Dockerfile: self-contained image with corpus + Chroma + BM25 baked in. Drawbar's compose pulls + runs without volume mounts. Built from sources.json (labels schema), PRODUCT_NAME=crop_chem by default, HYBRID_SEARCH=true (always-on for production quality). RERANK_URL + OLLAMA_URL get set at compose time. .gitea/workflows/refresh.yml: monthly cron (1st @ 06:00 UTC) does full scrape → reindex → image push. Scrapes Bayer (~30 min) + EPA PPLS row-crop filtered (~7h). Skips reindex+push if no corpus diff. Tags pushed: :latest, :<sha12>, :corpus-<YYYY.MM.DD>. .gitea/workflows/image-only.yml: on-demand or auto on code-only pushes to main (paths: docs_mcp/, rag/, scrape/, requirements.txt, Dockerfile, sources.json). Reindexes from committed corpus, builds image, pushes. ~10 min vs ~9h full refresh. .gitignore: corpus/ now COMMITTED (4,159 labels, 265 MB of .md + sidecars). Lets image-only.yml rebuild indexes without re-scraping. chroma/ + bm25/ still gitignored (regenerable binary indexes). .dockerignore: drops venv, eval results, PLAN/README/CLAUDE.md, deploy/, .git/ — keeps the image lean. corpus + chroma + bm25 explicitly NOT in dockerignore (those go INTO the image). Co-Authored-By: Claude Opus 4.7 (1M context) <noreply@anthropic.com>
20 KiB
PHOSKIL 2 DUST INSECTICIDE
- EPA Reg No: 279-464
- Registrant: FMC CORPORATION
- Signal word: Danger
- Active ingredients: Parathion (2%)
- Label accepted: 1987-11-09
- Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/000279-00464-19871109.pdf
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RESTRICTED USE PESTICIDE
Duft to very high acute toxicity to Humans ana l3irds
For retail saJe (0 and use only by certified appIicalOf or persons under their direct supecvisioo and
Olily (or those uses co"ered by (he certified applicator's certffication. Direct supeMsion for this
product Is defined as ., certified appticatOf being physically present during appicalion. mixing,
loading. repair and cIean..g of application equipment. Commercial certified appIicalDrS most also
ensure thai all persons invotved in these activities ate informed oltha ;>fecautiomvy stat€menlS.
Phoskil® 2 Dust
Insecticide
EPA Reg. No. 279-464 ZA EPA Est., 279-
_ ingredient: By WI.
Porathion; O.O-diethyl O·p-nitrophenyl
I":e:::::::::::::::::::::::::::::::::::::: --..;...-.. ":' .. :
100.00%
STOP! READ THE LABEL
CAN KILL YOU
NOT FOR HOME USE
DANGER POISON
Keep out 01 reach
01 children
See side panels
lor antidote
and precautions
PELIGRO
PRECAUCION AL USUARIO: Si usted no lee ingles. no use este pro
ducto hasta que la efiqueta Ie haya $ido explicado ampliamente.
...... ~ ....... ----.":,:,'
'\l:-eqi \
• . ....... t"t'!I
. . ·-.. ;'.L4i;,,;1981 ~
CCE D
1987
FMC Corporation
Agricultural Chemical Group
Philadelphia PA 19103 ,
..... 7
r-:---' UANGER-POISOH-PRECAUTIONS
~
SWAllOW
~:
NISONOUS IF SWALLOWED
ThiS product can kill you il swallowed even in
small amounls: spray mist or dust may be
latal if swalIov.ed.
POISONOUS BY SKIN CONTACT
t-.....
j-_. Poisonous iltouched by hands or spilled or
splashed on Skin, in eyes or on clothing (liquid
~;;;:;: goes through clothes)
00 NOT TOUCH
POISONOUS IF BREATHED
Breathing vapors. spray mist or dust may be
latal.
DO NOT
aREATH£
THIS PRODUCT MAY BE FATAL IF SWALLOWED. INHAlED. OR IF
ALLOWED TO CONTACT SKIN. FAILURE TO PROPERLY FOLLOW
ALL INSTRUCTIONS FOR PROTECTIVE CLOTHING AND EQUIp·
MENT WILL INCREASE YOUR RISK.
