crop-chem-docs/corpus/epa_ppls/264-342.md

LARVIN 500 THIODICARB INSECTICIDE

• EPA Reg No: 264-342
• Registrant: BAYER CROPSCIENCE, LLC
• Signal word: Warning
• Active ingredients: Thiodicarb (43.1%)
• Label accepted: 1988-08-22
• Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/000264-00342-19880822.pdf

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• • i ( I • ACCEPTED /lJJG 2 2 1S28 LARVINe brand 500 Thlocllcarb InNCtlcld .. Pendlng·4125188 UDd., Ih. rod.,,1 Insecticide Fungi:-ide ... n:1 R:;:l{!·.t:lticid. ~ oa ~me:tded. 1C)1 the ~tLClde -a"utered und.! . ? J. EPA Rog. No. 7 I_ ,,_ .J7:O LARVIN· 500 Thlodlcarb Insecticide Aqueous Flowable ACTIVE INGREDIENT Pe«:ent by weight lHlODlCARB DImeIhyI N. N' (INobIs ({melhylmlno) calbonyloxyD bis (ethanimidolhIoate)uu •.•••.•...••••••.•..•.•.•••••......•••••.••....•.•.••..•...•...•.••.... 43.1% INERT INGREDIENTS ....•.•.•••.•••••••••....••••••...•..•••••.••.••••.••....••.....•......••..••••..•............... 56.9% CONTAINS 42 pounds actiYe IhIocIcaItI per U.S. galon EPA RegIs!,allon No. 264-342 EPA Establshmenl No. 264-M~ • KEEP OUT OF REACH OF CHILDREN WARNING AVISO MAY BE HARMFUL OR FATAL IF SWAl.!.OWED OR INHALED. ANTIDOTE IS ATROPINE SUlFATE. seE STATEMENT OF PRACnCAL TREATMENT AND OTHER PRECAUTIONARY STATEMENTS ON LEFT PANEL. READ THE ENTIRE LABEL BEFORE USING THIS PESTICIDE. LA USUARIO: Si usted no lee Ingles. no use este proclJdo hasta CJl8 Ia eIiqueIa Ie haya sIdo Ilxplcada 8q)Iamente. (TO THE USER: II you cannoI read EngIsh. do no! use !lis proclJc:t until lIle label has been fully explained to you.) For Emergency Infonnation 0t4.Y 24 Hours A Day 1-600-334-7577. For pros Hancling.UU and Generallnlonnalion CAl.!. 1-800-334-9745. Rh6ne·Poulenc Ag CoIl1l8"Y •••••• P.O. Box 12014. 2 T. W. Alexander Drive : :: Research Triangle P8Ik, Norlh Caroina 2n09 • • •••••• • • • • • ••• • •• .. . Net contents 2.5 gallons (9 46 lIers) U.S. Patent No.: 4.382.957 • • •• • •• • •• •• •• •• :Mal:le In U.SA. ••••• .. . • •• .. . LARVlN4D Is a regiaered trademark of RhOne-Poulenc for Thlc.clicarb Inseclicide. .. . • •• ... 1

