crop-chem-docs/corpus/epa_ppls/5905-528.md

HELENA 4LB. METHYL PARATHION

• EPA Reg No: 5905-528
• Registrant: HELENA AGRI-ENTERPRISES, LLC, D/B/A HELENA CHEMICAL COMP
• Signal word: Danger
• Active ingredients: Methyl parathion (45.11%)
• Label accepted: 1997-06-03
• Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/005905-00528-19970603.pdf

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) 5105-521 '.-3- 11 11

• . - - UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Judy Oldham Helena Chemical Company 6705 Poplar Avenue, Suite 500 Memphis, Tennessee 3,8119 Dear Ms. Oldham: .. Subject: Labeling Amendment 4 lb. Methyl Parathion EPA Reg. No. 5905-528 WASHINGTON, D.C. 20460 JUN 031997 . Your submission dated March 17, 1997 The labeling amendment referred to above submitted in connection with registration under the Federal Insecticide, Fungicide, and Rodenticide Act, as amended, has been received and reviewed, and the following are the Agency's comments:

1. All products distributed or sold under 4 lb. Methyl Parathion EC (EPA Reg. No.5905~528) must be packaged in labeled containers bearing a unique identification number that will remain on the label or container atall times.
2. The label you submitted is acceptable providing you make the following changes and/or address the followil)g comments: a .. Change the application rate for treatment of leafhoppers and armyworms (to 3rd instar) on . Rye and What.r£m.~ y,.ts.» Y>.pints. ",.... ...,._ ... -,'-" , .. "
3. Submit three copies of the revised final printed label for the record. A stamped copy of the labeling is enclosed for your records. Enclosures Sincerely, M? Larry Fried . Insecticide-Rodenticide Branch Registration Divisi.on (7505C)

" ) ) RESTRICTED USE PESTICIDE Due to Very High Acute Toxicity to Humans and Birds ForretaiJ sale to and u~-,nlEy~ertified applicatorsotpersons under their direct supervision and only for those uses covered by the certified applicator's certification. Direct supervision for this product is defined as the certified applicator being physically present during application, mix iog, loading, repair and cleaning of application equipment. Commercial certified applicators must also ~nsure that aU persons involved in these activities are informed of the precautionary statements . 4 LB. METHYL PARATffi()N EMULSIFIABLE INSECTICIDE CONCENTRATE ACTIVE INGREDIENT: O,O-dimethyl O-p-nitrophenyl phosphorothioate* ..................................... . Related Compounds ............... : .... , ...................................................•.. INERT INGREDIENTS: ...................................................................•................. TOTAL ...................................................................................... . J gallon of 4 LB. METHYL PARATHION contains 4 pounds of Methyl Parathion. "'Methyl Parathion. ... -- 43.40% 1.71% 54.89% 100.00% DANGER POISON PELIGRO KEEP OUT OF REACH OF CHILDREN ORGANOPHOSPHATE

CAN KILL YOU.lF SWALLOWED: This product can kill you if swallowed even in small amounts; spray mist may be fatal if swallowed. CAN KILL YOU BY SKIN CONTACT: This product can kill you if touched by hands or spilled or splashed on skin, in eyes or on clothing (liquid goes through clothes). CAN KILL YOU IF BREA TIlED: This product can kill you if vapor, spray mist are breathed. Si usted no entiende la etiqueta, busque a alquien para que se la explique a usted en detaIle. (lfyou do not understand the label, [md someone to explain it to you in detail.) SPECIAL INSTRtiCTIONS FOR RESTRICTEDtiSE PESTICIDE RETAILERS: In addition to any other required records, restricted use pesticide retailers must record at the time of sale the unique container identification number on this label or container and .the identity Of the purchaser of the container. EPA REG. NO . .1905:52"8 EPA EST. NO:: Firstletters of product· batch code indicate producing establishment~=~ AC{.5-GA-I=CG.·5905=ARr:::,WA.- . NET CQN1EN'T~: "lIh cO~~_r A-I=KC 5905-JA-I =DI in EPA Letbl't':D'lIiOd-" . ,JUl'! 031997 MANUFACTURED BY: Toder the Federal wseetielde, ~Ullt;iddc. and Rodenticide Act ~ nmended, for the peslid«le :egis,ered under EPA Reg. ~~ 5]O$"'":" $j..« HELENA CHEMICAL COMPANY MEMPHIS, TN 38119 Bar C".ktJr uniqL.() ldMtify­ ingnumber

