crop-chem-docs/corpus/epa_ppls/9779-353.md

TERRONATE WDG

• EPA Reg No: 9779-353
• Registrant: WINFIELD SOLUTIONS, LLC
• Signal word: Caution
• Active ingredients: Fosetyl-Al (80%)
• Label accepted: 1998-06-05
• Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/009779-00353-19980605.pdf

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u.s. ENVIRONMENTAL PROTECTION AGENCY Office of pesticide programs Registration Division (7505C) 401 nM" St., S.W. Washington, D.C. 20460 NOTICE OF PESTICIDE: ~ Registration ___ Reregistration (under FIFRA, as amended) Name and Address of Registrant (include ZIP Code): Terra International, Inc. 600 Fourth Street P.O. Box 6000 ioux City, IA 51102 ATTN. : EPA Reg. Number: "'h,'J Date of Issuance:: ---.", -- ~~U JUN 5 1998 .. 9779-353 Term of Issuance: Conditional Name of Pesticide Product: Terronate WDG Steven E. Rogosheske .te; Cha.ng<;s in. label 'ng diffeiii:jig·#:!i#1l?ii#}$~ie:f£8ffi:\ili:':E acd,{ptecl.in conned£1:cnwith this"· ::~~~:!~ ~~~~~~e ub!t:~ tr1;~~~~~~~~~~~~;:;;~~j~~~~~~tyei;fft~~~»:o:e i .. ·· . . . "-' '. . .• """'''''' ," .:.:: ..... <.::.:.;,' ": .•. ,.:::,: .. ; "',,: .,:,: .• :,:.,.,::.:.-.:}::.;,:};.!.:.:::;., .. '-: .. '. , " : ',' :,:::.:::::.::;,:::::,;" ' ' . ' ,- ,.:, ;::: :,- On the basis of inforIT2tion furnished by the registrant, the above named pesticide is hereby registered/reregistered-under the Federal Insecticide, Fungicide and Rodenticide Act. Registration is in no y to be construed as an endorsement or recommendation of this product by the Agency. In order to protect health and tlie environment I the Administrator l on his motion I may at any time suspend or cancel the registration of a pesticide in accordance with the Ac. Tne acceptance of any name in connection with the registration of a product under this Act is not to- be construed as giving the registrant a right to exclusive use of the name or to its use if it has been covered by others. This product is conditionally registered in accordance with FIFRA sec. 3(c) (7) (A) provided that you: Submit and/or cite all data required for registration of your product under FIFRA sec. 3(c) (5) when the Agency requires all registrants of similar products to submit such data; and submit acceptable responses required for reregistration of your product under FIFRA section 4. 2. Modify the labeling as follows: a. Revise the EPA Registration Number to read, "EPA Reg. No. 9779- 353" b. On page 3 under #2 of the MIXING INSTRUCTIONS, change "Rhone­ Poulenc" to "Terra International". continued on page 2 Signature of Approving Official, Cynthia Giles-Parker Product Manager (22) Fungicide Branch Registration Division EPA Form 8570-6 ( 7505C) Date: JU: 5 \998

i t page 2 EPA Reg. No. 9779-535 3. c. On page 5 under the RESTRICTIONS AND LIMITATIONS for AVOCADO (BEARING), revise the first sentence to read: "Applications can be made on the same day of harvest (PHI = 12 hours}." d. On page 6 under CITRUS (BEARING), add "California only" under the disease "Ice-nucleating bacteria (Pseudomonas syringae, P. fluorescens, Erwinia herbicola) " for the Foliar application method at 5.0/Acre rate. e. On page 12 under STRAWBERRY for the disease "Leather Rot", change the second sentence under the APPLICATION PROGRAM to a "7 day time interval". Also, under RESTRICTIONS AND LIMITATIONS, revise the first sentence to read "Applications can be made on the same day as harvest (PHI = 12 hours)." I. On page 14 under the RESTRICTIONS AND LIMITATIONS for CUCURBIT CROP GROUPING, revise .the first sentence to read "Applications can be made on the same day as harvest (PHI = 12 hours) " go. On page 18 under PINEAPPLE, delete t.he line under the disease "Heart Rot (Phytophthora parasitical. Under APPLICATION PROGRAM, add "DIP:" before the first sentence and "FOLIAR:" before the second sentence to distinguish between these application types. Submit one copy of the revised final printed label for the record. If these conditions are not complied with, the registration will be subject to cancellation in accordance with FIFRA sec. 6(e). Your release for shipment of the product. constitutes acceptance of these conditions. A stamped copy of the label is enclosed for your records.

f ACTIVE INGREDIENT: TERRONATE WDG Fungicide Page 1 of 18 Aluminum tris (O·ethyl phosphonatel ................................................ . •...•. _.~ ••• , ___ .... _ ... ,;-.............. 80.0% INERT INGREDIENTS ........................................................... , ... , .... , • ." ... , .. ", .... ,." ........ ~ Total 100.0% KEEP OUT OF REACH OF CHILDREN CAUTION STATEMENT OF PRACTICAL TREATMENT IF IN EYES: Hold eyelids open and flush with a steady, gentle stream of water for 15 minutes. Get medical attention if irritation persists. IF ON SKIN: Wash with plenty of soap and water. Get medical attention if irritation persists. IF SWALLOWED: Call a physician or Poison Control Center. Drink one or two glasses of water and induce vomiting by touching back of throat with finger. Do not induce vomiting or give anything by mouth to an unconscious person. PRECAUTIONARY STATEMENTS CAUTION HAZARDS TO HUMANS AND DOMESTIC ANIMALS Harmful if swallowed or absorbed through the skin or inhaled. Caused moderate eye injury. Avoid contact with skin, eyes or clothing. Personal Protective Equipment (PPE) Applicators and other handlers must wear long-sleeved shirt and long pants, waterproof gloves, shoes plus socks. and protective eyewear. follow manufacturer's instructions for cleaning/maint(3ining Personal Protective Equipment {PPE}' If no such instructions for washables, use detergent and hot water. Keep and wash PPE separately from other laundry. When handlers use closed systems, enclosed cabs, or aircraft in a manner that meets the requirements listed in the Worker Protection Standard (WPS) for agricultural pesticides [40 CFR 170.240(d)(4-611, the handler PPE requirements may be reduced or modified as specified in the WPS. USER SAFETY RECOMMENDATIONS Users should wash hands before eating, drinking, chewing gum. using tobacco or using the toilet. Remove PPE clothing immediately if pesticide gets inside. Then wash thoroughly and 'put on clean clothing. EPA REG NO. 9779- EPA EST NO. Manufactured For TERRA INTERNATIONAL, INC. P.O. Box 6000, Sioux CitY, Iowa 51102 Riverside Serve§Agdculture. Agriculture Serves Everyone " < < , " , Net Contehts · GALS s'·G2E:j.;' · .. • • c (; t , .. c ~ c • • •• ...... '" . • •• • ( ....... , • • ••