( lARVINe brand 500 Thlodlc.rb Inaactlcld.Pandlng-4125188 PRECAUTIONARY STATEMENTS WARNING . HAZARDS TO HUMANS AND OOMESTIC ANIMALS May be hllllTlul or fatal H swallowed or Inhaled. May be harmful H absorbed through the skin. May be Initating to eyes and may c:aISe nild akin sensitization. Do not take IntemaJly. Avoid contact with &kin, eyes or c:klthlng. Avoid breathing spray nisI. Wear long-Sleeved clothing while using. Remove contaninated c:klthlng dally: wash before reuse. Wash exposed sldn thoI'oughly with soap and water after use and before eating or smoking. DiscontIIIJ8 use • aDergic reaction occurs. SIGNS AND syMPTOMS OF OVEREXposURE" Salvation, Watery eyes, f'Ir1IoInt eye pupils, BkJrred vision, Muscle tremors, Difllcul breathing, excessive sweating, AbdomInal , Nausea, Vorriting, DIarrtlea, Weakness, Headache. In severe cases, mlMlislons, unconsciousness and respiratory failure may occur. ANTIDOTE STATEMENT ATROPINE SULFATE IS HIGHLY EFFECTIVE AS AN ANTIDOTE. See NOTE TO PHYSICIAN below: STATEMENT OF PRACTICAL TREATMENT GENERAL Contact a physician Invnediately In aI cases of lUSpeCted poisoning. • breathing Slops, establsh an airway, &taIt 8I1ificial respiration and provide oxygen. Make certain to remove aI sources 01 contirUng contamination. Remove c:klthing and wash skin and hair Invnediately with large amounts of water. Transport lIIe patienl to a physician or hospltallrrrnedately and SHOW A COPY OF THIS LABel TO THE PHYSICIAN. IF SWALLOWED: Drink 1 or 2 glasses of water and Induce vomiting by touching back of throat with finger. Never ltIe anything by mouth to an unconsdous or mnvulslng person. Call a physician and follow General advica Isted above. IF IN EYES' FlIsh eyes with plenty of water. Get medical attention If Irritation persists. IF ON SKIN; Wash thoroughly with soap and water. IF INHALED' cat a physician and follow General a<Moe Isted above. NOTE TO PHYSICIAN LARVINe thiodicarb Is an oxime carbamate Insecticide, which Is a cholnesterase Inhibitor. OVerexposure to lIIis substance may cause toxic Signs and sorns due to stimulation of tile :. : choUnergic nervous system. These effects of overexposure are spontaneously lind f8Pdly • • • reversible. : .: • •••••• SpecifIC treatment mnslsts of parenteral atropine suHate. Caution should be malnttin8JI to prevent overatropirUation. Mild cases may be ltIen 1 to 2 roo Intramuscularty every 10 ninutps. : until fuD atropirUation has been achieved and repeated thereafter whenever sY""""'"' reappear." Severe cases should be ltIen 2 to .. roo Intravenously every 10 minutes until fuUy.,QQPltUed, • then Intramuscularty every 30 to 60 ninutes to maintain the eflact lor at least 12 hours. Dosages.' • 2 .. . .. . • • • .. .

( LARVINe bl1lnd lOCI Thlodarb InMCtlcld .. Pendlnll-4125188 for children should be appIOPIIately recU:ed. CoII1JIete l8COYeIY from overexposure Is to be expected within 24 hours. NanloIIca .nd other ledatlves should not be used. Further. drugs .e 2-PAM (pyrkIne-2- aldoxime methIodde) are NOT I8COII1118IIded unless organophosphate Intoxication Is also suggested. To aIcIln conIinnalion of a cIagnosis. UIIne ~ should be obtained within 24 hours of eJqlO8UlV.nd lImIedIateIy fIozen. Analyses wi. be arranged by RhOne Poulenc All Coqlany. Consultation 01\ therapy can be obIaIned .... hours by caIIng the Rh6ne-Poulenc emergency number : 1-800-334-7577. ENVIRONMENTAL HAZARDS AIIOId clrecllPPIIcdonI to lakes, It_ and ponds. Do nof apply wilen weather OOIdlions favor drift fIom .... treIIed. ThIs pnxU:t Is toxic to bees exposed to clred treatmenl. Do not apply when bees are adIveIy visiting the treaImenIarea. GENERAL INFORMATION LARViNe 500 Is an 1IIJI8OUS fIowabIe concentrate fonnulatlon cf< ThIodicaJb InsectIc:Ide that readily clsperses In water for PUlpOses of spraying by QIOUnd or air IIIJIlpment. Dir'9dions on this label are based 01\ tests and field eJq)8l'lence relating to effectiveness. ~ 01\ erwiIonment .nd AlsIclHIs Almailing In food and feed. READ THE ENTIRE LABa AND OBSERVE ALl LABa DIRECTIONS AND PRECAUTIONS BEFORE USE. DIRECTIONS FOR USE NOTE: IT IS A VIOI..AllON Of FEDERAl LAW TO USE THI!; PRODUCT IN A MANNER INCONSISTENT WIlH ITS LABEUNG. Do not use LARVIN 500 excepl as drecled 01\ this IaOOI or on other Rh6ne-Poulenc Ag CoqIany supplementallabelng for this product. GENERAL WORKEI~ PROTECTION STATEMENTS Do not apply this pnxU:t In IUCh a manner as to clrectly or through drift expose WOItIers or other persons. The area being tAlated must be vacated by unprotected persons. Do not enter treated areas without protective ctothlng until sprays have dried. ( ... Because ceI1ain Slates may requlAI more restrictive reentry Intervals lor various C'I!l!l'> treated ¥!(Iftl : this product. consuh your State Department of AgricuftuAl for further InfOrmatlo~. : : Written or oral warnings must be c;ven to WOItIers who aAl expected to be In a tAl'8t.<! ·~ .. a or In an area about to be treated with this pnxU:t. AdvIse WOItIers te ltay out of fields durln'''1\ : and until sprays have dried. Regular long-sleeved MIlk eIothing Should be worn ~ WOItcirYIIln' • tAlated fields, See PracautIonary Statement. Statement 01 PAlctiCal Treatment el"il.fllOle to ' Physician for Inlonnation on acx:Idental exposures. When oral warrings are . warrings t': . 3