) ) PRECAUTIONARY STATEMENTS HAZARDS TO HUMANS AND DOMESTIC ANIMALS DANGER WORKER SAFETY RULES 2 The National Pesticide T elecommunicationNetwork is available for recommendations regarding poisoning manags:ment, emergency treatment, and other information regarding the toxicity of methyl parathion. The toll free number for the National Pesticide Telecommunication Network is 1-800-858- 7378. Ifhandled indoors,provide mechanical exhaust ventilation. po notrub eyes or mouth with hands. If you feel sick in any way, STOP work arid get help right away. See First Aid Section. PERSONAL PROTECTIVE EQUIPMENT Some materials that are chemical-resistant to this product are listed below. If you want more options, follow the instructions for category G on an EPA chemical resistance category selection chart. Applicators and other handlers must wear: Coveralls over long-sleeved shirt and long pants Chemical-resistant gloves, such as Barrier Laminate or Viton2 14 mils Chemical-resistant footwear plus socks Protective eyewear Chemical-resistant headgear for overhead exposure Chemical-resistant aprortWhen cleaning equipment, mixing, or loading For exposure in enclosed areas, a respirator with either an organic vapor-removing cartridge with a prefilter approved for pesticides (MSHAJNIOSH approval number preflJ( TC-23C),or a canister approved for pesticides (MCHAJNIOSH llJ:>!lI"O"I).llU1cberjrefix TC-14G) .,. For exposures outdoors, dtiStfffiistfIlteringrespirator (MSHAINIOSH approval number prefix TC- 21C. Discard clothing and other absorbent materials that have been drenched or heavily contaminated with this product's concentrate. Do not reuse them. Follow manufacturer's instructions for cleaning! maintairiing PPE. If rio stich instructions for washables, use detergentand hot water. Keep and wash PPE separately from other laundry. When handlers use closed systems, enclosed cabs, or aircraft in a manner that meets the requirements listed in the Worker Protection Standard (WPS) for agricultural pesticides [40 CFR 170.240 (d) (4- 6)], the handler PPE requirements may be redm:ec! oLmodified _ecified in WPS. DURING AEIUA:LAPPLrCA rt6N HuMAN FLAGGERSARE PROHIBITED. USER SAFETY RECOMMENDATIONS Users should: Wash hands before eating, drinking, chewing gum, using tobacco or using the toi:el. Remove clothing immediately if pesticide gets inside. Then wash thoroughly and jlJ t vI', clem. lothing. ' Remove PPE immediately after handling this product. Wash the outside of glove lo>!f('lre removing. A.s soon as possible, was~thoroughly andchange into clean ~Iothing. _ ,', .,

) ) POISON SIGNS (SYMPTOMS): Methyl Parathion is a very dangerous poison. It rapidly enters 3 the body on contact with all skin surfaces and eyes. Exposed persons must receive prompt medical treatment or they may die. Some of the signs and symptoms of poisoning are: Headache, nausea, vomiting, cramps, weakness, blurred vision, pinpoint pupils, tightness in chest, labored breathing, nervousness, sweating, watering of eyes, drooling or frothing ofmQuth_and nose, muscle spasms and coma FIRST AID This product contains an organopbosphate and is a cholinesterase inhibitor. Call a doctor (physician), clinic or hospital immediately. EXplain that the victim has been exposed to methyl parathion and describe his condition. After fITst aid is given and if a doctor cannot come, take victim to clinic or hospital. F BREA TIllNG HAS STOPPED, start artificial respiration immediately and maintain until doctor eesvictim. E'SW ALLO\VED, drink 1 or 2 glasses of water and induce vomiting by touching back of throat witb '"mger. Do not induce vomiting or give anything by mouth to an unconscious person. Get medical ~ttention. , ,',' ., . ~ CASE OF CONTACT, inllnediately flush eyes or skin with plenty of water. See doctor immedi­ ~tely. ~OTE TO PHYSICIAN: Antidote - administer atropine sulfate in large doses, TWO to FOUR mg. ~travenously or intramuscularly as soon as cyanosis is overcome. Repeat at 5 to 10 minute intervals putil signs of atrcpinization appear. 2-P AM chloride is also antidotal and mllY be administered in Fonjunction with atropine. DQ NOTGIVE MORPHINE OR TRANQUILIZERS. Methyl parathion s a strong cholinesterase 'inhibitor affecting the central and peripheral nervous systems and producing pardiac and respiratory depression. At first sign of pulmonary edema, the patient should be given ~upplementa1 oxygen and treated symptomatically. Continued absorption of the poison may occur and Ifatal relapses have been reported after initial improvement. VERY CLOSE SUl'BRVISION OF THE PATIENT IS INDICATED FOR AT LEAST 48 HOURS. . . ' . ENVIRONMENTAL HAZARDS _' This pesticide is highly toxic to aquatic invertebrates and wildlife. Birds in treated areas may be killed. Shrimp and other aquatic organisms may be killed at recommended application rates. Do not apply directly to water, or to areas'where surface water is present or to iiltertidaI areas below the mean high water mark uuless otherwise permitted in Directions for Use. Runoff anddriftmay be hazardous to aquatic organisms in adjacent aquatic sites. Do not contaminate water by cleaning of equipment or disposal of equipment washwaters. This product is highly toxic to bees exposed to direct treatment or residues OP. bl'J'J'lling cro:ps or weeds. Do not apply this product or allow it to drift to blooming crops ?r wetds if Jees <.re visiting the treatment area. COMBUSTIBLE DO NOT USE OR STORE NEAR HEAT OR OPEN FLAME NOT FOR USE OR STORAGE IN OR AROUND THE HOME.

