crop-chem-docs/corpus/epa_ppls/352-667.md

DUPONT STOUT (MP)

• EPA Reg No: 352-667
• Registrant: CORTEVA AGRISCIENCE, LLC
• Signal word: Caution
• Active ingredients: Thifensulfuron (5%); Nicosulfuron (67.5%)
• Label accepted: 2005-10-27
• Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/000352-00667-20051027.pdf

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U.S. ENVIRONMENTAL PROTECTION AGENCY Office of Pesticide Programs Registration Division (7505C) 1200 Pennsylvania Ave., N.W. Washington, D.C. 20460 NOTICE OF PESTICIDE: -X Registration _ Reregistration (under FIFRA, as amended) Name and Address of Registrant (include ZIP Code): E.!. DuPont de Nemours and Company DuPont Crop Protection Stine-Haskell Research Center P. O. Box 30 Newark, DE 19714 EPA Reg. Number: Date of Issuance: 352-667 OCT 'L7 'LCJJ3 Term of Issuance: Conditional I~ame of Pesticide P.-oduct: DuPont Stout (mp) Herbicide Note: Changes in labeling differing in substance from that accepted in connection with this registration must be submitted to and accepted by the Registration Division prior to use of the label in commerce. In any correspondence on this product always refer to the above EPA registration number. On the basis of infonnation furnished by the registrant. the above named pesticide is hereby registered/reregistered under the Federal Insecticide, Fungicide and Rodenticide Act. Registration is in no \vay to be construed as an endorsement or recommendation of thiS product by the Agency. In order to protect health and the environment. the AdmlOistrator, on his motion. may al any time suspe-nd or cancel the registnmon of a pesticide in accordance with the Act. The acceptance of any name in connection \;th the registration ofa product under this \ct is not to be construed as giving the registrant a right to exclUSive use oflhe name or 10 its use if it has been covered by others. This product is conditionally registered in accordance with FIFRA section 3(c)(7)(A) provided that you: I. Submit and/or cite all data required for registration/reregistration of your product when the Agency requires all registrants of similar products to submit such data. 2. Make the labeling changes listed belo before you release the product for shipment: Signature of Approving Official: U ~i4.Ld:: "'-kl.::c, jc v James A. Tompkins, Product Manager (25) Herbicide Branch, Registration Division (7505C) EPA Forn1 8570-6 Date:

Page 2 EPA Reg. No. 352-667 a. Add the phrase "EPA Registration No. 352-667" b. In the Limitation of Warranty and Liability, revise the second sentence of the third paragraph to read "To the extent permitted by law, when you buy or use this product, you agree to accept these risks. 4. Submit one (1) copy of your final printed label before you release the product for shipment. If these conditions are not complied with, the registration will be subject to cancellation in accordance with FIFRA section 6 (e). Your release for shipment of the product constitutes acceptance of these conditions. A stamped copy of the label is enclosed for your records. Enclosure

<[UPUN~ H- 3/6 DuPont™ Stout™ (mp) herbicide DRAFT LABEL , " .. ,. H ••••••••• A Growing Partnership With iVatu1:e" . ____________ ~ ____ -__ -~~ ___ .-- -'f"::_:";;"~ ". -'> ___ , •• ' ... '. "", •• ' ----

TABLE OF CONTENTS Directions for Use . ........................... 2 General Information .......................... 2 When to apply ............................. 2 Timing to crop ........................... 2 Timing to weeds .......................... 2 Rate .................................. .3 Weeds controlled ........................ .3 Spray adjuvants .......................... 3 Mixing instructions ...................... .4 When to apply - sequential applications ..... ; .. .4 Tank mix applications ...................... .4 Braadleaf weeds .......................... 4 Crabgrass .............................. .5 Additional information .................... .5 Tank mix compatibility testing ................ 6 Sequential DuPont™ ACCENT® applications .... 6 Cultivation ................................ 6 Environmental conditions and biological activity ..................... 6 Soil insecticide interactions . ................. . 7 Crap rotation .............................. 7 Application information ...................... 7 Ground application ........................ 7 Aerial application ......................... 8 Sprayer preparation and cleanout .............. 8 Spray drift management ...................... 8 Integrated Pest Management .................. 9 Resistance ................................ 9 Important precautions ......................... 9 Storage and Disposal .......................... 10 Warranty ................................... 11

c[UPON~ OCT 27 zro; DuPont™ Stout™ (mp) herbicide A unit pack product for use in Field Corn Active Ingredients Nicosulfuron 2-[[(4.6-dimethoxypyrimidin-2- yl)aminocarbonyllaminosulfonyll­ N.N-dimethvl-3-pyridinecarboxamide Thifensulfuron-methyl MethyI3-[[([(4-methoxy-6-methyl-I.3.5- triazin-2-yl) aminolcarbonyllaminol sulfonyI1-2-thiophenecarboxylate Inert Ingredients TOTAL EPA Reg. No. 352-XXX By Weight 67.5% 5.0% 27.5% 100.0% KEEP OUT OF REACH OF CHILDREN CAUTION FIRST AID IF IN EYES: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses. if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treaunent advice. IF ON SKIN OR CLOTHING: Take 6ff contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor for treatment advice. IF SWALLOWED: Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by the poison control center or doctor. Do not give anything by mouth to an unconscious person. Have the product container or label with you when calling a poison control center or doctor, or going for treatment. You may also contact 1-800-441-3637 for emergency medical treatment information. 1 PRECAUTIONARY STATEMENTS (cont'd) HAZARDS TO HUMANS AND DOMESTIC ANIMALS CAUTION! Causes moderate eye irritation. Harmful if absorbed through skin. Avoid contact with skin. eyes or clothing. PERSONAL PROTECTIVE EQUIPMENT Some materials that are chemical resistant to this product are listed below. If you want more options follow the instructions for Category A on the EPA chemical resistance category selection chart. Applicators and other handlers must wear: Long-sleeved shirt and long pants. Chemical Resistant Gloves Category A (such as butyl rubber. natural rubber. neoprene rubber. or nitrile rubber) 14 mls. Shoes plus socks. Follow manufacturer's instructions for cleaning/maintaining PPE. If no such instructions for washables. use detergent and hot water. Keep and wash PPE separately from other laundry. Engineering Control Statement: When applicators use enclosed cabs in a mannr that meets the requirements listed in the Worker Protection Standards (WPS) for agricultural pesticides [40 CFR 170.240(d)(4-6)1. the handler PPE requirements may be reduced or modified as specified in the WPS. Important: When reduced PPE is worn because a closed system is being used. handlers must be provided all PPE specified above for "Applicators and Other Handlers" and have such PPE immediately available for use in an emergency. such as a spill or equipment breakdown. USER SAFETY RECOMMENDATIONS USERS SHOULD: Wash hands before eating. drinking. chewing gum. using tobacco or using the toilet. Remove clothing immediately if pesticide gets inside. Then wash thoroughly and put on clean clothing. Remove PPE immediately after handling dlis product. Wash the outside of gloves before removing. As soon as possible. wash thoroughly and change into clean clothing. ENVIRONMENTAL HAZARDS Do not apply directly to water. to areas where surface water is present or to intertidal areas below the mean high water mark. Do not contaminate water when cleaning equipment or disposing of equipment rinsewater. Do not apply where/when conditions could favor runoff.

