crop-chem-docs/corpus/epa_ppls/264-540.md

BUCTRIL 4EC HERBICIDE

• EPA Reg No: 264-540
• Registrant: BAYER CROPSCIENCE, LLC
• Signal word: Warning
• Active ingredients: Bromoxynil octanoate (28%); Bromoxynil heptanoate (27%)
• Label accepted: 2022-12-19
• Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/000264-00540-20221219.pdf

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UNITED STATES ENVIRONMENTAL PROTECTION AGENCY WASHINGTON, DC 20460

OFFICE OF CHEMICAL SAFETY AND POLLUTION PREVENTION

December 19, 2022

Matthew Graneto Senior Regulatory Manager Bayer CropScience 800 N. Lindbergh Blvd. St. Louis, MO 63167

Subject: Registration Review Label Amendments Incorporating Mitigation Measures from the Interim Decision for Bromoxynil and the National Marine Fisheries Services’ (NMFS) Biological Opinion on the Effects of Bromoxynil on Pacific Salmonids Product Name: BUCTRIL 4EC HERBICIDE EPA Registration Number: 264-540 Application Dates: 4/17/2020 and 2/22/2022 Decision Numbers: 561925 and 588735

Dear Matthew Graneto:

The Agency, in accordance with the Federal Insecticide, Fungicide and Rodenticide Act (FIFRA), as amended, has completed reviewing all the information submitted with your application to support the Registration Review of the above referenced product in connection with the Bromoxynil Interim Decision. The Agency has concluded that your submission is acceptable.

This letter also addresses the label mitigation resulting from the NMFS’ Biological Opinion on the effects of Bromoxynil on Pacific salmonids. The Agency has concluded that your submission is also acceptable. The label referred to above, submitted in connection with registration under FIFRA, as amended, is acceptable.

Should you wish to add/retain a reference to the company’s website on your label, then please be aware that the website becomes labeling under the Federal Insecticide Fungicide and Rodenticide Act and is subject to review by the Agency. If the website is false or misleading, the product would be misbranded and unlawful to sell or distribute under FIFRA section 12(a)(1)(E). 40 CFR 156.10(a)(5) list examples of statements EPA may consider false or misleading. In addition, regardless of whether a website is referenced on your product’s label, claims made on the website may not substantially differ from those claims approved through the registration process. Therefore, should the Agency find or if it is brought to our attention that a website contains false or misleading statements or claims substantially differing from the EPA approved registration, the website will be referred to the EPA’s Office of Enforcement and Compliance.

A stamped copy of your labeling is enclosed for your records. This labeling supersedes all previously accepted labeling. You must submit one copy of the final printed labeling

Page 2 of 2 EPA Reg. No. 264-540 Decision No. 561925 and 588735

before you release the product for shipment with the new labeling. In accordance with 40 CFR 152.130(c), you may distribute or sell this product under the previously approved labeling for 12 months from the date of this letter. After 12 months, you may only distribute or sell this product if it bears this new revised labeling or subsequently approved labeling. “To distribute or sell” is defined under FIFRA section 2(gg) and its implementing regulation at 40 CFR 152.3.

If you have any questions about this letter, please contact Quinn Gavin at gavin.quinn@epa.gov.

Sincerely,

Linda Arrington, Branch Chief Risk Management and Implementation Branch 4 Pesticide Re-Evaluation Division Office of Pesticide Programs

Enclosure

1 BUCTRIL® 4EC HERBICIDE FOR THE CONTROL OF CERTAIN BROADLEAF WEEDS IN CORN (FIELD AND POP) , SORGHUM (GRAIN AND FORAGE), WHEAT, BARLEY, OATS, RYE AND TRITICALE, S EEDLING ALFALFA, FLAX, GARLIC, MINT, ONIONS (DRY BULB), GRASSES GROWN FOR SOD PRODUCTION, NON-RESIDENTIAL TURFGRASS, AND NON- CROPLAND/INDUSTRIAL SITES. ACTIVE INGREDIENTS: Octanoic acid ester of bromoxynil* (3, 5-dibromo-4-hydroxybenzonitrile). ............................................................28% Heptanoic acid ester of bromoxynil (3, 5-dibromo-4-hydroxybenzonitrile) ............................................................27% INERT INGREDIENTS:..........................................................................................................................................45% TOTAL: 100% Contains xylene range/petroleum distillates. *Equivalent to not less than 4.0 pounds of bromoxynil per gallon. E.P.A. Reg. No. 264-540 E.P.A. Est. No. 34704-MS-1 KEEP OUT OF REACH OF CHILDREN AVISO WARNING Si usted no entiende la etiqueta, busque a alguien para que se la explique a usted en detalle. (If you do not understand the label, find someone to explain it to you in detail.) For MEDICAL And TRANSPORTATION Emergencies ONLY Call 24 Hours A Day 1-800-334-7577 For PRODUCT USE Information Call 1-866-99BAYER (1-866-992-2937) FIRST AID IF SWALLOWED: x Immediately call a poison control center or doctor for treatment advice. x Do not induce vomiting unless told to do so by a poison control center or doctor. x Do not give any liquid to the person. x Do not give anything by mouth to an unconscious person. IF ON SKIN OR CLOTHING: x Take off contaminated clothing. x Rinse skin immediately with plenty of water for 15-20 minutes. x Call a poison control center or doctor for treatment advice. IF IN EYES: x Hold eye open and rinse slowly and gently with water for 15-20 minutes. x Remove contact lenses, if present, after the first 5 minutes, then continue rinsing. x Call a poison control center or doctor for treatment advice. IF INHALED: x Move person to fresh air. x If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth -to- mouth if possible. x Call a poison control center or doctor for further treatment advice. For MEDICAL Emergencies Call 24 Hours A Day 1-800-334-7577. Have the product container or label with you when calling a poison control center or doctor or going for treatment. NOTE TO PHYSICIAN: Contains petroleum distillate – vomiting may cause aspiration pneumonia. BROMOXYNIL GROUP 6 HERBICIDE Dec 19, 2022 264-540

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PRECAUTIONARY STATEMENTS HAZARDS TO HUMANS AND DOMESTIC ANIMALS WARNING May be fatal if swallowed. Harmful if absorbed through skin or inhaled. Causes moderate eye irritation. Avoid contact with skin, eyes, or clothing. Avoid breathing spray mist. Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals.

ENGINEERING CONTROL STATEMENT When handlers use closed systems, enclosed cabs or aircraft in a manner that meets the requirements listed in the Worker Protection Standard (WPS) for agricultural pesticides [40 CFR 170.240 (d)(4-6)], the handler PPE requirements may be reduced or modified as specified in the WPS. Handlers must use closed mixing loading systems during mixing/loading liquids for aerial applications to fallow land and high-acreage field crops.

PERSONAL PROTECTIVE EQUIPMENT (PPE) Applicators and other handlers must wear a long-sleeved shirt and long pants, chemical resistant gloves such as barrier laminat e, butyl rubber > 14 mils, nitrile rubber > 14 mils, or neoprene rubber > 14 mils, for cleaning equipment and mixing/loading, a chemical -resistant apron when cleaning equipment and mixing/loading and shoes plus socks. Discard clothing and other absorbent materials that have been drenched or heavily contaminated with this product's concentrate. Do not reuse them. Follow manufacturer’s instructions for cleaning/maintaining PPE . If no such instructions for washables exist, use detergent and hot water. Keep and wash PPE separately from other laundry. When handlers use closed systems, enclosed cabs, or aircraft in a manner that meets the requirements listed in the Worker Prote ction Standard (WPS) for agricultural pesticides (40 CFR 170.240(d)(4-6), the handler PPE requirements may be reduced or modified as specified in the WPS. If you will handle a total of 30 gallons or more of this produc t per day, you must use a mechanical transfer system for all mix ing and loading operations. If this product is packaged in a 30-gallon dr um, you must use a mechanical transfer system, which terminate s in a drip-free hard coupling, which may be used only with a spray, or mix tank which has been fitted with a compatible coupling. If you do not presently own or have access to a mechanical transfer system with this type of coupling, contact your dealer for informatio n on how to obtain such a system or to modify your present system. When using a mechanical transfer system, do not remove or disconnect the pump or probe from the container until the container has been empt ied and rinsed. The pump or probe system must be used to rins e the empty container and to transfer the rinsate directly to the mixing or spray tank. Application from a tractor or aerial application with a complete ly enclosed cab is required whenever this product is applied to 360 or more acres in a day. To avoid contamination, coveralls and gloves worn when handling the concentrate must be removed prior to entering an enclosed cab or cockpit. When applying from a tracto r with an enclosed cab, clean coveralls and clean nitrile glove s must be kept inside the cab, and must be worn when exiting the cab to perform in-field maintenance or repair. To reduce exposure to residues, wash the spray rig, tractor, and all other equipment used to handle or apply this product with water daily or before using the equipment for any other purpose.

APPLICATION BY CHEMIGATION must be done by fixed pipe, overhead sprinkler systems or hand moved pipe. If hand moved pipe is used for chemigation, the pipe must not be handled in any way until 24 hours after chemigation has been completed and residues have been flushed from the system. When applying by chemigation, no person may enter the application site unless in an enclosed vehicle.

User Safety Recommendations Users should wash hands before eating, drinki ng, chewing gum, using tobacco or using the toilet. Users should remove clothing/P PE immediately if pesticide gets inside. Remove PPE immediately after handling this product. Wash the outside of gloves before rem oving. As soon as possible, wash thoroughly and change into clean clothing.

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ENVIRONMENTAL HAZARDS This pesticide is toxic to wildlife and fish. Use with care when applying to areas frequented by wildlife or adjacent to any bo dy of water. For terrestrial uses, do not apply directly to water, to areas whe re surface water is present or to intertidal areas below the mean high water mark. Do not apply when weather conditions favor drift fr om target areas. Do not contaminate water when cleaning equipmen t or disposing of equipment washwaters.

Non-Target Organism Advisory Statement This product is toxic to plants and may adversely impact the forage and habitat of non-target organisms, including pollinators , in areas adjacent to the treated site. Protect the forage and habitat of non -target organisms by following label direc tions intended to minimize spray drift.

Reporting Ecological Incidents To report ecological incidents, including mortality, injury, or harm to plants and animals, call [1-866-99BAYER (1-866-992- 2937)].

PHYSICAL AND CHEMICAL HAZARDS Do not use or store near heat or open flame.

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DIRECTIONS FOR USE It is a violation of Federal Law to use this product in a manner inconsistent with its labeling. Read entire label before using this product. Do not apply this product in a way that will contact workers or ot her persons, either directly or through drift. Only protected handlers may be in the area during application. For any requirements specif ic to your State or Tribe, consult the agency responsible for pesticide regulation. Endangered Species Protection Requirements: It is a Federal offense to use any pesticide in a manner that results in an unauthorized “take” (e.g., kill or otherwise harm) of an endangered species and certain threatened species, under the Endangered Species Act section 9. When using this product, you must follow the measures contained in the Endangered Species Protection Bulletin for the area in which you are applying the product. You must obtain a Bulletin no earlier than six months before using this product. To obtain Bulletins, consult http://www.epa.gov/espp/, call 1-844-447-3813, or email ESPP@epa.gov. You must use the Bulletin valid for the month in which you will apply the product.

USE RESTRICTIONS Aerial application to fallow land is restricted with 25 feet of residential areas (e.g., Homes, schools, playgrounds, shopping areas, hospital, etc.). Do not apply with backpack or hand-held application equipment. Do not apply this product to golf course turf. Apply to non-residential turf only. Do not apply to residential, playground, or schoolyard turf.

Use of this product in certain portions of California, Oregon, and Washington is subject to the January 22, 2004 Order for injunctive relief in Washington Toxics Coalition, et. al. v. EP, C01-0132C, (W.D.WA). For further information, please refer to http://www.epa.gov/espp/listatus/wtc/index.htm.

AGRICULTURAL USE REQUIREMENTS Use this product only in accordance with its labeling and with the Worker Protection Standard, 40 CFR part 170. This standard contains requirements for the protection of agricultural workers on fa rms, forests, nurseries, and greenhouses, and handlers of agricult ural pesticides. It contains requirements for training, decontamination, notification, and emergency assistance. It also contains sp ecific instructions and expectations pertaining to the statements on this label about personal protective equipment (PPE) and restrict ed-entry intervals. The requirements in this box only apply to uses of this product that are covered by the Worker Protection Standard. Do not enter or allow worker entry into treated crops during the re stricted entry interval (REI). REI for harvesting sod farm t urf is 12 days. The REI for other turf activities is 24 hours. For uses on turf grown for transplanting (e.g. on sod farms), notify worke rs of the application by warning them orally and by posting warning signs at entrances to treated areas. Do not enter or allow worker into treated areas during the restri cted -entry interval (REI) of 2 days for onion, corn, alfalfa, grass, mint and garlic. PPE required for early entry to treated areas that is permitted u nder the Worker Protection Standard and that involves contact with anything that has been treated such as plants, soil or water, is coveralls over long-sleeved shirt and long pants, socks, shoes , chemical resistant gloves such as barrier laminate, butyl rubber > 14 mils, nitrile rubber > 14 mils, or neoprene rubber > 14 mils, and protective eye wear.

NON-AGRICULTURAL USE REQUIREMENTS The requirements in this box apply to the use of this produc t on non-residential turfgrass and non-cropland and industrial sit es that are NOT within the scope of the Worker Protection Standard (WPS) for ag ricultural pesticides (40 CFR Part 170). The WPS applies whe n this product is used to produce agricultural plants on farms, forests, nurseries, or greenhouses. Do not enter or allow others to enter the treated area until sprays have dried.

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USE INFORMATION BUCTRIL® 4EC is formulated as an emulsifiable concentrate of octanoic acid and heptanoic acid esters of bromoxynil containing the equivalent of 4 pounds of bromoxynil per gallon. BUCTRIL 4EC is a selective postemergence herbicide for control of important broadleaf weeds infesting corn (field and pop), sor ghum (grain and forage), wheat, barley, oats, rye, triticale, al falfa (seedling), flax, onions, garlic, mint (established peppermint and spearmint), grasses grown for sod production, non-residential turfgrass, and non-cropland and industrial sites. Optimum weed control is obt ained when BUCTRIL 4EC is applied to actively growing weed seedlings. BUCTRIL 4EC is primarily a contact herbicide; therefore thorough coverage of the weed seedlings is essential for optimum control. BUCTRIL 4EC has little residual activity. Therefore, subsequent fl ushes of weeds will not be controlled by the initial treatmen t. Generally, crops that form a good canopy will help shade subsequent weed flushes. However, certain crops or short-straw varieties, for example Yaccora Rojo wheat, may not develop the crop canopy fast enough to shade the subsequent flushes of weeds. Occasional transitory leaf burn may occur. The temporary leaf bur n is similar to that seen with liquid fertilizer. Because the activity of BUCTRIL 4EC is not systemic, recovery of the crop is generally rapid with no lasting effect. Frequency and amount of leaf burn may be greater when crops are stressed by abrasive winds, cool to cold ev ening temperatures or mechanical injury, such as that caused by hail, sleet or insect feeding. To reduce the potential for temporar y leaf burn, applications should be made to dry foliage in t he recommended spray volumes per acre when weather conditions are not extreme. WEED RESISTANCE MANAGEMENT For resistance management, BUCTRIL 4EC is a Group 6 herbicide. Any weed population may contain or develop plants naturally resistant to BUCTRIL 4EC and other Group 6 herbicides. The resistant biotypes may dominate the weed population if these herbicides are used repeatedly in the same field. Appropriate resistance management strategies should be followed.

