crop-chem-docs/corpus/epa_ppls/9779-352.md

THIODICARB 3.2

• EPA Reg No: 9779-352
• Registrant: WINFIELD SOLUTIONS, LLC
• Signal word: Warning
• Active ingredients: Thiodicarb (34%)
• Label accepted: 1997-11-04
• Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/009779-00352-19971104.pdf

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• • 1m ol{ /(/4(97 /7 1/;0 Page 1 of 10 .CCEPTE Thiodicarb 3.2 NOV Aqueous Flowable Insecticido/Ovicide ' UDder th. FedorallnMctlclde. FuugJcld •• cmd RodepUdlc. CIa _dod. for the P""clde reg\alo,ed Wld ... ACTIVE INGREDIENT THIODICARB: EPAII • No. 77 - 3f Dimethyl N, N'[thiobis [{methyliminoj carbonyloxylJ bis !ethanimidothioatel ................................•. 34.0% INERT INGREDIENTS: ., .. , .• , .. , .. ,.,'.,"', .. , ................................................................................... fW.Q.%. TOTAL 100.0% CONTAINS 3.2 pounds active thiodicarb per U.S. galion KEEP OUT OF REACH OF CHILDREN WARNING AVISO Si ustcd no entlende la etil1tJcta, busquc a alguirm para que se la explique a listed en detalle. {If you do not understand the label, find someone to explain it to you in detaill. STATEMENT or PRACTICAL TREATMENT Thiodicarb is an NMmethyl ctlrbamatc. IF SWALLOWED: If patient is conscious and alert, give 2 to 3 glasses of water or milk to drink. If available. give one tablespoon 01 Syrup of Ireeae to induce vomiting. If vomiting does not occur within 20 minutes of the first dose, follow with a second F:lI1d last dose of 1 teaspoon. Altf!rnlltively, induce vomiting by touching back of throat with ringer. Do not make nn lInconscious person vomit. GET ME:DICAL ATTENTION. IF IN EYES: Hold eyelids ormn and flush with a steady, gentle stream of water for at least 15 minutes. GET MEDICAL ATTENTION. IF ON SKIN: Immediately flush skin with plenty of water. IF INHALED: Remove to fresh air. If not breathing, give artificial respiration. Administer oxygen if necossary. GET MEDICAL ATTENTION. GENERAL Contact a physician immedin!ely in all cases of suspected poisoning. If breathing stops, establish an airway, start artiricial respiration. and provide oxygen. Make certain to remove all sources of continuing contamina1ion'. Remove clothing and wash skin and hAir immediately with large amoun1s of water. Transport the patient to a physician or hospital immediately and SHOW A COPY OF THIS LABEL TO THE PHYSICIAN. If poisoning is suspected in animals. contact a veterinarIan. NOTE TO PHYSICIAN: All treatments should bo based on observed signs and symptoms of distress in the patient. Overexposure to materials other than this product may have occurred. : ••• :. • EPA REG NO. 9779- Manufactured For TERRA INTERNATIONAL. INC. P.O. Box 6000. Sioux City, Iowa 51102 Riverside Serves Agr;culture. Agriculture Serves Everyone. EPA E.i .. Q. • •• • • •••••• • • •••• o • •••• • • • • •• • ••• •• • ••• Net COMents • ..:... GAt!:;· ...... 9/G2117 · .. •• • ..... ••• • • • ..