) 4 DIRECTIONS FOR USE It is a violation of Federal law to use this product in a marmer inconsistent with its labeling. Do not apply this product in a way that will contact workers or other persons, either directly or through drift. Only protected handlers may be in the area during application. For any requirement specific tc your State or Tribe, c'onsult the agency responsible for pesticide regulation. AGRICULTURAL USE REQUIREMENTS' Use this product only in accordance with its labeling and with the Worker Protection Standard, 40 CFR part 170. This Standard contains requirements for the protection Qfagricultural workers on farms, forests, nurseries,and greenhouses, and handlers of agricultural pesticides. It contains require­ ments for training, decontamination, notification, and emergency assistance. It also contains specific instructions and exceptions pertaining to the statements on this label about personal protective equip­ ment"(pPE)and restricted-entry interval The requirements in this box only apply to uses of this product that are covered by the Worker Protection Standard. Do not enter or allow worker entry into treated areas during the restricted entry interval (REI) of 48 hours. PPE required for early entry to treated areas that is pennitted under the Worker Protection Standard and that involves contact with anything that has been treated, such as plants, soil, or water is : --Coveralls over long-sleeved shirt and long pants --Chemical-resistant gloves, such as Barrier Laminate or Viton:? 14 mils. --Chemical-resistant footwear plus socks --Protective eyewear --Chemical-resistant headgear for overhead exposure. Notify workers of the application by warning them orally and by posting warning signs a! e!ltrap.c~!c treated areas.' . ..- ............ ~ ..... ~ ....... ... . - ......-..... -_ ...... ::- .. '--"'-. .. ) In case of accidental exposure: Call a doctor (physician), clinic or hospital immediately. Explain that . . the victim has been exposed to methyl parathion and describe his condition. For further information, see the FIRST AID portion of the pesticide labeL STORAGE AND DISPOSAL PROHIBITIONS: Do not contaminate water, food, or feed by storage o ·disposal. Do not store under com:!itions which might adversely affect the container or its ability to function properly. -~-.---- -.-.. _---- STORAGE: 06 not stOre1Je16w O°F. Store in a sareIIl~~r.Do·not use or store near heat, vp<:n flame or hot surfaces. Keep out of reach of children and animals. Store in original ,con1;a,iners only. Store in a cool, dry place and avoid excess heat. Reduce stacking height where lo-:;a\ conditkns C.1Jl affect package strength. Personnel should Use clothing andequipment listedunde. 'P:;U;CACTION­ AR Y STATEMENTS" when handling open containers. Carefully open containers. Do not put concentrate or dilute material into food or drink containers. SPILLED MATERIAL: Block or dike tc prevent spreading of spill. Cover with absorbent It\li\teri,al such as lime, clay or sawdust. Scoop and sweep into a disposable container. Wash area with strdI'{t lye solution, absorb and place intc a disposable container.

) PESTICIDE DISPOSAL Pesticide wastes are acutely hazardous. Improper disposal of excess pesticide, spray mixture, or rinsate is a violation of Federal Law. If these wastes cannot be disposed of by use according to label instructions, contact your State Pesticide or Environmental Control Agency, or the Ha2:ardollS Wastes representative at the nearest EPA Region Officeror guidance. CONTAINER DlSPOSAL RetumablelRefillable Seal Container: Do not break seals or add any material to the container. Do not rinse container or empty any residue from coIltainer. This container must be retiuned intact after use to the point of purchase. DIRECTIONS Be sure to read the precautionary statements before using! This product is designed for application after dilution with water and for use by trained operators using airplane or power ground equipment. The hazards and precautions for handling the product in this container are equally applicable to it after dilution with water for spray application. REMOVAL OF PRODUCT FROM CONTAINER This container is fitted with the :MICRO MATIC "DV" liqUid transfervaIve system._Toremove product, use the :MICRO MA TIC coupler attachment which is available from the seller of this con­ tainer. The directions below must be followed: To Connect Coupler:

1. Attach pump hose to chemical pump.
2. Attach pump hose to coupler.
3. With coupler handle in disengaged position, insert coupler straight down into the drum valve, ensuring that the pins on the coupler align with the slots on the valve.
4. Turn coupler handle clockwise a quarter tum, until it locks into place. ) 5. Push down coupler handle to engage, ensuring that the lock bar clicks into place. To Disconnect Coupler:
5. Press down on coupler and disconnect the lock bar. Allow coupler handle to raise to its disen­ gaged position.
6. TiJrn Coupler handle counter clockwise and quarter tum. Lift coupler straight up. If you have any questions Of need assistance, please call your Distributor or 1-800-548-6113. Add the concentrate to the spray tank while filling with water, and mix thorovgr ly ither by 'lleansof a tank agitator or pump by-pass. For best results,-thoroughly coverall surfac<-s to]:,e treated with spray. Rates of application given below should not be exceeded. Never apply la:er than indicated to assure residue levels at harvest are below tolerance established by the Envirol'roptal Protecli0fl Agency.

• -- -'-----, - ----'------------ - ------ Consult the StaieAgilcultlirafExtension Service or Experiment Station for specific recoro~~~dations regardingapplication, dosage and timing of spray. For application by ground equipment, add t:ie