To delay herbicide resistance take one or more of the following steps: x Rotate the use of BUCTRIL 4EC or other Group 6 herbicides within a growing season sequence or among growing seasons with different herbicide groups that control the same weeds in a field. x Use tank mixtures with herbicides from a different group if such use is permitted; where information on resistance in target weed species is available, use the less resistance-prone partner at a rate that will control the target weed(s) equally as well as the more resistance-prone partner. Consult your local extension service or certified crop advisor if you are unsure as to which active ingredient is currently less prone to resistance. x Adopt an integrated weed-management program for herbicide use that includes scouting and uses historical information related to herbicide use and crop rotation, and that considers tillage ( or other mechanical control methods), cultural ( e.g., higher crop seeding rates; precision fertilizer application method and timing to favor the crop and not the weeds), biological (weed-competitive crops or varieties) and other management practices. x Scout after herbicide application to monitor weed populations for early signs of resistance development. Indicators of possibl e herbicide resistance include: (1) failure to control a weed species normally controlled by the herbicide at the dose applied, especially if control is achieved on adjacent weeds; (2) a spreading patch of non-controlled plants of a particular weed species; (3) surviving plants mixed with controlled individuals of the same species. If resistance is suspected, prevent weed seed production in the affected area by an alternative herbicide from a different group or by a mechanical method such as hoeing or tillage. Prevent movement of resistant weed seeds to other fields by cleaning harvesting and tillage equipment when moving between fields, and planting clean seed. x If a weed pest population continues to progress after treatment with this product, discontinue use of this product, and switch to another management strategy or herbicide with a different mode of action, if available. x Contact your local extension specialist or certified crop advisors for additional pesticide resistance-management and/or integrated weed-management recommendations for specific crops and weed biotypes. For further information or to report suspected resistance, contact Bayer CropScience at 1-866-99BAYER (1-866-992-2937). You can also contact your pesticide distributor or university extension specialist to report resistance.

MIXING, LOADING AND HANDLING INSTRUCTIONS 2.5 Gallon Containers Special care must be taken in mixing and loading this product. Hands should be placed on the container in such a way as to avoi d possible drip or splash. Correct procedures for mixing and loading are provided in Bayer CropScience’s Educational Program. 30 Gallon and Bulk Containers If you will handle a total of 30 gallons or more of this produc t per day, you must use a mechanical transfer system for all mix ing and loading operations. If this product is packaged in a 30-gallon dr um, you must use a mechanical transfer system, which terminate s in a drip-free hard coupling, which may be used only with a spray, or mix tank which has been fitted with a compatible coupling. If you do not presently own or have access to a mechanical transfer system with this type of coupling, contact your dealer for information on how to obtain such a system or to modify your present system. When using a mechanical transfer system, do not remove or disconnect the pump or probe from the container until the container has been empt ied and rinsed. The pump or probe system must be used to rins e the empty container and to transfer the rinsate directly to the mixing or spray tank. BUCTRIL 4EC ALONE: Fill the spray tank 1/2 to 3/4 full with clean water. Begin agitation and add the specified amount of BUCTRIL ® 4EC. Add water to the spray tank to the desired level. Maintain sufficient agitation to ensure a uniform spray mixture during application.

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TANK MIXTURES: BUCTRIL 4EC can be tank-mixed with other pesticide produ cts provided that these other products are registered for use on the crop/use site to be treated. The tank mix must be used in accordance with the more restrictive pesticide label l imitations and precautions. No label dosage rates may be exceeded. BUCTRI L 4EC cannot be mixed with any product containing a label prohibition against such mixing. Refer to the specific crop sect ion for rates and other restrictions. To apply BUCTRIL 4EC in m ixture with another product, fill the spray tank 1/2 to 3/4 full with clean water and begin agitation. If tankmixing with wettable pow der, soluble powder, flowable or dry flowable products, add the powder or flowable product first. After the other herbicide is thoroughly mi xed with water add the specified amount of BUCTRIL 4EC and add water to the spray tank to the desired level. If tankmixing with other pr oduct types, add the BUCTRIL 4EC first before adding the other produc t. Always mix one product in water thoroughly before adding anot her product or compatibility problems may occur. Never mix two products together without first mixing in water. Maintain sufficient agitation while mixing and during application to ensure a uniform spray mixture. If spray mixture is allowe d to remain without agitation for short periods of time, be sure to agitate until uniformly mixed before application.

COMPATIBILITY OF OTHER PESTICIDES WITH BUCTRIL 4EC The following foliar insecticides are compatible with BUCTRIL 4EC Herbicide as tank mixtures. INSECTICIDE COMMON NAME

TRADE NAME

FORMULATION Acephate Orthene® Soluble Powder Amitraz Ovasyn® Emulsifiable Concentrate Azinphos-methyl Guthion® Liquid Carbaryl Sevin® Sprayable wettable powder or Flowable Carbofuran Furadan® Flowable Chlorpyrifos Lorsban® Emulsifiable Concentrate Cyfluthrin Baythroid® Emulsifiable Concentrate Deltamethrin Decis® Emulsifiable Concentrate Diazinon Various Emulsifiable Concentrate Dicrotophos Bidrin® Emulsifiable Concentrate Dimethoate Various Emulsifiable Concentrate Esfenvalerate Asana XL® Emulsifiable Concentrate Fenvalerate Pydrin® Emulsifiable Concentrate Imidacloprid Provado® Flowable Lambda-Cyhalothrin Karate® Emulsifiable Concentrate Malathion Various Emulsifiable Concentrate Methomyl Lannate® Liquid Methyl Parathion Methyl Parathion® Emulsifiable Concentrate Methyl Parathion Penncap-M® Flowable Oxamyl Vydate® Liquid Oxydemeton-methyl Metasystox-R® Sprayable Concentrate Permethrin Pounce® Emulsifiable Concentrate Thiodicarb Larvin® Flowable Trichlorfon Dylox® Soluble Powder Zeta-Cypermethrin Fury® Emulsifiable Concentrate

HERBICIDE COMMON NAME

TRADE NAME

FORMULATION MSMA* MSMA® Prometryn Caparol® Liquid Pyrithiobac-Sodium Staple® Soluble Powder

• Note that MSMA cannot be used after December 2013

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PLANT GROWTH REGULATORS COMMON NAME

TRADE NAME

FORMULATION Mepiquat Chloride Pix® Liquid Concentrate Mepiquat Chloride MEP® Liquid Concentrate Mepiquat Chloride + Bacillus cereus Mep Plus® Liquid Concentrate

If tank mixing with products other than those listed above or withi n each crop section, a compatibility test is recommended to ensure satisfactory spray preparation. To test for compatibility, use a small container and mix a small amount (0.5 to 1 quart) of spr ay, combining all ingredients in the same ratio as the anticipated use. If any indications of physical incompatibility develop, do not use this mixture for spraying. Indications of incompatibility usually will appear within 5 to 15 minutes after mixing. To ensure maximum crop safety and weed control, follow all cautions and limitations on th is label and the labels of products used in the tank mixture with BUCTRIL® 4EC.

SPRAYABLE LIQUID FERTILIZERS AND SPRAY ADDITIVES BUCTRIL 4EC can be applied in combination with sprayable liquid fe rtilizer or spray additives such as surfactants or crop oil concentrate. When tankmixing with liquid fertilizer always add th e fertilizer to the spray tank first and agitate thoroughly be fore adding BUCTRIL® 4EC. Always predetermine the compatibility with liquid fertilizer by mixing small proportional quantities in advance. Agitation must be maintained during filling and application operations to ens ure that BUCTRIL 4EC is evenly mixed with the fertilizer. Le af burn may occur when BUCTRIL 4EC is applied with liquid fertilizer, but new leaves are not adversely affected. CAUTION: Fertilizers and spray additives can incr ease foliage leaf burn when applied with BUCTRIL ® 4EC. Do not apply fertilizers or spray additives with BUCTRIL 4EC if leaf burn is a major concer n due to environmental conditions, crop or variety sensitivity t o BUCTRIL® 4EC. Do not apply BUCTRIL 4EC in combinat ion with fertilizers or spray additives if restricted under the individual crop use directions.

APPLICATION PROCEDURES BUCTRIL 4EC can be applied to registered us e areas by ground, aerial and sprinkler irrigation equipment. The following provides registered methods of application for each crop.

TYPE OF APPLICATION EQUIPMENT

CROP

GROUND

AERIAL SPRINKLER IRRIGATION Corn, (field and pop) X X X Sorghum (grain and forage), and Sudangrass X X X Wheat, Barley, Oats, Rye and Triticale X X X Alfalfa (seedling) X X X Flax X X - Garlic X X X Mint X - X Onions X X* X Grass grown for sod production X X X Non-residential turfgrass X X - Non-cropland/Industrial sites X X - (X) indicates registered application use

• Preemergence only GROUND APPLICATION Use a standard herbicide boom sprayer that provides uniform and accurate application. Sprayer should be equipped with screens n o finer than 50 mesh in the nozzle tips and in-line strainers. Select a spray volume and delivery system that will ensure thorough and uniform spray coverage. For optimum spray distribution and thorough coverage use of flat fan nozzles (maximum tip size 8008) with a spray pressure of 40-60 psi are recommended. Other noz zle types and lower spray pressures that produce coarse spray dropl ets may not provide adequate coverage of the weeds to ensure optimum control. Raindrop® nozzles and flood nozzles are not recommended as weed control with BUCTRIL 4EC may be reduced. In general, a spray volume of 10 to 20 gallons per acre (GPA) is recommended for optimum spray coverage. A minimum of 5 GPA wit h a minimum spray pressure of 50 psi and a maximum ground spee d of 10 mph may be used with higher speed, low volume ground application if ground terrain, crop and weed density allow effective spray distribution. When using higher speed equipment, a m aximum ground speed of 10 mph is suggested if field conditions cause excessive boom movement during application which results in poor spray

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coverage. Ground applications made when dry, dusty field conditio ns exist may provide reduced weed control in wheel track areas . Applications using less than 10 gallons per acre may result in reduced weed control. When weed infestations are heavy, use of higher spray volumes and spray pressure will be helpful in obtaining uniform weed cove rage. When corn or grain sorghum are large enough to interfere with th e spray pattern, drop nozzles should be used to obtain uniform weed coverage. If you are unsure of the infestation level or size of crop, consult your local extension service. AERIAL APPLICATION Use orifice discs, cores and nozzle types and arrangements that will provide for optimum spray distribution and maximum coverag e. In general, a minimum spray volume of 5 GPA and a maximum pressure of 40 psi are recommended.

SPRINKLER IRRIGATION APPLICATION BUCTRIL 4EC Herbicide can be applied through sprinkler irrigation systems to wheat, barley, oats, rye and triticale, field corn, popcorn, and grain sorghum, mint, grasses grown for sod production, garlic, and seedling alfalfa. Apply BUCTRIL 4EC Herbicide through sprinkler systems including c enter pivot, lateral move, side (wheel) roll, solid set or han d move irrigation systems only. If hand moved pipe is used for chemigatio n, the pipe must not be handled in any way until 24 hours aft er chemigation has been completed and residues have been flushed from the system. When applying by chemigation, no person may enter the application site unless in an enclosed vehicle. Do not apply this product through any other type of irrigation system. SPECIFIC REQUIREMENTS FOR APPLICATION THROUGH AUTOMATED SPRINKLER IRRIGATION SYSTEM.

1. The system must contain a functional check valve, vacuum re lief valve, and low-pressure drain appropriately located on the irrigation pipeline to prevent water source contamination from backflow.
2. The pesticide injection pipeline must contain a functional, au tomatic, quick-closing check valve to prevent the flow of flui d back toward the injection pump.
3. The pesticide injection pipeline must also contain a functional, normally closed, solenoid-operated valve located on the int ake side of the injection pump and connected to the system interlock to prevent fluid from being withdrawn from the supply tank whe n the irrigation system is either automatically or manually shut down.
4. The system must contain functional interlocking controls to automatically shut off the pesticide injection pump when the wat er pump motor stops.
5. The irrigation line or water pump must include a functional pressure switch, which will stop the water pump motor when the w ater pressure decreases to the point where pesticide distribution is adversely affected.
6. Systems must use a metering pump, such as a positive displa cement injection pump (e.g., diaphragm pump) effectively designed and constructed of materials that are compatible with pesticides and capable of being fitted with a system interlock.
7. Do not apply when wind speed favors drift beyond the area intended for treatment.
8. Agitation is recommended in the pesticide supply tank when applying the BUCTRIL 4EC Herbicide.
9. BUCTRIL 4EC Herbicide should be applied continuously for the duration of the water application with center pivot and continuous lateral move systems. Application of BUCTRIL 4EC Herbicide sh ould be made during the last 30-45 minutes of the irrigation set with other overhead sprinkler systems.
10. For best performance, set the sprinkler system to deliver approximately 0.5 inch or less of water per acre.
11. Remove scale, pesticide residues and other foreign matter from the supply tank and entire injector system. Flush with clean water.
12. If BUCTRIL 4EC Herbicide is diluted in the supply tank, fill the tank with half of the water amount desired, add the BUCTRI L 4EC and then add remaining water amount with agitation. Always dilute with at least 4 parts water to 1 part BUCTRIL® 4EC.
13. Start the sprinklers and then inject BUCTRIL 4EC Herbicide in to the irrigation line. BUCTRIL 4EC should be injected with a positive displacement pump into the main line at least 8 feet ahead of a right angle turn to insure adequate mixing. Refer to t he BUCTRIL 4EC Herbicide label for detailed information on application rates and timings. CHEMIGATION USER PRECAUTIONS Application of more than 0.5 inch/acre of irrigation water may result in decreased product performance on certain soils. Do not apply when conditions favor drift, when system connections or fittings leak, or when nozzles do not provide uniform distribution. Allow sufficient time for pesticide to be flushed through all the lines and nozzles before turning off irrigation water. Crop injury, lack of effectiveness, or illegal pesticide residues in the crop can result from non-uniform distribution of treated water. Do not connect an irrigation system used for pesticide application to a public water system. If you have questions about calibration, you should contact Stat e Extension Service specialists, equipment manufacturers or oth er experts. A person knowledgeable of the chemigation system and responsibl e for its operations, or under the supervision of the responsibl e person, shall shut the system down and make necessary adjustments should the need arise.

