crop-chem-docs/corpus/epa_ppls/7969-186.md

HEADLINE FUNGICIDE

• EPA Reg No: 7969-186
• Registrant: BASF AGRICULTURAL SOLUTIONS US, LLC
• Signal word: Warning
• Active ingredients: Pyraclostrobin (23.6%)
• Label accepted: 2017-01-26
• Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/007969-00186-20170126.pdf

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UNITED STATES ENVIRONMENTAL PROTECTION AGENCY WASHINGTON, DC 20460

Fast Track Label Acceptable v.20150320 OFFICE OF CHEMICAL SAFETY AND POLLUTION PREVENTION January 26, 2017 David Haughey Product Registration Manager BASF Corporation 26 Davis Drive PO Box 13528 Research Triangle Park, NC 27709

Subject: Label Amendment: Updates “First Aid”/PPE sections; in California restricts against use for sugarcane; in California restricts against in-furrow use for corn, dried shelled peas and beans, oilseed crops (except sunflower in-furrow allowed), peanut, soybean; other minor revisions Product Name: Headline Fungicide EPA Registration Number: 7969-186 Application Date: August 31, 2016 Decision Number: 521087

Dear Mr. Haughey:

The amended label referred to above, submitted in connection with registration under the Federal Insecticide, Fungicide and Rodenticide Act, as amended, is acceptable. This approval does not affect any conditions that were previously imposed on this registration. You continue to be subject to existing conditions on your registration and any deadlines connected with them.

A stamped copy of your labeling is enclosed for your records. This labeling supersedes all previously accepted labeling. You must submit one copy of the final printed labeling before you release the product for shipment with the new labeling. In accordance with 40 CFR 152.130(c), you may distribute or sell this product under the previously approved labeling for 18 months from the date of this letter. After 18 months, you may only distribute or sell this product if it bears this new revised labeling or subsequently approved labeling. “To distribute or sell” is defined under FIFRA section 2(gg) and its implementing regulation at 40 CFR 152.3.

Should you wish to add/retain a reference to the company’s website on your label, then please be aware that the website becomes labeling under the Federal Insecticide Fungicide and Rodenticide Act and is subject to review by the Agency. If the website is false or misleading, the product would be misbranded and unlawful to sell or distribute under FIFRA section 12(a)(1)(E). 40 CFR 156.10(a)(5) list examples of statements EPA may consider false or misleading. In addition, regardless of whether a website is referenced on your product’s label, claims made on the website may not substantially differ from those claims approved through the registration process. Therefore, should the Agency find or if it is brought to our attention that a website contains false or misleading statements or claims substantially differing from the EPA approved registration, the website will be referred to the EPA’s Office of Enforcement and Compliance.

Page 2 of 2 EPA Reg. No. 7969-186 Decision No. 521087

Your release for shipment of the product constitutes acceptance of these conditions. If these conditions are not complied with, the registration will be subject to cancellation in accordance with FIFRA section 6.

If you have any questions, please contact Tony Kish by phone at 703 308-9443, or via email at kish.tony@epa.gov; or Craig Reeves by phone at 703 347-0486, or via email at reeves.craig@epa.gov.

Sincerely,

Tony Kish, Product Manager 22 Fungicide Branch Registration Division (7505P) Office of Pesticide Programs

Enclosure: Stamped Label

For use in disease control and plant health in the following crops: alfalfa, barley, citrus fruit, corn (all types), cotton, dried shelled peas and beans, edible-podded legume vegetables, grass grown for seed, mint, oats, oilseed crops, peanut, pecan, rye, sorghum, soybean, succulent shelled peas and beans, sugar beet, sugarcane, tuberous and corm vegetables (includes potato), and wheat and triticale Active Ingredient*: pyraclostrobin: (carbamic acid, [2-[[[1-(4-chlorophenyl)-1H-pyrazol-3- yl]oxy]methyl]phenyl]methoxy-, methyl ester) . . . . . . . . . . . . . . . . . . . . . . . . . . . 23.6% Other Ingredients**: . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 76.4% Total: . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 100.0%

• Equivalent to 2.09 pounds of pyraclostrobin per gallon. ** Contains petroleum distillates. EPA Reg. No. 7969-186 EPA Est. No. KEEP OUT OF REACH OF CHILDREN WARNING/AVISO See inside for complete First Aid, Precautionary Statements, Directions For Use, Conditions of Sale and Warranty, and state-specific crop and/or use site restrictions. In case of an emergency endangering life or property involving this product, call day or night 1-800-832-HELP (4357). Net Contents: BASF Corporation 26 Davis Drive, Research Triangle Park, NC 27709 Si usted no entiende la etiqueta, busque a alguien para que se la explique a usted en detalle. (If you do not understand this label, find someone to explain it to you in detail.) Group 11 Fungicide Jan 26, 2017 7969-186

2 Precautionary Statements Hazards to Humans and Domestic Animals WARNING. May be fatal if swallowed. Avoid contact with skin, eyes, or clothing. Causes moderate eye irritation. Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco, or using the toilet. Wear long sleeved shirt and long pants, socks, shoes, waterproof gloves, and protective eyewear. Personal Protective Equipment (PPE) Applicators and other handlers must wear: • Long sleeved shirt and long pants • Protective eyewear • Shoes plus socks • Waterproof gloves Follow the manufacturer’s instructions for cleaning and maintaining PPE. If no such instructions for washables exist, use detergent and hot water. Keep and wash PPE separately from other laundry. Engineering Controls Statement When handlers use closed systems, enclosed cabs, or air- craft in a manner that meets the requirements listed in the Worker Protection Standard (WPS) for agricultural pesticides [40 CFR 170.240(d)(4-6)], the handler PPE requirements may be reduced or modified as specified in the WPS. Environmental Hazards This product may contaminate water through drift of spray in wind. This product has a potential for runoff for several months or more after application. Poorly draining soils and soils with shallow water tables are more prone to produce runoff that contains this product. A level, well-maintained vegetative buffer strip between areas to which this product is applied and surface water features such as ponds, streams, and springs will reduce the potential for contami- nation of water from rainfall runoff. Runoff of this product will be reduced by avoiding applications when rainfall is forecast to occur within 48 hours. Sound erosion control practices will reduce this product’s contribution to surface water contamination. This pesticide is toxic to fish and aquatic invertebrates. Drift and runoff may be hazardous to aquatic organisms in water adjacent to treated areas. DO NOT apply directly to water, areas where surface water is present, or intertidal areas below the mean high water mark. DO NOT contaminate water when disposing of equipment washwaters or rinsate. USER SAFETY RECOMMENDATIONS Users should: • Wash hands before eating, drinking, chewing gum, using tobacco, or using the toilet. • Remove clothing/PPE immediately if pesticide gets inside. Then wash thoroughly and put on clean clothing. • Remove PPE immediately after handling this product. Wash the outside of gloves before removing. As soon as possible, wash thoroughly and change into clean clothing. FIRST AID If swallowed • Call a poison control center or doctor immediately for treatment advice. • DO NOT give any liquid to the person. • DO NOT induce vomiting unless told to do so by a poison control center or doctor. • DO NOT give anything by mouth to an unconscious person. If on skin or clothing • Take off contaminated clothing. • Rinse skin immediately with plenty of water for 15 to 20 minutes. • Call a poison control center or doctor for treatment advice. If in eyes • Hold eyes open and rinse slowly and gently with water for 15 to 20 minutes. • Remove contact lenses, if present, after first 5 minutes; then continue rinsing eyes. • Call a poison control center or doctor for treatment advice. If inhaled • Move person to fresh air. • If person is not breathing, call 911 or an ambulance; then give artificial respiration, preferably by mouth to mouth, if possible. • Call a poison control center or doctor for further treatment advice. Note to Physician: Contains petroleum distillate. Vomiting may cause aspiration pneumonia. HOTLINE NUMBER Have the product container or label with you when calling a poison control center or doctor or going for treatment. You may also contact BASF Corporation for emergency medical treatment information: 1-800-832-HELP (4357).

3 Groundwater Advisory This chemical has properties and characteristics associat- ed with chemicals detected in groundwater. This chemical may leach into groundwater if used in areas where soils are permeable, particularly where the water table is shallow. Directions For Use It is a violation of federal law to use this product in a man- ner inconsistent with its labeling. DO NOT apply this product in a way that will contact workers or other persons, either directly or through drift. Only protected han- dlers may be in the area during application. For any requirements specific to your state or tribe, consult the agency responsible for pesticide regulation. (continued) AGRICULTURAL USE REQUIREMENTS Use this product only in accordance with its labeling and with the Worker Protection Standard (WPS), 40 CFR part 170. This standard contains requirements for the protec- tion of agricultural workers on farms, forests, nurseries, and greenhouses, and handlers of agricultural pesticides. It contains requirements for training, decontamination, notification, and emergency assistance. It also contains specific instructions and exceptions pertaining to the statements on this label about personal protective equip- ment (PPE), notification to workers, and restricted-entry interval. The requirements in this box only apply to uses of this product that are covered by the Worker Protection Standard. DO NOT enter or allow worker entry into treated areas during the restricted-entry interval (REI) of 12 hours. PPE required for early entry to treated areas that is permitted under the Worker Protection Standard and that involves contact with anything that has been treated, such as plants, soil, or water, is: • Coveralls • Waterproof gloves • Shoes plus socks • Protective eyewear STORAGE AND DISPOSAL DO NOT contaminate water, food, or feed by storage or disposal. Pesticide Storage Store in original containers only. Keep container closed when not in use. DO NOT store near food or feed. Pesticide Disposal Wastes resulting from using this product may be disposed of on-site or at an approved waste disposal facility. If these wastes cannot be disposed of according to label instructions, contact your State Pesticide or Environmental Control Agency, or the Hazardous Waste representatives at the nearest EPA Regional Office for guidance. Container Handling Nonrefillable Container. DO NOT reuse or refill this container. Triple rinse or pressure rinse container (or equivalent) promptly after emptying; then offer for recycling, if available, or reconditioning, if appropriate, or puncture and dispose of in a sanitary landfill, or by inciner- ation, or by other procedures approved by state and local authorities. Triple rinse containers small enough to shake (capacity ≤ 5 gallons) as follows: Empty the remaining contents into application equipment or a mix tank and drain for 10 seconds after the flow begins to drip. Fill the container 1/4 full with water and recap. Shake for 10 sec- onds. Pour rinsate into application equipment or a mix tank, or store rinsate for later use or disposal. Drain for 10 seconds after the flow begins to drip. Repeat this pro- cedure two more times. Triple rinse containers too large to shake (capacity > 5 gallons) as follows: Empty the remaining contents into application equipment or a mix tank. Fill the container 1/4 full with water. Replace and tighten closures. Tip container on its side and roll it back and forth, ensuring at least one complete revolution, for 30 seconds. Stand the container on its end and tip it back and forth several times. Turn the container over onto its other end and tip it back and forth several times. Empty the rinsate into application equipment or a mix tank, or store rinsate for later use or disposal. Repeat this proce- dure two more times. Pressure rinse as follows: Empty the remaining con- tents into application equipment or mix tank and continue to drain for 10 seconds after the flow begins to drip. Hold container upside down over application equipment or mix tank, or collect rinsate for later use or disposal. Insert pressure rinsing nozzle in the side of the container and rinse at about 40 PSI for at least 30 seconds. Drain for 10 seconds after the flow begins to drip.

