. Read and follow all directions, restrictions, and precautions on this label and on the label of each product added to the spray mixture. Follow the most restrictive labeling. Fill the tank about half full with the liquid fertilizer, then add the required amount of this product with agitation. Maintain agitation and complete filling the tank with liquid fertilizer. Apply immediately and continue spray tank agitation during application. Do not store the spray mixture. Do not apply during cold weather (less than 40°F) to avoid spray mixture compatibility problems.

1. Rinse and flush application equipment thoroughly after use at least three times with water. Dispose of all rinse water by application to treatment area or apply to non-cropland area away from water supplies.
2. During the second rinse, add 1 quart of household ammonia for every 25 gallons of water. Circulate the solution through the entire system so that all internal surfaces are contacted (15 to 20 min.). Let the solution stand for several hours, preferably overnight.
3. Flush the solution out of the spray tank through the boom.
4. Rinse the system twice with clean water, recirculating and draining each time.
5. Remove nozzles and screens and clean separately.
6. If equipment is to be used to apply another pesticide or agricultural chemical to a 2,4-D susceptible crop, additional steps may be required to remove all traces of 2,4-D, including cleaning of disassembled parts and replacement of hoses or other fittings that may contain absorbed 2,4-D. Groundboom Applications Do not apply with a nozzle height greater than 4 feet above the crop canopy. Mixing with Liquid Nitrogen Fertilizer This product may be combined with liquid nitrogen fertilizer suitable for foliar application to accomplish Broadleaf weed control and fertilization of Corn, small grains or pastures in a single operation. Use this product in accordance with the directions for these crops provided in this label. Use liquid fertilizer at rates specified by the supplier or Extension Service Specialist. Test for mixing compatibility as describe above before mixing in spray tank. A compatibility aid may be needed in some situations. Compatibility is best with liquid fertilizer solutions containing only nitrogen. Mixing with N-P-K solutions may not be satisfactory, even with the addition of a compatibility aid. Pre-mixing 1 part of this product with up to 4 parts water may help in situations when mixing difficulty occurs. Tank-Mixing Precautions A jar test is recommended prior to tank mixing to ensure compatibility of this product and other pesticides. Use a clear glass quart jar with lid and mix the tank mix ingredients in their relative proportions. Invert the jar containing the mixture several times and observe the mixture for approximately 0.5 hour. If the mixture balls­ up, forms flakes, sludge, gels, oily films or layers, or other precipitates, it is not compatible and the tank mix combination should not be used. MIXING Mix this product only with water unless otherwise directed on this label. Add about half of the water to the mixing tank, then add this product with agitation, and finally add the rest of the water with continuing agitation. SPRAYER CLEAN-OUT To avoid injury to desirable plants, equipment used to apply this product should be thoroughly cleaned before re-use or applying other chemicals. APPLICATIONS Apply with calibrated air or ground equipment using sufficient spray volume to provide adequate coverage of target weeds or as otherwise directed in specific use directions. For broadcast application, use a spray volume of 2 gallons or more per acre by air and 10 gallons or more per acre for ground equipment. Where states have regulations that specify minimum spray volumes, they should be observed. In general, spray volume should be increased as crop canopy, height and weed density increase in order to obtain adequate spray coverage.

0.5 0.66 3/4 1 8 Conversion factor: 1 fl. oz. = 29.6 (30 mL); 16 fl. ozs. = 1 pint X X Page 7 of 32 3 (88 mL) Handheld Sprayers Hand-held sprayers may be used for spot applications in labeled crops. Care should be taken to apply the spray uniformly and at a rate equivalent to a broadcast application. Application rates in the table are based on a treatment area of 1000 sq. ft. Mix the amount of this product (fl. oz. or mL) corresponding to the desired broadcast rate in one (1) gallon or more of spray. To calculate the amount of this product required for larger areas, multiply the table value (fl. oz. or mL) by the number ofthousandsof square feet of area to be treated. An area of 1000 square feet is approximately 10.5 X 10.5 yards (strides) in size. To calculate the amount of this product required for a broadcast rate higher than those listed, use a multiple of the table value. Spot Treatments To prevent misapplication, spot treatments should be applied with a calibrated boom or with hand sprayers using a fixed spray volume per 1000 square feet as indicated below. Band volume per treated acre 1/5 (5.5 mL) Band width in inches Row width in inches Band width in inches Row width in inches Band Application This product may be applied as a band treatment. Use the formula below to determine the appropriate rate and volume per treated acre. 0.33 (8.3 mL) 3/8 (11 mL) 3/4 (22 mL) 1/4 (7.3 mL) 1 (33 mL) 1.5 (44 mL) WEEDS CONTROLLED This product will kill or control the following in addition to many other noxious plants susceptible to 2,4-D: Broadcast rate per acre Band rate per treated acre Spot Treatment Rate Conversion Table____________________________________ Label Broadcast Rate (P int/Acre Pt./Ac.) _______ ’ 2 I 3 I ~4 Equivalent Amount of This Product per 1000 sq. ft. (fl. oz.) Broadcast volume per acre Beggarticks* Bittercress, Small-flowered Bitterweed Broomweed, Common* Burdock, Common Buttercup, Small-flowered* Carpetweed Cinquefoil, Common Cinquefoil, Rough Cocklebur, Common Coffeeweed Copperleaf, Virginia Croton, Texas Croton, Woolly Flixweed Galinsoga Geranium, Carolina Hemp, wild Horseweed (Marestail) Jewelweed Jimsonweed Knotweed*_____ ‘These weeds are only partially controlled and may require repeated applications and/or use of higher specified rates of this product even under ideal conditions of application. Ragweed, Common Ragweed, Giant Rape, Wild Rocket, Yellow Salsify, Common* Salsify, Western* Shepherdspurse Sicklepod Smartweed (Annual species)* Sneezeweed, Bitter Sowthistle, Annual Sowthistle, Spiny Spanishneedles Sunflower Sweetclover Tansymustard Thistle, Bull Thistle, Musk* Thistle, Russian (tumbleweed)* Velvetleaf Vetch ANNUALS OR BIENNIALS Kochia Lambsquarters, Common Lettuce, Prickly* Lettuce, Wild Lupines Mallow, Little* Mallow, Venice* Marshelder Morningglory, Annual Morningglory, Ivy Morningglory, Woolly Mousetail Mustards (except Blue Mustard) Parsnip, Wild Pennycress, Field Pepperweed* Pigweed {Amaranthus spp.)* Poorjoe Primrose, Common Purslane, Common Pusley, Florida Radish, Wild

Indigo Creeping Jenny Curly indigo Time of Application Specific Use Instructions Spring Page 8 of 32 Spatterdock Johnswort Stinkweed Sumac RESTRICTIONS FOR USE IN ASPARAGUS • The pre-harvest interval (PHI) is 3 days. • Limited to 2 applications per crop cycle. • Maximum of 2.75 pints of this product per acre per application. • Maximum of 2 lbs. a.e. per acre per application. • Minimum of 30 days between applications. Amount of This Product per Acre (Pts.) 2 to 2.75 pints Sunflower Tanweed Tarweed Toadflax Tumbleweed Vin Apply this product in the Spring on actively growing weeds in 50 to 60 gallons of water per acre by ground or in 12 gallons of water per acre by air. Refer to the "WEEDS CONTROLLED" section of this label for list of weeds. If spears are present, apply this product immediately after cutting. Spears contacted by the spray may be malformed and off-flavored. If spears are malformed by spray, cut immediately and discard. Only apply as postharvest spray using drop nozzles to avoid spraying the fern. CROPS ASPARAGUS PERENNIALS Coffeeweed Cress, Hoary* Dandelion Docks* Dogbanes* Evening primrose. Cutleaf Garlic, Wild* Goldenrod Hawkweed, Orange* Heal-all Ironweed, Western Ivy, Ground* May require repeated application and/or use of the higher specified label rate of this product even under ideal conditions. In California, do not use this product to control Saltcedar. Indian mallow Locoweed Marijuana Mexican weed Nut sedge Loco, Bigbend Nettles (including Stinging) Onion, Wild* Pennywort Plantains Ragwort, Tansy* Sowthistle, Perennial Thistle, Canada* Vervains* Waterplantain Wormwood Alder Alligator weed American lotus Biden Bittersweet Bitter wintercress Blackeyed Susan Blessed thistle Boxelder Buckhorn Bulrush Bur ragweed Chickweed Cockle Common waterplantain Water primrose Water shield Wild strawberry Wild sweet potato Willow Witchweed Wormseed Yellow rocket OTHERS Devil's claw (Proboscidea louisianica) Duckweed Elderberry Frenchweed Goatsbeard Goosefoot Gumweed Henbit Hoary cress* Horsetail Honeysuckle •ginia creeper W^er hyacinth Water lily Alfalfa* Artichoke, Jerusalem* Aster, Many-flowered* Austrian fieldcress* Bindweed (Hedge, Field, European)* Blue lettuce Blueweed, Texas Broomweed Bullnettle * Carrot, Wild* Catnip Chicory Clover, Red*__________________________________________________________________ ‘These weeds are only partially controlled and may require repeated applications and/or use of higher specified rates of this product even under ideal conditions of application. Orange hawkweed* Parrot feather Poison hemlock Poison ivy Pokeweed Povertyweed Puncture vine Purslane Rush Sagebrush SaRcedar* Sheperdspurse Southern wild rose IP