• • Paga 2 of 10 This product contains an N-mctlwl carbamate insecticide. which is a cholinesterase inhibitor. Overexposure to this substance may cause toxic signs and symptoms due to stimulation 01 the cholingeric nervous system: These effects of overexposure are srontaneously and rapidly reversible. Gastric lavage may be used if this prouct has been swallowed. THIODICARB 3.2 poisoning may occur rapidly after ingestion a!)d prompt removal of stomach contents is Indicated. Specific treatment consists of pamnteral atropine suHate. Caution should be maintained to prevent over atropinization. Mild cases m<3V be given 1 to 2 mg intramuscularly every 10 minutes until full atropinization has been achieved and repeatm:l thereafter whenever symptoms reappear. Severe cases should be given 2 to 4 mg intravenously very 10 minutes until fully atropinized, then intramuscularly every 30 to 60 minutes as needed to maintain the effect (or at leDst 12 hours. Dosages for children should be appropriately reduced. Complete recovery from overexposure is to be expected within 24 hours. Narcotics and other sedativf!c; should not be used. Further, drugs like 2-PAM (pyridine-2·aldoxime methiodide) are NOT recommended unless organophosphate intoxication is also suggested. To aid in confirmation or a diagnosis, urine samples should be obtained within 24 hours of exposure and immediately frozen. PRECAUTIONARY STATEMENTS HAZARDS TO HUMANS (AND DOMESTIC ANIMALS) WARNING IIlnnss may result mpidly following overexposure to this product. May be fatal if swallowed. Harmful if inhaled or absorbed through the skin. May be irritating to eyes and may cause mild skin sensiti7ation. Do not take internally. Avoid contact with skin, eves or clothing. Avoid breathing spray mist. Keep away from domestic animals. Discontinue use if allergic rcllr:tion occurs. Do not eat or use tobacco while lIsing this product. SIGNS AND SYMPTOMS OF OVEREXPOSURE Salivation, Muscle tremors, Nausea, Watery eyes, Difficult breathing, Vomiting, Pinpoint eye pUI"ils, Excessive sweating, Diarrhe<'l, Blurred vision, Abdominal cramps, Weakness, Headache. IN SEVERE CASES, CONVULSIONS, UNCONSCIOUSNESS AND RESPIRATORY FAILURE MAY OCCUR. ANTIDOH: ATROPINE SUI.FATE IS HIGHLY EFFECTIVE AS AN ANTIDOTE. See NOTE TO PHYSICIAN. PERSONAL PROTECTIVE EQUIPMENT (PPE): Applicators and other handlers must wear long· sleeved shirt and long pants, waterproof gloves, shoes plus socks and chemical·resistant he<'ldgoar ror overhead exposure. Discard clothing and other absorbent materials that have been drenched or heavily contaminated with this product's concentrato. Do not reuse them. rollow manufacturer's instructions for cleaning/maintaining PPE. If no such instructions for wash ables, use detergent and hot water. Keep and wac;h PPE separately from other laundry . When handlers use closed sytcms, enclosed cabs, or aircrElrt in a manner that meets the requirements listed in the Worker Protection Standard (WPS) for agricultural pesticides [40 CFR 170.240{d)(4-611, the handler PPE requIrements may be reduced or modified as specified in the WPS. ., USER SAFETY RECOMMENDATIONS Users should wash hands before eating, drinking, chewing gum, using tobacco or using the toilet. Remove .lothiQQ immediately if pesticide gets inside. Then wash thoroughly and put on clean clothing. • ••••• ENVIRONMENTAL HAZARDS ••• 111 • • •••• This product is toxic to fish, birds, invertebrates and other wildlife. For terrestriElI uses, de: : ~;ply directly to water, or to areas where surrace water is present or to intertidal areas below the mean higtf water·mark .• 00J'l0% contamillflte water by cleaning of equipment or dispo!>al of wastes. Do not apply when wetlndition!f'''a,, drift from area treated. This product is toxic to hees exposed to direct treatment. Do not ap!1I1 when beet;eare actively visiting the treatment area. ...... • ••••• • • ••••• • • •• •• • •••• ••• • • • •• 2-j (0