DIRECTIONS FOR USE It is a violation of federal law to use this product in a manner inconsistent with its labeling. Do not apply this product in a way that will contact workers or other persons, either directly or through drift. Only protected handlers may be in the area during application. For any requirements specific to your State or Tribe, consult the agency responsible for pesticide regulation. AGRICULTURAL USE REQUIREMENTS Use this product only in accordance with its labeling and with the Worker Protection Standard, 40 CFR part 170. This Standard contains requirements for the protection of agricultural workers on farms, forests, nurseries, and greenhouses, and handlers of agricultural pesticides. It contains requirements for training, decontamination, notification, and emergency assistance. It also contains specific instructions and exceptio!lS pertaining to the statements on this label about personal protective equipment (pPE) and restricted-entry interval. The requirements in this box only apply to uses of this product that are covered by the Worker Protection Standard. Do not enter or allow worker entry into treated areas during the restricted entry interval (REI) of 4 hours. PPE required for early entry to treated areas that is permitted under the Worker Protection Standard and that involves contact with anything that has been treated, such as plants, soil, or water, is: Coveralls. Chemical Resistant Gloves Category A (such as butyl rubber, natural rubber, neoprene rubber, a, nitrile rubber) .,14 mIs . . Shoes plus socks. DuPont™ STOUTTM (mp) herbicide should be used only in accordance with recommendations on this label or in supplemental DuPont publications. DuPont will not be responsible for losses or damage resui!ing from use of this product in any manner not specifically recommended by DuPont. GENERAL INFORMATION STOUTTM .(mp) herbicide is a convenient unit pack that is used at the rate of 112 - 3/4 ounce per acre for selective postemergence grass and broadleaf weed control in field com. Open package completely and empty contents of both compartments into spray tank. Do not apply to field com grown for seed, to popcorn or to sweet com. Do not make more than one application of STOUTTM (mp) per cropping season. Do not apply aerially in California or New York State. 2 CORN HYBRID INFORMATION Apply STOUTTM (mp) to field com hybrids with a relative maturity (RM) rating of 88 days or more, including "food grade" (yellow dent, hard endosperm), waxy and oil com. Not all field com hybrids ofless than 88 days RM, not all white com hybrids nor Hi-Lysine hybrids have been tested for crop safety, nor does DuPont have access to all seed company data. Consequently, injury arising from the use of STOUTTM (mp) on these types of com is the responsibility of the user. Consult with your seed supplier before applying STOUTTM (mp) to any of these com types. Seed company publications indicate "Warning", "Crop Response Warning". or "Sensitive" notations for the use of some ALS herbicides on com hybrids of 88 CRM or higher, As noted in the seed company pUblications, DuPont sulfonylurea herbicides such as STOUTTM (mp) should be used with caution on these hybrids. Consult with your local DuPont representative or the DuPont Label Web Site (http://cropprotection.dupont.coml) for any additional supplemental labeling information relative to potential com hybrid sensitivity to STOUTTM (mp). WHEN TO APPLY TIMING TO CROP STAGE ,·;t ;"11 ;CflW/) !jIh1>1 ~~~:h:r!) fi!) wtfrnn.m nrp® "ila:l !te i°J.' ".;qim)JttiJ IJij) l® 8Iili1 !J:i:&f~~ ~ . tC1:0l li[Cll urr-hy ft) 1£1.eJ]f!l P.jlliffilim G:?{o:rr-@1jl1mft..:@' jiB": • t",it ('ro1ljil-', 'liffil !1I.!ill91ill!!1 :§lffij)~l ",,,,,'rW").ikmHj, (®? i~~). :ifujl dilJ r\QXcJ1'iffi(ffi!j) r!=Ji1 'fm.sirSr~~ 'tiu'/ )Ii? f'~~B.'j:[o) (t{cfO].:fllil!® lf!im.ll f :cli to{'M~~(mh' :."r· 0'-.:116 (gaJfb'l!lli !.:<lCiJ( !:;gPJ1.i,.tL.i'(tlr9J~~ it,n '.IMlil[}fi§J]li]l!t,m . \'/b1t-:, "';rCrL"f(l'iUICiiP~) l!g~ tl~ .@., f.~~imJ-~~~· .i(f!;.JJ(ti" iJ®,{tW''fI, 'l""il 00l[,1li;. ... 00 (cl%m ,imrIi.,H!\o)®(;l"f,-'";@9G!['i-liJr~~~i':Ai9D~(· z.1i1 \'k!:'1 tffi9 r:r.i~-'Jh, L~ flli:·· •. , Jilill: [lJ!" (Ell! !loli l.i.jift' . Limit STOUTTM(mp) applications to com that is up to 12" tall, up to anti including 5 leaf collars, whichever is most restrictive. in the,states ofKS, OK and TX. TIMING TO WEEDS Apply STOUTTM (mp) when grasses are young and actively growing, but before they exceed the sizes list"d on this label. • Applications made to weeds at growth stages greater than those listed below may result in incomplete control. Grass competition due to incomplete control may reduce yields.