USE ONLY WHEN WEARING THE FOLLOWING PROTECTIVE
CLOTHING AND EQUIPMENT DURING MIXINGILOADING. APPLI·
CATION. REPAIR AND CLEANING OF APPLICATION EQUIPMENT.
DISPOSAL OF PESTICIDE. AND EARLY REENTRY INTO TREATED
FIELDS:
Waterprool pants and coat; heavy-duty chemical· resistant gtoves; ",b
ber boots or ",bile< overshoes; hood or wlde-brimmed hat; safety gog.
gles or face shield; HIOSH 8DI)fOVed respirator. In addition. mix8f/IQsd·
ers must wear a chemical reSIstant apron when = concentraled
product. During aerial application In nOllellclosed • a helmet with
a visor may be substituted for the hood or wide·brimmed hat and safety
goggles or face shield requirements.
POISONOUS TO ASH AND WlLDUFE
POI!lON SIGNS (Symptom.)
PARATHION Is a very dangerous polson. H rapldty enters the body on
contact with all skin sorloces and eyes. Clothing wei with this malerial
must be removed immediately. Exposed persons must rOCGlve prompt
medical treatment or they may die.
Some of the signs and symptoms of poisoning are: Headaohe. nausea.
vomiting. cramps. weakness. blurred vision. Pin·potnt pupils. tightness
in chest. labored breathing. nervousness. sweating. watering of ayes.
drooling Of kOlhing of mouth and nose. muscle spasms and coma.
WORK SAFETY RULES
IF MIXINGilOADING IS PERFORMED USING A CLOSED SYSTEM.
THE FOLLOWING PROTECTIVE CLOTHING AND EQUIPMENT MAY
BE WORN AS AN ALTERNATIVE:
Heavy-duty chemical resistant gloves; chemical resistant apron. long·
sleeved shlrt (Of gauntleis and short &lee .. shirt) and Iong.togged I'8flts; _ and sockS.
Safety goggle. or a laceshlelcl must be worn when the system Is under
pressure. · ... 11 other protective clothing and equipment required for use
with open aysiems must be 8vailatM nearby,
.'
IF APPLICATION IS PERFORMED USING AN ENCLOSED CAB OR
COCKPIT, THE FOLLOWING PROTECTIVE CLOTHING AND EQUIP
MENT MAY BE WORN AS AN ALTERNATIVE:
Clean Iong·sleeved shirt and long-legged panls. All other protective
clothing and equipment required (or use during applicalion must be
available in the cab and must be wom when exiting the cab inlo treated
areas. n used tor this purpose. contaminated dothing may not be brought
back into the cab unless in an enclosure such as a plastic bag.
REMEMBER-THIS CLOTHING IS NOT INTENDED TO PROTECT
YOU DURING REPAIR AND CLEANING OF APPLICATION EQUIP
MENT OR DURING EARLY REENTRY! REFER TO THE INSTRUC
TIONS ABOVE.
HUMAN FLAGGERS ARE STRICTLY PROHIBITED DURING AERIAL
APPLICATION.
IMPORTANT! If pesticide comes in contact with skin. wash oH with soap
and water. and contact a physician immedtately. Always wash hands.
face, and arms with soap and water before smoking, eating. drinking,
or toileling.
AFTER WORK: Wash gJoves with soap and waler before removing.
Take or. all work clothes and shoes. Store pr()ective clothing separately
from pe<sOOaI 00thing.1.aundef protective dOtNng a!ler each use. Shower
using soap and water. Wear only clean dolhes when leaving job. Do
not wear contaminated cJolhing. Personal clothing worn during mixing!
Joading, appIicalton, repair and cleaning of application equipment. dis·
posal of pesticide. and early reentry into treated fields must be stored
and laundered separately from household articles. Clothing and equip
ment heavily contaminated or drenched with parathion must be de
stroyed according to slate and local regulations.
HEAVILY CONTAMINATED OR DRENCHED CLOTHING CANNOT BE
ADEQUATELY DECONTAMINATED.
{_ 'lirators should be cleaned and cartridges replace<! according to
'C ,uctions included with respirafors. Replace gloves frequently.