• • P'age30fl0 GENERAL INFORMATION Thiodicarb 3.2 is an aqueous flowable formulmion that readily disperses in water for spraying by grouM or air equipment, Directions on this label are based on tests and field experience relatil)9 to effectiveness, impact on environment and residues remaining in food and feed. READ THE ENTIRE LABEL AND OBSERVE ALL LABEL DIRECTIONS AND PRECAUTIONS BEFORE USE. DIRECTIONS FOR USE It is a violation of Federal law to use this product In a manner inconsistent with its labeling. Read entire label before using this product. Do not apply this product in D way that will contact workers or other persons, either directly or through drift. Only protected handlers may be in the Drea during application. For <Jny requirements specinc to your State or Tribe, consult the agency responsiblfl for pesticide reglilations. Do not use this product except as directed on this label or on other Rhdne-Poulenc Ag Company supplemental labeling for this product. Applications at higher rates or c1t more frequent intervals than is stated on the label may result in iIIp.gal residues in crops, meat and milk. ....,... ..... AGRICULTURAL USE REQUIREMENTS Use this product only in accordance with its labeling and with the Worker Protection Standard. 40 CFR part 170. This standard contains requirements for the protection of agricultural workers on farms, forests, nurseries, and greenhouses. and hrtndlers of agricultural pesticides. It contains requirements for training, decontamination, notification. and emergency assistance. It also contains spocific instructions and exceptions pertaining to the statements on this label about pp.rsonal protectivo equipment (PPE) and restricted-entry intervals. The requirements in thIs box only apply to uses of this product that are covered by the Worker Protection Standard. Do not enter or allow worker entry into treated areas during the restricted entry interval (REI) of 12 hours. PPE required for early entry to treated areas that is permitted under the Worker Protection Standard and that involvos contact with anything that has been treated, such as plants, soil, or water, is coveralls, waterproof gloves, shoes plus socks and chemical-r~.istant h'r~$.J.ear f~r Q.erhead exp.osure. See Precautionary Statement, Stiltement of Practical Treatment, and Note to Physician for information on accidenttll exposures, STORAGE AND DISPOSAL STORAGE Do not store in or around the home. Store unused product in a cool, ventilated, dry, prolonged storage in areas where temperatures frequently exceed 115°F (46°C). PRODUCT TO ANOTHER CONTAINER FOR STORAGE . locked area. Do not allow NEVER TRANSFER THIS If container is damaged, before clean-up, put on long-sleeved shirt and long pants, waterproof gloves, shoes plus socks and chemicalresjstant headgear for overhead exposure. PESTICIDE DISPOSAL Do not conttlminate water, food or reed by stamge or disposal. Contamination with this product will render water. food or feed unfit for human or animal consumption. Wastes resulting from the use of this product may be disposed of on site or at an approved waste disposal facility. • • CONTAINER DISPOSAL : ••••• NEVER REUSE EMPTY CONTAINERS. Triple rinse or equivalent. Then offer for recycling or recondition~~ ~r puncture and dispose of in a sanitary landfill or by incineration, or if allowed by state and local authori"~s. ~~ burning. If container is burned, stay out of smoke. • ••••• • •• • • •••••• • • .. • • • • •• • ••• • ••• • • •••• • · .. •• • •••• ••• • • • ..

• • Page 4 of 10 GENERAL DIRECTIONS • SPRAY PREPARATION: TO ASSURE A UNIFORM PRODUCT, AGITATE OR SHAE ALL CONTAINERS OF THIS PRODUCT PRIOR TO USE. Remove oil. rust, scle. pesticide residues and other foreign matter from sprayer and strainer. Flush with clean water. Use 50 mesh screens or equivalent slotted strainers in spray system, To preparo for spraying. till tank to approximately 1/2 the needed volume of water. Add the required amount of this insecticide and mix thoroughly by mechanical or hydraulic agitation. Finish filling tank with water to desired volume and thoroughly mix. Do not store spray mixture for prolonged periods. If tank mixes are to be used. Thiodicarb 3.2 must be fully disJ1ersed in water first. followed by the addition of the intended tank·mix material. COMPATIBILITY: Thiodicarb Insecticide when diluted with an equal volume of water. is physically compatible with a wide range of commonly used spray products, but the full range of compatibilities under local conditions is not know, Therefore, It is essential that before using Thiodicarb 3.2 in any tank mixture the compatibility of the mixture