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CULTIVATION When properly utilized, timely cultivations of row crops may aid overall weed control efforts as well as crop growth. However, cultivation BEFORE or DURING BUCTRIL 4EC applications may place target wee ds under stress, resulting in erratic weed control. Whenever BUCTRIL 4EC is being utilized in an overall weed control program , plan to postpone any anticipated cultivations until 5-7 days after application to ensure best performance.

MANDATORY SPRAY DRIFT MANAGEMENT Aerial Applications x Do not release spray at a height greater than 10 ft above the ground or vegetative canopy, unless a greater application height is necessary for pilot safety. x Applicators are required to use a fine or coarser droplet size (ASABE S641). x Do not apply when wind speeds exceed 10 mph at the application site. x The boom length must be 75% or less of the wingspan for fixed-wing aircraft and 90% or less of the rotor diameter for helicopters. x Applicators must use ½ swath displacement upwind at the downwind edge of the field. x Do not apply during temperature inversions.

Ground Boom Applications x User must only apply with the release height recommended by the manufacturer, but no more than 4 feet above the ground or crop canopy. x Do not apply when wind speeds exceed 10 mph at the application site. x Do not apply during temperature inversions.

SPRAY DRIFT ADVISORIES THE APPLICATOR IS RESPONSIBLE FOR AVOIDING OFF-SITE SPRAY DRIFT. BE AWARE OF NEARBY NON-TARGET SITES AND ENVIRONMENTAL CONDITIONS.

IMPORTANCE OF DROPLET SIZE An effective way to reduce spray drift is to apply large droplets. Use the largest droplets that provide target pest control. While applying larger droplets will reduce spray drift, the potential for drift will be greater if applications are made improperly or under unfavorable environmental conditions.

Controlling Droplet Size – Ground Boom x Volume - Increasing the spray volume so that larger drop lets are produced will reduce spray drift. Use the highest practical spray volume for the application. If a greater spray volume is needed, consider using a nozzle with a higher flow rate. x Pressure - Use the lowest spray pressure recommended for the nozzle to produce the target spray volume and droplet size. x Spray Nozzle - Use a spray nozzle that is designed for the in tended application. Consider using nozzles designed to reduce drift.

Controlling Droplet Size – Aircraft Adjust Nozzles - Follow nozzle manufacturers recommendations for setting up nozzles. Generally, to reduce fine droplets, nozzles should be oriented parallel with the airflow in flight.

BOOM HEIGHT – Ground Boom For ground equipment, the boom should remain level with the crop and have minimal bounce.

RELEASE HEIGHT - Aircraft Higher release heights increase the potential for spray drift.

SHIELDED SPRAYERS Shielding the boom or individual nozzles can reduce spray drift. Consider using shielded sprayers. Verify that the shields are not interfering with the uniform deposition of the spray on the target area.

TEMPERATURE AND HUMIDITY When making applications in hot and dry conditions, use larger droplets to reduce effects of evaporation.

TEMPERATURE INVERSIONS Drift potential is high during a temperature inversion. Temperature inversions are characterized by increasing temperature with altitude and are common on nights with limited cloud cover and light to no wind. The presence of an inversion can be indicated by ground fog or by the movement of smoke from a ground source or an aircraft smoke generator. Smoke that layers and moves laterally in a concentrated cloud (under low wind conditions) indicates an

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inversion, while smoke that moves upward and rapidly dissipates indicates good vertical air mixing.

WIND Drift potential generally increases with wind speed. AVOID APPLICATIONS DURING GUSTY WIND CONDITIONS. Applicators need to be familiar with local wind patterns and terrain that could affect spray drift.

WEED LIST Postemergence application of BUCTRIL 4EC Her bicide will control the following weeds when sprayed in the seedling stage. Maximum weed stage of growth is listed under USES for each crop. MOST SUSCEPTIBLE BROADLEAF WEED SPECIES Annual Sowthistle (Sonchus oleraceus) Black Nightshade (Solanum nigrum) Blue Mustard (Chorispora tenella) Bristly starbur (Acanthospermum hispidum) Coast Fiddleneck (Amsinckia intermedia) Common Cocklebur (Xanthium strumarium) Common Lambsquarters (Chenopodium album) Common Tarweed (Hemizonia congesta) Cutleaf Nightshade (Solanum triflorum) Eastern Black Nightshade (Solanum ptycanthum) Field Pennycress (Thlaspi arvense) Green Smartweed (Polygonum scabrum) Hairy Nightshade (Solanum sarachoides) Jimsonweed (Datura stramonium) Ladysthumb (Polygonum persicaria) Lanceleaf sage (Salvia reflexa) Pennsylvania Smartweed (Polygonum strumarium) Pepperweed spp. (annual) (Lepidium spp.) Shepherdspurse (Capsella bursa-pastoris) Silverleaf Nightshade (Solanum elaeagnifolium) Tartary Buckwheat (Fagopyrum tatoricum) 1Sunflower (Helianthus annus) Wild Buckwheat (Polygonum convolvulus) 1For control of sunflower, delay application until first emerging sunflower seedlings are 4 inches in height.

2 For effective control, these weeds should not exceed the 4-leaf stage or 2 inches in height, whichever comes first. SUSCEPTIBLE BROADLEAF WEED SPECIES Buffalobur (Solanum rostratum) Burcucumber ( Sicyos angulatus) Cluster Flower (Flaveria trinervia) Common Groundsel (Senecio vulgaris) Common ragweed (Ambrosia artemisiifolia) Corn Chamomile (Anthemis arvensis) Corn Gromwell (Lithospermum arvense) Cow Cockle (Saponaria vaccaria) Devils claw (Proboscidea louisianica) Giant Ragweed (Ambrosia trifida) Hemp Sesbania (Sesbania exaltata) Hophornbean Copperleaf (Acalypha ostryaefolia) Ivyleaf morningglory (Ipomoea hederacea) Knawel (Scleranthus annus) 2Kochia (Kochia scoparia) London Rocket (Sisymbrium irio) Mayweed (Anthemis cotula) Pitted morningglory ( Ipomoea lacunosa) Prairie sunflower (Helianthus petiolaris) Prostrate Knotweed (Polygonum aviculare) Puncture Vine (Tribulus terrestris) 2Redroot Pigweed (Amaranthus retroflexus) Russian Thistle (Salsola kali) 2Spiny Pigweed (Amaranthus spinosus) Tall Morningglory (Ipomoea purpurea) 2Tall Waterhemp (Amaranthus tuberculatus) Tumble mustard (Sisymbrium altissimum) Velvetleaf (Abutilon theophrasti) Venice Mallow (Hibiscus trionum) Wild Mustard (Sinapis arvensis) Wild Radish (Raphanus raphanistrum) Woolly Croton (Croton capitatus) Yellow Starthistle (Centaurea solstitialis)

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WEED SUPPRESSION BUCTRIL 4EC suppresses the growth of Canada thistle (Cirsium arvense) by burning down top growth. Regrowth may occur. CALIFORNIA REGISTRATIONS Only the following recommendations referenced in this label ar e registered for use in California: seedling alfalfa, small grai ns (wheat, barley, oats, rye and triticale), flax, corn (post emergence ap plication only), sorghum (post emergence application only), onio ns, garlic; chemigation in seedling alfalfa, small grains, onions and garlic; 2,4-D and MCPA tank mixtures in small grains; 2,4-D and atraz ine tank mixtures in corn and sorghum; 2,4-DB and Pursuit tank mixtures in seedling alfalfa; grass for sod production, non-residential t urfgrass; and non-cropland and industrial sites. All applications must be made with a minimum spray volume of 10 GPA by ground or 5 GPA b y air equipment. SPECIFIC CROP DIRECTIONS CEREAL GRAIN CROPS Corn (Field and Pop), Sorghum (Grain and Forage), and Sudangrass Wheat, Barley, Oats, Rye and Triticale FORAGE, FIBER AND SPECIALTY CROPS Alfalfa (Seedling) Flax Garlic Mint (Established Peppermint and Spearmint) Onions GRASS CROPS Grass Grown for Sod Production Non-Residential Turfgrass NON-CROPLAND Non-cropland and Industrial Sites

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CEREAL GRAIN CROPS

CORN (FIELD AND POP), SORGHUM (GRAIN AND FORAGE), AND SUDANGRASS BUCTRIL 4EC DIRECTIONS

APPLICATION TIMING AND SPECIFIC COMMENTS PRODUCT RATE CROP WEEDS BUCTRIL® 4EC Preemergence 1/2-3/4 pint/A Apply to corn or sorghum before planting until just prior to crop emergence. See CORN AND SORGHUM APPLICATION RATE TABLE - BUCTRIL 4EC for list of weeds and corresponding stages of growth that 1/2 pint/A Apply to corn after emergence but prior to tassel emergence. are controlled by BUCTRIL 4EC at specified rates of application. For control of additional weeds not Apply to sorghum and sudangrass between the 3-leaf stage but prior to the preboot stage (growth stage 4). listed in the rate table see the WEED LIST. 3/4 pint/A Apply to corn between the 4-leaf stage and prior to tassel emergence.

Apply to sorghum and sudangrass between the 4-leaf stage but prior to preboot stage (growth stage 4).

1 Pint/A Apply to field corn only between the 4- leaf stage but prior to tassel emergence. WARNING: DO NOT APPLY THE 1 PINT/A RATE OF BUCTRIL 4EC ALONE OR IN TANK- MIXTURES TO SORGHUM. Use the 1 pint/A rate on corn to control susceptible weeds that are growing under less than optimum conditions and where BUCTRIL 4EC + atrazine tank mixtures cannot be used. Chemigation 1 pint/A only Apply to corn after emergence but prior to tassel emergence. Apply to sorghum and sudangrass after emergence but prior to preboot stage (growth stage 4). Apply through automated sprinkler irrigation systems with a mechanical transfer loading system only . See MIXING, LOADING AND HANDLING INSTRUCTIONS section for complete details. Apply to MOST SUSCEPTIBLE broadleaf weeds up to the 8-leaf stage or 4 inches in height or 2 inches in diameter, whichever comes first. Apply to SUSCEPTIBLE broadleaf weeds up to the 4-leaf stage, 2 inches in height or 1 inch in diameter, whichever comes first . Do not use chemigation for control of weeds that exceed 4 inches in height because control may be unacceptable.

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CORN AND SORGHUM APPLICATION RATE TABLE - BUCTRIL® 4EC

WEED SPECIES 1 1/2 Pint/A 3/4 to 1 Pint/A 4 When determining leaf stage, M ax. Max. Weed Max. Max. Weed count all leaves except Leaf Height Leaf Height cotyledonary leaves Stage (inches) Stage (inches) Black Nightshade (Solanum nigrum) 6 6 6 6 Buffalobur (Solanum rostratum) 4 2 6 4 Burcucumber (Sicyos angulatus) - - 4 4 Common Cocklebur (Xanthium strumarium) 6 8 8 10 Common Lambsquarters (Chenopodium album) - 6 - 8 Common Ragweed (Ambrosia artemisiifolia) 6 4 8 6 Eastern Black Nightshade (Solanum ptycanthum) 6 6 6 6 Giant Ragweed (Ambrosia trifida) 6 4 6 6 Hemp Sesbania (Sesbania exaltata) - - 4 4 Ivyleaf Morningglory (Ipomoea hederacea) 3 3 4 4 Jimsonweed (Datura stramonium) 4 4 6 6 Kochia (Kochia scoparia) - - - 2 Ladysthumb (Polygonum persicaria) 4 4 6 6 Pennsylvania Smartweed (Polygonum pensylvanicum) 4 4 6 6 Pitted Morningglory (Ipomoea lacunosa) 3 3 4 4 Redroot Pigweed3 (Amaranthus retroflexus) - - 4 2 Spiny Pigweed3 (Amaranthus spinosus) - - 4 2 Sunflower (Helianthus annus) 4 6 6 8 Tall Morningglory (Ipomoea purpurea) 3 3 4 4 Tall Waterhemp3 (Amaranthus tuberculatus) - - 4 2 Velvetleaf (Abutilon theophrasti) 4 3 6 5 Venice Mallow (Hibiscus trionum) - - 4 2 Wild Buckwheat (Polygonum convolvulus) 4 6 6 8 Wild Mustard (Sinapis arvensis) - - 4 4 WEEDS SUPPRESSED2 Canada Thistle (Cirsium arvense) Not Recommended 8 inch to bud stage 1/When determining leaf stage, count all leaves except cotyledonary leaves. 2/ BUCTRIL 4EC suppresses the growth by burning down of top growth. Regrowth may occur. 3/Control of pigweeds in the high plains areas of Texas and Oklahoma may not be satisfactory with BUCTRIL 4EC Herbicide. Repeat applications may be necessary to achieve satisfactory control. 4/ Do not apply BUCTRIL 4EC at the 1 pint/A rate to sorghum.

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BUCTRIL 4EC TANK MIXTURE DIRECTIONS

APPLICATION TIMING AND SPECIFIC COMMENTS PRODUCT RATE CROP WEEDS BUCTRIL® 4EC + atrazine Preemergence 3/8-3/4 pint/A + 1/2-1 1/5 lb ai/A Apply to corn or sorghum before planting until just prior to crop emergence. See CORN AND SORGHUM APPLICATION RATE TABLE - BUCTRIL® 4EC+ ATRAZINE TANK MIXTURES for list of weeds and corresponding stages of growth that 3/8-1/2 pint/A + 1/2-1 1/5 lb ai/A Apply to corn after emergence but before corn is 12 inches tall. Apply to sorghum between the 3-leaf stage but prior to the preboot stage (growth stage 4) or 12 inches in height, whichever comes first. are controlled by BUCTRIL ® 4EC+ Atrazine tank mixtures at specified rates of application . For control of additional weeds not listed in the rate table, see the WEED LIST. 3/4 pint/A + 1/2-1 1/5 lb ai/A Apply to corn between the 4-leaf stage and before corn is 12 inches tall. Apply to sorghum between the 4-leaf stage but prior to the preboot stage (growth stage 4) or 12 inches in height, whichever comes first.

ATRAZINE TANK MIX RESTRICTIONS Atrazine is a Restricted Use Herbicide due to ground water concerns; users must read and follow all precautionary statements and instructions on the atrazine label in order to minimize the potential for atrazine to reach ground water.

