Dockerfile: self-contained image with corpus + Chroma + BM25 baked in. Drawbar's compose pulls + runs without volume mounts. Built from sources.json (labels schema), PRODUCT_NAME=crop_chem by default, HYBRID_SEARCH=true (always-on for production quality). RERANK_URL + OLLAMA_URL get set at compose time. .gitea/workflows/refresh.yml: monthly cron (1st @ 06:00 UTC) does full scrape → reindex → image push. Scrapes Bayer (~30 min) + EPA PPLS row-crop filtered (~7h). Skips reindex+push if no corpus diff. Tags pushed: :latest, :<sha12>, :corpus-<YYYY.MM.DD>. .gitea/workflows/image-only.yml: on-demand or auto on code-only pushes to main (paths: docs_mcp/, rag/, scrape/, requirements.txt, Dockerfile, sources.json). Reindexes from committed corpus, builds image, pushes. ~10 min vs ~9h full refresh. .gitignore: corpus/ now COMMITTED (4,159 labels, 265 MB of .md + sidecars). Lets image-only.yml rebuild indexes without re-scraping. chroma/ + bm25/ still gitignored (regenerable binary indexes). .dockerignore: drops venv, eval results, PLAN/README/CLAUDE.md, deploy/, .git/ — keeps the image lean. corpus + chroma + bm25 explicitly NOT in dockerignore (those go INTO the image). Co-Authored-By: Claude Opus 4.7 (1M context) <noreply@anthropic.com>
116 KiB
HARDBALL
- EPA Reg No: 5905-549
- Registrant: HELENA AGRI-ENTERPRISES, LLC, D/B/A HELENA CHEMICAL COMP
- Signal word: Danger
- Active ingredients: 2,4-D (19.6%)
- Label accepted: 2012-08-15
- Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/005905-00549-20120815.pdf
2.01 L UNITED STATES ENVIRONMENTAL PROTECTION AGENCY WASHINGTON DC 20460 OFFICE OF CHEMICAL SAFETY AND POLLUTION PREVENTION Mr Bill Washburn Helena Chemical Company 225 Schilling Boulevard Suite 200 Colherville TN38017 Subject Label Amendment to remove RUP classification Product Name HARDBALL EPA Reg No 5905 549 Application dated March 13 2012 Decision Number 462706 Dear Mr Washburn The labeling referred to above submitted in connection with registration under the Federal Insecticide Fungicide and Rodenticide Act (FIFRA) as amended is acceptable One copy of the label stamped Accepted is enclosed for your records Products shipped after 18 months from the date on this notice or the next printing of the label, whichever occurs first, must bear the new revised label Amended labeling will supersede all previously accepted ones Per 40 CFR 156 10(6) submit one copy of your final printed labeling before you release the product for shipment If you have questions or concerns regarding this letter please contact Beth Benbow at (703) 347 8072 or email at benbow bethanv@epa gov Sincerely .KathrynV Montague Product Manager 23 Herbicide Branch Registration Division (7505P)
"/ A C C II f T ID 5 20HZ the Fsdsra! inseckcMe F ngicae a*xl r^TMcirtc Act«j ^julkltSSa. fc? 0 HardBall ^eraa a" ACTIVE INGREDIENT 2 4 Dichlorophenoxyacetic Acid OTHER INGREDIENTS TOTAL Equivalent to 19 6% 2 4 D Acid or 1 74 Ib /gal Isomer specific by AOAC Method 6 D01 5 (12th Ed) Patent No 5877112 Other Patents Pending KEEP OUT OF REACH OF CHILDREN DANGER PELIGRO Si usted no entiende la etiqueta busque a alguien para que se la explique a usted en detalle (If you do not understand the label find someone to explain it to you) 196% 80 4% 1000% FIRST AID IF IN EYES IF SWALLOWED IF INHALED IF ON SKIN OR CLOTHING • Hold eye open and rinse slowly and gently with water for 1 5 20 minutes « Remove contact lenses if present after the first 5 minutes then continue rinsing eye « Call a poison control center or doctor immediately for advice « Call a poison control center or doctor immediately for advice « Have person sip a glass of water « Do not induce vomiting unless instructed to do so by poison control center or doctor « Do not give anything by mouth to an unconscious or convulsing person • Move victim to fresh air e If person is not breathing call 91 1 or an ambulance then give artificial respiration preferably mouth to mouth if possible « Call a poison control center or doctor immediately for further treatment advice « Take off contaminated clothing « Rinse immediately with plenty of water for 1 5 20 minutes « Call a poison control center of doctor for treatment advice HOTLINE NUMBER Have the product container or label with you when calling a poison control center or doctor or going for treatment For emergency assistance call toll free 1 800 424 9300 (ChemTrec) NOTE TO PHYSICIAN Probable mucosal damage may contramdicate the use of gastric lavage Causes irreversible eye damage See Additional Precautions and Use Directions on Inside Panels EPA REG NO 5905 549 EPA EST NO First Letters of Product Batch Code Indicate Producing Establishment 5905 AR 1=WA 5905 GA 1=CG • 5905 IA 1=DI • 5905 CA 1=KC SN 1206/1008 NET CONTENTS MANUFACTURED FOR HELENA CHEMICAL COMPANY 225 SCHILLING BOULEVARD SUITE 300 COLLIERVILLE TENNESSEE 38017 Filename Hardball (5905-549) 080312 CLN doc
PRECAUTIONARY STATEMENTS HAZARDS TO HUMANS AND DOMESTIC ANIMALS DANGER-PELIGRO Corrosive Causes irreversible eye damage Harmful if swallowed Harmful if inhaled Do not get in eyes or on clothing Avoid breathing spray mist or vapor Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals PERSONAL PROTECTIVE EQUIPMENT (PPE) Some materials that are chemical resistant are made of barrier laminate nitnle rubber neoprene rubber or viton If you want more options follow the instructions for category F on an EPA chemical resistance category selection chart All mixers loaders applicators daggers and other handlers must wear ° long sleeved shirt and long pants e shoes and socks • face shield or goggles « chemical resistant gloves when applying with any handheld equipment mixing or loading cleaning up spills or equipment or otherwise exposed to the concentrate and « Chemical resistant apron when mixing or loading cleaning up spills or equipment or otherwise exposed to the concentrate See engineering controls for additional requirements User Safety Requirements Follow manufacturers instructions for cleaning/maintaining PPE If no such instructions for washables exist use detergent and hot water Keep and wash PPE separately from other laundry Engineering Control Statements Pilots must use an enclosed cockpit that meets the requirements listed in the WPS for agricultural pesticides [40 CFR 170240(d)(6)] USER SAFETY RECOMMENDATIONS Users should wash hands before eating drinking chewing gum using tobacco or using the toilet ( Users should remove clothmg/PPE immediately if pesticide gets inside Then wash thoroughly and put on clean clothing If pesticide gets on skin wash immediately with soap and water Users should remove PPE immediately after handling this product Wash the outside of gloves before removing As soon as possible wash thoroughly and change into clean clothing ENVIRONMENTAL HAZARDS For terrestrial uses This product may be toxic to fish and aquatic invertebrates Do not apply directly to water to areas where surface water is present or to mtertidal areas beiow the mean high water mark except as noted on appropriate labels Drift and runoff may be hazardous to aquatic organisms in water adjacent to treated areas Do not contaminate water when disposing of equipment wash waters or nnsate This chemical has properties and characteristics associated with chemicals detected in groundwater The use of this chemical in areas where soils are permeable particularly where the water table is shallow may result in groundwater contamination Application around a cistern or well may result in contamination of drinking water or groundwater Filename Hardball (5905-549) 080312 CLN doc 2
r Aquatic Weed Control Fish breathe dissolved oxygen in the water and decaying weeds also use oxygen When treating continuous dense weed masses it may be appropriate to treat only part of the infestation at a time For example apply the product in lanes separated by untreated strips that can be treated after vegetation in treated lanes has disintegrated During the growing season weeds decompose in a 2 to 3 week period following treatment Begin treatment along the shore and proceed outwards in bands to allow fish to move into untreated areas Waters having limited and less dense weed infestations may not require partial treatments Groundwater Contamination Most cases of groundwater contamination involving phenoxy herbicides such as 2 4 D have been associated with mixing/loading and disposal sites Caution should be exercised when handling 2 4 D pesticides at such sites to prevent contamination of groundwater supplies Use of closed systems for mixing or transferring this pesticide will reduce the probability of spills Placement of the mixing/loading equipment on an impervious pad to contain spills will help prevent groundwater contamination This product may cause injury to desirable plants by contacting foliage stems or roots Use care in all applications to avoid surface water or soil transport to non target plant areas Avoid contamination of irrigation or domestic water supplies Avoid applications in the vicinity of susceptible plants or when winds are blowing toward nearby susceptible plants or when temperature inversions are expected Avoid direct application or spray drift to susceptible plants since very small quantities of this herbicide can cause severe injury in the growing or dormant period Plants contacted may be killed or suffer significant injury resulting in grade or yield losses Do not apply in greenhouses Use an agriculturally accepted drift retardant designed to increase droplet size CHEMIGATION PROHIBITION Do not apply this product through any type of irrigation system Filename Hardball (5905 549) 080312 CLN doc
AGRICULTURAL USE REQUIREMENTS Use this product only in accordance with its labeling and with the Worker Protection Standard 40 CFR part 170 This Standard contains requirements for the protection of agricultural workers on farms forests nurseries and greenhouses and handlers of agricultural pesticides It contains requirements for training decontamination notification and emergency assistance It also contains specific instructions and exceptions pertaining to the statements on this label about personal protective equipment (PPE) and restricted entry interval The requirements in this box only apply to uses of this product that are covered by the Worker Protection Standard Do not enter or allow worker entry into treated areas during the restricted entry interval (REI) of 48 hours PPE required for early entry to treated areas that is permitted under the Worker Protection Standard and that involves contact with anything that has been treated such as plants soil or water is Coveralls Chemical resistant gloves made of any water proof material Shoes plus socks Protective Eyewear NON AGRICULTURAL USE REQUIREMENTS The requirements in this box apply to uses of this product that are NOT within the scope of the Worker Protection Standard for agricultural pesticides (40 CFR Part 170) The WPS applies when this product is used to produce agricultural plants on farms forests nurseries or greenhouses USE REQUIREMENTS FOR PASTURES PERENNIAL GRASSLANDS RANGELAND FALLOW LAND AND NONCROP AREAS Do not enter treated areas until spray has dried TURF USE REQUIREMENTS Do not allow persons (other than applicator) or pets on treated area during application Do not enter treated areas until spray has dried NOTE For application to turf being grown for sale or other commercial use as sod or for commercial seed production or for research purposes follow AGRICULTURAL USE REQUIREMENTS on this label DIRECTIONS FOR USE It is a violation of Federal law to use this product in a manner inconsistent with its labeling SPRAY DRIFT MANAGEMENT A variety of factors including weather conditions (e g wind direction wind speed temperature relative humidity) and method of application (e g ground aerial airblast) can influence pesticide drift The applicator must evaluate all factors and make appropriate adjustments when applying this product Droplet Size When applying sprays that contain 2 4 D as the sole active ingredient or when applying sprays that contain 2 4 D mixed with active ingredients that require a Coarse or coarser spray apply only as a Coarse or coarser spray (ASAE standard 572) or volume mean diameter of 385 microns or greater for spinning atomizer nozzles When applying sprays that contain 2 4 D mixed with other active ingredients that require a Medium or more fine spray apply only as a Medium or coarser spray (ASAE standard 572) or a volume mean diameter of 300 microns or greater for spinning atomizer nozzles Filename Hardball (5905-549) 080312 CLN doc 4
Wind Speed Do not apply at wind speeds greater than 15 mph Only apply this product if the wind direction favors on target deposition and there are not sensitive areas (including but not limited to residential areas bodies of water known habitat for nontarget species nontarget crops) within 250 feet downwind If applying a Medium spray leave one swath unsprayed at the downwind edge of the treated field Temperature Inversions If applying at wind speeds less than 3 mph the applicator must determine if a) conditions of temperature inversion exist or b)stable atmospheric conditions exist at or below nozzle height Do not make applications into areas of temperature inversions or stable atmospheric conditions Susceptible Plants Do not apply under circumstances where spray drift may occur to food forage or other plantings that might be damaged or crops thereof rendered unfit for sale use or consumption Susceptible crops include but are not limited to cotton okra flowers grapes (in growing stage) fruit trees (foliage) soybeans (vegetative stage) ornamentals sunflowers tomatoes beans and other vegetables or tobacco Small amounts of spray drift that might not be visible may injure susceptible broadleaf plants Other State and Local Requirements Applicators must follow all state and local pesticide drift requirements regarding application of 2 4 D herbicides Where states have more stringent regulations they must be observed Equipment All aerial and ground application equipment must be properly maintained and calibrated using appropriate carriers or surrogates Additional requirements for aerial applications The boom length must not exceed 75% of the wmgspan or 90% of the rotor blade diameter Release spray at the lowest height consistent with efficacy and flight safety Do not release spray at a height greater than 10 feet above the crop canopy unless a greater height is required for aircraft safety This requirement does not apply to forestry or rights of way applications When applications are made with a crosswmd the swath will be displaced downwind The applicator must compensate for this by adjusting the path of the aircraft upwind Additional requirements for ground boom application Do not apply with a nozzle height greater than 4 feet above the crop canopy Filename Hardball (5905 549) 080312 CLN doc