be established. Add a small amount of this product to an equal volume of water in a small container and then add the other pesticide or spray product and mix thoroughly. DO NOT USE MIXTURES THAT CURDLE, PRECIPITATE, OR GREASE. THIS PRODUCT IS NOT COMPATIBLE WITH NON·EMULSIFIED VEGETABLE OR CROP OIL DILUENTS. FOR BEST RESULTS, SPRAY MIXTURES SHOULD BE USED IMMEDIATELY AFTER MIXING WITH ADEQUATE AGITATION. NOTE: Thiodicarb Insecticide is hydrolytically sensitive to degradation of active ingredient by strong acids, strong bases, and certain heavy mfltal oxidas and salts of certain fungicides. Degradation can cause reduced effectivenoss, plant phytotoxicity and increased handling hazards, DO NOT USE THIS PRODUCT IN SPRAY MIXTUReS WITH THE ABOVE TYPE OF PRODUCTS INCLUDING MIXTURES WITH Maneb, Manc02cb (except Manzate 200 and Dithan~ M-45 wettable powdnrs where mixtures arc used immediately after mixing), Copper COllnt N-B, and Bordeaux mixture. DO NOT ADD Thiodicarb 3.2 TO WATER WITH pH VALUES BELOW 3.0 OR ABOVE B.S. If necossary, water should be buffered within this range before adding Thiodicarb 3.2. DIRECTIONS FOR AERIAL OR GROUND SPRAY APPLICATION APPLICATION TIMING: Begin applictltion ,"'vhen insect populations rerlch recognized economic threshold levels. Consult tho Cooperative Extension Service. professional consultants or other qualified authorities to determine appropriate threshold levels for treatment in your area. APPLICATION INSTRUCTIONS: Apply a minimum finished spray volume of 2 gallons per acre by air or 5 gallons per acre by ground unless otherwise directed under crop srecific directions. Under extreme pest populations and dense foliage. use a minimum spray vohlme of 5 gallons per acre by air and a minimum spray volume of 10 galion!> per acre by ground. For best results, it i!> important to obtain thorough and uniform spray coverage of the plant, To maintain control repeat application as needed within dO!>lJge and time limits listed for each crop uner "'use Restrictions..... Use higher dosage rates for heavy infestation!>, large larvae. or dp.nse roliage. The specific length of residual control depends on cnvironmp.ntal factors, plant growth, dosage rate, and degree of i'1sect infestation, Although Thiodicarb 3.2 has some contact activity. larvae not feeding on treated foliage will not be controlled. When banding. determine the amount of chemical to use per acre by dividing the band width by the row width and multiplying by the appropriMc broadcast rate . To clean the sprayer after use, drain and flush with water. Use rinsings on crop according to label instructions or dispose of in an approved manner (See STORAGE AND DISPOSAL). DIRECTIONS FOR USE THROUGH SPRINKLER IRRIGATION SYSTEMS Apply this product only through center pivot and solid set sprinkler irrigation systems. through any other type of irrigation system. Do not apply this product • • • ••••• • SPRAY PREPARATION: Remove scale, pesticide residues, and other foreign matter from the chtlmical 'tj~"'lm~ entire injector system. Flush with dean water. • ••• •••••• • APPLICATION INSTRUCTIONS: First prepare a suspension of Thiodicarb 3.2 in a mix tank! FilTtk with.1/2 4' 3/4 the desired amount of water. Start mechanical or hydraulic agitation. Add thi.r'liIwi"ed arrftwt.rf THIODICARB 3.2. and then the remaining volume of water, {Suspension co~¥~rations •• uiirg • • ••••• • ••• • • ••••• • • •• •• • •••• ••• • •• •• if/IO

• • Page 5 of 10 the appropriate dosage per acre recommended on this label of THIODICARB 3.2 per 1 to 4 gallons of water are recommended). Then set sprinkler to deliver 0.1 to 0.3 inch of water per acre. Start sprinkler and uniformly inject the suspension of THIODICARB 3.2 into the irrigation water line so as to deliver the desired rate per aere. The suspension of THIODICARB 3.2 should be injected with a positive displacement PlIrt!P into the main line ahead of a right angle turn to insure adequate mixing. If you should have any other quostions aboLit calibration, you should contact State Extension Service specialists, equipment manufacturers or other experts. NOTE: When treatment with Thiodicarb 3.2 has been compfetod, further field irrigation over the troateri area should be avoided for 24 to 48 hours to prevent washing ttle chemical