crop-chem-docs/corpus/epa_ppls/10182-239.md

DYFONATE 4-ED

• EPA Reg No: 10182-239
• Registrant: SYNGENTA CROP PROTECTION
• Signal word: Danger
• Active ingredients: Fonofos (45.1%)
• Label accepted: 1990-02-13
• Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/010182-00239-19900213.pdf

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4 i u (r I· Page 1 of 18 Dyfonate 4ED 15.-011990 RESTRICTED USE PESTICIDE Due to ACUTE DERMAL TOXICITY For retail sale to use application only by Certifi Applicators or personnel under their direct supervisi for those uses covered by the Certified Applicator's Cert ACTIVE INGREDIENTS: D Y F 0 NAT E 4-ED Eaulsifiable Liquid Insecticide (Contains 4 pounds DYFONATE per gallon) O-Ethyl S-phenyl ethylphosphonodithioate* • • INERT INGREDIENTS: •••••••••••• . . . . . *DYFONATE and ication.. 13 :.: ,. r1:U j.J:.,.>_ 45.11 54.9% 100.0% tlds product coatsiDa tbs toz1c iDa" iDgredleDt 2-llathOXJ ... thanql DAN G E R - POISON (SKULL 6 CROSSBONES) KEEP OUT OF REAQI OF CHILDREN PELIGRO-PRECAUCION AL USUARIO: SI USTED NO LEE INGLES, NO USE ESTE PRODUCTO BASTA QUE LA ETIQUETA LE BAYA SIOO EXPLICADA AHPLlAHENTE. DANGER-READ ALL LABEL DIRECTIONS BEFORE USING STATEMENT OF PRACTICAL TREA'l'KENT FOR PESTICIDE EMERGENCY CALL A PHYSICIAN lKHEDIATELY: If a known exposure occurs, or if pOisoning is suspected, do not wait for symptoms t, develop. Immediately initiate the recommended procedures below. Slmultane-ously contact a physiCian, or the nearest hospital, or the nearest Poison Control Center. Inform the person contacted of the type and extent of expoaure, describe the victim's symptoms, and follow the advice given. FOR 24-HOUR EMERGENCY MEDICAL ASSISTANCE, CALL 1-800-F-A-S-T-M-E-D (327-8633). FOR CHEMICAL EMERGENCY: Spill, leak, fire, exposure, or accident call CHEHTREC 1-800-424-9300. For other product information, contact your local ICI Americas Distributor or see Material Safety Data Shep.t. Note: Be sure to advise the physiCian that the compound is a cholinesterase inhibitor, and fJllow the physician's advice. POISON SYMPTOMS -- DYFONATE 4-ED is a highly toxic cholinesterase inhibito~ • • ,. .... "I Symptoms include headache, blurred vision, weakness, nausea, discomfort-in the chest abdominal craaps, vomiting, diarrhea, salivation, sweating and pinpOint pupils. This product is sold only for usea stated on its label. No express or }ied license is granted to use or sell this product under any patent in any cotry except as specified: Country: United States of ABerica. EPA Reg. No. 10182-239 EPA E.t. No. 10182- Gal. Net L. Made in U.S.A. by ICI Alricultural Product. ICI "'rlc •• Inc. VU.,,.,tI,,, n .,"' 'lEST .fAUiU -1 f

Page 2 of 18 Dyfonate 4ED RS-011990 ALWAYS CALL A PHYSICIAN IN CASE OF SUSPECTED POISONING ATROPINE BY INJECTION IS ANTIDOTAL FIRST AID -- If patient has stopped breathing, t..edistely reaove from contaainated area, then start artificial respira-tion, preferably by aechanical aeans. If swallowed !.mediately dilute the swallowed material by giving large quantities of water and induce vomiting by gagging the victim with £ finger or blunt object placed on the back of the victim's tongue. Give flUids until vaaitus is clear. Never give anything by mouth to an unconscious person. Call a physician or the nearest poison control center. If inhaled, remove to fresh air. Get medical 9ttention if spira!ory irritation occurs. For eye contact, flush with large amounts of running water for at least 15 ainutes. Hold eye-lids apart to insure rinsing of the entire surface of the eyes. Get medical attention. For skin contact, remove contaminated clothing and tm.ediately wash skin thoroughly for 15 minutes with soap and water. Avoid abrading the skin. INFORtTION FOR PHYSICIAN -- Initial measures include removal of secretions, aaintensnce of a patent airway and, if necessary, artificial respiration. When cyanosis is relieved, atropine aay be administered in large the-apeutic doses. repeated as necessary to the point of tolerance. If sympto~ ~arrant further treatment, protopam chloride (pral1dox1me chloride, 2-PAM ci.!oride) has shown utility as adjunctive therapy. Hever use morphine. Continued absorption of the poison may occur. re-sulting in a fatal relapse after initial iaprovement; very close supervision of the patient is indicated for at least 48 to 72 hours. IN CASE OF SPILL ISOLATE the spill. Bold this package. ~ther cargo and vehiclea involved. IMMEDIATELY TELEPHONE (24-hour service) for emergency aSSistance: 800-424-9300. PRECAUTIONARY STATEMENTS Hazards to Humans and Domestic Animals X POISON DANGER X DANGER: POISONOUS IF SWALLOWED, INHALED OR ABSORBED THROUGH THE SKIN. RAPIDLY ABSORBED THROUGH THE SKIN. DO NOT GET IN THE EYES. ON SKIN, OR ON CLOTHING. DO NOT BREATHE SPRAY KIST. • •••••• •• •• • Use a respirator approved by the National Institute for Occupational Salety'and' , Health (30 cra Part 11 - Subpart H) for protection against pesticide inhal.tion ••• :::: Wear rubber gloves, shoes, protective clothing and goggles when applying. • • • •• handl1nfbr:' • ••••• • • • •• o. 0 .... • •••• • • ••••• • •••••• • • •• •••••• • • •• ••