STORAGE AND DISPOSAL Do not contaminate water food or feed by storage or disposal PESTICIDE STORAGE Do not store below temperature of 0°F If frozen warm to 40°F and re dissolve before using by rolling or shaking container This product can be stored in an unheated building Store in a safe manner Store in original container only Keep container tightly closed when not in use Reduce stacking height where local conditions can affect package strength Do not store under conditions which might adversely affect the container or its ability to function properly PESTICIDE DISPOSAL Pesticide wastes are toxic Improper disposal of excess pesticide spray mixture or nnsate is a violation of Federal law and may contaminate groundwater If these wastes cannot be disposed of by use according to label instructions contact your State Pesticide or Environmental Control Agency or the Hazardous Waste representative at the nearest EPA Regional Office for guidance CONTAINER DISPOSAL NONREFILLABLE METAL CONTAINER (EQUAL TO OR LESS THAN 5 GALLONS) Do not reuse or refill this container Triple rinse container (or equivalent) promptly after emptying Triple rinse as follows Empty the remaining contents into application equipment or a mix tank and dram for 10 seconds after the flow begins to drip Fill the container 1/4 full with water and recap Shake for 10 seconds Pour rmsate into application equipment or a mix tank or store rmsate for later use or disposal Dram for 10 seconds after the flow begins to drip Repeat this procedure two more times Offer for recycling if available or puncture and dispose of in a sanitary landfill or by other procedures approved by state and local authorities NONREFILLABLE METAL CONTAINER (GREATER THAN 5 GALLONS) Do not reuse or refill this container Triple rinse container (or equivalent) promptly after emptying Triple rinse as follows Empty the remaining contents into application equipment or a mix tank Fill the container V4 full with water Replace and tighten closures Tip container on its side and roll it back and forth ensuring at least one complete revolution for 30 seconds Stand the container on its end and tip it back and forth several times Turn the container over onto its other end and tip it back and forth several times Empty the rmsate into application equipment or a mix tank or store rmsate for later use or disposal Repeat this procedure two more times Offer for recycling if available or puncture and dispose of in a sanitary landfill or by other procedures approved by state and local authorities NONREFILLABLE PLASTIC CONTAINER (EQUAL TO OR LESS THAN 5 GALLONS) Do not reuse or refill this container Triple rinse container (or equivalent) promptly after emptying Triple rinse as follows Empty the remaining contents into application equipment or a mix tank and dram for 10 seconds after the flow begins to drip Fill the container % full with water and recap Shake for 10 seconds Pour rmsate into application equipment or a mix tank or store rmsate for later use or disposal Dram for 10 seconds after the flow begins to drip Repeat this procedure two more times Offer for recycling if available or puncture and dispose of in a sanitary landfill or incineration if allowed by state and local authorities by burning If burned, stay out of smoke NONREFILLABLE PLASTIC CONTAINER (GREATER THAN 5 GALLONS) Do not reuse or refill this container Triple rinse container (or equivalent) promptly after emptying Triple rinse as follows Empty the remaining contents into application equipment or a mix tank Fill the container % full with water Replace and tighten closures Tip container on its side and roll it back and forth ensuring at least one complete revolution for 30 seconds Stand the container on its end and tip it back and forth several times Turn the container over onto its other end and tip it back and forth several times Empty the rmsate into application equipment or a mix tank or store rmsate for later use or disposal Repeat this procedure two more times Offer for recycling if available or puncture and dispose of in a sanitary landfill or incineration if allowed by state and local authorities by burning If burned stay out of smoke Filename Hardball (5905 549) 080312 CLN doc 6
REFILLABLE CONTAINER Refill this container with pesticide only Do not reuse this container for any other purpose Prior to refilling inspect thoroughly for damage such as cracks punctures abrasions and damaged or worn out threads on closure devices Do not refill or transport damaged or leaking containers Check for leaks after refilling and before transportation Cleaning the container before final disposal is the responsibility of the person disposing of the container Cleaning before refilling is the responsibility of the refiller To clean the container before final disposal empty the remaining contents from this container into application equipment or mix tank Fill the container about 10 percent full with water Agitate vigorously or recirculate water with the pump for 2 minutes Pour or pump rmsate into application equipment or rmsate collection system Repeat this rinsing procedure two more times If the container is not being refilled return to the point of purchase or designated location PRODUCT INFORMATION Local conditions crop varieties and application method may affect performance of this product User should consult local extension service agricultural experiment station or university weed specialists and state regulatory agencies for recommendations in your area Best results are obtained when product is applied to young succulent weeds that are actively growing Application rates lower than specified will not be satisfactory on susceptible annual weeds For perennial weeds and conditions such as the very dry areas of the western states where control is difficult the higher listed rates should be used When product is used for weed control in crops the growth stage of the crop must be considered Some plants and weeds especially woody varieties are hard to control and may require repeat applications Application rates should be 1 to 5 gallons of total spray by air or 5 to 25 gallons by ground equipment unless otherwise directed In either case use the same amount of HardBall per acre HardBall should not be allowed to come into contact with desirable susceptible plants such as beans cotton fruit trees grapes legumes ornamentals peas tomatoes and other vegetables HardBall should not be used in greenhouses If stored below freezing it may be necessary to warm product to 40°F and agitate before using This does not affect the efficacy of the product Spray equipment used to apply HardBall or other products containing 2 4 D should not be used for any other purpose until thoroughly cleaned with a suitable chemical cleaner WEEDS CONTROLLED HardBall will control or partially control the following as well as many other noxious plants susceptible to 2 4 D Alders Alligatorweed American Lotus Arrowhead Artichoke Austrian Fieldcress Biden Bittersweet Bittercress smallflower Black eyed Susan Bitterweed Bitter wmtercress Blessed Thistle Blue lettuce Blue Thistle Blueweed Texas Box elder Broomweed common Buckhorn Bull nettle Bull Thistle Bulrush Burdock common Bur ragweed Buttercup smallflowered Burhead Carpetweed Carolina geranium Chickweed Catnip Chicory Cmquefoil common & rough Cockle Cocklebur common Filename Hardball (5905-549) 080312 CLN doc j
Coffeebean Creeping jenny Croton (Texas woolly) Dandelion Dogfennel (mayweed) Evening primrose common Fanweed Fleabane Florida Pusley Four o clock Frenchweed Goatsbeard Hemp Henbit Honeysuckle Indigo Jerusalem artichoke Jimsonweed Ladysthumb Loco Bigbend Marestail Mexican weed Mornmgglory (annual common woolly) Mustards (except blue) prior to bolting Parrotfeather Pennywort Plantains Peppergrass Pokeweed Poverty weed Prickly lettuce Purslane common Radish Ragweeds (common giant) Rough fleabane Shepherdspurse Sneezeweed bitter Spanish Needles Stinging Nettles Stmkweed Sunflower Sweetclover (annual) Tarweed Thistles Toadflax Coffeeweed Cornflower Curly indigo Devil s Claw Proboscidea louisianica Duckweed Elderberry Evening primrose cutleaf Fixweed Figwort Goosefoot Galmsoga (elderberry hairy) Gumweed Healall Horsetail Indian Mallow Jewelweed Klamathweed Lambsquarters common Marijuana Mallow (Venice dwarf little) Marshelder Milk vetch iv Mousetail Nutgrass Parsnip Pennycress (fanweed) Pepperweeds (except perennial) Poison ivy Poorjoe Primrose Puncture vine Quickweed Redstem Rush Sicklepod Sowthistle (annual spiny) Spatterdock Speedwell St John s Wort Sumacs Tanweed Velvetleaf Venicemallow Virginia copperleaf Water hyacinth Filename Hardball (5905 549) 080312 CLN doc
10, Tumbleweed Vetches except hairy Virginia creeper Water lily Wild carrot Wild hemp Wild mustard Wild radish Wild sweet potato Witchweed Yellow goatsbeard Yellow starthistle Water plantain Water primrose Water shield Wild lettuce Wild parsnip Wild rape Wild strawberry Willow Wormwood Yellow rocket Weeds Partially Controlled (Higher rates and/or repeated applications may be needed) Alfalfa Bindweeds (hedge European) Bull thistle Chamise Corn gromwell Dandelion Dogbanes Ground ivy Henbit Ironweed Knotweed Manzanita Nettles Prickly lettuce Russian thistle Sagebrush (big sand) Sand shmnery oak Salt Cedar (T ramossissim) Smartweed Pennsylvania Vervains Western ironweed Wild garlic Beggarticks Buckbrush Canada thistle Clover red Coyotebrush Docks Goldenrod Hawkweed Hoary cress Mallow Many flowered aster Musk thistle Orange Hawkweed Peppergrass Rabbitbrush Sage coastal Salsify (western common) Smartweed annual Tansyragwort Vetch hairy Wild carrot Wild onion Weeds Partially Controlled And For Which Locally Resistant Biotypes May Occur Pigweed Weeds Suppressed When Another Labeled Herbicide Is Also Applied Bindweed (field) Russian knapweed Filename Hardball (5905 549) 080312 CLN doc
r r i//f i MIXING INSTRUCTIONS HardBall is a macro emulsifiable concentrate formulation intended for dilution in water for many applications For certain specified applications liquid fertilizer or oil may replace part or all of the water as diluent If dry flowable (DF) wettable powder (WP) or flowable (F) tank mix products are to be used these should generally be added to the spray tank first Refer to the mixing directions on the labels of the tank mix products For best results thoroughly clean sprayer immediately after use by flushing system with water and heavy duty detergent such as Wipe Out® Water Spray To prepare a water spray mixture fill clean spray tank about 1/2 to 2/3 full with clean water With agitation turned on add the required amount of HardBall Continue agitation while adding balance of water and during spray operations NOTE In water this product forms a macro emulsion and can separate upon prolonged standing If spray mixture is allowed to stand agitate again to assure uniformity Liquid Fertilizer Spray Due to increased risk of crop foliage burn with fertilizer use only as recommended on this label or supplemental labeling distributed for HardBall Use fertilizer rate recommended locally Fill clean spray tank about 1/2 to 2/3 full with liquid nitrogen fertilizer (UAN or urea) solution Add required amount of product with vigorous agitation running Continue agitation while adding balance of liquid fertilizer and during spray operations Application should be made immediately Overnight storage of mixture is not recommended Application during very cold (near freezing) temperatures is not advisable because of the likelihood of crop injury This product is formulated to be compatible with most liquid nitrogen solutions however due to variability in fertilizers users may wish to perform a jar compatibility test before large scale mixing Oil Spray Use only as recommended on this label or supplemental labeling distributed for HardBall Fill clean spray tank about 1/2 to 2/3 full with an oil approved for agricultural use (diesel oil fuel oil stove oil etc) Add required amount of product with agitation turned on Continue agitation while adding balance of oil The resulting mixture is a solution and will generally remain uniform without agitation once mixed However agitation is suggested if available Do not allow any water to get into the spray mixture to avoid formation of an invert emulsion (mayonnaise consistency) Water Spray With Oil Use only as recommended on this label or supplemental labeling distributed for HardBall Where a combination of water and oil diluent is recommended the use of emulsifiable crop oil or crop oil concentrate is suggested since mild agitation will be sufficient Mix in the sequence of water product and oil If diesel or other non emulsified oils listed above under Oil Spray are desired for use with water add no more than 1 quart of such oil per 1 gallon of water and agitate vigorously until tank is emptied If possible premix non emulsified oil with this product and add this premix to a mostly filled spray tank with agitation on Follow these procedures carefully to avoid formation of an invert emulsion (mayonnaise consistency) APPLICATION PROCEDURES Use calibrated spray equipment for all types of applications to assure applying the recommended amount of spray mixture per acre Use sufficient spray volume within the ranges specified to obtain good coverage of weeds HardBall is absorbed sufficiently within 1 hour after application to provide adequate weed control Ground Broadcast Spray Unless otherwise specified in the appropriate crop or non crop directions apply in 5 or more gallons of spray solution per acre Use enough spray volume to provide uniform coverage of weeds taking into account the amount of vegetation present and the type of application equipment to be used As crop canopy and weed density increase a higher spray volume may be needed for equivalent coverage and weed control Typical crop applications utilize 10 to 50 gallons of spray solution per acre while certain high volume non crop applications may utilize more than 100 Filename Hardball (5905-549) 080312 CLN doc \Q
r gallons per acre Use coarse sprays to minimize potential spray drift Do not apply with hollow cone nozzles or other nozzles that produce fine spray droplets Boom spraying with flat fan or low volume nozzles is generally most suitable for ground broadcast applications Ground Band Spray Determine band equivalents to broadcast rates and volumes by the following formulas Band width in inches x Broadcast = Band rate Row width in inches rate per acre per acre Band width in inches x Broadcast = Band volume Row width in inches volume per acre per acre Aerial Broadcast Spray Unless otherwise specified in the appropriate crop or non crop directions apply in 1 to 5 gallons of spray solution per acre For best coverage and weed control as well as reduced potential for spray drift a minimum of 3 gallons per acre is suggested Avoid using nozzles or nozzle configurations that generate fine droplets One configuration usually found to be suitable includes straight stream nozzles (such as disk with no swirl plate) directed straight back along the wind stream Mechanical flagging or GPS (Global Positioning Systems) is suggested to obtain more uniform application With fixed wing or helicopter application an exactly even swath deposition may not be achieved and consequently crop injury or pesticide nonperformance may result wholly or in part Do not apply by air during periods of thermal inversion Avoid application if potential for drift is excessive and/or susceptible crops are growing in the vicinity Filename Hardball (5905-549) 080312 CLN doc