off the crop. GENERAL PRECAUTIONS FOR APPLICATIONS THROUGH SPRINKLER IRRIGATION SYSTEMS Maintain continuous agitation in mix tank during mixing and application to assure a uniform suspension. Greater accuracy in calibration and distribution will be achieved by injecting a larger volume of a more dilute solution per unit time. The system must contain a functional check valve, vacuum relier valve, and low pressure drain appropriately located on the irrigation pipeline to prevent water source contamination from backflow. The pesticide injoctlon pipeline must contain a functional, automatic, quick-closing check valve to prevent the flow or fluid back toward the injeotion pump. The pesticide injection pipeline must also contain a functional, normally closed solenoid-operated valve located on the intake side of the injection pump and connected to the system interlock to provent fluid from being withdra'Nn from the supply tank when the irrigation system is either automatically or manually shutdown. The system must contain functional interlocking controls to automatically shut off the pesticide injection pump when the water pump motor stOps. The irrigation line or water pump must include a functional pressure switch which will stop the water pump motor when the water pressure decreases to the point where pestlcido distribution Is adversely affected. Systems must use a metering pump, such as a positive displacement injection pump (fl.g .• diaphragm pump) effectively designed and constructerl of materials that are compatible with pesticides and capable of being fitted with a system interlock. Do not apply when wind speed favors drift beyond the area intenr!ed for treatment. Do not apply when wind speed favors drift. when system connection or fittings leak, whon nozzles do not provide unirorm distribution or when lines containing the product must be dismAntled and drained. Crop Injury, lack of effectiveness, or iIIogal pesticide residues in the crop may (esult from non-uniform distribution of treated water. Allow sufficient time for pesticide to be rlUShArl through all lines and All nozzles before turning off irrigation water. A person knowledgeable of the chemigation system and responsible for its operation shall shut the system down and make necessary adjustments should the need arise. Do not connect an irrigation syr.tem (including greenhouse systems) used for pesticide application to a public water system unless the label· prescribed safety devicos for puhlic water supplies are in place. RECOMMENDEO USES FOR BROCCOLI, CABBAGE AND CAULIFLOWER SPRAY VOLUME FOR BROCCOLI, CABBAGE AND CAULIFLOWER: Apply in a minimum finished spmy volume or 5 gallons per acre by air or 20 gallons per acre by ground. • •• • • •••••• • • • •••• Spray as needed. As insect populAtions increase and/or new plant growth is rapid, the spray'ntervarshoul<i.e. : shorter. Use higher dosage rates for heavier infestations or large larvae. Use lower rates for't.OCftt(moderaftl· •• infestations. •• • ••• NOTE: Regional dirrerences hAve been nmerlin the susceptibility of certAin strains of diamondtl •• If,moth to· ••••• thiodicarb. If local experience indicates inadequate control, use an altArnate pesticide. ..:.. • • USE RESTRICTIONS • •• •• • •••• Do not exceed 6.0 pounds of active ingredient f240 fluid ounces of Thiodicarb 3.2) per acre per season. D.nilt • .. , ..

• • Page 6 of 10 RECOMMENDED USES FOR COTTON INTEGRATED PEST MANAGEMENT IIPMI USE OF THIS PRODUCT: Thiodicarb 3.2 has both contact and residual ovicidal activity which can be crrcctively utilized in (PM programs (See ovicide section). Thiodicarb 3.2 !!sed as a ovicide or a larvicide has been shown to Icave substantial porulations of beneficial insects and spiders after use. The lower rates allow for maximum benaficial survival and faster rebound of beneficial pOr'lulations. Larvicidal and ovicidal control coupled with mtention of beneficial insects and spiders can offer significant benefits to those producers lItilizing integrated pest control programs. SPRAY VOLUME FOR COTTON: Thiodicarb 3.2 should be applied in a minimum finished spray volume of 2 gallons per acre by aircraft and 5 gallons per acre by ground equirment. Under extreme pest populations or dense foliago. use a minimum spray volume of 5 