CEREAL GRAINS (Barley, Millet, Oat, Rye, Triticale, Wheat) (Not Underseeded with Legumes) See table for specified use rates. Specific Use Instructions 0.66 to 1.33* 0.33 0.5 to 1 1.75 0.66 Page 9 of 32 Pre-harvest application (All Cereals) Apply after grain is fully tilled, but before boot stage of growth (usually about 4 to 8 inches tall) but not forming joints in the stem and weeds are small. Do not apply before tillering or during early boot through the mill stage of growth. Emergency weed control in Triticale, Wheat: Perennial broadleaf weeds Application Timing/Stage of Growth Barley, Millet, Rye, Triticale, Wheat: Post-emergence Annual and biennial broadleaf weeds Amount of this Product per Acre (Pwte Pts.) 0.33 to 1.33* Oats: Fall Seeded RESTRICTIONS AND LIMITATIONS FOR USE IN CEREAL GRAINS • For aerial application on grain, apply this product in 3 to 10 gallons of water per acre. • For ground application a minimum of 10 to 15 gallons of water per acre is specified for proper spray coverage. • Do not permit dairy animals or meat animals being finished for slaughter to forage treated grain fields within 2 weeks after treatment. • Do not feed treated straw to livestock if an emergency treatment as described above is applied. • Post-emergence: o Limited to one application per crop cycle. o Maximum of 1.75 pints of this product per acre per application. o Do not exceed 1.25 lbs. a.e. per acre per application. Apply after crop is fully tillered (usually 4 to 8 inches tall) but not forming joints in the stem and weeds are small. Do not apply before tillering or during early boot through the milk stage of growth. Do not apply during or immediately following cold weather. Apply when weeds are approaching bud stage, after the grain dough stage. Do not spray during the boot to dough stage. The 1.75 pts./Ac. pints per acre application can produce injury to Wheat. Balance the severity of your weed problem against the possibility of crop damage. Where perennial weeds are scattered, spot treatment is suggested to minimize the extent of crop injury.________ Apply using air or ground equipment to control cereals) weeds that could interfere with harvest, or to suppress perennial weeds. Apply when grain is in dough stage. Do not apply during early boot early boot through milk stage of growth.__________________ *Usethe lower rate ifsmall annual and biennial weeds are the major problem. Use the higher rate if perennial weeds or annual and biennial weeds are present which are in the hard-to-kill categories as determined by local experience. The higher rates increase the risk of crop injury and should be used only where the weed control problem justifies the grain damage risk. Do not apply this product to grain in the seedling stage. Consult state Agricultural Experiment Station or Extension Service Weed Specialist for recommendations or suggestions to fit local conditions. Barley, Millet, Rye, Triticale, Wheat: Post-emergence Perennial broadleaf weeds_______________ Oats: Spring Seeded

CORN (Field Corn, Popcorn and Sweet) Specific Use Instructions 0.33 to 0.66 0.66 0.66 Up to 2 Page 10 of 32 Post-emergence: Perennial Weeds Pre-harvest (Field Corn and Popcorn only) General: For best results, growth conditions should be favorable for active weed growth. Use a high rate in the rate range for less susceptible weeds, cover crops such as alfalfa, weeds in advanced stages of development, or under less favorable growth conditions. • Pre-harvest: o Limited to one application to crop cycle. o Maximum of 0.7 pint (11.2 fl. ozs.) of this product per acre per application, o Do not exceed 0.5 lb. a.e. per acre per application. • Pre-harvest interval (PHI) is 14 days. Pre-plant: Apply 7 to 14 days before planting Corn to control emerged Broadleaf weed seedling or existing cover crops. Pre-emergence: Apply any time after planting, but before Corn emerges to control Broadleaf weed seedlings or existing cover crops. Do not use on light sandy soils. Post-emergence Annual Broadleaf weeds: Crop up to 8 inches tall Precautions: Corn hybrids vary in tolerance to 2,4-D. Apply this product only to varieties known to be 2,4-D tolerant. Consult your seed company representative or local Agricultural Experiment Station or Extension Service Weed Specialist for information on 2,4-D tolerance of Corn varieties. Application of this product may cause temporary stem brittleness in Corn. To avoid stem breakage, delay cultivation for 8 to 10 days following application. Apply when weeds are small and Corn is less than 8 inches tall (to top of canopy). If Corn is more than 8 inches tall, use drop nozzles and keep spray off foliage. Treat perennial weeds when they are in the bud to bloom stage. Do not tank mix with atrazine, oil or other adjuvants. To avoid crop injury, do not apply from tasseling to hard dough stage. NOTE: Corn treated with 2,4-D may become temporarily brittle. Wind or cultivation may cause stem breakage during the period of time that Corn is brittle. Sweet Corn: To minimize potential for crop injury, use only the lowest rate in rate range. Application Timing/Stage _of Growth Pre-plant (Burndown), Pre-emergence Amount of this Product per Acre (Ptnte Pts.) 0.66 to 1.33 Post-emergence Annual Broadleaf weeds: Crop 8 inches tall to tasseling (Directed spray only) Apply after Corn is in hard dough (or denting) stage.

o o FILBERTS (Not For Use in California) Page 11 of 32 o o o o RESTRICTIONS FOR USE IN FILBERTS • Do not apply within 45 days of harvest. • Allow at least 30 days between applications. • Do not make more than 4 applications per year. • Do not apply more than 1.375 pints of this product per 100 gallons of spray solution per application. • Maximum of 1 lb. a.e. per 100 gallons of spray solution per application. RESTRICTIONS AND LIMITATIONS FOR USE IN FIELD AND POPCORN • Pre-harvest Interval (PHI) is 7 days. • Do not harvest for grain or fodder for 7 days following application. • Maximum use rate per acre per crop cycle is 4.2 pints. • Pre-plant or Pre-emergence: o Limited to ©ne 1 application per crop cycle. Maximum of 1.33 pints per acre per application. • Post-emergence: Limited to one application per crop cycle. Maximum of 0.66 pints per acre per application. • Pre-harvest: Limited to-ene 1 application per crop cycle. Maximum of 2 pints per acre per application. RESTRICTIONS AND LIMITATIONS FOR USE IN SWEET CORN • Pre-harvest Interval (PHI) is 45 days. • Do not harvest for grain or fodder for 7 days following application. • Minimum of 21 days between applications. • Maximum use rate per acre per crop cycle is 2 pints. • Pre-plant or Pre-emergence: o Limited to 1 application per crop cycle, o Maximum of 1.33 pints per acre per application. • Post-emergence: o Limited to 1 application per crop cycle. Maximum of 0.66 pints per acre per application. Amount of this Product per Acre (Pwte Pts.) 1 to 1.33 Target Suckers Specific Use Instructions Apply in 100 gallons ofwater per acre. Use nozzles with large orifice nozzles and low tank pressure. Spray to the point of runoff when suckers are 6 to 9 inches tall. Apply when needed from April through August.

HOPS Application Timing Specific Use Instructions Post-emergence ORCHARD FLOORS (Pome Fruits*, Stone Fruits**, Tree Nuts*** and Pistachios) Specific Use Instructions 0.66 to 1.33 Up to 2.66 Page 12 of 32 Post-emergence: Perennial weeds Time of Application / Target Weeds Amount of this Product per Acre (Pints Pts.) o o o o o o o o o For application to orchard floors, use coarse, low pressure sprays and sufficient water for thorough coverage of weeds. Apply to annual weeds when small and actively growing. Apply to perennial weeds from bud to bloom stage. Make directed applications to the row middles. Make up to 3 applications at 30 day intervals with the last application before harvest.____________________ Precautions: Hop foliage, especial y new grov/th, is susceptible to this product. Take care to avoid spray or drift outside target area. The use of shielded or hooded sprayers, coarse sprays and low pressure (30 psi or less) will minimize contact with foliage and plant injury. This product contains 0.7 pound of 2,4-D per pint. When tank mixing with products that contain 2,4-D, do not exceed a combined total of 1.5 lbs. a.e. per crop cycle. ‘Pome fruits including Apples, Crabapples, Loquat, Mayhaw, Oriental Pear, Pears, Quince **Stone fruits including Apricot, Chickasaw plum, Damson plum. Fresh prunes, Japanese plums. Nectarines, Peadies, Plums. Plumcot, Sweet cherry. Tart Cherry ***Tree nuts including Almonds, Beech nut. Black walnut, Brazil nut. Butternut, Cashew, chestnut. Chinquapin, English walnut. Hickory nut. Macadamia nut (bush nut). Pecan. (Excludes Filberts. For use on Filberts, see "FILBERTS" section.) RESTRICTIONS AND LIMITATIONS • Pome Fruits: o Do not apply within 14 days of harvest. o Maximum of 2.66 pints of this product (2 lbs. a.e.) per acre per application, o Allow a minimum of 75 days between applications, o Do not cut forage for hay within 7 days after last application. • Stone Fruits: Allow at least 75 days between applications. Do not apply within 40 days of harvest. Maximum of 2.66 pints of this product (2 lbs. a.e.) per acre per application. Allow a minimum of at least 30 days between applications. Do not cut forage for hay within 7 days after last application. RESTRICTIONS AND LIMITATIONS FOR USE IN HOPS • Pre-harvest Interval (PHI) is 28 days. • Post-emergence: Limited to 3 applications per crop cycle. Maximum of 0.66 pint (10.5 fl. ozs.) of this product per acre per application. Maximum of 0.5 lb. a.e. per acre per application. Maximum of 1.5 lbs. a.e. of this product per acre per crop cycle. Minimum 30 days between applications. Post-emergence: Annual and Biennial weeds Amount of this Product per Acre (Pwte Pts.) 0.66 (10.5 fl. ozs.)