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(

LARVINe brenci 500 Thlocllcarb In.lCtlcld.pendlng- .. '25188

be s;ven In • language QlstomaIIly underslood by WOIkers. Oral warnings ITIIIIt be s;ven .Ihere Is

reason to beleve thai Wllllen warrings camot be understood by workers. Written warnings InJst

InciJde the following '''ormation: appropfIate signal word (WARNING), area lrealed with LARVlN4D

brand 500 Thlocicarb Insecticide, date of appication, appropriate pIOtecllw ~,lPPIopriate

reentry Interval, H appIIc;IbIe.

GENERAL DIRECTIONS

SPRAY PREPARATION: TO ASSURE A UNIFORM PRODUCT, AGITATE OR SHAKE All

CONTAINERS OF LARViNe 500 PRIOR TO USE. Remove oil, rust, 1C8Ie, peSllclde resk1.Ies and

0Iher foreign mailer from sprayer and lllralner. Fklsh with clean water. Use 50 mesh IC1I8OS or

sIolled &trainers In spray system. To prepare for spraying, liU tank appIt'"CImately one-haII ful of

water. Add LARVIN 500 insedidde and nix lhoroughly by mechanical ,~hydraulc agiIaIion.

Rnlsh ._ng tank with water to desired volume and !hroughly nix. 00 not IIore spray nnture for

prolonged periods. Itanll-nixes are to be used, LARVIN 500 ITIIIIt be fuIy dspersed In water

firsI, tollouued by the addIIon of the Intended tank-/rix mate!lal.

COMPAnBIUlY· LARVINe 500 when dklted with an 8CJl81 volume of water, II physIcaly

~ with a wide range ot ClOI1Im:II";Iy used spnIy pcocU:Is. but the ful range of

co!r4)9tibiltles under local condlions Is ,.,t known. Therefore, It Is essential thai before using any

tank niXfure of LARVIN 500 Insecticide, !he con1)atibiity of !he nixture be estabished. Add a

smaD amount of LARVIN 500 Insedicicle to an equal voklme of water In a smal container and !hen

add the other pesticide or spray procU:t and nix 1hoIOugh1y. 00 NOT USE MIXTURES lHAT

CURDLE, PRECIPITATE, OR GREASE. llilS PRODUCT IS NOl MISCIBLE WITH VEGETABLE

OIL DILUENTS. TANK MIXTURES SHOULD BE USED WITHIN 6 HOURS AFTER MIXING.

NOTE: lARVIN ThlodcaIb InsecIIcIde is hydrolytical1y sensil!ve \0 degradation of aclive

ingredent by strong acids, strong bases, and certain heavy metal oxides and sals of certain

fungicides such as Maneb, Mancozeb, Copper Count N-8, and Bordeaux nixture. 00 NOT USE

LARVIN 500 INSECllCIDE IN SPRAY MIXTURES WITH lliE ABOVE METAl. PRODUCTS. 00

NOT ADO LARViN 500 TO WATER WITH pH VAl.UES BELOW 3.0 OR ABOVE 85 .• necessary,

water should be buffered within !hIs range before adding LARVIN ThIodcarb Insedicicle.