In Case of Emergency In case of large-scale spillage regarding this product, call: • CHEMTREC 1-800-424-9300 • BASF Corporation 1-800-832-HELP (4357) In case of medical emergency regarding this product, call: • Your local doctor for immediate treatment • Your local poison control center (hospital) • BASF Corporation 1-800-832-HELP (4357) Steps to be taken in case material is released or spilled: • In case of spill on floor or paved surfaces, mop and remove to chemical waste storage area until proper dis- posal can be made if product cannot be used according to label. • Dike and contain the spill with inert material (sand, earth, etc.) and transfer liquid and solid diking material to sepa- rate containers for disposal. • Remove contaminated clothing and wash affected skin areas with soap and water. • Wash clothing before reuse. • Keep the spill out of all sewers and open bodies of water. Product Information This package contains Headline, an emulsifiable concen- trate (EC). The active ingredient in Headline, pyraclostrobin, is a member of the strobilurin class of chemistry and is derived from a natural antifungal substance. Preventive applications optimize disease con- trol, resulting in improved plant health. The increase in plant health comes from the combined effect of disease control (including fungal diseases listed in Crop-specific directions), improved growth efficiency and improved stress tolerance. Overall increased plant health may result in an improvement in crop growth and crop quality as well as increased crop yields. Information regarding the contents and levels of metals in this product is available on the Internet at http://www.aapfco.org/metals.htm. To maximize disease control, apply Headline in a regularly scheduled protective spray program and use in a rotation program with other fungicides. Because of its high specific activity, Headline has good residual activity against target fungi. Headline is not for use in greenhouse or transplant production. Mode of Action Pyraclostrobin, the active ingredient of Headline, belongs to the group of respiration inhibitors classified by the U.S. EPA and Canada PMRA as Quinone Outside Inhibitors (QoI) or target site of action Group 11 fungicides. Resistance Management Headline is effective against pathogens resistant to fungi- cides with modes of action different from those of QoI fungicides (target site Group 11), such as dicarboximides, sterol inhibitors, benzimidazoles, or phenylamides. Fungal isolates resistant to Group 11 fungicides, such as pyraclostrobin, azoxystrobin, fluoxastrobin, trifloxystrobin, and kresoxim-methyl, may eventually dominate the fungal population if Group 11 fungicides are used predominantly and repeatedly in the same field in successive years as the primary method of control for the targeted pathogen species. This may result in reduction of disease control by Headline or other Group 11 fungicides. DO NOT exceed the maximum annual use rate or the total number of Headline applications per year and the maxi- mum number of Headline applications stated in Restrictions and Limitations - All Crops and Table 2. Headline ® fungicide Crop-specific Requirements. Follow the label instructions for use of Headline or other target site of action Group 11 fungicides that have a similar site of action on the same pathogens. When using a Group 11 fungicide as a solo product, the number of applications should be no more than 1/3 of the total number of fungicide applications per year. STORAGE AND DISPOSAL (continued) Container Handling (continued) Refillable Container. Refill this container with Headline® fungicide only. DO NOT reuse this container for any other purpose. Triple rinsing the container before final dis- posal is the responsibility of the person disposing of the container. Cleaning before refilling is the responsibility of the refiller. Triple rinse as follows: To clean the container before final disposal, empty the remaining contents from this container into application equipment or mix tank. Fill the container about 10% full with water. Agitate vigorously or recirculate water with the pump for 2 minutes. Pour or pump rinsate into application equipment or rinsate collec- tion system. Repeat this rinsing procedure two more times. When this container is empty, replace the cap and seal all openings that have been opened during use; return the container to the point of purchase or to a designated location. This container must only be refilled with Headline. Prior to refilling, inspect carefully for damage such as cracks, punctures, abrasions, worn-out threads and closure devices. Check for leaks after refilling and before transport. DO NOT transport if this container is damaged or leaking. If the container is damaged, or leak- ing, or obsolete and not returned to the point of purchase or to a designated location, triple rinse emptied container and offer for recycling, if available, or dispose of container in compliance with state and local regulations. 4

In programs in which tank mixes or pre-mixes of a Group 11 fungicide with a fungicide of another group are utilized, the number of Group 11 fungicide (QoI)-containing applications should be no more than 1/2 of the total num- ber of fungicide applications per year. In programs in which applications of Group 11 fungicides are made with both solo products and mixtures, the num- ber of Group 11 fungicide (Qol)-containing applications should be no more than 1/2 of the total number of fungi- cide applications per year. In fungicide alternation programs of Group 11 (QoI)- containing fungicides with non-Group 11 fungicides of dif- ferent modes of action, the maximum number of sequential applications stated in Restrictions and Limitations - All Crops and Table 2. Headline ® fungicide Crop-specific Requirements must be alternated with at least an equal number of applications of a non-Group 11-containing fun- gicide prior to using the Group 11 (QoI)-containing fungicide again. For example, in cases where two sequen- tial applications of a Group 11 (QoI)-containing fungicide are made, this block of applications should be followed by 2 or more applications of a non-Group 11-containing fun- gicide prior to using the Group 11 (QoI)-containing fungicide again. Resistance Management Advisory The following instructions may be considered to delay the development of fungicide resistance:

1. Tank mixtures - Use tank mixtures with effective fungi- cides from different target-site-of-action groups that are registered/permitted for the same use and that are effec- tive against the pathogens of concern. Use at least the minimum labeled rates of each fungicide in the tank mix.
2. IPM - Headline should be integrated into an overall dis- ease and pest management program. Cultural practices known to reduce disease development should be followed. Consult your local extension specialist, certified crop advisor and/or BASF representative for additional IPM strategies established for your area. Headline may be used in agricultural extension advisory (disease fore- casting) programs, which recommend application timing based on environmental factors favorable for disease development.
3. Monitoring - Monitor efficacy of all fungicides used in the disease management program against the targeted pathogen and record other factors that may influence fungicide performance and/or disease development. If a Group 11 target-site fungicide, such as Headline, appears to be less effective against a pathogen that it previously controlled or suppressed, contact a BASF representative, local extension specialist, or certified crop advisor for further investigation. Cleaning Spray Equipment Spraying equipment must be cleaned thoroughly before and after applying this product, particularly if a product with the potential to injure crops was used prior to Headline. Application Instructions Apply rates of Headline as instructed Table 2. Headline® fungicide Crop-specific Requirements section of the Headline container label. Apply Headline with ground sprayer, aerial equipment or through sprinkler irrigation equipment. Equipment should be checked frequently for calibration. Under low-level disease conditions, the minimum applica- tion rates can be used while maximum application rates and shortened spray schedules are recommended for severe or threatening disease conditions. Ground Application Apply Headline in sufficient water to ensure thorough cov- erage of foliage, blooms, and fruit. Refer to Additives and Tank Mixing Information section for adjuvant or crop oil restrictions for ground applications in corn. See Table 2. Headline® fungicide Crop-specific Requirements for in-furrow instructions. Aerial Application For aerial application in New York State, DO NOT apply within 100 feet of aquatic habitats (such as, but not limited to lakes, reservoirs, rivers, streams, marshes, ponds, estuaries, and commercial fish ponds). Unless otherwise specified on this label, use no less than 5 gallons of spray solution per acre. For aerial application to citrus orchards, use no less than 10 gallons of spray solution per acre. DO NOT apply when conditions favor drift from target area. Aerial application to alfalfa, barley, corn, oats, rye, soybeans, wheat and triticale Aerial applications of Headline may be made to corn, soy- beans, wheat and triticale in water volumes of 1 or more gallons of spray solution per acre (gpa). Aerial applications of Headline may be made to alfalfa, barley, oats and rye in water volumes of 2 or more gallons of spray solution per acre (gpa). The use of a crop oil or adjuvant may be used to improve spray coverage (see Additives and Tank Mixing Information section). Refer to the adjuvant prod- uct label for specific use directions and restrictions. For optimum results in cases of high disease pressure, use a minimum spray volume of 4 gpa. Select spray nozzles, pumping pressure, and sprayer height to provide medium- to-fine spray droplets that penetrate throughout the crop canopy. Spray calibration must be conducted to confirm spray droplet sizes. Continue to monitor spray application (including weather conditions) to assure proper droplet size and canopy penetration. 5

Spray Drift Management DO NOT spray when conditions favor drift beyond area intended for application. Conditions that may contribute to drift include thermal inversion, wind speed and direction, spray nozzle/pressure combinations, spray droplet size, temperature/humidity, etc. Contact your state extension agent for spray drift prevention guidelines in your area. All aerial and ground application equipment must be properly maintained and calibrated using appropriate carriers. Avoiding spray drift at the application site is the responsibil- ity of the applicator. Aerial Application Methods and Equipment The interaction of many equipment- and weather-related factors determines the potential for spray drift. The applica- tor and the grower are responsible for considering all these factors when making decisions. DO NOT apply under circumstances where possible drift to unprotected persons, to food, forage, or other plantings that might be damaged, or crops thereof rendered unfit for sale, use or consumption can occur. DO NOT release spray at a height greater than 10 feet above the crop canopy unless a greater height is required for aircraft safety. The following drift management requirements must be fol- lowed to avoid off-target drift movement from aerial applications to agricultural field crops. These requirements DO NOT apply to forestry applications, public health uses or to applications using dry formulations.

1. The distance of the outermost nozzles on the boom must not exceed 3/4 the length of the wingspan or rotor.
2. Nozzles must always point backward parallel with the airstream and never be pointed downward more than 45 degrees. Where states have more stringent regulations, they must be observed. The applicator must be familiar with and take into account the information covered in the aerial drift reduction advisory information. Information on Droplet Size The most effective way to reduce drift potential is to apply large droplets. Use the largest droplet size consistent with acceptable efficacy. Applying larger droplets reduces drift potential but will not prevent drift if applications are made improperly or under unfavorable environmental conditions (see Wind; Temperature and Humidity; and Temperature Inversions). Controlling Droplet Size: • Volume - Use high flow rate nozzles to apply the highest practical spray volume. Nozzles with higher rated flows produce larger droplets. • Pressure - DO NOT exceed the nozzle manufacturer’s recommended pressures. For many nozzle types, lower pressure produces larger droplets. When higher flow rates are needed, use higher flow rate nozzles instead of increasing pressure. • Number of Nozzles - Use the minimum number of noz- zles that provide uniform coverage. • Nozzle Orientation - Orienting nozzles so that the spray is released parallel to the airstream produces larger droplets than other orientations and is recommended practice. Significant deflection from the horizontal will reduce droplet size and increase drift potential. • Nozzle Type - Use a nozzle type that is designed for the intended application. With most nozzle types, narrower spray angles produce larger droplets. Consider using low-drift nozzles. Solid-stream nozzles oriented straight back produce the largest droplets and the lowest drift. Wind DO NOT apply at wind speeds greater than 15 mph. Drift potential is lowest when wind speed does not exceed 10 mph. However, many factors, including droplet size and equipment type, determine drift potential at any given speed. Application should be avoided below 2 mph due to variable wind direction and high inversion potential. Local terrain can influence wind patterns. Every applicator should be familiar with local wind patterns and how they affect spray drift. Temperature and Humidity Low humidity and high temperatures increase the evapora- tion of spray droplets and, therefore, the likelihood of increased spray drift. Avoid spraying during conditions of low humidity and/or high temperatures. When making applications in low relative humidity, set up equipment to produce larger droplets to compensate for evaporation. Droplet evaporation is most severe when conditions are both hot and dry. Temperature Inversions Applications should not occur during a temperature inver- sion because drift potential is high. Temperature inversions restrict vertical air mixing, which causes small, suspended droplets to remain in a concentrated cloud. This cloud can move in unpredictable directions due to the light, variable winds common during inversions. Temperature inversions are characterized by increasing temperatures with altitude and are common on nights with limited cloud cover and light-to-no wind. They begin to form as the sun sets and often continue into the morning. Their presence can be indicated by ground fog; however, if fog is not present, inversions can also be identified by the movement of smoke from a ground source or an aircraft smoke generator. Smoke that layers and moves laterally in a concentrated cloud (under low wind conditions) indicates an inversion, while smoke that moves upward and rapidly dissipates indicates good vertical air mixing. Sensitive Areas The pesticide should only be applied when the potential for drift to adjacent sensitive areas (e.g. bodies of water or nontarget crops) is minimal and when wind is blowing away from the sensitive areas. 6