RICE (Not For Use in California) Weeds in Crop Specific Use Instructions Pre-plant Post-emergence0.66 to 1.33 Page 13 of 32 General Precautions: Rice varieties vary in tolerance to 2,4-D, or may be susceptible to injury under certain conditions or stages of growth. Do not apply at early seedling stage or after Rice internodes exceed one-half inch or panicle initiation. Consult your seed company representative or local Agricultural Experiment Station or Extension Service Weed Specialist for information on 2,4-D tolerance of Rice varieties, including optimum rates and timing. • Tree Nuts and Pistachios: o Maximum of 2.66 pints of this product per acre per application, o Maximum of 2 lbs. a.e. per acre per application. o Allow a minimum of least 30 days between applications, o Do not apply within 60 days of harvest. o Do not cut forage for hay within 7 days after last application, o Do not make more than 2 applications per year. RESTRICTIONS AND LIMITATIONS FOR USE IN RICE • Pre-harvest Interval (PHI) is 60 days. • Maximum of 1.5 lbs. a.e. per acre per crop cycle. • Pre-plant: o Limited to 1 application per crop cycle. o Maximum of 1.33 pints of this product per acre per application, o Maximum of 1 lb. a.e. per acre per pre-plant application. • Post-emergence: o Limited to 1 application per crop cycle. o Maximum of 1.5 lbs. a.e. per acre per application. Amount of This Product per Acre (Ptnte Pts.) 0.66 to 1.33 Use Precautions: • Because newly established trees or young orchards are more susceptible to 2,4-D injury, apply only to orchards that are at least one year old and well-established as indicated by vigorous plant growth. • To avoid tree injury, do not allow spray drift to contact foliage, fruit, stems, trunks or trees or exposed roots. • Do not apply when orchards are blooming. • Do not make orchard floor applications in areas with light sandy soils. • Avoid application immediately before irrigation and withhold irrigation for 2 days before and 3 days after application. Apply 2 to 4 weeks prior to planting Rice. DO NOT USE IN CALIFORNIA. _______________ Apply when Rice is in the late tillering stage of development at the time of first joint development (first to second green ring). Do not apply after panicle initiation, after Rice internodes exceed one-half inch, at early seedling, early panicle, boot or heading stages. Consult local university or Agricultural Extension Service specialists for more specific information on rates and timing of application. DO NOT USE IN CALIFORNIA.

WILD RICE (For Use in Minnesota Only) Application Timing Specific Use instructions SORGHUM (Grain Sorghum (Milo) and Forage Sorghum) WEEDS IN CROPS Specific Use Instructions 0.5 to 1 Do not use with oil or other adjuvants. Page 14 of 32 Grain Sorghum (Milo): 4 to 10 inches Grain Sorghum (Milo): 10 inches and above Do not treat during the boot, flowering or dough stage. Higher rates may be used to control some hard to control weeds. Broadcast in 4 to 10 gallons total spray volume. Do not spray after wild Rice has reached the boot stage. Apply when Sorghum is 6 to 15 inches tall with secondary roots well established. If Sorghum is taller than 8 inches to top of the canopy, use drop nozzles and keep spray off the foliage. Precautions: Temporary crop injury can be expected under conditions of high soil moisture and high air temperatures. If it is necessary to apply this product under these conditions, use no more than 0.66 pint per acre. Sorghum hybrids vary in 2,4-D tolerance. Apply only to varieties known to be tolerant to 2,4-D. Consult your seed company representative or local agricultural experiment station or extension service weed specialist for information on 2,4-D tolerance of Sorghum varieties. RESTRICTIONS FOR USE IN WILD RICE • For use in Minnesota only. • Pre-harvest interval (PHI) is 60 days. • Post-emergence: Limited to 1 application per crop cycle. Maximum of 0.33 pint per acre per application. Maximum of 0.25 lb. a.e. per acre per application. For use only on wild Rice grown in commercial paddies. Do not apply to wild Rice growing in lakes or streams. Water that is drained out of wild Rice paddies is not to be used to irrigate other crops. In order to protect federally listed endangered species, the Minnesota Department of Agriculture has a program to pre­ notify landowners where pesticide applications may affect federally listed endangered or threatened species. Apply wild Rice is in the 1 to 2 aerial leaf to early tillering stage and after Waterplantain has emerged from the water and when Wild rice is in the 1 to 2 aerial leaf stage. Amount of this Product per Acre (Pints Pts.) 0.33 to 1 Amount of this Product per Acre (Pints Pts.) 0.33

Application Timing Specific Use Instructions Pre-plant {Burndown) 0.66 to 1 Page 15 of 32 Important Notice: Unacceptable injury to Soybeans planted in treated fields may occur. Whether or not soybean injury occurs and the extent of such injury will depend on weather (temperatures and rainfall) from herbicide application until soybean emergence and agronomic factors such as the amount of weed vegetation and previous crop residue present at the time of application. Injury is more likely to occur under cool rainy conditions and where there is less weed vegetation and crop residue present. Tank-Mixture: This product may be applied pre-plant to Soybeans in tank-mixtures with other herbicides such as Imitator® Plus, Quik-Quat™, Honcho®, Poast®, Poast Plus®, Prowl®, Pursuit Plus®, Scepter®, Scepter Plus®, Squadron® and others that are registered for pre-plant use in Soybeans. Crop oil concentrates, agricultural surfactants and fluid fertilizers approved for use on growing crops may be added to spray mixtures of this product to increase the herbicidal effectiveness on certain weeds. Read and follow all directions and precautions on this label and on the label of each product added to the spray mixture. Follow the most restrictive labeling. Refer to the "MIXING" section of this label for tank mixing instructions and compatibility testing. o o PRECAUTIONS AND RESTRICTIONS FOR SOYBEANS • Apply no less than 15 days before planting Soybeans when weeds are small and actively growing. • IMPORTANT; Unacceptable injury to Soybeans planted in treated fields may occur. Whether or not Soybean injury occurs and the extent of such injury will depend on weather (temperature and rainfall) from herbicide application until Soybean emergence and agronomic factor; such as the amount of weed vegetation and previous crop residue present at the time of application. Injury is more likely under cool rainy conditions and where there is less weed vegetation and crop residue present. • Do not disturb treated soil through tillage between application and planting of Soybeans. • Do not use on sandy soils with less than 1% organic matter. SOYBEANS For Use in Crop Residue Management Systems (Pre-plant Burndown Application Only) Amount of this Product per Acre (Wnte Pts.) 0.5 to 0.66 See “Precautions and Restrictions for Soybeans” below.__________ Apply not less than 30 days before planting Soybeans when weeds are small and actively growing. Use the higher rate on larger weeds and when perennials are present. See “Precautions and Restrictions for Soybeans” below.__________ Compatible crop oil concentrates, agricultural surfactants and fluid fertilizers approved for use on growing crops may be added to spray mixtures to increase the herbicidal effectiveness on certain weeds. Read and follow all directions and precautions on this label and on the label of each product added to the spray mixture. RESTRICTIONS AND LIMITATIONS FOR USE IN SORGHUM • Sorghum (Milo): Pre-harvest Interval (PHI) is 30 days. Do not harvest grain for 30 days Do not permit meat or dairy animals to consume treated crop as fodder or forage for 30 days following application. Post-emergence: Limited to 1 application per crop cycle. Maximum of 1 lb. a.e. per acre per application.