( ( Page 2 of 18 ENVIRONMENTAL HAZARDS This product is toxic to aquatic and estuarine invenebrates. Drift and runoff may be hazardous to aquatic and estuarine organisms in neighboring areas. Do not apply directly to water, ':0 areas where surface water is present or to intertidal areas below the mean high water mark. Do not contaminzte water when disposing of equipment washwaters. DIRECTIONS FOR USE It is a violation of Federal law to use this product in a manner inconsistent with its labeling. Read entire label before using this product. Do not apply this product in a way that will contact workers or other persons, either directly or through drift. Only protected handlers may be in the area during application. for any requirements specific to your State or Tribe, consult the agency responsible for pesticide regulation. . AGRICULTURAL USE REOUIREMENTS Use this product only in accordance with its labeling and with the Worker ?rotection Standard, 40 CFR part 170. This Standard contains requirements for the protection of agricultural wo:--kers on farms. forests, nurseries, and greenhouses, and handlers of agricultural pesticides. It contains requirements for training, decontamination, notification, and emergency assistance. It also contains specific instruc:ions and exceptions pertaining to the statements on this label about Personal Protective Equipment (PPE) and res:ricted-entr{ interval. The requirements in this box only apply to uses of this product that are covered by the Works!" Protection Standard. Do not enter or allow worker entry into treated areas during the restncted-e,.try imerval of 12 hours. PPE required fo-r early entry to treated areas that is permitted under the: Worker Protection Standard and that involves contact with anything that has been treated. such as ptants, s:;:;:, or water, is: coveralls, waterproof gloves, shoes plus socks~ and protective eye wear. ' .. c STORAGE AND DISPOSAL Do not contaminate Water food or feed by storage or d,isposal. PESTICIDE Pesticide wastes are acutely hazardous. Improper disposal of excess p6Sticida, spray mixture, or rinsate is a viotation of Federal law. If these wastes cannot be disposed of by use acccrding to label instructions, contact your State Pesticide or Environmental Control Agency. or the Hazardous Was.e representative at the nearest EPA Regional Office for guidance. CONTAINER Completely empty bag into application equipment. Then dispose of emptY bag in a sanitary landfill or by incineration. or. if allowed by State and local 2U1horities, by burning. It bUfl");d, stay out of smoke. DIRECTIONS THROUGH SPRINKLER IRRIGATION SYSTEMS Use of TERRONATE WDG Fungicide through chemigation is not allowed in Cajifomia. except for Citrus. Apply this product only through sprinkler irrigation systems including mini-sprinkler, drip, solid set and center pivot. Do not apply this product through any other type of irrigation system. SPRAY PREPARATION: Remove scale~ pesticide residues. and other foreign matter from the chemical tank and entire injector systems. Flush with clean water APPLICATION INSTRUCTIONS: First prepare a suspension of IERRONATE WDG in a mix tan/<.. !=il1 tank with 112 to 3/4 the desired amount of water. Start mechanIcal or hydraulic agC'tatjon. Add the required amoln':t of TERRONATE WOG. and then the remaining votume of water. Then set sprinkler to deliver 0.1 to 0.3 inch 6ft('ra~t per acre. Start sprinkler and uniformly inject the suspension of T.ERRONA TE WOO into the irrigation water tio"t so as to d.eliver the desired rate per acre. The suspension of TERRONATE \VOG should be injected with a ppsitiye displacement pump into the main line ahead of a right angle turn to "insure aaeGuate mixing. 1f you should h.Jv(. an) other Questions about calibration. you should contact State Extension Service- specialists. equipment manufacturers or other experts. ' c , . , , . .. • • II; ,c ~ Co • • •• • • • • ••

( ( ( I Page 3 of 18 Note: For Mini-sprinkler and Drip Irrigation Systems: When treatment with TERRONATE WDG has been completed, further field irrigation over the treated area should be avoided for 24 to 48 hours. For Solid Set and Center Pivot Irrigation Sy.stems: When treatment with TERRONATE WDG has been completed, further field irrigation over the treated area should be avoided until foliage is dry to prevent washing the chemical off the crop. GENERAL PRECAUTIONS FOR APPLICATIONS THROUGH SPRINKLER IRRIGATION SYSTEMS Maintain continuous agitation in mix tank during mixing and application to assure a uniform suspension. The system must contain a functional check valve, vacuum relief valve. and low pressure drain appropriately located on the irrigation pipeline to prevent w<iter source contamination from backflow. The pesticide injection pipeline must contain a functional, automatic, quick-closing check valve to prevent the flow of fluid back toward the injection pump. The pesticide injection pipeline must also contain a functional. normally closed solenoid­ operated valve located on the intake side of the injection pump and connected to the system interlock to prevent fluid from being withdrawn from the supply tank when the irrigation system is either automatically or manually shut down. The system must contain functional interlocking controls to automatically shut off the pesticide injection pump when the water pump motor stops. The irrigation line or water pump must include a functional pressure switch which wi)1 stop the water pump motor when the water pressure decreases to the point where pesticide distribution is adversely affected. Systems must use a metering pump. such as a positive displacement injection pump (e.g., diaphragm pump) effectively designed and constructed of materials that are compatible with pesticides and capable of being fitted with a system interlock. Do not apply when wind speed favors drift, when system connection or fittings leak. when nozzles do not provide uniform distribution or when lines containing the product must be dismantled and drained. Crop injury, lack of effectiveness. or illegal pesticide residUes in the crop may result from nonuniform distribution of treated water. Allow sufficient time for pesticide to be flushed through aU lines and al[ nozzles before turning off irrigation water. A person knowledgeable of the chemigation system and responsible for its operation shall shut the system down and make necessary adjustmen'ts should the need arise. Do not connect an irrigation system (including greenhouse systems,) used for pesticide application to a public water system unless the label-prescribed safety devices for public water supplies are in place. GENERAL APPLICATION INSTRUCTION FOR FOLIAR APPLICATIONS TERRONATE WDG Fungicide is an effective systemic product for control of various diseases when used according to the label directions. MIXING INSTRUCTIONS 1. 2. 3. 4. 5. Fill the spray tank with 1/4 - 1/2 of the required volume of water prior to the addition of TERRONATE WOG. Add TERRONATE WDG slowly to the tank and agitate by hydraulic or mechanical means. NOTE: Rhone-Poulenc has determined that phytotoxicity from solubilized copper may occur if products containing copper are tank-mixed with TERRONATE WDG or if unbuffered TERRONATE WOG is applied to foHage with copper residues. • Do not tank-mix wn:h copper compounds. When applied prior to or after copper compounds, the pH of TERRONATE WDG should be raised to 6.0 or above with the addition of an alkaline buffer such as Potassium Carbonate (3 Ibs Potassium Carbonate to 5 Ibs TERRONATE WDG) or DiAmmonium Phosphate (5 Ibs DiAmmonium Phosphate to 5 Ibs TERRONATE WDG). Slowly add alkaline buffering agent {if needed}. CAUTION: When Potassium Carbonate is used as a buffer Carbon Dioxide (C0 2) gas is released during the buffering process. The spray tank must NOT be sealed until the C02 release associated with the reaction subsides (approximately 5' minutes). Continue to fill the tank with water to the desired volume while agitating. Continue agitation when applying. . " , , , GENERAL APPLICATION INSTRUCTIONS FOR TRUNK SPRAYS AND PAINTS.