Directions For Use Through Sprinkler Irrigation Systems Sprayer Preparation Chemical tank and injector system should be thoroughly cleaned. Flush system with clean water. Application Instructions Apply Headline® fungicide at rates and timings as required in this label. Sprinkler Irrigation Applications Use Precautions • Apply this product only through sprinkler irrigation sys- tems including center pivot, lateral move, end tow, side (wheel) roll, traveler, big gun, solid set, or hand move irri- gation systems. DO NOT apply this product through any other type of irrigation system. • Add this product to the pesticide supply tank containing sufficient water to maintain a continuous flow by the injection equipment. In continuous moving systems, inject this product/water mixture continuously, applying the labeled rate per acre for that crop. DO NOT exceed 1/2 inch (13,577 gallons) per acre. In stationary or non- continuous moving systems, inject the product/water mixture in the last 15 to 30 minutes of each set allowing sufficient time for all of the required pesticide to be applied by all the sprinkler heads and applying the labeled rate per acre for that crop. DO NOT apply when wind speed favors drift beyond the area intended for treatment. Crop injury, lack of effectiveness, or illegal pesticide residues in the crop can result from non- uniform distribution of treated water. Thorough coverage of foliage is required for good control. Good agitation should be maintained during the entire application period. • If you have questions about calibration, you should con- tact state extension service specialists, equipment manufacturers or other experts. • The system must contain a functional check valve, vacuum-relief valve, and low-pressure drain appropriately located on the irrigation pipeline to prevent water-source contamination from backflow. • The pesticide injection pipeline must contain a functional, automatic, quick-closing check valve to prevent the flow of fluid back toward the injection pump. • The pesticide injection pipeline must also contain a func- tional, normally closed, solenoid-operated valve located on the intake side of the injection pump and connected to the system interlock to prevent fluid from being with- drawn from the supply tank when the irrigation system is either automatically or manually shut down. • The system must contain functional interlocking controls to automatically shut off the pesticide-injection pump when the water pump motor stops. • The irrigation line or water pump must include a function- al pressure switch that will stop the water pump motor when the water pressure decreases to the point where pesticide distribution is adversely affected. • Systems must use a metering pump, such as a positive displacement injection pump (e.g. diaphragm pump), effectively designed and constructed of materials that are compatible with pesticides and capable of being fitted with a system interlock. • Allow sufficient time for pesticide to be flushed through all lines and all nozzles before turning off irrigation water. A person knowledgeable of the chemigation system and responsible for its operation, or under supervision of the responsible person, shall shut the system down and make necessary adjustments should the need arise. • DO NOT connect an irrigation system (including green- house systems) used for pesticide application to a public water system unless the pesticide label-prescribed safety devices for public water systems are in place. Specific Instructions for Public Water Systems:

1. Public water system means a system for the provision to the public of piped water for human consumption if such system has at least 15 service connections or regularly serves an average of at least 25 individuals daily at least 60 days out of the year.
2. Chemigation systems connected to public water systems must contain a functional, reduced-pressure zone, back-flow preventer (RPZ) or the functional equiv- alent in the water supply line upstream from the point of pesticide introduction. As an option to the RPZ, the water from the public water system should be discharged into a reservoir tank prior to pesticide intro- duction. There shall be a complete physical break (air gap) between the outlet end of the fill pipe and the top or overflow rim of the reservoir tank of at least twice the inside diameter of the fill pipe.
3. The pesticide injection pipeline must contain a function- al, automatic, quick-closing check valve to prevent the flow of fluid back toward the injection pump.
4. The pesticide injection pipeline must contain a function- al, normally closed, solenoid-operated valve located on the intake side of the injection pump and connected to the system interlock to prevent fluid from being withdrawn from the supply tank when the irrigation sys- tem is either automatically or manually shut down.
5. The system must contain functional interlocking controls to automatically shut off the pesticide injection pump when the water pump motor stops, or in cases where there is no water pump, when the water pressure decreases to the point where pesticide distribution is adversely affected.
6. Systems must use a metering pump, such as a positive displacement injection pump (e.g. diaphragm pump), effectively designed and constructed of materials that are compatible with pesticides and capable of being fit- ted with a system interlock. Additives and Tank Mixing Information Headline can be tank mixed with most recommended fungicides, insecticides, herbicides, liquid fertilizers, biologi- cal control products, adjuvants, and additives as specified in Table 2. Headline ® fungicide Crop-specific Requirements. Under some conditions, the use of additives or adjuvants may improve the performance of Headline. However, all 7

varieties and cultivars have not been tested with possible tank mix combinations. Local conditions can also influence crop tolerance and may not match those under which BASF has conducted testing. Physical incompatibility, reduced disease control, or crop injury may result from mixing Headline ® fungicide with other products. Therefore, before using any tank mix (fungicides, insecti- cides, herbicides, liquid fertilizers, biological control products, adjuvants and additives), test the combination on a small portion of the crop to be treated to ensure that a phytotoxic response will not occur as a result of applica- tion. Always follow the most restrictive label. Adjuvant or Crop Oil Use Limitations on Corn (ground and aerial applications) Adjuvant crop damage can occur when an adjuvant or crop oil is used after the V8 stage and before the VT stage (the VT stage is defined as when the tassel’s last branch is completely visible outside the whorl). If an adjuvant or crop oil is used after the V8 stage and before the VT stage, the grower and user are responsible for contacting the adju- vant source (adjuvant distributor, retailer, or manufacturer) for advice and confirmation that the adjuvant has been tested and proven to be safe for application from V8 to VT corn stage. Refer to adjuvant and/or crop oil labels for spe- cific use directions and restrictions. Always follow the most restrictive label. Another fungicide or an insecticide may be included in the tank mix if needed and labeled for use on corn. Refer to the tank mix pesticide product labels for specific use direc- tions and restrictions. Always follow the most restrictive label. Mixing Order

1. Water - Agitate a thoroughly clean sprayer tank three- quarters full of clean water.
2. Agitation - Maintain constant agitation throughout mix- ing and application.
3. Inductor - If an inductor is used, rinse it thoroughly after each component has been added.
4. Products in PVA bags - Place any product contained in water-soluble PVA bags into the mixing tank. Wait until all water-soluble PVA bags have fully dissolved and the product is evenly mixed in the spray tank before continuing.
5. Water-dispersible products (such as dry flowables, wettable powders, suspension concentrates, or suspo-emulsions).
6. Water-soluble products.
7. Emulsifiable concentrates (such as Headline, or oil concentrates when applicable).
8. Water-soluble additives (such as AMS or UAN when applicable).
9. Remaining quantity of water. Make sure that each component is thoroughly mixed and suspended before adding tank mix partners. Maintain con- stant agitation during application. See Table 2. Headline ® fungicide Crop-specific Requirements for more details. Restrictions and Limitations - All Crops • DO NOT exceed the maximum product rate (fl ozs/A) per year, the maximum rate per application, or the total num- ber of applications of Headline per year as stated in Table 1. Headline ® fungicide Restrictions and Limitations Overview and Table 2. Headline® fungicide Crop-specific Requirements. Preharvest interval (PHI) restrictions are also included in these tables. • DO NOT use Headline in greenhouse or transplant production. • For aerial application in New York State, DO NOT apply within 100 feet of aquatic habitats (such as, but not limited to lakes, reservoirs, rivers, streams, marshes, ponds, estuaries, and commercial fish ponds). Crop Rotation Restriction Crops listed on the Headline, Cabrio® EG fungicide and Pristine® fungicide labels may be planted immediately following the last application. For all other crops, DO NOT plant sooner than 14 days after the last application. Ground Application Directed or Banded Sprays The application rates shown in the following tables pertain to both aerial and ground (broadcast) methods of applica- tion. Headline may also be applied as a directed or banded spray over the rows or plant beds with alleys or row middles left unsprayed. For such uses, reduce the rate of Headline in proportion to the area actually sprayed. This adjustment is necessary to prevent applying the product at use rates higher than permitted on this label. Use the following formula to determine the broadcast equivalent rate for doing directed or banded sprays: sprayed bed width + unsprayed row middles = total row width Example: A directed spray application will be made to 45 inches plant beds that are separated by 15 inches of unsprayed row-middles. 45 inches sprayed bed width + 15 inches unsprayed row middles = 60 inches total row width The calculations to determine the appropriate equivalent rate of product to use for this situation based on a label broadcast rate of 12 fl ozs/acre follows: Sprayed Bed Width in Inches X Broadcast Rate = Band Rate Total Row Width in Inches Treated Acre Field Acre 45 Inches Sprayed Bed Width X 12 fl ozs Headline = 9 fl ozs Headline 60 Inches Total Row Width Treated Acre Field Acre 8

9 Table 1. Headline® fungicide Restrictions and Limitations Overview1 Crop/Crop Group2 Minimum Time from Application to Harvest (PHI) (days) Maximum Product Rate per Application (fl ozs/A) Maximum Number of Sequential Foliar Applications Maximum Product Rate per Year (fl ozs/A) (lb ai pyraclostrobin) Alfalfa3 14 9 3 27 (0.45) Barley See Table 2. Headline® fungicide Crop-specific Requirements 9 2 18 (0.29) Citrus Fruit Group4 0 15 2 54 (0.88) Corn5, 6 (all types) 7 12 2 72 (1.18) Cotton5 30 12 2 36 (0.58) Dried Shelled Peas and Beans 5, 6 (except soybeans) 21 9 2 18 (0.29) Edible-podded Legume Vegetables 7 9 2 18 (0.29) Grass Grown for Seed 14 12 2 24 (0.39) Mint 14 12 2 48 (0.78) Oats Apply no later than the beginning of flowering (Feekes 10.5, Zadok’s 59) 9 2 18 (0.29) Oilseed Crops5, 6 21 12 2 24 (0.39) Peanut5, 6 14 15 2 45 (0.73) Pecan 14 7 2 28 (0.46) Rye Apply no later than 50% head emergence (Feekes 10.3, Zadok’s 55) 9 2 18 (0.29) Sorghum Apply no later than 25% flowering 12 1 12 (0.20) Soybean5, 6 21 12 2 24 (0.39) Succulent Shelled Peas and Beans 7 9 2 18 (0.29) Sugar Beet5 (roots and tops) 7 12 2 48 (0.78) Sugarcane7 14 12 2 48 (0.78) Tuberous and Corm Vegetables Subgroup 5 (including potato) 3 12 1 72 (1.18) Wheat and Triticale Apply no later than the beginning of flowering (Feekes 10.5, Zadok’s 59) 9 2 18 (0.29) (continued)

10 Table 1. Headline® fungicide Restrictions and Limitations Overview1 (continued) 1 See Table 2. Headline® fungicide Crop-specific Requirements for complete directions and exceptions. 2 For a complete list of crops within a crop group, see Table 2. Headline® fungicide Crop-specific Requirements. 3 DO NOT apply more than 27 fl ozs/A (0.45 lb ai/acre) of Headline in alfalfa per year. 4 Maximum product rate per acre per application may vary for citrus fruits depending on target disease. Refer to Table 2. Headline® fungicide Crop-specific Requirements, Citrus Fruits for maximum rates per application by target disease. 5 The maximum product rate per year includes the combination in-furrow and foliar uses. 6 Not for in-furrow use in California. 7 Not for use in sugarcane in California. Aerial application is permitted for all labeled crops. For aerial application in New York State, DO NOT apply within 100 feet of aquatic habitats (such as, but not limited to lakes, reservoirs, rivers, streams, marshes, ponds, estuaries, and commercial fish ponds).