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CORN (FIELD AND POP) AND SORGHUM (GRAIN AND FORAGE) (continued)

CORN AND SORGHUM APPLICATION RATE TABLE - BUCTRIL® 4EC+ ATRAZINE TANK MIXTURES

WEED SPECIES1 BUCTRIL 4EC AND ATRAZINE RATE (TANK MIX) When determining leaf stage, count all leaves except cotyledonary leaves 3/8 Pint/A + 1/2 lb ai/A 3/8 Pint/A + 1 1/5 lb ai/A 1/2 Pint/A + 1/2 lb ai/A 1/2 Pint/A + 1 1/5 lb ai/A 3/4 Pint/A + 1/2 lb ai/A 3/4 Pint/A + 1 1/5 lb ai/A MAX LEAF STAGE MAX WEED HEIGHT MAX LEAF STAGE MAX WEED HEIGHT MAX LEAF STAGE MAX WEED HEIGHT MAX LEAF STAGE MAX WEED HEIGHT MAX LEAF STAGE MAX WEED HEIGHT MAX LEAF STAGE MAX WEED HEIGHT Black Nightshade (Solanum nigrum) 4 4 4 4 6 6 6 6 6 6 6 6 Buffalobur (Solanum rostratum) 4 4 4 4 6 4 6 4 6 4 6 4 Burcucumber (Sicyos angulatus) 4 4 4 4 4 4 6 6 6 6 6 6 Common Cocklebur (Xanthium strumarium) 6 8 8 10 8 10 10 12 10 12 10 12 Common Lambsquarters (Chenopodium album) - 6 - 10 - 10 - 12 - 12 - 12 Common Ragweed (Ambrosia artemisiifolia) 6 4 8 6 8 6 8 6 8 6 8 6 Eastern Black Nightshade (Solanum ptycanthum) 4 4 4 4 6 6 6 6 6 6 6 6 Entireleaf Morningglory (Ipomoea hederacea) - - 4 3 4 3 4 3 4 3 4 3 Giant Ragweed (Ambrosia trifida) 4 6 6 8 6 8 6 8 8 10 8 10 Hemp Sesbania (Sesbania exaltata) 4 4 4 4 4 4 4 4 4 4 4 4 Ivyleaf Morningglory (Ipomoea hederacea) 3 3 4 4 4 4 4 4 4 4 4 4 Jimsonweed (Datura stramonium) 4 4 4 4 6 6 6 6 6 6 6 6 Kochia (Kochia scoparia) - 2 - 2 - 2 - 2 - 4 - 4 Ladysthumb (Polygonum persicaria) 4 4 4 4 6 6 8 8 8 8 8 8 Marestail (Conyza canadensis) - - - 3 - 5 - 5 - 5 - 5 Palmleaf Morningglory (Ipomoea wrightii) - - 4 3 4 3 4 3 4 3 4 3 Pennsylvania Smartweed (Polygonum strumarium) 4 4 4 4 6 6 8 8 8 8 8 8 Pitted Morningglory (Ipomoea lacunosa) 3 3 4 4 4 4 4 4 4 4 4 4 Pokeweed (Phytolacca americana)

• • 4 4 6 6 6 6 6 6 6 6 Prickly Sida (Sida Spinosus) - - 6 2 4 1 6 2 4 1 6 2 Puncturevine (Tribulus terrestris) - - - - - - 6 4 6 4 6 4 Purple Morningglory (Ipomoea muricata) - - 2 3 2 3 2 3 2 3 2 3 Redroot Pigweed3 (Amaranthus retroflexus) 4 2 8 6 6 4 8 6 6 4 8 6 Smallflower Morningglory (Jacquemontia tamnifolia)
• • 4 3 4 3 4 3 4 3 4 3 Smooth Pigweed3 (Amaranthus hybridus) 4 2 6 4 4 2 6 4 6 4 6 4 Spiny Pigweed3 (Amaranthus spinosus) 4 2 8 6 6 4 8 6 6 4 8 6 Sunflower (Helianthus annus) 6 8 8 10 8 10 10 12 10 12 10 12 Tall Morningglory (Ipomoea purpurea) 3 3 4 4 4 4 4 4 4 4 4 4 Tall Waterhemp3 (Amaranthus tuberculatus) 4 2 8 6 6 4 8 6 6 4 8 6 Toothed Spurge (Euphorbia dentata) 2 2 2 2 4 4 4 4 4 4 4 4 Velvetleaf (Abutilon theophrasti) 4 3 4 3 6 5 6 5 8 6 8 6 Venice Mallow (Hibiscus trionum) 4 2 4 2 4 2 4 2 4 2 4 2 Wild Buckwheat (Polygonum convolvulus) 6 8 8 10 8 10 10 12 10 12 10 12 Wild Mustard (Sinapis arvensis) 4 4 4 4 4 4 4 4 4 4 4 4 WEEDS SUPPRESSED2 Canada thistle (Cirsium arvense) Not Recommended Not Recommended

8"-bud

8"-bud

8"-bud

8"-bud 1 When determining leaf stage, count all leaves except cotyledonary leaves. 2 Selected rates of BUCTRIL® 4EC+ atrazine tank mixtures suppress the growth by burning down of top growth. Regrowth may occur. 3 If pigweeds (Amaranthus sp.) present in the field to be treated have been identified as triazine resistant biotypes, use BUCTRIL 4EC at 3/4 pint/A in a tank mixture with atrazine at 1/2 or 1 1/5 lb ai/A. Applications should be made when pigweeds do not exceed the 4- leaf stage and 2 inches in height. Control of pigweeds in the hi gh plains areas of Texas and Oklahoma may not be satisfactory w ith BUCTRIL® 4EC+ atrazine tank mixtures. Repeat applications may be necess ary to achieve satisfactory control, but do not exceed maximum application rates.

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ATRAZINE CONVERSION TABLE1/ ATRAZINE RATE ATRAZINE ATRAZINE POUNDS OF ACTIVE FORMULATION FORMULATION INGREDIENT PER ACRE RATE PER ACRE Atrazine 4L 1/2 1 Pint 1 1/5 2 2/5 Pints Atrazine 80WP 1/2 5/8 Pound 1 1/5 1 1/2 Pounds Aatrex® Nine-O 1/2 3/5 Pound 1 1/5 1 1/3 Pounds 1/Follow all precautions and limitations on the labels of products used in tank mixture with BUCTRIL® 4EC. SPECIAL USE DIRECTIONS FOR OTHER WEED PROBLEMS IN CORN AND SORGHUM Large Common Cocklebur, Common Lambsquarters and Sunflower For control of common cocklebur and common lambsquarters up to 14 inches in height and sunflower up to 18 inches in height, use a postemergence application of BUCTRIL 4EC at 1/2 pint/A. Make a second application of BUCTRIL 4EC at the same rate 7 to 10 days later. Large Velvetleaf For control of velvetleaf up to 14 inches in height, use postemergence application of BUCTRIL 4EC at 3/4 - 1 pint/A or BUCTRIL 4EC + atrazine tank mixture at 1/2 pint/A + 1 1/5 lb ai/A. Make a seco nd application of BUCTRIL 4EC at 1/2 pint/A 7 to 10 days later, but do not exceed a total of 1 pint/A of BUCTRIL 4EC per season on corn (field and pop). Canada Thistle Management For effective management of Canada thistle, the following BUCTRIL 4EC treatments should be applied to thistle from 8 inch to th e bud stage for in-season burndown of top growth: BUCTRIL 4EC at 3/4-1 pint/A BUCTRIL 4EC at 1/2 - 3/4 pint/A + atrazine at 1/2 - 1 1/5 lbs ai/A BUCTRIL 4EC at 1/2 - 3/4 pint/A + Banvel ® or Clarity® at 1/4 - 1/2 pint/A BUCTRIL 4EC at 1/2 - 3/4 pint/A + at razine at 1/2 -1 1/5 lbs ai/A + Banvel® or Clarity® at 1/8 - 1/4 pint/A BUCTRIL 4EC at 1/2 - 3/4 pint/A + 2, 4-D at 1/8 - 1/4 lb ai/A BUCTRIL 4EC at 1/2 - 3/4 pint/A + atrazine at 1/2 - 1 1/5 lbs ai/A + 2, 4-D at 1/8 - 1/4 lb ai/A If possible, follow with cultivation 14-21 days after treatment. In the fall apply 2,4-D (such as WEEDONE® 638), Banvel ®, Clarity®, or Roundup® at recommended rates to Canada thistle 4-8 inches tall prior to killing frost. Follow with a similar control program in next year’s rotational crop.

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ADDITIONAL BUCTRIL 4EC TANK MIXTURE RECOMMENDATIONS

APPLICATION TIMING AND SPECIFIC COMMENTS PRODUCT RATE CROP WEEDS BUCTRIL® 4EC + Banvel® 1 1/2 pint/A + 1/8-1/2 pint/A Apply to field corn after emergence but before corn is 36 inches tall or 15 days before tassel emergence, whichever comes first.

Apply to sorghum between the 3-leaf stage but prior to the preboot stage (growth stage 4) or 15 inches in height, whichever comes first . Do not apply in the boot stage. Use drop nozzles if crop is taller than 8 inches. All weeds controlled by BUCTRIL 4EC at specified rates of application plus improved control of pigweed . For Canada thistle burndown and field bindweed suppression up to the mid- bloom stage, use 1/4

• 1/2 pint/A of Banvel® with BUCTRIL® 4EC. 3/4 pint/A

1/8-1/2 pint/A Apply to field corn between the 4-leaf stage but before corn is 36 inches tall or 15 days before tassel emergence, whichever comes first.

Apply to sorghum between the 4-leaf stage but prior to the preboot stage (growth stage 4) or 15 inches in height, whichever comes first . Do not apply in the boot stage . Use drop nozzles if crop is taller than 8 inches.

BUCTRIL® 4EC + atrazine + Banvel® 1

1/2 pint/A + 1/2-1 1/5 lb ai/A + 1/8-1/4 pint/A

Apply to field corn after emergence but before corn is 12 inches tall. Apply to sorghum between the 3-leaf stage but prior to the preboot stage (growth stage 4) or 12 inches in height, whichever comes first . Use drop nozzles if crop is taller than 8 inches . All weeds controlled by BUCTRIL ® 4EC+ atrazine tank mixtures at specified rates of application plus improved control of pigweed . For field bindweed suppression, use 1/4 pint/A of Banvel/Clarity with BUCTRIL® 4EC. 3/4 pint/A + 1/2-1 1/5 lb ai/A + 1/8-1/4 pint/A Apply to field corn between the 4-leaf stage and before corn is 12 inches tall. Apply to sorghum between the 4-leaf stage but prior to the preboot stage (growth stage 4) or 12 inches in height, whichever comes first . Do not apply in the boot stage . Use drop nozzles if crop is taller than 8 inches.

1Clarity® may be used at the same rates as Banvel ® in a tank mixture on corn. These mixtures must be applied before corn exceeds 8 inches in height. Do not use Clarity® in a tank mixture with BUCTRIL 4EC or BUCTRIL 4EC + atrazine on sorghum.

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CORN (FIELD AND POP) AND SORGHUM (GRAIN AND FORAGE) ADDITIONAL BUCTRIL 4EC TANK MIXTURE DIRECTIONS (continued)

APPLICATION TIMING AND SPECIFIC COMMENTS PRODUCT RATE CROP WEEDS BUCTRIL® 4EC + 2,4-D (such as WEEDONE® and WEEDAR® brand Herbicide) 1/2 pint/A + 1/16-1/4 lb ai/A

Apply to field corn after emergence but prior to tassel emergence . Use drop nozzles if crop is taller than 8 inches. Apply to sorghum between the 3-leaf stage but prior to the preboot stage (growth stage 4) or 15 inches in height, whichever comes first. Use drop nozzles if crop is taller than 8 inches. All weeds controlled by BUCTRIL 4EC at specified rates plus improved pigweed and kochia control . For Canada thistle burndown and field bindweed suppression up to the mid -bloom stage, use 1/8 - 1/4 lb ai/A of 2, 4-D with BUCTRIL® 4EC. 3/4 pint/A + 1/16-1/4 lb ai/A Apply to field corn between the 4-leaf stage but prior to tassel emergence . Use drop nozzles if crop is taller than 8 inches.

Apply to sorghum between the 4-leaf stage but prior to the preboot stage (growth stage 4) or 15 inches in height, whichever comes first. Use drop nozzles if crop is taller than 8 inches.

BUCTRIL® 4EC + atrazine + 2,4-D (such as WEEDONE® and WEEDAR® brand Herbicide) 1/2 pint/A + 1/2-1 1/5 lb ai/A + 1/16 -1/4 lb ai/A Apply to field corn after emergence but before the corn is 12 inches tall . Use drop nozzles if crop is taller than 8 inches. Apply to sorghum between the 3-leaf stage but prior to the preboot stage (growth stage 4) or 12 inches in height, whichever comes first . Use drop nozzles if crop is taller than 8 inches. All weeds controlled by BUCTRIL ® 4EC+ atrazine tank mixtures at specified rates of application plus improved devils claw control. For C anada thistle burndown and field bindweed suppression, use 1/8 - 1/4 lb ai/A of 2, 4-D with BUCTRIL® 4EC. 3/4 pint/A + 1/2-1 1/5 lb ai/A + 1/16-1/4 lb ai/A Apply to field corn between the 4-leaf stage but before the corn is 12 inches tall . Use drop nozzles if crop is taller than 8 inches. Apply to sorghum between the 4-leaf stage but prior to the preboot stage (growth stage 4) or 12 inches in height, whichever comes first. Use drop nozzles if crop is taller than 8 inches.

BUCTRIL® 4EC + Accent® + Non-ionic surfactant 1/2 pint/A + 2/3 oz/A + 1 qt/100 gal of water (0.25% v/v) Apply to field corn preemergence or postemergence up to 36 inches tall. Use drop nozzles when corn is 24 to 36 inches tall . Do not apply this tankmix to sorghum.

All broadleaf weeds controlled by BUCTRIL 4EC at 1/2 or 3/4 pint/A plus grasses and broadleaves controlled by Accent ®. For optimum weed control, treat when broadleaves and grasses are in the recommended growth stage or size . Follow the weed size guideline on the BUCTRIL 4EC or Accent ® labels that are least restrictive. 3/4 pint/A + 2/3 oz/A + 1 qt/100 gal of water (0.25% v/v) Apply to field corn between the 4-leaf stage up to 36 inches in height . Use drop nozzles when corn is 24 to 36 inches tall . Do not apply this tankmix to sorghum.

19

CORN (FIELD AND POP) AND SORGHUM (GRAIN AND FORAGE) ADDITIONAL BUCTRIL 4EC TANK MIXTURE DIRECTIONS (continued)

APPLICATION TIMING AND SPECIFIC COMMENTS PRODUCT RATE CROP WEEDS BUCTRIL® 4EC + atrazine + Accent® + Non-ionic surfactant 1/2 pint/A + 1/2 - 1 1/5 lb ai/A + 2/3 oz/A + 1 qt/100 gal of water (0.25% v/v) Apply to field corn preemergence or postemergence but before the corn is 12 inches tall . Do not apply this tankmix to sorghum.