• Pale 3 of 18 Dyfonate 4ED 15-011990 Wash hands, srms, aDd fsce thoroughly with soap and water aft.r handlina and bafore eatinl or s.okinl. Routinely shower or bathe after work and wash all clothiDi with soap and hot water before re-usinl. In cas. of contact. t..ediately remove contaminated clothing and wash thoroughly with soap and water. Do not transport or store DYFONATE 4-ED with any food or feed intented for human or ani.,.l consumption. Not for use or storage in or around the home. Do not use. pour. spill or store near heat or open flame. Do not apply or allow to drift to areas occupied by unprotected huaans or beneficial animals or onto adjoining food. fiber or pasture crops. Do not contaminate food or feed. Environmental Hazards This pesticide is toxic to fish and wildlife. Birds feeding in treated areas .ay be killed. Remove or cover if spills occur. Runoff from treated areas may be hazardous to fish in neighboring areas. Do not apply directly to water or wetlands. Do not contaminate water by cleaning of equip.ent or disposal of vaste. For guidance contact your regional office of the i.PA. Apply this product only as specified on the label. Physical and Chemical Hazards Do not use or store near heat or open flame. General Precautions Read all directions before uBing. Do not apply to any crop. or in any manner not Bpecified on this label. Do not rotate with carrots. Black Cutworw. Cabbage Kaggot Corn Leaf Aphid Garden Symphylan Onion Maggot Greenbug Seed Corn Maggot (SuppreBsion only) INSECTS CONTROLLED (Agrotis ipsilon) (8ylamya braBBicae) (Rhopalosiphum maidiB) (Scutigerella t.maculata) (8yle!ya antiqua) (Schizaphis graminum) (8ylama platura) • • ..... . -• , • • · .' •• •• • • •••••• • • • •• •• • •••• •••• • • •••• , , •••••• • •• • • •••••• • • " ••••• • • ••••• , •••••• · , .. •••••• • • •• ••

FLEA BEETLES: Elongate Flea Beetle Pal.striped Flea Beetle Sweetpotato Flea Be.tle Thre.spotted Flea Beetle IOO'l'WORHS : Northern Corn Rootworm Southern Corn Rootworm Western Corn Rootwora WIREWORKS: Corn Wireworm PacUic Coast Wireworm Southern Potato Wireworm Sugarbeet Wirewora Tobacco Wireworm Western Field Wireworm Wheat Wireworm Ctenicera lobata Dalopius pallidu6 Page 4 of 18 Dyfonate 4ED RS-01l990 (Syste .. a elongate) (Syst.na blanda) (Chaetocnema confinil) (Disonycha triangularia) (Diabrot1ca 10ngicornil) (Diabrotica undeci!punctata howard i) (Diabrotica virgifera) (Melanotus communis) (Limonius canus) (Conoderus falli) (Liaonius californicus) (Conoderus vespertinus) (Liaonius infuscatus) (Agriotes aancus) DIRECTIONS FOR USE It is a violation of federal law to use this product in a manner inconsistent with ita labeling. Do not apply this product through any type of irrigation system. REENTRY STATEMENT • Do dot enter treated areas for 24 hours after application nless appropriate protective clothing 1s worn. • Foliar.t. l1caUona ov.r the t for Sor bua: Do DOt allow worker r_tq iato tr .. ted 1. cia v1t1a1a 8 boura of application UDlala appropriata protecti.e clotb1D& 18 worn. Protacti ... clotb1D& ana, at .l_t. a bat or otber suitable ba...s coveria,. I1Ofta. a 10Dl-al .. ftd abirt aDd loq-lqaed trouaara or coverall type aar-at (all cloaely vov fabdc COftrtq the lIody. iDclacl1D1 the ar.a .... la .. > •• boac. and eDC:b.' ............ . • Because certain states asy require more restrictive reentry various crops treated with this product, consult your State Aariculture for further information. intervl:B" f!)r Departael1t"bf