( TANK MIXES Unless otherwise prohibited on this label or the label of an intended tank mix product this product may be applied in combination with any herbicide registered for the same crop timing and method of application Observe the most restrictive label statements of various tank mix products used LIABILITY FOR CROP INJURY RESULTING FROM A TANK MIXTURE NOT SPECIFIED ON THIS LABEL OR SUPPLEMENTAL LABELING DISTRIBUTED FOR HardBall IS SPECIFICALLY DISCLAIMED BY HELENA CHEMICAL COMPANY Glyphosate Tank Mixes HardBall + Glyphosate (various formulations) may be used on all approved crops use sites and use patterns approved on both labels HardBall should be used at the rate of 1 5 3 pints in combination with the appropriate rate of Glyphosate per acre to provide best control of weed pest species Consult the Glyphosate label to determine proper rate of Glyphosate to be used in combination with HardBall COMPATIBILITY Before full scale mixing of this product with other herbicides fertilizer solutions and adjuvants it is advisable to determine the compatibility of the proposed mixture Use proportionate quantities of each ingredient and mix in a small container Always mix one product thoroughly with the diluent before adding another product If no incompatibility is evident after 30 minutes the mixture is generally compatible for spraying PUNTING IN TREATED AREAS Labeled Crops Within 29 days following an application of this product plant only those crops named as use sites on this or other registered 2 4 D labels Follow more specific limitations if any provided in the directions for individual crops Labeled crops may be at risk for crop injury or loss when planted soon after application especially in the first 14 days Degradation factors described below should be considered in weighing this risk Other Crops All other crops may be planted 30 or more days following an application without concern for illegal residues in the planted crop However under certain conditions there may be a risk of injury to susceptible crops Degradation factors described below should be considered in weighing this risk Under normal conditions any crop may be planted without risk of injury if at least 90 days of soil temperatures above freezing have elapsed since application Degradation Factors When planting into treated areas the risk of crop injury is less if lower rates of product were applied and conditions following application have included warm moist soil conditions that favor rapid degradation of 2 4 D Risk is greater if higher rates of product were applied and soil temperatures have been cold and/or soils have been excessively wet or dry in the days following application Consult your local Agricultural Extension Service for information about susceptible crops and typical soil conditions in your area APPLICATIONS READ ALL PROCEEDING GENERAL SECTIONS OF LABEL AND WARRANTY BEFORE USE Unless otherwise specified applications may be made by ground or air equipment Ground applications may provide more thorough coverage and better weed control For selective postemergent weed control in crops do not add oil surfactant fertilizer or other additives unless specifically recommended on this label or supplemental labeling Filename Hardball (5905 549) 080312 CLN doc 12
r ASPARAGUS CROP STAGE After cutting APPLICATION RATE/ACRE 892 pints (1 75 - 2 0 Ibs acid equivalent) DIRECTIONS/TIMING Apply on actively growing weeds RESTRICTIONS AND LIMITATIONS FOR USE ON ASPARAGUS e PHI Do not harvest within 3 days of application « Max application rate/acre 9 2 pints (2 0 Ibs acid equivalent) o Max seasonal rate 2 3 gals (4 0 ibs acid equivalent per acre) » Do not exceed two applications per crop cycle » Do not apply within 30 days of previous application LOW BUSH BLUEBERRIES CROP STAGE Postemergence Postharvest APPLICATION RATE/ACRE Wiper solution containing 0 14 to 0 17 pints (2 24 to 2 72 ounces) (003 00375 Ibs /gallon (36 45g/l) acid eq ) Solution containing 75 1 0 Ib acid equivalent per 10 gallons of oil DIRECTIONS/TIMING Make directed wipe or spot applications when tips are above the crop Make directed application to cut hardwoods in row middles in summer or fall after harvest RESTRICTIONS AND LIMITATIONS FOR USE ON LOW BUSH BLUEBERRIES Postemergence « Limited to one postemergence application per year « Maximum of 2 72 ounces (0375 Ibs acid equivalent) e « Avoid herbicide contact with blueberry foliage 0 Apply only in the nonbearmg year Postharvest « Limited to one post harvest application per crop cycle • Max of 1 0 Ib ae/gallon spray solution per application • For spot or directed wipe treatment only • Apply only in non bearing years Filename Hardball (5905-549) 080312 CLN doc 13
HIGH BUSH BLUEBERRIES CROP STAGE Postemergence Postharvest APPLICATION RATE/ACRE 3540 pints 3540 pints DIRECTIONS/TIMING Make directed or shielded application in the spring Make directed application to row middles in summer or fall after harvest RESTRICTIONS AND LIMITATIONS FOR USE ON HIGH BUSH BLUEBERRIES Postemergence and Postharvest • PHI Do not harvest within 30 days of application « Limited to two (2) applications per year « Maximum rate 102 ounces (1 4 Ibs acid equivalent) per acre per application CEREAL GRAINS (Spring Wheat and Tnticale) WEEDS IN CROPS AMOUNT OF HARDBALL PER ACRE DIRECTIONS FOR USE Not underseeded with legumes Onset of Tillering Stage Postemergence Annual and biennial broadleaf weeds Perennial broadleaf weeds 1 1 75 pints Apply after gram is well tillered (usually about 4 to 8 inches high) Do not spray gram in the boot to dough stage Grains are generally tolerant of these treatments but risk of crop injury is greater than at full tillering stage Do not make application if the risk of injury is unacceptable The onset of tillering stage is defined as gram having 1 or more tillers as well as 3 or more leaves Full Tillering Stage Postemergence Annual and biennial broadleaf weeds Perennial broadleaf weeds 1 3 25 pints For these applications full tillering stage is defined as gram that has 3 or more tillers and the flag leaf should not be visible Apply after gram is 8 inches tall Do not spray gram in boot to dough stage Do not spray alfalfa or sweet clover unless the infestation is severe and injury to these legumes can be tolerated Emergency Weed Control in Tnticale Wheat Perennial broadleaf weeds 45 To control difficult weed problems in certain areas such as under dry conditions especially in Western areas higher rates up to 4 5 pints per acre may be needed Higher rates increase the risk of crop injury The severity of the weed problem should be balanced against the possibility of crop injury Do not apply before the tiller stage or from boot to dough stage
- Use the lower rate if small annual and biennial weeds are the major problem Use the higher rate if perennial weeds or annual and biennial weeds are present which are in the hard to kill categories as determined by local experience The higher rates increase the risk of gram injury and should be used only where the weed control problem justifies the gram damage risk Do not apply Hardball to gram in the seedling stage Filename Hardball (5905 549) 080312 CLN doc 14
f RESTRICTIONS AND LIMITATIONS FOR USE ON SPRING WHEAT & TRITICALE • For aerial application on gram apply HardBall in 3 to 10 gallons of water per acre e For ground application a minimum of 10 to 15 gallons of water per acre is needed for proper spray coverage « Do not permit dairy animals or meat animals being finished for slaughter to forage treated gram fields within 2 weeks after treatment » Do not feed treated straw to livestock if an emergency treatment as described above is applied » Postemergence 0 Limited to one application per crop cycle 0 Maximum of 92 ounces per acre per application « Preharvest 0 Limited to one application per crop cycle 0 Maximum of 36 ounces per acre per application « Preharvest interval (PHI) is 14 days » Limited to 1 gallon per acre per crop cycle WINTER WHEAT BARLEY AND RYE WEEDS IN CROPS AMOUNT OF HARDBALL PER ACRE DIRECTIONS FOR USE Not underseeded with legumes Onset of Tillering Stage Postemergence Annual and biennial broadleaf weeds Perennial broadleaf weeds 1 3 25 pints Apply after gram is well tillered (usually about 4 to 8 inches high) Do not spray gram in the boot to dough stage Grains are generally tolerant of these treatments but risk of crop injury is greater than at full tillering stage Do not make application if the risk of injury is unacceptable The onset of tillering stage is defined as gram having 1 or more tillers as well as 3 or more leaves Full Tillering Stage Postemergence Annual and biennial broadleaf weeds Perennial broadleaf weeds 1 3 25 pints For these applications full tillering stage is defined as gram that has 3 or more tillers and the flag leaf should not be visible (usually 4 to 8 inches tall) Do not spray gram in boot to dough stage Do not spray alfalfa or sweet clover unless the infestation is severe and injury to these legumes can be tolerated Emergency Weed Control in Tnticale Wheat Perennial broadleaf weeds 4 5 pints To control difficult weed problems in certain areas such as under dry conditions especially in Western areas higher rates up to 4 5 pints per acre may be needed Higher rates increase the risk of crop injury The severity of the weed problem should be balanced against the possibility of crop injury Do not apply before the tiller stage or from boot to dough stage Use the lower rate if small annual and biennial weeds are the major problem Use the higher rate if perennial weeds or annual and biennial weeds are present which are in the hard to kill categories as determined by local experience The higher rates increase the risk of gram injury and should be used only where the weed control problem justifies the gram damage risk Do not apply Hardball to gram in the seedling stage Filename Hardball (5905 549) 080312 CLN doc 15
r RESTRICTIONS AND LIMITATIONS FOR USE ON CEREAL GRAINS • For aerial application on gram apply HardBall in 3 to 10 gallons of water per acre « For ground application a minimum of 10 to 15 gallons of water per acre is needed for proper spray coverage « Do not permit dairy animals or meat animals being finished for slaughter to forage treated gram fields within 2 weeks after treatment « Do not feed treated straw to livestock if an emergency treatment as described above is applied » Postemergence Limited to one application per crop cycle 0 Maximum of 5 68 pints per acre per application o Preharvest 0 Limited to one application per crop cycle 0 Maximum of 36 ounces per acre per application • Preharvest interval (PHI) is 14 days o Limited to 1 gallon per acre per crop cycle CEREAL GRAINS (Not Underseeded with a Legume) (OATS) WEEDS IN CROPS AMOUNT OF HARDBALL PER ACRE* (Average Conditions) DIRECTIONS FOR USE Spring Planted Oats Full Tillering Stage Postemergence Annual and biennial Broadleaf weeds Perennial broadleaf weeds 1 pint Apply in sufficient water to give good coverage Apply after the fully tillered stage except during the boot to dough stage Note Oats are less tolerant to 2 4 D than wheat or barley andmore likely to be injured Grains should have 3 or more tillers and the flag leaf should not be visible Oats are less tolerant to HardBall than wheat or barley and present a greater risk of crop injury The severity of the weed problem should be balanced against the possibility of crop injury Larger weeds and hard to kill weeds may be poorly controlled especially under dry conditions Fall Planted Oats 1 3 25 pints Apply after full tillering but before early boot stage Some difficult weeds may require higher rates per acre for maximum control but injury may result Do not spray during or immediately following cold weather Note Oats are less tolerant to 2 4 D than wheat or barley and more likely to be injured Pre Harvest 2 pints Apply with recommended amount of water per acre when grains are in the hard dough stage to control large weeds that may interfere with harvest Best results will be obtained when soil moisture is sufficient to cause succulent weed growth Addition of a nonionic surfactant such as INDUCE® OR DYNE AMIC® usually improves weed control Filename Hardball (5905-549) 080312 CLN doc 16
If band treatment is used base the dosage rate on the actual area sprayed RESTRICTIONS AND LIMITATIONS FOR USE ON OATS (Not Underseeded with a Legume) o The higher rates increase the risk of gram injury and should be used only where the weed control problem justifies the grain damage risk e Apply HardBall in sufficient water for adequate coverage o Do not permit dairy animals or meat animals being finished for slaughter to forage treated gram fields within 2 weeks after treatment « Do not feed treated straw to livestock • Postemergence Limited to one application per crop cycle 0 Maximum of 92 ounces per acre per application • Preharvest 0 Limited to one application per crop cycle 0 Maximum of 36 ounces per acre per application • Preharvest interval (PHI) is 14 days » Limited to 1 gallon per acre per crop cycle Livestock Feeding Restrictions Do not permit dairy animals or meat animals being finished for slaughter to forage or graze treated gram fields within 2 weeks after treatment Do not feed treated straw to livestock if an emergency and/or preharvest treatment are applied Liquid Nitrogen Fertilizers At full tiller product may be combined with liquid nitrogen fertilizers suitable for foliar application to small grains Refer to Mixing Instructions section of this label for further information Fertilizers can increase foliage contact burn of herbicides Reducing the fertilizer rate and concentrations will reduce the hazard of foliage burn Tank Mixtures HardBall may be tank mixed with other herbicides for control of certain weeds in small grains Use tank mix directions appearing on the labels of the specific herbicides when tank mixing with this product Observe all precautions and limitations on labeling of product used in a particular tank mix Suggested 2 way tank mix combinations are listed below HardBall + Ally® (Use on Wheat & Barley only) HardBall + Amber® (Use on Wheat & Barley only) HardBall + Canvas® (Use on Wheat & Barley only) HardBall + Express® (Use on Wheat & Barley only) HardBall + Finesse® (Use on Wheat & Barley only) HardBall + Glean® (Use on Wheat Oats & Barley only) HardBall + Harmony® Extra (Use on Wheat Oats & Barley only) HardBall + Peak® (Use on Wheat Oats Barley & Rye) HardBall + Bromoxynil (Use on Wheat Oats Barley & Rye) HardBall + Dicamba (Use on Wheat Oats & Barley only) HardBall + Diuron (Use on Wheat Oats & Barley only) HardBall + Metnbuzm (Use on Wheat & Barley only) Suggested 3 way tank mixes include HardBall + Bromoxynil or Dicamba or Diuron or Metnbuzm + Ally® HardBall + Bromoxynil or Dicamba or Diuron or Metnbuzm + Amber® HardBall + Bromoxynil or Dicamba or Diuron or Metnbuzm + Canvas® HardBall + Bromoxynil or Dicamba or Diuron or Metnbuzm + Express® Filename Hardball (5905-549) 080312 CLN doc 17
