crop-chem-docs/corpus/epa_ppls/9779-288.md

VALCO BRAND METHYL PARATHION EMULSIFIABLE NO. 4

• EPA Reg No: 9779-288
• Registrant: WINFIELD SOLUTIONS, LLC
• Signal word: Danger
• Active ingredients: Chevron 100 (48.26%); Methyl parathion (45.49%)
• Label accepted: 1985-01-14
• Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/001063-00104-19850114.pdf

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tilII(1n. :U,1! .re. or klc: ill any way 'Pnuii7al lrt'al~ )WI:\G IIXG "r rubi'er "'er' Splnt'lr JIJJntly Admlr.lstfat!(m n.l II"IHIUH<' lor ()f 30 erR part .... lIh Si)ap !>r.d p ;ttl.:! ",Uer t:.e- -". S!:<)'"(r •.. bmg ","'E the Job Dc> .Qthmg and pro ,.lSe RI'plrator .trurljUIlS mdud- re.·II)' r through 'fig ueated cT'lut .reentc' lntef'al ~ )'our' State De: .. d;a are exp<!cted trNted 1,Iqth this , !leld.lo that may :Ici!lang pec:f:ffi O'..l.;,n,.:: \I"3Im!.'!)1 Itl(; a:d Hl cae ve'l 1f1 a [a:'"!>!.;as': '1'::!!, -:JJ'~~~~~1 19 In [ormatIOn __ .d;,.te) __ 109 lOr -\6 houa this product label .)n ((lod or forage l" DirlX{inns (or .yl parathion ttH.)' ct. mhalation or Of under ..... ('athl'r reas 1"101 Jnlended protC'-Cte-d humans ;lnd other ...... Jdhle ",liN. Keep nut of . Shrimp .md crab Ibis lahel, Do flot apply ''here fun­ er condltlor,$ favor ;.er by deamrlg of t only as specified .::IirKt treatment or obtaine4 (rom )'OUf ARO heat or name. \ RESTRICTED USE PESTICIDE For retail sa.le to and use only by Certified Applicators or persons und(>T their direct supeTvision, and only tor those uses covered by the Certiried Applicator's certiflcation. ® \ NET CONTENTS ______ GALLONS ALeo B R A N METHYL PARATHION EMULSIFIABLE NO. 4 D (CONTAINS 4 LBS. METHYL PARATHION PER GALLON) ACTIVE INGREDIENTS: BY WEIGHT O,O-dimethy! O-p-nitrophenyl Related Compounds Thiophosphate' 13.22·-~ Aromatic Petroleum Solvent I:-<ERT INGREDIENTS: TOTAL. 'Methyl Parathion 2.27% -18.26% 6.25:0 100.00% DANGER: BEFORE USING, READ THIS LABEL CAREFULLY ~ POISON DANGER KEEP OUT OF REACH OF CHILDRSN SEE OTHER WARNINGS ON LEFT PANEL Manufactured By VALLEY CHEMICAL COMPAft'V GREENVILLE P. O. BOX 1317 MISSISSIPJ-. / I / / /

( DANGER - POISON - PRECAunONS NOT FOR HOME USE r·I(t~ Jl'P.i"''U' .. ~ -.,. "'" ... ..,. ~ ---..... --... --. "' .. -- ........... 1 • ...- ..Wt..MJ._et'!I_~!...,,'1. .... .-...." .... ,.,. ....... -............. _ .. ,." ••• -0,.. ---_ .... ,-..... ........ --,- ... :ft~~~ • ... .. -....... - ~ PQlSOK SIGHS (SymptomJ) !ethyl arathion i5 a very danierous poison. It rapid!>" colen the budy Oil contact with aU ,kin sw-faces and ey. Clothing wet v. lib this materia! mW;t be remO'ed immediately. Exposed persons must re­ ceive prompt medical treatment or they may die. Some 01 the signs and .yrnptoms of po[oning art headaches, nausea, \·omltng. cramp$. \l.uknes:s, blurred vision, pin_point pupils, tightness In chest. labore..i bredthing, nef'''ousness. sweating, watering (If eyes, droohng or froll-ung of mouth and m:·se. muscle spasms and CQma. POISON ATROi>lNE IS AN ANTIDOTE. CONSULT PHYSICIAN FOR EMERGENCY SUPPLY. CALL A PHYSIClAS AT ONCE IN ALL CASES OF SUSPECTED tETH'L PAR.A.THlO:-i POISONING If symJltoms or signs of poisoning include blurted vision. abdominal cramps. and ngntn<:ss in the chest, do not \I.·<lit for a doctor but gi' t ..... o atropine tblets :;each 11100 gnin of 0.65 milligrams) at once ,r)n" tablet :0 ch!icren under {iv(o years of aie.)