OR STRAWBERRIES (Established planting only) Application Timing Specific Use Instructions Dormant or After Last Picking SUGARCANE Specific Use Instructions 2 to 2.66 Page 16 of 32 Apply in established Strawberry plantings only. Do not apply unless possible injury to the crop is acceptable. Follow recommendations of State Extension Horticultural Specialist in the area. • Do not replant fields treated with this product in the same growing season with crops other than those labeled for 2.4-D pre-plant use. Amount of This Product per Acre (Pinte Pts.) 2 Apply before canes appear for control of emerged broadleaf weeds. Do not use in California.__________ Apply after cane emerges and through lay-by {canopy closure). Use higher rate in the rate range for perennial weeds and difficult to control weeds. Do not use in California. RESTRICTIONS FOR USE IN STRAWBERRIES: DO NOT APPLY IN CALIFORNIA OR FLORIDA. Dormant or after last picking; Limited to 1 application per crop cycle. Maximum of 1.5 lbs. a.e. per acre per application. Amount of this Product per Acre (Pwrts Pts.) 1.33 to 2.0 Post­ emergence Apply in 25 to 50 gallons of water per acre. Pre-plant: o Limited to 1 application per crop cycle. o Maximum of 1 lb. a.e. per pre-plant application, o Apply not less than 30 days prior to planting Soybeans. Weeds in Crop Pre-emergence • In treated fields, plant soybean seed as deep as practical, but not less than 1 inch deep. Adjust the planter, if necessary, to ensure that planted seed is adequately covered. • Do not pre-plant apply this product in Soybeans unless you are prepared to accept the results of soybean injury, including possible stand loss and/or yield reduction. • During the growing season following application, do not replant treated fields with crops other than those labeled for use with this product. • Do not apply more than 1 lb. a.e. per acre per use season. • Pre-plant: o Limited to 2 pre-plant applications per crop cycle. o Maximum of 0.5 lb. a.e. per acre per pre-plant application. o Apply no less than 15 days prior to planting Soybeans.

SUGARCANE (HI Only) Time of Application Specific Use Instructions feet above ground (pre-emergence) inopy (post emergent broadcast) Page 17 of 32 Pre-emergence, Post-emergence This product contains 0.7 pound a.e. of 2,4-D per pint. When tank mixing with products that contain 2,4-D, do not exceed a combined totai of 4 pounds a.e. per crop cycle. Limited to 1 appiication per crop cycie. Maximum of 2 ibs. a.e. per acre per appiication • Post-emergence: Limited to 1 application per crop cycle. Maximum of 2 Ibs. a.e. per acre per application. Amount of This Product per Acre (Pints Pts.) 0.66 to 2 o o RESTRICTIONS AND LIMITATIONS FOR USE IN SUGARCANE • Do not use in California. • Do not harvest cane prior to crop maturity. • Do not apply more than 4 Ibs. a.e. per acre per crop cycle. • Pre-emergence: o o If used in the islands of Maui and Kauai, the general wind restriction is raised to 20 mph. When applying in winds in excess of 15 mph, the following requirements are in effect: Aerial Application: • No application shall be made within a distance of 1000 feet of sensitive areas such as Nature Preserves, Wildlife Refuges, Parks, Lakes, Reservoirs, Rivers, Streams, Non-irrigation Canals, Natural Ponds, Estuaries, Wetlands, Intertidal Areas, Ecologically Significant Grasslands, homes, public or private buildings, or fields with crops other than sugarcane whenever these sensitive areas are downwind from the spray areas and subject to possible spray drift. In instances where these sensitive areas are upwind from the spray area, the minimum restricted distance shall be 300 feet. • Apply only as a coarse or coarser spray (ASAE standard 572 or a volume mean diameter of 385 microns). • Use a spray drift retardant and/or other measures known to control drift. Ground Broadcast Applications: • Apply by around boom with nozzle height no more than 2 feet above ground (pre-emergence) or crop canopy (post emergent broadcast) applications or, for directed sprays, no more than 1 foot above the ground, or 1.25 ft. (15 inches) for better spray patterns without boom levelers on uneven terrain. • Apply only as a coarse or coarser spray (ASAE standard 572) or a volume mean diameter of 385 microns. • Use spray drift retardants and/or other measures known to control drift. Applications techniques to reduce off-site drift include, but are not limited to, the use of hooded or shielded sprayers or other means to reduce drift.

FALLOW LAND AND CROP STUBBLE Types of Weeds Specific Use Instructions Annual Broadleaf weeds Biennial Broadleaf weeds 1.33 to 2.66 Perennial Broadleaf weeds 1.33 to 2.66 2.66 Page 18 of 32 Wild garlic and Onion in crop stubble Planting in Treated Areas (Labeled Crops): Plant only labeled crops within 29 days following application. Follow more specific limitations, if any, provided in directions for specific crops. Labeled crops may be at risk of crop injury or loss if planted soon after application, especially during the first 14 days. Degradation factors described below should be considered in weighing this risk. All other crops may be planted 30 days or more after application without concern for illegal residues in the planted crop. However, under certain conditions, there may be a risk of injury to susceptible crops. Degradation factors described below should be considered in weighing this risk. Under average conditions, any crop may be planted without risk of injury if at least 90 days of soil temperatures above freezing have elapsed since application. General Precautions: Degradation Factors: When planting into treated areas, the risk of crop injury is less if lower rates of product were applied and conditions following application have included warm, moist soil conditions that favor rapid breakdown of 2,4-D. Risk is greater if higher rates of product were applied and soil temperatures have been cold and/or soils have been excessively wet or dry in the days following application. RESTRICTIONS FOR USE IN SUGARCANE (HI Only) • Do not harvest cane prior to crop maturity. • Do not apply more than 4 lbs. a.e. per acre per year. • Limited to 1 pre-emergence application per crop cycle. • Post-emergence: Limited to 1 application per crop cycle. Do not apply more than 2 lbs. a.e. per acre per application. Lay-by application can be made but crop damage may occur in some sugarcane varieties. Amount of This Product per Acre _(Pints Pts.) 0.66 to 1.33 Use a lower rate in the rate range when weeds are small (2 to 3 inches tall) and conditions are favorable for active growth and a higher rate in the rate range when weeds are larger and/or growing conditions are less favorable. Apply when musk thistles or other biennial species are in the seedling to rosette stage and before development of flower stalks. Use lower rates in the rate range in the spring during the rosette stage and the highest rate in the rate range in the fall or when flower stalks have developed. Apply when perennial weeds are in bud to bloom stage and actively growing. Do not disturb treated areas for at least 2 weeks after application or until top growth is dead. Apply to new regrowth of wild garlic or onion that stubble occurs in the fall after harvest of other crops.

TURFGRASS USES Weeds in Crop Specific Use Instructions 0.5 to 0.66 1.33 to2 2 Page 19 of 32 ORNAMENTAL TURF: (Excluding Grasses Grown For Seed or Sod Farms) (Includes Golf Courses, Cemeteries, Parks, Sports fields, Turfgrass, Lawns, Airfields, Roadsides, Vacant lots and other Grass areas) This product contains 0.7 pound a.e. of 2,4-D per pint. When tank mixing with products that contain 2,4-D, the maximum season rate is 3 lbs. a.e. per acre, excluding spot treatments. Post-emergence: Well-established grasses Post-emergence: Biennial and perennial broadleaf weeds Amount of This Product per Acre (Pints Pts.) Precautions: • Do not use on creeping grasses such as Bentgrass except as a spot treatment. • Do not use on injury-sensitive southern grasses such as St. Augustinegrass. • Do not use on Dichondra or other herbaceous ground covers. Legumes may be damaged or killed. • Do not reapply within 21 days of previous application. • Reseeding: Delay reseeding at least 30 days following application. Preferably, with Spring application reseed in the Fall and with Fall application, reseed in the Spring. This product contains 0.7 pound a.e. of 2,4-D per pint. When tank mixing with products that contain 2,4-D, do not exceed a combined total of 4.0 pounds of a.e. per acre per year. Apply when weeds are small and actively growing. For best results, apply when soil moisture is adequate for active weed growth. Deep-rooted perennial weeds such as Bindweed and Canada thistle may require repeat applications. Do not apply to newly seeded' grasses until well established (5-leaf stage or later) and then use a maximum of 0.66 pints/aore pt./Ac. Cool season grasses are tolerant of higher rates. RESTRICTIONS FOR USE IN FALLOWLAND • Pre-harvest Interval: Do not cut forage for hay within 7 days of application. • Make no more than two applications per year. • Do not apply more than 2.66 pints per acre per application. • Minimum spray interval between applications is 30 days • Plant only labeled crops within 29 days following application. RESTRICTIONS FOR USE IN ORNAMENTAL TURFGRASS • Do not apply more than 2 pints per acre per application. • Maximum of 1.5 lbs. a.e. per acre per application. • Do not make more than 2 applications per year. • The maximum seasonal rate is 3 lbs. a.e. per acre, excluding spot treatments. • Minimum spray interval between broadcast applications is 30 days. Post-emergence: Seedling grass (5-leaf stage or later)