HardBall + Bromoxynil or Dicamba or Diuron or Metnbuzm + Finesse® HardBall + Bromoxynil or Dicamba or Diuron or Metnbuzm + Glean® HardBall + Bromoxynil or Dicamba or Diuron or Metnbuzm + Harmony® Extra HardBall + Bromoxynil or Dicamba or Diuron or Metnbuzm + Peak® HardBall + Diuron + Metnbuzm HardBall + Diuron + Dicamba HardBall + Diuron + Bromoxynil HardBall + Dicamba + Metnbuzm HardBall + Dicamba + Bromoxynil HardBall + Metnbuzm + Bromoxynil Refer to the previous section (Suggested 2 way tank mix combinations) and the registered product labels to determine the specific small gram crops that may be treated CORN (Field AND Pop) WEEDS IN CROPS AMOUNT OF HARDBALL PER ACRE DIRECTIONS FOR USE Corn (Field and Pop) Preplant Fine and medium texture soils having 1% or more organic matter For coarse textured soils with 2% or more organic matter Preemergence Fine and medium texture soils having 1% or more organic matter For coarse textured soils with 2% or more organic matter Postemergence Annual broadleaf weeds Early Postemergence (from spike to 4 leaf stage or up to 8 inches) Perennial broadleaf weeds Late Postemergence (corn is 8 36 inches tall before tasselmg) Preharvest 1 4 5 pints 1 3 0 pints 145 1 pint* 1/2 pint to 2 25 pints 1 3 to 2 25 pints 2 to 6 75 pints To control emerged broadleaf weed seedlings or existing cover crops prior to planting corn apply 7 to 14 days before planting Use high rate for less susceptible weeds or cover crops such as alfalfa Apply 3 to 5 days after planting but before corn emerges Liquid fertilizers and agriculturally approved surfactants may be added *Due to the lower rate partial weed control may result on coarse soils Apply when weeds are small and corn is less than 8 inches tall (to top of canopy) Many types of adjuvants will increase risk of crop injury Where an adjuvant is required because of tank mixing with another herbicide use the lowest recommended concentration of a nonionic surfactant such as INDUCE® (often at 0 25% vol /vol or less) to minimize such risk Corn may be brittle and subject to breaking by wind and/or cultivation especially in the 2 weeks following application Avoid spraying just after corn leaves unfold When corn is 8 36 inches tall use drop Filename Hardball (5905 549) 080312 CLN doc 18
nozzles and keep spray off foliage Treat perennial weeds when they are in the bud to bloom stage The timing can extend until corn is 36 inches tall or to tasselmg whichever comes first but weeds usually become too large and hard to control Lowest rates may not provide adequate weed control unless used in a tank mix with another registered herbicide After the hard dough (or denting) stage when silks have turned brown apply the appropriate rate to suppress perennial weeds such as hemp dogbane or field bindweed and many tall weeds such as cocklebur pigweed and sunflower that interfere with harvest Weed seed production will also be suppressed if application is prior to the flowering stage of weeds The high rate is recommended under dry conditions RESTRICTIONS AND LIMITATIONS FOR USE ON Corn (Field and Pop) • Corn (Field and Pop) 0 Preharvest Interval (PHI) is 7 days 0 Do not use treated crop as fodder for 7 days following application 0 Do not apply on fine or coarse textured soils (silt & clay loams) with less than 1% organic matter or on coarse textured soils (sand sandy loam loamy sand) with less than 2% organic matter 0 Maximum Use rate per acre per crop cycle is 1 75 gallons 0 Preplant or Preemergence « Limited to one application per crop cycle « Maximum of 4 5 pints per acre per application « Do not apply preemergence if a preplant application of this product was made 0 Postemergence • Limited to one application per crop cycle » Maximum of 2 25 pints per acre per application » Do not spray corn in the tassel to dough stage o Do not apply with liquid fertilizer or oil • Postemergence application should not follow a preplant or preemergence application by less than 3 weeks 0 Preharvest » Limited to one application per crop cycle » Maximum of 6 75 pints/acre per preharvest application Filename Hardball (5905-549) 080312 CLN doc 19
r CORN (Sweet) WEEDS IN CROPS AMOUNT OF HARDBALL PER ACRE DIRECTIONS FOR USE Corn (Sweet) Preplant Fine and medium texture soils having 1% or more organic matter For coarse textured soils with 2% or more organic matter Preemergence Fine and medium texture soils having 1% or more organic matter For coarse textured soils with 2% or more organic matter Postemergence Annual broadleaf weeds Early Postemergence (from spike to 4 leaf stage or up to 8 inches) Perennial broadleaf weeds Late Postemergence (corn is 8 36 inches tall before tasselmg) 1 4 5 pints 1 3 0 pints 145 1 pint 2 25 pints 1 3 to 2 25 pints To control emerged broadleaf weed seedlings or existing cover crops prior to planting corn apply 7 to 14 days before planting Use high rate for less susceptible weeds or cover crops such as alfalfa Apply 3 to 5 days after planting but before corn emerges Liquid fertilizers and agriculturally approved surfactants may be added *Due to the lower rate partial weed control may result on coarse soils Apply when weeds are small and corn is less than 8 inches tall (to top of canopy) Many types of adjuvants will increase risk of crop injury Where an adjuvant is required because of tank mixing with another herbicide use the lowest recommended concentration of a nonionic surfactant such as INDUCE® (often at 0 25% vol /vol or less) to minimize such risk Corn may be brittle and subject to breaking by wind and/or cultivation especially in the 2 weeks following application Avoid spraying just after corn leaves unfold When corn is 8 36 inches tall use drop nozzles and keep spray off foliage Treat perennial weeds when they are in the bud to bloom stage The timing can extend until corn is 36 inches tall or to tasselmg whichever comes first but weeds usually become too large and hard to control Lowest rates may not provide adequate weed control unless used in a tank mix with another registered herbicide Filename Hardball (5905-549) 080312 CLN doc 20
RESTRICTIONS AND LIMITATIONS FOR USE ON Corn (Sweet) • Corn (Sweet) 0 Preharvest Interval (PHI) is 45 days 0 Do not use treated crop as fodder for 7 days following application 0 Minimum of 21 days between applications 0 Do not apply on fine or coarse textured soils (silt & clay loams) with less than 1 % organic matter or on coarse textured soils (sand sandy loam loamy sand) with less than 2% organic matter 0 Maximum Use rate per acre per crop cycle is 110 ounces 0 Preplant or Preemergence « Limited to one application per crop cycle <» Maximum of 4 5 pints per acre per application • Do not apply preemergence if a preplant application of this product was made 0 Postemergence « Limited to one application per crop cycle « Maximum of 2 25 pints per acre per application o Do not spray corn in the tassel to dough stage « Do not apply with liquid fertilizer or oil o Postemergence application should not follow a preplant or preemergence application by less than 3 weeks CRANBERRIES CROP STAGE Dormant Postemergence APPLICATION RATE/ACRE 1 6 - 2 25 gallons 35-55 pints DIRECTIONS/TIMING Make broadcast application in the dormant season Make directed wipe or spot applications when weed tops are above crop RESTRICTIONS AND LIMITATIONS FOR USE ON CRANBERRIES • PHI Do not harvest within 30 days of application « Dormant Make only one dormant application per crop cycle « Max Dormant rate 2 25 gallons (4 Ibs acid equivalent) per acre in the dormant season • Postemergence Limited to (2) two applications per crop cycle • Maximum Postemergence rate 5 5 pints (1 2 Ibs ae/acre per postemergence application) Filename Hardball (5905-549) 080312 CLN doc 21
FILBERTS CROP STAGE For sucker control APPLICATION RATE/ACRE 345 pints DIRECTIONS/TIMING For control of suckers spray to wet leaves and stems of suckers that are 6 to 8 inches in height during April through August RESTRICTIONS AND LIMITATIONS FOR USE ON FILBERTS o PHI Do not harvest nuts within 45 days of application » Minimum Allow at least 30 days between applications «» Limited to 4 applications per year « Maximum Use Rate 4 5 pints per 100 gallons of spray solution per application GRAPES CROP STAGE APPLICATION RATE/ACRE DIRECTIONS/TIMING Apply after shatter following bloom and before grape shoots reach the ground or during dormant season 4 5 - 6 25 pints Applications to at least 3 year old established vineyard Use hooded boom sprayer or equivalent to direct coarse spray to weeds and minimize potential contact with grape foliage shoots or stems RESTRICTIONS AND LIMITATIONS FOR USE IN GRAPES «> For use only in California « The preharvest interval (PHI) is 100 days 9 Limited to 1 application per crop cycle » Maximum of 100 ounces (1 36 Ibs ae/acre) per application NOTE Do not use more than 1 36 ibs acid equivalent per season Do not apply to grape foliage shoots or stems FALLOW LAND AND CROP STUBBLE Fallow land or land idle between crops may be subject to unwanted weed growth For control of many annual broadleaf species apply at the rate of 1 0 - 4 0 pints per acre To aid in suppressing certain perennial or biennial broadleaf weeds (including cotton regrowth) this product may be applied at the rate of 2 25 - 8 0 pints per acre either alone or in combination with other registered herbicides such as dicamba or picloram Use the high rate on older plants drought stressed plants or for hard to kill species See Planting in Treated Areas section Follow more restrictive limitations for tank mix products used HardBall may be used to kill fall alfalfa stands in preparation for spring planting of row crops under conservation tillage The treated alfalfa crop cannot be grazed fed to livestock or cut for hay Filename Hardball (5905 549) 080312 CLN doc 22
Restrictions and Limitations » Plant only labeled crops within 29 days following application • Limited to 2 applications per year » Maximum of 1 15 gallons (2 0 Ibs ae/acre) per application « Minimum of 30 days between applications GRASS PASTURES To control many emerged broadleaf weeds apply 10-40 pints HardBall per acre Addition of a nonionic surfactant such as INDUCE® or DYNE AMIC® usually improves weed control Preferred timing is in the early spring when sufficient weeds have emerged and when weeds are small and actively growing but before weeds are too mature Summer applications to older drought stressed weeds are less effective However weeds are more susceptible again in the fall when cooler wetter conditions support active growth before a killing frost For fall treatment of mature weeds or perennial weed regrowth use 35-80 pints per acre Several seasons of spring plus fall treatments may be necessary to control certain perennials For susceptible annual and biennial broadleaf weeds Use 1 0 Ibs ae per acre per application For moderately susceptible biennial and perennial broadleaf weeds Use 1 - 2 Ibs ae per acre per application For difficult to control weeds and wood plants Use 2 Ibs ae per acre per application Plant Response Injury may result to bent grass other warm season or southern grasses and alfalfa clover or other legumes Do not use if this risk of injury is unacceptable Clovers may recover from early spring applications If grass seed production is desired do not apply when grass is in boot to milk stage or after heading begins Do not apply to newly seeded areas until grass is well established Reseeding is not recommended for at least 30 days following application Addition of a surfactant may increase the risk of injury to newly seeded grasses Livestock Feeding Restrictions Do not graze dairy animals on treated areas within 7 days after application Do not graze meat animals on treated areas within 3 days before slaughter Do not cut treated grass for hay within 30 days of application RESTRICTIONS AND LIMITATIONS GRASS PASTURES « Plant only labeled crops within 29 days following application o Limited to 2 applications per year e Maximum of 1 15 gallon (2 Ibs ae)/acre per application « Minimum of 30 days between applications • Do not cut forage for hay within 7 days of application « If grass is to be cut for hay Agricultural Use Requirements for the Worker Protection Standard are applicable GRASS SEED CROPS To control many emerged broadleaf weeds apply 1 0 - 3 25 pints per acre Use on established stands of cool season grass seed crops such as bentgrass bluegrass fine fescue tall fescues orchard grass annual ryegrass and perennial ryegrass Make applications in the spring from the tiller to early boot stage Do not spray in boot stage New spring seedlings may be treated after the grasses have more than 5 true leaves On established stands that have had the seed crop removed perennial weed regrowth may be treated in the fall at up to 4 5 pints per acre Refer to Plant Response and Livestock Feeding Restrictions under GRASS PASTURES section above « Do not apply more than 2 applications per year • The maximum individual application rate is 2 Ibs ae per acre per application • The retreatment interval is 21 days Filename Hardball (5905-549) 080312 CLN doc 23