All broadleaf weeds controlled by BUCTRIL® 4EC+ atrazine plus grasses and broadleaves controlled by Accent ®. For optimum weed control, treat when broadleaves and grasses are in the recommended growth stage or size . Follow the weed size guideline on the BUCTRIL 4EC or Accent® labels that are least restrictive. 3/4 pint/A + 1/2 - 1 1/5 lb ai/A + 2/3 oz/A + 1 qt/100 gal of water (0.25% v/v) Apply to field corn between the 4-leaf stage of crop growth but before the corn is 12 inches tall. Do not apply this tankmix to sorghum.

BUCTRIL 4EC + Beacon ® + Non-ionic surfactant

1/2 pint/A + 0.38-0.76 oz/A (1-2 packets/4 acres) + 1 qt/100 gal of water (0.25% v/v) Apply to field corn from 4 to 20 inches in height. Do not apply this tankmix to sorghum.

All broadleaf weeds controlled by BUCTRIL 4EC at 1/2 pint/A plus grasses and broadleaves controlled by Beacon ®. For optimum weed control treat when broadleaves and grasses are in the recommended growth stage or size . Follow the weed size guidelines on the BUCTRIL 4EC or Beacon ® labels that are least restrictive. BUCTRIL 4EC + Exceed ® + Non-ionic surfactant

3/8-1/2 pint/A + 0.5 - 1.0 oz/A + 1 qt/100 gal of water (0.25% v/v) Apply to field corn from 4-48 inches in height and before tasseling, whichever comes first . Do not apply this tankmix to sorghum. Addition of Exceed ® at 0.5 ounce/A to BUCTRIL 4EC at 3/8- 1/2 pint/A will control all weeds on the BUCTRIL 4EC label at 1/2 pint/A plus improved control of velvetleaf and pigweed species.

Addition of Exceed® at 1.0 ounce/A to BUCTRIL 4EC at 3/8- 1/2 pint/A will control all weeds on both the BUCTRIL 4EC and Exceed ® labels. Follow the weed size guidelines on the BUCTRIL 4EC and Exceed ® labels that are least restrictive. BUCTRIL 4EC + Permit ® + Non-ionic surfactant

3/8-1/2 pint/A + 1/3-2/3 oz/A + 1 qt/100 gal of water (0.25% v/v) Apply to field corn from the 3-leaf stage to layby. Do not apply this tankmix to sorghum. Addition of Permit ® at 1/3 ounce/A to BUCTRIL 4EC at 3/8- 1/2 pint/A will control all weeds on the BUCTRIL 4EC label at 1/2 pint/A plus improved control of velvetleaf and pigweed species.

Addition of Permit ® at 2/3 ounce/A to BUCTRIL 4EC at 3/8- 1/2 pint/A will control all weeds on both the BUCTRIL 4EC and Permit ® labels. Follow the weed size guidelines on the BUCTRIL 4EC and Permit ® labels that are least restrictive.

20

CORN (FIELD AND POP) AND SORGHUM (GRAIN AND FORAGE) ADDITIONAL BUCTRIL 4EC TANK MIXTURE DIRECTIONS (continued)

APPLICATION TIMING AND SPECIFIC COMMENTS PRODUCT RATE CROP WEEDS BUCTRIL® 4EC + Stinger® 1/2 pint/A + 1/3-2/3 pint/A

Apply to field corn after emergence up to 24 inches in height . Do not apply this tankmix to sorghum.

All weeds controlled by BUCTRIL 4EC at specified rates of application plus improved Canada thistle burndown . For optimum performance, apply to Canada thistle at least 4 inches in diameter or height but before bud stage. 3/4 pint/A + 1/3 - 2/3 pint/A Apply to field corn from 4-leaf stage up to 24 inches in height. Do not apply this tankmix to sorghum.

BUCTRIL 4EC + Atrazine + Stinger® 1/2 pint/A + 1/2-1 1/5 lb ai/A + 1/3-2/3 pint/A Apply to field corn after emergence but before corn is 12 inches tall . Do not apply this tankmix to sorghum.

All weeds controlled by BUCTRIL 4EC + atrazine tank mixtures at specified rates of application plus improved Canada thistle burndown. For optimum performance, apply to Canada thistle at least 4 inches in diameter or height but before bud stage. 3/4 pint/A + 1/2 - 1 1/5 lb ai/A + 1/3 - 2/3 pint/A Apply to field corn from 4-leaf stage but before corn is 12 inches tall . Do not apply this tankmix to sorghum.

BUCTRIL 4EC + Pursuit® + Non-ionic surfactant + UAN Fertilizer solution 3/8-1/2 pint/A + 4 oz/A + 1 qt/100 gallons + 1-2 quarts/A Apply this tankmix only on field corn hybrids possessing resistance to Pursuit ® herbicide. Contact your seed supplier for further information. Apply this tank mix to corn between the 3 leaf to 8-leaf stage of growth. Do not use crop oil concentrates when applying BUCTRIL 4EC + Pursuit ® tank mixtures. This tank mix will control all broadleaf weeds listed as controlled by BUCTRIL 4EC at 1/2 pint/A plus giant foxtail, redroot pigweed, and other grass and broadleaf weeds listed on the Pursuit ® label.

21

CORN (FIELD AND POP) AND SORGHUM (GRAIN AND FORAGE) ADDITIONAL BUCTRIL 4EC TANK MIXTURE DIRECTIONS (continued)

APPLICATION TIMING AND SPECIFIC COMMENTS PRODUCT RATE CROP WEEDS BUCTRIL 4EC + Roundup® Preemergence 1/2-3/4 pint/A + 1/2-3 pints/A Apply to corn or sorghum before planting time up until just prior to crop emergence. All weeds controlled by BUCTRIL 4EC at specified rates of application plus control of certain grass and perennial weeds. Refer to Roundup® label for rate to use depending on weeds present at time of application.

RESTRICTIONS AND PRECAUTIONS: Corn (Field and Pop) and Sorghum (Grain and Forage), and Sudangrass

• BUCTRIL 4EC does not control grasses. Ther efore, it is recommended that a suitable grass control program be used to provide any required grass control. • Addition of a spray additive or mixture with liquid fertilizers may cause excessive crop leaf burn. • Seed corn producers should consult the respective seed corn company regarding tolerance of certain seed production inbred line s to BUCTRIL® 4EC. • Do not apply BUCTRIL 4EC to postemergence to seed corn inbreds or popcorn prior to the 3 leaf stage of crop growth as excessive crop leaf burn may occur. • Do not plant rotational crops within 30 day s following BUCTRIL 4EC Herbicide application. • Do not cut crop for feed, fodder or graze within 45 days of application. • The total cumulative rate must not exceed 1 pint/A per season (0.5 lbs. a.i./A/year). • Postemergence application prior to the 3-leaf growth stage of corn or sorghum may result in increased crop leaf burn. • Tank mixtures with Accent ®/nonionic surfactant or Beacon®/nonionic surfactant may result in increased initial crop leaf burn. Use of crop oil concentrate, nitrogen fertilizer solution or other adjuvants in BUCTRIL 4EC + Accent® or BUCTRIL 4EC + Beacon® tank mixtures may result in a further increase in crop leaf burn. • Special care must be taken when using BUCTRIL 4EC and Banvel®, Clarity®, or 2, 4-D tank mixtures to avoid off target drift to sensitive crops. • Tank mixtures with 2, 4-D, Banvel®, or Clarity ® can cause stalk brittleness to field corn. Tank mixtures with 2, 4-D and Banvel®, can cause stalk brittleness to sorghum. Winds or cultivation may cause breakage while crop is brittle. • Follow all restrictions and precautions on the label of all products used in tank mixture with BUCTRIL® 4EC. • Do not apply BUCTRIL 4EC at any rate to sorghum after the pr eboot stage of growth (growth stage 4) as severe crop injury, including loss of crop yield may result. • Do not apply the 1 pint/A rate of BUCTRIL 4EC to sorghum. • Do not apply the BUCTRIL 4EC + Pursuit ® tankmix except to field corn hybrids known to possess resistance to Pursuit®, or severe crop injury may result.

22

WHEAT, BARLEY, OATS, RYE AND TRITICALE

BUCTRIL 4EC DIRECTIONS

APPLICATION TIMING AND SPECIFIC COMMENTS PRODUCT RATE CROP WEEDS BUCTRIL 4EC 1/2-1 pint/A Spring seeded wheat, barley, oats, rye and triticale. Use in all states except Idaho, Oregon, Washington, Colorado, Wyoming, and Montana. Apply from emergence up and prior to the boot stage. Apply 1/2 pint/A to MOST SUSCEPTIBLE and 3/4- 1 pint/A to SUSCEPTIBLE weeds that do not exceed the 4 leaf stage or 2 inches in height, whichever comes first . If weed forms rosette, apply before weeds exceed 1 inch in diameter. Use BUCTRIL 4EC at 3/4- 1 pint/A for control of kochia that is 2 -4 inches in height and pigweed that does not exceed the 4 leaf stage or 2 inches in height, whichever comes first.

3/4-1 pint/A Fall seeded wheat, barley, oats, rye and triticale throughout the United States . Apply from emergence to the boot stage. Spring seeded wheat, barley oats, rye and triticale in Idaho, Oregon, Washington, Colorado, Wyoming, and Montana . Apply from emergence up and prior to the boot stage. Apply to MOST SUSCEPTIBLE weeds (see WEED LIST) up to the 8- leaf stage or 4 inches in height, whichever comes first . If weed forms rosette apply before weeds exceed 2 inches in diameter. Apply to SUSCEPTIBLE broadleaf weeds up to the 4-leaf stage, 2 inches in height or 1 inch in diameter, whichever comes first. Chemigation 1 pint/A only Apply to wheat, barley, oats, rye and triticale from emergence to the boot stage . Apply through automated sprinkler irrigation systems with a mechanical transfer loading system only . See MIXING, LOADING AND HANDLING INSTRUCTIONS section for complete details. Apply to MOST SUSCEPTIBLE broadleaf weeds up to the 8-leaf stage or 4 inches in height or 2 inches in diameter, whichever comes first. Apply to SUSCEPTIBLE broadleaf weeds up to the 4-leaf stage, 2 inches in height or 1 inch in diameter, whichever comes first . Do not use chemigation for control of weeds that exceed 4 inches in height because control may be unacceptable.

Small Grains underseeded with Alfalfa 1/2-3/4 pint/A Apply to wheat, barley, oats, rye or triticale underseeded with alfalfa after small grains emergence up to the boot stage and when underseeded alfalfa has a minimum of 4 trifoliate leaves. Follow all precautions and restrictions listed under the small grains and seedling alfalfa sections.

Apply 1/2 pint/A to MOST SUSCEPTIBLE and 3/4 pint/A to SUSCEPTIBLE broadleaf weeds that do not exceed the 4 leaf stage, 2 inches in height or 1 inch in diameter, whichever comes first.

23

WHEAT, BARLEY, OATS, RYE AND TRITICALE (continued)

BUCTRIL 4EC TANK MIXTURE DIRECTIONS

APPLICATION TIMING AND SPECIFIC COMMENTS PRODUCT RATE CROP WEEDS BUCTRIL 4EC + 2,4-D (such as WEEDONE® and WEEDAR® brand Herbicide) 1/2-1 pint/A + 1/4-1/2 lb ai/A Apply to wheat, barley, oats and rye from the fully tillered but before jointing stage.

This tankmix improves control of mustards and pigweed . Ap ply to weeds up to the 4-leaf stage, 2 inches in height or 1 inch in diameter, whichever comes first. 3/8-1/2 pint/A + 1/4-1/2 lb ai/A Apply to wheat and barley in Minnesota, North and South Dakota from the fully tillered but before jointing stage.

This tankmix improves control of wild buckwheat, redroot pigweed and wild mustard . Apply to weeds up to the 4- leaf stage, 2 inches in height or 1 inch in diameter, whichever comes first. BUCTRIL 4EC + MCPA (such as RHONOX® or RHOMENE®) 1/2-1 pint/A + 1/4-1/2 lb ai/A

Apply to wheat, barley, oats and rye from the 4-leaf stage but before jointing. This tankmix improves control of mustards, pigweed and kochia . Apply to weeds up to the 4-leaf stage, 2 inches in height or 1 inch in diameter, whichever comes first.

BUCTRIL 4EC + Banvel® 1/2-3/4 pint/A + 1/8-1/4 pint/A

FOR USE ON WHEAT ONLY . DO NOT TREAT BARLEY, OATS, RYE AND TRITICALE. Fall seeded wheat apply prior to the jointing stage . Spring seeded wheat apply up to the 5-leaf stage.

This tankmix improves control of broadleaves such as prostrate knotweed . Apply to weeds up to the 4- leaf stage, 2 inches in height or 1 inch in diameter, whichever comes first. BUCTRIL 4EC + Glean® + Non-ionic surfactant 3/8-3/4 pint/A + 1/6-1/3 oz/A + 1 qt/100 gal of water Apply to wheat and barley from the 2- leaf stage but before boot stage. Refer to Glean ® label for crop rotation and other restrictions.

This tankmix improves control of broadleaves such as henbit, tansy mustard and pigweed . Apply to weeds up to the 4-leaf stage, 4 inches in height or 2 inches in diameter, whichever comes first.

BUCTRIL 4EC + Ally® + Non-ionic surfactant 3/8-3/4 pint/A + 1/10 oz/A + 1 qt/100 gal of water Apply to wheat and barley from the 2- leaf stage but before the boot stage. Refer to Ally ® label for crop rotation and other restrictions. This tankmix improves control of broadleaves such as tansy mustard and pigweed . Apply to weeds up to the 4-leaf stage, 4 inches in height or 2 inches in diameter, whichever comes first. BUCTRIL 4EC + Finesse® + Non-ionic surfactant 3/8-3/4 pint/A + 1/6-1/3 oz/A + 1 qt/100 gal of water Apply to wheat and barley from the 2- leaf stage but before the boot stage. Refer to Finesse ® label for crop rotation and other restrictions.

This tankmix improves control of broadleaves such as tansy mustard, henbit, chickweed and pigweed . Apply to weeds up to the 4-leaf stage, 4 inches in height or 2 inches in diameter, whichever comes first. BUCTRIL 4EC + Amber® + Non-ionic surfactant 3/8-3/4 pint/A + 0.28-0.56 oz/A + 0.25-0.5% v/v Apply to wheat and barley after the 3- leaf stage but before the flagleaf is visible. Refer to the Amber ® label for crop rotation and other restrictions. This tankmix improves control of broadleaves such as tansy mustard, henbit, and pigweed . Apply to weeds up to the 4-leaf stage, 4 inches in height or 2 inches in diameter, whichever comes first.