ARST AID TREATMENT
Call a doctor (physician). clinic or hospital immediately. Explain that the
victim has been exposed to parathion and describe his condition.
tf breathing MS stopped, start artificial respiration immediately and
maintain until doctor sees viclim.
tf awallowed, drink 1 or 2 91asses of water and induce vomiting by
touching back of throat with flr. Neve~ give anything by mouth to an
unconscioUs persort Have victim lie dowt, and keep quiet. See doctor
immediately.
In case of contKt. immediately flush eyes or skin With plenty of water
for at least 15 minutes while removing contaminated dothing and shoes.
See doctor immediately.
NOTE TO PHYSICIAN
Antidote-administer atropine sulfate in large doses. TWO to FOUR
mg. intravenously or intramuscularly as soon as cyanosis is overcome.
Repeat at 5 to 10 minute intervals until signs of atropinization appear.
2·PAM chloride is also antkSotaJ and may be administer6d in conjunction
with alropine. 00 NOT GIVE MORPHINE OR TRANQUILIZERS. Par
athion is a strong cholinesterase inhibitor affecting central and periph
f"r:tl nervous systems and producing cardiac and respiratory depression.
( ·rst sign of pulmonary ede.l1a, the patiEmt stlouki be given supple
.. .. nlal oxygen and treated symptomatically. Continued absorption of
the poison may occur and fatal relapses have been reported after initial
improvemenl; VERY CLOSE SUPERVISION OF THE PATIENT IS IN
DICATED FOR AT LEAST 48 HOURS.
FOR EMERGENCY ASSISTANCE CALL
716-735-3765
POST TRUTED AREA
Consult your State Agricullur3t Extension Service or Experiment Station
regarding posting treated areas.
ENVIRONMENTAL HAZARDS
This pesticide is high1y toxic to (ish and wildlife. Birds in treated aTeas
may be kWed. 00 not apply diredly 10 water or wetlands (swamps,
marshes, bogs, and pothOles) Run·off and drift from target areas may
be hazardous to aquatic organisms in adjacent aqualic sites. Do not
conlaminate water by cleaning of equipment or disposal of wasles.
This produd is extremely toxic to bees exposed to diTect "eatment or
residues on bb:>rnlng crops or weeds. 00 not apply this product or allow
to drift to blooming crops or weeds if bees are visiting the treatment
area.
DIRECTIONS FOR USE
It I •• violation 01 Federal law 10 u .. Ihls product In a manner incon
sllIenl with Ita labeling.
Do nol apply thl. product In such a manner as 10 directly h,ough
drift expoae WOf1(ers Of other persons. The afea being treated must be
vacated by unprotected peroons. .
Reentry into apple, citrus, peach. nectarine or grape lieJds in the states
of Arizona, Catilomia. Nevada. New Mexico, Oklahoma, Texas, and
Utah is prohibited for seven days after (he end of application, unless all
protective clothing and equipment required for earty reentry as de
scribed elsewhere on the label is worn. Reentry inlo all other treated
areas is prohibited for 48 hours after end of application, unless all re
quired protective clothing and equipment is worn.
Because certain states may require more reslrictive reentry intervals for
various crops treated With this product. consult your State Department
of Agriculture for further informalion.
Written or oral warnings must be given to workers who are expected to
be in a treated area OT in an area aoo.Jt to be treated with this product.
Inform workers of areas or fields that may not be entered without specific
protective clothing, period of time field must be vacated and appropriate
actions to take in case of accidental expo&"lre. An d:xample of such
information is given under wrinen warnings. When oral warnings are
given. warnings shall be given in a language customarily understOod by
workers. Oral warnings must be given if there is reason to believe that
wrinen warnings cannot be understood by workers. Wrinen warnings
must include the folJowing informalion:
DANGER
Area treated with Phoskil· 2 Dust on (insert date). Do not enter
wilhout appropriate protective clothing for 48 hours (insert Stale
Department of AgricuHure's re-entry interval, if lTIOfe restrictive).
In case of accidental exposure to pesticide spray or duss, wash
the skir. thoroughly With soap and water. Remove contaminated
clothing and wash before reuse. If in eyes, flush with plenty of
water. If inhaled, 90 to an area where the pesticide has not been
appUed. Get mechcal attention if needed.