11 Table 2. Headline® fungicide Crop-specific Requirements Crop Target Disease Product Rate per Application (fl ozs/A) Maximum Number of Sequential Foliar Applications Maximum Product Rate per Year* (fl ozs/A) Minimum Time from Application to Harvest (PHI) (days) Alfalfa Anthracnose (Colletotrichum trifolii) Rust (Uromyces spp.) Spring black stem and leaf spot (Phoma medicaginis) Common leaf spot (Pseudopezizza medicaginis) Leaf spot (Leptosphaerulina briosiani) Powdery mildew (Erysiphe pisi) Summer black stem and leaf spot (Cercospora medicaginis) Yellow leaf blotch (Leptotrichila medicaginis) Stemphyllium leaf spot (Stemphyllium spp.) Downy mildew (Peronospora trifoliorum) Rhizoctonia blight/ black patch (Rhizoctonia spp.) Stagnospora leaf spot (Stagnospora meliloti) 6 to 9 3 27 (0.45 lbs ai/acre) 14 Application Directions. For optimal disease control, begin applications of Headline prior to disease development. Resistance Management. DO NOT make more than three (3) applications of Headline per year. Repeat applications on a 14 to 21 day interval if conditions are conducive for disease development. DO NOT make more than 2 applications per cutting or 3 applications per year. Use the higher rate and shorter interval when disease pressure is high. *DO NOT apply more than 27 fl ozs/A (0.45 lb ai/acre) of Headline in alfalfa per year.

12 Table 2. Headline® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Rate per Application (fl ozs/A) Maximum Number of Sequential Foliar Applications Maximum Product Rate per Year (fl ozs/A) Minimum Time from Application to Harvest (PHI) (days) Barley Black point (Kernel blight or Head mold) (Cochliobolus sativus, Alternaria spp.) Leaf rust (Puccinia hordei, P. recondita) Net blotch (Pyrenophora teres) Powdery mildew (Erysiphe graminis f. sp., hordei) Scald (Rhynchosporium secalis) Septoria leaf and glume blotch (Septoria spp., Stagonospora spp.) Spot blotch (Cochliobolus sativus) Stem rust (Puccinia graminis f. sp., tritici) Stripe rust (Puccinia striiformis) Tan spot (Yellow leaf spot) (Pyrenophora trichostoma) 6 to 9* 2 18 (0.29 lb ai/acre) Apply no later than 50% head emergence (Feekes 10.3, Zadok’s 55); 14 days in selected states (see map). Application Directions. Begin applications of Headline prior to disease development. To maximize yields in cereals, it is important to protect the flag leaf. Apply Headline immediately after flag leaf emergence for optimum results. Headline does not control Fusarium head blight (head scab) or prevent the reductions in grain quality that can result from this disease. When head blight is a concern, growers should manage this disease with fungicides that are labeled for and effective in managing this disease, and with cultural practices like crop rotation and plowing to reduce crop residues that serve as an inoculum source. Resistance Management. To limit the potential for development of resistance, DO NOT apply more than 0.29 lb ai pyraclostrobin (= 18 fl ozs Headline) per acre per year. DO NOT make more than two (2) sequential applications of Headline before alternating to a labeled non-Group 11 fungicide with a different mode of action. DO NOT harvest barley hay or feed green-chopped barley within 14 days of last application.

• For early season control of net blotch, Septoria leaf and glume blotch, spot blotch, and tan spot when conditions favor disease development, apply 3 to 6 fl ozs per acre of Headline either in combination with a herbicide application or when conditions favor disease development. When the 3 to 6 fl ozs early season application rate is used, a second application of Headline may be required to protect the emerged flag leaf. Environmental conditions for disease or cur- rent disease pressure at the time of flag-leaf emergence should be used to determine the Headline rate for the second application. For high disease pressure, use the higher rate of Headline. Early season control is not registered for use in California.

13 Table 2. Headline® fungicide Crop-specific Requirements (continued) Application Directions (continued) Barley may be harvested 14 days after the last application in the following states: AZ (north of I-10), CO, ID, MT (west of Rt 87/I-15), NV, NM, OR, TX (west of Rt 283/377), UT, WA, and WY (west of I-25/I-90), as shown in the Headline Use Area Map, 14-Day PHI in barley. Headline Use Area Map - Barley 14-Day PHI

14 Table 2. Headline® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Rate per Application (fl ozs/A) Maximum Number of Sequential Foliar Applications Maximum Product Rate per Year (fl ozs/A) Minimum Time from Application to Harvest (PHI) (days) Citrus Fruit Group Australian desert lime Australian finger lime Australian round lime Brown River finger lime Calamondin Chironja Citron Citrus hybrids Grapefruit Japanese summer grapefruit Kumquat Lemon Lime Mediterranean mandarin Mount white lime New Guinea wild lime Orange, sour Orange, sweet Pummelo Russell River lime Satsuma mandarin Sweet lime Tachibana orange Tahiti lime Tangelo Tangerine (mandarin) Tangor Trifoliate orange Uniq fruit Cultivars, varieties and/or hybrids of these Greasy spot (Mycosphaerella citri) Scab (Elsinoe fawcettii) 9 to 12 2 54 (0.88 lb ai/acre) 0 Alternaria brown spot (Alternaria citri) Anthracnose (Colletotrichum acutatum, C. gloeosporioides) Black spot (Guignardia citricarpa) Melanose (Diaporthe citri) Post bloom fruit drop (Colletotrichum acutatum) 12 to 15 Application Directions. For optimal disease control, begin applications of Headline prior to disease development and continue on a 10- to 21-day interval. For control of diseases other than greasy spot, integrate 1 to 2 applications of Headline early in the spray program. For greasy spot control, integrate 1 to 2 applications of Headline into the fungicide program during the mid-to-late season. Use the higher rate when disease pressure is high. For aerial application to citrus orchards, use no less than 10 gallons of spray solution per acre. No livestock feeding restrictions. Resistance Management. To limit the potential for development of resistance, DO NOT apply more than 0.88 lb ai pyraclostrobin (= 54 fl ozs of Headline) per acre per year. DO NOT make more than two (2) sequential applications of Headline before alternating to a labeled fungicide with a different mode of action.

15 Table 2. Headline® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Rate per Application (fl ozs/A) Maximum Number of Sequential Foliar Applications Maximum Product Rate per Year* (fl ozs/A) Minimum Time from Application to Harvest (PHI) (days) Corn** Field corn Pop corn Sweet corn Seed prod uc tion corn Anthracnose*** (Colletotrichum graminicola) Eyespot (Kabatiella zeae) Gray leaf spot (Cercospora zea-maydis) Northern corn leaf blight*** (Exserohilum turcicum) Northern corn leaf spot*** (Cochliobolus carbonum) Physoderma brown spot*** (Physoderma maydis) Rust, common (Puccinia sorghi) Rust, southern (Puccinia polyspora) Southern corn leaf blight*** (Bipolaris maydis) Yellow leaf blight*** (Phyllosticta maydis) 6 to 12 2 72 (1.18 lbs ai/acre) 7 Application Directions. For optimal disease control, begin applications of Headline prior to disease development and continue on a 7- to 14-day interval if conditions are conducive for disease development. Use the higher rate and shorter interval when disease pressure is high. Under high disease pressure for Northern corn leaf blight and Southern corn leaf blight, apply 9 to 12 fl ozs per acre. Headline may be used with adjuvants in corn. See Additives and Tank Mixing Information and Mixing Order sec- tions for more details. No livestock feeding restrictions. Resistance Management. To limit the potential for development of resistance, DO NOT apply more than 1.18 lbs ai pyraclostrobin (= 72 fl ozs of Headline) per acre per year. In field corn, DO NOT make more than two (2) sequential applications of Headline per year. DO NOT make more than two (2) sequential applications of Headline before alternating to a labeled non-Group 11 fungicide with a different mode of action. If more than two (2) applications of Headline are made in a multiple spray program, alternate each subsequent Headline application with at least one (1) application of a non-Group 11 fungicide. *The maximum product rate per year includes the combination of in-furrow and foliar uses. ** Not for in-furrow use in California. ***The use rate in California is 9 to 12 fl ozs per acre.

16 Table 2. Headline® fungicide Crop-specific Requirements (continued) Instructions for In-furrow Use to Control Soilborne Rhizoctonia spp. and Suppression of Fusarium spp. and Pythium spp. in Corn Rate Per 1000 row feet Headline Rate (fl ozs/A) (fl oz product) 15-inch rows 20-inch rows 22-inch rows 30-inch rows 32-inch rows 34-inch rows 36-inch rows 38-inch rows 40-inch rows 0.1 3.5 0.2 7.0 5.2 4.7 3.5 3.3 3.2 3.0 0.3 10.5 7.8 7.1 5.2 5.0 4.8 4.5 4.3 4.0 0.4 see footnote1 10.4 9.5 6.9 6.7 6.4 6.0 5.7 5.4 0.5 see footnote1 see footnote1 11.8 8.7 8.4 8.0 7.5 7.1 6.7 0.6 see footnote1 see footnote1 see footnote1 10.4 10.0 9.6 9.0 8.5 8.1 0.7 see footnote1 see footnote1 see footnote1 see footnote1 11.7 11.2 10.5 10.0 9.4 0.8 see footnote1 see footnote1 see footnote1 see footnote1 see footnote1 see footnote1 12.0 11.4 10.8 Application Directions. Use 0.1 to 0.8 fl oz of Headline per 1000 row feet. Refer to this chart to determine the rate per acre. Apply at planting as an in-furrow application by directing the spray into the furrow before seed is covered. Use a minimum volume of application of 2.5 gallons of water per acre. When seedling disease pressure conditions are expected to be severe or if the field has a history of seedling diseases, use Headline at a product rate per acre equivalent to 9 to 12 fl ozs and/or tank mix with a fungicide having a different mode of action. DO NOT apply more than 12 fl ozs per acre of Headline. 1 For 32- to 34-inch rows, use a maximum of 0.7 fl oz per 1000 row feet. For 30-inch rows, use a maximum of 0.6 fl oz per 1000 row feet. For 22-inch rows, use a maximum of 0.5 fl oz per 1000 row feet. For 20-inch rows, use a maximum of 0.4 fl oz per 1000 row feet. For 15-inch rows, use a maximum of 0.3 fl oz per 1000 row feet.