HOPS WEEDS IN CROPS Annual broadleaf weeds AMOUNT OF HARDBALL PER ACRE 1 2 pints DIRECTIONS FOR USE Make directed applications to the row middles RESTRICTIONS AND LIMITATIONS HOPS • Limited to three (3) applications per crop cycle » Maximum of 36 ounces per acre per application « Maximum of 110 ounces per acre per crop cycle « Minimum of 30 days between applications e Preharvest Interval (PHI) is 28 days after application ROADSIDES MEDIANS HIGHWAY RAILROAD UTILITY AND PIPELINE RIGHTS OF WAY VACANT LOTS AROUND UTILITY INSTALLATIONS TRANSFORMERS PUMP HOUSES AND BUILDINGS STORAGE AREAS FENCES GUARDRAILS LUMBERYARDS INDUSTRIAL SITES AIRPORTS TANK FARMS FARMSTEADS AND SIMILAR NONCROP AREAS For the control of many broadleaf weeds and small woody plants applications may be as broadcast sprays small areas or spot treatments Regardless of the method of application use adequate spray volume for full coverage of weeds Preferred application timing is in the early spring when sufficient weeds have emerged and are still small an actively growing and before weeds are too mature Summer applications to older drought-stressed weeds are less effective However weeds and small woody plants are more susceptible again in the fall when cooler wetter conditions support active growth before a killing frost Postemerqence (annual and perennial weeds) • Limited to 2 applications per year 9 Maximum of 4 5 quarts (2 0 Ibs) ae/acre per application « Minimum of 30 days between applications Note Plant Response Bent grass other warm season or southern grasses alfalfa clover or other legumes may be killed or injured Do not apply when grass is in boot to milk stage or after heading begins if grass production is desired Do not apply to newly seeded areas until grass is well established Reseedmg is not recommended for at least 30 days following application Do not make repeat applications within 30 days of the previous application Apply no more than 4 5 quarts (2 0 Ibs acid equivalent) per acre per use season Postemergence (woody plants) 9 Limited to 1 application per year o Maximum of 2 25 gallons (4 0 Ibs) ae/acre per year Applications to non cropland areas are not applicable to treatment of commercial timber or other plants being grown for sale or other commercial use or for commercial seed production or for research purposes Postemergence Control of Annual and Perennial Weeds Apply 0 5 1 gallon of HardBall to emerged weeds For best results treat when weeds are young and actively growing Postemergence Control of Woody Plants Apply 05-2 gallons of HardBall to trees and brush when foliage is fully expanded and plants are actively growing Filename Hardball (5905-549) 080312 CLN doc 24
Special Uses On rights of way Up to2 25 gallons (4 0 Ibs acid equivalent) can be applied in a single application This includes electrical power lines communication lines pipelines highways and railroads that intersect wooded areas or stands of trees brush and woody plants Usage under this section is not applicable to treatment of commercial timber or other plants being grown for sale or other commercial use or for commercial seed production or for research purposes ORNAMENTAL AND RECREATIONAL TURFGRASSES LAWNS GOLF COURSES (Fairways Aprons Tees and Roughs), PARKS AND CEMETERIES Do not apply more than 1 5 Ibs ae per acre per application The maximal seasonal application rate is 3 0 Ibs ae per acre excluding spot treatments The maximum number of broadcast applications per treatment site is 2 per year For best results do not mow turf 1 to 2 days before or after application Turf watering should be delayed for at least 1 hour after application Avoid contacting desirable trees shrubs flowers or vegetables since plant injury may result Do not apply to newly seeded areas until grass is well established and has been mowed several times A period of about 30 days after application is usually a sufficient interval before reseedmg grasses (or other plants) Seeding a small area and observing response is recommended before large scale seeding Cool Season Grasses To control many emerged broadleaf weeds in cool season turfgrasses such as tall fescue bluegrass or perennial ryegrass apply 1 0 - 1 75 quarts per acre (0 75 1 28 fluid ounces per 1 000 square feet) Preferred application timing for broadcast treatment is in the early spring when small weeds have emerged and are actively growing under good moisture conditions For very weedy turf a follow up broadcast or spot application may be needed from 2 to 4 weeks later Summer applications are typically spot treatments of individual weeds that have emerged after a spring broadcast treatment In the fall when cooler wetter conditions favor active weed growth broadcast application may be appropriate for very weedy turf such as an area that had no spring broadcast treatment Do not use on centipede carpetgrass St Augustine bentgrass or Dichondra turf or where desirable clovers are present RANGELAND PASTURES AND PERENNIAL GRASSLANDS NOT IN AGRICULTURAL PRODUCTION HardBall can be used to control or suppress a number of susceptible broadleaf weeds in rangeland or perennial grasslands that are set aside from agricultural use such as in the Conservation Reserve Program (CRP) or similar government programs Consult program rules to determine whether grass and hay may be used For best results apply when broadleaf weeds are small Adequate moisture is needed for best grass tolerance and weed control Addition of a nonionic surfactant such as INDUCE® or DYNE AMIC® usually improves weed control RESTRICTIONS AND LIMITATIONS Postemergence For susceptible annual and biennial broadleaf weeds Use 4 5 pints (1 0 Ibs ae/acre per application) For moderately susceptible biennial and perennial broadleaf weeds 2 25 4 5 quarts (1 0 Ib to 2 Ibs ae/acre per application For difficult to control weeds and woody plants Use 4 5 quarts (2 0 Ibs ae/acre) per application • Limited to 2 applications per year • Maximum of 2 0 Ibs ae/acre per application » Minimum of 30 days between applications « If grass is to be cut for hay Agricultural Use Requirements for the Worker Protection Standard are applicable « The preharvest interval (PHI) is 7 days (cut forage for hay) • For program lands such as Conservation Reserve Program consult program rules to determine whether grass or hay may be used The more restrictive requirements of the program rules or this label must be followed Plant Response Injury to legumes bent grass and other warm season grasses is likely to occur Grasses may be discolored following treatment If grass seed production is desired do not apply when grass is in boot to milk stage or after heading begins Filename Hardball (5905-549) 080312 CLN doc 25
New Stands Preseedmg applications can be made at least 30 days prior to seeding Newly seeded stands should only be treated after they are all well established (more than 5 true leaves) or injury may occur Apply 10-40 pints per acre when weeds are small and actively growing Addition of a surfactant may increase the risk of injury at this stage of growth Established Stands For optimum results weeds must be actively growing Apply 2 25 - 3 25 pints per acre for annual weeds and up to 4 5 pints per acre for biennial or perennial weeds Treat biennial weeds when they are in the seedling to rosette stage and before flower stalks become apparent Treat perennial weeds in the bud to bloom stage For brush species in rangeland apply up to 4 5 quarts per acre in an oil spray (see Mixing Instructions ) Another option is to add 1 gallon of oil per acre to a HardBall water spray (see Mixing Instructions) Repeat applications in the same or subsequent year may be needed to control brush species Livestock Feeding Restrictions Do not graze dairy animals on treated areas within 6 days of application Do not graze meat animals within 3 days of slaughter Treated grass cut for hay should not be cut within 30 days of application For government program grasslands follow program grazing restrictions if more restrictive than those stated above PISTACHIOS FILBERTS POME FRUITS STONE FRUITS AND TREE NUT ORCHARDS HardBall is comprised of a 2 4 D acid formulation that may be used in low volume ground application equipment The product is used in directed applications to control broadleaf weeds in established pistachio pome fruits stone fruits and tree nut plantings and orchards HardBall is to be applied as a broadcast treatment in the row middles of established trees as well as a band application to control many broadleaf weeds in the tree rows and the orchard floor Note Established and transplanted stock must be at least (1) one year old and in good growing conditions APPLICATION METHOD The precise and uniform application of HardBall is essential to obtain satisfactory economic control while minimizing the potential injury to the trees Avoid direct contact with the fruit foliage lower limbs stems tree trunks and any exposed roots It is best to use a fixed boom with flat fan nozzles at not more than 25 psi For small concentrated infestations small areas individual weeds or as a follow up application spot treating is recommended with hand held nozzle sprayer Do not apply HardBall when conditions favorable to drift are present APPLICATION TIMING Most annuals will be best controlled when they are actively growing either in the spring or fall Most biennials are best controlled when they are in the seedling to rosette stage Sequential applications may have to be utilized to obtain the best results Perennials that are either in the early bud to bloom stage or during fall regrowth have the best chance of being controlled at this time TANK MIXTURES For improved broadleaf control HardBall may be applied in combination with other approved products The combination must be used in accordance to the most restrictive label limitations of the product in the tank mix Both products must be labeled for the site of application Dosages of the tank mix must not cause either product to exceed the tolerance established for that active ingredient on the use site to be applied on All applications of the tank mix must be in accordance with Federal State and local use limitations IRRIGATION RESTRICTIONS Hardball is not to be applied to sandy or shallow soils or to dry soils without vegetation in Pistachio Pome Fruit Stone Fruit or Tree Nut Orchards Best results with HardBall can be obtained when the product is applied 1 2 days following irrigation Filename Hardball (5905-549) 080312 CLN doc 26
r Do not apply the product immediately prior to irrigation or irrigate immediately following an application DO NOT APPLY HardBall THROUGH ANY TYPE OF IRRIGATION SYSTEM DOSAGE RATES FOR BROADLEAF WEED CONTROL The following dosage rate listed are for broadcast applications The proper amount of HardBall to be used in banded or row applications must be determined by using the following formula Dosage Rate per Treated Acre = Spray Band Width x Broadcast rate per Acre Tree Row Width Recommended Spray Volumes Generally 1-10 gallons per acre is sufficient but in many cases 10-25 gallons may be needed to obtain adequate coverage Note Do not graze or feed cover crops from treated orchards to livestock PISTACHIOS CROP STAGE APPLICATION RATE/ACRE DIRECTIONS/TIMING Orchard Floor Broadcast 06-1 15 gallons Most annuals will be best controlled when they are actively growing either in the spring or fall Most biennials are best controlled when they are in the seedling to rosette stage Sequential applications may have to be utilized to obtain the best results Perennials that are either in the early bud to bloom stage or during fall regrowth have the best chance of being controlled at this time RESTRICTIONS AND LIMITATIONS PISTACHIOS « Limited to 2 applications per year • Maximum of 4 5 quarts (2 0 Ibs) ae/acre per application • Minimum of 30 days between applications • PHI (Pre Harvest Interval) 60 days « Do not cut orchard floor forage for hay within 7 days of application POME FRUITS (Apples and Pears) CROP STAGE APPLICATION RATE HardBall DIRECTIONS/TIMING Orchard Floor Broadcast 06-1 15 gallons per acre Apply broadcast for the control of unwanted vegetation on the orchard floors It is important to avoid contact with the fruit fruit foliage and tree trunks lower limbs and exposed brace roots Two applications 75 days apart are permitted Filename Hardball (5905-549) 080312 CLN doc 27
r Sf. RESTRICTIONS AND LIMITATIONS POME FRUITS Postemergence « Limited to 2 applications per year « Maximum of 4 5 quarts (2 0 Ibs) ae/acre per application • Minimum of 75 days between applications « Do not cut orchard floor forage for hay within 7 days of application « PHI (Pre Harvest Interval) 14 days STONE FRUITS (Cherries. Peaches. Plums) CROP STAGE APPLICATION RATE HardBall DIRECTIONS/TIMING Orchard Floor Broadcast 06-1 15 gallons per acre Apply at the broadcast rate of per application for the control of unwanted vegetation on the orchard floors It is important to avoid contact with the fruit foliage tree trunks lower limbs and exposed brace roots Two applications 75 days apart are permitted per year RESTRICTIONS AND LIMITATIONS STONE FRUITS Postemergence « Limited to 2 applications per year • Maximum of 4 5 quarts (2 0 Ibs) ae/acre per application « Minimum of 75 days between applications e Do not cut orchard floor forage for hay within 7 days of application • PHI (Pre Harvest Interval) 40 days POTATOES (Fresh Market Only) CROP STAGE Postemergence APPLICATION RATE 3 25 - 5 0 ounces per acre (Max rate 07 Ibs acid equivalent per acre) DIRECTIONS/TIMING Make first application when potatoes are in pre bud stage (about 7 to 10 inches) and make a second application 10 to 14 days later RESTRICTIONS AND LIMITATIONS POTATOES Postemergence « PHI (Pre Harvest Interval) Do not harvest within 45 days of application » Maximum rate 0 07 Ibs acid equivalent per acre per application e Limited to 2 applications per year « Retreatment Interval Minimum of 10 days between applications Filename Hardball (5905 549) 080312 CLN doc 28
RICE WEEDS IN CROPS AMOUNT OF HardBall PER ACRE DIRECTIONS FOR USE Preplan! Postemergent 1-225 quarts 1 - 3 25 quarts Apply HardBall 2 4 weeks prior to planting Apply in the late tillering stage of development at the time of first joint development (first to second green ring) usually 6 to 9 weeks after emergence Preplant « Limited to one preplant application per crop cycle • Maximum of 4 5 pints (1 0 Ib ae/acre) per preplant application Postemerqence
- Limited to one postemergence application per crop cycle » Maximum of 1 5 Ibs ae/acre per postemergence application Note Do not apply after panicle initiation after rice mternodes exceed Vz inch at early seedling early panicle boot flowering or early heading growth stages Do not harvest within 60 days of application Maximum allowable use rate per acre per season is 1 5 pounds acid equivalent Use 2 or more gallons of spray solution per acre 2 4 D can injure some rice varieties Before spraying consult local Extension Service or University specialists for appropriate rates and timing of sprays WILD RICE (For use in Minnesota Only) CROP STAGE MAXIMUM APPLICATION RATE/ACRE DIRECTIONS/TIMING Postemergence paddies 10-12 ounces For use only on wild rice grown commercially Apply to rice in the 1 to 2 aerial leaf through early tillering stage Do not spray after wild rice has reached the boot stage For best coverage apply 4 to 10 gallons total spray solution per acre RESTRICTIONS AND LIMITATIONS FOR USE ON WILD RICE • PHI Do not harvest within 60 days of application « Limited to one (1) Application per crop cycle • Max seasonal rate Apply no more than 18 ounces (0 25 Ib acid equivalent) per acre use season » Use 2 or more gallons of spray solution per acre Filename Hardball (5905-549) 080312 CLN doc 29