1. Mix TERRONATE WDG with a small volume of water. The specific rates and gallonage to use are list~d ~r .c.:~r the citrus and stone fruit sections of the label.
2. Apply to wound area as a spray or paint on limbs or trunk of citrus or stone fruit trees in sufficient v6Il~("l'e 1.;' cover the entire area to be ·treated. • « • • .. " .. '"

( Page 4 of 18 COMPATIBILITY TER~ONATE WDG Fungicide is compatible with most products used in agriculture; however, crop sensitivity to these mixtures may vary. In particular, fotiar ferttlizers and copper products may not be compatible with TERRONATE WDG Fungicide and the combined use may cause phytotoxicitY to various crops. If these combinations or others have not been used before, do not tank mix without first testing the safety of the combination (compatibility and crop phytotoxicity). The use of spray adjuvants (I.e .• stickers, spreaders. wetting agents! is not recommended with TERRONAT£ WDG Fungicide. However, if an adjuvant is going to be mixed with TERRONATE WDG Fungicide, it should be tested prior to use for compatibility. Due to TERRONATE WDG fungicide's acidic nature. do not tank mix with acid type compatibility spray adjuvants (i.e., Buffit® Spray-aide, Triton AG-44M) or with adjuvants designed to enhance pesticide penetration (e.g., Hetbex'$ or Induce). Physical compatibility with TERRONATE WDG should be checked when mIxing with soluble concentrate or "flowable" formulation pesticides such as Bravo® 720 and Rovral19 4F. Add the correct proportions of each product and water into a clear container, thoroughly mix and then let stand for 3-5 minutes. If the mixture remains in suspension or can be remixed readily, the products are considered campatible. Buffering as described above may increase compatibility. To determine if a combination if phytotoxic to a specific crop, spray a few plantsltrees and then evaluate 3·7 days tater for visual effects. APPLICATION Apply TERRONATE WDG Fungicide with sufficient water volumes to obtain adequate coverage of foliage. The gallonage needed will vary by crop and growth stage. For vegetables and small fruit, do not apply TERRONATE WDG Fungicide by ground in less than 20 gals/A. Aerial applications fot all labeled crops should not be made in less than 10 gals/A. To insure good coverage of tree fruit, spray to wet. TERRONATE WDG FUNGICIDE IS REGISTERED FOR USE ON THE FOLLOWING CROPS TREE FRUITS AND NUTS Avocado {Non-Bearing and Bearingl Citrus {Non-Bearing and Bearing} Fame: Fruit (Non-Bearing and Bearing) Stone Fruit and Almond (Non-Searing) SMALL FRUITS Caneberry Crop Grouping Strawberry VEGETABLES Asparagus Brassica Crop Grouping Cucurbit Crop Grouping Leafy Vegetable Crop Grouping Onion (Dry Bulb) Tomato MISCELLANEOUS CROPS Ginseng Hops Pineapple < , , • " • < .. ,,~~ ••• • . • .. .,,, of"·" , , • < ~ . ~ ... • '" <

Page 5 of 18 AVOCADO INON-BEARINGI (Trees that wilt not product marketable fruit 101' 12 months after the last TERRONATE WDG application) When used in conjunction with good cultural management practices. TERRONATE WDG is effective in controlling avocado root rot caused by Phyrophrhora cinnamomi and avocado canker caused by P. citrico/a.

DISEASE APPLICATION RATE .. METHOD Ibs produ~t Phytophthora Canker Trunk Spray or Paint 2.5 - 5.015 gals (Phytophrhora citricola) APPLICATION PROGRAM Mix the desired amount of Terronate WDG with 5 gallons of water and apply to the trunk lesion in a sufficient volume to thoroughly wet the entire lesion. If no lesion is present. the application should be made from the soil line up the trunk approximately two feet. If trunk lesions are present. the higher rate should be used. Nursery tree resets and new plantings should be treated at the time of planting. - Phytophthora Drench Use at a concentration of Root Rot 5.0 oz/l 0 gals APPLICATION PROGRAM Apply 1 quart of .9Iution to the pot or sleev of each tree 2·3 days .prior to transplanting. (Phytophthora cinnamomi) I Fo!iar . I - .5.011 00 gals APPLICATION PROGRAM Begin application at transplanting or the start of the growing season and continue for up to 4 applications per year at 60 day intervals. Spray to run-off. • c RESTRICTIONS AND LIMITATIONS. For foliar applications do not exceed 1 00 GPA. Do not allow livestock to graze on the floor of treated grov;s. Do not cut cover crops for feed. AVOCADO (BEARING} When used in conjunction with good cultural management practices. TERRONATE WDG is effective in controlling avocado root rot caused by Phytophthora cinnamomi and avocado canker caused by P. citricoJa. Mix the desired amount of TERRONATE WDG with 5 gallons of water and apply to the trunk lesion in a sufficient volume to thoroughly wet the entire lesion. If no lesion is present. the application should be made from the soil line up the trunk approximately two feet. If trunk lesions are present. the higher rate should be used. Nursery tree 60 Apply as instructed above. This volumetric concentration is derived from a per acre foliar application rate at 5 lbs of TERRONATE WDG diluted Applications can be made on tHe same day of harvest (PHI = 0 day). " , , , , , , For foliar applications do not exceed 500 GPA. Do not apply more then 5.0 Ibs of TERRONATE WOG per acre per application. Do not exceed 20 Il::is product/acre per year. Do not allow livestock to graze on the floor of treated groves. " Do not cut cover crops for feed. , . , • • < c;c:.;( ... • 0 , .0 .'",. '.4'''.'' • • • • • 0; "c c c; e , • " , "- { l 0; , iC: { , "- ,

( l Page60f18 NOTE: In order to apply the correct amount of product to your groves you must know the number of gallons of water needed to spray one acre of trees to the point of drip. If you do not know this gallonage you should conduct a test to determine it. If you do not know how to conduct such a test with your equipment you should seek assistance from your equipment dealer of Cooperative Extension Service. CITRUS (BEARING) TERRONATE WDG applied in conjunction with good cultural practices will provide effective control of foot rot. root rot. gummosis, and fruit brown rot caused by Phytophthora spp. TERRONATE ·WDG also controls ice-nucleating Alternaria Brown I of TERRONATE WDG with 5 gallons of water and apply to the trunk lesion in a sufficient the entire lesion. If no lesion is present, the application should be made from the soil line 2 feet. If trunk lesions are the I rate should be used. favor dise.ase development. {If you are unsure about whether these Extension Service.} This volumetric concentration is derived from a per acre foliar application rate of 5 Ibs Begin application when conditions favor disease development. (If you are unsure about whether these conditions exist, check with your Cooperative Extension Service.) Inject TERRONATE WDG continuously during a scheduled (Alternaria spp.) (Suppression only) I TERRONATE WDG suppresses Alternaria spp. that cause Brown Spot. The first application should be applied int he spring at the first sign of new growth. A second and third application should follow at 30-45 day intervals. Apply This volumetric concentration is derived from a per acre foliar application rate of 5 lbs in 500 Foliar Ne,ve,';'I,.r (this allows sufficient time for the ice-nucleating bacteria to decompose before This volumetric concentration is derived from a per acre foliar application rate of 5 Ibs of water.