APPUCAllONi Begin application when Insect populations reach recognized eco,.,nic

threshold levels. Consult the Cooperative Extenslon SeIVice, Professional Consulants or other

quailled auIhorities to detemine appropriate !hreshold lewis lor treatment In your area. Apply a

ninllnJm Irished spray volume of 3 gaJIons per acre by air or 15 galons per acre by ground for

sweet com. Repeat appIcation as needed to maintain control. Use higher dosage rates lor

heavier lnIestations or lalger larvae. Use lower rates lor Ight to moderate Infestations.

To clean the sprayer altlir use, drain and fklsh with water.

-..___ .... ' I. (

; CH.-"'''----.nuIOUGH.'8PRlNKLEIl'RRlOA.mM.;;,.'f''·;!·:

i Do ,.,t apply this product through any other type of Irrigation system. "

~ Apply this product only through sprinkler Irrigation systems Incklding center pivql aljd ~Ud set., /_

...... ..

J' SPRAY REPARATION: Remove scele, pesticide residues, and other foreign :rnaiter ,"?m , i

the chemcal tank and entire Injector system. Rush with clean water. ' , , , . ,. 'J ~. :; ... -, ..... , "

, ;~ , ( ., ~ , , :'J -, .. J , ' LARVIN4D brand 500 Thlocllcartl InMctlcld.Pandlng-4/25188 APPLICADON INSTBUcnONS: Alit prepare a IUspension of LARVI~ brand 500 ThIodcaJb insecticide In a mix tank. AD ... with 112 10 314 the desired amount of water. Start mechancat or hydraulc~. Add the recpred amount of LARVlN4D brand 500. and then the remaining vok/me of water. (Suspension concellbidlools using the appropIIale dosage per acre recommended on this label of LARVlN4D brand 500 per 1 to 4 gallons of water are recomnendecl).Then HlIpII'*Ier 10 delver 0.1 to 0.3 Inch of water per acre. Start IpIInkIer and uniformly I~ the auspenslcn of LARVIN4D brand 500 Into the Irrigation water lne 10 as to delver the de&lred rate per acre. The IUsp8t ilion of LARVIN4D brand 500 shoulcl be Injected with a ' positive clsplacement puqllnto the main Ine ahead of a right angle tum to Insure edeq.Iale mixing. • you should have any other queSIIons about calibration, you should COIUCI Slate extension Servtce spec:ldsts, equipment rnarUadurerI or other experts. tmIE: When treatment with LARVIN4D brand 500 ThiocIc:artlllll8Cllclde has been ~ed, turther IIeId InIgation over the treated 8188 should be avoided for 24 10 48 hours to prevent washing the chemical of! the crop. GENERAL PRECAUTIONS FOR APPLICATIONS THROUGH SPRINKLER IRRIGATION SYSTEMS MalrUln conIIruous agitation In nix ... ~rtng rnIxIng and appIcaIIon to assure a unifonn suspension. Greater accuracy In caIbratIon and cI&IrtbWon wi. be achieved by injecting a larger vokIme of a (', more clUte sokItion per unif lime. The system must oonlain a functional check valve, v.:uum relet valve, and low p!'8SSIIl8 drain approprtately located on t'le Irrigation pipeline 10 prevent water source contamination from baddlow. The pesticide Injection pipeline must oolll8ln a tunclional, automatic, -doslng check valve to prevent the flow of fUld back Iowald the Ion PUfr4). The pes!ic:Ide InjedIon plpelne rrost also oonlain a tunctional, normally closed soIenoicf.operated valve located on the Intake side of the Injection PUfr4) and oomec:ted to tIM system Interlock to prevent IUd from ~ o. being withdrawn lrom the supply ... when the InIgation system Is either lUoma!IcaIIy or l'IIInIaly ,. shutdown. The system must contain tunclionallnterlocklng oontrols to automaticaly shut 011 the pesticide InjedIon PUfr4) when the water PUfr4) motor SlDps. The Inigation line or water PUfr4) must InckIde a functional pressure switch which wi. stop the water PUfr4) motor when the water pressure decreases 10 the point where pesticide cistribution Is adversely affected. Systems must use a metertng PUfr4), such as a positive dlsplacemerrt Injection PUfr4) (e.g., daphragm PUIl1l) effectively designed and constructed 01 matertals that are OOfr4)a!ible with pes!iddes and capable 01 being filled with a system Irrterlock. Do not apply when wind speed lavors drift beyond the area Irrtended lor treatmerrt. <I ••• o 0 0 Do not apply when wind speed lavors drift, when system oonnection or fittings ieG'k: Wtien nozZles 0 do not provide unllonn cistrtbulion or when lnes oorrtalnlng : ': 0 the product must be dsmantled and drained. ' ° : ° ° : • • I • •• Crop Injury, lack 01 effectiveness, or Illegal pesticide residues In the crop may resuft,!lOm non! 0 0 00: unllonn dstrtbulion 01 treated water. :: 0 ..... .. 0 • • 0 .. 0 .. 0 o 0 0 ... 5 _ • __ 0_ 4. __ _