• FIRST AID TREATMENT + STATEMENT OF PRACTICAL TREATMENT (",d a doctor (ph)".'idaQ), dmic or hospital immediately. ExplaiQ ';,,..t the victim has toeen exposed to me:hyl parathion and derilx­ :r .. ~ ;::nndition. If doc\N cannot corne. takc 'Ictlm to clinic or hospital. !., e patient irnn·,crl.ately (rom the area where methyl parathIOn is 'W-H'nt. !F '-:;HALED. rem·}·c \1ctim to fresh air. U not breathing immel-Ii· t,,:)· gh'e arifJ(:'! respiration. prde:3bly mouth· to· mouth. and InZl:ttain UntIl d·Xl')r sees nctim. If breathmg IS dlfflcl.!ll. gwe o~:;g(;n. IF l~ EYES Ok OX SKJ:ol, immediately flush with plenty of water for ilt least U minutts while remol'i:!! contaminated personal dCllting and sh(,e~ to avoid continued p?sslble e)tposure W 'ictim or- persor.s in attendance. • F SWALLOWED .• r,duct vomiting immediiltel)' by giving two glasses of ,.,tater and by touching back of throat ... .ith finger. DO MOT IN­ D1jCE VOMITIXG OR GIVE ANYTHING lJY MOUTH TO AN i:!'{CONSCIOUS PERSON. Han 'ic(jm lie down and k~~p quiet. HOTE TO PHYSICIAN Ail.!;j'ole - adrnin1!ler atropine sulfate in lafjte doses. TWO to FOUR m.: ir..t~&\·enously or intramuscularly as 500n as yanosis i! over· -:<;1' t'". H--peat at 5 to 10 minute intervals unl:1 signs of atropinization .lp""1or 2·PAM chlOride Is a pharmacolog.c antidote and may be ad· m.I·''itued as an ad)J..:nd to, but not a subs·lltute fOr. atropine which is .1 symptomatic ami often Hle·sa,ing ao"ltidote. DO SOT GIVE MORPHINE OR TRANQUILIZERS 8ECACSE THESE AXTIDOTES tA Y PRODUCE ADVERSE EFFECTS ACCENTUATING THE PH.\RMACOLOcaC EFFECT OF THIS PRODUCT. ThiS product is , r"g cholinesterase inhibitor affecting the central and I*ripheraJ r .. _:,o'-lS ystems and producing cardiac: and respiratory depression. .'t {'r:;.: !ign of pulmo)nary edema. the patient should be gl'en s,!p­ P:"'r'\tal o,;ygen a·1 treated sympl,(,matically_ Conhnued absorb. iOn "If tre poi..$on,!:1ay OCfur and fa"l ":~es hiV"beil\ leportt<: aft<-l \fl,tial imprr, emef\l: .• "ERY CL,')SE :tCPERVIION.OF THE P;'T!';T IS IND1(l,,-1TJ) rOR AT t.EA'iT .8 HOllRS .• $.vQHK SFrtY RiILFS' •• •• REP£..'\ n:LI :EXPOS:'RF.8 TO Ct-IoLINisT[RAS lNtlIBITORS S1jCH .... 5 ARE CO=--':'AIN:f.D IN THIS PRODUCT MAY. WITHOUT WAlenSG, CAt:SE PROLONGED SUSCEPTIBILITY TO VERY SMALL D.)SES 0: A).Y·:;HOL:NEST!fMSE nann:'OR • ( • '. f I Penura workin, wih ti1..9. prot .... :t Lhot..f.":'avl" t;cqu'" blood. tt.!J .f hfir cboUnt:ste!"e t:e"lis.j If '.he ch.Jlif.tl.ulce let1- falb below :: clllie-a; po!nl, no lurfile! d}<U" st,".Jll,t & 4;1ol".t1 until it hilS 'n dterm:ned h)' mead.! uf b.u)d t«t.s lhat th .:hOIlc.terase le ... el h ... • returl'<:'d to non11l1. Ref¢re using this product consult tbe Stat Ap-iculturf' Exteruion Service or puiInental StOltion for sific ue:ommendations fegudin, liueh blood tesu. It handled indooCl, provide mechanical e)thaust -entilation. Keep all unprotected persoru and animals a""'<I), trom tr(!ated area or .... ·here there is da.nger o( drilt. Do not rub yes or mouth with hands It you feel ick in any way STOP work <lnd ret help rirM a ..... a)·. See Fint Aid (Practkal Ireat· ment) section. USE ONLY WliEN WEARING T'HE FOLtOWlSG PROTECTIVE EQUIPMENT AND CLOTHING (I) Wear water·proof pOlnts. coil, hat. rubber bo<lu or rubber over­ shoes. (2) Wear afety goggl(!s (3) Wear a pesticid;} respirator jointly appro'ed by the Mining [nfr)r(":ement and Safety Administration .formerI)· the U.S. Buruu of Mines) and the !