24

WHEAT, BARLEY, OATS, RYE AND TRITICALE BUCTRIL 4EC TANK MIXTURE DIRECTIONS (continued)

APPLICATION TIMING AND SPECIFIC COMMENTS PRODUCT RATE CROP WEEDS BUCTRIL 4EC + Express® + Non-ionic surfactant 1/2-3/4 pint/A + 1/6-1/3 oz/A + 1 qt/100 gal of water Winter wheat. Apply after crop is in the 2-leaf stage but before the flag leaf is visible . Refer to Express ® label for crop rotation and other restrictions. This tankmix improves control of broadleaf weeds such as redroot pigweed, tansy mustard and suppression of Canada thistle . Apply to annual weeds up to the 4-leaf stage, 4 inches tall or across, whichever comes first, and to Canada thistle 4 to 8 inches tall with 2 to 6 inches of new growth. 3/8-3/4 pint/A + 1/6-1/3 oz/A + 1 qt/100 gal of water Spring wheat and barley. Apply after crop is in the 2-leaf stage but before the flag leaf is visible . Refer to Express® label for crop rotation and other restrictions.

BUCTRIL 4EC + Harmony® Extra + Non-ionic surfactant 3/8-3/4 pint/A + 3/10-1/2 oz/A + 1 qt/100 gal of water Winter wheat. Apply after the 2-leaf stage but before the 3rd node is detectable . Refer to the Harmony ® Extra label for crop rotation and other restrictions.

Spring wheat and barley . Apply after the 2-leaf stage but before the 1st node is detectable . Refer to the Harmony® Extra label for crop rotation and other restrictions. This tankmix improves control of broadleaf weeds such as henbit, chickweed and redroot pigweed. Apply to weeds up to the 4-leaf stage, 4 inches in height or across, whichever comes first.

BUCTRIL 4EC + Curtail® or Curtail® M4

1/2-3/4 pint/A + 2 pints/A

Apply to wheat and barley after the crop begins to tiller up to the 1st node detectable. This tankmix improves control of kochia, wild buckwheat and Canada thistle. Apply to annual broadleaf weeds up to the 8-leaf stage up to 4 inches in height or 2 inches in diameter and Canada thistle in the rosette to prebud stage. BUCTRIL 4EC + metribuzin (Sencor® or Lexone®)

1/2-5/8 pint/A + 1/8-1/4 lb ai/A

Winter wheat in Idaho, Montana, Oregon and Washington . Apply in spring after growth has started and secondary roots with a minimum of 3 to 4 tillers have been established but before boot stage . Avoid application when crop has experienced winterkill, frost damage, disease or drought . This tankmix improves control of broadleaves such as chickweed, filaree, henbit and dogfennel . Apply to weeds that do not exceed 2 inches tall or rosettes of 2 inches in diameter. The higher use rates of both products should be used only in emergency weed situations and if some minor crop injury is acceptable . A recognized authority should be consulted concerning the use of this mixture in your area. BUCTRIL 4EC + diuron

1/2 pint/A + 4/10 lb ai/A

Winter wheat and winter barley in Idaho, Oregon and Washington . Use only in areas where annual rainfall exceeds 16 inches . One fall application after emergence but before soil freezes or in spring as soon as soil thaws. This tankmix improves control of broadleaves such as henbit and gromwell . Apply to weeds before they are 2 inches tall or 2 inches in diameter.

BUCTRIL 4EC + Tiller®

1/2 pint/A + 1 pint/A Spring wheat. Apply when crop begins to tiller (3 – 4 leaf stage) up to the 6- leaf stage. Refer to the Tiller label for complete use directions and restrictions. In addition to broadleaf weeds controlled by BUCTRIL 4EC this tankmix will control green foxtail from the 2-leaf to 2-tiller stage of growth.

25

WHEAT, BARLEY, OATS, RYE AND TRITICALE BUCTRIL 4EC TANK MIXTURE DIRECTIONS (continued)

APPLICATION TIMING AND SPECIFIC COMMENTS PRODUCT RATE CROP WEEDS BUCTRIL 4EC + Hoelon®

1/2-1 pint/A + 2 2/3 pints/A

Spring Barley . After emergence but before jointing . Avoid using this tank mixture on barley exposed to cold (lower than 40 degrees F) and/or prolonged wet weather conditions as crop injury may result.

This tankmix will provide wild oat, green foxtail and annual ryegrass control in addition to broadleaves. Apply to grasses 1 -3 leaf stage and broadleaves no larger than 4 leaf stage or rosettes of 1.5 inches in diameter.

1/2-1 pint/A + 2 2/3-3 1/3 pints/A Winter wheat and spring wheat . After emergence but before jointing.

BUCTRIL 4EC + Hoelon® + Crop Oil Concentrate 1/2-1 pint/A + 2-2 2/3 pints/A + 1-2 pints/A Winter wheat and spring wheat . After emergence but before jointing . Use a minimum of 10 gallons of spray volume per acre. DO NOT USE ON BARLEY.

BUCTRIL 4EC + Avenge® 1/2-1 pint/A + 2 1/2-4 pints/A This tankmix will provide wild oat control in addition to broadleaves. Apply to wild oats in the 3 -5 leaf stage and broadleaves that do not exceed the 4 leaf stage or rosettes of 1.5 Spring Wheat . Five to 6 leaf stage. Refer to Avenge® label for varietal and other restrictions. inches in diameter. Avenge use rates per acre are 2.5 pints (1 -10 oats per sq ft), 3 pints (11-25 oats per sq ft) or 4 pints (more than 25 oats per Barley. Two to 7 leaf stage. sq ft).

RESTRICTIONS AND PRECAUTIONS: Wheat, Barley, Oats, Rye and Triticale • Do not graze treated fields within 45 days following treatment. • Do not apply when crops are under moisture stress. • Do not apply when crop canopy covers the weeds as poor weed control will result. • Do not apply when underseeded alfalfa is under moisture, temperat ure, insect or disease stress or has been stressed by other pesticide carryover or application. • Do not add a surfactant or crop oil when applying to underseeded alfalfa or increased injury will occur. • Do not cut for feed or graze spring treated underseeded alfalfa within 30 days following treatment. • Do not cut for feed or graze fall or winter treated underseede d alfalfa until spring, at least 60 days following treatment. • Reduced weed control may occur when weeds are stressed from lack of moisture or cold temperatures. • Refer to labels of products used in tank mixture for additional restrictions and precautions. • Do not plant rotational crops within 30 day s following BUCTRIL 4EC Herbicide application. • The total cumulative rate must not exceed 1 pint/A per season (0.5 lbs. a.i./A/year).

26

FORAGE, FIBER AND SPECIALTY CROPS

ALFALFA (SEEDLING)

BUCTRIL 4EC DIRECTIONS

APPLICATION TIMING AND SPECIFIC COMMENTS PRODUCT RATE CROP WEEDS BUCTRIL 4EC 1/2 – 3/4 pint/A In the states of California, Washington, Oregon, Idaho, Montana, Wyoming, Colorado, Utah, Nevada, Arizona, New Mexico, and the western halves of North Dakota, South Dakota, Nebraska and Kansas:

Apply in the fall or spring to seedling alfalfa when the majority of the field has a minimum of 2 trifoliates. Unacceptable crop injury may occur to alfalfa seedlings less than the 2 trifoliate stage . BUCTRIL 4EC applications made when temperatures are expected to exceed 80oF at and 3 days following application can result in unacceptable crop injury. In the remaining states, apply in the fall or spring to seedling alfalfa when the majority of the field has a minimum of 4 trifoliate leaves . When alfalfa stand is uneven and conditions favor leafburn, unacceptable crop injury may occur to alfalfa in the 2 trifoliate or smaller stage of growth. If you are unsure of growth stage conditions, contact your local extension service. BUCTRIL 4EC applications made when temperatures are expected to exceed 70 oF at and 3 days following application can result in unacceptable crop injury. Follow all other use directions listed on the BUCTRIL 4EC label. Apply 1/2 pint/A to MOST SUSCEPTIBLE broadleaf weeds and 1 3/4 pint/A to SUSCEPTIBLE broadleaf weeds (See WEED LIST) when weeds do not exceed 4 leaf stage, 2 inches in height or 1 inch in diameter, whichever comes first. BUCTRIL 4EC will not adequately control over -wintered pennycress, henbit and mustards. BUCTRIL 4EC Chemigation Only 1 pint/A Apply to seedling alfalfa with a minimum of 2 trifoliate leaves . Apply through automated sprinkler irrigation systems with a mechanical transfer loading system only . See MIXING LOADING AND HANDLING INSTRUCTIONS Section for complete details . BUCTRIL 4EC applications made when temperatures are expected to exceed 85 oF at and 3 days following application can result in unacceptable crop injury. Apply to MOST SUSCEPTIBLE broadleaf weeds up to the 8-leaf stage, 4 inches in height or 2 inches in diameter, whichever comes first. Apply to SUSCEPTIBLE broadleaf weeds up to the 4-leaf stage, 2 inches in height or 1 inch in diameter, whichever comes first.

27

Forage, Fiber and Specialty Crops (Alfalfa (Seedling)) (continued)

BUCTRIL 4EC TANK MIXTURE DIRECTIONS

APPLICATION TIMING AND SPECIFIC COMMENTS PRODUCT RATE CROP WEEDS BUCTRIL® 4EC + BUTYRAC® 200 (2,4-DB) 1/2 pint/A + 1 quart/A Apply in the fall or spring to seedling alfalfa when the majority of the field has a minimum of 4 trifoliate leaves. When alfalfa stand is uneven and conditions favor leafburn, unacceptable crop injury may occur to alfalfa in the 2 trifoliate or smaller stage of growth . If you are unsure of growth stage conditions, contact your local exten sion service. In the states of California, Washington, Oregon, Idaho, Montana, Wyoming, Colorado, Utah, Nevada, Arizona, New Mexico, and the western halves of North Dakota, South Dakota, Nebraska and Kansas, BUCTRIL 4EC applications made when temperatures are expected to exceed 80 o F at and 3 days following application can result in unacceptable crop injury . In the remaining states BUCTRIL 4EC applications made when temperatures are expected to exceed 70 oF at and 3 days following application can result in unacceptable crop injury . Rainfall or overhead irrigation within 7 -10 days following a BUTYRAC ® 200 application can cause unacceptable crop injury. This tankmix improves control of pigweed species, kochia, and tansy mustard . Apply when weeds do not exceed t he 4-leaf stage, 2 inches in height or 1 inch in diameter, whichever comes first . BUCTRIL 4EC

• BUTYRAC 200 tank mixtures will not adequately control over -wintered pennycress, henbit and mustards. BUCTRIL® 4EC

Pursuit® + Non-ionic surfactant

3/8-1/2 pint/A + 3-6 oz/A + 1 qt/100 gallons

In the states of California, Washington, Oregon, Idaho, Montana, Wyoming, Colorado, Utah, Nevada, Arizona, New Mexico, and the western halves of North Dakota, South Dakota, Nebraska and Kansas:

Apply in the fall or spring to seedling alfalfa when the majority of the field has a minimum of 2 trifoliate leaves. When alfalfa stand is uneven and conditions favor leafburn, unacceptable crop injury may occur to alfalfa treated prior to the 2nd trifoliate stage of grow th. If you are unsure of growth stage conditions, contact your local extension service. BUCTRIL 4EC + Pursuit ® applications made when temperatures are expected to exceed 80 oF at and 3 days following application can result in unacceptable crop injury.

This tank mix will control MOST SUSCEPTIBLE broadleaf weeds (See WEED LIST) when weeds do not exceed the 4-leaf stage, 2 inches in height or 1 inch in diameter, whichever comes first; and other grass and broadleaf weeds listed on the Pursuit ® label. Weeds shou ld be 1-3 inches tall for optimum control.

28

Forage, Fiber and Specialty Crops (Alfalfa (Seedling)) (continued)

BUCTRIL 4EC TANK MIXTURE DIRECTIONS

APPLICATION TIMING AND SPECIFIC COMMENTS PRODUCT RATE CROP WEEDS BUCTRIL® 4EC + Pursuit® + Non-ionic surfactant

1/4 - 3/8 pint/A + 3-6 oz/A + 1 qt/100 gallons

In all states except California, Washington, Oregon, Idaho, Montana, Wyoming, Colorado, Utah, Nevada, Arizona, New Mexico, and the western halves of North Dakota, South Dakota, Nebraska and Kansas:

Apply in the fall or spring to seedling alfalfa when the majority of the field has a minimum of 2 trifoliate leaves. When alfalfa stand is uneven and conditions favor leafburn, unacceptable crop injury may occur to alfalfa treated prior to the 2nd trifoliate stage of growth . If you are unsure of growth stage conditions, contact your local extension service. BUCTRIL 4EC + Pursuit ® applications made when temperatures are expected to exceed 70 oF at and 3 days following application can result in unacceptable crop injury.

BUCTRIL 4EC at 1/4 pint/A tankmixed with Pur suit® will control common lambsquarters up to 2 inches in height plus weeds listed on the Pursuit ® label. BUCTRIL 4EC at 3/8 pint/A + Pursuit ® will control the MOST SUSCEPTIBLE annual broadleaf weeds (See WEED LIST) when weeds do not exceed the 4 leaf stage, 2 inches in height or 1 inch in diameter, whichever comes first plus weeds listed on the Pursuit ® label. Applications should be made when the majority of the weeds are 1-3 inches tall and when common lambsquarters do not exceed 4 inches in height . F or low growing weeds (such as mustards), apply before the rosette exceeds 3 inches in diameter. Refer to the Pursuit ® label for a list of susceptible weeds at each of the recommended rates.

RESTRICTIONS AND PRECAUTIONS: Alfalfa (Seedling) • Crop leafburn can occur following BUCTRIL 4EC application. Warm , humid conditions may enhance leaf burn. New crop growth will not be affected. Alfalfa yield should not be reduced although tota l biomass tonnage may decrease compared to a weedy field due to weed removal. • Do not apply when alfalfa is under moisture, temperature, insect or disease stress or has been stressed by other pesticide car ryover or application. • If combined with herbicides requiring oil adjuvants or surfactants, increased alfalfa injury will occur. • Do not cut for feed or graze spring treated alfalfa within 30 days following treatment. • Do not cut for feed or graze fall or winter treated al falfa until spring, at least 60 days following treatment. • Do not plant rotational crops within 30 day s following BUCTRIL 4EC Herbicide application. • Do not enter or allow worker entry into treated areas during the restricted-entry interval (REI) of 2 days for alfalfa. • The total cumulative rate of BUCTRIL 4EC must not exceed 1 pint/A per season (0.5 lbs. a.i./A/year). • The total cumulative rate of BUCTRIL 4E C must not exceed 1 pint/A per season. • The use of Eptam ® preemergence may enhance crop leaf burn from postem ergence application of BUCTRIL 4EC and should be considered prior to using BUCTRIL® 4EC. • Follow all restrictions and precautions on the tank mixt ure product label when a BUCTRIL 4EC tank mixture is used. • Tank mixture with 2, 4-DB may result in unacceptable cr op leaf burn especially under warm, humid weather conditions. • BUCTRIL 4EC alone can be applied to seedling alfalfa that has been underseeded into small grains that include wheat, barley, o ats, rye and triticale. See application restrictions under the WHEAT, BARLEY, OATS, RYE AND TRITICALE SECTION. • Rainfall or overhead irrigation within 7 – 10 days following BUTYRAC® 200 application can cause unacceptable crop injury.