RATE DuPont™ STOUT'" (mp) is a unit pack product which will treat up to 15 acres of com as a broadcast application. Refer to the following table for the number of acres treated by each 7.5 ounce container of STOlJTTM (mp) when used at 0.5 ot 0.75 ounces per acre. 7.5 oz bags of STOUTTM (mp) I use rate· ounces per acre 0.5 0.75 15 acres 10 acres 2 30 acres 20 acres 3 45 acres 30 acres Apply STOlJTTM (mp) at a rate of 112 • 3/4 ounce per acre for season-long control of grass and broadleaf weeds listed below. Table 1. Weeds controlled with STOlJTTM (mp) Grasses Bamyardgrass Broadleaf signalgrass Foxtails (bristly. giant. green, yellow) ltchgrass Jobnsongrass seedling rhizome Panicum (Texas. brownlOp. fall) Quackgrass· Ryegrass (Italian. perennial) Sandbur (field.longspine)* Sbattercane Sorghum almum Timothy Maximum Height or Diameter 1I2oz 3/4oz 2" 4" 2" 2" 4" 3" 6" 6" 12" 6" 18" 2" 3" 10" 6" I" 3" 6" 12" 6" 12" 3" 6" Volunteer cereals (barlev. oats. rYe, triticale, wheat) 2" 6-·· Wild oats 2" 4" Wild prosQ millet 2" 4" Wtrestem muhly· 8" Witch!ZI3SS 3" 6" Woolly Cupgrass· 4"· • Requires the use of coe plus anunonium nitrogen fertilizer. Cultivation or re-treatment may be required. See "FOR ADDITIONAL CONTROL OF LATER EMERGING GRASSES" •• 10 inches in the states ofWA, OR. 10, and MT. where the use ofMSO adjuvants are preferred. See SPRAY ADJUVANTS. Broadleaves Burcucumber Dandelion Hemp dogbane· Jimsonweed bsguane.conunon Momingglo!), (ivvleaf. pitted) tall Pigweed Credroot. smooth) Pokeweed· Smartweeds (lad .... sthumb, PA) Thistle. Canada· Velvetleaf *suppression Maximum Height or Diameter 3/40z 3" 6" 4" 3" 4" 3" 2" 4" 4" 4" 4" 4" 3 As weeds mature, their sensitivity to STOUT'" (mp) decreases, Grassy weeds growing under stress due to drought or other environmental factors may become mature (more than 3 tillers) before they reach the size listed, in which case their susceptibility to STOUTTM (mp) may be reduced. SPRAY ADJUVANTS Applications of STOlJTTM (mp) must include either a crop oil concentrate or a nonionic surfactant. In addition, an ammonium nitrogen fertilizer must be used unless specif­ ically prohibited by tank mix partner labeling. Crop oil concentrate plus ammonium nitrogen fertilizer is the preferred adjuvant system for STOUTTM (mp). Consult local DuPont fact sheets, technical bulletins, and service policies prior to using other adjuvant systems, If another herbicide is tank mixed with STOlJTTM (mp), select adjuvants authorized for use with both products. Products must contain only EPA-exempt ingredients (40 CFR 100 I). Petroleum Crop Oil Concentrate (COC) or Modified Seed Oil (MSO) • Apply at 1% v/v (I gallon per 100 gallons spray solution) or 2% under arid conditions. • MSO adjuvants may be used at 0.5% v/v (0.5 gallon per 100 gallons spray solution) if specifically noted on adjuvant product labeling. • Oil adjuvants must contain at least 80% high quality, petroleum (mineral) or modified vegetable s"ed oil with at least 15% surfactant emulsifiers, Nonionic Surfactant (NIS) • Apply at 0.25% v/v (I quart per 100 gallons spray solution) or 0.5% under arid conditions. • Surfactant products must contain at least 60% nonionic surfactant with a hydrophilic/lipophilic balance (HLB) greater than 12. Ammonium NiJrogen Fertilizer • Use 2 quarts/acre of a highpquality urea ammonium nitrate (UAN). such as 28%N or 32%N, or 2 pounds/acre of a spray-grade ammonium sulfate (AMS), Use 4 quarts/acre VAN or 4 pounds/acre AMS under arid conditions. • Do not use liquid nitrogen fertilizer as the total carrier solution. Special Adjuvant Types • Combination adjuvant products may be used at doses that provide the required amount of NIS, COC. MSO andlor ammonium nitrogen fertilizer. Consult product literature for use rates and restrictions. In addition to the adjuvants specified above. other adjuvant types may be used if they provide the same functionality and have been evaluated and approved by DuPont Product Management. Consult separate DuPont technical bulletins for detailed information before using adjuvant types not specified on this label.