1 ( ( r: Page 7 of 18 RESTRICTIONS AND LIMITATIONS: Do not apply within 30 days of harvest (PHI = 30 days). Any combination of labeled application methods can be used. however, do not exceed a total of four applications or 20 Ibs/Acre per year. For foliar applications do not exceed 500 GPA. TERRONATE WDG may he "applied by ground, air, or chemigation. Do not graze livestock in treated groves. Do not feed forage from treated groves. Note: In order to apply the correct amount of product to your groves you must know the number of gallons of water needed to spray one acre of trees to the point of drip. If you do not know the gallonage you should conduct a test to determine it. If you do not know how to conduct such a test with your equipment you should seek assistance from your equipment dealer or Cooperative Extension Service. Note: Phytotoxic~ from solubilized copper may occur if products contaIning copper are tank~mixed with TERRONATE WDG or if unbuffered TERRONATE WOG is applied to foliage with copper residues. 00 not tank-mix with copper compounds. When applied prior to or after copper compounds, the pH of TERRONATE WOG should be raised to 6.0 or above with the addition of alkaline buffer such as Potassium Carbonate (3 lbs Potassium Carbonate to 51bs TERRONATE WOGI orOiAmmonium Phosphate (5 lbs DiAmmonium Phosphate to 5 lb. TERRONATE WDGI. Adjuvants which enhance pesticide penetration should not be used with TERRONATE WOG. Note: Controlling ice-nucleating bacteria may provide some protection against light frost. TERRONATE WDG is not recommended for this use in those areas where conditions favor severe frost. CITRUS (NON·BEARINGI (Trees that will not produce marketable fruit for 12 months after the last TERRONATE WDG application) TERRONATE WOG applied in conjunction with good cultural management practices wi!! provide effective conuol of foot rot, root rot and gummosis caused by Phytophthora spp. DISEASE APPLICATION RATE METHOD Ibs product Phytophthora Foot & Root Rot Root Dip 3.0/1 00 gals (Phytophthora spp.) APPLICATION PROGRAM Thoroughly mix TERRONATE WDG in the desired volume of water and dip the entire root system for 30-60 minutes prior to planting in the field. Phytophthora Foot & Root Rot Foliar 5.0/100 gals (Phytophthora spp.). APPLICATION PROGRAM Begin application when conditions favor disease development. (If you are unsure about whether these conditions exist, check with your Cooperative Extension Service.) Phytophthora Foot & Root Rot Chemigation 5.0/Acre (Phytophthora ~p.) APPLICATION PROGRAM For foliar applications spray to wet. For chemigation inject TERRONATE WOG continuously while applying a scheduled irrigation. Phytophthora Root Rot or Gummosis Trunk Spray or Paint 2.5 ·5.0/5 gals (Phytophthora spp.) APPLICATION PROGRAM Mix the desired amount of TERRONATE WDG with 5 gallons of water and apply to the trunk lesion in a sufficient volume to thoroughly wet the entire leSion. If no lesion is present. the application should be made from the soil line up the trunk approximately two feet. If trunk lesions are present, the higher rate should be used. Nursery tree resets and new plantings should be treated at the_ time of planting.

( ( Page 8 of 18 RESTRICTIONS AND LIMITATIONS: Any combination of labeled application methods can be used. however. do not exceed a total of four applications or 20 Ibs/Acre per year. TERRONATE WDG may be applied by ground, air, or chemigation. Do not exceed 100 GPA for foliar applications Do not graze livestock in treated groves. Do not feed forage from treated groves. NOTE: Phytotoxicity from solubilized copper may occur if products containing copper are tank·mixed with TERRONATE WDG or if unbuffered TERRONATE WDG is applied to foliage with copper residues. Do not tank·mix with copper compounds. When applied prior to or after copper compounds, the pH of TERRONATE WDG should be raised to 6.0 qr above with the addition of an alkaline buffer such as Potassium Carbonate {3 Ibs Potassium Carbonate to 5 Ibs TERRONATE WOGl or DiAmmonium Phosphate (5 Ibs DiAmmonium Phosphate to Sibs TERRONATE WDG). Adjuvants which enhance pesticide penetration should not be used with TERRONATE WDG. 'POME FRUIT CROP GROUPING (NON-BEARING) (Trees that will not produce marketable fruit for 12 months after the last TERRONATE WDG Application) TERRONATE WOG applied as part of complete disease control program will provide effective control of collar and root rot caused by Phytophthora s'pp. TERRONATE WDG used in a program with other registered bactericides and recommended sanitation measures aids in the control of Fire Blight caused by Erwinia amy/ovora. DISEASE APPLICATION RATE METHOD tbs product Fire Blight Foliar 2.5 - 5.0/100 gals (Erwin/a amy/avora) APPLICATION PROGRAM Begin applications in the spring when conditions are favorable for disease development. (Check with your Cooperative Extension Service if you are unsure about whether these conditions exist.) Adequate foliage should be available for absorption (e.g. tight cluster). Thorough coverage is required. Reapply at 4 - 7 day intervals as long as conditions favor disease development. {See application note below.} An additional application in the fall prior to leaf drop may be applied to reduce inoculum in newly forming bud tissue. .. Phytophthora Root Dip 3.0/100 gals Collar and Root Rot (Phyrophthora spp.J APPLICATION PROGRAM Mix TERRONATE WDG in the desired volume of water and dip the entire root system for 30-60 minutes prior to planting in the field. Phytophthora Foliar 2.5 - 5.0/100 gals Collar and Root Rot {Phytophthora spp.J APPLICATION PROGRAM Apply TERRONATE WDG on a 30 ., 60 day interval when conditions favor disease development. (Check with your Cooperative Extension Service if you are unsure about whether these conditions exist.) Thorough coverage is required. Under moderate disease pressure apply TERRONATE WDG, 3 or 4 times at 5.0 Ibs/100 gals on a 60 day spray interval or 6 - 8 applications at 2.5 Ibs/1 00 gals on a 30 day interval. Nursery tree resets and new plantings should be treated aftr laf efO~rgence'. • Pome FrUit Crop GrouplO9. Apple, Crabapple. Loquat. Mayhaw. Pear. Oriental Pear. QUince RESTRICTIONS AND LIMITATIONS: Application Note: Do not apply more than 5.0 Ibs of TERRONATE WDG per acre per application. Do not exceed 20 Ibs per acre per season. Applications for Fire Blight and Blister Spot control should occur early in the season. Applications for Phytophthora spp. control should be delayed until 30 days after last Fire Blight or Blister Spot application.

( ( _. Page 9 of 18 Do not graze livestock. on floor of treated orchards. The use of TERRONA TE WDG on Perne Fruit is restricted to protect endangered fresh water mollusks and their habitat. En the following states and counties. the use rate is limited to a maximum of 3.75 pounds product (3 Ibs ail per ac:'e per application: IL: Adams. Pike VA: Botetour .... Wise MN: Washington, Winona VT: Windsor OH: Washington, Wayne WI: Crawforc, Richland, Vernon TN: Cocke WV: Monroe NOTE: Phytotoxicity from solubilized copper may occur :7 products containing copper are tank-mixed with TERRONAT-E-WDG- or if unbuffered TE"RRONA TE WDG is applie-d to foliage with copper residues. Do not tank-mix with copper compounds. When applied prior to or after copper compounds, the pH of TERRONATE WDG should be raised to 6.0 or above with t..'le addition of an alkaline buffer such as Pota$sium Carbonate (3 Ibs Potassillm Carbonate to 5 Ibs TERRONATE \· ... OG) ·or DiAmmonium Phosphate (5 Ibs DiAmmonium Phosphate to Sibs TERRONATE WOG). Adjuvants which enhance pesticide penetration should not be !.!Sed with TERRONATE WOG. 'POME FRUIT CROP GROUP (BEARING) TERRONATE WOG applied as part of a complete disease contral program will provide effective control of collar and root rot caused by Phytophthora spp and Apple Blister Spot caused by Pseudomonas syn"ngae. TERRONATE WDG used in a program with other registered bactericides and recommended sanitation measures aids in the control of Fire Blight caused by Erwinia amy/ovora .. DISEASE APPLICATION RATE METHOD Ibs product Fire Blight Foliar 2.5 - 5.0/Acre (Erwinia WI!ylovora) . APPLICATION PROGRAM Begin applications in the spring when conditions are favoable for' disease development. {Check with your Cooperative Extension Service if you are unsure about whethe- these conditions exist.} Adequate foliage should be available for absorption (e.g. tight cluster). Thorough covera;= is required. Reapply at 4 - 7 day intervals only as long as conditions favor Fire Blight development. (See application note below.) An additional application in the fall prior to leaf drop may be applied to reduce inoculum in newly forming bud tissue. . Fire Blight - 0.5 ~ 1.0/100 gals Erwinja amvlovora APPLICATiON PROGRAM _.Apply as instructed above. This volumetric concentration is d-srived tram a per acre foliar application rate of 2.5 ~ 5 Ibs of TERRONATE WDG dilutli!'d in 50.0 gals of water. Apple Blister Spot Foliar 2.5 - 5.0/Acre (Pseudomonas syringael APPLICATION PROGRAM Begin applications when blossoms are at the pink stage. Mc.ke additional applications at 7 day intervals only as long as conditions favor Blister Spot development. {See application note below.} Apple Blister Spot - 0.5 ~ 1.0/100 gals (Pseudomonas syrlngae) APPLICATiON PROGRAM Apply as instructed above. This volumetric concentration is delved from a per acre foliar application rate of 2.5 - 5 Ibs of TERRONATE WDG diluted in 500 gals of water. Phytophthora Foliar 2.5 - 5.0/Acre Col/ar and Root Rot IPhytophthor. sop.1 APPLICATION PROGRAM Apply TERRaNA TI; WDG on a 30 - 60 day interval when condhions favor disease development. (Check with your Cooperative Exte.nsion Service if you are unsure about whether these conditions exist.} Thorough coverage is required. Under moderate disease pressure apply TERRONATE WOG, 3 Of 4 times at 5.0 Ibs/Acre on a 60 day spray interval or 6 - 8 applications at 2.5 Ibs/Acr on a. ~O day interv.a!. Phytophthora - 0.5 • 1.0/100 gals Collar and Root Rot (Phytophtl]ora pp. Apply as instructed above. This volumetric concentration is derived from a per acre foliar application rate of 2.5 - 5 lbs of TERRONATE WDG diluted in 500 9a!s Qi.water.