r SORGHUM (Miio Gram) WEEDS IN CROPS AMOUNT OF HardBall PER ACRE DIRECTIONS FOR USE Postemergence 1/2 4 5 pints Over the top Application 1/2 2 25 pints To control small broadleaf weeds apply when sorghum is 6 to 15 inches tall to top of canopy If sorghum is taller than 8 inches to top of canopy use drop nozzles to keep spray off crop foliage The lowest rates may not provide adequate weed control unless used in a tank mixture with another registered herbicide Highest rates may increase risk of injury Do not treat during the boot flowering or early dough stages Do not permit meat or dairy animals to consume treated crop as fodder or forage for 30 days following applications When crop is 6 to 8 inches tall use as an over the top broadcast spray by ground or air RESTRICTIONS AND LIMITATIONS SORGHUM (Milo) • Do not permit meat or dairy animals to consume treated crop as fodder or forage for 30 days following application « PHI Do not harvest within 30 days of application « Limited to one (1) Application per crop cycle « Max seasonal rate Apply no more than 4 5 pints (1 0 Ib acid equivalent) per acre use season « Use 2 or more gallons of spray solution per acre SORGHUM - SUDAN GRASS HYBRIDS (Forage Crop Only) WEEDS IN CROPS AMOUNT OF HardBall PER ACRE DIRECTIONS FOR USE Postemergence 1-45 pints To control small broadleaf weeds apply when sorghum sudan has at least 6 leaves is well established and is 5 to 10 inches tall at the rate of 16 to 35 fluid ounces per acre Do not treat crop over 10 inches tall through maturity Plant response Even when sprayed at the proper stage some crop injury is likely including reduced seed production If risk of crop injury is unacceptable do not use this product The lower rate may reduce the risk of crop injury but will result in reduced weed control Filename Hardball (5905 549) 080312 CLN doc 30
RESTRICTIONS AND LIMITATION Sorghum Sudan Grass Hybrids (Forage Crop Only) • Do not permit meat or dairy animals to consume treated crop as fodder or forage for 30 days following application • PHI Do not harvest within 30 days of application <> Limited to one (1) application per crop cycle » Max seasonal rate Apply no more than 4 5 pints (1 0 Ib acid equivalent) per acre use season e Use 2 or more gallons of spray solution per acre SOYBEANS (Preplan! Only) WEEDS IN CROP AMOUNT OF HardBall PER ACRE DIRECTIONS FOR USE Preplant only 2 to 2 25 pints 4 5 pints Apply not less than 30 days prior to planting soybeans when weeds are small and actively growing Use the higher rate on larger weeds and when perennials are present Limited to two (2) applications Apply not less than 30 days prior to planting soybeans when weeds are actively growing Limited to one (1) application In addition to those weeds found on the GENERAL WEED LIST HardBall will suppress or control the following broadleaf weeds frequently encountered in reduced tillage soybean production systems alfalfa bullnettle smallflowered bittercress Carolina geranium smallflowered buttercup common and rough cmquefoil red clover* horseweed or marestail mousetail wild mustard field pennycress cutleaf evening primrose common purslane speedwell velvetleaf and Virginia copperleaf* These weeds are only partially controlled Apply no more than 2 0 pints of HardBall in one season prior to planting soybeans After applying plant soybean seed as deep as practical or at least 1 1/2 to 2 inches deep Adjust the planter press wheel if necessary to ensure that planted seed is completely covered If desired HardBall may be applied pre plant to soybeans in tank mixtures Filename Hardball (5905-549) 080312 CLN doc
with other herbicides such as Poast® PoastPlus® Roundup® Roundup D Pak® Honcho® Gramoxone Extra® Prowl® Pursuit Plus® Scepter® Scepter 70 DC Squadron® and others that are registered for pre plant soybean use NOTE Unacceptable injury to soybeans planted in fields previously treated with HardBall may occur and the extent of injury will depend on weather and agronomic factors such as the amount of weed vegetation and previous crop residue present that may be in effect between the time of application and the emergence of the soybean plant RESTRICTIONS AND LIMITATIONS FOR USE IN SOYBEANS (PRE PLANT) Preplan! 0 Preplan! for Two (2) applications per crop cycle • Limited to 2 preplant applications per crop cycle « Maximum of 36 ounces per acre per preplant application • Apply not less than 15 days prior to planting soybeans 0 Preplant for Single (1) application per crop cycle « Limited to 1 preplant application per crop cycle « Maximum of 72 ounces per acre per preplant application • Apply not less than 30 days prior to planting soybeans o Do not apply HardBall when weather conditions such as temperature air inversions or wind favor drift from treated areas to susceptible plants « Do not apply HardBall prior to planting soybeans if you are not prepared to accept the results of soybean injury including possible loss of stand and yield • Do not replant fields treated with HardBall in the same growing season with crops other than those labeled for 2 4 D pre plant use « Do not mow or cultivate weeds prior to treating with HardBall as poor control may result « Do not cut for feed treated hay forage or fodder or graze treated soybeans to livestock « Do not apply HardBall pre plant to soybeans in fields having a coarse textured soil where the percent organic matter is <1 0% o Do not feed treated hay forage or fodder Livestock should be restricted from feeding/grazing of treated cover crops » Not currently registered for use in California Filename Hardball (5905-549) 080312 CLN doc 32
r STRAWBERRIES CROP STAGE Dormant or after last picking APPLICATION RATE/ACRE 6 6 75 pints DIRECTIONS/TIMING Apply to established plantings when strawberries have gone into dormancy or soon after the last picking RESTRICTIONS AND LIMITATIONS FOR USE IN STRAWBERRIES Limited to 1 application per crop cycle Maximum seasonal rate 110 ounces (1 5 Ibs acid equivalent) per acre per application State Restrictions Do not apply in California or Florida SUGARCANE WEEDS IN CROPS Preemergence Postemergence AMOUNT OF HardBall PER ACRE 4 to 8 pints 8 to 9 2 pints DIRECTIONS FOR USE Apply as a preemergent spray before canes appear for control of emerged weeds Apply after cane emerges through canopy closure Consult local Agricultural Experiment or Extension Service Weed Specialists on specific use of this product RESTRICTIONS AND LIMITATIONS Preemergence » Limited to one application per crop cycle » Maximum of 2 0 Ibs ae/acre per application Postemergence » Limited to one application per crop cycle • Maximum of 2 0 Ibs ae/acre per application « Do not harvest cane prior to crop maturity Maximum per Crop Cycle • Do not apply more than 4 Ibs ae/acre per crop cycle e Always use more than 2 gallons of spray solution per acre SOD FARMS HardBall is intended for use on Sod Farms to provide selective control of certain broadleaf weeds in cool season and warm season turfgrass established for commercial sod production Apply HardBall to actively growing broadleaf weeds Follow up may be required for dense infestations of perennial and biennial weeds For best results do not mow turf 1 to 2 days before or after application Turf watering should be delayed until two days after application Do not apply to newly seeded areas until grass is well established and has been mowed at least twice Reseedmg Grass areas Do not reseed until at least 30 days after application of ® HardBall Seeding a small area and observing response is recommended before a large scale seeding is accomplished Filename Hardball (5905 549) 080312 CLN doc 33
r Application Rates HardBall application rates and spray volumes will vary with the growth stage and population of broadleaf weeds to be controlled In general the smaller the weed the lower use of the listed rate range will provide satisfactory control The larger the weed the population and environmental conditions will require the higher end of the rate range to achieve satisfactory control especially for many of the perennial broadleaf weeds Rate For Sod Farms Species Amount of Product Pints/Acre Spray Volume Gallons/Acre Cool Season Turf Kentucky Bluegrass Perennial Ryegrass Fescue spp Creeping Bentrgass 2 to 3 5 2 to 3 5 2 to 3 5 1 5 20 to 100 20 to 100 20 to 100 20 to 100 Warm Season Turf Centipede grass Common Bermudgrass Hybrid Bermudagrass Bahiagrass Zoysiagrass 1 5 to 2 5 1 5 to 2 5 15to25 15to25 1 5 to 2 5 20 to 100 20 to 100 20 to 100 20 to 100 Precautions and Limitations for SOD FARMS « Limited to two (2) applications per year • Maximum of 4 5 quarts (2 Ibs ae) per acre per application • Retreatment interval is 21 days • Do not apply this HardBall to any variety of St Augustine grass Do not use HardBall on carpet grass Dichondra or where desirable clovers are present e Do not apply this product through any type of irrigation system • Avoid drift or spray mist onto vegetables flowers ornamental plants shrubs trees and other desirable plants Do not pour spray solution or rmsate near any desirable plants « Do not apply HardBall immediately before rainfall or irrigation Do not water the turfgrass for 24 hours after application « Application to Bermuda grass can be during dormancy or when actively growing Do not apply during periods of semi dormancy or transition FOREST MANAGEMENT (INCLUDING SITE PREP FOREST ROADSIDES BRUSH CONTROL ESTABLISHED CONIFER RELEASE) For the general control of annual biennial and perennial broadleaf weeds and brush Apply to emerged weeds and brush For best results treat when weeds and brush are young and actively growing For broadcast applications apply no more than 2 25 gallons (4 0 Ibs acid equivalent) per acre per 12 months Broadcast application Limited to 1 broadcast application per year Maximum of 2 25 gallons (4 0 Ibs ae/)acre per broadcast application Filename Hardball (5905 549) 080312 CLN doc 34
Basal spray Cut Surface - Stumps and Frill Limit of one basal spray or cut surface application per year Maximum of 4 5 gallons (8 0 Ibs ae) per 100 gallons of spray solution Injection Limit to one injection application per year Maximum of 2 ml of 4 0 Ibs ae formulation per injection site For specific use site applications and restrictions see the appropriate site specific instructions as follows Forest Site Preparation Bud break Spray For control of alder susceptible broadleaf weeds and susceptible woody plants before planting forest seedlings apply up to 2 0 gallons per acre in a minimum of 10 gallons spray mixture per acre Apply as an oil spray (see Mixing Instructions ) after alder buds break but before foliage is 1/4 full size A water spray including 2 to 4 quarts per acre of diesel oil fuel oil stove oil or crop oil concentrate may also be used ANNUAL BIENNIAL PERENNIAL BROADLEAF WEEDS AND GENERAL BRUSH CONTROL Foliage Spray To control seedlings and susceptible woody plants before planting forest apply up to 2 0 gallons per acre in a minimum of 10 gallons spray mixture per acre If desired apply as a water spray including up to 1 quart of diesel oil fuel oil stove oil or crop oil concentrate per gallon of water (see Mixing Instructions ) For best results apply after alder foliage has reached full size TREE AND BRUSH CONTROL (i e alder ash aspen birch black gum, cherry elm, oak, sweet gum tulip poplar, willow and others) Basal Spray Treatment Mix 2 4 gallons of HardBall per 100 gallons of diluent (may contain oil) Apply directly to base and root collar of all stems until the spray begins to accumulate at the ground line Also wetting stems with this mixture may aid control Cut Surface Stumps Mix 2 4 gallons of HardBall per 100 gallons of diluent (may contain oil) Apply as soon as possible after curing trees Thoroughly soak the entire stump with 2 4 D mixture Also treat exposed roots and bark Frill Mix 2 4 gallons of HardBall per 100 gallons of diluent (may contain oil) Make frills with an axe or other tool that can cut overlapping v shaped notches through the bark in a continuous ring around the base of the tree Treat freshly cut frills with as much HardBall mixture as they will hold Injection Make injections as near to the root collar as possible using one injection per inch of trunk dbh (4 Vz feet) for resistant species such as hickory Injections should overlap For best results injections should be made during the growing season (May 15th through October 15th in many areas) The injection bit must penetrate the bark Apply 2 4 ml of HardBall per injection site Conifer Release To control alder susceptible broadleaf weeds and susceptible woody plants in young conifer stands apply up to 1 gallon per acre in a minimum of 10 gallons spray mixture per acre This spring foliage treatment should be applied as a water spray when 3/4 of the brush foliage has full size leaves and before new conifer growth reaches 2 inches in length Such stages usually occur between early May and mid June but application timing should be based on growth stages of brush and conifers Application may cause leader deformation and other conifer injury but trees should overcome it during the next growing season Filename Hardball (5905 549) 080312 CLN doc 35
To control tanoak madrone ceanothus canyon live oak and manzanita and to release Douglas fir hemlock Sitka spruce or grand fir apply up to 1 5 gallons per acre in a minimum of 10 gallons spray mixture per acre This spring foliage treatment should be applied as a water spray including if desired up to 1 quart of diesel oil fuel oil stove oil or crop oil concentrate per gallon of water (see Mixing Instructions ) Make application before new growth on Douglas fir is 2 inches long To release ponderosa pine from the same species treat before new pine growth begins in the spring Addition of oil or oil concentrate may cause unacceptable injury to pines For dormant applications in late winter or early spring for control of susceptible woody species such as alder willow poplars cherry vine maple ceanothus tanoak madrone and manzanita apply up to 1 5 gallons per acre in a minimum of 10 gallons spray mixture per acre This dormant treatment should be applied in diesel oil fuel oil stove oil or other suitable diluent such as water plus crop oil concentrate (see Mixing Instructions ) Do not use in plantations where pine and larch are among the desired crop species To control hazel brush in the Lake states apply up to 1 0 gallon per acre in a minimum of 10 gallons spray mixture per acre Apply as a water spray when new shoot growth of hazel is complete (usually mid July) After conifer species such as white pine ponderosa pine jack pine red pine black spruce white spruce red spruce and balsam fir crease growth and harden off and brush is still actively growing in late summer apply up to 1 5 gallons per acre in a minimum of 10 gallons spray mixture per acre Apply as a water spray to control certain competing hardwoods such as alder aspen birch hazel and willow However if possible injury cannot be tolerated do not use since this treatment may cause conifer injury Forest Roadsides To control susceptible broadleaf weeds and woody plants on forest roadsides apply 05 15 gallons per acre in a minimum of 10 gallons spray mixture per acre Apply as a water spray and if desired include up to 3 quarts per acre of diesel oil fuel oil stove oil or crop oil concentrate (see Mixing Instructions ) Apply when sufficient foliage is present for absorption Established Conifers (including Christmas trees) Directed Spray or Spot Spray To control susceptible broadleaf weeds mix up to 1 0 gallon per 100 gallons of water and apply to emerged weeds in the spring with ground equipment Avoid contacting conifer foliage with spray or drift as injury may result For brush mix 20 gallons per 100 gallons of water Thoroughly spray brush in full foliage but avoid contacting conifer foliage with spray or drift Do not apply more than the equivalent of 2 0 gallons per acre Over the Top Broadcast Application To control susceptible broadleaf weeds apply 0 5 gallons per acre in a minimum of 10 gallons spray mixture per acre To decrease the potential for injury to firs apply only before bud break in the spring and/or after complete bud set and hardening in the late summer or fall Avoid treatment during the year of intended harvest AQUATIC WEED CONTROL Notice to Applicators Before application coordination and approval of local and state authorities may be required either by letter of agreement or issuance of special permits for such use Ground or Surface Application Do not apply when wind speeds are at or above 10 mph Air Application Do not apply when wind speeds are at or above 5 mph The restrictions do not apply to subsurface applications used in weed control programs Filename Hardball (5905-549) 080312 CLN doc 36