.. • Do not apply this product in such expoae workers or other persons. by unprotected persons. Page 5 of 18 Dyfonate 4ED -O1l990 a manner as to directly or through drift The area being treated must be vacated • Do not apply or allow to drift to areas occupied by beneficial animals or onto adjoining food, fiber or pa.ture crops. Do not contaainate food or feed. • Written or oral warnings must be given to workers who are expected to be in a treated area or in au area abut to be treated with this product. Oral warnings must be given if there is reason to believe that written warnings cannot be understood by workers. When oral warnings are given, warnings shall be given in a language customarily understood by workers and .ust indicate the specific period of time that treated areas may not be entered without protective clothing. Oral warnings aust also include appropriate first aid instructions in case of accidental exposure. These instructions are given in the STATEMENT or PRACTICAL TREATMENT at the beginning of this label. Written warnings must include the following information, "WARNING. Area treated with DYFONATE Agricultural Insecticide on (date of application). Do not enter treated areas for 24 hours (48boora fo:tfoliu appl1ca~ 111 aorab_) after application unless appropriate protective clothing is worn (or other reentry intervsl if your state has a more restrictive interval for this product). If accidental exposure occurs. follow the instructions below." (Written warnings must include the STATEMENT OF PRACTICAL TREATMENT given at the beginning of this label.) Application should be aade only with tractor mounted spray equipment or larger. custom applicator type vehicles. Application should be made by trained personnel only, using approved proter.tive equipment. Pour the recommended a.ount of DYFONATE 4-ED into nearly filled spray tank. Add balance of water to fill tank. Keep agitator running during filling and spraying operations. Apply in 20 to 50 gallons of water per broF.dcast acre USing a properly calibrated, low-pressure sprayer having good sgitation. DYFONATE 4-ED may be comM.ned with solution. slurry, and suspension fertilizers. In addition, certain herbicides may be combined with DYFONATE 4-ED, both with and without fertilizer. Read the recommendations for epecific uses. Before combining in the spray tank, )hysical compatibility with these fluid fertilizers must be deterained. See Appendix 1 for special directions regarding these combinations. Even though found to be compatible, agitation aust be maintained during filling and application operations to insure ~~ distribution of material. • • Preplant broadcast applications should be mixed (incorporated) into the'if: to a depth of 2 to 3 inches. • • •••••• • • • •• •• • •••• •••• -::-:;;-;-iftiV1' • ~ ... lEst "'IUIU COPY •••••• • •• • • •••••• • • •• ••••• • • • •••• • •••••• • • ., •••••• • • •• ••

------------------------------------------------- - Page 6 of 18 Dyfonate 4ED RS:-011990 RECOMMENDATIONS BEANS (GREEN AND DRY): For control of garden aymphylan. and wlreworaa. apply 2 quart. (for a,.phylaoe) or 1 sallon (for yaphylan. and wlreworaa) DYFONATE 4-ED per acre, broadcast prlor to plantins and incorporate into the soil using suitable tllla equip.ent. (For garden syaphylans only, reduce the rate proportionately for band treatments.) ror control of seed corn "Sgot: Northwestern U.S. Apply 2 quarts to 1 gallon DYPONATE 4-ED per acre, broadcast on soil surface. prior co planting and incorporate to a depth of 2 to 4 inches using suitable tillage equipment. Use higher rate where population pressure is severe. Northeastern U.S. Apply 1 gallon DyrONATE 4-ED per acre, broad-cast on soil surface. prior to planting and incororate to a depth of 2 to 4 inches using suitable tillase equipment. All treat.ents may be applied as a tank mix with EPTAK 7-E Selective Herbicide in fluid fertilizer and/or watec. Follow the appropriate regional recaa.endations in the crop section of the EPTAM 7-E label for broadcast, preplant incorporated applications. Use only fluid fertilizers compatible with EPTAM 1-E and DYFONATE 4-ED (see Appendix 1). Observe all use precautions and l1aitatioDB on the EPTAM 7-E label. BEANS, (LIKA): For control of garden syaphylans and wireworms, apply 2 quarts (for symphylans) or 1 gallon (for symphylans and wireworms) DYPONATE 4-ED per acre, broadcast, prior to planting and incorporate into the soil using suitable tillage equipment. The higher rate is recommended on lima beans grown in California only. (For garden symphylans only, reduce the rate proportionately for band treatments.) COLE CROPS (BROCCOLI. BRUSSELS SPROUTS, CABBAGE, CAULIFLOWER): Garden Sy!phylans: Prior to or at ti.e of seeding or transplanting apply 2 quarts DYFONATE 4-ED per acre, broadcast, and incorporate into the soi: using suitable tillage equipment. (Reduce the rate proportionately for band treataents. ) Cabbage Kaggot: - (Northeastern U.S. only) - For transplant cole crops use 1 to 2 quarts DYFONATE 4-ED in 200 to 400 gallons of water per acre. Apply with a aprayer equipped with drop nozzles to direct a drenching spray to the base of the plants. Apply immediately after transplanting. ..;(>.:.F..::I:::ELD:=..!,--=;SW;:.:E:::E:..:.T....:AND=:....:..;PO::.:P:..;:C:.::O=RN) : NOTE: Kay be used in corn grown for grain or sUage. A. Band application for control of northern, southern and western rootworms • • ••••••• • • • • • •• •• •• corp • •••••• • • Apply, at planting, 3/4 to 1 quart DYFONATE 4-ED per acre in a 6 t~ ~~ch band over corn rows 38 to 40 inches apart. • ••• •••• • • •••• I BEST AY~ILABLE COttJ • ••••• • •• • • •••••• • • •• ••••• • • ••••• • •••••• • • •• •••••• • • •• ••