) ) desired amount of concentrate to sufficient water to apply at least 3 gallons of water per acre. For 6 application by aircraft, add the atnount of concentrate desired per acre to 1 to 3 gallons of water consistent with crop growth and good coverage. Do not use in undiluted form. DO NOT APPLY 'tHIS PRODUCT THROUGH ANY TYPE OF IRRIGATION SYSTEM. COMPATIBILITY - A void combinations containing highly alkaline materials such as lime-sulfur solutions or lime. Alkaline compounds will reduce the effectiveness of methyl parathion. ALFALFA: Flea Beetles, Climbing Cutworms, - Apply \12-I pint per acre. Aphids (including Pea Aphids and Spotted Alfalfa Aphid) - Apply \12-I pint per acre. For Spotted Alfalfa Aphid, apply early in spring. Alfalfa Weevil (larvae)- Apply \12-1 pint per acre. Apply when 75% terminals show feeding, when buds and shoots appear ragged, or when the larval count reaches 25 per sweep. Web­ worms, Clover Leaf Weevil, Alfalfa Caterpillar, Armyworms, Alfalfa Weevil (adult) (Refer also to Egyptian Weevil) Thrips and Grasshoppers - Apply I pint per acre. Egyptian Alfalfa Weevil, Leafhoppers, LygusBugs, Mites, Stink Bugs, and Spider Mites - Apply 1-2 pints per acre. Do not apply within 15 days of harvest. Alfalfa Seed Chalid - Apply I \12-2\12 pints per acre. Plant Bugs (for use on seed crops only) - Apply \12-1 pint per acre. Do not apply within 15 days of harvest, cutting or grazing. In California and Nevada, do not usemore than Y. pint per acre. Do not apply if the crops or weeds in the treatment area are in bloom. BARLEY: Thrips - Apply \12-1 \12 pints per acre. Leafhopper, Cutworms (Climbing) - Apply Y. to 1 pint per acre. Stink Bugs, Armyworm (to 3r<i ins tar), Black Grass Bugs, Aphid (including Greenbug), Winter Grain Mites - Apply \12-1 \12 pints per acre. Apply early spring for greenbug control. Say's Plan{Bugs, Spider Mites, False Chinch Bug, Grasshopper, Chinch Bugs - Apply 1 \12 pints per acre. Western Wheat Mites, BrownWheat Mites - I pint. Do not apply within 15 days ofharvest. BEANS (DRY AND GREEN): Leafhoppers, Flea Beetles, Plant Bugs (including Lygus Bugs), Aphids, Armyworms (to 3rd Instar), Mites - Apply 1-3 pints per acre. Cabbage Looper - Apply 2 pints per acre. Stink Bugs, Cowpea Curculio, Cutworms (including climbing and surface feed­ ing species) - Apply 2-3 pints per acre. Do not apply within 15 days ofharvesl. For green and lima beans, do not apply within 15 days of harvest for application rates through I pint, Do.not apply within 21 days of harvest for dosage rates exceeding I pint per acre. DO NOTapplyifthe crop or weeds in the treatment area are in bloom. BEETS: Mites, Aphids, Armyworms, Flea·Beetles, Leafhopper, Grasshoppers, Sugar BLet Webworms - Apply 1-2 pints per acre. Stink Bugs, Plant Bugs (including Lygu~ ,Bgs), Cabbage Looper - Apply 2 pints per acre. Do not al'ply within 20 daysQLharvesU)Q not ?ppiy Within 60 .jays iftops are to oefed'to'iinimals.-- '--- BROCCOLI: Thrips - Apply \12-1 pint per acre. Aphids, Armyworms, Flea Be~~;'es) Leafhopper, Mites - Apply 1-3 pints per acre. Imported Cabbageworms, Cabbage Looper, Stink Bug - /I.P1?ly 2-3 pints per acre. Plant Bugs - Apply 2\12 pints per acre. Do not apply within 7 days of harveSt through 1 pint, within 21 days of harvest from 1 pint through 3 pints. , ,

7 " . ' BRUSSELS SPROUtS: Aphids, Armyworms, Thrips, Flea Beetles, Leafhoppers, Mites­ Apply 1-3 pints per acre. Imported Cabbageworms, Cabbage Looper, Stink Bugs - Apply 2-3 pints per acre. Plant Bngs - Apply 2Yzpints per acte. Do not apply within 7 days of harvest through 1 pint, within 21 days of harvest from 1 pint through 3 pints. CABBAGE: Aphids, Armyworms, Flea Beetles, Leafhoppers, Mites - Apply 1-3 pints per acre. Imported Cabbageworms, Cabbage Looper, Stink Bugs - Apply 2-3 pints per acre. Plant Bugs - Apply 2Yz pints per acre. Do not apply within 10 days of harvest through 1 pint, within 21 days of harvest from I pint through 2Yz pints. CARROTS: Aphids, Armyworms, Flea Beetles, Leathopper~, Mites - Apply 1-2 pints per acre. Cutworms (surface feeding and climbing), Cabbage Looper, Plant Bugs - Apply 2 pints per acre. Do not apply within 15 days of harvest. DO NOT use treated carrot tops for food or feed. CAULIFLOWER.: Aphids, Armyworm, Fle~ Betles, Leafhopper, Mites - Apply 1-3 pints per acre. Imported Cabbageworm, ClIbbage Looper, Stink Bugs - Apply 2-3 pints per acre. Plant Bugs - Apply 3 pints per acre. Do not apply within 7 days of harvest through 1 pint, within 21 days of harvest from 1 pint through 3 pints. CELERY: Aphids, Armyworms, Flea Beetles, Leafhoppers, Mites, Lygus Bugs, Cabbage Looper, Plant Bugs, Stink Bugs - Apply 2 pints per acre. Do not apply within 15 days of harvest. CLOVER: Leaibopper, Armyworm, Aphids (including Spotted Alfalfa Aphid) (apply early in the spring), Alfalfa Weevil (larvae) (apply when 75% ofterminals show feeding, when buds and shoots appear ragged, or when the larval count reaches 25 per sweep) - Apply 1-1 Y2 pints per acre. Egyptian Alfalfa Weevil - Apply 1-2 pints per acre. Do not apply within 15 days ofhar­ vest. Clover Seed Chalcid (for use on seed crops only), Climbing Cutworm - Apply YZ-2YZ pints per acre. Plant Bugs (for use on seed crops only) - Apply V,-1 pint per acre. Do not apply within 15 days of harvest from 1 pint through 2 pints. Do not apply within 20 days of harvest from 2 pints ) through 2Yz pints per acre. COLLARDS: Aphids, Armyworms, Flea Beetles, Leafhopper, Mites - Apply I -3 pints per acre. Imported Cabbageworm, Cabbage Looper, Stink Bugs, Thrips - Apply 2-3 pints per acre. Plant Bugs - Apply 3 pints per acre. Do not apply within 10 days of harvest through 1· pint. Do not apply within 21 days of harvest from one pint through 3 pints per acre. CORN: Aphids (incfudilig corn leaiaphid), Armyworm, Fall Armyworm, Corn Rootworm (including western corn rootworm) (adults), Flea Beetles, Mites, Stink Bugs - Apply Yo pt per acre. Grasshoppers - 1 pint per acre. Do not apply within 12 days of harvest . Do p,ot apply to com during the pollen shed period. COTTON: Thrips(apply before or during the 4-leaf stageandrepeat 1 to 3 times at 7 to IJ ,lay intervals), Flea hoppers (including cotton fleahopper) - Apply Y. to 1 pint fer ::cre. Grass!lOpper, Fall Armyworm (to 3rd instar), Aphids (including cotton aphid) (apply when aphiC's ~p:rear in buds and on leaves of seedliugs or when honeydew appears on older plants), CottOI1, l.eafworm, Garden Webworm - Apply V,-6 pints per acre. Lygus Bugs, Mites, Spider (including desert