29

FLAX (Linum usitatissimum only)

BUCTRIL 4EC DIRECTIONS

APPLICATION TIMING AND SPECIFIC COMMENTS PRODUCT RATE CROP WEEDS BUCTRIL 4EC 1/2 pint/A Apply to flax that is 2 to 8 inches in height. Do not apply BUCTRIL 4EC to flax during or after the bud stage. Apply to MOST SUSCEPTIBLE weeds that do not exceed the 4-leaf stage, 2 inches in height or 1 inch in diameter, whichever comes first.

BUCTRIL 4EC TANK MIXTURE DIRECTIONS

APPLICATION TIMING AND SPECIFIC COMMENTS PRODUCT RATE CROP WEEDS BUCTRIL 4EC + Poast® + Crop oil Concentrate or Dash® 1/2 pint/A + 1-1 1/2 pints/A + 2 Pints/A or 2 pints/A Apply to flax that is 2 to 8 inches in height. Do not apply this tankmix to flax during or after the bud stage, or within 75 days of flax harvest.

This tankmix will control broadleaf weeds plus grassy weeds listed on the Poast label. Apply to MOST SUSCEPTIBLE broadleaf weeds (see list on the BUCTRIL 4EC label) that do not exceed the 4-leaf stage, 2 inches in height or 1 inch in diameter, whichever comes first.

RESTRICTIONS AND PRECAUTIONS: Flax (Linum usitatissimum only) • Do not plant rotational crops within 30 day s following BUCTRIL 4EC Herbicide application. • Do not apply if temperatures are expected to exceed 85° F at or 3 days following application or crop injury may occur. • Unacceptable crop injury may occur following BUCTRIL 4EC applic ation to flax grown on high organic, peat type soils. • Application under high humidity conditions can injure flax. • Unless otherwise instructed, do not apply BUCTRIL 4EC to flax with crop oil concentrate, surfactants or nitrogen solutions. • Do not use on ornamental flax. • Follow all precautions, directions and restrictions on the Poast ® label when using this tank mixture with BUCTRIL® 4EC. • Do not apply more than 1/2 pint of BUCTRIL 4EC per acre in a single growing season (0.25 lbs. a.i./A/year).

30

GARLIC BUCTRIL 4EC DIRECTIONS

APPLICATION TIMING AND SPECIFIC COMMENTS PRODUCT RATE CROP WEEDS BUCTRIL 4EC 3/4 - 1 pint/A Apply to garlic after emergence but before 12 inches in height. Apply to MOST SUSCEPTIBLE and SUSCEPTIBLE broadleaf weeds up to the 4-leaf stage, 2 inches in height or 1 inch in diameter, whichever comes first. BUCTRIL 4EC (Only for garlic grown in muck soils in Northeastern United States)* 3/4 - 1 pint/A Apply to garlic after emergence but before 12 inches in height. *May be harvested 60 days after treatment.

PRECAUTIONS AND RESTRICTIONS: Garlic • Do not plant rotational crops within 30 day s following BUCTRIL 4EC Herbicide application. • Use a minimum of 20 gallons per acre for ground application. • BUCTRIL 4EC can be applied through automated sprinkler irrigation application. • Do not harvest within 112 days following treatment (except ga rlic grown in muck soils in Northeastern United States). • Do not enter or allow worker entry into treated areas during the restricted-entry interval (REI) of 2 days for garlic. • Do not apply more than 1 pint of BUCTRIL 4EC per acre in a single growing season (0.5 lbs. a.i./A/year).

31

MINT (ESTABLISHED PEPPERMINT AND SPEARMINT ONLY)

BUCTRIL 4EC DIRECTIONS

APPLICATION TIMING AND SPECIFIC COMMENTS PRODUCT RATE CROP WEEDS BUCTRIL 4EC 1/2-3/4 pint/A Apply to dormant or actively growing established peppermint or spearmint crops that exhibit good vigor. Apply to MOST SUSCEPTIBLE and SUSCEPTIBLE weeds that do not exceed the 4-leaf stage, 2 inches in height or 1 inch in diameter, whichever comes first.

Chemigation 1 pint/A only Apply to dormant or actively growing established peppermint or spearmint crops that exhibit good vigor.

Apply through automated sprinkler irrigation systems with a mechanical transfer loading system only . See MIXING, LOADING AND HANDLING INSTRUCTIONS section for complete details.

RESTRICTIONS AND PRECAUTIONS: Mint • Application made to mint when temperatures are expected to exceed 70 oF at or 5 days following application may result in unacceptable crop injury. This injury is more likely to occur following BUCTRIL 4EC application in the spring. • Do not apply to mint growing under adverse conditions includi ng diseases, insects, nematodes, high salt content soil, drought, excessive moisture, winter damage or other environmental stress. • Application of BUCTRIL 4EC to mint should not be made within two weeks of a Sinbar® application or unacceptable crop injury may result. • Do not use in spring on newly established mint. Fall applications to spring planted mint should be acceptable if the crop is well established. • BUCTRIL 4EC can cause temporar y stunting and discoloration of the mint particularly from the spring application. However the injury symptoms are only temporary and have not caused yield reduction. • Use of BUCTRIL 4EC in combination with other product s may increase temporary stunting and discoloration. • Do not harvest within 70 days following treatment. • Do not enter or allow worker entry into treated areas duri ng the restricted-entry interval (REI) of 2 days for mint. • Do not apply more than 3 pints of BUCTRI L 4EC per acre to mint in a single growing season (1.5 lbs. a.i./A/year). • Do not plant rotational crops within 30 day s following BUCTRIL 4EC Herbicide application.

32

ONIONS (DRY BULB)

BUCTRIL 4EC DIRECTIONS

APPLICATION TIMING AND SPECIFIC COMMENTS PRODUCT RATE CROP WEEDS BUCTRIL 4EC

Preemergence 1/2-3/4 pint/A

Preemergence use is restricted to onions grown east of the Mississippi River only on muck soils containing greater than 10% organic matter. Apply at least 3 to 4 days prior to emergence. Rainfall or irrigation within 2 days following preemergence applications or 3 days prior to crop emergence may result in unacceptable crop injury. Preemergence applications can be applied using either ground or aerial equipment. Apply BUCTRIL 4EC at 1/2 pint/A to control MOST SUSCEPTIBLE weeds and 3/4 pint/A for SUSCEPTIBLE weeds. Weeds should not exceed the 4-leaf stage, 2 inches in height or 1 inch in diameter, whichever comes first. Postemergence 1/2-3/4 pint/A Apply only to onions, which have 2 to 5 true leaves. Use at least 50 -70 gallons of water per acre and apply by ground equipment or chemigation only . Water volume is important - CONCENTRATED SPRAYS KILL ONIONS . Thorough and uniform coverage is necessary for good weed control. In onion -producing areas, certain environmental conditions reduce development of waxy coating on the onion leaves, thus increasing the possibility of injury. Dry soil, dry onion foliage, high light intensity, low humidity, and high temperatures tend to increase the waxy coating on onion leaves and thus reducing chances for injury . It is essential that the soil and onion foliage be dry at the time of application. Humidity should be low and dew should be off the plants.

RESTRICTIONS AND PRECAUTIONS: Onions (Dry Bulb) • The sensitivity of onions to BUCTRIL 4EC varies with the va riety and environmental conditions. Therefore, even if all the label directions are followed, BUCTRIL 4EC application still may cause injury to onions under certain circumstances. • Do not irrigate onions that have received a preemergence applic ation of BUCTRIL 4EC for 2 days following application or within 3 days of crop emergence. • Do not apply BUCTRIL 4EC preemergence to onions grown West of the Mississippi River. • Do not use BUCTRIL 4EC on onions grown under low light inte nsity, in areas such as Oregon, west of the Cascades. • Do not treat onions damaged by sand, insects, or diseases. • Do not apply postemergence applications of BUCTRIL 4EC to onions with aerial equipment. • Do not add surfactant. • Do not enter or allow worker entry into treated areas during the restricted-entry interval (REI) of 2 days for onion. • Do not apply more than 3/4 pint of BUCTRIL 4EC per acre in a single growing season (0.375 lbs. a.i./ A/ year). • Do not plant rotational crops within 30 day s following BUCTRIL 4EC Herbicide application.

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GRASS CROPS

GRASSES GROWN FOR SOD PRODUCTION

BUCTRIL 4EC DIRECTIONS Seedling and Established Grasses

RATE RATE APPLICATION TIMING AND SPECIFIC COMMENTS PRODUCT Per ACRE Per 1000 SQ FT CROP WEEDS BUCTRIL 4EC 0.5 to 1.0 Pint 0.188 to 0.375 Fl. Oz. Apply to established and newly seeded grasses grown for sod production before the boot stage. Established grasses tolerant to BUCTRIL 4EC include bentgrasses, Kentucky Bluegrass, Fescues, Ryegrass, Bermudagrass, St. Augustinegrass and Zoyiagrass. BUCTRIL 4EC may also be used on seedling grasses such as Merion, Park, Delta, or common Kentucky Bluegrasses, Pennlawn, Chewings, Illahee or Alta Fescues, Orchard grass, Highland, Seaside or Astoria Bentgrasses, perennial Ryegrasses, Bahiagrass and Zoysiagrass.

Refer to the WEED LIST for a listing of susceptible broadleaf weeds. Optimal control will be attained when weeds are treated in the seedling stage (less than 4 leaf stage, 2 inches in height, or 1 inch in diameter).

BUCTRIL 4EC Chemigation 1 Pint Only 0.375 Fl. Oz. Apply to established and newly seeded grasses grown for sod production before the boot stage. Apply through automated sprinkler irrigation systems with mechanical transfer loading system only . See MIXING LOADING AND HANDLING INSTRUCTIONS section for complete details . Refer to the list of established grasses that are tolerant to BUCTRIL® 4EC.

RESTRICTIONS: Grasses grown for sod production • Do not allow livestock to graze in treated areas or feed treated grasses, forage, hay, straw, silage, or seed to livestock. • Do not apply BUCTRIL 4EC to grasses grown for sod production with backpack or hand-held application equipment. • Do not apply more than 1 pint of BUCTRIL 4EC per acre in a single growing season (0.5 lbs. a.i./A/year). • Do not enter or allow worker entry into treated areas during the restricted-entry interval (REI) of 2 days for grass. • Do not plant rotational crops within 30 day s following BUCTRIL 4EC Herbicide application.

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NON-RESIDENTIAL TURFGRASS

BUCTRIL 4EC DIRECTIONS Seedling and Established Non-Residential Turfgrass

RATE RATE APPLICATION TIMING AND SPECIFIC COMMENTS PRODUCT Per ACRE Per 1000 SQ FT CROP WEEDS BUCTRIL 4EC 0.5 to 1.0 Pints

0.188 to 0.375 Fl. Oz. Apply to established and newly seeded non-residential turfgrass when weeds are small and actively growing. Established turfgrasses that are tolerant to BUCTRIL 4EC include bentgrasses, Kentucky Bluegrass, Fescues, Ryegrass, Bermudagrass, St. Augustinegrass and Zoyiagrass. BUCTRIL 4EC may also be used on seedling grasses such as Merion, Park, Delta, or common Kentucky Bluegrasses, Pennlawn, Chewings, Illahee or Alta Fescues, Orchard grass, Highland, Seaside or Astoria Bentgrasses, perennial Ryegrasses, Bahiagrass and Zoysiagrass.

Refer to the WEED LIST for a listing of susceptible broadleaf weeds. Optimal control will be attained when weeds are treated in the seedling stage (less than 4 leaf stage, 2 inches in height, or 1 inch in diameter).

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BUCTRIL 4EC TANKMIXTURE RECOMMENDATIONS Established Non-Residential Turfgrass

RATE RATE APPLICATION TIMING AND SPECIFIC COMMENTS PRODUCT Per ACRE Per 1000 SQ FT CROP WEEDS BUCTRIL 4EC + WEEDONE® DPC Ester

1 Pint

3 to 4 Pints

0.375 Fl. Oz. + 1.125 to 1.5 Fl. Oz.

Apply to established non- residential turfgrass only . This treatment may cause injury to bentgrasses, St. Augustinegrass, centipedegrass, and carpetgrass. All weed species previously listed in the WEED LIST for BUCTRIL 4EC plus the following species: Dandelion (Taraxacum officinale) Plantains (Plantago spp.) Ground Ivy (Glechoma hederacea) Red Clover (Trifolium pratense) White Clover (Trifolium repens) Hop Clover (Trifolium agrarium) Common Chickweed (Stellaria media) Prostrate Spurge (Euphorbia supina) Oxalis (Oxalis europaea) Knotweed (Polygonum aviculare) Optimal control will be attained when weeds are treated in the seedling stage (less than 4 leaf stage, 2 inches in height, or 1 inch in diameter).

BUCTRIL 4EC + MCPP

1 Pint + 1.0 lb ai

0.375 Fl. Oz. + 0.025 lb ai

Apply to established non- residential turfgrass only . This treatment is not recommended for use on St. Augustinegrass or centipedegrass . All weed species previously listed in the WEED LIST for BUCTRIL 4EC plus the following species: Red Clover (Trifolium pratense) White Clover (Trifolium repens) Common Chickweed (Stellaria media) Mouseear Chickweed (Cerastium vulgatum) Ground Ivy (Glechoma hederacea) Stitchwort (Stellaria gramminea) Knotweed (Polygonum aviculare) Prostrate Spurge (Euphorbia supina) Optimal control will be attained when weeds are treated in the seedling stage (less than 4 leaf stage, 2 inches in height, or 1 inch in diameter).

BUCTRIL 4EC + dicamba

1 Pint

0.125 to 0.25 lb ai

0.375 Fl. Oz. + 0.006 to 0.012 lb ai

Apply to established non- residential turfgrass only . This treatment may cause injury to bentgrasses, St. Augustinegrass, centipedegrass, and carpetgrass. All weed species previously listed in the WEED LIST for BUCTRIL 4EC plus the following species: Red Clover (Trifolium pratense) White Clover (Trifolium repens) Common Chickweed (Stellaria media) Mouseear Chickweed (Cerastium vulgatum) Pepperweed (Lepidium spp.) Knotweed (Polygonum aviculare) Optimal control will be attained when weeds are treated in the seedling stage (less than 4 leaf stage, 2 inches in height, or 1 inch in diameter).

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Established Non-Residential Turfgrass (CONT.)