gallons per acre by air and a minimum spray volume of 1 ° gallons per acre by ground. I DOSAGE PER .ACRE PEST I Pounds Active I Fluid Ounces SITE: COTTON .. Ovicide: 0.125 to 0.25 5.0 to 10.0 Cotton Bollworm Tobacco bud worm SPECIFIC DIRECTIONS Apply on a 3 to 5 day schedule when moth flights begin or sufficient eggs are present. Thorough spray coverage is necessary as eogs must be contacted by Thiodicarb 3.2 for activity to occur. Eggs laid on untreated foliage or not contacted by Thiodicarb 3.2 sprays will not be controlled . If significant number of larvae survive, use higher recommended Thiodicarb 3.2 rates or 0.125 to 0.25 Ibs ai/A of Thiodicarb 3.2 in tank mixture combinations with organophosphates. pyrethroids or Bacillus thuringiensis such as DiPel'~ ES registered for use on cotton at their lilbel recommended rates. Observe all restrictions and precautions which appear on the labels of all products to be tank mixed with Thiodicarb 3.2. USE RESTRICTIONS Do not apply less than 28 days before harvest. Do not exceed 0.9 pound active ingredient per acre per .lrrlication or 5.4 pounds active ingredient per acre per season. Do not apply more than O.g pound active ingredient per acre of this product in any 7 day period. In Arizona and California, apply before bolls begin to open and do not exceed 1.8 pounds active ingredient per acre per season. . . . Larvicide: 0.6 to 0.9 24.0 to 36.0 Cotton bollworm Tobacco bud worm Armyworms (such as: Beet. rail, etc.) Cabbage looper Cotton leaf perforator Cotton leafworm Soybean looper r:leahopper {Suppressionl rink bollworm {Suppresslonl Plant bugs (Suppression) SPECIFIC DIRECTIONS In this rate range, Thiodicarb 3.2 is a direct contact and residual contact ovicide, as well as an effective larvicide. Although Thiodicarb 3.2 has some contact activity, larvae must feed on treated foliage to be controlled. Use the higher rato when insect larvae populations are heavier or 'Nllen infestations are predominantly large Imva9l(> 1r/4 inch in size}. As pest pressure increases, reduce intervals between applications andfor increase dosage: ra" -a\ indicated in specific directions below. • ••• A rate of 24 fluid ounces (0.60 Ibs. active) should be used when: For low to moderate insect populatlt>{I~.qrI!I when maximum survival of bendicial insects and spiders is desired. •••••• • Rates of 30 to 36 fluid ounces (0.75 to 0.90 Ibs. active) should be used when: Insect POfula.io.s arc heavy or infestation Is predominantly large larvae. Although Thiodicarb 3.2 has some contact activity, larva~ must.feeri oil treated foliage to be controlled. Applications for suppression of Pink bollworm should be tirrfetl:~r :he presMce·rJf adult moths. •• • ••• • 0 USE RESTRICTIONS ••••• • ••• 0 0 Do not apply less than 28 days before harvest. ••••• 0 Do not exceed O.g pound active ingredient per acre per arplication or 5.4 pounds active ingredient per ";!crGtlller season. Do not apply more than 0.9 pound active ingredient per acre of this product in any 7 day period. 0 • • • ••• In Arizona and California, apply before bolls begin to open and do not exceed 1.8 pounds active ingredientn. acr.p pc:r !'Ieason. 0 0 '/- /0

• • • Page 7 of 10 I DOSAGE PER ACRE • PEST I Pounds Active I Fluid Ounces SITE: COTTON Boll weevil I 0,6 to 0,9 I 24.0 to 36.0 (Suppression) SPECIFIC DIRECTIONS Light Boll Weevil Populations: When spraying Thiodicarb 3.2 on a 5 to 7 day worm control schedule. control of boll weevil will usually be adequate to maintain boll weevil populations below estahlished economic thresholds. Moderate to Heavy Boll Weevil Populations: When spraying Thiodicarb 3.2 on a worm contra! schedule, application of a registered boll weevil control product and/or tank mix of Thiodicarb 3.2 plus a registered boll weevil product should be used. A 3 to 5 day interval betwp.en sprays may be required to maintain boll weevil control under heavy infestations. USE RESTRICTIONS Do not apply less than 28 days berore harvest. Do not exceed 0.9 pound active ingredient per acre per application or 5.4 pounds active ingredient per acre per season. Do not apply more thDn 0.9 pound active ingredient per acrp. of this product in any 7 day period. In Arizona and California, apply before bolls begin to open and do not exceed 1.8 pounds active