STORAGE AND DISPOSAL
Pesticide Storage
00 not store in or around the home.
Keep out of reach of children and animals. Store in original con·
lainers only. Store in a COOl. dry place and avoid excess heat.
Carefully open containers. After partial use, fold and roll back
bags, damp and dose tightly. Do not pul concentrate or dilute
malerial into food or drink containers. Do not contaminate other
pesticides, fertilizers. water. food or feed by storage or disposal.
In case of spill. avoid contact. isolate area and keep out animals
and unprotected persons. Coniine spillS. Call FMC collect: (716)
735-3765.
To confine spill: If liquid, dike surrounding area or absorb wilh
sand, cat litter or commercial day. If dry material, cover to pre·
vent dispersal. Place damaged package in a holding container.
Idenlify contenls.
Pesticide Disposal
Pesticide wastes are acutely hazardoUs. Improper disposal of
excess pesticide, spray mixture, or rinsate is a violation of Fed
erallaw. H these wastes cannol be disposed of by use according
to label instruc\ions. contact your State Pesticide Of Env1ron
mental Control Aaency, or the HazardoUs Waste representative
at the nearest EFfA Regional Office for guidance.
CoINII_D1sposal
Comple\e\y empty ""II inlo applicallon equipment. Then dispose
of empty bag in a sanitary landfill or by incineration, or, if alkwfed
by Slate and local authorities, by burning. " burned, slay oot 01
smoke.
ENDANGERED SPECIES RESTRICTIONS
The lailowlng reslrictions apply to use 01 this product aHer February I,
19BB.
Belore using this pesticide on com, wheat. oats andlor barley in the
counties lisled below, you musl oblain the PESTICIDE USE BULLETIN
FOR PROTECTION OF ENDANGERED SPECIES lor lhe county in
which the product is 10 be used. The bulletin Is availabte from your
County Exlension Agenl, Siale Fish and Game OIIice, or yoor pesliCide
deaier. UN of thll product In I mon_ Inconlillont with the PES
TICIDE USE BULLETIN FOR PROTECTION OF ENDANGERED SPE·
CIES II I violation of Federll ,,"WI,
Allblml
Colbert, Greene. Jackson, lamar, lauderdale. Umeslone, Madison.
Marsh.II, Morgan, Pickens and SUmler
Arizona
Grahem, Maricopa, Mohave, Pima, Pinal and Sanla Cruz
ArIuonl ..
Benton, Clark, gay, Cross, Lawrence, Lee, _0, Polk, Randolph,
Sharp and St. Francis
CoIliomll
Bulle, Colusa, Glenn, Imperial, Inyo, Kern, Los Angel •• , Merced,
c
• t
c
. . .
Modoc, Orango, Riverside, Sacramento, San Bernardino, San lJiego,
Santa BarbaTa. Solano, Stanislaus, Sutter, T~, VenI1Jfa and Yolo
Florida
Alachua. Bake'. Bradford. Brevard. Broward, Charlotte, Citrus, Clay,
Collier, Columbia, Oade, De Soto. Dixie, Duva!. FI&gler, Gadsden.
Gi;.:t,rest, Glades, Hardee, Hendry, Hernando, HighIan<Is, HiHsborough,
Indian River, Jefferson. Lafayette. Lake. Lee, leon. Levy. Madison,
Manatee, Marion. Martin, Monroe, Nassau, Okeechobee, Orange.
Osceola. Palm BeaCh. Pasco. Pinellas. Polk. Putnam, SI. Johns, St.
Lucie, Sarasola, Seminole, Sumler, Suwannee, Taylor, Union, Volusia
and Wakulla
Georgi.
Branlley, Bryan, Bulloch, Burlce, Camden, Candler, Char1lon, Chalham,
Effingham, Emanuel. Evans, Glascock. Glynn, Jefferson. Jenkins.
Johnson. liberty, Long. McIntosh. Pierce, Richmond. Screven. Ware,
Wasihington and Wayne
Kin ...
Clarlc, Comanclle, Meade and SlaHord
Kentucky
Ballard. Butler, Edmundson, Green, Hart. Jackson, Laurel. Livingston.