DITCH BANK APPLICATION RESTRICTIONS AND LIMITATIONS WEED AND BRUSH ON IRRIGATION CANAL DITCHBANKS o Postemergence o Limited to 2 applications per season o Maximum of 1 15 gallons (2 Ib ae) per acre per application o Maximum of 2 25 gallons (4 Ib ae) per acre per season o Minimum of 30 days between applications « Spot treatment permitted o Do not use on small canals with a flow rate less than 10 cubic feet per second (CFS) where water will be used for drinking purposes CFS may be estimated by using the formula below The approximate velocity needed for the calculation can be determined by observing the length of time that it takes a floating object to travel a defined distance Divide the distance (ft) by the time (sec) to estimate velocity (ft per sec) Repeat 3 times and use the average to calculate CFS Average Width (ft) x Average Depth (ft) x Average Velocity (ft per sec) = CFS
- Note For ditchbank weeds o Do not allow boom spray to be directed onto water surface o Do not spray across stream to opposite bank • When spraying shoreline weeds allow no more than 2 foot overspray onto water with an average of less than one foot overspray to prevent introduction of greater than negligible amounts of chemical into the water Use power sprayers operated with a boom or spray gun mounted on a boat tractor or truck Thorough wetting of foliage is essential for maximum control Use 100 to 400 GPA of spray mixture Special precautions such as the use of low pressure large nozzles and thickening agents should be taker") to avoid spray drift in areas of sensitive crops For DIRECTASPRA™ operation use with 1 pint of drift control agent in 50 to 100 gallons of water For other applications follow the drift control agent label for mixing directions FOR AQUATIC WEEDS IN LAKES PONDS RESERVOIRS MARSHES BAYOUS DRAINAGE DITCHES CANALS AND RIVERS AND STREAMS THAT ARE QUIESCENT OR SLOW MOVING INCUDING PROGRAMS OF THE TENNESSEE VALLEY AUTHORITY Use 1 5 gallons of HardBall per acre foot For best results apply in spring or early summer A second treatment may be needed when weeds show signs of recovery but no later than September in most areas Spray to wet foliage thoroughly Application should be made when leaves are fully developed above water line and plants are actively growing Apply to attain a concentration of 2 to 4 ppm EMERGENT AND FLOATING WEEDS Surface Application Apply 2 3 gallons per acre in a minimum spray volume of 5 gallons mix per acre Air Application Use drift control spray equipment or thickening agents mixed into the spray solution Apply 2 3 gallons per acre through standard boom systems with a minimum of 5 gallons of spray mix per acre For MICROFOIL® drift control spray systems apply in 12 15 gallons spray mix per acre o Maximum of 2 3 gallons (4 0 Ibs ae)/surface acre per application o Limited to 2 applications per season » Minimum of 21 days between applications « Spot treatments are permitted Filename Hardball (5905 549) 080312 CLN doc 37
Apply to emergent aquatic weeds in ponds lakes reservoirs marshes bayous drainage ditches non irrigation canals rivers and streams that are quiescent or slow moving Coordination and approval of local and state authorities may be required either by letter of agreement or issuance of special permits for aquatic applications Water Use 1 Water for irrigation or sprays A If treated water is intended to be used only for crops or non crop areas that are labeled for direct treatment with 2 4 D such as pastures turf or cereal grains the treated water may be used to irrigate and/or mix sprays for these sites at anytime after the 2 4 D aquatic application B Due to potential phytotoxicity considerations the following restrictions are applicable If treated water is intended to be used to irrigate or mix sprays for plants grown in commercial nurseries and greenhouses and other plants or crops that are not labeled for direct treatment with 2 4 D the water must not be used unless one of the following restrictions has been observed i A setback distance from functional water mtake(s) of >600 ft was used for the application or ii A waiting period of 7 days from the time of application has elapsed or HI An approved assay indicates that the 2 4 D concentration is 100 ppb (01 ppm) or less at the water intake Wait at least 3 days after application before initial sampling at water intake 2 Drinking water (potable water) A Consult with appropriate state or local water authorities before applying this product to public waters State or local agencies may require permits The potable water use restrictions on this label are to ensure that consumption of water by the public is allowed only when the concentration of 2 4 D in the water is less than the MCL (Maximum Contaminant Level) of 70 ppb Applicators should consider the unique characteristics of the treated waters to assure that 2 4 D concentrations in potable water do not exceed 70 ppb at the time of consumption B For floating and emergent weed applications the drinking water setback distance from functioning potable water intakes is >600ft C If no setback distance of ^600 ft is used for the application applicators or the authorizing organization must provide a drinking water notification prior to a 2 4 D application to the party responsible for a public water supply or to individual private water users Notification to the party responsible for a public water supply or to individual private water users must be done in a manner to assure that the party is aware of a water use restrictions when this product is applied to potable water The following is an example of an example of notification via posting but other methods of notification which convey the above restrictions may be used and may be required in some cases under state or local law or as a condition of a permit Example Posting notification should be located every 250 feet including the shoreline of the treated area and up to 250 feet of shoreline past the application site to include immediate public access points Posting must include the day and time of application Posting may be removed if analysis of a sample collected at the intake 3 or more days following application shows that the concentration in the water is less than 70 ppb (100 ppb for irrigation or sprays) or after 7 days following application whichever occurs first Text of notification Wait 7 days before diverting functioning surface water intakes from the treated aquatic site to use as drinking water irrigation or sprays unless water at functioning drinking water intakes is tested at least 3 days after application and is demonstrated by assay to contain not more than 70 ppb 24 D (100 ppb for irrigation or sprays) Application Date Time Filename Hardball (5905-549) 080312 CLN doc 33
r c D Following each application of this product treated water must not be used for drinking water unless one of the following restrictions has been observed i A setback distance from functional water mtake(s) of >600 ft was used for the application or n A waiting period of at least 7 days from the time of application has elapsed or in An approved assay indicates that the 2 4 D concentration is 70 ppb (0 07 ppm) or less at the water intake Sampling for drinking water analysis should occur no sooner than 3 days after 2 4 D application Analysis of samples must be completed by a laboratory that is certified under the Safe Drinking Water Act to perform drinking water analysis using a currently approved version of analytical Method Number 515 555 other methods for 2 4 D as may be listed in Title 40CFR Part 141 24 or Method Number 4015 (immunoassay of 2 4 D) from U S EPA Test Methods for Evaluating Solid Waste SW 846 E Note Existing potable water intakes that are no longer in use such as those replaced by a connection to municipal water system or a potable water well are not considered to be functioning potable water intakes F Drinking water setback distances do not apply to terrestrial applications of 2 4 D adjacent to water bodies with potable water intakes 3 Except as stated above there are no restrictions on using water from treated areas for swimming fishing watering livestock or domestic purposes SUBMERGED AQUATIC WEEDS Subsurface Application Apply 25-62 gallons per acre foot as a concentrate directly into the water through boat mounted distribution systems Maximum of 10 8 Ibs ae/per acre foot per application Limited to 2 applications per season Apply to aquatic weeds in ponds lakes reservoirs marshes bayous drainage ditches non irrigation canals rivers and streams that are quiescent or slow moving Do not apply within 21 days of previous application When treating moving bodies of water applications must be made while traveling upstream to prevent concentration of 2 4 D downstream from the application Coordination and approval of local and state authorities may be required either by letter of agreement or issuance of special permits for such use Table 1 Amount of 2 4 D to Apply for a Target Subsurface Concentration Surface Area 1 acre Average Depth 1ft 2ft 3ft 4ft 5ft For typical conditions - 2 ppm 2 4 D ae/acre foot 5 4 Ibs 10 8 Ibs 16 2 Ibs 21 6 Ibs 27 0 Ibs For difficult conditions* 4ppm 2 4 D ae/acre 10 8 Ibs 21 6 Ibs 32 4 Ibs 43 2 Ibs 54 0 Ibs Examples include spot treatment of pioneer colonies of Eurasian Water Milfoil and certain difficult to control aquatic species Filename Hardball (5905 549) 080312 CLN doc 39
Water Use 1 Water for irrigation or sprays A If treated water is intended to be used only for crops or non crop areas that are labeled for direct treatment with 2 4 D such as pastures turf or cereal grains the treated water may be used to irrigate and/or mix sprays for these sites at anytime after the 2 4 D aquatic application B Due to potential phytotoxicity and/or residue considerations the following restrictions are applicable If treated water is intended to be used to irrigate or mix sprays for unlabeled crops non crop areas or other plants not labeled for direct treatment with 2 4 D the water must not be used unless one of the following restrictions has been observed i A setback distance described in the Drinking Water Setback Table was used for the application or ii A waiting period of 21 days from the time of application has elapsed or HI An approved assay indicates that the 2 4 D concentration is 100 ppb (0 1 ppm) or less at the water intake See Table 3 for the waiting period after application but before taking the imtial sampling at water intake 2 Drinking water (potable water) A Consult with appropriate state or local water authorities before applying this product to public waters State or local agencies may require permits The potable water use restrictions on this label are to ensure that consumption of water by the public is allowed only when the concentration of 2 4 D in the water is less than the MCL (Maximum Contaminant Level) of 70 ppb Applicators should consider the unique characteristics of the treated waters to assure that 2 4 D concentrations in potable water do not exceed 70 ppb at the time of consumption B For submersed weed applications the drinking water setback distances from functioning potable water intakes are provided in Table 2 Drinking Water Setback Distance (below) C If no setback distance from the Drinking Water Setback Table (Table 2) is to be used for the application applicators or the authorizing organization must provide a drinking water notification and an advisory to shut off all potable water intakes prior to a 2 4 D application Notification to the party responsible for a public water supply or to individual private water users must be done in a manner to assure that the party is aware of the water use restrictions when this product is applied to potable water The following is an example of an example of notification via posting but other methods of notification which convey the above restrictions may be used and may be required in some cases under state or local law or as a condition of a permit Example Posting notification should be located every 250 feet including the shoreline of the treated area and up to 250 feet of shoreline past the application site to include immediate public access points Posting should include the day and time of application Posting may be removed if analysis of a sample collected at the intake no sooner than stated in Table 3 (below) shows that the concentration in the water is less than 70 ppb (100 ppb for irrigation or sprays) or after 21 days following application whichever occurs first Text of notification Wait 21 days before diverting functioning surface water intakes from the treated aquatic site to use as drinking water irrigation or sprays unless water at functioning drinking water intakes is tested no sooner than (insert days from Table 3) and is demonstrated by assay to contain not more than 70 ppb 24 D (100 ppb for irrigation or sprays) Application Date Time Filename Hardball (5905 549) 080312 CLN doc 40