( ( ( ( Page 10 of 18 "Pome Fruit Crop Grouping: Apple, Crabapple, Loquat. Mayhaw, Pear. Oriental Pear. Quince RESTRICTIONS AND liMITATIONS: Do not apply within 14 days of harvest {PHI = 14 days]. Do not apply within 2-3 weeks of leaf senescence. Do not exceed 500 GPA. Application Note: Do not apply more than 5.0 Ibs of TERRONATE WDG per acre per application. Do not exceed 20 Ibs per acre per season. Applications for Fire Blight and Blister Spot control should occur early in the season. Applications for Phytophthora spp. control should be delayed until 30 days after last Fire Blight or Blister Spot application. 00 not graze livestock on floor of treated orchards. Note: In order to apply the correct amount of product to your groves you must know the number of gallons of water needed to spray One acre of trees to the point of drip. If you do not know this gallonage you should conduct a test to determine it. If you do not know how to conduct such a test with your equipment you should seek assistance from your equipment dealer or Cooperative Extension Service. The use of TERRONATE WDG on Pome Fruit is res.tricted to prote_ct endangered fresh water mollusks and their habitat. In the following states and counties, the use rate is limited ::0 a maximum of 3.75 pounds product (3 Ibs ail per acre per application: IL: Adams, Pike MN: Washington, Winona OH: Washington, Wayne TN: Cocke VA: Botetourt. Vlise VT: Windsor WI: Crawford. Rich.land, Vernon WV: Monroe NOTE: Phytotoxicity from solubilized copper may occur if produc;:s containing copper are tank-mixed with TERRONA TE WDG or if unbuffe~ed TERRONATI:WDG is applied 10 foliage with copper residues. Do not tank-mix with copper compounds. When applied prior to or after copper compounds, the pH of TERRONATE WDG should be raised to 6.0 or above with the addition of an alkaline buffer such as Potassium Carbonate (3 .lbs Potassium Carbonate to 5 Ibs TERRONATE WDGY or OiAmmonium Phosphate (5 lbs OiAmmonium Phosphate to 5 Ibs TERRa NATE WDG). Adjuvants which enhance pesticide penetration should not be used with TERRONATE WOG. 'STONE FRUIT CROP GROUPING (NON-BEARING) ALMONDS (NON-BEARING) (Trees that will not produce marketable fruit for 12 months after the last TERRONATE WDG application} TERRONATE WDG applied in conjunction with good cultural management practices will provide effective control of collar and root rot caused by Phytophthora spp. and Almond pruning-wound canker caused by Phytophthora sydngae. Apply as a paint or spray to the pruning wound area in a sufficient volume to thoroughly wet the entire wound surface. Under severe disease conditions (e.g. active canker lesion). the higher rate should be used. For small volume applications, mix 0.5 - 0.8 oz (3.0 - 4.5 level tablespoons) product per gallon of water. This is to 3 - 5 Ibs

Page 11 of 18 *Stone Fruit Crop Grouping: Apricot, Cherry (sour and sweet), Nectarine, Peach. Plum. Chickasaw Plum. Damson Plum, Japanese Plum. Plumcot. Prune (fresh) RESTRICTIONS AND LIMITATIONS, Do not apply more than 5.0 lbs of TERRONATE WDG per acre per application. Do not exceed 20 Ibs per acre per year. Do not exceed four applications per year. Do not exceed 1.00 GPA. NOTE: Phytotoxicity from solubilized copper may occur if products containing ·copper are tank-mixed with TERRONATE WDG or if unbuffered TERRONA TE WDG is applied to foliage with copper residues. Do not tank-mix with copper compounds. When applied prior to or after copper compounds, the pH of TERRONATE WDG should be raised to 6.0 or above with the addition of an alkaline buffer such as Potassium Carbonate (3 lbs Potassium Carbonate to 5 Ibs TERRONATE WDG) or DiAmmoniurn Phosphate (Sibs DiArnmonium Phosphate to 5 Ibs TERRONATE WDG). Adjuvants which enhance pesticide penetration should not be used with TERRONATE WDG. 'CANEBERRY CROP GROUP (Rubus spp.) When used in conjunction with good cultural management practices, TERRONATE WDG is effective in controlling Phytophthora root rot (Phytophthora spp.) of caneberries. DISEASE APPLICATION RATE METHOD Ibs product Phytophthora Root Rot Foliar S.O/Acre (Phytophthora spp.) APPLICATION PROGRAM In new plantings, TERRONATE WDG applications should begin when plants produce 1 - 3 inches of new growth. Applications in established plantings should begin when conditions favor disease development (e.g., high soil moisture and cool temperatures). Apply TERRONATE WDG in sufficient water to thoroughly wet the foliage. WEST OF THE ROCKY MOUNTAINS Fall Application: Apply when conditions favor disease development (Check with your Cooperative Extension Service if you are unsure about whether these conditions exist) and then repeat, if necessary, in 3 - 4 weeks. Spring Application: Apply the first spray after bud break (1 - 3 inches new growth) and a second spray 3 -4 weeks fater. EAST OF THE ROCKY MOUNTAINS Begin application in the spring after bud break (1 -3 inches new growth) and continue spraying on a 45 - 60 day schedule, up to_ a ma_xilJ1um of four sprays during the growing season.

• Caneberry Crop Group: Blackberry , Loganberry. Red and Black Raspberry, cultivars and/or hybrids of these RESTRICTIONS AND LIMITATIONS, Do not apply within 60 days of harvest (PHI = 60 days). Under severe disease pressure four applications per year should be used. (Check with your Cooperative Extension Service if you are unsure about whether these conditions exist.) The last fall application should be" applied at least 30 days prior to leaf drop. NOTE: Phytotoxicity from solubilized copper may occur if products containing copper are tank-mixed with TERRONATE WO"C3 or if unbuffered TERRONATE WDG i~ applied to foliage with copper fj3sidues. Do not tank-mix with copper compounds. When applied prior to or after copper compounds, the pH of TERRONATE WDG should be raised to 6.0 or above with the addition of an alkaline buffer such as Potassium Carbonate {3 Ibs Potassium Carbonate to 5 lbs TERRONATE WDGJ or OiAmmonium Phosphate (5 Ibs DiAmmonium Phosphate to Sibs ALIETTE WDG).