ingredient per acre pN season. Cutworms I 0,6 I 24,0 SPECIFIC DIRECTIONS See 'SPECIAL DIRECTIONS ON CUTWORMS" USE RESTRICTIONS Do not apply less than 28 days before harvest. Do not exceed 0.9 pound active ingredient per acre per application or 5.4 pounds active ingredient per acre per season. Do not apply more than 0.9 pound active ingredient per acre of this produGt in any 7 day period. In Arizona and California, arply before bolls begin to open and do not exceed 1.8 pounds active ingredient pcr (Icre per season. RECOMMENDED USES FOR LEAFY VEGETABLES SPRAY VOLUME FOR LEAFY VEGETABLES: Apply in a minimum finished spray volume of 5 9fllions per acre by air or 20 gallons per acre by ground. DOSAGE PER ACHE !.''?':lr-ds Fluid SITE PEST Active Ounces LEAFY VEGETABLES Alfalfa looper 0.4 to 0,75 16.0 to 30.0 Amaranth, arrugula, Armyworms (Such as cardoon, celery,chinese Beet, Fall, Southern) celery, celtuce, chervil, Heliothis zea corn SAlad, chrysanthe- (Bollworm, Corn mum fedible leaved, carworm, Tomato garland), cress (garden, fnJitworm) upland), dandelion. dock, endive. r-Iorence fennel, lettuce Cabbage looper 0,6 to 0.75 24,0 to 30,11 • fhead, leaO, orach, pars- •••••• • ley. purslane, (garden, •••• winter), radicchio, • • •••• rhubarb. spinach fleaf, •••••• • vine. New Zealand), Swiss • • • chard • • • • • • • SPECIFIC DIRECTIONS • • Spray as needed. •• • ••• • • Use the higher dosage rates for eavier infestations of larger IDrvae. Use the lower rates ror "':lt:elTloderatl!··· infestations. • •••• • • •• USE RESTRICTIONS • • • •••• Do not exceed 1.5 pounds of active ingredient (60 fluid ounces) per acre per season. • •• • Do not apply less than 14 days before harvest, • •

• • Page 8 of 10 RECOMMENDED USES FOR SOYBEANS ISTANDARD AND LOW SPRAY VOLUMES) • STANDARD SPRAY VOLUME FOR SOYBEANS: Apply in a minimum finished spray .volume of 2 gallons per acre by air or 5 gallons per acre by ground. Under extreme pest populations or dense foliage, use a minimum spray volume of 5 gallons per acre by air and a minimum or 10 gallons per acre by ground. LOW SPRAY VOLUME FOR SOYBEANS: Apply in a minimum finished spray volume of 1 gallon per acre by aircraft. Only use the low volume aerial application (i.e., minimum of 1 GPA) where that spray volume will provide adequate coverage of the crop. . - - . -.- DOSAGE PER ACRE Pounds Fluid PEST Active Ounces SITE: SOYBEAN (Standard Spry_Volume Applications) PCldworms 0.25 to 0.75 10.0 to 30.0 (Bollworm, Corn earworm Tobacco budworm Armyworms (Such as Beet, rail, Southern, Yellow-striped, etc.) Green clovorworm Vclvetbean caterpillar VI/oollyhflar caterpillar Soybean looper 0.45 to 0.75 18.0 to 30.0 CAbbage looper Mexican be-an beetle BQan leaf beetle Stinkbugs (Suppression) Ttuee-Cornored llifaifa hopper (Suppression) Cutworms See ·SPECIAL DIRECTIONS ON CUTWORMS· SPECIFIC DIRECTIONS Ue the lower rates for low to moderllte populations and maximum protection of benericials. USE RESTRICTIONS Do not feed forage, hay, or straw to livestock. Do not rtpply less than 28 days before harvest. Do not exceed 0.75 pound active ingredient per acre per application or 3.0 pounds active ingredient per acre per season. Do not rtpply more tha!1.0.75 poul)d .. actjY9 ingredient per aqre of his prodL!ct.in any 7 day period. SITE: SOYBEAN -. {Low Spray Vp.!ume Applications) Podworms 0.25 to 0.75 10.0 to 30.0 (Bollworm, Corn earworm, Tobacco budworml Green Clavcrworm Velvotbean caterpillar Armyworms {Such as Fall, Beet, Southern, etc.1 \Voollybear caterpillar SPECIFIC DIRECTIONS For best results. use the lower rates for low to moderate popUlations and maximum protection of beneficial911 • When applying at 1 gallon of spray volume per acre by air. use 1 quart of emulsified crop or vegetable OiT tf.. emulsified corn. soybean or cottonseed oill. Water alone may be used as a diluent for spray volumes of 2 gglJp,61s or higher per acre. • • •••• TANK MIX DIRECTIONS FOR EMULSIFIED CROP OR VEGETABLE OILS: Fill spray tank witl:lt pWb;imately 3/4 of the water required for the spray mixture. Add the required amount of Thiodicarb 3.2 to ttf'e spra" tank h.th. agitator running. Then add the desired amount of emulsiFied crop or vegetable oil. Continuo·.tft4ttftQn while d!tl the remainder or water. •• • ••• • • ••••• • ••• USE RESTRICTIONS • • ••••• • FOR USE ONLY IN: Maryland, Virginia, North Carolina, Delaware, South Crtrolina, Georgia. Alabama. Miissil:wi, Louisiana. Arkansas and Missouri. • • • .... -Do not feed forage, hay, or straw to livestock. Do not apply Ie 55 than 2B days before harvest. Do not exceed 0.75 pound active ingredient pr.r acre per application or 3.0 pounds active Ingredient per ce.p:- season. Do not apply marc than 0.75 pound qf t~is product in any 7 day period. ••