) 8 spider mite and two-spotted spider mites) - Apply Yz-2 pints per acre. Southern Green Stink Bug, False Chinch Bug - Apply I pint per acre. Lfr0ller_Cabbagel&oper, Cotton Leaf-Perfo­ rator, Cutworms~ . Apply 1-2 pints per acre. Stink Bugs - Apply 2 pints per acre. Armyworms - Apply 2-4 pints peracte. Bollworm, Saltmarsh Caterpillar, - Apply 2Yz-6 pints per acre. Tobacco Budworm - Apply 2 pints per acre. Do not handpick within 7 days of application through 2 pints per acre. Boll Weevil - Apply 1-6 pints per acre. For early season control of overwintering boll weevils, apply as early as the 2-t041eaf stage and repeat 1-3 times at 7-10 day intervals. For midseason control, apply at the start of squaring or after 10-25% of the fust squares are punctured and repeat at 3-to-8 day intervals as needed or until the top bolls are full grown. Repeat at 3-day intervals during the major fruiting season, and periods of heavy .weevil migration. Boll Weevil (Texas only) - For the control of boll weevils apply liz-I pint (.25 to 0.5 lb. active ingredient) per acre in a minimum of I quart of once refined vegetable oil (such as soybean/cottonseed). For overwintered adults, apply early season as needed. Apply mid to late season as needed. High rates are required for severe infestation and late season. Aircraft should be outfitted with a delivery system designed to apply droplets with a VMD of I 00-200 microns. Swath width should not exceed wing span plus 10 percent. When using conventional hydraulic nozzle systems, the nozzles should be oriented 90 degrees to the laminar airflow. Note: When temperatures are 70· F or below, keep the spray mixture under agitation and do not allow mixture to stand for any long period of time. Do not handpick or harvest within 7 days of application. Do not feed forage or gin trash -to livestock. GRASS (HAY, PAS11.lRE) (FbRXGE): Armyworm (t 3rd instar), Crested Wheat Bugs, Black Grass Bugs (Including IJ:"bi.sia), False Chinch Bugs, Grasshoppers, Leafhoppers - Apply I Yz pints per acre. For aphids, apply Yz pint per acre. Range Caterpillars - I pint per acre. Do not apply within IS days of harvest or grazing. KUE: Aphids, Armyworms, Flea Beetles, Leafhopp·ers, Mites - Apply 1-3 pints per acre. Im­ ported Cabbageworm, Cabbage Looper, Stink Bugs - Apply 2-3 pints per acre. Plant Bugs - Apply 3 pints per acre. Do not apply within 10 days of harvest through I pint. Do not apply within 21 days of harvest from I pint through 3 pints. LETTUCE: Aphids, Armyworms, Flea Beetles, Imported Cabbageworm, Leafhoppers, Mites, Cabbage Looper, Plant Bugs - Apply 2 pints per acre. Do not apply within 21 days of harvest. MUSTARD GREENS: Aphids, Armyworms, Flea Beetle, Leafhoppers, Mites - Apply 1-3 pints per acre. Imported Cabbageworm, Cabbage Looper, Stink Bugs - Apply 2-3 pints per acre. Plant Bugs - Apply 3 pintsper acre. Do not apply within 10 days of harvest through I pint, or within 21 days of harvest from above I pint through 3 pints. OATS: Browil Wheat Mites, Westero Wheat Mites -Apply I pint per acre. Aphids (incJ,ltdin~ greenbug), Black. GrassJugs (including Irbisia), Stink Bugs - liz-I Yz pints per, acr". Barley. Thrips - Yz-¥. pints per acre. Climbing Cutworms, Grasshoppers - % - I pint per ade. Leftfbcp­ pers, Armyworm (to 3rd instar) - I Yz pints per acre. Winter Grain Mites, Sti.t.ll>;:3J.<gs - 2-i liz . pints per acre.Say's Plant Bugs, Chinch Bugs, False Chinch Bug and Fall Arn;Jfflorm - j y pints per acre. Do not use more-than Yz pint per acre within 15 days of harvest. , --.-. ---,--. ~~ " .. - '0. __ ,.. _____ ~w ~ O)l10NS: Thrips (inCluding onion thripsY ~Y;:lpintper acre. Do not apply within 15 daxs 'ill . harvest. ' . ;