Marshall. McCracken, McCreary. Pulaski, Rockcastie, Taylor, Warren
and Wayne
MI .. I .. lppl
Claiborne. Copiah, Hinds, Jrawamba, lOwndes. Monroe and Noxubee
Mluourl
Barry, Benton, camden, Christian, OaUas, Greene, Hickory, Jaspar,
Lawrence, Miller, Newlon, Osage, Polk, 51. Clair, Slone and Websler
tono
Gartieid, McCone, Sheridan and Vaney aka
Boyd, Brown, Buffalo, Buller. Cass, Cedar, Colfax. Dawson, Dodge,
Ias, Hall, Hamihon, Hoh, Howard, Kearney, Keya Paha, Knox,
Merrick, Nance, Phelps, Platte, Polk, Rock, Sarpy and Saunders
-Clarlc
_Mexico
Chaves, Debaca and Eddy
North Corollo.
Edgecombe, Nash and Pitt
North Dllkol8
Sanson. Bottineau, Burke. Burleigh. DMde, Dunn, Eddy. Emmons.
Foster. Kidder, Loaan, McHen,,!, Mclnlosh, McKenzie, McLean, Mercer,
Morton. Mountrair. Nelson, OlIVer, Pierce. Ramsey, Ranville, Rolette.
Sheridan. Sioux, Stutsman. Towner. Ward. Wells and Williams
Ohio
Pickaway
Oklohoma
Delaware. McCurtain and Pushmataha
Otegon
Lake
SoutII Corollo.
AJkn, Barnwell. Beaufort. Berkley. Charleston, Colleton. Dorchester.
Georgetown. Hampton. Harty, Jasper and Marion
South OIIkoto
aay, Haakon, Hughs, Potier, Stanley, SUlly, Union, WaIwof1h, Yankton
and Ziebach
Ton
Bedford. B&ount. Claiborne. Decatur. Franklin. Hancock. Hardin.
HawIdns, Hickman, Knox, Lawrence, l.incxlIn, Loodon, Marshall, Maury,
r.4eigs, Monroe, Rhea, Roane, Scott, Sequalchie, Smith, Sullivan,
Trousdale and Wayne
T ....
Aransas, Austin, Bastrop. Burteson. Camet'on, Colorado, Comal. Fort
Bend, Goliad, Harris, Hays. Jeff Davis, Pecos. Reeves, Refugio and
VICtoria
IItoh
Lffah Rnd Wasihington
Virginia
lee, Russen, Soon, Smyth, Tazewen, Washington and Wise
Apply when peSls lirsl appear and repeal as required. May be applied
by ground or air. Observe days Interval between lasl application and
harvesl indicated by number In ( ) lollowing crop.
Michal<. (7): Michoke Plume Moth - Use 25 pounds per acre.
lINn. (7): Aphids, Whilelty, Lealhopper and Mexican Bean BeeUe -
Use 25 pounds per acre.
Broccofl ~), Bru."', Sprout. (7), Cobboge (7).. Coul (7),
Kohl.... : Aphids, Vege\abIe W_I, ArmywOrms, Diamondback MOth
Larvae, a Imported Cabt.ageworm - Use 1510 20 pounds per acre.
Climbing CulWorms, Cabbage Loopers - Use 25 POUnds per acre.
ConotII (15): Aphids, Vegelable Weevil and Pelrobla Mile - Use 25
poun<lo per acre. Do not use lrealed corrot lops lor lood or leed.
Celery: Aphido, Celery LeaHler, Climbing Cutworms - Use 20 to 25
pounds per acre. Le.lIloppers - Use 20 pound. per are. Do nol apply
within 21 days of harveol. Lea/miner, LOOpI<S, WhltllIies - Use 35
pounds per acre. Do not apply '·.ilhln 30 days of harvest.
. CoItord. (10), Kale (10), Muotord G_I (10): Aphids, Vegelable
Weevil, Gabbage Looper, Almyworms, CUmiling CvIwoons, Diamond·
back Molh Larvae, Imported Cabbagewonn -lfse 25 pounds per acre.
Com (12): Spider Miles- Use 25 pounds per acre. Do nol apply within
12 days of harvest.