RATE RATE APPLICATION TIMING AND SPECIFIC COMMENTS PRODUCT Per ACRE Per 1000 SQ FT CROP WEEDS BUCTRIL 4EC + MCPP

dicamba

1 Pint + 0.5 to 1.0 lb ai + 0.125 to 0.25 lb ai

0.375 Fl. Oz. + 0.0125 to 0.025 lb ai + 0.003 to 0.006 lb ai

Apply to established non -residential turfgrass only . This treatment is not recommended for use on St. Augustinegrass or centipedegrass. All weed species previously listed in the WEED LIST for BUCTRIL 4EC and BUCTRIL ® 4EC/Dicamba tank mixtures plus the following species: Dandelion (Taraxacum officinale) Plantains (Plantago spp.) Optimal control will be attained when weeds are treated in the seedling stage (less than 4 leaf stage, 2 inches in height, or 1 inch in diameter).

BUCTRIL 4EC + MCPP

2.4-D

1 Pint + 0.5 to 1.0 lb ai + 0.5 to 1.0 lb ai

0.375 Fl. Oz. + 0.0125 to 0.025 lb ai + 0.0125 to 0.025 lb ai

Apply to established non -residential turfgrass only . This treatment is not recommended for use on St. Augustinegrass or centipedegrass. All weed species previously listed in the WEED LIST for BUCTRIL 4EC and BUCTRIL ® 4EC/2,4-D tank mixtures plus the following species: Dandelion (Taraxacum officinale) Plantains (Plantago spp.) Red Sorrell (Rumex acetosella) Knotweed (Polygonum aviculare) Optimal control will be attained when weeds are treated in the seedling stage (less than 4 leaf stage, 2 inches in height, or 1 inch in diameter) . Optimal control of red sorrell will require the high use rate of 2 , 4-D or MCPP.

RESTRICTIONS: Non-residential turfgrasses • BUCTRIL ® 4EC/WEEDONE® DPC tankmixes are not allowed in California. • Do not allow livestock to graze in treated areas or feed treated grasses, forage, hay, straw, silage, or seed to livestock. • Do not apply BUCTRIL 4EC to non-residential turf with backpack or hand-held application equipment. • Do not apply more than 1 pint of BUCTRIL 4EC per acre in a single growing season (0.5 lbs. a.i./A/year).

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NON-CROPLAND

NON-CROPLAND AND INDUSTRIAL SITES

BUCTRIL 4EC DIRECTIONS

RATE RATE APPLICATION TIMING AND SPECIFIC COMMENTS PRODUCT Per ACRE Per 1000 SQ FT CROP WEEDS BUCTRIL 4EC 0.5 to 1 Pint 0.188 to 0.375 Fl. Oz. Apply to non -cropland and industrial sites when weeds have emerged and are actively growing. Refer to the WEED LIST for a listing of susceptible broadleaf weeds . Use adequate spray volumes to ensure thorough coverage. Optimal control will be attained when weeds are treated in the seedling stage (less than 4 leaf stage, 2 inches in height, or 1 inch in diameter).

RESTRICTIONS AND PRECAUTIONS: Non-Cropland and Industrial Sites • Do not allow livestock to graze in treated areas or feed treated plant material to livestock. • Addition of surfactant or crop oil concentrate may improv e burndown of broadleaf weeds under cool, dry conditions. • Do not apply BUCTRIL 4EC to non-cropland and industrial si tes with backpack or hand-held application equipment. • Do not apply more than 1 pint of BUCTRIL 4EC per acre in a single growing season (0.5 lbs. a.i./A/year).

STORAGE AND DISPOSAL Proper pesticide storage and disposal are essential to protect against exposure to people and the environment due to leaks and spills, excess product or waste, and vandalism. Do not allow this product to contaminate water, foodstuffs, feed or seed by storage or disposal. PESTICIDE STORAGE: Store pesticides away from food, pet food, feed, seed, fertilizers, and veterinary supplies. Keep container closed to prevent spills and contamination. PESTICIDE DISPOSAL: To avoid wastes, use all material in this container, including rinsate, by application according to label directions. If wastes cannot be avoided, offer remaining product to a waste disposal facility or pesticide disposal program. Such programs are often run by state or local governments or by industry. All disposal must be in accordance with applicable federal, state and local regulations and procedures CONTAINER HANDLING AND DISPOSAL: [Container Handling and Disposal for Nonrefillable Containers] Nonrefillable container. For nonrefillable containers of 5-gallon capacity or less Do not reuse the container to hold materials other than pesticides or dilute pesticides (rinsate). After emptying and cleaning, it may be allowable to temporarily hold rinsate or other pesticide-related materials in the container. Contact your state regulatory agency to determine allowable practices in your state. Triple rinse or pressure rinse (or equivalent) the container promptly after emptying. Triple rinse as follows: Empty the remaining contents into application equipment or a mix tank and drain for 10 seconds after the flow begins to drip. Fill the container ¼ full with water and recap. Shake for 10 seconds. Pour rinsate into application equipment or a mix-tank or store rinsate for later use or disposal. Drain for 10 seconds after the flow begins to drip. Repeat this procedure two more times. Pressure rinse as follows: Empty the remaining contents into application equipment or a mix tank and continue to drain for 10 seconds after the flow begins to drip. Hold container upside down over application equipment or mix-tank while rinsing, or collect rinsate for later use or disposal. Insert pressure rinsing nozzle in the side of the container and rinse at about 40 PSI for at least 30 seconds. Drain for 10 seconds after the flow begins to drip. For nonrefillable containers of greater than 5-gallon capacity

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Do not reuse or refill this container. Triple rinse or pressure rinse (or equivalent) the container promptly after emptying. Triple rinse large nonrefillable containers NOT equipped with pumping systems as follows: Empty the remaining contents into application equipment or mix-tank. Fill the container ¼ full with water. Replace and tighten closures. Tip the container on its side and roll it back and forth for 30 seconds, ensuring at least one complete revolution. Stand the container on its end and tip it back and forth several times. Turn the container over onto its other end and tip it back and forth several times. Empty the rinsate into application equipment or mix-tank, or store rinsate for later use or disposal. Repeat this procedure two more times. Triple rinse large nonrefillable containers equipped with pumping systems as follows: Empty the remaining contents into application equipment or mix-tank. Fill the container about 10 percent full with water. Agitate vigorously or recirculate water with the pump for 2 minutes. Pour or pump rinsate into application equipment or rinsate collection system. Repeat this rinsing procedure two more times. Pressure rinse large containers as follows: Empty the remaining contents into application equipment or mix-tank. Place container so that it can drain directly into application equipment or mix-tank while rinsing, or collect rinsate for later use or disposal. Insert pressure rinsing nozzle through the opening of the container or directly into the side of the container and rinse at about 40 PSI for at least 30 seconds or until rinsate runs clear. Continue to drain for 10 seconds after the flow begins to drip. Once the nonrefillable container is properly rinsed, offer for recycling, if available. Some container manufacturers offer container recycling. See additional information regarding manufacturer recycling programs attached to the container, if available. If no recycling information is available on the container, contact your chemical dealer or Bayer CropScience at 1-866-99BAYER (1-866-992-2937), or contact the Ag Container Recycling council (ACRC) at 1-877-952-2272 or at www.acrecycle.org, to find the nearest recycling location. If recycling is not available, dispose of in accordance with federal, state and local regulations and procedures, which may include puncturing the properly rinsed container and disposing in a sanitary landfill. [Container Handling and Disposal for Refillable Containers] Refillable container. Refill the container with pesticide only. Do not reuse the container for any other purpose.

Cleaning the container before refilling is the responsibility of the refiller. Cleaning the container before final disposal is the responsibility of the person disposing of the container. Triple rinse or pressure rinse (or equivalent) the container promptly after emptying and before final disposal. To triple rinse the refillable container before final disposal, empty the remaining contents from the container into application equipment or mix-tank. Fill the container at least 10 percent full with water. Agitate vigorously or recirculate water with the pump for 2 minutes. Pour or pump rinsate into application equipment or rinsate collection system. Repeat this procedure two more times. To pressure rinse the refillable container before final disposal, empty the remaining contents from the container into application equipment or mix-tank. Position the container so that it can drain directly into application equipment or mix- tank while rinsing, or collect rinsate for later use or disposal. Insert pressure rinsing nozzle through the opening of the container or directly into the side of the container and rinse all interior area at about 40 PSI for at least 30 seconds or until rinsate drains clear.

Once the refillable container is properly rinsed, offer for recycling, if available. Some container manufacturers offer container recycling. See additional information regarding manufacturer recycling programs attached to the container, if available. If no recycling information is available on the container, contact your chemical dealer or Bayer CropScience at 1-866-99BAYER (1-866-992-2937), or contact the Ag Container Recycling council (ACRC) at 1-877-952-2272 or at www.acrecycle.org, to find the nearest recycling location. If recycling is not available, dispose of in accordance with federal, state and local regulations and procedures, which may include puncturing the properly rinsed container and disposing in a sanitary landfill. [Optional additional container disposal statement: IBC EMPTY? – FREE CALL – 1-888-SCHUETZ (1- 888-724-8389) www.schuetz.net/ticket; Schuetz ticket service] [Optional additional container disposal statement: FREE IBC PICKUP] [For continental USA and Canada only.] [Optional additional container disposal statement: RETURNnet SYSTEM – To return empty IBC’s Email or Call – www.returnnetsystem.com – 1-888-758-SHIP – United States and Canada (1-888-758-7447 – IBCNA – Clarkston, Michigan – USA] [Optional additional container label statements for the CUBE refillable packaging system only:

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CUBE Bayer CropScience Refillable Delivery System FEATURES INCLUDE: • Automatic Venting • Heavy duty one-way 2-inch camloc ball valve with protective shield door • Complete coated steel protective enclosure • Durable 4-way plastic pallet Lift door to access one-way valve] [For Transport Vehicle labels only, as defined at 40 CFR § 156.3] FOR BULK PESTICIDE TRANSPORT ONLY. STORAGE AND DISPOSAL Proper pesticide storage and disposal are essential to protect against exposure to people and the environment due to leaks and spills, excess product or waste, and vandalism. Do not allow this product to contaminate water, foodstuffs, feed or seed by storage or disposal. PESTICIDE STORAGE: Store pesticides away from food, pet food, feed, seed, fertilizers, and veterinary supplies. Keep container closed to prevent spills and contamination. PESTICIDE DISPOSAL: To avoid waste, empty as much product from this transport vehicle as possible for repackaging or use in accordance with label directions. If wastes cannot be avoided, offer remaining product or rinsate to a waste disposal facility or pesticide disposal program. All disposal must be in accordance with applicable federal, state and local regulations and procedures. CONTAINER HANDLING AND DISPOSAL: Emptied transport vehicle container retains vapor and product residue. Observe all precautions stated on this label until the container is cleaned, reconditioned or destroyed. Prior to refilling, inspect carefully for damage such as cracks, punctures, abrasions, and worn-out threads and closures. Clean thoroughly before reuse for transportation of a material of different composition or before retiring this transport vehicle container from service. THIS LABEL FOR USE WITH TRANSPORT VEHICLES ONLY

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IMPORTANT: READ BEFORE USE Read the entire Directions for Use, Conditions, Disclaimer of Warranties and Limitations of Liability before using this product . If terms are not acceptable, return the unopened product container at once. By using this product, user or buyer accepts the following Conditions, Disclaimer of Warranties and Limitations of Liability. CONDITIONS: The directions for use of this product are believed to be adequate and must be followed carefully. However, it is impossible to eliminate all risks associated with the use of th is product. Crop injury, ineffectiveness or other unintended con sequences may result because of such factors as weather conditions, presence of other materials, or the manner of use or application, all of which are beyond the control of Bayer CropScience. All such risks shall be assumed by the user or buyer. DISCLAIMER OF WARRANTIES: TO THE EXTENT CONSISTENT WITH APPLICABLE LAW, BAYER CROPSCIENCE LP MAKES NO OTHER WARRANTIES, EXPRESS OR IMPLIED, OF MERCHA NTABILITY OR OF FITNESS FOR A PARTICULAR PURPOSE OR OTHERWISE, THAT EXTEND BEYOND THE STATEMENTS MADE ON THIS LABEL. No agent of Bayer CropScience LP is authorized to make any warranties beyond those contained herein or to modify the warranties contained herein. TO THE EXTENT CONSISTENT WITH APPLICABLE LAW, BAYER CROPSCIENCE LP DISCLAIMS ANY LIABILITY WHATSOEVER FOR SPECIAL, INCIDENTAL OR CONSEQUENTIAL DAMAGES RESULTING FROM THE USE OR HANDLING OF THIS PRODUCT. LIMITATIONS OF LIABILITY: TO THE EXTENT CONSISTENT WITH APPLICABLE LAW, THE EXCLUSIVE REMEDY OF THE USER OR BUYER FOR ANY AND ALL LOSSES, INJURIES OR DAMAGES RESULTING FROM THE USE OR HANDLING OF THIS PRODUCT, WHETHER IN CONTRACT, WARRANTY, TORT, NEGLIGENCE, STRICT LIABILITY OR OTHERWISE, SHALL NOT EXCEED THE PURCHASE PRICE PAID, OR AT BAYER CROPSCIENCE LP’S ELECTION, THE REPLACEMENT OF PRODUCT.

Warning: This product contains a chemical known to the State of California to cause developmental harm.

NET CONTENTS: 2.5 GALLONS

BUCTRIL, SEVIN, Dash, Hoelon and Tiller are registered trademarks of Bayer Group. Butyrac is a registered trademark of Albaugh, Inc. Avenge and Pursuit are registered trademarks of BASF Corporation Dylox, Metasystox, Sencor, and Systox are registered trademarks of Bayer CropScience. Raindrop is a registered trademark of Delavan Corporation. Curtail, Lorsban, and Stinger are registered trademarks of DowElanco Chemical Company. Accent, Ally, Express, Finesse, Glean, Harmony, Lexone, and Pydrin are registered trademarks of E.I. DuPont DeNemours and Co. Furadan and Pounce are registered trademarks of FMC Corporation. Roundup and Permit are registered trademarks of Monsanto Company. Banvel and Clarity are registered trademarks of Sandoz Crop Protection Corporation. Eptam is a registered trademark of ICI Americas Inc. Aatrex, Amber, Beacon and Exceed are registered trademarks of SYNGENTA CROP PROTECTION, LLC. Poast is a registered trademark of BASF Corporation. Rhomene, Rhonox, Weedar and Weedone are registered trademarks of NuFarm.

Produced for

Bayer CropScience LP 800 N. Lindbergh Blvd. St. Louis, MO 63167 1-866-99BAYER (1-866-992-2937)

BUCTRIL 4EC Herbicide (PENDING) 04/16/2020, 08/23/2021, 05/11/2022, 05/20/2022, 05/31/2022, 11/08/2022