• , Page 9 or 10 RECOMMENDED USES FOR SWEET CORN SPRAY VOLUMES FOR SWEET CORN: Please observe the spray volumes recommended for whorl feers, silks and ears and foliage feders under specific directions. For aerifll applications, only ater may be used as a diluent and total spray volume mUEit bo at leat 2 gullons per acre DOSAGE PEFi ACRE Pounds Fluid PEST Active Ounces SITE: SWEET CORN (Florida, Fresh Market Only) Corn earworm 0.5 to 0.75 20 to 30 European corn borer Armyworms (Such as Fall, Bect, etc.) Western bean cutworm Cutworms See "SPECIAL DIRECTIONS ON CUTWORMS· SPECIFIC DIRECTIONS Whorl Feeders: Spray as needed. As insect populations increase andlor whon new plant growth is rapid, the spray interval should be shorter. For best rosults, usn spray volumes of 15 gallons or more per acre applied by ground eqlJinment using solid or hollow cone nozzles directed into the plant whorl. Insects Attacking Silks and E.ars: Apply at 1 to 7 day intervrd~ starting when silks first appear and continuing until harvest, if necessary. As insect populCltions increase and/or silk growth is rapid, the spray interval ::;hOLlId be shorter. Use the higher dosage rate and apply at 1 to 2 day interval~ following periods of heavy moth flights. Follow local recommr.ndations for proper timing. Foliage Feeders: Use at least 2 gallons finished spray volume per acre by air or 10 gallons per acre by ground. Spray as needed. USE RESTRICTIONS After silk initiation, rio not e'Xcced 7.5 pounds of active ingredient (300 fluid ouncr.s of this product) per acre per soason. Dn not AllOW livestock to graze treated field. Do not feed treatE!d corn silage (green plant) or fodder to livestoCk. Ears may be harvested on day of last flprlication. SPECIAL DIRECTIONS ON CUTWORMS SPRAY VOLUMES FOR CUTWORMS: Apply in n minimum finished spray volume of 3 gallons per acre by air or 15 gallons per acre by ground. DOSAGE PER ACRE PEST Pounds I Fluid Active Ounces SITE: COTTON. SOYBEANS. SWEET CORN (Flor;da. Fresh Market Only) Cutworms I 0.5 tu 0.75 I 20.0 to 30.0 SPECIFIC DIRECTIONS Postemergence Rescue Treatments: For best results, apply as a broadcast spray when cutworms are actively fp.eding. If cutworms are feeding below the around, control will be more difficult. Light cultivation with ~ r')tpr.' hoc before spraying may enhance control. If I,mndino, usc a minimum width of 10 inches over the row; When banding, determine the amount of chemical to use per acre, by dividing the band width by the row wij1'd, .Md multiplying by the aprropriate broadcast rate. . USE RESTRICTIONS Refer to each spf!cific crop for use restrictions. . -

• • Page 10 of 10 FIELD USE CONVERSION TABLE DOSAGE ACRES TREATED PER VOLUME OF Thiodicarb 3.2 PER ACRE ... .. . • . .. Pounds Fluid , Active Ounces 1 gallon ... 2.5 gallons 5 gallons 0.125 5.0 25.6 64.0 128.0 0.25 10.0 12.8 32.0 64.0 0.33 13.2 9.7 24.2 48.5 0.40 16.0 8.0 20.0 40.0 0.45 18.0 7.1 17.7 35.5 0.50 20.0 6.4 16.0 32.0 0.55 22.0 5.9 14.5 29.0 0.60 24.0 5.3 13.2 26.5 0.65 26.0 4.9 12.3 24.6 0.70 28.0 4.6 11.4 22.8 0.75 30.0 4.2 10.5 21.4 0.80 32.0 4.0 10.0 20.0 0.90 36.0 3.6 8.9 17.8 1 U.S. Gallon Equals 128 FlUId Ounces NOTICE: Seller wmrants that the product conforms to its chemical description and is reasonably fit for the purposes stated on the lubel when IIsed in occordance with directions under normal conditions of use, but neither this warranty nor any nther warranty of merchantability or fitness ror a particular purpose, express or implied, extends to the use of this product contrary to lubel instructions. or under abnormal conditions. or under conditions not reasonably foreseeable to Sellar, and l3uyer assumes the risk of any such use . •••••• • •• • • •••••• • • • 0 ••••• • • ••••• • 0 •••••• • •••• • • •••• • • 0 • •• • ••• •••• • • • ••• • • •• o. . •••• ••• • • • 00