17 Table 2. Headline® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Rate per Application (fl ozs/A) Maximum Number of Sequential Foliar Applications Maximum Product Rate per Year* (fl ozs/A) Minimum Time from Application to Harvest (PHI) (days) Cotton Alternaria leaf spot, boll rot (Alternaria spp.) Anthracnose, boll rot (Glomerella spp.) Ascochyta blight, boll rot (Ascochyta spp.) Cercospora blight and leaf spot (Cercospora spp.) Diplodia boll rot (Diplodia spp.) Hard lock, boll rot (Fusarium spp.) Phoma blight, boll rot (Phoma spp.) Rust (Puccinia spp., Phykopsora spp.) Stemphyllium leaf spot (Stemphyllium spp.) 6 to 12 2 36 (0.58 lb ai/acre) 30 Application Directions. For optimal foliar and boll rot disease control, begin applications of Headline prior to disease development and continue on a 7- to 14-day interval if conditions are conducive for disease development. Use the higher rate and shorter interval when disease pressure is high. For seedling disease control, see in-furrow appli- cation instructions following. Resistance Management. To limit the potential for development of resistance, DO NOT apply more than 0.58 lb ai pyraclostrobin (= 36 fl ozs Headline) per acre per year. DO NOT make more than two (2) sequential applications of Headline before alternating to a labeled non-Group 11 fungicide with a different mode of action. NO livestock grazing or feeding restrictions.

• The maximum product rate per year includes the combination of in-furrow and foliar uses.

18 Table 2. Headline® fungicide Crop-specific Requirements (continued) Instructions for In-furrow Use to Control Soilborne Rhizoctonia spp. and Suppression of Fusarium spp. and Pythium spp. in Cotton Rate Per 1000 row feet Headline Rate (fl ozs/A) (fl oz product) 15-inch rows 20-inch rows 22-inch rows 30-inch rows 32-inch rows 34-inch rows 36-inch rows 38-inch rows 40-inch rows 0.1 3.5 0.2 7.0 5.2 4.7 3.5 3.3 3.2 3.0 0.3 10.5 7.8 7.1 5.2 5.0 4.8 4.5 4.3 4.0 0.4 see footnote1 10.4 9.5 6.9 6.7 6.4 6.0 5.7 5.4 0.5 see footnote1 see footnote1 11.8 8.7 8.4 8.0 7.5 7.1 6.7 0.6 see footnote1 see footnote1 see footnote1 10.4 10.0 9.6 9.0 8.5 8.1 0.7 see footnote1 see footnote1 see footnote1 see footnote1 11.7 11.2 10.5 10.0 9.4 0.8 see footnote1 see footnote1 see footnote1 see footnote1 see footnote1 see footnote1 12.0 11.4 10.8 Application Directions. Use 0.1 to 0.8 fl oz of Headline per 1000 row feet. Refer to this chart to determine the rate per acre. Apply at planting as an in-furrow application by directing the spray into the furrow before seed is covered. Use a minimum volume of application of 2.5 gallons of water per acre. When seedling disease pressure conditions are expected to be severe or if the field has a history of seedling diseases, use Headline at a product rate per acre equivalent to 9 to 12 fl ozs and/or tank mix with a fungicide having a different mode of action. DO NOT apply more than 12 fl ozs per acre of Headline. 1 For 32- to 34-inch rows, use a maximum of 0.7 fl oz per 1000 row feet. For 30-inch rows, use a maximum of 0.6 fl oz per 1000 row feet. For 22-inch rows, use a maximum of 0.5 fl oz per 1000 row feet. For 20-inch rows, use a maximum of 0.4 fl oz per 1000 row feet. For 15-inch rows, use a maximum of 0.3 fl oz per 1000 row feet.

19 Table 2. Headline® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Rate per Application (fl ozs/A) Maximum Number of Sequential Foliar Applications Maximum Product Rate per Year* (fl ozs/A) Minimum Time from Application to Harvest (PHI) (days) Dried Shelled Peas and Beans** (except soybean) Broad bean Chickpea Guar Lablab bean Lentil Pigeon pea Lupinus spp. Grain lupin Sweet lupin White lupin Phaseolus spp. Field bean Kidney bean Lima bean Navy bean Pink bean Pinto bean Tepary bean Vigna spp. Adzuki bean Black-eyed pea Catjang Cowpea Crowder pea Moth bean Mung bean Rice bean Southern pea Urd bean Pisum spp. Field pea Anthracnose (Colletotrichum spp.) Alternaria leaf and pod spot (Alternaria spp.) Asian soybean rust (Phakopsora pachyrhizi) Ascochyta blight (Phoma exigua, Ascochyta spp.) Cercospora leaf spot (Cercospora spp.) Downy mildew (Phytophthora nicotianae) Mycosphaerella blight (Mycosphaerella spp.) Powdery mildew (Erysiphe polygoni) Rust (Uromyces appendiculatus) 6 to 9 2 18 (0.29 lb ai/acre) 21 Application Directions. For optimal disease control, begin applications of Headline prior to disease development and continue on a 7- to 14-day interval if conditions are conducive for disease development. Use the higher rate and shorter interval when disease pressure is high. Bean forage, bean hay, pea vines, and pea hay may be fed no sooner than 14 days after last application. Headline may be used with adjuvants in dried shelled peas and beans (except soybean). See Additives and Tank Mixing Information and Mixing Order sections for more details. Resistance Management. To limit the potential for development of resistance, DO NOT apply more than 0.29 lb ai pyraclostrobin (= 18 fl ozs of Headline) per acre per year. DO NOT make more than two (2) applications of Headline before alternating to a labeled non-Group 11 fungicide with a different mode of action.

• The maximum rate per year includes the combination of in-furrow and foliar uses for dried shelled beans. ** Not for in-furrow use in California.

20 Table 2. Headline® fungicide Crop-specific Requirements (continued) Instructions for In-furrow Use to Control Soilborne Rhizoctonia spp. and Suppression of Fusarium spp. and Pythium spp. in Dried Shelled Beans* (except soybeans) Rate Per 1000 row feet Headline Rate (fl ozs/A) (fl oz product) 15-inch rows 20-inch rows 22-inch rows 30-inch rows 32-inch rows 34-inch rows 36-inch rows 38-inch rows 40-inch rows 0.1 3.5 0.2 7.0 5.2 4.7 3.5 3.3 3.2 3.0 0.3 see footnote1 7.8 7.1 5.2 5.0 4.8 4.5 4.3 4.0 0.4 see footnote1 see footnote1 see footnote1 6.9 6.7 6.4 6.0 5.7 5.4 0.5 see footnote1 see footnote1 see footnote1 8.7 8.4 8.0 7.5 7.1 6.7 0.6 see footnote1 see footnote1 see footnote1 see footnote1 see footnote1 see footnote1 9.0 8.5 8.1 Application Directions. Use 0.1 to 0.6 fl oz of Headline per 1000 row feet. Refer to this chart to determine the rate per acre. Apply at planting as an in-furrow application by directing the spray into the furrow before seed is covered. Use a minimum volume of application of 2.5 gallons of water per acre. When seedling disease pressure conditions are expected to be severe or if the field has a history of seedling diseases, use Headline at a product rate per acre equivalent to 9 fl ozs and/or tank mix with a fungicide having a different mode of action. DO NOT apply more than 9 fl ozs per acre of Headline.

• Adzuki bean, black-eyed pea, broad bean, catjang, chickpea, crowder pea, field bean, grain lupin, guar, kidney bean, lablab bean, lima bean, moth bean, mung bean, navy bean, pink bean, pinto bean, rice bean, Southern pea, sweet lupin, tepary bean, urd bean, and white lupin 1 For 30- to 34-inch rows, use a maximum of 0.5 fl oz per 1000 row feet. For 20- to 22-inch rows, use a maximum of 0.3 fl oz per 1000 row feet. For 15-inch rows, use a maximum of 0.2 fl oz per 1000 row feet.

21 Table 2. Headline® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Rate per Application (fl ozs/A) Maximum Number of Sequential Foliar Applications Maximum Product Rate per Year (fl ozs/A) Minimum Time from Application to Harvest (PHI) (days) Edible-podded Legume Vegetables Jack bean Pigeon pea Soybean (immature seed) Sword bean Phaseolus spp. Runner bean Snap bean Wax bean Vigna spp. Asparagus bean Chinese longbean Moth bean Yardlong bean Pisum spp. Dwarf pea Edible-podded pea Snowpea Sugar snap pea Anthracnose (Colletotrichum spp.) Alternaria leaf and pod spot (Alternaria spp.) Asian soybean rust (Phakopsora pachyrhizi) Ascochyta blight (Phoma exigua, Ascochyta spp.) Cercospora leaf spot (Cercospora spp.) Downy mildew (Phytophthora nicotianae) Mycosphaerella blight (Mycosphaerella spp.) Powdery mildew (Erysiphe polygoni) Rust (Uromyces appendiculatus) 6 to 9 2 18 (0.29 lb ai/acre) 7 Application Directions. For optimal disease control, begin applications of Headline prior to disease development and continue on a 7- to 14-day interval if conditions are conducive for disease development. Use the higher rate and shorter interval when disease pressure is high. Bean forage, bean hay, pea vines, and pea hay may be fed no sooner than 14 days after last application. Headline may be used with adjuvants in edible-podded legume vegetables. See Additives and Tank Mixing Information and Mixing Order sections for more details. Resistance Management. To limit the potential for development of resistance, DO NOT apply more than 0.29 lb ai pyraclostrobin (= 18 fl ozs of Headline) per acre per year. DO NOT make more than two (2) applications of Headline before alternating to a labeled non-Group 11 fungicide with a different mode of action.

22 Table 2. Headline® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Rate per Application (fl ozs/A) Maximum Number of Sequential Foliar Applications Maximum Product Rate per Year (fl ozs/A) Minimum Time from Application to Harvest (PHI) (days) Grass Grown for Seed Rust (Puccinia recondita, P. graminis) Suppression Only: Powdery mildew (Erysiphe graminis) 6 to 12 2 24 (0.39 lb ai/acre) 14 Application Directions. For optimal disease control, begin applications of Headline prior to disease development. Apply again 14 to 21 days later. Use the higher rate and shorter interval when disease pressure is high. DO NOT graze or feed forage or hay to livestock within 27 days of last application. Resistance Management. To limit the potential for development of resistance, DO NOT apply more than 0.39 lb ai pyraclostrobin (= 24 fl ozs Headline) per acre per year. DO NOT make more than two (2) applications of Headline before alternating to a labeled non-Group 11 fungicide with a different mode of action. Table 2. Headline® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Rate per Application (fl ozs/A) Maximum Number of Sequential Foliar Applications Maximum Product Rate per Year (fl ozs/A) Minimum Time from Application to Harvest (PHI) (days) Mint Leaf spot (Ramularia spp., Alternaria spp., Phoma spp.) Powdery mildew (Erysiphe spp.) Rust (Puccinia spp.) 9 to 12 2 48 (0.78 lb ai/acre) 14 Application Directions. For optimal disease control, begin applications of Headline prior to disease development and continue on a 7- to 14-day interval if conditions are conducive for disease development. Use the higher rate and shorter interval when disease pressure is high. Headline may be used with adjuvants in mint. See Additives and Tank Mixing Information and Mixing Order sec- tions for more details. Resistance Management. To limit the potential for development of resistance, DO NOT apply more than 0.78 lb ai pyraclostrobin (= 48 fl ozs Headline) per acre per year. DO NOT make more than two (2) sequential applications of Headline before alternating to a labeled non-Group 11 fungicide with a different mode of action.