MIXING INSTRUCTIONS

1. Fill the tank 1/4 to 1/3 full of water.
2. While agitating. add the required amount of DuPont™ STOlJ'TTM (mp).
3. Continue agitation until the STOlJ'TTM (mp) is fully dispersed. at least 5 minutes.
4. Once the STOlJ'TTM (mp) is fully dispersed, maintain agitation and continue filling tank with water. Thoroughly mix STOlJ'TTM (mp) with water before adding any other material.
5. As the tank is filling, add the required spray adjuvants (crop oil concentrate, nonionic surfactant, or ammonium nitrogen fertilizer). 6.If the mixture is not continuously agitated, settling will occur. If settling occurs, thoroughly re-agitate before using.
6. Apply STOUTTM (mp) spray mixture within 24 hours of mixing to avoid product degradation. S.If STOUTTM (mp) and a tank mix partner are to be applied in multiple loads, pre-slurry the STOUTTM (mp) in clean water prior to adding to the tank. This will prevent the tank mix partner from interfering with the dissolution of the STOUTTM (mp). WHEN TO APPLY - SEQUENTIAL APPLICATIONS FOLLOWING REDUCED RATES OF PREEMERGENCE HERBICIDES STOlJ'TTM (mp) may be used as a sequential application in a planned postemergence weed control prognim in com following a reduced rate of a preemergence herbicide. Apply a reduced rate of a preemergence herbicide prior to com emergence and then follow with a postemergence application of STOlJTl'M (mp). Apply products such as DuPont™ CINCH®, "Balance" PRO. "Axiom", ''Dual'' II Magnum, "Swpass". "Frontier" and "Hamess" Xtra at as low as 114 to 112 of the full labeled use rate and follow with a sequential postemergence applicationof ST01JTT" (mp). Refer to WHEN TO APPLY­ POSTEMERGENCE and ENVIRONMENTAL CONDmONS AND BI01.0GICAL ACTIVITY sections for complete application information and precautions. Refer to the preemergence herbicide label for use restrictions, application information, rotational crop guidelines, and cautionary statements prior to applying STOlJTTM(m'p). " Do not apply STOlJTTM (mp) to com that ei<ltibits herbicide injury from previous applications made to the current or preceding crop. TANK MIX APPLICATIONS Application of STOlJTT" (nip) tqnk n¥tU,::es."J1\ilining·· atrazine andlor dicamba (in soni.I:i(ei)liteIjfui~O'tD com that is up to 12" tall, up to and il\t'liITng'frt[f colhm, ' whichever is most restrictive. See TANK MIXTURES WITH "DISTINCT" OR DICAMBA for additional information. Refer to the table below for weeds controlled using preferred tank mixtures. 4 For Additional Control of BroadleafWeeds STOlJTTM (mp) may be tank mixed with the herbicides below for additional control of broadleaf weeds. See the tank mix partner label for weeds controlled, precautions, use restrictions and crop rotation information. Crop oil concentrate must be used in the tank mixtures specified below. The use of nonionic surfactant is permitted in place of crop oil concentrate for tank mixtures containing dicamba, however, overall weed control may be reduced. See SPRAY ADJUVANTS for adjuvant rate recommendations. fu!dul:I Bal<lA. atrazine 90DF up to 35 ounces ''Callisto'' 1.5 - 3.0 fluid ounces "Homet"WDG 2.0 - 3.0 ounces Rates listed are for the specific products noted in the table. If other brands or formulations are used, rates of active ingredients should be adjusted to correspond to the products indicated. Formulations of products other than those listed may not have been tested with STOlJTTM (mp). Check with the manufacturer for information on tank mix compatibility prior to using (see TANK MIX COMPATIBILITY TESTING). ADDITIONAL RECOMMENDATIONS AND/OR RECOMMENDATIONS FOR SPECIFfC WEED PROBLEMS Tank Mixtures with Atrazine STOlJTTM (mp) may be tank mixed with 114 - 2 pounds a.i. atrazine for additional control of many broadleaf weeds, including: Species Maximum weed beight or diameter Sicklepod 2 inches Prickly sida 2 inches Wild Radish 12 inches Cutleaf evening primrose 6 inches Florida pusley 2 inches *Forbesr(~ltS aad 0.25·2.0 quarts atrazine 4LOR 4 - 35 ounces atrazine 90DF. Products containing atrazine are restricted use products. STOlJTTM (mp) + atrazine tank mix may result in reduced control of grasses (antagonism) if applied to grasses under low moistute stress or to grasses exceeding the maximum labeled height Before applying STOlJTl'M (mp) + atrazine tank mix, refer to the wazine product label for information regarding the maximum'iimount of atrazine that may be applied in a season.

Tank Mixtures wiJh "Callisto" DuPont™ STO{}TTM (mp) may be tank mixed with 1.5 - 3.0 fluid ounce,sfacre of "Callisto" herbicide for weed control as indicated in the table below: Maximum Weed Height (in inches) "CallisIa" aloDe ':!;ajlislo" ± atrazicc'" Scies 1.50z 2.00z 3.00z 1.5.1)z; ... 2.0 oz 3.00z . Cocklebur 4" 4" 4" .10" 10" 10" Dandelion 10" lO" 10" .10" 10" 10" Jimsonweed 4" 4" 4" 4" 10" 10" Kochia 4" 4" 4" Lambsquarters, common 4" 4" 4" 10" 10" to" Morningglory annual 4" 4" 4" 4" 4" 4" Nightshade, (black. eastern black) 4" 4" 4" 10" 10" 10" Palmer amaranth (eieed) 4" 4" 4" 4" Pigweed, redrool 4" 4" 4" 10" 10" 10" Ragweed, common 4" 10" 10" Ragweed, mant 3" 4" 4" 10" 10" Srnartweed, ladxsthurnb 4" 4" 4" 10" 10" Srnartweed, Penns~]vania 4" 4" 4" 4" 10" 10" Sunflower, common 4" 4" 4" 4" A" 10" Velvetleaf 4" 4" 4" 10" 10" 10" Walerhernp, tall & cominon - 4" 4" 4" 10" 10" ·Plus 0.25 10 0.75 pound ai. atrnzine per acre, may provide better control when weeds are at maximum height. For improved grass and broadleaf weed control, STOUfTM (MP) tank mixtures with 1.5 ounces "Callisto" (with or without atrazine) may be applied with 0.5 % vlv />4S0 spray adjuvant Tank Mixt!,m wiJh "Distinct"", STOUT'M (mp) may be =~~~~,;;::, dicamba (e!g. up to 4 fluid of "Distinct") for additional contrQl ofiiJa!"ybroa<dle<tf In situation,s where the use of croll -oil growth regulator herbicides is not desiraple(e'g', cold weather), STOlfrr:- (mp) may be]:!!1tiDixwjth 2 ounces "Distinct" + a nonionic surfactantarO.2~%v/v (1 quart/I 00 gallons spray solution) in place <if crop oil c.oncentrate, but overall weed control may beTedUCied" Tank mixture applications of STOUfTM (0) with herbicides containing dicamba (e.g. 1-2 ounces "Distincf' and 4 fluid ounces "Clarity") should be limited to com that is up to 12" tall, up to and including 5 leaf collars, whicheveiis most restrictive, except for the states east of the line formed by the western .".;;- -<- 5