) ) P·ASTURE: (Irrigated) (Refer a,lso to Grass): Mosquitoes (Larvae) - Apply 118 pint per acre. Do not apply within 7 days of harvest. Broadcast application. PEAS: Aphids, Armyworm (to 3rd instar), Flea Beetles, Leafhoppers, Mites,Plant Bugs (in­ cluding Lygus Bugs) - Apply 1-2 pints per acre. Stink Bugs, Cowpea Curculio, Cutworm (in­ cluding climbing and surface feeding species), Cabbage Looper - Apply 2 pints per acre. Do not apply within 10 days of harvest through I pint. Do not apply within 15 days ofharvst from 1 pint through 2 pints. DO NOT apply if the crop or weeds in the treatment area are in bloom. POTATOES: Aphids, Flea BeetleS, Armyworm, Leafhoppers, Mites, False Chinch Bugs, Cabbage Looper, Plant Bugs (including Lygus Bugs), Stink Bugs, Shield Bugs - Apply 3 pints per acre. Thrips - Apply I II.. pints per acre. Do not apply within 6 days of harvest. 9 RAPESEED/CANOLA: Cabbage Seedpod Weevil- 1 pint per acre. Make first application when two or more insects can be found per plant on young pods. Flea _Beetles,Cabl1ageA,phids - I pint per acre. Treat iIi early season when slgnHicant evidence of shot holing by the adults becomes evident on the seedlings. Diamondback Moth Larvae - I pint per acre. Treat about mid-growing season when populations reach damaging levels and there is evidence of appreciable feeding beginning on the flowers andlor pods. Do not apply within 28 days of harvest. DO NOT graze treated fields or feed treated forage or threshings to livestock. Apply by ground or air in sufficient water for coverage (minimum oB gallons per acre by air). Do not apply more than two applications per season. To protect pollinators, apply onlyTn the evenillg Qr early morning (this includes a period from 3 hours before sunset until 3 hours after sunrise of the following day) NOTE -IN OREGON - apply product only in the evening (this includes a period from 3 hours before sunset un,til !I)idnightp[tbesame day). DO NOT APPLY IN IDAHO AND WASHINGTON STATE. Pesticide applicators in Idaho and Washington MUST refer to supplemental labeling exclusive to your state. If this supplemental labeling cannot be found at the end of this booklet, you can obtain it by calling HeleD<L Chemical at (90 I) 752-4420 and a copy will he faxed or mailed to you directly. RICE: Stink Bugs, ArmywormsApply I-Ill, pints per acre. Grasshoppers - /. pint per acre. Do not apply within 15 days of harvest. Crabs, crayfish and shrimp may be killed. Do not apply where they are important resources. Rice Leafminer, Tadpole Shrimp - Apply I Y:z pints per acre. Use restricted to California:. Apply at first sign of infestation a:fterplilllting. Apply oy air in 5- I 0 gallons of water. Restrict spill from rice fields for 3 days. Do not use within 14 days of application 00',4'- dichloropropiommllide as injury may result. . . RYE: Brown Wheat Mites, Western WheaiMites - Apply I p4 acre. n4~;y Thcips - Yz-'!' pint per acre. LeafhoPP!1"s,.<.!rnyworm (t()}!:,d is!ar): APply '2Y~'pints peraCie. Climb'inp ,_ - -- -- =;-- ..0= .. "-."""' -------. - _.- f Cutworms, Grasshoppers - %-1 pint per acre. Aphids (including.-greenbug), R1ack Gras~ Bugs (including Irbisia), Winter Grain Mites, Stink Bugs - Y:z-I Y:z pints per acre. False Chioe!. ~ug, Say's Stink Bugs, Chinch Bug -I Y:z pints per acre. Do not use more than Yz pint per acre Within 15 days of harvest.

'\ I ) , ; ' " " 10 SOYBEANS: Climbing Cutworms, Three-cornered Alfalfa Hopper, Webworm (including Garden Webworm), Aphids, BlisterBeetJes, Mexkan Bean Beetles, Stink Bugs, Thrips, Velvetbean Caterpillar, Two Spotted Mites - Apply 31._2 pints per acre. Green Cloverworm, Cabbage Looper - Apply 1-2 pints per acre. Armyworm, Fall Armyworm ( to 3rd instar), Bean Leaf Beetle, Corn Earworm, Grasshoppers, Bollworms - Apply 2 pints per acre. Plant Bugs (for use on seed crops only) - Apply Yo-I pint per acre. Do not apply within 20!iays of harvest or graz-ing. . ...... . . SPINACH: Aphids, Armyworms, Mites, Flea Beetles, Leaiboppers, Seed Corn Maggot (in crown), Crown Mites - Apply 1-2 pints per acre. Cabbage Looper, Plant Bugs - Apply 2 pints per acre. Do not apply within 15 days of harvest thrQugh I pint. Do not apply within 21 days of harvest from 1 pint through 2 pints. SUGAR BEETS: ArmyWorm, FaliArmywom>. Cutworm (inclllding Climbing Cutworms), Flea Beetles, Grasshoppers, Leaiboppers, Sugar Beet Webworms, Mites - Apply Yo-l4 pint per acre. Lygus Bugs, Stink Bugs, Webworms - l4 pints per acre. ) Aphids - Apply l4 pints per acre. Do not apply within 20 days of harvest; 60 days iftops are to be fed to animals. SUNFLOWERS;·Sunfl01ver Moth, Sunflower Maggot, Sunflower Seed Weevil - Apply 2 pints per acre. Donotapply within 30 days of harvest. Do not apply more than 3 times at 5-day intervals per season. Do not feed seeds to birds. SWEET POTATOES: Aphids, Armyworm (to 3rd instar), Cutworms (including climbing and surface feeding species,) Flea Beetles, Leaiboppers, Cabbage Looper, Spider Mites - Apply 1 Yo pints per acre. Do nOt apply within 6 days of harvest. TURNIPS: Aphids (including Cabbage Aphid), Armyworms (to 3rd instar), Flea Beetles, Leaiboppers, Leafminer, Mites - Apply 1-1 Yo pints per acre. Imported Cabbage Worm, Cabbage Looper, Plant Bugs - Apply I Yo pints per acre. Do not apply within 10 days of harvest through Yo pint (roots). Do not apply within 21 days of harvest from 1 to 1 Yo pints (roots). Do not apply within 21 days of harvest if tops are to be used as food or feed. VETCH: Alfalfa Weevil (larvae) - Apply -1 pint per acre. Apply when 75% ofteoninals show feeding, when budS and shoots appear ragged, or when the larval count reaches 25 per sweep. Aphids, Leaiboppers, Mites - Yo-I pint per acre. Climbing Cutworms, Lygus Bugs, Vetch Bruchid - I pint per acre. Armyworm - YO-2YO pints per acre. Do not apply within 15 days of harvest through 2 pints. Do np! apply within 20 days of harvest from 2 pints through 2Yo pints. WHEAT: Brown Wheat Mites, Western Wheat Mites - Apply 1 pin! per acre . .B::rley Thrips­ Apply Yz-l4 pints per acre. Leallioppers, ArmyworJll (to 3r<Unstar)-Appl;J'1ts per ,cre. Climbing Cutwonns, Grasshoppers·-APply%-J pint per acre. Aphids (incJudin~ Green~<lg), 111"