TURF GROWN FOR SEED OR SOD Specific Use Instructions 1.33 to 2.66 Sod Farms 1.33 to 2.66 Page 20 of 32 Agricultural Use Requirements for Forest Use (Except Tree Injection Use): For use in forests, follow PRE and re-entry instructions in the “AGRICULTURAL USE REQUIREMENTS" Agricultural Use Requirements section under the “DIRECTIONS FOR USE" heading of this label. Agricultural Use Requirements for Rangeland, Pasture, Forest (Tree Injection Only) and Noncropland Areas: When this product is applied to Rangeland and established Pastures not harvested for hay or seed; non-cropland areas, and when applied by tree injection in forest sites, follow re-entry requirements given in the “NON-AGRICULTURAL USE REQUIREMENTS" t4on-Agf\Gu{\jra\ Use Requirements section under the “DIRECTIONS FOR USE ” heading of this label. Use Precautions and Restrictions: • Maximum rate per application is 2 lbs. a.e. per acre per application. • Do not use on creeping grasses such as Bentgrass except for spot treatment. • Do not use on susceptible southern grasses such as St. Augustinegrass. • Do not use on Dichondra or other herbaceous ground covers; legumes may be damaged or killed. • Do not reapply to a treated area within 21 days of a previous application. • Reseeding: Delay reseeding at least 30 days following application. Preferably, with Spring application reseed in the Fall, and with Fall application, reseed in the Spring. • Pre-harvest interval: Do not cut forage for hay within 7 days of application. • Do not make more than 2 applications of this product per year. Treatment Site (Application and Timing) Grasses Grown for Seed (Post-emergence): Seedling grass (5-leaf stage or later) FORESTRY, RANGELAND, ESTABLISHED PASTURES, AND NON-CROPLAND AREAS (Including Perennial Grasslands Not In Agricultural Production Such as Conservation Reserve Program Acres) Amount of This Product per acre (Pints Pts.) 0.5 to 0.66 Grasses Grown for Seed (Post-emergence): Well-established grasses Apply when weeds are small and actively growing. For best results, apply when soil moisture is adequate for active weed growth. Do not apply to newly seeded grasses until well established (5-leaf stage or later) and then use a maximum of 0.66 pts./Ac. pints per acre. Cool season grasses are more tolerant to higher rates. For grasses grown for seed, do not apply to grass in the early boot through milk stage. When grass is well established, higher rates of up to 2.66 pts./Ac. pints per acre may be applied for control of hard to kill annual or perennial weeds.________________________ Deep-rooted perennials such as bindweed and Canada thistle may require repeat applications. Avoid mowing sod farms for 2 days before or after application. Delay irrigation until the day following application.

Specific Use Instructions 2.66 to 5.33 pts. 2 to 4 pts. Page 21 of 32 Spot Treatment to control Broadleaf weeds Basal spray (May also be used in Rangeland, Pastures and Non­ cropland) Directed Spray: Conifer plantations including Pine 5.33 ptSr pts./100 gals, per 100 gallons of spray solution 10.66 pts pts./100 gals, per 100 gallons of spray solution Conifer Release; Species such as White pine, Ponderosa pine. Jack pine. Red pine, Black spruce, White spruce. Red spruce, -Land Balsam fir 0.85 fl. oz. per gallon fl. oz./gal. of spray solution (See instructions for “Spot Treatment”) TREATMENT SITE METHOD OF APPLICATION _______ Annual Weeds Biennial and perennial Broadleaf weeds and susceptible woody plants Apply when weeds are small and growing actively before the bud stage. Apply when biennial and perennial species are in the seedling to rosette stage and before flower stalks appear. For difficult to control perennial broadleaf weeds and woody species use up to 5.33 pints pts. of this product and 1 to 4 quarts qts. of a Triclopyr (3 Ibs./gal.) herbicide product per acre. Note: To control Broadleaf weeds in small areas with a hand sprayer, use an application rate equivalent to the specified broadcast rate and spray to thoroughly wet all foliage. See “Rate Conversion Tab/e” and instructions for "Spot Treatment" and use of hand-held sprayers under "APPLICATIONS". To control competing hardwood species such as Alder, Aspen, Birch, Hazel and Willow, apply from mild to late Summer when growth of Conifer trees has hardened off and woody plants are still actively growing. Apply with ground or air equipment, using sufficient spray volume to ensure complete coverage. Because this treatment may cause occasional Conifer injury. Do not apply if such injury cannot be tolerated._______________ Apply when brush or weeds are actively growing by directing the spray so as to avoid contact with Conifer foliage and injurious amounts of spray. Apply in oil, oil-water, or water carrier in a spray volume of 10 to 100 gallons per acre. gals./Ac.______ Thoroughly wet the base and root collar of all stems until the spray begins to accumulate around the root collar at the ground line. Wetting stems also with the mixture may aid in control. FORESTRY USES Forest Site Preparation, Forest Roadsides, Brush Control and Established Conifer Release (Including Christmas Trees and Reforestation Areas)__________________ Amount of This Product per Acre 1.33 to 2.66 pts.

1 to 2 mL per injection site Page 22 of 32 Use Precautions and Restrictions: • Do not allow sprays to contact Conifer shoot growth (current year's new growth) or injury may occur. • Do not apply to nursery seedbeds. • For Conifer release, do not use on plantations where larch is among the desired species. • For broadcast applications, do not apply more than 5.33 pints of this product per acre per 12 month period. Maximum of 4 lbs. a.e. per acre per broadcast application. Limited to 1 broadcast application per year. • For basal spray, cut surface stumps, and frill applications, do not apply more than 8 lbs. a.e. per 100 gallons of spray solution. Limited to 1 basal spray or cut surface application per year. • For injection application, limit to 1 injection application per year. Maximum of 2 mL of 4 lbs. a.e. formulation per injection site. Surface of cut stumps (May also be used in Rangeland, Pastures and Non-cropland) 1.75 fluid ounces per gallon fl. oz./gal. of water 1.75 fl. ozs/gal. of water To control and prevent the sprouting of unwanted hardwood tress such Elm, Hickory, Oak and Sweetgum in forest and other non-crop areas, apply by injecting 1 mL of this product undiluted per inch of trunk diameter as measured at breast height (OBH), approximately 4.5 feet above the ground. Injection sites, however, should be as close to the root collar as possible and the injection bit must penetrate the inner bark. Applications may be made throughout the year, but for best results apply between May 15 and October 15. Do not treat Maples used for maple syrup production. For hard to control species such as Ash, Maple and Dogwood use 2 mL of this product undiluted per injection site or double the number of 1 mL injections. Note: No Worker Protection Standard worker entry restrictions or worker notification requirements apply when this product is directly injected into agricultural plants. Frill and Girdle (May also be used in Rangeland, Pastures and Non- cropland) ________________ Tree injection application (May also be used in Rangeland, Pastures and Non-cropland) Apply as soon as possible after cutting trees. Thoroughly wet the cambium layer of the cut surface being careful to wt the entire circumference.______________ Cut frills (overlapping V-shaped notches)

Specific Use Instructions 1.33 to 2.66 2.66 1.33 to 2.66 1.33 2.66 2.66 Up to 2.66 Page 23 of 32 Sand shinnery oak Sand sagebrush Southern wild rose: broadcast application Biennial and perennial Broadleaf weeds Big sagebrush Rabbitbrush Target Weeds or Woody plants Rangeland, Established Grass Pastures (Including Perennial Grasslands not in Agricultural Production such as Conservation Reserve Program Acres): Spot treatment to control broadleaf weeds Annual broadleaf weeds Broadcast: Apply in a spray volume of 5 gallons gals, or more per acre by aircraft or 10 gallons or more per acre by ground equipment. 0.85 fl. oz./gal. per gallon of spray solution (see instructions for “Spot Treatment’} Tree injection application__________ Wild garlic and Wild onion______________ Broadleaf weed control in newly sprigged coastal bermudagrass For best results, apply when weeds are small and growing actively before the bud stage. Apply when musk thistles or other biennial species are in the seedling to rosette stage and before flower stalks appear. Refer to the “WEEDS CONTROLLED ” section for a listing of susceptible weed species and weeds that may be only partially controlled and require repeat applications and/or use of higher specified rates, even under ideal conditions of application_________________________________ To control Broadleaf weeds in small areas with a hand sprayer, use an application rate equivalent to the broadcast rate specified for this treatment site and spray to thoroughly wet all foliage. Mix 0.85 fl. oz. of spray solution per gallon and apply through pump-up sprayer or backpack sprayer. Add non­ ionic surfactant to improve coverage. Refer to "Spot Treatments" section for instructions and rate conversion table under "APPLICATIONS" section of this label.__________________________________ See instructions for “Tree Injection Application" in "Forestry Uses" section._______________________ Make three applications (fall-spring-fall or spring-fall spring) starting in late Fall or early Spring.________ Applications may be made either pre-emergence or post-emergence. Follow specific use instructions for annual, biennial and perennial broadleaf weed control above.______________________________ Sand shinnery oak: Apply by aircraft between May 15 and June 15. Sand sagebrush: Apply by ground or aircraft when foliage is fully expanded and plants are actively growing. Use a 1:4 oil-water emulsion as carrier and a spray volume of 3 to 5 gallons per acre. gals./Ac.________ Apply by ground or aircraft when foliage is fully expanded and plants are actively growing. Use a 1 ;4 oil-water emulsion as carrier and a spray volume of 3 to 5 gallons per acre. gals./Ac. Retreatment may be needed._________________________________ Apply by ground or aircraft when foliage is fully expanded and plants are actively growing. Use water or 1:4 oil-water emulsion as carrier and spray volume of 5 to 10 gallons per acre. gals./Ac. Retreatment may be needed. Buckbrush, Chamise, Chaparral species, Coastal sage. Coyotebrush and Manzanita Amount of This Product per Acre (P4nts Pts.) 1.33