{ational Institute for (kcupational Safety and Health under the provisions of 30 CFR part 11 (4) Wear heavy duty nOltural rubber gloves. ILPORTA!ow." Befofe temO\·lOg gloves. \uh them With soap and water. AI ....... j"s wash hands, lace and arms ..... Ith soap and water be· lore smoking. ealing or drinking AFTER WORK take aU all work clothes and shoes. Shower using soap and water. Wear only dean cloth('S ..... }:(!n lea'lng the job. Do not wear contaminated clothing. ""ash protectIVe clothing and pro teclwe equipment with soap and waler a(ter ea(:h use. Respirator should be cle3.nfd and hlter replaced aCCOtdmg to Instructions Includ~ ed wllh re:plrator. RtENTRY STATEMENT Do not apply this product In such a mannt'r as to directly or through dnft e)tpose .... ·orkers or other persons. The area being treated must be \·acated by unprotected persOns. D:I n()t enter treatcd areas (or 46 hours unless appropriate prot('('ti\·e clothing is wotn. 8(,(,aUse certain states may rt""..(uire more restricth'{' reentry interl'als for 'arious crops treated with this product. consult )'our Slate De~ partrnent of Agriculture for further information. Written or oral warnings must be gh'en to workers who an~ expected to be in a treated area or in an area about to bt' treated ",:Uh Ihis product_ ORAL WARXIXGS shall inform workers of areas or fields that may not be entered. wiihout protective equiptnent and clothing specified On thIS label. during treatment or for 48 hours following treatm(!nt. Follow First AId Treatment instructions shown on this lab(!1 in case of acc~dcntal (!xosure Whell oral ..... arnmgs are gi\·en. warnmgs shall be gwen In a language cu,;tomarlly unaerstood by ..... orkers Oral warnmgs must te gwen If there I! reJson to behe"e ~hat .... ·ritten ..... arnings cannot be understood by HHkrs. WRITTE:-4 WAR!'OIXGS must include the foJ!lowmg information DAXGER-Art'a tr{'ated ... ·ith ~tethyl parathion on __ (dale) __ 00 nOl enter ..... lthout appropriate protecti\·e dothing for 48 hours Follow First Ai<l Trealrr.ent Instructions shown on this prOduct label In case of accidental exposure . ATTENTIOH To avoid e)tces--h'e residuei of methyl parathion on food or forage crops always obsen·e the statements f{lund under ~Diree:tions for t:e." limiting the time before han'est when methyl parathion may be applied Because this material is poisonous by $kin contact. inhalation Qr swaIJ'l ..... ing il should not be used in such a manner or under weather conoiillons as will permit dnft of thE' £pray onto areas not intended t ... be sprayed. Do not apply (.;r aUow drift to areas occupied by Unprotected humans or beneficl,ll animals. ENVIRONMENTAL HAZARD This product IS toxic to fiSh, shrimp. crab. birds, ;lnd other ..... ildlife. Birds and