• • ,-----,--,--,--,--,------ - bonders ofM!, IN, KY, TN, and MS, and except where noted in local DUPont Technical Bulletins. ~1!1ttr.t:ti"lC}fl) oH''))Clff'-&t1Iml)?~iiG lh"lt,.", 0' 'J'" 1M, ';::'l.fiffilll !iil'K'" 81JtLtlten') Ite) )G®lf!:Em4f' (E!1J®.! :1.-;.',," I,,"),',' jf <!!1L@(0Iillllill A com planfs p!edisposition to develop fused tissue emerging from the whorl (rattail) after the V-II stage may increase when a product containing dicamba (i.e. ''Clarity'', "Marksman") is applied to small cpm under early stressful conditions. Be aware of this when applying tank mixes, with dicamba to small com under stressful conditions. See ENVIRONMENTAL CONDmONS for a description of these stressful conditions. For Additional Control of Crabgrass and Later Emerging Grasses STOUfTM (mp) may be tank mixed with full or reduced rates of preemergence gtilss herbicides labeled for early postemergence application to field com (such as DuPont™ CINCH®, "Prowl", "Surpass" EC, ''Dual'' IT Magnum, and "Outlook',) for increased residual activity of later -emerging flushes of grasses such as smooth and large crabgrass. Application must be made before the crabgrass emerges and before other grass weeds on the STOUfTM (mp) label exceed their labeled sizes. Tank mixes of STOUfTM (mp) and preemergence grass herbicides must be broadcast applied postemergence to field

com before the crop exceeds the heights listed on the preemergence grass herbicide label. Refer to WHEN TO APPLY-POSTEMERGENCE and the preemergence grass herbicide label for complete postemergence application information, rates. and restrictions. For Additional Control of Kochia DuPont™ STOlJTTM (mp) may be tank mixed with 1/3 to 213 pint per acre of "Starane" for improVed control of kochia. Use higher rates when weed infestation is heavy. Refer to the specific "Starane" label for application timing and restrictions. Tank Mixtures with Insecticides STOUTTM (mp) may be tank mixed with pyrethroid or carbamate insecticides such as DuPont™ ASANA® XL or DuPont™ LANNAlE® insecticides. General 7lmk Mixture Information '1!li!J.'.(.Jl!lb_J'lil?;1)lll.l~{(~; 1WillJ;&fMtom@]',~ '.i;1 ti1® ill9 i1lJljl.fi1!ili:l.inr{!f~(WJjt} , .' j ill:')fol.'lJ \ll1.il1"ifi;l !;"li.:r®!t!..>Iilli "IDI''RT!ji'Jif t.J.il!l ",. :ttlMillto:tP):~~~-i'ill!f/(O~~ '', [P.l:')'R'lHl>.,f;l.'\o()I\(\fIJ"iD)«oTI.L.L·r r~~fill. __ 1ID(·l@~~'-:I;'; jP.ro'Wl~~~\l111lJlt.J (I !lll.f' !1."!..!J1". to iih14Lro I,."d-"'··"'!l. ,,. ,'., , '@.i.!l1)': ". .. ' .., , .. "',' ,"',-, .... : .. .. .. " _ .. - .. ·.'.:"·f'" f . 9 .mr.(J;:!¥)WA1fil@1ll&1'::; },~~~~IffiJG~'IiB,~ =:@W1l)!".,';~VJ Other than the exceptions noted, and in addition to the tank mix partners and rates indicated above, STOUTTM (mp) may be tank mixed or followed with sequential applications of other products registered for use in field com. STOUTTM (mp) may be applied in tank mix combinations with full or reduced rates of other products provided: The tank mix product is labeled for the same timing, method of application, adjuvants, and use restrictions as STOUTTM (mp). • The tank mixture is not specifically prohibited on the label of the tank mix product. • The tank mix combination is compatible as detennined by a "jar tesf' described in the TANK MIX COMPATIBILITY TESTING section below. Tank Mixing Precautions: • Weed control and crop response with tank mixtures not specifically recommended in'this label are the responsibility of the user and manufacturer of the tank mix product. • Read and follow all applicable use directions, precautions, and limitations specified on the respective product labels and fact sheets. Do not exceed labeled application rates. Do not tank mix STOlJTTM (mp) with other products that contain the same active ingredient as STOlJ[TM (mp) (rimsulfuron) unless the 6 label of either tank mix partner specifies the maximum rate that may be used. TANK MIX COMPATIBILITY TESTING Perform a jar test prior to tank mixing to ensure compatibility of STOUTTM (mp) and other pesticides. Use a clear glass quart jar with lid and mix the tank mix ingredients in their relative proportions. Invert the jar containing the mixture several times and observe the mixture for approximately 112 hour. If the mixture balls-up, forms flakes, sludges, gels, oily film or layers, or other precipitates, it is not compatible and the tank mix combination should not be used. SEQUENTIAL DUPONpM ACCENT® APPLICATIONS Apply ACCENT® herbicide 14 or more days after STOlJ[TM (mp) applications to control grasses that may emerge later in the season. Refer to the ACCENT® label for grass species controlled, proper size of weeds, rates, com sizes, and other information. Wben following a STOlJTTM (mp) application, do not use more than 213 ounce ACCENT® per acre. CULTIVATION A timely cultivation may be necessary to control suppressed weeds, or weeds that emerge after an application of STOl)TTh1 (mp) in the absence of an activating rainfall. Optimum timing for cultivation is 7-14 days after STOUTTM (mp) application or upon seeing the establishment of new weeds. ENVIRONMENTAL CONDITIONS AND BIOLOGICAL ACTIVITY STOlJTTM (mp) provides best results when applied to young. actively growing weeds. Applications made during warm, moist conditions (70'F or more) and adequate soil moisture both before and after application maximizes performance. The degree and duration of control depend on spray coverage, weed spectrum, weed size, growing conditions before and after treatment, soil moisture, and adjuvant selection. STOUTTM (mp) is rainfast in 4 hours. Treating weeds that exceed maximum label heigllt or that are under stress may result in incomplete control. Poor weed control or crop injury may result from applications made to plants under stress from: • abnormally hot or cold weather • environmental conditions such as drought. water-saturated soils, hail damage, or frost disease, insect, or nematode injury • prior herbicide, or carryover from a previous year's herbicide application