CRP Acres Grasses (Pastures and Rangeland Not in Agricultural Production) Weeds in Crop Specific Use Instructions 2.5 to 2.85 Page 24 of 32 Annual broadleaf weeds Southern wild rose: Spot treatment Biennial and perennial broadleaf weeds 0.85 fl. oz./gal. per gallon of spray solution Do not apply more than 2 applications per year. For susceptible annual and biennial broadleaf weeds; Use 1 lb. a.e. per acre per application. For moderately susceptible biennial and perennial broadleaf weeds; Use 1 to 2 lbs. a.e. per acre per application. For difficult to control weeds and woody plants: Use 2 lbs. a.e. per acre per application. Spot treatment: Use 2 lbs. a.e. per acre. The maximum rate is 4 lbs. a.e. per acre per year. Minimum of 30 days between applications. If grass is to be cut for hay, Agricultural Use Requirements for the Worker Protection Standards are applicable. o o o o o Apply when weeds are small and actively growing and prior to bud stage. Spray while musk thistles or other biennial species are in the seedling to rosette stage and before flower stalks become apparent. The lower rate can be used in the spring during rosette stage. Use the highest rate in the fall or after flower stalks have developed. Do not apply to newly areas Until grass is well established. Do not apply to grass in the early boot through milk stage if grass seed production is desired. Bentgrass and legumes may be injured by this treatment Spot treatment: Apply when foliage is well developed. Thorough coverage is required. Mix 0.85 fluid ounce fl. oz. of spray solution per gallon and apply through pump up sprayer or backpack sprayer. Add non-ionic surfactant. Two or more treatments may be required. Do not exceed 2.66 pints per acre pts./Ac. per application.___________ For program lands such as CRP, consult program rules to determine whether grass or hay may be used. The more restrictive requirements of the program rules or this label must be followed. Livestock Feeding Restrictions: • Do not cut treated grass for hay within 7 days after application. • Do not graze dairy animals on treated areas within 7 days after application. • Do not graze meat animals on treated areas within 3 days before slaughter. Amount of This Product per Acre (Pints Pts.) 2 to 2.5 RESTRICTIONS AND PRECAUTIONS FOR USE IN PASTURES AND RANGELANDS • Do not use on Bentgrass, Alfalfa, Clover or other legumes. • Do not use on newly seeded areas until grass is well established. • Do not use from early boot to milk stage where natural grass reseeding is desired. • For government program grasslands, follow program grazing restrictions if more restrictive than those given above. • Post-emergence: o o o

Specific Use Instructions 1.33 to 2.66 pints pts. 2.66 pints pts. Upto 5.33pints-pts. Page 25 of 32 Biennial and perennial Broadleaf weeds Non-Cropland Areas (Such as Fencerows, Hedgerows, Roadsides, Drainage ditches, Rights-of way, Utility power lines. Tailroads and other non-crop areas) 0.66 gallon per 100 gallons gal./lOO gals, of spray solution Southern wild rose: Spot treatment Broadcast: Apply in a spray volume of 5 gallons or more per acre by aircraft or 10 gallons or more per acre by ground equipment. Spot Treatment: Apply when foliage is well developed. Thorough coverage is required. Mix 0.85 fluid ounce fl. oz. of spray solution per gallon and apply through pump-up sprayer or backpack sprayer. Add non-ionic surfactant to improve coverage. Two treatments or more may be required. o o o o Amount of This Product per Acre Target weeds or Woody plants Annual broadleaf weeds For program lands such as Conservation Reserve Program (CRP), consult program rules to determine whether grass or hay may be used. The more restrictive requirements of the program rules or this label must be followed. RESTRICTIONS AND PRECAUTIONS FOR USE IN GRASSES (Pastures and Rangeland Not in Agricultural Production) • The pre-harvest interval (PHI) is 7 days (cut forage for hay). • Post-emergence: Limited to 2 applications per year. Maximum of 2 lbs. a.e. per acre per application. Minimum of 30 days between applications. If grass is to be cut for hay, Agricultural Use Requirements for the Worker Protection Standard are applicable. Susceptible woody plants on rights-of- way Woody plants: Basal spray, Cut surface, Frill and Girdle and Tree injection application methods Southern wild rose: Broadcast application Apply when annual weeds are small and growing actively before the bud stage. Biennial and perennial weeds should be at rosette to bud stage, but not flowering at the time of application. For difficult to control perennial broadleaf weeds and woody species, tank mix up to 2.66 quarts qts. of this product plus 1 to 4 quarts qts. of Triclopyr 3A per acre. Oil or wetting agent may be added to the spray, if needed for increased effectiveness. For ground application (high volume): apply a total spray volume of 100 to 400 gallons per acre gals./Ac.; (low volume) apply a total spray volume of 10 to 100 gallons per acre gals./Ac. For helicopter: Apply a total spray volume of 5 to 30 gallons per acre._________________________________ Note: To control Broadleaf weeds in small areas with a hand sprayer, use an application rate equivalent to the broadcast rates specified for this treatment site and spray to thoroughly wet all foliage. Mix 0.85 fl. oz. of spray solution per gallon and apply through pump up sprayer or backpack sprayer. Add non-ionic surfactant to improve coverage. Refer to "Spot Treatment" section for instructions and rate conversion table under "APPLICATIONS ” section of this label.________________ Refer to the “Forestry Uses” section for specific use instructions for these application methods. Spot treatment to control Broadleaf weeds 2.66 to 5.33 pints pts. 0.85 fl. oz./gal. per gallon of spray solution (See “Spot Treatment” instructions)

AQUATIC USES Control of Weeds and Brush on Banks of Irrigation Canals and Ditches Target weeds Specific Use Instructions Annual weeds 2.66 square feet (10.5 X 10.5 steps). Page 26 of 32 Do not use on small canal with a flow rate less than 10 cubic feet per second (CFS) where water will be used for drinking purposes. CFS may be estimated by using the formula below. The approximate velocity needed for the calculation can be determined by observing the length of time that it takes a floating object to travel a defined distance. For woody species and patches of perennial weeds, mix 0.66 gallon gals. (5.33 pts.) of DMA 6 per 64 to 150 gallons gals, of total spray. Wet foliage by RESTRICTIONS AND PRECAUTIONS FOR NON-CROPLAND AREAS • Do not apply to newly seeded areas until grass is well established. • Bentgrass, St. Augustinegrass, clover, legumes and Dichondra may be severely injured or killed by this treatment. • Annual and perennial weeds (post-emergence): Do not apply more than 2 lbs. a.e. per acre per use season. Do not make more than 2 applications per season. Minimum of 30 days between applications. • Woody plants (post-emergence): Do not apply more than 4 lbs. a.e. per acre per use season. Do not make more than 1 application per year. • Applications to non-cropland areas are not applicable to treatment of commercial timber or other plants being grown for sale or other commercial use, or for commercial seed production or for research purposes. Amount of This Product per Acre {Pints Pts.) 1.33 to 2.66 Apply when weeds are small and growing actively before the bud stage. Apply when biennial and perennial species are in the seedling to rosette stage and before flower stalks appear. For hard-to-control weeds, a repeat application after 30 days at the same rate may be needed. Apply using low pressure spray (10 to 40 psi) in a spray volume of 20 to 100 gallons per acre gals/Ac. using power operated spray equipment. Apply when wind speed is low, 5 mph or less. Apply working upstream to avoid accidental concentration of spray into water. Cross-stream spraying to opposite banks is not permitted and avoid boom spraying over water surface. When spraying shoreline weeds, allow no more than 2 foot overspray onto water surface with an average of less than 1 foot of overspray to prevent significant water contamination. RESTRICTIONS AND LIMITATIONS • Do not apply more than 2 treatments per season. • Minimum of 30 days between applications. • Use 2 gallons or more of spray solution per acre. • Do not apply more than 2 lbs. a.e. per acre per application or more than 5.6 pints (4 lbs. a.e.) per acre per use season. • Spot treatments are permitted. Biennial and Perennial Broadleaf weeds and Susceptible woody plants