Cucum ...... (15) .nd SqUOlh (15): Aphid, Climbing Cutworms, Cu·
cumber Beetle. Squash Bug, leafmlner. Thrips and Ffea BeeUe - Use
25 pounds per acre. Do not apply before vining on cucumbers.
Eggpl.nl (15): Aphid, Whilelly, and Lealminer - Use 25 pounds per
acre.
Grope. (14): Thrips, HopIi. Beetle, Grape teaNolder - Use 25 1033
pounds per acre. Grape Mealybug - Use 30 to 35 pounds per acre.
GrCMJnd application preferred.
Hop. (15): Aphids - Use 25 10 40 pounds per acre.
Lettuce (Heod 7, lMf 21): Aphids, Lealttoppers, Lealminer, Anny·
worms, Cabbage Looper, Imported Gabbagewonn - Use 25 pounds
per acre.
Melons (7): Aphids. leafhopper, Leafminer, Thrips, Petrobia MitE' tJnd
Cucumber Beelles - Use 2 pounds per acre.
Onion. (15): Lealminer, Thrips and Petrobla. Mile (Ca1ilomIa) - Use
25 pounds per acre.
Peochll, Nec1ort"": Oriental FruH Moth, European Red Mile, Two·
Spoiled SPider MHes and Brown MHe - Use 50 pounds per acre. Apply
by ground or air. Apply when insects are in damaging numbers. In
Caliromia: do not apply within 21 days of harvest. DO not apply mors
than once per bloom. Do nol appty more than 5 pounds actual parathion
per acre between January 1 aoo harvest. in areas other than California;
do nol apply within 14 days 01 harvest Do not apply marelhan 5 pounds
actual parathion per acre per year.
Pe .. (10): Aphid, Pea Weevil, Thrips, Climbing Cutworms, Almyworms
and Lealminer - Use 25 pounds per acre.
"-(15): Aphids - Use 1010 15 pounds per acre.
Pumpkins (19): Aphids, Cucumber BeeUe - Use 20 pounds per acre.
Climbing Cutworms and Squash Bugs - Use 25 pounds per acre.
Smou Grains (Borley. Oota. ) (15): Petrobla (Brown Wheal)
Mite, Black Grass Bug and Stinkbugs - Use 25 to 37 pounds per acre.
Aphids - Use 25 pounds per acre.
Splnoch (14): Aphids, Lealminer, Cabbage Looper, Arrnywonn, Crown
Mites (cali/omia only) - Use 25 pounds per acre .
Slrow (14): AIAlids, Lygus Bugs, Lealttoppers, Strawberry Leal·
roller and Whitefly - Use 25 pounds per acre.
Tomoloeo (10): Aphid, Loalminer - Use 25 pounds per acre. Russel
Mes and Stink Bugs - Use 121022 pounds per acre.
Dealers Should Sell In Original Packages Only.
Term. 01 Sole or Use: On purchase 01 Ihis producl buyer and user
agree 10 the loIlowing COO<Iilicns:
Wlrranty: FMC makes no warranty, expressed or Implied. concerning
Ihe use 01 Ihis product other !han Indicaled on the label. Excepl as so
warranted, the prodlact is sold as Is. Buyer and user assume all risk of
use and/or handling and/or storage of this material when such use and!
or handling and/or storage is contrary to label instructions.
Dlrectlon •• nd ___ Ion.: Follow diroc;;ons careluny. Timing
and method of appIation, weather and crop conditions, mixture with
Olher chemicals nol specifically recommended and o:her Influencing
lactors in lhe use 01 this product are beyond lha conlrol ollhe sener
and are assumed by the buyer al his own risk.
UN 01 Product: FMC's recommendations lor lha use 01 Ihls product
are based upon lesls believed 10 be reliable. The use 01 Ihis product
being beyond the conl~ 01 the manufacturer, no guarantee. expressed
or implied, is made as 10 lhe effects 01 such or the resuns 10 be obtained
if not used in accordance with directions or established sate practice.
Dlmagea: Buyer's Of user's exclusive remedy for damages for breach
of warranty or negligence shall be limited to direct damages not ex·
caoding lhe purchase price paid and shan nollnclude incidenlal or con·
sequential damages.
Phoskil and ..... -fMC Trademlr1tS 130060'"71