Stress from conditions immediately following application may also result in crop injury or poor weed control. Stress affects all weeds, but especially weeds such as woolly cupgrass, green and yellow foxtail, and wild proso millet If the com or grass weeds are under stress, delay application until stress passes and both weeds and com resume active growth. Apply DuPont™ STO{)TfM (mp) when minimum nighttime temperatures are above 4O'F and the maximum daytime temper­ atures are below 92'F to maximize performance and minimize the potential for crop injury. Applications made during or immediately following periods of large day/night temperature fluctuations or where daytime temperatures do not exceed 50'F may decrease weed control and increase the potential for crop injury. STO{)TfM (mp) rapidly inhibits the growth of susceptible weeds, reducing weed competition within as little as 6 hours after application. Susceptible plants are controlled in 7-21 days. Ground application of STO{)TfM (mp) to dry, dusty fields may reduce weed control in wheel track areas. SOIL INSECTICIDE INTERACTION INFORMATION STO{)TfM (mp) may interact with certain insecticides previously applied to the crop. Crop response varies with field com type, insecticide used, insecticide application method, and soil type. STO{)TfM (mp) may be applied to com previously trealed with "Fortress", "Aztec", or ''Force'' insecticides or non· organophosphate (OP) soil insecticides regardless of soil type. -DO NOT APPLY STOUT'M (mp) to com previously treated with "Counter" 15G or to com treated with "Counter" 20CR infurrow or over the row at cultivation. -Applications of STO{)TfM (mp) to com previously treated with "Counter" 20 CR, "Lorsban", or "Thimet" may cause unacceptable crop injury, especially on soils of less than 4% organic matter. CROP ROTATION Rotational crops vary in their response to low conc~trations of STO{)TfM (mp) remaining in the soil. STOlJTTM (mp) dissipates rapidly in warm, acidic, microbiologically active soils. The amount of STOUT'M (mp) which may be present in the soil depends on soil pH and organic matter content, elapsed time since application, crop production practices, and environmental factors. Injury to rotational crops may occur in high-pH, cold soils if dry weather prevails between application and rotational crop planting. For fields treated with sequential applications of STO{)TfM (mp) and DuPont™ ACCENT® herbicide, consult the crop rotation intervals listed on the ACCENT® and STO{)TfM (mp) labels. Use the most restrictive recrop interval from either label. 7 The following rotational intervals must be observed when using STO{)TfM (mp): STOlJTTM (MP) ROTATIONAL CROP GUIDELINE Crop Rotational Interval in Months Com (field, seed) Anytime Com (pop, sweet) 10** Soybeans 0.5 (15 days) Cereals, winter (barley. oats, rye, wheat) 4 Cereals, spring (barley. oats, rye, wheat) 8 Alfalfa1I. 10 Canola" 10 Conon 10 Dry Beans, Peas, Snap Beans 10 Potato" 10 Sunflower 10 Red Clover" 10 Sorghum"" 10 SugarbeetsAM. 10 Sunflower" 10 Other Crops not listed 18

• On sprinlder irrigated fields in Idaho, Utah, and Northern Nevada it is best to use deep fall tillage such as plowing prior to planting alfalfa. Product degradation may be less on furrow irrigated soils and may result in some crop injury. --Except the sweet com varieties "Merit", ''Carnival'', and "Sweet Success", for which the minimwn time interval is 15 months. 1\ Rotational interVals shouJd be extended to 12 months if Crought conditions prevail after application and before the rotational crop is planted. unless sprinkler irrigation has been applied and totals greater than 15" during the growing season. AA With composite soil pH >7.5 extend the rotation interval to 18 months except in Texas and Oklahoma east of Highway 281, where the rotational interval is 10 months. rega.n!!ess of pH. AMFor soils with composite pH > 6.5 the rotational interval is 18 months except on irrigated sites in Colorado, Wyoming, Nebrnska, Texas, Michigan. and Ohio, where precipitation following application must exceed 2Y' prior to planting beets. where the interval is 10 months on soils with pH < 7.5. In North Dakota and nonhwest Minnesota. the cumuJative precipitation in the 18 months following application to soils >pH 6.5 must exceed 28~ in order to rotate to sugarbeets. APPLICATION INFORMATION Many crops are highly sensitive to STOUTTM (mp). All direct or indirect contact (such as spray drift) with crops other than field corn should be avoided (see also SPRAY DRIFf MANAGEMENT). For all application systems. use 50-mesh or larger strainer screens. Do not apply STOUT£M (mp) through any type of irrigation system. GROUND APPLICATION Broadcast Application Use a minimum of 15 gallons of water per acre (GPA) to ensure thorough coverage of the weeds and the best performance. Use a minimum of 10 GPA for light, scattered stands of weeds. For best performance, select nozzles and pressure that deliver MEDIUM spray droplets, as indicated, for example, by ASAE Standard S572. Nozzles that deliver COARSE spray droplets may be used to reduce drift, provided spray volume is increased to maintain coverage on smalI weeds. For optimal product performance and minimal spray drift, adjust the spray boom to the lowest possible spray height recommended in manufacturers' specifications. Ensure that equipment is set up to avoid applying an excessive rate directly over the rows and into the com plant

whorl. Overlaps or starting, stopping, slowing, and turning while spraying may result in crop injury. Band Application For band applications, use proportionately less spray mixture. To avoid crop injury, carefully calibrate the band applicator to not exceed the labeled rate. Carefully follow the manufacturer's instructions for nozzle type (flat fans), orientation, distance of nozzles from the crop and weeds, spray volumes, calibration and spray pressure. AERIAL APPLICATION Aerial application is not permitted in the States of New York and California. Use nozzle types and arrangements that will provide optimum spray distribution and maximum coverage at a minimum of 3 GPA. Do not apply during a temperature inversion, when winds are gusty, or when conditions favor poor coverage andlor off-target spray movement. SPRAYER PREPARATION/CLEANUP It is important that spray equipment is clean and free of previous pesticide deposits before using DuPont™ STOUTTM (mp) and then properly cleaned oui following application. Clean all application equipment before applying STOUTTM (mp). Follow the cleanup procedures specified on the label of the product previously sprayed. If no cleanup procedure is provided, use the procedure that follows. Immediately following applications of STOUTTM (mp), thoroughly clean all mixing and spray equipment to avoid subsequent crop injury. Note: • When cleaning spray equipment before applying STOUTTM (mp), read and follow label directions for proper rinsate disposal of the product previously sprayed. • Steam cleaning of aerial spray tanks will help to dislodge any visible pesticide deposits. When spraying or mixing equipment will be used over an extended period to apply multiple loads of STOUTTM (mp), partially fill the tank with fresh water at the end of each day of spraying, flush the boom and hoses, and allow to sit overnight Cleanup Procedure