Divide the distance (fl.) by the time (sec) to estimate velocity (ft./sec. per sec.). Repeat 3 times and use the average to calculate CFS. Average Width (ft.) x Average Depth (ft. x Average Velocity (ft./sec. per sec.) = CFS Emergent and Floating Aquatic Weeds: Including Water Hyacinth {Eichornia crassipes) Application Rate: 2.66 to 4.66 pints of this product per acre. Page 27 of 32 For ditch bank weeds: Do not spray cross-stream to opposite bank. Do not allow boom spray to be directed onto water. Notice to Applicators; Before application, coordination and approval of local and state authorities may be required, either by letter or agreement or issuance of special permits for aquatic applications. Aerial Application; Use drift control spray equipment or drift control products mixed in the spray mixture. Apply 0.66 gallon (5.3 pts. pints) of this product per acre using standard boom systems using a minimum spray volume of 5 gallons per acre. For Microfoil drift control spray systems, apply this product in a total spray volume of 12 to 15 gallons per acre. Surface Application: Use power operated sprayers with boom or spray gun mounted on boat, tractor or truck. Thorough wetting of foliage is essential for maximum control. Use 100 to 400 gallons of spray mixture per acre. Special precautions such as use of low pressure, large nozzles and drift control agents should be taken to avoid spray drift to susceptible crops. Follow label directions for use of any drift control agent. For shoreline weeds; Boom spraying onto water surface must be held to a minimum and allow no more than 2 foot overspray onto water with an average of less than 1 foot overspray to prevent introduction of greater than negligible amounts of chemical into the water. Specific Use Directions Application Timing: Spray weed mass only. Apply when water hyacinth plants are actively growing. Repeat application as necessary to kill regrowth and plants missed in previous operation. Use the 5.3 pints per acre rate when plants are mature or when weed mass is dense. Aquatic Weed Control in Ponds, Lakes, Reservoirs, Marshes, Bayous, Drainage Ditches, Canals, Rivers and Streams that are Quiescent or Slow Moving, Including Programs of the Tennessee Valley Authority Fish breathe dissolved oxygen in the water and decaying weeds also use oxygen. When treating continuous, dense weed masses, it may be appropriate to treat only part of the infestation at a time. For example, apply the product in lanes separated by untreated strips that can be treated after vegetation in treated lanes has disintegrated. During the growing season, weeds decompose in a 2 to 3 week period following treatment. Waters having limited and less dense weed infestations may not require partial treatments. Other local factors such as water exchange and sediment load can also influence the dissolved oxygen level. Coordination and approval of local and state authorities may be required, either by letter of agreement or issuance of special permits for aquatic applications. RESTRICTIONS AND LIMITATIONS FOR SURFACE APPLICATIONS TO EMERGENT AQUATIC WEEDS • Do not exceed 4 lbs. a.e. per surface acre per application. • Limited to 2 applications per year. • Minimum of 21 days between applications. • Spot treatments are permitted.

Time: Page 28 of 32 D. Following each application of this product, treated water must not be used for drinking water unless one of the following restrictions has been observed: 2. Drinking water (potable water): A. Consult with appropriate state or local water authorities before applying this product to public waters. State or local agencies may require permits. The potable water use restrictions on this label are to ensure that consumption of water by the public is allowed only when the concentration of 2,4-D in the water is less than the MCL (Maximum Contaminant level) of 70 ppb. Applicators should consider the unique characteristics of the treated waters to assure that 2,4-D concentrations in potable water do not exceed 70 ppb at the time of consumption. i. A setback distance from functional water intake(s) of > 600 ft was used for the application, or, ii. A waiting period of at least 7 days from the time of application has elapsed, or, iii. An approved assay indicates that the 2,4-D concentration is 70 ppb (0.07 ppm) or less at the Example: Posting notification should be located every 250 feet including the shoreline of the treated area and up to 250 feet of shoreline past the application site to include immediate public access points. Posting must include the day and time of application. Posting may be removed if analysis of a sample collected at the intake 3 days or more following application shows that the concentration in the water is less than 70 ppb (100 ppb for irrigation or sprays), or after 7 days following application, whichever occurs first. Text of notification: Wait 7 days before diverting functioning surface water intakes from the treated aquatic site to use as drinking water, irrigation, or sprays, unless water at functioning drinking water intakes is tested at least 3 days after application and is demonstrated by assay to contain not more than 70 ppb 2,4-D (100 ppb for irrigation or sprays). Application Date: C. If no setback distance of > 600 feet is used for the application, applicators or the authorizing organization must provide a drinking water notification prior to a 2,4-D application to the party responsible for a public water supply or to individual private water users. Notification to the party responsible for a public water supply or to individual private water users must be done in a manner to assure that the party is aware of a water use restrictions when this product is applied to potable water. The following is an example of a notification via posting, but other methods of notification which convey the above restrictions may be used and may be required in some cases under state or local law or as a condition of a permit. Water Use:

1. Water for irrigation or sprays: A. If treated water is intended to be used only for crops or non-crop areas that are labeled for direct treatment with 2,4-D such as Pastures, Turfgrass or Cereal grains, the treated water may be used to irrigate and/or mix sprays for these sites at any time after the 2,4-D aquatic application. B. Due to potential phytotoxicity considerations, the following restrictions are applicable: If treated water is intended to be used to irrigate or mix sprays for plants grown in commercial nurseries and greenhouses; and other plants or crops that are not labeled for direct treatment with 2,4-D, the water must not be used unless one of the following restrictions has been observed: i. A setback distance from functional water intake(s) of > 600 feet was used for the application or, ii. A waiting period of 7 days from the time of application has elapsed, or, iii. An approved assay indicates that the 2,4-D concentration is 100 ppb (0.1 ppm) or less at the water intake. Wait at least 3 days after application before initial sampling at water intake, B. For floating and emergent weed applications, the drinking water setback distance from functioning potable water intakes is > 600 feet.

Submersed Aquatic Weeds: Including Eurasian Water Milfoil (Myriophyllum spicatum) Treatment Site Specific Use Instructions ''This product contains 5.6 pounds a.e. per gallon of product. For difficult conditions - 4 ppm* 1 acre Page 29 of 32 water intake. Sampling for drinking water analysis should occur no sooner than 3 days after 2,4-D application. Analysis of examples must be completed by a laboratory that is certified under the Safe Drinking Water Act to perform drinking water analysis using a currently approved version of analytical Method Number 515,555, other methods for 2,4-D as may be listed in Title 40CFR, Part 141.24, or Method Number 4015 (immunoassay of 2,4-D) from U.S. EPA Test Methods for Evaluating Solid Waste SW-846. F. Drinking water setback distances do not apply to terrestrial applications of 2,4-D adjacent to water bodies) with potable water intakes. Aquatic weed control in ponds, lakes, reservoirs, marshes, bayous, drainage ditches, canals, rivers, and streams that are quiescent or slow moving, including programs of the Tennessee Valley Authority. Average Depth (ft) Maximum Application Rate'* 1.89 gals, gallons (15.1 pts. pints) (10.8 lbs. a.e.) per acre foot 2,4-D (lbs. a.eJacre) 5.4 10.8 16.2 21.6 27.0 1 2 Z 4 5 *Examples include spot treatments of pioneer colonies of Eurasian 'Water Milfoil and certain difficult-to-control aquatic species. Table 1: Amount To apply for a Target Subsurface Concentration Surface Area 2,4-D (lbs. a.e./acre) 10.8 21.6 32.4 43.2 54.0 Application Timing: For best results, apply in spring or early summer when aquatic weeds appear. Check for weed growth in areas heavily infested the previous year. A second application may be needed when weeds show signs of recovery, but no later than mid- August in most areas. Subsurface Application: Apply this product undiluted directly to the water through a boat mounted distribution system. Shoreline areas should be treated by subsurface injection application by boat to avoid aerial drift. Surface Application: Use power operated boat mounted boom sprayer. If rate is less than 5 gals./Ac. gallons per acre, dilute to a minimum spray volume of 5 gallons per surface acre. Aerial Application: Use drift control spray equipment or drift control agents mixed with sprays to reduce drift. Apply through standard boom systems in a minimum spray volume of 5 gals. gallons per surface acre. For Microfoil drift control spray systems, apply this product in a total spray volume of 12 to 15 gals./Ac. gallons per acre. Apply to attain a concentration of 2 to 4 ppm (see table below). For typical conditions - 2 ppm___ This Product gal./acre 0.95 1.89 2.84 3.79 4.74 This Product gal./acre 1.89 3.79 5.68 7.58 9.47 E. Note: Existing potable water intakes that are no longer in use, such as those replaced by a connection to a municipal water system or a potable water well, are not considered to be functioning potable water intakes.