• Page 7 of 18 Dyfonate 4ED RS-01l990 Incorporate into the top 1/2 to 1 inch of soil by .aking application ahead of tbe press wbeels or by use of special covering devices or by dragging a short lengtb of chain bebind tbe press wbeels. Do not place DYFONATE 4-ED in direct contct with seed. B. Broadcast application for control of sympbylans, nortbern, soutbern and western corn rootworms. and wirewr.as. and for suppression of black cutworm Apply 2 quarts (for symphylans). 3 quarts (for symphylans and earn rootworms). or 4 quarts (for sympbylsns. corn rootworms, wireworms and black cutworm) DYFONATE 4-ED per'acre prior to planting and incorporate into the soil using suitable tillage equipment. Tbi~ treatment may be applied as a tank mix witb ERADICANE® 6.7-E or SUTAN®+ 6.7-E, selective herbicides or tbeir recommended tank mixes witb Atrazine 80W or 4L or BLADEX. 80W or 4L. A compatible fluid fertilizer (aee Appendix 1) or water may ~ used as carrier. Follow all directions, limitations, and use precautions on the ERADICANE 6.7-E, SUTAN+ 6.7-E, Atrazine, and BLADEX labels. Do not tank mix DYFONATE 4-ED with ERADICANE 6.7-E on sweet corn or popcorn. C. Split boot application for control of no thern and wester& corn rootworma (recoDDDended in the Nortbcentral and Midwest.ern corn growing areas only) -- Apply, at planting, 1 quart DYFONATE 4-ED in 5 to 20 gallons of compatible fluid fertilizer, (see Appendix 1), per acre (40 in~h row spacing) in subsurface split bands on each side of the corn row. 1-1/4 to 1-1/2 inches to each side of tbe seed and 1 to 2 inches deep. Do not place DYFONATE 4-ED in direct contact with the seed. MINT (PEPPERHlNT, SPEARMINT): For control of garden syaphylans 2 quarts DYFONATE 4-ED per acre, broadcast. and incorporate the soil using suitable tillage equipment prior to planting on established plantings prior to Spring growth. (Do not apply terbacil for at least 3 weeks before or after the DYFONATE 4-ED application.) BULB ONIONS: For control of onion .. ggot. apply as a furrow treatment at time of planting. Based on a 20 inch row spacing, apply at a rate of I quart DYFONATE 4-£0 per acre (1 quart per 2,61) feet of row; 3-1/4 fluid ounces per 2,613 feet of row; 1-1/4 fluid ounces per 1,000 feet of row). Use on organic soils only (soils contalning 10% or more organic matter). SUTAN and SUTAN+ are Reg. in the U.S. Pat. TH Off. • Bladex 1s a registered trademark of Shell Chemical Company. • • · ...... • • • • • •• •• •• • • • ••••• • • ••••• • •• • • •••••• • • .. ••••• • • • •••• •

Page 8 of 18 Dyfonate 4ED RS;-01l990 PEPPERS: For control of garden symphylana and wirewos, apply 2 qusrts (for aymphylana) or 4 quarts (for symphylans and wirewonDs) DYFONATE 4-ED per acre, broadcast, prior to planting and incorporate into the aoil uaing auitable tillage equipment. (For garden aymphylana only, reduce the rate proportionately for band treatmenta.) POTATOES (IRISH): A. Broadcast preplant application for control of garden symphylana and wireworms: ; Apply 2 quarts (for aymphylana) or 4 quarta (for aymphylana and wireworms) DYFONATE 4-ED per acre prior to planting and incorporate into the aoil using suitable tillage equipment. This treatment aay also be applied in certain areas as a tank mix with EPTAH® 7-E selective herbicide in a compatible fluid fertilizer and/or water (aee Appendix 1). Follow recommendations in the crop section of the £PTAM 7-E label for broadcast, preplant incorporated applications. For use in the Northern, Western, and Pacific Northwest Regions only. Observe all uae precautions and limitations on the EPTAM 7-E label. B. Banded preplant soil injection with fluid fertilizer for control of wireworms (Northwestern U.S. only): \pply through fluid fertilizer ahank illllllediately ahead of the planter. Set the shank to run 8 to 10 inc he a deep. Apply 2 quarts DFONATE 4-£D per crop acre, based on 36" row spacing, in the recOllllllended quantity of compatible liquid fertilizer (aee Appendix 1). NOTE: For heavy wireworm infestations, use the broadcast application only. SORGHUM (KILO): For control of corn leaf aphid and greenbug, apply 3/4 to 1 quart DYFONATE 4-ED in 5 to 30 gallons of water per acre over the top using aerial or ground application equipMent. Do not apply within 14 daya of harvest nor feed or graze to livestock within 14 days of application. Limit use to 2 applications per crop. STRAWBERRIES: For control of symphylans apply 2 quarts DYFONATE 4-ED per acre, broadcast, and incorporate into the aoil using tillage equipment prior to planting. (Reduce the rate proportionately for band treatments.) SUGAR BEETS: For control of garden aymphylans and wirevoraa, apply 2 quarts (for aygphylans) or 1 gallon (for aymphylana and wireworms) DYFONATE 4-ED per acre, broadcast, prior to planting and incorporate into the soil using ,le tillage equipment. (For garden ayaphylans only, reduce the rate proportionately for band treat.ents.) r+' -. "*, ----- .- •• • ',~ •• ~.' • • ,'f • ~ • ~ - - ;. , .!. '.. • • • • •• •• •• , . •••••• • • • •• •• • •••• •••• • • • • ••• •••••• • •• • • •••••• • • •• ••••• • • ••••• • •••••• • • •• •••••• • • •• ••