Page 12 of 1 S Adjuvants which enhance pesticide penetration should not be used with TERRONA rE WOG. Do not mix TERRONATE WOG with surfactants or foliar fertilizers. STRAWBERRY TERRONA TE WDG Fungicide is effective in controlling Red Stele caused by Phytophthora fragariae and Leather Rot caused by P. cactorum when used in conjunction with go~d cultural management practices. APPLICATION METHOO strawberry roots and crowns for 15-30 minutes. Plant within 24 hours after dipping. I Annual planting: Begin applications 14 - 21 days after planting and continue on a 30 - 60 day interval as long as conditions favor disease development. Perennial planting: -In the spring, begin applications when the plants start active growth. If disease conditions continue to persist or reoccur make additional applications on a 30 - 60 day interval. If using Red Stele susceptible strawberry varieties or if disease pressure is heavy, the shorter (30 day) time interval, high rates (4.0 to 5.0 IbsJAcre) and maximum number of applications should be used. {Check with your Begin applications between 10% bloom and early fruit set and continue on a 7 -14 day interval as long as conditions are favorable for disease development. When disease pressure is heavy the shorter (30 day) time interval, high rates (4.0 to 5.0 IbsJAcre) and maximum number of applications should be used. {Check with your Cooperative Extension Service if you are unsure about conditions RESTRICTIONS AND LIMITATIONS: Applications can be made on the same day as harvest {PHI = 0 days). Do not apply by fixed wing or rotary aircraft. Do not exceed 30 Ibs of product per acre per season. The use of TERRONATE WDG on Strawberries is restricted to protect endangered fresh water mollusks and their habitat. In the following states and counties, the use rate ;s limited to a maximum of 3.75 pounds product (3 Ibs ai) per acre per application. AR: White IL: Whiteside IA: Scott IN: Knox KY: Campbell, Marshall, Rockcastle, Todd, Warren LA: Livingston. Rapides MO: Caroline, St. Mary's MN: Houston, Washington MS: Monroe MO: Franklin, Jefferson NH: Cheshire, Sullivan NC: Granville, Johnston OH: Washington WI: Iowa. St. Croix, Trempealeau NOTE: Phytotoxicity from solubilized copper may occur if products contalnrng copper are tank-mixed with TERRONATE WDG or if unbuffered TERRONATE WDG is applied to foliage with copper residues. Do not tank-mix with copper compounds. When applied prior to or after copper compounds, the pH of TERRONATE WDG should be raised to 6.0 or above with the addition of an alkaline buffer such as Potassium Carbonate (3 Ibs Potassium Carbonate to 5 Ibs TERRONATE WDG) or DiAmmonium Phosphate (5 Ibs OiAmmonium Phosphate to 5 Ibs ALLIETTE WOG). Adjuvants which enhance pesticide penetration should not be used with TERRONATE WDG.

1 / I I Page 13 of 18 ASPARAGUS TERRONATE WOG will provide eifective conuol of Asparagus Spear Slime and Crown Rot caused by Phytophthora spp. , DISEASE APPLICATION RATE ~ METHOD Ibs product Asparagus Spear Foliar 5.0/Acre Slime and Crown Rot Phytophthora spp.) ".,. APPLICATION PROGRAM Apply TERRONATE WDG once per season. TERRONATE WOG should be applied to fully expanded asparagus ferns. Do not apply to fern~ that are beginning to senesee. ThorQugh coverage is required. RESTRICTIONS AND LIMITATIONS: FOR USE IN CALIFORNIA ONLY Do not apply within 110 days of harvest (PHI 110 daysi. Do not exceed 50 GPA. *BRASSICA CROP GROUPING When applied in conjunction with good cultural management practices TERRONA TE WDG will provide effective Downy Mildew caused by Peronospora parasi'o"ca. Apply TEARONATE WDG when conditions favor disease development (e.g., high mois'tUre and moderate temperatures) and continue on a 721 day interval. Use a sufficient volume of water fOf good coverage. The lower rates of TERRONATE WDG (2.0 - 3.0 Ibs/Acre) can be used when tank mixed with another fungicide (other than copper) which is labeled for downy mildew control. When used alone, apply TERRONATE WDG at 3.0- 5.01bs/Acre. With moderate to high disease pressure the higher rates of TERRONATE WDG and a shorter spray interval should be *Brassica Crop Grouping: Broccoli, Broccoli Raab (rapini), Brussels Sprouts, Cabbage, Chinese Broccoli (Gai Lon}, Chinese Cabbage (Sok Choy), Chinese Cabbage (Napa}, Chinese Mustard Cabbage (Gai Choy}, Cauliflower, Caval0 Broccolo, Collards, Kale, Kohlrabi, Mizuna, Mustard Greens, Mustard Spinach, Rape Greens RESTRICTIONS AND LIMITATIONS: Do not apply within three days of harvest (PHI = 3 days), Do not exceed seven applications per season. Do not apply in less than 10 GPA. NOTE: Phytotoxicity from solubilized copper may occur if products containing copper are tank-mixed with TERRONATE WDG or if unbuffered TERRONATE WDG is applied to foliage with copper residues. Do not tankmix with copper compounds. When applied prior to or after copper compounds, the pH of TERRONATE WDG should be raised to 6.0 or above with the addition of an alkaline buffer such as Potassium Carbonate {3 Ibs Potassium Carbonate to 5 Ibs TERRONATE WDGJ or DiAmmonium Phosphate {5 Ibs DiAmmonium Phosphat. to 5 Ibs ALiETTE WDGI. Adjuvants which enhance pesticide penetration should not be used with TERRONAiE WDG. Do not mix TERRONATE WDG with surfactants of foliar fertilizers. , " " ';