) ) Black Mites, Stink Bugs, Winter Grain Mites - Apply It,-J It, pints per acre. Say's Plant Bugs, Chinch Bugs, False Chinch Bug, Fall Armywonn - I It, pints per acre. Do not use more than Y, pint per acre within 15 days of harvest. 11 NONAGRICULTURAL LAND, WASTELANDS: Mosquitoes (larvae) - Apply 1/5 pint per acre. Do not apply within 7 days of harvest through 115 pint. For use by mosquito abatement districts and official government agencies only. Repeat as needed. Toxic to fish and wildlife. Do not use where shrimp and crabs are an important resource: Do not use in any estuaries, or coastal or tidal areas along the southeast, Atlantic or Gulf coasts of the United States. ATTENTION: Do not use in any manner other than reco=ended on this label. To avoid excessive residues of methyl parathion oIl food or forage crops, always observe the stateIl1ents found under "DIRECTIONS FOR USE" Hruiting thetime before harvest when methyl parathion may be applied. CONDITIONS OF ~ALE- LIMITED WARRANTY AND LIMITATIONS OF LIABILITY AND REMEDIES The directions on this label are believed to be reliable and should be followed carefully. Insufficient control of pests and/or injury to the crop to which the product is applied may result from the occur­ rence of extraordinary or unusual weather conditions, the failure to follow the label directions, or good application practices, all of which are beyond the control of Helena Chemical Company (the "Company") or seller. In addition, failure to follow label directions may cause injury to crops, ani­ mals, man, or the environment. The Company warrants that this product conforms to the chemical description on the label and is reasonably fit for the purpose referred to in the directions for use subject to the factors noted above which are beyond the control of the Company. The Company makes no other warranties or representations of any kind, express or implied, concerning the product, including no implied warranty of merchantability or fitness for any particular purpose,and no such warranty shall be implied by law. The exclusive remedy against the Company for any cause of action relating to the handling or use of this product is a claim for damage and in no event shall damages or any other recovery of any kind against the Company exceed the price of the product which causes the alleged loss, damage, injury, or other claim. The Company shall not be liable and any and all claims against the Company are waived for special, indirect, incidental, or consequential damages or eXpense of any nature, including, but not limited to, loss of profits or income. . The Company and the seller offer this product and the buyer and user accept it, subject to the forego­ ing conditions of sale and limitation of warranty, liability, and remedies. , " , . . ,

) ) 12 RESTRICTED USE PESTICIDE - Due to vel:-yhigli aciitetoxiCity toHumansand Bird~· For retail sale to and use by certified applicator or persons under their direct supervision and only for those uses covered by the certified applicator's certification. Direct supervision for this product is defined as the certified applicator being physically present during application, mixing, loading, repair and cleaning of application equipment. Commercial certified applicators must also ensure that all persons involved in these activities are informed of the precautionary statementS: SUPPLEMENTAL LABELING· READ AND FOLLOW THE ENTIRE LABEL BOOKLEt FOR 4 LB. METHYL PARATHION EMULSIFIABLECONCENTRA TEBEFORE PROCEEDING WimTHEUSE])OOcTIONS CONTAINED IN THIS SUPPLEMENTAL LABELING Label as used in this supplemental Jabeling refers to the product label for 4 Lb. Methyl Parathion and this supplement. DANGER PELIGRO 4 LB. METHYL PARATHION . EMULSIFIABLE CONCENTRATE EPAREG.NO.5905-- FOR APPLICATlON TO RAPEsEED/CANOLA IN WASHINGTON STATE ONLY KEEP OUT OF REACH OF CHILDREN --------------=-----~~--~-- --POISON Si usted no entiende la etiqueta, busque a alquien para que se la esplique a usted in detalle._ CIfyou do not uriderstalld the label, find someone to explain it to you in detail). DIRECTIONS FOR USE It is a violation of Federal law to use this product in any manner inconsistent With its labeling. All applicable directions, restrictions, and precautions on the EPA registered label are to be followed. This label must be in the possession of the user at the time of insecticide application. See "DIRECTIONS FOR USE" and all general information on the Methyl Parathion 4 EC label for essential product performance information. This label restricts use to Canola/Rapeseed oil seed varieties only. CANOLA!RAPESEED: For control ofCa.bbage Seedpod Weevil(ceutorhYrlchus assimilis), Flea Beetle (phyllotreta sp.), Diamondback Moth (Pllltella xylostella) and Cabbage Aphids (Brevicoryne sp.), apply I pint per acre by ground or air in sufficierit water for "coverage (mini­ mum of 3 gallons per acre by air). Do not apply more than two applications per season. (A) Except as provided in (B) below, this product cannot be applied to blossoming.canola except under the following conditions: 1.) The field to be treated is at the end of the blossom period with no more tha" 25% blvom_ remaining. 2). The application may only be made in the evening from three hours before ~'!~9'!t to midpight, and only if bees are not foraging in the field to be treated at time of application and are Hot expected to be foraging in the treated field for the remainder oftha! day. (B) The WashingtonStiite Department 6fAgncuiturehasdeflll.ed areas Withinwiifa-Willa 2r:-d