\ ( AIIM IUfIIcIert time for pesticide to be tIuIhed thlOUQllll IlIIIn II nozzles tIIIcn "Iring oft IrrIgaIIon WIlIer. A penon knowledgeable of the cIIerngatIon system MIt ralPOflllble for .. opetlllon IhlllIIU the system down MIt make necessary 8IIjuItInerU should the need 1JIse. Do nat conned an Inigatlon system (lrQdng greero:lOUse systems) used for pesticide IA 4caIkIn to • pubic water system unless the Iabef.prescIIbe lIIety deIIIces for pubic water "!llPI.1 _In pBe. , 6 •••• • •• •• • • •• • • • • ••••• • • • • .. • •••• • • • • ~;oI':1 • • • •• • ••• • .. . • •• ••• •• • • •• ... ~~- -----------------------------------------------------

\ , I ( • LARVINe brend 100 Tilloclicarb InMCtIcId.Pendlnll-412S/88 RECOMMENDED USES CROP Sweet Com (FraIh MaIk8t Only) , INSECT Comearwonn European com bcnr AmP,worms Western bean CiIlwomI DOSAGE PER ACRE POUNDS FLUID ACTIVE OUNCES 0.5 to 0.75 (fIoIIda Only) 15.2 to 22.8 SPECIFIC DIRECTIONS """." ettwttm "'In M": Apply .1·7 day InteMlllIIarIIt III whirl Illes flIIt ....... and conti"," Ing unllllllcs begin to dry or 1nIesta· Ion potenllll CIII.. FoIow local I'IICOI'I'ImCIIIdaIone for proper timing. Wbm! 1M' '0' .. !eer!era .If belt ...,... lilt ..,. 0115 JIIonI or more per acN IJ""'" by gftIUfId ecpprnanl UIIng IOIcI or IIoIIow 'lOII8 nozzles cIrec:Ied Into tile plant .. :101'1. Also refer to gelleral cll8CIIo .. for use. PREHARVEST AND GRAZING USE INFORMATION AND UMITATIONS To avoid IIegaI residues In or on: SWEET CORN o Alter lilk tntIatIon, do not elCC8ed 7.5 pounds 01 active Ingredient (228 IIuId ounces 01 LARVINe 500) per acre per Mason. o Do noI aIow lveseock to graze treated llelda. • Do noIfeed treated com IIIage (green plant) or fodder to Ivestock. • Ears may be halvested on day 0I1a11t appIcabo!l. 7 •••• o 0 0 • • • • • • ••• · '. t •• • , . • ••••• • • • • • • •• • • 0 ••••• •• •• • • • 0 0 ••••• .. . • •• ... .. . • o. .. . ---,.---.--.----.-.. -.- ... -------