Page 9 of 18 Dyfonate 4ED RS.-01l990 SUGARCANE: At planting - For wireworm control, apply 4 quarts DYFONATE 4-ED per acre in a 14 inch band on cane rows 60 inches apart. This is equivalent to 11 to 14-1/2 fluid ounces of DYFONATE 4-ED per 1,000 linear feet of row. Apply over the top of sugarcane seed pieces immediately ahead of covering discs. SWEET FOTATOES: For control of wireworms and flea beetle larvae, 1 gallon DYFONATE 4-ED per acre, broadcast, at planting and into the soil usi~g suitable tillage equipment. TABLE BEETS: For control of cabbage maggot ~nd garden symphylans, apply 2 quarts DYFONATE 4-ED per acre, broadcast, prior to planting. Incorporate into the soil using suitable tillage equipment. (For garden symphylans only, reduce the rate proportionately for band treatments.) TOBACCO: For control of wireworms, apply 1 to 2 quarts DYFONATE 4-ED per acre, broadcast, prior to bedding and transplanting and incorporate into the soil using suitable tillage equipment. FLUE CURED TOBACCOS ONLY: DYFONATE 4-ED in combination with TILLAM 6-E controls wireworms and certain weeds (see TILLAH 6-E label) in tobacco. Add to the spray tank and apply 1 quart DYFONATE 4-ED and 2-2/3 quarts TILLAM 6-E in 20 to 50 gallons of water per acre (see Appendix I). Use a properly calibrated, low-pressure, boom-type sprayer having good agitation. lKPORTANT: Refer to both DYFONATE 4-ED and TILLAH 6-E labels for pertinent directions for use, and use precautions and restrictions. The soil should be well worked and dry enough to permit good soil incorporation. The tank mix must be incorporated (mixed) into the soil immediately after application to prevent loss of the herbicide by evaporation. Whenever possible, application and incorporation should be done in the same operation. Use power driven cultivation equipment set to cut to a depth of 3" in light soil and 3" to 4" in heavy soil, or a tandem disc set to cut to a depth of 4" to 6". Cross disc at right angles for thorough mixing. The bedding operation should follow the incorporation as soon as practical. Planting may be done immediately after bedding or at a later date; however, to insure long term weed control, the crop should be planted as soon as possible after application and bedding. TOMATOES: For control of garden symphylans, apply 2 quarts of DYFONATE 4-ED per acre, broadcast, prior to planting and incorporate into the soil using suitable tillage equipment. (Reduce the rate proportionately for band treatments. ) • • ..... ." • • • • • • • •• •• • • •••••• • • • •• • • • •••• •••• • • •••• •••••• • • • • • •••••• • • •• ••••• • • ••••• • •••••• • • •• • ••••• • • •• ••

APPENDIX I Page 10 of 18 Dyfonate 4ED RS-01l990 PROCEDURE FOR TESTING THE TANK-MIX COMPATIBILITY OF DYFONATE 4-ED WITH FLUID FERTILIZERS AND DYPOkATE 4-£0 WITH HERBICIDES AND WATER OR FLUID FERTILIZERS. This procedure is suggested for determining whether DYFONATE 4-ED and a apecific fluid fertilizer and/or the specifically approved herbicide(s) may be combined for spray-tank application. Materials Required: a. b. DYFONATE 4-ED. DYFONATE 4-ED/herbicide combinations (EPTAM 7-E, ERADICANE 6.7-E, SUTAN + 6.7-E, TILLAM 6-E, Atrazine 80W or 4L, or Bladex 80W or 4L. 2. Water or fluid fertilizer to be used. 3. Adjuvant for tank mix - Compex*, Sponto* 168-D, Unite* or equivalent. The adjuvant which performs best depends on the specific fertilizer being considered. 4. Two one-quart, wide-mouth glass jars with tops. 5. Measuring spoons: a graduated cylinder or pipette will provide more accurate measurement). 6. Measuring cup, 8 oz. (237 mI.) Procedure:

1. Add one pint (2 cups or approximately 473 al) of the test water or fluid fertilizer to each of the quart jars.
2. Add adjuvant to one of the jars and mix (see rate tables).
3. Carefully add the pesticides to each jar (see rate tables) as follows: a. If only DYFONATE 4-ED is to be used, add it directly to each jar. b. c. If a tank mix with a herbicide emulsifiabl~ concentrate is to be used, add the herbicide first and mix, and then add the DYFONATE 4-ED. • • ••••• • , . If a tank .ix with a herbicide emulsifiable concentrate ana - . wettable powder or flowable formulation is to be used, add andx. the pesticides in the follOWing order: ••••• : • o.pex is a trademark of Kal Laboratories, Inc., tr',rk of Witco Chemical Corporation; Unite is a h"pkLs Agricultural Chemical Company. • • Sponto 16D'ls a trademark of' • •• •• • •••• •• •• • • •••• • ••••• • •• • • • ••••• · , .. ••••• • • ••••• • •••••• • • .. •••••• • • •• ••

• 4. 5. 6. Page 11 of 18 Dyfonate 4ED RS.-O 11 990

1. add and mix the wettable powder or flowable foraulation first (preaixing these in water prio~ to addition to fluid fertilizer often provides a more compatible mix with fluid fertilizer),
2. Add and .ix the herbicide eaulsifiabe concentrate second,
3. aDd finally, add the DYFONATE 4-ED. Securely close each jar using the top and mix the contents by inverting the jar ten tiaes. Inspect the mixtures immediately and after standing for thirty ~inutes wi thout lllixing. Dispose of jar mixea according to disposal statements contained within this label. A mixture may be incompatible if either of the following conditions is observed: a. an oil layer or large oil globules are observed, or b. sludge or clumps are present. If either mixture remains uniform for thirty minutes, the combination may be used. Should either mixture separate after thirty minutes, but remix readily with teu jar inversious, the combination can be used if good agitation is maintained in the spray tank. If nondispersible oil, sludge or cluaps persist, the combination DUst not be used. If the mixture with the adjuvant stays mixed, or remixes readily to form a uniform di.persion, but the one without adjuvant does not, be .ure to use the adjuvant in the spray tank. Add the adjuvant first to the water or fluid fertilizer at the reca.mended rate. Kin1lllize foaming by using moderate agitation. • • :····1 • • • • • • •• •• • • •••••• • • • •• • • • •••• ..... • • .... • ••••• • • • • • •••••• • • •• ••••• • • • •••• • •••••• • • •• • ••••• • • •• ••

CalloDa of Fluid Fertilizer To Be Applied Per Acre 10 15 20 25 40 1-: Pale 12 of 18 Dyfonate 4ED i .\ 15-('11990 aate Table For DYPONATE 4-ED and Adjuvant** ________ v1==tht~he Fluid Fertilizer Milliliter. or Tea.poona of DYPONATE 4-ED* To Be Added to One Pint of Fertilizer Ml. Tsp. 12 2-1/2 8 1-2/3 6 1-1/4 5 1 3 2/3

• Based on a fluid rate of one pound active inlredient per acre in the fertilizer volumes indicated. Adjust volume proportionately to correspond with intended rate in terms of pounds active inlredient per acre (e.g. for a field rate of 2 pounds active ingredient in 10 lallons of fertilizer per acre, add 24 aL or 5 tsp. DYFONATE 4-ED to each jar for compatibility testing purposes. ** A typical adjuvant rate of use is 3 pints per 100 lallons of fluid fertilizer. Two (2) milliliters or one-half (1/2) teaspoon of adjuvant should be added to 1 pint of fertilizer in order to equal a rate of 3 pints of adjuvant per 100 gallons of fluid fertilizer. • .. .... .. .. . ,. .' ... -... • .. ...

Page 13 of 18 Dyfonate 4ED RS.-01l990 RATE TABLE FOR DYFONATE 4-ED/EPTAM 7-E and ADJUVANT** WITH THE FLUID FERTILIZER Milliliters or Teaspoons Milliliters or Teaspoons Gallons of Fluid of DYFONATE 4-ED* to of EPTAM 7-E* to Be Fertilizer To Be Be added to 1 Pint Added to 1 Pint Applied Per Acre of Fertilizer of Fertilizer MI. TSp. !1!. Tsp. 10 12 2-1/2 6-2/3 1-1/3 15 8 1-2/3 5 1 20 6 1-1/4 3-1/3 2/3 25 5 1 2-1/2 1/2 40 3 2/3 1-2/3 1/3