23 Table 2. Headline® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Rate per Application (fl ozs/A) Maximum Number of Sequential Foliar Applications Maximum Product Rate per Year (fl ozs/A) Minimum Time from Application to Harvest (PHI) (days) Oats Crown rust (Puccinia coronata) Helminthosporium leaf spot (Drechslera avenae) Leaf blotch (Pyrenophora avenae) Leaf rust (Puccinia spp.) Septoria blotch and Stem rot (Septoria avenae, Phaeosphaeria avenaria, Stagnospora avenae) Spot blotch (Bipolaris spp.) Stem rust (Puccinia graminis) 6 to 9* 2 18 (0.29 lb ai/acre) Apply no later than the beginning of flowering (Feekes 10.5, Zadok’s 59) Application Directions. Begin applications of Headline prior to disease development. To maximize yields in cereals, it is important to protect the flag leaf. Apply Headline immediately after flag leaf emergence for optimum results. Headline does not control Fusarium head blight (head scab) or prevent reductions in grain quality that can result from this disease. When head blight is a concern, growers should manage this disease with fungicides that are labeled for and effective in managing this disease, and with cultural practices like crop rotation and plowing to reduce crop residues that serve as an inoculum source. DO NOT harvest oat hay or feed green-chopped oats within 14 days of last application. Resistance Management. To limit the potential for development of resistance, DO NOT apply more than 0.29 lb ai pyraclostrobin (= 18 fl ozs Headline) per acre per year. DO NOT make more than two (2) sequential applications of Headline before alternating to a labeled non-Group 11 fungicide with a different mode of action.

• For early season control of leaf blotch, Septoria blotch and stem rot, and spot blotch when conditions favor disease development, apply 3 to 6 fl ozs per acre of Headline either in combination with a herbicide application or when con- ditions favor disease development. When the 3 to 6 fl ozs early season application rate is used, a second application of Headline may be required to protect the emerged flag leaf. Environmental conditions for disease or current disease pressure at the time of flag-leaf emergence should be used to determine the Headline rate for the second application. For high disease pressure, use the higher rate of Headline. Early season control is not registered for use in California.

24 Table 2. Headline® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Rate per Application (fl ozs/A) Maximum Number of Sequential Foliar Applications Maximum Product Rate per Year* (fl ozs/A) Minimum Time from Application to Harvest (PHI) (days) Oilseed Crops** Flax seed Pasmo (Septoria linicola) 6 to 12 2 24 (0.39 lb ai/acre) 21 Rapeseed Blackleg (Leptosphaeria maculans) Blackspot (Alternaria spp.) Sunflower Alternaria leaf spot (Alternaria spp.) Cercospora leaf spot (Cercospora helianthi) Downy mildew (Plasmopara halstedii) Powdery mildew (Erysiphe cichoracearum) Rust (Puccinia helianthi, Uromyces spp.) Septoria leaf spot (Septoria spp.) White rust (Albugo tragopogonis) Application Directions. For optimal disease control, begin applications of Headline prior to disease development and continue on a 7- to 14-day interval if conditions are conducive for disease development. Flax seed. Apply Headline at mid-flowering (7 to 10 days after flower initiation). Make a second application 7 to 10 days later if disease persists or if weather conditions are favorable for disease development. Rapeseed. For control of blackleg, apply Headline at 2- to 4-leaf stage. For optimal control of blackspot, apply Headline at early pod development. A second application 7 to 10 days later may be made if disease persists or if weather conditions are favorable for disease development. Use the higher rate and shorter interval when disease pressure is high. Headline may be used with adjuvants in oilseed crops. See Additives and Tank Mixing Information and Mixing Order sections for more details. No livestock feeding restrictions. Resistance Management. To limit the potential for development of resistance, DO NOT apply more than 0.39 lb ai pyraclostrobin (= 24 fl ozs Headline) per acre per year. DO NOT make more than two (2) applications of Headline before alternating to a non-Group 11 fungicide with a different mode of action.

• The maximum product rate per year in sunflower includes the combination of in-furrow and foliar use. (For above- listed crops, in-furrow use is permitted in sunflower only). ** Not for in-furrow use in California.

25 Table 2. Headline® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Rate per Application (fl ozs/A) Maximum Number of Sequential Foliar Applications Maximum Product Rate per Year (fl ozs/A) Minimum Time from Application to Harvest (PHI) (days) Oilseed Crops* (continued) Borage Calendula Castor oil plant Chinese tallowtree Crambe Cuphea Echium Euphorbia Evening primrose Gold of pleasure Hare’s ear mustard Jojoba Lesquerella Lunaria Meadowfoam Milkweed Mustard seed Niger seed Oil radish Poppy seed Rose hip Safflower Sesame Stokes aster Sweet rocket Tallowwood Tea oil plant Vernonia Alternaria spp. Septoria spp. 6 to 12 2 24 (0.39 lb ai/acre) 21 Application Directions. For optimal disease control, begin applications of Headline prior to disease development and continue on a 7- to 14-day interval if conditions are conducive for disease development. Use the higher rate and shorter interval when disease pressure is high. Headline may be used with adjuvants in oilseed crops. See Additives and Tank Mixing Information and Mixing Order sections for more details. No livestock feeding restrictions. Resistance Management. To limit the potential for development of resistance, DO NOT apply more than 0.39 lb ai pyraclostrobin (= 24 fl ozs Headline) per acre per year. DO NOT make more than two (2) applications of Headline before alternating to a non-Group 11 fungicide with a different mode of action.

• Not for in-furrow use in California.

26 Table 2. Headline® fungicide Crop-specific Requirements (continued) Instructions for In-furrow Use to Control Soilborne Rhizoctonia spp. and Suppression of Fusarium spp. and Pythium spp. in Sunflower Rate Per 1000 row feet Headline Rate (fl ozs/A) (fl oz product) 15-inch rows 20-inch rows 22-inch rows 30-inch rows 32-inch rows 34-inch rows 36-inch rows 38-inch rows 40-inch rows 0.1 3.5 0.2 7.0 5.2 4.7 3.5 3.3 3.2 3.0 0.3 10.5 7.8 7.1 5.2 5.0 4.8 4.5 4.3 4.0 0.4 see footnote1 10.4 9.5 6.9 6.7 6.4 6.0 5.7 5.4 0.5 see footnote1 see footnote1 11.8 8.7 8.4 8.0 7.5 7.1 6.7 0.6 see footnote1 see footnote1 see footnote1 10.4 10.0 9.6 9.0 8.5 8.1 0.7 see footnote1 see footnote1 see footnote1 see footnote1 11.7 11.2 10.5 10.0 9.4 0.8 see footnote1 see footnote1 see footnote1 see footnote1 see footnote1 see footnote1 12.0 11.4 10.8 Application Directions. Use 0.1 to 0.8 fl oz of Headline per 1000 row feet. Refer to this chart to determine the rate per acre. Apply at planting as an in-furrow application by directing the spray into the furrow before seed is covered. Use a minimum volume of application of 2.5 gallons of water per acre. When seedling disease pressure conditions are expected to be severe or if the field has a history of seedling diseases, use Headline at a product rate per acre equivalent to 9 to 12 fl ozs and/or tank mix with a fungicide having a different mode of action. DO NOT apply more than 12 fl ozs per acre of Headline. 1 For 32- to 34-inch rows, use a maximum of 0.7 fl oz per 1000 row feet. For 30-inch rows, use a maximum of 0.6 fl oz per 1000 row feet. For 22-inch rows, use a maximum of 0.5 fl oz per 1000 row feet. For 20-inch rows, use a maximum of 0.4 fl oz per 1000 row feet. For 15-inch rows, use a maximum of 0.3 fl oz per 1000 row feet.

27 Table 2. Headline® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Rate per Application (fl ozs/A) Maximum Number of Sequential Foliar Applications Maximum Product Rate per Year* (fl ozs/A) Minimum Time from Application to Harvest (PHI) (days) Peanut** Early leaf spot (Cercospora arachidicola) Late leaf spot (Cercosporidium personatum) Pepperspot (Leptosphaerulina crassiasca) Rust (Puccinia arachidis) Web blotch (Phoma arachidicola) 6 to 15 (see details below) 2 45 (0.73 lb ai/acre) 14 Rhizoctonia limb rot, Peg rot, and Pod rot (Rhizoctonia solani) Sclerotium rot - Southern stem rot, Southern blight, and White mold (Sclerotium rolfsii) Suppression Only: Sclerotinia blight (Sclerotinia minor) 9 to 15 Cylindrocladium black rot (Cylindrocladium crotalariae) 12 to 15 Application Directions. For control of early and late leaf spot, pepperspot, rust, and web blotch, begin applications of Headline prior to disease development and continue on a 14- to 21-day interval. When using a 14-day spray interval, apply Headline at 6 to 12 fluid ounces per acre. At spray intervals between 14 and 21 days, apply Headline at 9 to 15 fluid ounces per acre. For control of Rhizoctonia and Sclerotium, begin applications of Headline prior to disease development and continue on a 14- to 28-day interval. For intervals greater than 14 days, use 15 fluid ounces per acre. Use the higher rate and/or shorter spray interval when disease pressure is high or in fields with a history of disease. Headline can be used with adjuvants in peanut; however, mixes with silicone-containing adjuvants may cause crop injury under certain conditions. See Additives and Tank Mixing Information and Mixing Order sections for more details. Peanut meal can be fed. DO NOT graze or harvest for forage use. Resistance Management. To limit the potential for development of resistance, DO NOT apply more than 0.73 lb ai pyraclostrobin (= 45 fl ozs Headline) per acre per year. DO NOT make more than two (2) sequential applications of Headline before alternating to a labeled fungicide with a different mode of action. In spray programs where four or less fungicide applications are made in a year, Headline should be alternated with at least one (1) application of a labeled non-Group 11 fungicide with a different mode of action.

• The maximum product rate per year includes the combination of in-furrow and foliar uses. ** Not for in-furrow use in California.

28 Table 2. Headline® fungicide Crop-specific Requirements (continued) Instructions for In-furrow Use to Control Soilborne Rhizoctonia spp. and Suppression of Fusarium spp. and Pythium spp. in Peanut Rate Per 1000 row feet Headline Rate (fl ozs/A) (fl oz product) 15-inch rows 20-inch rows 22-inch rows 30-inch rows 32-inch rows 34-inch rows 36-inch rows 38-inch rows 40-inch rows 0.1 3.5 0.2 7.0 5.2 4.7 3.5 3.3 3.2 3.0 0.3 10.5 7.8 7.1 5.2 5.0 4.8 4.5 4.3 4.0 0.4 see footnote1 10.4 9.5 6.9 6.7 6.4 6.0 5.7 5.4 0.5 see footnote1 see footnote1 11.8 8.7 8.4 8.0 7.5 7.1 6.7 0.6 see footnote1 see footnote1 see footnote1 10.4 10.0 9.6 9.0 8.5 8.1 0.7 see footnote1 see footnote1 see footnote1 see footnote1 11.7 11.2 10.5 10.0 9.4 0.8 see footnote1 see footnote1 see footnote1 see footnote1 see footnote1 see footnote1 12.0 11.4 10.8 Application Directions. Use 0.1 to 0.8 fl oz of Headline per 1000 row feet. Refer to this chart to determine the rate per acre. Apply at planting as an in-furrow application by directing the spray into the furrow before seed is covered. Use a minimum volume of application of 2.5 gallons of water per acre. When seedling disease pressure conditions are expected to be severe or if the field has a history of seedling diseases, use Headline at a product rate per acre equivalent to 9 to 12 fl ozs and/or tank mix with a fungicide having a different mode of action. DO NOT apply more than 12 fl ozs per acre of Headline. 1 For 32- to 34-inch rows, use a maximum of 0.7 fl oz per 1000 row feet. For 30-inch rows, use a maximum of 0.6 fl oz per 1000 row feet. For 22-inch rows, use a maximum of 0.5 fl oz per 1000 row feet. For 20-inch rows, use a maximum of 0.4 fl oz per 1000 row feet. For 15-inch rows, use a maximum of 0.3 fl oz per 1000 row feet.