\ ( • LARVINGD brand 500 ThlocllClirb InMCtIcId.Pendlng-4125188 FIELD USE CONVERSION TABlE DOSAGE PER ACRE Pounds Fluid Active Ounces 0.25 0.33 0.40 0.45 0.50 0.55 0.60 0.65 0.70 0.75 7.6 10.1 12.2 13.7 15.2 16.8 16.3 19.8 21.3 22.8 kIes treated per gallon 01 LARVINGD 500 16.8 12.7 10.5 9.3 8.4 7.6 7.0 6.5 6.0 5.6 1 U.S. GaIon EcJJaI8128 Rid Ounces , STORAGE AND DISPOSAL STORAGE· Do noIllore In or around lhe home. Store unused product In a cool. ventilaled. dry. locked l118a. Do not dow pIOIonged skW'.ge In areas where temperatures frecJlently exceed 115°F (46OC). Do not contaminate food. water or feed by lIorage or disposal. NEVER TRANSFER THIS PRODUCT TO ANOTHER CONTAINER FOR STORAGE. PESDClpe PISPOSAL· wastes resullng from lhe use 01 this product may be disposed 01 on lite or II an IIPJIIOV8CI waste disposal lacilty. CONTAINER DISpOSAL· NEVER REUSE EMPTY CONTAINERS. Triple rinse or equIvIIenI. Then oller lor ng or reconditioning or puncture and dspose olin a aaritary IancIUI or by Incineradon. or II allowed by state and local authorities. by buonng. II oonIainer II burned. Slay out 0I1IIIOke. ACClpENTS· In case oIa major _ 01 LARVlNGD 500 Thiodcarb Insecticide; TaEPHONE (24 HOURS A DAY) IN THE USA 1-800-334-75n. • ••• o 0 0 In case 01 minor apliis or leaks follow d precautions Indcated above and cIeately. 0 0 0 Soak up with .. nd. earth or oIher eu!labIe material and dispose of wastes and brOkell ct ef11llY 0 oontalners In a landfill appIOVedlor pelllclde use. 0.00 •• • • • 0 • • •• o 0 0 ••••• •• •• • • o 0 0 ••••• .. 0 o 0 0 .. 0 .. 0 o 0 0 ... 8

, ( LARVIN«I brand 500 Thlodlcarb InHCtICld .. Pendlng·CI25188 LIMITED WARRANTY AND DISCLAIMER

1. The manullIClunll" wanart. (8) thatlhls proclIGt conIormI to the chemical ~ on the label; (b) that this pcoduc:t Is reasonably fit for the purposes set forth In the clrectIons for use when It Is used In ac:conIance with such cIrec:tions; and (e) that the clrectIons. wanings and other statemeru on this label 818 based upon responsible experts' evaklation of reasonable tests of effectivel188S. of toxicity to laboratory animals and to plants. and of I8SiclJes on food crops. and upon reports of field expe!IeIlC8S. Tests have not been made on aD valletles or In II Slates or under aD COIdtiolis. THE MANUFACTURER NEITHER MAKES NOR INTENDS. NOR DOES IT AUTHORIZE ANY AGENT OR REPRESENTATIVE TO MAKE. ANY OTHER WARRANTIES. EXPRESS OR IMPLIED. AND IT EXPRESSLY EXClUDES AND DISClAIMS ALL IMPLIED WARRANTIES OF MERCHANTABIUTY OR RTNESS FOR A PARTICULAR PURPOSE.
2. THIS WARRANTY DOES NOT EXTEND TO. AND THE BUYER SHAll. BE SOlELY RESPONSIBLE FOR. ANY AND ALL LOSS OR DAMAGE WHICH RESUI.. TS FROM THE USE OF THIS PRODUCT IN ANY MANNER WHICH IS INCONSISTENT WITH THE LABEL DlREC11ONS. WARNINGS OR CAUTIONS.
3. BUYER"S EXCLUSIVE REMEDY AND ... .ANUFACTURER'S OR SELLER'S EXCLUSIVE LIABIL1TY FOR ANY AND ALL ClAlMS. LOSSES. DAMAGES. OR INJURIES RESUL 11NG FROM THE USE OR HANDLING OF THIS PRODUCT. WHETHER OR NOT BASED IN CONTRACT. NEGLIGENCE. STRICT LIABILITY IN TORT OR OTHERWISE. SHAll. BE LIMITED. AT THE MANUFACTURER'S OPTION. TO REPLACEMENT OF. OR THE REPAYMENT OF THE PURCHASE PRICE FOR. THE OUANTITY OF PRODUCT WITH RESPECT TO WHICH DAMAGES ARE CLAIMED. IN NO EVENT SHAI..L MANUFACTURER OR SELLER BE LIABLE FOR SPECIAL. INOtRECT OR CONSEQUENTIAl.. DAMAGES RESUL 11NG FROM "!liE USE OR HANDUNG OF THIS PRODUCT. NOTICE TO THE BUYER Purchase of this material does not confer any rights under patents goyeming this ~ or the use thereof In countries outside 01 the United States. 9 • • •• • •• · .... , . . . • •• • •• • • • · , . , .. • • • • • • • • •• " . . . . .. .. • • •• • • •••• .. . • •• ••• •• • • •• •••