Page 140f 18 'CUCURBIT CROP GROUPING When applied in conjunction with good cultural management practices TERRONATE WDG will provide effective control of Downy Mildew Pseudoperonospora cubensis) and Phytophthora Root and Fruit Rot (P.hvtophthora spp.). DISEASE APPLICATION RATE METHOD Ibs product Downy Mildew FO.liar 2.0 -5.C/Acre (Psedoperonospora cubensisJ Phyophthora Root and Fruit Rot (Phytophthora spp.) APPLICATION PROGRAM Begin applications when conditions favor disease development (e.g .• high moisture and moderate temperatures). Continue on a 7-14 day interval. Use a sufficient volume of water for good coverage. The lower rates of TERRONATE WDG (2.0-3.0 IbsfAcre) can be used when tank-mixed with another fungicide (other than copper) fabeled for downy mildew control. When used alone. apply TERRONATE WDG at 3.0-5.0 Ibs/Acre. With moderate to heavy disease pressure the higher rates of TERRONATE WDG and a shorter spray interval should be used. (Check with your Cooperative Extension Service if you are unsure about whether these conditions exist.) ·Cucurbit Crop Grouping: Chinese Waxgourd. Citron Melon. Cucumber. Gherkin. Gourd (Edible). Momordica spp (Balsam Apple. Balsam Pear. Bitter Melon. Chinese Cucumber). Muskmelon. Pumpkin. Summer and Winter Squash. Watermelon RESTRICTIONS AND LIMITATIONS: Applications can be made on the same day as harvest (PHI = 0 day). Do not exceed seven applications per season. The use of TERRONATE WDG on Cucurbits is restricted to protect endangered fresh water mollusks and their habitat. In the following s:ates and counties. the use rate is limited to a maximum of 3.75 Ibs product {3 Ibs ail per acre per applica<:ion. AL: Hale, Jackson. Lauderdale. Marshrt Morgan, Washington AR: Cray. Craighead. LaYl. ... ence. Mississippi, St. Francis, Saline, Sharp, White, Woodruff Il: Gallatin. Mercer, Whi't:side IA: Allamakee, Louisa, M:..:scatine IN: Knox KY: Hart Logan, Marshall, Warren LA: Rapides, St. Helena MD: Caroline MN: Chisago. Washington MS: Monroe MO: Butler, Cedar, Dunklin. Franklin. Jefferson. Ripley. St. Louis NC: Franklin. Granville. Johnston. Nash. Pitt OH: Williams, Washington TN: Brount. Lincoln VA: Botetourt VT: Windsor NOTE: Phytotoxicity frol":1 solubilized copper may occur if products contammg copper are tank-mixed with TERRONATE WDG or_if urbu.ffered TERRONATE WDG is applied to foliage with copper residues. Do not tank-mix with copper compounds. When applied prior to or after copper compounds. the pH of TERRONATE' WOG should be raised to 6.0 or above' with the addition of an alkaline buffer such as Potassium Carbonate (3 lbs Potassium Carbonate to 5 fbs TERRONATE WDG) or DiAmmonium Pnosphate (5 Ibs DiAmmonium Phosphate to 5 Ibs ALLIETTE WDG). Adjuvants which enhance pesticide penetration should not be used with TERRONATE WDG. Do not mix TERRONATE \VDG with surfactants or foliar fertilizers. NOTE: Applications of TERRONATE WDG Fungicide for Downy Mildew or Phytophthora Root and Fruit Rot control will provide moderate suppression of whitefly (Bemisia spp.J populations. TERRONATE WDG Fungicide only suppresses whitefly populations. In most locations where whiteflies are a problem suitable insecticide applications wilt also be required to minimize damage. +LEAFY VEGETABLES (except Brassica vegetables) CROP GROUPING TERRONATE WDG applied in conjunction with good cultural management practices will provide effective control of Downy Mildew (Bremia lactucae. Peronospora spp.) on leafy vegetables (except brassica vegetables). TERRONATE WDG effectively controls White Rust (Albugo occidentalis) on spinach.

Page 15 of 18 DISEASE APPLICATION RATE METHOD Ibs product Downy Mildew Foliar 2.0 ~ 5.0/Acre (Bremia /actucae, Peronospora spp.) White Rust (Albugo occidents/is) (Spinach only) APPLICATION PROGRAM Apply TERRONATE WDG when conditions favor disease development (e.g.,. high moisture and moderate temperatures) and continue on a 7-21 day interval. Use a sufficient volume of water for good .coverage. The lower rates of TERRONATE WOG (2.0 - 3.0 Ibs/Acre) can be used when tank-mixed with another fungicide (other than copper) labeled for downy mildew control. When used alone, apply TERRONATE WDG at 3.0 - 5.0 Ibs/Acre. With moderate to heavy disease pressure the higher rates of TERRONATE WOG and a shorter spray interval should be used. (Check with your Cooperative Extension Service if you are unsure about whether these conditions exist. *Leafy Vegetable (except Brassica vegetables) Crop Grouping: Amaranth. Arugula (Raquette), Cardoon. Celery, Celery (Chinese), Celtuce. Chervil. Chrysanthemum (Edible Leaves. Garland}. Corn Salad. Cress (Garden. Upland). Dandelion .. Dock (Sorrel). Endive (Escarole}. Fennel (Florence}. Lettuce ((Head and Leaf). Orach. Parsley, Purslane [Garden. Winter). Radicchio (Red Chicory). Rhubarb. Spinach {New Zealand and Vine}. Swiss Chard RESTRICTIONS AND LIMITATIONS: 00 not apply within three days of harvest {PHI 3 days). Do not exceed seven applications per season. Do not apply in less than 10 GPA. NOTE: Phytotoxicity from solubilized copper may occur if products containing copper are tank-mixed with TERRONATE WOG or if unbuffered TERRONATE WOG is applied to foliage with copper residues. Speckling can also occur when TERRONATE WOG is applied to lettuce and spinach. To minimize the chances of speckling and phytotoxicity from solubilized copper do not tank-mix with copper compoands. For aU applications the pH of TERRONATE WDG should be raised to 6.0 or above with the addition of an alkaline buffer such as Potassium Carbonate (3 Ibs Potassium Carbonate to 5 Ibs TERRONATE WOG) or DiAmmonium Phosphate (5 Ibs DiAmmonium Phosphate to 5 Ibs TERRONATE WDG). Adjuvants which enhance pesticide penetration should not be used with TERRONATE WOG. Do not mix TERRONATE WDG witl": surfactants or foliar fertiliz.ers. ONIONS (DRY BULB) TERRONATE WOG will provide effective control of Downy Mildew (Peronospora destructor} and suppress Purple Blotch (Alternaria pom} on onion when applied in a preventive program in conjunction with good cultural management ·practices. DISEASE APPLICATION RATE METHOD Ibs product Downy Mildew Foliar 2.0 - 3.0/Acre (Peronospora destructor) Purple Blotch (A/ternar;'! porriJ APPLICATION PROGRAM For optimum results. TERRONATE WOG should be used in a preventive disease control program. Begin applications when conditions favor disease development (e.g., high humidity and cool evening temperatures) and continue on a 7 - 14 day interval as needed. If disease is already present. TERRONATE WDG should be applied at the 3.0 Ibs/Acre rate and at the 7 day time interval. {Check with your Cooperative Extension Service if you are unsure about whether these conditions exist.l

Page 16 of 18 RESTRICTIONS AND LIMITATIONS: Do not apply within seven days of harvest (PHI = 7 days). Do not exceed seven applications per crop season. Applications by air should be in a minimum of 10 GPA. Applications by ground should be in a minimum of 20 GPA. NOTE: Phytotoxicity from solubilized copper may occur if products contamlng copper are tank-mixed with TERRONATE WDG or if unbuffered TERRONATE WDG is applied to foliage with copper residues. Do not tank-mix with copper compounds. When applied prior to or after copper compounds. the pH of TERRONATE WDG should be raised to 6.0 or above with the addition of an alkaline buffer such as Potassium Carbonate (3 Ibs Potassium Carbonate to 5 lbs TERRONATE WDGJ or DiAmmonium Phosphate (SIbs DiAmmonium Phosphate to 5 lbs ALUETTE WDG). Physical compatibility with TERRONA TE WDG should be checked when mlxmg with soluble concentrate or "flowable'" formulation pesticides such as Bravo® 720 and Rovral® 4F. Add the correct proportions of each product and water into a clear container, thoroughly mix and then let stand for 3-5 minutes. If the mixture remains in suspension or can be remixed readily, the products are considered compatible. Buffering as described in the previous paragraph may increase compatibility. Do not tank mix TERRONATE WDG with acid type compatibility adjuvants or adjuvants which enhance pesticide penetration. Do not mix TERRONATE WDG with suriactants or foliar fertilizers. TOMATO TERRONATE WDG Fungicide will control damping off caused by Pythium spp. and root rots caused by Phytophthora spp. when used in conjunction with good cultural management practices. DISEASE APPLICATION RATE METHOD Ibs product Root Rot Foliar 2.5 - 5.D/Acre fPhytophthora spp.J Damping Off fPythium spp.} APPLICATION METHOD Apply at the 2 - 4 leaf stage of growth for direct seeded tomatoes or immediately after transplanting to the field. Continue applications on a 7·14 day interval if conditions are favorable for disease development. Apply in a sufficient volume of water to wet the entire plant canopy. With moderate disease pressure the higher rate (4.0 to 5.D Ibs/Acre) and shorter spray interval should be used. RESTRICTIONS AND LIMITATIONS: Do not apply within 14 days of harvest (PH! = 14 days). Do not exceed 20 Ibs product per acre per season. Do not apply in less than 10 GPA. The use of TERRONATE WOG on tomato is restricted to protect endangered fresh water mollusks and their habitat. The following is a list of the counties by state where the us~ of TERRONATE WDG on tomato is prohibited: AL: Jackson, St. Clair CA: Sonoma IA: Louisa, Muscatine, Scott IN: Knox KY: Campbell, Green. Kenton, Wayne LA: Rapides MD: Caroline, Queen Annes·s. St. Marys, Talbot MO: Butler, Jefferson St. Louis NC: Granville. Johnston OH: Williams TN: Cocke. Davidson, Grainger. Gundy, Ham,ilton. Knox. Meigs. Rhea, Sumner