other wlldllfe in treat.ed area$ may be killed. Keep out of lakes. streams. ponds. tidal marshes and e-stuaries. Shrimp and crab may be killed at application rates rC'Cornmendt'd On this label. Do not apply where these are important resources. Do nl' -·· ... Iy ..... here run. oU is likely to occur. Do not apply when weal . ""Iditions favor drift from areas treated. Do not contaminate wilter by cleaning of equipment Or disposal or wastes. Apply this prodUct onl)' as specified. on this label. This product is highly toxic to bees expo!ed to dire<:t treatment or residUe! on crops. Prote-ctive informatiOQ may be obtained from your Coot>erative Agricl.lUural Extension Se ... ·ic. PHYSICAL on CHEMICAL HAZARD Combustible: Do not we, POt "pill or store nUr heat or Game. In case of FIRE. USt watr spray. ~ . dry chemical or CO ...

< ~ / I I SPILL or LE.AK keep ;1) unprotected penonS a ..... a)·. Cover with .bwrnt such as soda ash. lime, da)" or Slt....- dust. Sweep up and bw),. Wash area thorouehly .... ·itt. s\t'1.>ni lye solution.. STORACE AND DISPOSAL Do not contllmjn:;;t ..... a.tr. food. or feed by ,Iorage or disposal STORAGE AND HAh"ULlNG: I. HUldIe container cUfun)· so a$ to altoid damtge Vld prevent luka,t. 2. Do not me or store In or around Ole horne. 3. Store «mlainer iii a well ventilated place. 4. Empty ('(Illtainer retams , .. por and tm:)(Juct residue Observe .u '.bel s.afeguards until container is <:leaned, .rf'C'Onditioned or destroyed. S. Keep Ollt t)f reah of children and dOmtk animals. DtSPOSAL: Wules of this pesticide are ilcutely hazardoU$. Improper disposal oj UC'4$ peSticide. pray mixtures, or rinsate IS iii "'IQialion of federal I.,,, ... If these 'aI['$ cannot be dBposed of aC«lrdmg to label U$e in strUttlOns, contact your state pestlcldt' or £n'I:ironmen\a\ Cl)n\ro\ Alency, or the Hazardous Waste Repreentatwe at the nere.st EPA Rellonal Office for guidance. !3:Ie...!~~; ';hetYofitfe:ec:~" :r c:~~~I~~~n st~~\on un~!~~~ to prevent other ue 3nd dispOse of in an appro,,·t<:I 1andflfl. or by other proc:ure appfo ... ed b' state and 1000ai 3uthorilie$. DIRECTiONS FOR ust It i$ • 'lo)a1l0n oJ Ff'deral Law \0 use thl~ pTodu1::1 in any manner incooslstel:;{ with It, Itbehng. Be !lure 1O read the precautionilry statements befor(' using~ Thb product i50 de5igoed for apphcatllm after dilution wllh water and lor use by tramed operators uSing .llrplanc or power ground equlpmen, The hlard< and prec'lulions tor handling Ih'" product in thIS n13mer aTe equally apphcable to It after dilulion with ..... ater for spray applicatlc.n Add the concentrate 10 the spray tank while fjlline with ..... ater and mix thoroughly either b' means of a tank agitator or pump bypass_ For best resuhs_ thoroughly ct)'l:U aU sur~ facts to be treated ..... ith spray. Rat("l: of applicatIOn gwen belov.