) ) Columbia counties in which it feels honey bees are at risk from Methyl Parathion application. DoI3 . not apply this product to blossoming canola in these areas except under the following conditions:

1. The field to be treated is at the end of the blossom period with not more than 10% bloom remaining.
2. The application may only be made in the evening from three hours before sunset to midnight, and only if bees are not foraging in the field to be treated at time of application and are not expected to be foraging in the treated field for the remainder of the day.
3. The field to be treated must be inspected immediately prior to the application to ensure bees are not foraging. .
4. The Washington State Department of Agriculture must be notified of such an application one day prior to the expected application day. Notification must include the name and phone number of the grower, name and phone number of the applicator and the location of the canola field to be treated. Notify the departmentby caJling (509) 527-4130 or by faxing the information to (509) 529-9771. - . Maps of these areas can be obtain from the Washington State Department of Agriculture by calling (509) 527-4130 or (360) 902-2030. For Flea Beetle and Aphids treat in early season when significant evidence of shotholing by the adults become evident on the seedlings. For Diamondback Moth larvae, treat about mid-growing season when popUlations reach damaging levels and there is evidence _of appreciable feedinglJ~ginning on the flowers andlor pods. - Do not apply this product through!lIlytype of irrigation system. Do not apply this product within 28 days of harVest: Do· not graze treated field or feed treated forage or threshing to livestock. The restricted entry interval is 48 hours. Please read "ATTENTION" and "WARRANTY" sections at the end of the 4 Lb. Methyl Par­ athion label before using product. Those terms apply to this supplemental labeling also, MANUFACTURED BY: HELENA CHEMICAL COMPANY MEMPHIS, TN 38119

) ) ____ .. ~."'.-.=:..,=:=::- "~-,::"::O _:C-O ~ -.:::"- :-:::----'--'-:0'· -14 - RESTRICTED USE PESTICIDE --Du;t-;;-;ery"high"cute toxicity to Humans and Birds For retail sale to and use by certified applicator or persons under their direct supervision and only for those uses covered by the certified applicator's certification. Direct supervision for this product is defmed as the certified applicator being physically present during application, mixing, loading, repair and cleaning of application~quipment. Co=erciaI certified applicators must also ensure that all persons involved in these activities are infonned of the precautionary statements. SUPPLEMENTAL LABELING READ AND FOLLOW THE ENTIRE WEI. BO()KLET FOR 4 LB. METHYL PARATHION EMULSIFIABLE CONCENTRATE BEFORE PROCEEDING WITH THE USE DIRECTIONS CONTA1NED IN THis SUPPLEMENTAL LABELING Label as used in this supplemental labeling refers to the product labeJ for4 Lb. Metbyl Parathion and this supplement. DANGER PELIGRO 4 LB. METHYL P ARATIDON EMULSIFIABLE CONCENTRATE EPA REG. NO. 5905- FOR APPLICATION TO RAPESEEDICANOLA IN IDAHO ONLY KEEP OUT OF REACH OF CIDLDREN POISON Si usted no erUiende la etiqueta, busque a alquien para que se la esplique a usted in detalle. DIRECTIONS FOR USE It is a violation of Federal law to use this product in any manner inconsistent with its labeling. All applicable directions, restrictions,arrdprecllUtions on the EPA registered label are to be followed. This lalleI I1lUst be in the possession of the user at the time of insecticide application. See "DIRECTIONS FOR {]SE" and allgeneral ipJormation on the 4 Lb. Methyl Parathion label for essentiaJ product performance information. This label restricts use to CanolafRapeseed oil seed varieties only. CANOLAIRAPESEED: For control of Cabbage Seedpod Weevil (ceutorhynchus assimilis), Flea Beetle (phyl!otreta sp.), Diamondback Moth (Plutel!a.xylostella) and Cabbage Aphids (Brevicoryne sp.), apply I pillt per acre by ground or air in sufficient water fof coverage (mini- . mum of3 gallons per acre by air). Do not apply more than two applications per season.

• ~ - -- For Cabbage Seedpod 'Weevil and Cabbage Aphid, make first application when two 0, mere insects may be found per plant on young pods. 4 Lb. Methyl Parathion should be applied when 10% of the bloom isremitining, ()r when most of the early developed pods ar" 1.0(· - 1.25 in~hes in length. ., For Flea Beetle treat in early season when significant evidence of shotholing (.;' tlJ..:: adults he­ comes evident on the seedlings. -"._=

) ) For Diamondback Moth larvae, treat about mid-growing season when populations teach damaging levels and there is evidence of appreciable feeding beginning on'the flowers anel/or pods, Do not apply this product through any type of irrigation system. To protect polIinators~ apply only in the evening or early moming (this includes a period from 3 hours before sunset until three hours after sunrise the following day). Do not apply within 28 days of harvest. Do not graze treated fields or feed treated forageor threshings to livestock. The restricted entry interval is 48 hours. Please read the "ATTENTION" alid "WARRANTY" sections at the end of the 4 Lb. Methyl Parathion label before using this product. _ Those terms apply to this supplemental labeling also. MANUFACTURED BY: HELENA CHEMICAL COMPANY MEMPHIS, TN 38119 15