Page 170f 13 NOTE: Phytotoxicity from solubilized copper may occur if products containing copper are !ank·mixed wi"[h TERRONA TE WDG or if unbuffered TERRONA TE WDG is applied to foliage with copper residues. Do not tank-mix with copper compounds. When applied prior to or after copper compounds, the pH cot TERRONATE WDG should be raised to 6.0 or above with the addition of an alkaline buffer such as PotassiUM Carbonate .(3 Ibs Potassium Carbonate to 5 Ibs TERRONATE WDG) or DiAmmonium Phosphate (5 Ibs DiAmmonium Phosphate to 5 Ibs ALLIETTE WDGI. Adjuvants which enhance pesticide penetration should not'be used with TERRONATE WDG. GINSENG TERRONATE_WDG will provide effective control of Phytophthora Foliar and Root Rot (Phytophthora cactorum) ar.d suppress Alternaria leaf Blight (Alternaria panax) when applied in conjunction with good cultural management practices. DISEASE APPLICTION RATE METHOD Ibs product Phytophthora Foliar and Root Rot Foliar 5.0/100 gals. fPhytophthora cactorum} Alternaria Leaf Blight (Alternaria panax) (Suppression only) APPLICATION PROGRAM Make the first application as conditions become favorable for disease development in the spring .. Contim.:: applications on a 7 day interval as long as conditions favor disease development. (Check with your Cooperatj·.~ Extension Service if you are unsure about whether these conditions exist.) RESTRICTIONS AND LIMITATIONS: Do not apply within 31 days of harvest (PHI = 31 days). Do not exceed nine applications per season. Do not apply in less than 100 GPA. NOTE: Phytotoxicity from solubilized copper may occur if products containing copper are tank-mixed w~n TERRONATE WDG or if unbuffered TERRONATE WDG is applied to foliage with copper residues. Do not tank·mix with copper compounds. When applied prior to or after copper compounds, the pH :f TERRONATE WDG should be raised to 6 .. 0 or above with the addition of an alkaline buffer such as PotassiL.:r! Carbonate (3 Ibs Potassium Carbonate to 5 Ibs TERRONATE WDG) or DiAmmonium Phosphate (5 Ibs DiAmmonlL.:n Phosphate to 5 Ibs ALLIETTE WDGI. Adjuvants which enhance pesticide penetration should not be used with TERRONATE WDG. Do not mix TERRONATE WDG with surfactants or foliar fertilizers. HOPS* When used in conjunction with good cultural management practices, TERRONATE WDG is effective in controlHng Hop Downy Mildew {Pseudoperonospora humul11. DISEASE APPLICA nON RATE METHOD Ibs product Hop/Downy Mildew Foliar 2.5/Acre (Pseudoperonospora humilO APPLICATION METHOD Apply TERRONATE WDG as a directed foliar spray using ground equipment only. When conditions are favorable ior disease development (warm and humid) applications should be made as follows: (1) when shoots are 6 -12 inches high; (2) after training when vines are 5 • 6 feet talt; (3) approximately three weeks after the second application; and (4) during bloom. Use sufficient volume of water to insure complete coverage of foliage.

) Page 18 of 18 RESTRICTIONS AND LIMITATIONS: Do not apply within 24 days of harvest (PHI = 24 days). Do not appry more than 10 Ibs/Acre per growing season Do not feed hop refuse to animals NOTE: Phytotoxicity from solubilized copper may occur if products contatmng copper are tank-mixed with TERRONATE WOG or if unbuffered TERRONATE WOG is applied to foliage with copp.erresidues. Do not tank-mix witn copper compounds. When applied prior to or after copper compounds, the pH of TERRONATE WOG should be raised to 6.0 or above with the addition of an alkaline buffer such as Potassium Carbonate (3 Ibs Potassium Carbonate to 5 lbs TERRONATE WDG) or DlAmmonium Phosphate (5 Ibs DiAmmonium Phosphate to 5 Ibs ALLIETTE WDG). Adjuvants which enhance pesticide penetration should not be used with TERRONATE WDG. Do not mix TERRONATE WDG with surfactants or foliar fertilizers.

• Not currently registered for use in California PINEAPPLE: When used in conjunction with good cultural management practices~ TERRONA TE WDG is effective in controlling Heart Rot {Phytophthora parasitical. DISEASE APPLICATION RATE METHOD Ibs product Heart Rot Dip 2.5/1 00 gals fPhytophthora parasitical Foliar 3.75/100 gals APPLICA nON PROGRAM Apply as a pre-plant dip immediately prior to planting. (100 gallons is intended to treat the number of slips required to plant one acre. Apply TERRONATE WDG to established plants when environmental conditions conducive to disease development (e.g., excessive rainfall) occur or are anticipated and continue applications at three month intervals. Apply in sufficient water for thorPugh coverage. RESTRICTIONS AND LIMITATIONS: Do not apply within three months of harvest (PHI 3 months). Do not exceed six foliar applications. For foliar applications do not exceed 400 GPA. NOTE: Phytotoxicity from solubilized copper may occur if products containing copper· are tank-mixed with TERRONATE WDG or if unbuffered TERRONATE WOG is applied to foliage with copper residues. Do not tank-mix with copper compounds. When applied prior to or after copper compounds, the pH of TERRONATE WOG should be raised to 6.0 or above with the addition of an alkaline buffer such as Potassium Carbonate (3 Ibs Potassium Carbonate to 5 Ibs TERRONATE WDG) or DiAmmonium Phosphate (5 Ibs DiAmmonium Phosphate to 5 Ibs ALiETTE WDG). Adjuvants which enhance pesticide penetration should not be used with TERRONATE WDG. Do not mix TERRONATE WDG with surfactants or foliar fertilizers. Bravo® Registered Trademark of 15K Biosciences Rovral® Registered Trademark of Rhome Poulenc NOTICE: Seller warrants that the product c_onforms to its chemical description and is reasonably fit for the purposes stated on the label when used in accordance with .directions under normal _conditions oJ use, but neither this warranty nor any other warranty of merchantability or fitness for a: particular purpose, express or· implied, extends to the use of this product contrary to label instructions, or under abnormal conditions, or under conditions not reasonably foreseeable to 5eller~ and Buyer assumes the risk of any such use.