D Following each application of this product treated water must not be used for drinking water unless one of the following restrictions has been observed i A setback distance described in the Drinking Water Setback Distance Table was used for the application or ii A waiting period of at least 21 days from the time of application has elapsed or MI An approved assay indicates that the 2 4 D concentration is 70 ppb (0 07 ppm) or less at the water intake Sampling for drinking water analysis should occur no sooner than stated in Table 3 Analysis of samples must be completed by a laboratory that is certified under The Safe Drinking Water Act to perform drinking water analysis using a currently approved version of analytical Method Number 515 555 other methods for 2 4 D as may be listed in Title 40CFR Part 141 24 or Method Number 4015 (immunoassay of 24 D) from U S EPA Test Methods for Evaluating Solid Waste SW 846 E Note Existing potable water intakes that are no longer in use such as those replaced by a connection to a municipal water system or a potable water well are not considered to be functioning potable water intakes F Drinking water setback distances do not apply to terrestrial applications of 2 4 D adjacent to water bodies with potable water intakes 3 Except as stated above there are no restrictions on using water from treated areas for swimming fishing watering livestock or domestic purposes Table 2 Drinking Water Setback Distance for Submersed Weed Applications Application Rate and Minimum Setback Distance (feet) from Functioning Potable Water Intake 1 ppm* 600 2ppm 1200 3ppm 1800 4ppm 2400 ppm acid equivalent target water concentration Table 3 Sampling for Drinking Water Analysis Applications After 2 4 D Application for Submersed Weed Minimum Days After Application Before Initial Water Sampling at the Functioning Potable Water Intake 1 ppm 5 2ppm 10 3ppm 10 4ppm 14 ppm acid equivalent target water concentration WATER HYACINTH (Eichomia crassipe) For control of actively growing plants with surface and air applications use 4 8 pints per acre Spray the weed mass only Use 8 pints when plants are matured or when the weed mass is dense WATER MILFOIL (Mynophyllum spicatum) For Eurasian Water Milfoil in programs conducted by the Tennessee Valley Authority (TVA) in dams and reservoirs of the TVA system HardBallwill control Water Milfoil with surface subsurface and air applications To control water milfoil when less than 5 gallons of concentrate per acre is specified dilute the concentrate with water to apply a minimum of 5 gallons of spray mix per acre Do not treat within Vz mile of potable water intakes Shoreline areas should be treated by sub surface injection applied by boat to avoid aerial drift Do not apply when weather conditions favor drift from target area Filename Hardball (5905-549) 080312 CLN doc 4]
Restrictions and Limitations for Aquatic Use Do not exceed 4 0 Ibs acid equivalent per surface acre per application Do not reapply less than 3 weeks after prior application Do not apply within 1 500 feet of active potable water intakes Fish breathe dissolved oxygen in the water and a water/oxygen ratio must be maintained Decaying weeds use up oxygen When treating continuous dense weed masses it may be appropriate to treat only part of the infestation at a time For example apply HardBall in lanes separated by untreated strips that can be treated after vegetation in treated lanes has disintegrated During the growing season weeds decompose in a 2 to 3 week period following treatment Waters having limited and less dense weed infestations may not require partial treatments Other local factors such as water exchange and sediment load can also influence the dissolved oxygen level To avoid fish kill from decaying plant material do not treat more than one half the lake or pond at one time For large bodies of weed infested waters leave buffer strips of at least 100 feet wide and delay treatment of these strips for 4 to 5 weeks or until the dead vegetation has decomposed Water Use Instructions Unless an approved assay indicates that the 2 4 D concentration is 100 ppb (0 1 ppm) or less or only growing crops and non crop areas labeled for direct treatment with 2 4 D will be effected do not use water from treated areas for 1 Irrigating plants (especially cotton grapes and tomatoes) 2 Mixing sprays for agricultural or ornamental plants Unless an approved assay indicates the 2 4 D concentration is 70 ppb (0 07 ppm) or less do not use water from treated areas for potable water (drinking water) Except as stated above there are no restrictions on using water from treated areas for fishing watering livestock or domestic purposes CONDITIONS OF SALE LIMITED WARRANTY AND LIMITATIONS OF LIABILITY AND REMEDIES Read the Conditions of Sale Warranty and Limitations of Liability and Remedies before using this product If the terms are not acceptable return the product unopened and the full purchase price will be refunded The directions on this label are believed to be reliable and should be followed carefully Insufficient control of pests and/or injury to the crop to which the product is applied may result from the occurrence of extraordinary or unusual weather conditions or the failure to follow the label directions or good application practices all of which are beyond the control of Helena Chemical Company (the Company) or seller In addition failure to follow label directions may cause injury to crops animals man or the environment The Company warrants that this product conforms to the chemical description on the label and is reasonably fit for the purpose referred to in the directions for use subject to the factors noted above which are beyond the control of the Company To the extent consistent with applicable law the Company makes no other warranties or representations of any kind express or implied concerning the product including no implied warranty of merchantability or fitness for any particular purpose and no such warranty shall be implied by law To the extent consistent with applicable law the exclusive remedy against the Company for any cause of action relating to the handling or use of this product shall be limited to at Helena Chemical Company s election one of the following 1 Refund of the purchase price paid by buyer or user for product bought or 2 Replacement of the product used Filename Hardball (5905-549) 080312 CLN doc 42
To the extent consistent with applicable law the Company shall not be liable and any and all claims against the Company are waived for special indirect incidental or consequential damages or expense of any nature including but not limited to loss of profits or income The Company and the seller offer this product and the buyer and user accept it subject to the foregoing conditions of sale and limitation of warranty liability and remedies © Copyright Helena Holding Company 2010 ® is a registered trademark of Helena Holding Company WIPE OUT® INDUCE® and DYNE AMIC® are a registered trademarks of Holding Company ACCENT® ALLY® CANVAS® EXPRESS® FINESSE® GLEAN® and HARMONY® are registered trademarks of E I DuPont de Nemours & Co Inc AMBER® GRAMOXONE® EXTRA and PEAK® are registered trademarks of Syngenta Crop Protection Inc ROUNDUP®, ROUNDUP® D PAK HONCHO® are registered trademarks of Monsanto Company PROWL® PURSUIT® PLUS SCEPTER® 70DG SQUADRON® POAST® POAST® PLUS are registered trademarks of BASF Ag Products Filename Hardball (5905-549) 080312 CLN doc 43
BASE LABEL LANGUAGE HardBalS ACTIVE INGREDIENT 2 4 Dichlorophenoxyacetic Acid 19 6% INERT INGREDIENTS 804% TOTAL 1000% Equivalent to 19 6% 2 4 D Acid or 1 74 Ib /gal Isomer specific by AOAC Method 6 D01 5 (12th Ed) Patent No 5877112 Other Patents Pending KEEP OUT OF REACH OF CHILDREN DANGER PELIGRO Si usted no entiende la etiqueta busque a alguien para que se la explique a usted en detalle (If you do not understand the label find someone to explain it to you) FIRST AID IF IN EYES IF SWALLOWED IF INHALED IF ON SKIN OR CLOTHING « Hold eye open and rinse slowly and gently with water for 1 5 20 minutes « Remove contact lenses if present after the first 5 minutes then continue rinsing eye <• Call a poison control center or doctor immediately for advice • Call a poison control center or doctor immediately for advice e Have person sip a glass of water «> Do not induce vomiting unless instructed to do so by poison control center or doctor o Do not give anything by mouth to an unconscious or convulsing person « Move victim to fresh air o If person is not breathing call 91 1 or an ambulance then give artificial respiration preferably mouth to mouth if possible • Call a poison control center or doctor immediately for further treatment advice « Take off contaminated clothing « Rinse immediately with plenty of water for 1 5 20 minutes « Call a poison control center of doctor for treatment advice HOTLINE NUMBER Have the product container or label with you when calling a poison control center or doctor or going for treatment For emergency assistance call toll free 1 800 424 9300 (ChemTrec) NOTE TO PHYSICIAN Probable mucosal damage may contramdicate the use of gastric lavage Causes irreversible eye damage See Additional Precautions and Use Directions on Inside Panels EPA REG NO 5905 549 EPA EST NO First Letters of Product Batch Code Indicate Producing Establishment 5905 AR 1=WA • 5905 GA 1=CG • 5905 IA 1=DI • 5905 CA 1=KC SN 1206/1008 NET CONTENTS MANUFACTURED FOR HELENA CHEMICAL COMPANY 225 SCHILLING BOULEVARD SUITE 300 COLLIERVILLE TENNESSEE 38017 Filename Hardball (5905 549) 080312 CLN doc 44
r PRECAUTIONARY STATEMENTS HAZARDS TO HUMANS AND DOMESTIC ANIMALS DANGER-PELIGRO Corrosive Causes irreversible eye damage Harmful if swallowed Harmful if inhaled Do not get in eyes or on clothing Avoid breathing spray mist or vapor Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals DIRECTIONS FOR USE It is a violation of federal law to use this product in a manner inconsistent with its labeling STORAGE AND DISPOSAL Do not contaminate water food or feed by storage or disposal PESTICIDE STORAGE Do not store below temperature of 0 F If frozen warm to 40 F and re dissolve before using by rolling or shaking container This product can be stored in an unheated building Store in a safe manner Store in original container only Keep container tightly closed when not in use Reduce stacking height where local conditions can affect package strength Do not store under conditions which might adversely affect the container or its ability to function properly PESTICIDE DISPOSAL Pesticide wastes are toxic Improper disposal of excess pesticide spray mixture or nnsate is a violation of Federal law and may contaminate groundwater If these wastes cannot be disposed of by use according to label instructions contact your State Pesticide or Environmental Control Agency or the Hazardous Waste representative at the nearest EPA Regional Office for guidance CONTAINER DISPOSAL NONREFILLABLE METAL CONTAINER (EQUAL TO OR LESS THAN 5 GALLONS) Do not reuse or refill this container Triple rinse container (or equivalent) promptly after emptying Triple rinse as follows Empty the remaining contents into application equipment or a mix tank and dram for 10 seconds after the flow begins to dnp Fill the container / full with water and recap Shake for 10 seconds Pour nnsate into application equipment or a mix tank or store nnsate for later use or disposal Dram for 10 seconds after the flow begins to drip Repeat this procedure two more times Offer for recycling if available or puncture and dispose of in a sanitary landfill or by other procedures approved by state and local authorities NONREFILLABLE METAL CONTAINER (GREATER THAN 5 GALLONS) Do not reuse or refill this container Triple rinse container (or equivalent) promptly after emptying Triple rinse as follows Empty the remaining contents into application equipment or a mix tank Fill the container / fu II with water Replace and tighten closures Tip container on its side and roll it back and forth ensuring at least one complete revolution for 30 seconds Stand the container on its end and tip it back and forth several times Turn the container over onto its other end and tip it back and forth several times Empty the nnsate into application equipment or a mix tank or store nnsate for later use or disposal Repeat this procedure two more times Offer for recycling if available or puncture and dispose of in a sanitary landfill or by other procedures approved by state and local authorities NONREFILLABLE PLASTIC CONTAINER (EQUAL TO OR LESS THAN 5 GALLONS) Do not reuse or refill this container Tnple nnse container (or equivalent) promptly after emptying Triple rinse as follows Empty the remaining contents into application equipment or a mix tank and dram for 10 seconds after the flow begins to drip Fill the container / full with water and recap Shake for 10 seconds Pour rmsate into application equipment or a mix tank or store nnsate for later use or disposal Dram for 10 seconds after the flow begins to dnp Repeat this procedure two more times Offer for recycling if available or puncture and dispose of in a sanitary landfill or incineration if allowed by state and local authorities by burning If burned stay out of smoke NONREFILLABLE PLASTIC CONTAINER (GREATER THAN 5 GALLONS) Do not reuse or refill this container Triple rinse container (or equivalent) promptly after emptying Triple rinse as follows Empty the remaining contents into application equipment or a mix tank Fill the container / full with water Replace and tighten closures Tip container on its side and roll it back and forth ensuring at least one complete revolution for 30 seconds Stand the container on its end and tip it back and forth several times Turn the container over onto its other end and tip it back and forth several times Empty the nnsate into application equipment or a mix tank or store nnsate for later use or disposal Repeat this procedure two more times Offer for recycling if available or puncture and dispose of in a sanitary landfill or incineration if allowed by state and local authorities by burning If burned stay out of smoke REFILLABLE CONTAINER Refill this container with pesticide only Do not reuse this container for any other purpose Prior to refilling inspect thoroughly for damage such as cracks punctures abrasions and damaged or worn out threads on closure devices Do not refill or transport damaged or leaking containers Check for leaks after refilling and before transportation Cleaning the container before final disposal is the responsibility of the person disposing of the container Cleaning before refilling is the responsibility of the refiller To clean the container before final disposal empty the remaining contents from this container into application equipment or mix tank Fill the container about 10 percent full with water Agitate vigorously or recirculate water with the pump for 2 minutes Pour or pump nnsate into application equipment or nnsate collection system Repeat this rinsing procedure two more times If the container is not being refilled return to the point of purchase or designated location Filename Hardball (5905-549) 080312 CLN doc 45