• Based on a field rate of one pound active ingredient per acre in the fertilizer volllllles indicated. Adjust volllllles proportionately to correspond with intended field rates in terms of pounds active ingredients per acre (e.g. for a field rate of 3 pounds of actual [PTAM 7-E in 20 gallons of fertilizer per acre, add 10 ~ or 2 tsp. of [PTAM 7-E to each jar for comp-atibility testing purposes). **A typical adjuvant rate of use in 3 pints per 100 gallons of fluid fertilizer. Two (2) milliliters or one-half (1/2) teaspoon of adjuvant should be added to 1 pint of fertilizer in order to equal a rate of 3 pints of adjuvant per 100 gallons of fluid fertilizer. • • •••••• • • • • • • • • •• •• • • ... ., .. • • • .. • • • •••• ..... • • ..... • ••••• • • 0 • • •••••• • • •• ••••• 0 0 ••••• • ..... , • • .. ....... • • •• ••

Page 14 of 18 Dyfonate 4ED RS-01l990 RATE TABLE FOR DYFONATE 4-ED/ERADICANE 6.1-E AND DYFONATE 4-EC/SUTAN + 6.1-E AND ADJUVANT** WITH FLUID FERTILIZER Milliliters or Teaspoons Milliliters or Teaspoons eallons of Fluid of DYFONATE 4-ED* to of ERADICANE 6.1-E* or Fertilizer To Be Be added to 1 Pint SUTAN + 6.1-E To Be Added Applied Per Acre of Fertilizer to 1 Pint of Fertilizer M1. Tsp. M1. Tsp. 10 12 2-1/2 1 1-1/2 15 8 1-2/3 5 1 20 6 1-1/4 3-1/2 3/4 25 5 1 2-1/2 1/2 40 3 2/3 1-3/4 1/3 *Based on a field rate of one pound active ingredient per ~cre in the fertilizer voluaes indicated. Adjust volumes proportionately to correspond with intended field rates in terms of pounds active ingredients per acre (e.g. for a field rate of 4 pounds of actual SUTAN + 6.1-E in 20 gallons of fertilizer per acre.-add 14.1 or 3 tsp. of SUTAN + 6.1-E:to each jar for comp-atibility testing purposes). **A typical adjuvant rate of use in 3 pints per 100 gallons of fluid fertilizer. Two (2) milliliters or one-half (1/2) teaspoon of adjuvant should be added to 1 pint of fertilizer in order to equal a rate of 3 pinLs of adjuvant per 100 gallons of fluid fertilizer. • • •••••• • • • • • •• •• •• • • •••••• • • .. • •••••• • •• • • •••••• • • •• • •••• • • ••••• • •••••• • • • • • ••••• .... . . •• •• .....

Page 15 of 18 Dyfonate 4ED RS-o 11 990 ••• • •• • • ••• RATE TABLE FOR DYFONATE 4-ED/ERI DlCAN! 6.7-E/ATRAZINE OR BLAUEX AND DYFONATE It-ED SUTAN + 6.7-E/ATRAZINE OR BLADEK AND ADJUVANT** WITH WATER OR FLUID FERTILIZEi: Gallons of Water or Fluid Fertilizer To Be Applied/Acre Measure Milliliters or Teaspoons of DYFONATE 4-ED* To Be Added to 1 Pint of Water or Fertilizer Milliliters or Teaspoons of ERADlCANE 6. 7-E* or SUTAN

• 6.7-E* to be added to 1 Pint of Water or Fertilizer Milliliters or Teaspoons of Atrazine SOw* or Bladex 80W* To Be Added to 1 Pint of Water or Fertilizer Milliliters or Teaspoons of Atrazine 4L* or Bladex 4L* To Be Added to 1 Pint of Water or Fertilizer 10 Ml. Tsp. 12 2-1/2 7 1-1/2 22 4-1/2 12 2-1/2 15 25 • • • •• Ml. Tsp. 20 Ml.- Tap. MI. 12.:. Ml. 8 1-2/3 6 1-1/4 5 1 3 5 1 3-1/2 3/4 2-1/2 1/2 1-3/4 15 3 11 2-1/4 8-2/3 1-3/4 5 8 1-2/3 6 1-1/4 5 1 3 *Based on a field rate of one pound active ingredient per acre in the water or fertilizer volw Adjust volu.es proportionately to correspond with intended field rates in teras of pounds acti' per acre (e.g. for a field rate of ~ pounds of actual SUTAN + 6.7-E in 40 gallons of fertilizel add 7.1 or 1-1/2 tsp. of SUTAN + 6.7-E to each jar for coap-atibility testing purposes, i.e., 10-gallon rate for 1 pound equals 28 ml or 6 tsp.; then dividing by the dilution factor four [. gives 7 at or 1-1/2 tsp. per pint, which is equivalent to 4 pounds actual SUTAN + 6.7-£/40 gall **A typical adjuvant rate of use i. 3 pints per 100 gallons of fluid fertilizer. Two (2) .illl one-half (1/2) te.spoon of adjuvant should be added to 1 pint of fertilizer in order to equal I pints of adjuvant per 100 gallons of fluid fertilizer.