1. Drain the tank and thoroughly hose down the interior surfaces. Flush the tank, hoses, and boom willi clean water for a minimum of 5 min.
2. Partially fill the tank with clean water and add one gallon of household ammonia' (containing 3% active) for every 100 gallons of water. Finish filling the tank with water, then flush the cleaning solution through the hoses, boom, and nozzles. Add more water to completely fill the tank and allow to agitate/recirculate for at least 15 min. Again, flush the hoses, boom, and nozzles with the cleaning solution, then drain the tank.
3. Repeat Step 2.
4. Remove the nozzles and screens and clean separately in a bucket containing the cleaning agent and water. 8
5. Thoroughly rinse the tank with clean water for a minimum of 5 min, flushing the water through the hoses and boom. • Equivalent amounts of an alternate strength ammonia solution or a tank cleaner recommended in the DuPont bulletin "Sulfonylurea Herbicides, A Guide to Equipment CJeanout, .. may be used. SPRAY DRIFT MANAGEMENT The interaction of many equipment and weather-related factors determines the potential for spray drift. The applicator is responsible for considering all these factors when making application decisions. AVOIDING SPRAY DRIFT IS THE RESPONSIBILITY OF THE APPUCATOR. IMPORTANCE OF DROPLET SIZE The most effective way to reduce drift potential is to apply large droplets (>150 - 200 microns). The best drift management strategy is to apply the largest droplets that provide sufficient coverage and control. The presence of sensitive species nearby, the environmental conditions, and pest pressure may affect how an applicator balances drift control and coverage. APPLYING LARGER DROPlETS REDUCES DRIFT POTENTIAL, BUT WILL NOT PREVENT DRIFT IF APPLICATIONS ARE MADE IMPROPERLY OR UNDER UNFAVORABLE ENVIRON­ MENTAL CONDmONS! See Wind, Temperature and Humidity, and-Temperature Inversions sections of this label. Controlling Droplet Size - General Techniques • Volume - Use high flow rate nozzles to apply the highest practical spray volume. Nozzles with higher rated flows produce larger droplets. • Pressure - Use the lower spray pressures recommended for the nozzle. Higher pressure reduces droplet size and does not improve canopy penetration. WHEN HIGHER FLOW RATES ARE NEEDED, USE A HIGHER­ CAPACITY NOZZLE INSTEAD OF INCREASING PRESSURE. • Nozzle Type - Use a nozzle type that is designed for the intended application. With most nozzle types, narrower spray angles produce larger droplets. Consider using low­ drift nozzles. Controlling Droplet Size - Aircraft • Number of Nozzles - Use the minimum number of nozzles with the highest flow rate that provide uniform coverage. • Nozzle Orientation - Orienting nozzles so that the spray is emitted backwards, parallel to the airstream will produce larger droplets than other orientations. • Nozzle Type - Solid stream nozzles (such as disc and core with swirl plate removed) oriented straight back produce larger droplets than other nozzle types. • Boom Length - The boom length should not exceed 3/4 of the wing or rotor length - longer booms increase drift potential. • Application Height - Application more than 10 ft above the canopy increases the potential for spray drift.

BOOM HEIGHT Setting the boom at the lowest labeled height (if specified) which provides uniform coverage reduces the exposure of droplets to evaporation and wind. For ground equipment. the boom should remain level with the crop and have minimal bounce. WIND Drift potential increases at wind speeds of less than 3 mph (due to inversion potential) or more than 10 mph. However. many factors. including droplet size and equipment type determine drift potential at any given wind speed. AVOID GUSTY OR WINDLESS CONDITIONS. Note: Local terrain can influence wind patterns. Every applicator should be familiar with local wind patterns and how they affect spray drift. TEMPERATURE AND HUMIDITY When making applications in hot and dry conditions. set up equipment to produce larger droplets to reduce effects of evaporation. TEMPERATURE INVERSIONS Drift potential is high during a temperature inversion. Temperature inversions restrict vertical air mixing, which causes small suspended droplets to remain close to the ground and move laterally in a concentrated cloud, Temperature inversions are characterized by increasing temperature with altitude and are common on nights with limited cloud cover and light to nO wind. They begin to form as the sun sets and often continue into the morning. Their presence can be indicated by ground fog; however, if fog is not present. inversions can also be identified by the movement of smoke from a ground source or an aircraft smoke generator. Smoke that layers and moves laterally in a concentrated cloud (under low wind conditions) indicates an inversion. while smoke that moves upward and rapidly dissipates indicates good vertical air mixing. SHIELDED SPRAYERS Shielding the boom or individual nozzles can reduce the effects of wind. However, it is the responsibility of the applicator to verify that the shields are preventing drift and not interfering with uniform deposition of the product. INTEGRATED PEST MANAGEMENT This product may be used as part of an Integrated Pest Management (!PM) program that can include biological. cultural. and genetic practices aimed at preventing economic pest damage. !PM principles and practices include field scouting or other detection methods. correct target pest identification. population monitoring. and treating when target pest popUlations reach locally determined action thresholds. Consult your state cooperative extension service, professional consultants or other qualified authorities to determine appropriate action treatment threshold levels for treating specific pest/crop systems in your area. 9 RESISTANCE When herbicides that affect the same biological site of action are used repeatedly over several years to control the same weed species in the same field. naturally-occurring resistant biotypes may survive a correctly applied herbicide treatment. propagate. and become dominant in that field. Adequate control of these resistant weed biotypes cannot be expected. If weed control is unsatisfactory. it may be necessary to retreat the problem area using a product affecting a different site of action. To better manage herbicide resistance through delaying the proliferation and possible dominance of herbicide resistant weed biotypes. it may be necessary to change cultural practices within and between crop seasons such as using a combination of tillage, retreatment. tank-mix partners andlor sequential herbicide applications that have a different site of action. Weed escapes that are allowed to go to seed will promote the spread of resistant biotypes. It is advisable to keep accurate records of pesticides applied to individual fields to help obtain information on the spread and dispersal of resistant biotypes. Consult your agricultural dealer. consultant. applicator. andlor appropriate state agricultural extension service representative for specific alternative cultural practices or herbicide recommendations available in your area. IMPORTANT-PRECAUTIONS Injury to or loss of desirable vegetation may result from failure to observe the following: • Do not apply DuPont™ STOUTTM (mp) or drain or flush application equipment on or near desirable trees or other plants. or on areas where their roots extend. or in locations where the chemical may be washed or moved into contact with their roots. • Do not use on lawns. walks. driveways. tennis courts. or similar areas. • Prevent drift of spray to desirable plants. • Do not contaminate any body of water. • Thoroughly clean application equipment immediately after use. (See the Sprayer Cleanup section of this label for instructions.) • Do not graze or feed forage. hay. or straw from treated areas to livestock within 30 days of STOUTTM (mp) application.