· should not be exceeded Ne"'er apply later than ihdicated 10 assure rsidul' )I;''eh at har .. e\ ar~ bl!to ..... tolerances establ:shed b)' the Food lind Drug Administration. FOR CoNTROL OF:-Boll Wee'l:il. Thrips. Cotton Aphid, F1ea Hop­ pers. Lygu'5 Bug~, TarnISh Plant Bugs ahd Stlhk Bugs on rlee MIXING: - Add the amount o! "aleu Bran~ MNh,,1 Parall.IQr. Em. Ulsl'la.ble 1'0_ 4 rec::llnmended for thf' control o! each insect te> the water n(ct'ssary to treat one aCH'_ MIlo; thoroughl belore d-pplYlng If soluuon IS allo ..... ed t~ statld se'eral hours. agitate well before uSing. USt: ON COTTON: _ Use Valea Brand MetJwl Paathion Ernuls.h. able o 4 at the rates reC'(lJr.mended belo ..... f'Or putiCUlar insect to' be controlled. This product should be ll$ed on 3 to $ day inten·als. or as nrtessary to keep insect under eontrol. The rate and inter"'al of application will depend Ilpon the size of co\on. degre-e of \Mecl infe$l.ation ...... eather. and method of application Proper tuning ttnd uniform application ttre essential for best resull.5_ Methyl parathion hJ..$. to rapid action 01'\ ins. but a short residual to:<:I(,l1y Frequent ap);)lications are often necessary Make no application within IS days of haf,'eH or pasturing. TliRlPS: - Appl)' at Tilte of one {1} g"or, p,er 20 c. BOLL WEEVIL ANb COTTON VHID; - Apply at rate o( one (II (aUon poE'r 8 to 16 ,u;:rE'"S_ , f"L.EAHOPPER. LYGUC BOGS AND TARNISHED PUNT BUGS: Apply at rate of one (I) galon per 16 to 26 acres. SOYBEANS: - For conlfol of BoUWorffiS apply a\ ute 01 one {U ,_Uon per 4 acre-s ?ot;:.ke no applicatIOns withm 20 d'n,·s of harvest Do. not appl}' more lhan twice r growing season. RICE: _ For control o( slink bugs ap);)ly at rate of one (I) gallon per liS acrs Make no application Within J5 days of han:est. WHEN MAKiNG APPLICATION'S WITH AIRPLANES: - Follow the- $Ame Apphcation Program given for ground spraye~. applying one (1) eallon per 16 acres, in I to 3 gallons spray mix per acre. MOTICl: TO USERS: Selkr Vo'arrants that the product conforms to its chemical description and is reasonably fit for the purpose staled on the label ... ·hen u.:.td, In accordance .... ·ith directions W1der normal conditions of use but ithr this warranty nor any (lther warranty of merchantability or fitness for I particular purpose, txrress or implitd, extends to th~ UIIe 01 thili product conbaT)' \0 labe instructions, or under abnormal eonditioru, or under condilions not reasonably forst-elilble to leUn. IJ\d bUyer umes !.he rltk of .,. ... luch use. S'Re-c. Trldemark (It V ALLE. ThtlCAL COMPANY I-P.A. Re,. No. 1063·10. ~ EPA Ed. lDe.3~MS.1

StJPPL£M£NTAL LABI:L1NG METHYL PARATHION f;MULSlFiABL£ NO .• For States 01 Mississippi and Arkansas sL:-i No. MS·8!O028 SLN No. AR·815533 For use on small grain; Bade}", Whc-at and Oats. apply 1I'l to 2 1/2 pts ;:X-J" s,:-re for control of aphids ond army\"orms. Us€' higher rates {or armyworm controi. DO NOT apply within 15 days of harvest. Bt rf'Sults u·m be vbt..ained when daytime tempcralur~~ are in Ute 70·s. Rt'fer to label on conta.iner (or mixing ir.:..t! oJ.:.-tivns and safely informdtion. This labeling must be in the possession of the user at t}-,(> -;.;me of appHcation. It is a violation of Federal lav: to use this product iI) a m.JflJlcr inconSlstant with its laVcling. METHYL PARATHION MIXTURE, LIQUID, POISON 8, NA .. 2783, RQ ACe E P 'l'-E D , , .. i \ 1 -. I I