.. -. .:.::.a:. • - =.=..' - 10 12 2-1/2 8 1-2/3 15 8 1-2/3 5-1/4 1 20 6 1-1/4 4 3/4 25 5 1 3-1/4 2/3 40 3 2/3 2 1/3 *Bi.'.sed on a field rate of one pound active in1redient per acre in ·he fertilizer voJ.Ullles indicated. Adjust volumes proportionately to correspond li.th intended field rates in terms of pounds active ingredients per acre (e.g. .or a field rate of 4 pounds of actual TILLAK 6-E in 20 gallons of fertilizer per acre, add 10 at or-2 tsp. of TILLAM 6-E to each jar:for compatibility tesing purposes). **A typical adjuvant rate of use in 3 pints per 100 gallor ,,~ fluid fertilizer. Two (2) milliliters or one-half (1/2) teaspoon of adjuvant should be added to 1 pint of fertilizer in order to equal a rate of 3 pints of adjuvant per 100 gallons of fluid fertilizer. • • • •••••• 0 • • • • • • •• o. • • •••••• • • • .. 0 0 • •••• ... . •••••• • • • • • •••••• • • •• ••••• • • • •••• • •••••• • • .. •••••• 0 0 .0 ..

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• I' Page 17 of 18 /' Tank Mix Directions Dyfonate 4ED RS.-011990

1. Fill the spray tank at least 2/3 full of the appropriate carrier fluid. Be sure tank is clean and not contaminated with 2,4-D type herbicides, oil residue or other .ateriala.
2. Start agitation and continue moderate agitation throughout mixing and application procedures.
3. Add the proper amount of adjuvant and mix (if adjuvant is to be used).
4. Next add the Atrazine BOW or 4L or Bladex 80W or 4L (if it ia to be combined in the tank) and mix to disperse it thoroughly.
5. Then add the herbicide emulsifiable concentrate (EPTAM 7-E, ERADICANE 6.7-E, SUTAN + 6.7-E or TILLAH 6-E and mix thoroughly •
6. Lastly, add the DYFONATE 4-ED.
7. Complete fill1ng the remaining portion of the tank with carrier fluid; mix thoroughly.
8. The tank-mix combination should not be left in the spray tank for prolonged periods; batches should be mixed and applied the same day. NOTE: Constant moderate agitation is required for successful tank-mix preparation and application. Avoid excessive agitation which can cause tank-mix incompatibility. All return lines to the tank must discharge below l1q u id level. • • • •••••• • • • • • • • .. .. • • •••••• • • • .. • • • •••• •••• • • •••• •••••• • • • • • •••••• • • .. ••••• • • ••••• • •••••• • • .. •••••• • • .. ..

• ,~ STORAGr. AND DISPOSAL Page 18 of 18 Dyfonate 4ED RS.-011990 . .' STORAGE: Minimum atorage te_perature: O' F. Product may crystallize below O· F. Roll or shake well before opening to assure uniformitf. Any ateel container , be corroded by itll contentll. DeTts or damage may pro.lOte corrosion. Use d.-ged and older containers FIRST. Inll,ect rusted cans 'or leaks. PROHIBITIONS: Do not contaminate water. food, or feed by storage or disposal. Open dumping is prohibited. PESTICIDE DISPOSAL: Pesticide wastes are acutely hazardous. Improper disposal of excesll pesticide, spray mixture, or rinsate is a violation of Federal law. If these wastes cannot be disposed of by use according to label instructions, contact your State Pesticide or Environmental Control Agency, or the Hazardous Waste representative at the nearest EPA Regional Office for guidance. CONTAINER DISPOSAL: Triple rinse (or equivalent). Then offer for recycling or reconditioning, or puncture and dispose of in a sanitary landfill, or by other procedures approved by State and local authorities. NOTICE TO BuYER AND USER: Seller warrants that this product conforms to the che.ical description on the label and is reasonably fit for the purposes stated on the label when used in accordance with directions under normal conditions of use. This warranty does not extend to the use of this product contrary to label instructions, or under abnormal use conditions, or under conditions not reasonably foreseeable to Seller, and Buyer and User assume the risk of any such use. SELLER DISCLAIMS ALL OTHER WARRANTIES EXPRESSED OR IMPLIED INCLUDING ANY WARRANTY OF FITNESS OR MERCHANTABILITY. SELLER SHALL NOT BE LIABLE FOR CONSEQUENTIAL, SPECIAL OR INDIRECT DAMAGES RESULTING FROM THE USE OR HANDLING OF THIS PRODUCT AND SELLER'S SOLE LIABILITY AND BUYER'S AND USER' S EXCLUSIVE REMEDY SHALL BE LIMITED TO THE REFUND OF THE PURCHASE PRICE. • • •••••• • • . . \ • ••••• • •• • • •••••• • • • • . . .... 011890crbOJ ..... · .. .. .. .. .. . · ....... • • L-________________________________________________________________________ _