29 Table 2. Headline® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Rate per Application (fl ozs/A) Maximum Number of Sequential Foliar Applications Maximum Product Rate per Year (fl ozs/A) Minimum Time from Application to Harvest (PHI) (days) Pecan Pecan scab (Cladosporium caryigenum) 6 to 7 2 28 (0.46 lb ai/acre) 14 Application Directions. Begin applications of Headline prior to disease development and continue on a 14-day inter- val. For optimum performance, Headline applications early in the spray program (e.g. prepollinationand first cover) are recommended. Resistance Management. To limit the potential for development of resistance, DO NOT apply more than 0.46 lb ai pyraclostrobin (= 28 fl ozs Headline) per acre per year. DO NOT make more than two (2) sequential applications of Headline before alternating to a labeled non-Group 11 fungicide with a different mode of action.

30 Table 2. Headline® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Rate per Application (fl ozs/A) Maximum Number of Sequential Foliar Applications Maximum Product Rate per Year (fl ozs/A) Minimum Time from Application to Harvest (PHI) (days) Rye Leaf rust (Puccinia recondita) Leaf spot (Pyrenophora spp.) Powdery mildew (Erysiphe graminis) Septoria leaf and glume blotch (Septoria spp., Stagonospora spp.) Stem rust (Puccinia graminis) Stripe rust (Puccinia striiformis) 6 to 9* 2 18 (0.29 lb ai/acre) Apply no later than 50% head emergence (Feekes 10.3, Zadok’s 55) Application Directions. Begin applications of Headline prior to disease development. To maximize yields in cereals, it is important to protect the flag leaf. Apply Headline immediately after flag leaf emergence for optimum results. Headline does not control Fusarium head blight (head scab) or prevent the reductions in grain quality that can result from this disease. When head blight is a concern, growers should manage this disease with fungicides that are labeled for and effective in managing this disease, and with cultural practices like crop rotation and plowing to reduce crop residues that serve as an inoculum source. No livestock feeding restrictions. Resistance Management. To limit the potential for development of resistance, DO NOT apply more than 0.29 lb ai pyraclostrobin (= 18 fl ozs Headline) per acre per year. DO NOT make more than two (2) sequential applications of Headline before alternating to a labeled non-Group 11 fungicide with a different mode of action.

• For early season control of leaf spot and Septoria leaf and glume blotch when conditions favor disease development, apply 3 to 6 fl ozs per acre of Headline either in combination with a herbicide application or when conditions favor disease development. When the 3 to 6 fl ozs early season application rate is used, a second application of Headline may be required to protect the emerged flag leaf. Environmental conditions for disease or current disease pressure at the time of flag-leaf emergence should be used to determine the Headline rate for the second application. For high disease pressure, use the higher rate of Headline. Early season control is not registered for use in California.

31 Table 2. Headline® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Rate per Application (fl ozs/A) Maximum Number of Sequential Foliar Applications Maximum Product Rate per Year (fl ozs/A) Minimum Time from Application to Harvest (PHI) (days) Sorghum Anthracnose (Colletotrichum graminocola) Gray leaf spot (Cercospora spp.) Northern leaf blight (Exserohilum turcicum) Rust (Puccinia spp.) Southern leaf blight (Bipolaris spp.) 6 to 12 1 12 (0.20 lb ai/acre) Apply no later than 25% flowering Application Directions. For optimal disease control, begin applications of Headline prior to disease development. Use the higher rate when disease pressure is high. Under high disease pressure for Northern leaf blight and Southern leaf blight, apply 9 to 12 fl ozs per acre. Resistance Management. To limit development of resistance, DO NOT apply more than 0.20 lb ai/acre pyraclostrobin (12 fl ozs Headline) per acre per year. DO NOT make more than one (1) application of Headline per year. If additional fungicide applications are needed, use a labeled non-Group 11 fungicide with a different mode of action.

32 Table 2. Headline® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Rate per Application (fl ozs/A) Maximum Number of Sequential Foliar Applications Maximum Product Rate per Year* (fl ozs/A) Minimum Time from Application to Harvest (PHI) (days) Soybean** Alternaria leaf spot (Alternaria spp.) Anthracnose (Colletotrichum truncatum) Asian soybean rust (Phakopsora pachyrhizi) Brown spot (Septoria glycines) Cercospora blight (Cercospora kikuchii) Frogeye leaf spot (Cercospora sojina) Pod and stem blight (Diaporthe phaseolorum) Rhizoctonia aerial blight (Rhizoctonia solani) 6 to 12 2 24 (0.39 lb ai/acre) 21 Suppression Only: Southern blight (Sclerotium rolfsii) 12 Application Directions. For optimal disease control, begin applications of Headline prior to disease development and continue on a 7- to 14-day interval if conditions are conducive for disease development. Use the higher rate and shorter interval when disease pressure is high. For control of soybean rust, apply Headline prior to infection. Headline may be used with adjuvants in soybeans. See Additives and Tank Mixing Information and Mixing Order sections for more details. Soybean forage may be fed no sooner than 14 days after last application. Soybean hay may be fed no sooner than 21 days after last treatment. Resistance Management. To limit the potential for development of resistance, DO NOT apply more than 0.39 lb ai pyraclostrobin (= 24 fl ozs Headline) per acre per year. DO NOT make more than two (2) applications of Headline before alternating to a labeled non-Group 11 fungicide with a different mode of action.

• The maximum product rate per year includes the combination of in-furrow and foliar uses. ** Not for in-furrow use in California.

33 Table 2. Headline® fungicide Crop-specific Requirements (continued) Instructions for In-furrow Use to Control Soilborne Rhizoctonia spp. and Suppression of Fusarium spp. and Pythium spp. in Soybean Rate Per 1000 row feet Headline Rate (fl ozs/A) (fl oz product) 15-inch rows 20-inch rows 22-inch rows 30-inch rows 32-inch rows 34-inch rows 36-inch rows 38-inch rows 40-inch rows 0.1 3.5 0.2 7.0 5.2 4.7 3.5 3.3 3.2 3.0 0.3 10.5 7.8 7.1 5.2 5.0 4.8 4.5 4.3 4.0 0.4 see footnote1 10.4 9.5 6.9 6.7 6.4 6.0 5.7 5.4 0.5 see footnote1 see footnote1 11.8 8.7 8.4 8.0 7.5 7.1 6.7 0.6 see footnote1 see footnote1 see footnote1 10.4 10.0 9.6 9.0 8.5 8.1 0.7 see footnote1 see footnote1 see footnote1 see footnote1 11.7 11.2 10.5 10.0 9.4 0.8 see footnote1 see footnote1 see footnote1 see footnote1 see footnote1 see footnote1 12.0 11.4 10.8 Application Directions. Use 0.1 to 0.8 fl oz of Headline per 1000 row feet. Refer to this chart to determine the rate per acre. Apply at planting as an in-furrow application by directing the spray into the furrow before seed is covered. Use a minimum volume of application of 2.5 gallons of water per acre. When seedling disease pressure conditions are expected to be severe or if the field has a history of seedling diseases, use Headline at a product rate per acre equivalent to 9 to 12 fl ozs and/or tank mix with a fungicide having a different mode of action. DO NOT apply more than 12 fl ozs per acre of Headline. 1 For 32- to 34-inch rows, use a maximum of 0.7 fl oz per 1000 row feet. For 30-inch rows, use a maximum of 0.6 fl oz per 1000 row feet. For 22-inch rows, use a maximum of 0.5 fl oz per 1000 row feet. For 20-inch rows, use a maximum of 0.4 fl oz per 1000 row feet. For 15-inch rows, use a maximum of 0.3 fl oz per 1000 row feet.

34 Table 2. Headline® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Rate per Application (fl ozs/A) Maximum Number of Sequential Foliar Applications Maximum Product Rate per Year (fl ozs/A) Minimum Time from Application to Harvest (PHI) (days) Succulent Shelled Peas and Beans Pigeon pea Vigna spp. Black-eyed pea Cowpea Southern pea Pisum spp. English pea Garden pea Green pea Broad bean Phaseolus spp. Lima bean, green Anthracnose (Colletotrichum spp.) Alternaria leaf and pod spot (Alternaria spp.) Asian soybean rust (Phakopsora pachyrhizi) Ascochyta blight (Phoma exigua, Ascochyta spp.) Cercospora leaf spot (Cercospora spp.) Downy mildew (Phytophthora nicotianae, P. phaseoli) Mycosphaerella blight (Mycosphaerella spp.) Powdery mildew (Erysiphe polygoni) Rust (Uromyces appendiculatus) 6 to 9 2 18 (0.29 lb ai/acre) 7 Application Directions. For optimal disease control, begin applications of Headline prior to disease development and continue on a 7- to 14-day interval if conditions are conducive for disease development. Use the higher rate and shorter interval when disease pressure is high. Bean forage, bean hay, pea vines, and pea hay may be fed no sooner than 14 days after last application. Headline can be used with adjuvants in succulent shelled peas and beans. See Additives and Tank Mixing Information and Mixing Order sections for more details. Resistance Management. To limit the potential for development of resistance, DO NOT apply more than 0.29 lb ai pyraclostrobin (= 18 fl ozs Headline) per acre per year. DO NOT make more than two (2) applications of Headline before alternating to a labeled non-Group 11 fungicide with a different mode of action.

35 Table 2. Headline® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Rate per Application (fl ozs/A) Maximum Number of Sequential Foliar Applications Maximum Product Rate per Year* (fl ozs/A) Minimum Time from Application to Harvest (PHI) (days) Sugar Beet (roots and tops) Cercospora leaf spot (Cercospora beticola) Powdery mildew (Erysiphe betae) 9 to 12 2 48 (0.78 lb ai/acre) 7 Application Directions. Begin applications prior to disease development. Apply Headline at 14-day intervals. Use the higher rate when disease pressure is high. Applications of Headline will aid in the control of Rhizoctonia stem canker and crown rot. In sugar beet, Headline can be combined with low rates of crop oil concentrate (COC), methylated seed oil (MSO), and nonionic surfactant (NIS) adjuvants. DO NOT use silicone-containing adjuvants. Some combinations and rates may result in temporary crop injury. Headline Tank Mixes. Headline can be tank mixed with herbicides such as Poast ® herbicide, Select® herbicide, Assure® II herbicide or Prism® herbicide for postemergence control of grasses in sugar beet. DO NOT use silicone- based adjuvants in such combinations. Headline tank mix combinations can include COC or MSO; however, crop injury may result. The likelihood and level of injury tends to increase with increasing rates of COC or MSO. See Additives and Tank Mixing Information and Mixing Order sections for more details. No livestock feeding restrictions. Resistance Management. To limit the potential for development of resistance, DO NOT apply more than 0.78 lb ai pyraclostrobin (= 48 fl ozs Headline) per acre per year. DO NOT make more than one (1) application of Headline before the 4-leaf stage of plant growth. After the 4-leaf stage of plant growth, DO NOT make more than one (1) appli- cation of Headline before alternating to a non-Group 11 fungicide with a different mode of action.