( STORAGE AND DISPOSAL Pesticide Storage: Store product in original container only. Do not contaminate water, other pesticides, fertilizer, food or feed in storage. Store in a cool, dry place. Pesticide Disposal: Do not contaminate water, food, or feed by disposal. Waste resulting from the use of this product may be disposed of on site or at an approved waste disposal facility. Container Disposal: For Plastic Containers: Triple rinse (or equivalent) the container. Then offer for recycling or reconditioning, or puncture and dispose of in a sanitary landfill, or by incineration, or, if allowed by state and local authorities, by burning. If burned, stay out of smoke. For Fiber Sacks: Completely empty fiber sack by shaking and tapping sides and bottom to loosen clinging particles. Empty residue into application equipment. Dispose of bags at an approved waste disposal facility, in accordance with Federal, state and local regulations. For Fiber Drums With Liners: Completely empty liner by shaking and tapping sides and bottom to loosen clinging particles. Empty residue into application equipment. Then dispose of liner in a sanitary landfill or by incineration if allowed by state and local authorities. If drum is contaminated and cannot be reused, dispose of in the same manner. For Bags Containing Water Soluble Packets: Do not reuse the outer box or the resealable plastic bag. When all water-soluble packets are used, the outer packaging should be clean and may be disposed of in a sanitary landfill or by incineration, or if allowed by state and local authorities, by open burning. If burned, stay out of smoke. If the resealable plastic bag contacts the formulated product in any way, the bag must be triple-rinsed with clean water. Add the rinsate to the spray tank and dispose of the outer wrap as described above. For Metal Containers (non aerosol): Triple rinse (or equivalent) the container. Then offer for recycling or reconditioning, or puncture and dispose of in a sanitary landfill, or by other procedures approved by state and local authorities. :. 10 NOTICE TO BUYER: Purchase of this muterial does not confer any rights under patents of countries outside of the United States. The DuPont Oval Logo, DuPont™, STOUTTM, ACCENT®, CINCH®, ASANA® and LANNATE® are trademarks or registered trademarks of E. I. duPont de Nemours and Company "Axiom", "Aztec", "Balance" are trademarks or registered trademarks of Bayer Crop Protection "Basagran", "Clarity", "Counter", "Distinct", "Frontier", "Laddok", "Marksman", "Outlook". "Prowl", "Thimet" are trademarks or registered trademarks of BASF Ag Products "Callisto", "Dua)", "Force", "Lumax", "Bicep" are registered trademarks of Syngenta Crop Protection Inc. "Fortress" is a registered trademark of Amvac Chemical Corp. "Harness" is a registered trademarks of Monsanto Technology LLC "Hornet", "Lorsban", "Surpass", "Starane" are registered trademarks of Dow AgroSciences LLC D ·1051 090805

• LIMITATION OF WARRANTY AND LIABILITY NOTICE: Read This Limitation of Warranty and Liability Before Buying or Using This Product If the Tenns Are Not Acceptable, Return the Product at Once, Unopened, and the Purchase Price Will Be Refunded. It is impossible to eliminate all risks associated with the use of this product. Such risks arise from weather conditions. soil factors, off target movement, unconven· tional farming techniques, presence of other materials, the manner of use or application. or other unknown factors, all of which are beyond the control of DuPont. These risks can cause: ineffectiveness of the product; crop injury, or; injury to non-target crops or plants. DuPont does not agree to be an insurer of these risks. WHEN YOU BUY OR USE TIllS PRODUCT, YOU AGREE TO ACCEPT THESE RISKS. DuPont warrants that this product confonns to the chemical description on the label thereof and is reasonably fit for the purpose stated in the Directions for Use, subject to the inherent risks described above, when used in accordance with the Directions for Use under normal conditions. DUPONT MAKES NO OTIffiR EXPRESS OR IMPLIED WARRANTY OF FITNESS OR OF MERCHANTABlUTY OR ANY OTIffiR EXPRESS OR IMPLIED WARRANTY. TO THE FULLEST EX1ENT ALLOWED BY LAW, IN NO EVENT SHALL DUPONT OR SELLER BE LIABLE FOR ANY INCIDENTAL, CONSEQUENTIAL OR SPECIAL DAMAGES RESULTING FROM THE USE OR HANDLING OF TIllS PRODUCT. BUYER'S OR USER'S BARGAINED-FOR EXPECTATION IS CROP PROTECTION. THE EXCLUSIVE REMEDY OF THE USER OR BUYER AND THE EXCLUSIVE LIABlUTY OF DUPONT OR SELLER, FOR ANY AND ALL CLAIMS, LOSSES, INJURIES OR DAMAGES (INCLUDING CLAIMS BASED ON :. BREACH OF WARRANTY OR CONTRACT, NEGliGENCE, TORT OR STRICT UABlUTY), WHETIffiR FROM FAILURE TO PERFORM OR INJURY TO CROPS OR OTHER PLANTS, AND RESULTING FROM THE USE OR HANDLING OF TIllS PRODUCT, SHALL BE THE RETURN OF THE PURCHASE PRICE OF THE PRODUCT, OR AT THE ELECTION OF DUPONT OR SELLER, THE REPLACEMENT OF THE PRODUCT. DuPont or its Ag Retailer must have prompt notice of any claim so that an immediate inspection of buyer's or user's growing crops can be made. Buyer and allosers shall promptly notify DuPont or a DuPont Ag Retailer of any claims, whether based on contract, negligence, strict liability, other tort or otherwise or be barred from any remedy. This Limitation of Warranty and Liability may not be· amended by any oral or written agreement. For product infonnation call: 1·888·6·DUPONT Internet address: http://cropprotection.dupont.com/ © 2005 E. I. du Pont de Nemours and Company, Wilmington, Delaware 19898. All rights reserved. 11