Do not apply more than 2 applications per season. Do not apply within 21 days of previous application. Page 30 of 32 When treating moving bodies of water, applications must be made while traveling upstream to prevent concentration of 2,4-D downstream from the application. Coordination and approval of local and state authorities may be required, either by letter of agreement or issuance of special permits for such use. 2. Drinking water (potable water): A. Consult with appropriate state or local water authorities before applying this product to public waters. State or local agencies may require permits. The potable water use restrictions on this label are to ensure that consumption of water by the public is allowed only when the concentration of 2,4-D, in the water is less than the MCL (Maximum Contaminant Level) of 70 ppb. Applicators should consider the unique characteristics of the treated waters to assure that 2,4-D concentrations in potable water do not exceed 70 ppb at the time of consumption. Fish breathe oxygen in the water and a water-oxygen ratio must be maintained. Decaying weeds use up oxygen, but during the period when applications should be made, the weed mass is fairly sparse and the weed decomposition rate is slow enough that the water-oxygen ratio is not disturbed by treating the entire area at one time. If treatments must be applied later in the season when the weed mass is dense and repeat treatments are needed, apply product in lanes, leaving buffer strips which can then be treated when vegetation in treated lanes has disintegrated. During the growing season, weeds decompose in a 2 to 3 week period following treatment. C. If no setback distance from the "Drinking Water Setback Table (Table 2)" is to be used for the application, Aapplicators or the authorizing organization must provide a drinking water notification and an advisory to shut off all potable water intakes prior to a 2,4-D application. Notification to the party responsible for a public water supply or to individual private water users must be done in a manner to assure that the party is aware of the water use restrictions when this product is applied to potable water. B. For submerged weed applications, the drinking water setback distances from functioning potable water intakes are provided in "Table 2: Drinking Water Setback Distance" (below). Water Use:

1. Water for irrigation or sprays: A. If treated water is intended to be used only for crops or non-crop areas that are labeled for direct treatment with 2,4-D such as Pastures, Turfgrass or Cereal grains, the treated water may be used to irrigate and/or mix sprays for these sites at any time after the 2,4,-D aquatic application. B. Due to potential phytotoxicity and/or residue considerations, the following restrictions are applicable: If treated water is intended to be used to irrigate or mix spray for unlabeled crops, non-crop areas or other plants not labeled for direct treatment with 2,4-D, the water must not be used unless one of the following restrictions has been observed,: i) A setback distance described in the “Drinking Water Setback” Table was used for the application, or, ii) A waiting period of 21 days from the time of application has elapsed, or, iii) An approved assay indicates that the 2,4-D concentration is 100 ppb (0.1 ppm) or less at the water intake. See “Table 3” for the waiting period after application but before taking the initial sampling at water intake. RESTRICTIONS AND LIMITATIONS FOR AQUATIC SITES WITH SUBMERSED WEEDS Do not exceed 10.8 lbs. a.e. per acre foot per application.

Table 2: Drinking Water Setback Distance for Submersed Weed Applications Page 31 of 32 Table 3: Sampling for Drinking Water Analysis After 2,4-D Application for Submersed Weed Applications: F. Drinking water setback distances do not apply to terrestrial applications of 2,4-D adjacent to water bodies with potable water intakes. E. Note: Existing potable water intakes that are no longer in use, such as those replaced by a connection to a municipal water system or a potable water well, are not considered to be functioning potable water intakes. Text of notification: Wait 21 days before diverting functioning surface water intakes from the treated aquatic site to use as drinking water, irrigation; or sprays, unless water at functioning drinking water intakes is tested no sooner than {insert days from Table 3) and is demonstrated by assay to contain not more than 70 ppb 2,4-D (100 ppb for irrigation or sprays). Application Date: Time: 3 ppm* 10 4 ppm* 14 The following is an example of a notification via posting, but other methods of notification which convey the above restrictions may be used and may be required in some cases under state or local law or as a condition of a permit. D. Following each application of this product, treated water must not be used for drinking water unless one of the following restrictions has been observed: i) A setback distance described in the “Drinking Water Setback Distance" fable was used for the application, or, ii) A waiting period of at least 21 days from the time of application has elapsed, or, ill) An approved assay indicates that the 2,4-D concentration is 70 ppb (0.07 ppm)or less at the water intake. Sampling for drinking water analysis should occur no sooner than stated in “Table 3". Analysis of samples must be completed by a laboratory that is certified under The Safe Drinking Water Act to perform drinking water analysis using a, currently approved version of analytical Method Number 515,555, other methods for 2,4-D as may be listed in Title 40CFR, Part 141-24, or Method Number 4015 (immunoassay of 2,4-D) from U.S. EPA Test Methods for Evaluating Solid Waste SW-846. ________1 ppm* ___________5 ppm acid equivalent target water concentration Minimum Days After Application Before Initial Water Sampling at the Functioning Potable Water Intake _________2 ppm 10 Example: Posting notification should be located every 250 feet including the shoreline of the treated area and up to 250 feet, of shoreline past the application site to include immediate public access points. Posting should include the day and time of application. Posting may be removed if analysis of a sample collected at the intake no sooner than stated in “Table 3”(below) shows that the concentration in the water is less than 70 ppb (100 ppb for irrigation or sprays), or after 21 days following application, whichever occurs first. Application Rate and Minimum Setback Distance (feet) From Functioning Potable Water Intake 3 ppm* 1800 2 ppm* 1200 4 ppm* 2400 ________1 ppm* _________600 *ppm acid equivalent target water concentration

Disclaimer: Always refer to the label on the product before using De-Amine 6 or any other product. Page 32 of 32 DE-AMINE, IMITATOR, MIX, QUIK-QUAT and the Drexel logo are trademarks or registered trademarks of Drexel Chemical Company. All other brand names, product names, or trademarks belong to their respective holders. WARRANTY - CONDITIONS OF SALE OUR DIRECTIONS FOR USE of this product are based upon tests believed reliable. Follow directions carefully. Timing and method of application, weather and crop conditions, mixtures with other chemicals not specifically directed, and other influencing factors in the use of this product are beyond the control of the Seller. To the extent consistent with applicable law, Buyer assumes all risks of use, storage and handling of this material not in strict accordance with the directions given herewith. To the extent consistent with applicable law, in no case shall the Manufacturer or the Seller be liable for consequential, special or indirect damages resulting from the use or handling of this product when such use and/or handling is not in strict accordance with the directions given herewith. The foregoing is a condition of sale by the Seller and is accepted as such by the Buyer. STORAGE AND DISPOSAL Do not contaminate water, foodstuffs, feed by storage or disposal. PESTICIDE STORAGE: Keep container tightly closed when not in use. If exposed to subfreezing temperatures, the product should be warmed up to at least 40T and mixed thoroughly before using. Store this product above 44®F. Once this product is mixed in water, the spray solution is stable down to 32T. PESTICIDE DISPOSAL: Pesticide wastes are toxic. Improper disposal of excess pesticide, spray mixture, or rinsate is a violation of Federal law and may contaminate groundwater. If these wastes cannot be disposed of by use according to label instructions, contact your State Pesticide or Environmental Control Agency or the Hazardous Waste Representative at the nearest EPA Regional Office for guidance. CONTAINER DISPOSAL: Nonrefillable Container (rigid material; < 5 gallons): Nonrefillable container. Do not reuse or refill this container. Offer for recycling, if available. Clean container promptly after emptying. Triple rinse as follows; Empty the remaining contents into application equipment or a mix tank and drain for 10 seconds after the flow begins to drip. Fill the container one-fourth full with water and recap. Shake for 10 seconds. Pour rinsate into application equipment or a mix tank or store rinsate for later use or disposal. Drain for 10 seconds after the flow begins to drip. Repeat this procedure two more times. Dispose of empty container in a sanitary landfill or by incineration, or, if allowed by State and local authorities, by burning. If burned, stay out of smoke. Nonrefillable Container (rigid material; > 5 gallons up to < 250 gallons): Nonrefillable container. Do not reuse or refill this container. Offer for recycling, if available. Clean container promptly after emptying. Triple rinse as follows: Empty the remaining contents into application equipment or a mix tank. Fill the container one-fourth full with water. Replace and tighten closures. Tip container on its side and roll it back and forth, ensuring at least one complete revolution, for 30 seconds. Stand the container on its end and tip it back and forth several times. Turn the container over onto its other end and tip it back and forth several times. Empty the rinsate into application equipment or a mix tank or store rinsate for later use or disposal. Repeat this procedure two more times. Dispose of empty container in a sanitary landfill or by incineration, or, if allowed by State and local authorities, by burning. If burned, stay out of smoke. Refillable Container (> 250 gallons & Bulk): Refillable container. Refill this container with pesticide only. Do not reuse this container for any other purpose. Cleaning the container before final disposal is the responsibility of the person disposing of the container. Cleaning before refilling is the responsibility of the refiller. To clean the container before final disposal, empty the remaining contents from this container into application equipment or mix tank. Fill the container about 10% full with water. Agitate vigorously or recirculate water with the pump for 2 minutes. Pour or pump rinsate into application equipment or rinsate collection system. Repeat this rinsing procedure two more times. Then offer for recycling if available or puncture and dispose of in a sanitary landfill, or by incineration, or by other procedures approved by state and local authorities. Manufactured By: □rexel Chemical Company PO BOX 13327. TN 0327