• The maximum product rate per year includes the combination of in-furrow and foliar uses.

36 Table 2. Headline® fungicide Crop-specific Requirements (continued) Instructions for In-furrow Use to Control Soilborne Rhizoctonia spp. and Suppression of Fusarium spp. and Pythium spp. in Sugar Beet Rate Per 1000 row feet Headline Rate (fl ozs/A) (fl oz product) 15-inch rows 20-inch rows 22-inch rows 30-inch rows 32-inch rows 34-inch rows 36-inch rows 38-inch rows 40-inch rows 0.1 3.5 0.2 7.0 5.2 4.7 3.5 3.3 3.2 3.0 0.3 10.5 7.8 7.1 5.2 5.0 4.8 4.5 4.3 4.0 0.4 see footnote1 10.4 9.5 6.9 6.7 6.4 6.0 5.7 5.4 0.5 see footnote1 see footnote1 11.8 8.7 8.4 8.0 7.5 7.1 6.7 0.6 see footnote1 see footnote1 see footnote1 10.4 10.0 9.6 9.0 8.5 8.1 0.7 see footnote1 see footnote1 see footnote1 see footnote1 11.7 11.2 10.5 10.0 9.4 0.8 see footnote1 see footnote1 see footnote1 see footnote1 see footnote1 see footnote1 12.0 11.4 10.8 Application Directions. Use 0.1 to 0.8 fl oz of Headline per 1000 row feet. Refer to this chart to determine the rate per acre. Apply at planting as an in-furrow application by directing the spray into the furrow before seed is covered. Use a minimum volume of application of 2.5 gallons of water per acre. When seedling disease pressure conditions are expected to be severe or if the field has a history of seedling diseases, use Headline at a product rate per acre equivalent to 9 to 12 fl ozs and/or tank mix with a fungicide having a different mode of action. DO NOT apply more than 12 fl ozs per acre of Headline. 1 For 32- to 34-inch rows, use a maximum of 0.7 fl oz per 1000 row feet. For 30-inch rows, use a maximum of 0.6 fl oz per 1000 row feet. For 22-inch rows, use a maximum of 0.5 fl oz per 1000 row feet. For 20-inch rows, use a maximum of 0.4 fl oz per 1000 row feet. For 15-inch rows, use a maximum of 0.3 fl oz per 1000 row feet.

37 Table 2. Headline® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Rate per Application (fl ozs/A) Maximum Number of Sequential Foliar Applications Maximum Product Rate per Year (fl ozs/A) Minimum Time from Application to Harvest (PHI) (days) Sugarcane* Brown Rust (Puccinia melanocephala) Orange Rust (Puccinia kuehnii) 9 to 12 2 48 (0.78 lb ai/acre) 14 Application Directions. For optimal disease control, begin applications of Headline prior to disease development and continue on a 14 to 28 day interval if conditions are conducive for disease development. Use the higher rate and shorter interval when disease pressure is high. Resistance Management. To limit the potential for development of resistance, DO NOT apply more than 48 ozs of Headline per acre per year. DO NOT make more than two (2) sequential applications of Headline before alternating to a labeled non-Group 11 fungicide with a different mode of action.

• Not for use in California.

38 Table 2. Headline® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Rate per Application (fl ozs/A) Maximum Number of Sequential Foliar Applications Maximum Product Rate per Year* (fl ozs/A) Minimum Time from Application to Harvest (PHI) (days) Tuberous and Corm Vegetables Subgroup Arracacha Arrowroot Chinese artichoke Jerusalem artichoke Cassava (bitter and sweet) Chayote (root) Chufa Dasheen Edible canna Ginger Leren Sweet potato Tanier True yam Turmeric Yam bean Downy mildew (Plasmopara spp.) Leaf spot (Cercospora spp., Alternaria spp.) Powdery mildew (Erysiphae spp., Leveillula taurica) Rust (Uromyces spp., Puccinia spp.) 6 to 12 1 72 (1.18 lbs ai/acre) 3 Potato Black dot (Colletotrichum coccodes) Early blight (Alternaria solani) 6 to 9 Late blight (Phytophthora infestans) Powdery mildew (Erysiphe spp., Leveillula taurica) Suppression Only: White mold (Sclerotinia sclerotiorum) 6 to 12 Application Directions. Begin applications of Headline at 7- to 14-day intervals prior to disease development. The low rate and longer interval can be used early season prior to the observance of symptoms and when disease pressure is low. For control of late blight, follow application of Headline with a labeled fungicide with a different mode of action 5 to 7 days later. Use the higher rates and shorter intervals once disease has been confirmed in your area or if weather conditions are conducive to disease development. No livestock feeding restrictions. Resistance Management. To limit the potential for development of resistance, DO NOT apply more than 1.18 lbs ai pyraclostrobin (= 72 fl ozs Headline) per acre per year. DO NOT make more than one (1) application of Headline fun- gicide before alternating to a labeled non-Group 11 fungicide with a different mode of action.

• The maximum product rate per year includes the combination of in-furrow and foliar uses. (For above-listed crops, in-furrow use is permitted in potato only).

39 Table 2. Headline® fungicide Crop-specific Requirements (continued) In-furrow Use to Control Soilborne Rhizoctonia spp. and Suppression of Fusarium spp. and Pythium spp. in Potatoes Use 0.4 to 0.8 fl oz of Headline per 1000 row feet (for applications on 32-inch or 34-inch rows, the maximum application rate is 0.73 fl oz/1000 row feet). Refer to the chart below to determine the rate per acre. Apply at planting as an in-furrow spray by directing spray pattern to uniformly cover seed pieces and surrounding soil. The spray pattern should be a 4- to 8-inch band that is applied to the seed piece prior to being covered with soil. When disease pressure conditions are expected to be severe or if the field has a history of Rhizoctonia infestations, use Headline at 0.6 to 0.8 fl oz per 1000 row feet and/or tank mix with a fungicide having a different mode of action. DO NOT apply more than 12 fl ozs per acre of Headline. Use a minimum volume of application of 5 gallons of water per acre. Headline Rate per 1000 row feet Headline Rate (fl ozs/A) (fl oz product) 32-inch rows 34-inch rows 36-inch rows 38-inch rows 40-inch rows 0.4 6.7 6.4 6.0 5.7 5.4 0.6 10.0 9.6 9.0 8.6 8.1 0.8 see footnote1 see footnote1 12.0 11.4 10.8 1 For 32-inch or 34-inch rows, use a maximum of 0.73 fl oz per 1000 row feet.

40 Table 2. Headline® fungicide Crop-specific Requirements (continued) Crop Target Disease Product Rate per Application (fl ozs/A) Maximum Number of Sequential Foliar Applications Maximum Product Rate per Year (fl ozs/A) Minimum Time from Application to Harvest (PHI) (days) Wheat and Triticale Black point (Kernel smudge) (Alternaria spp., Helminthosporium spp.) Leaf rust (Puccinia triticina) Powdery mildew (Erysiphe graminis f. sp., tritici) Septoria leaf and glume blotch (Septoria spp., Stagonospora spp.) Spot blotch (Cochliobolus sativus) Stem rust (Puccinia graminis f. sp., tritici) Stripe rust (Puccinia striiformis f. sp., tritici) Tan spot (Yellow leaf spot) (Pyrenophora spp.) 6 to 9* 2 18 (0.29 lb ai/acre) Apply no later than the beginning of flowering (Feekes 10.5, Zadok’s 59) Application Directions. Begin applications of Headline prior to disease development. To maximize yields in cereals, protect the flag leaf. Apply Headline immediately after flag leaf emergence for optimum results. Headline does not control Fusarium head blight (head scab) or prevent the reductions in grain quality that can result from this disease. When head blight is a concern, growers should manage this disease with fungicides that are labeled for and effective in managing this disease, and with cultural practices like crop rotation and plowing to reduce crop residues that serve as an inoculum source. DO NOT harvest wheat hay or feed green-chopped wheat within 14 days after last application. Resistance Management. To limit the potential for development of resistance, DO NOT apply more than 0.29 lb ai pyraclostrobin (= 18 fl ozs Headline) per acre per year. DO NOT make more than two (2) sequential applications of Headline before alternating to a labeled non-Group 11 fungicide with a different mode of action.

• For early season control of tan spot, Septoria leaf and glume blotch, and spot blotch when conditions favor disease development, apply 3 to 6 fl ozs per acre of Headline either in combination with a herbicide application or when con- ditions favor disease development. When the 3 to 6 fl ozs early season application rate is used, a second application of Headline may be required to protect the emerged flag leaf. Environmental conditions for disease or current disease pressure at the time of flag-leaf emergence should be used to determine the Headline rate for the second application. For high disease pressure, use the higher rate of Headline. Early season control is not registered for use in California.

Cabrio, Headline, Poast and Pristine are registered trademarks of BASF. Assure and Prism are registered trademarks of E.I. duPont de Nemours and Company. Select is a registered trademark of Arysta Life Science North America Corporation. © 2017 BASF Corporation All rights reserved. 007969-00186.20161222d.NVA 2016-04-088-0041 Supersedes: NVA 2013-04-088-0141 BASF Corporation 26 Davis Drive Research Triangle Park, NC 27709 Conditions of Sale and Warranty The Directions For Use of this product reflect the opinion of experts based on field use and tests. The directions are believed to be reliable and must be followed carefully. However, it is impossible to eliminate all risks inherently associated with the use of this product. Crop injury, ineffectiveness or other unintended consequences may result because of such factors as weather conditions, presence of other materials, or use of the product in a manner inconsistent with its labeling, all of which are beyond the control of BASF CORPORATION (“BASF”) or the Seller. To the extent consistent with applicable law, all such risks shall be assumed by the Buyer. BASF warrants that this product conforms to the chemical description on the label and is reasonably fit for the purposes referred to in the Directions For Use, subject to the inherent risks, referred to above. TO THE EXTENT CONSISTENT WITH APPLICABLE LAW, BASF MAKES NO OTHER EXPRESS OR IMPLIED WARRANTY OF FITNESS OR MERCHANTABILITY OR ANY OTHER EXPRESS OR IMPLIED WARRANTY. TO THE EXTENT CONSISTENT WITH APPLICABLE LAW, BUYER’S EXCLUSIVE REMEDY AND BASF’S EXCLUSIVE LIABILITY, WHETHER IN CONTRACT, TORT, NEGLIGENCE, STRICT LIABILITY, OR OTHERWISE, SHALL BE LIMITED TO REPAYMENT OF THE PURCHASE PRICE OF THE PRODUCT. TO THE EXTENT CONSISTENT WITH APPLICABLE LAW, BASF AND THE SELLER DISCLAIM ANY LIABILITY FOR CONSEQUENTIAL, EXEMPLARY, SPECIAL OR INDIRECT DAMAGES RESULTING FROM THE USE OR HANDLING OF THIS PRODUCT. BASF and the Seller offer this product, and the Buyer and User accept it, subject to the foregoing Conditions of Sale and Warranty which may be varied only by agreement in writing signed by a duly authorized representative of BASF. 1108 41