crop-chem-docs/corpus/epa_ppls/352-441.md

DUPONT "ASSURE" HERBICIDE

• EPA Reg No: 352-441
• Registrant: CORTEVA AGRISCIENCE, LLC
• Signal word: Caution
• Active ingredients: Quizalofop (9.5%)
• Label accepted: 1994-01-14
• Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/000352-00441-19940114.pdf

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p~l\ :)·5 05J..- '-1'-\ \ UNITED STATES ENVIRONMENTAL PROTECTION AGENCY WASHINGTON, D.C. 20460 Jl.t\ I L Marie M. Chubb EJ. DU PONT DE NEMOURS AND CO. BARLEY MILL PLAZA. WALKER'S MILL WILMINGTON. DE 19880 ::' .- . --'. '. -. OfFICE Of PREVENTION. PESTlClOES AND TOXIC SUBSTANCES Subject: Label Amendment Submission of 08/10/93 in Response to PR Notice 93-7 EPA REG. NO. 352-441 DUPONT "ASSURE" HERBICIDE Dear Registrant: The labeling cited above and submitted in connection with regi:;tration under the Federal Insecticide. Fungicide. and Rodenticide Act (FIFRA). as amended. is accepted. A copy of your proposed labeling stamped "ACCEPTED WITH COMMENTS" is enclosed. WHAT THIS ACCEPTANCE MEANS: Based on your certification. the Agency has accepted the labeling changes that are necessary to comply with the Worker Protection Standard (WPS) labeling requirements of 40 CFR part 156. subpart K. described in PR Notices 93-7 and 93-1l. Any other labeling changes submitted in connection with this amendment application but not directly related to compliance with the WPS have not been reviewed or accepted by the Agency. If you wish to make such changes. you must submit a separate amendment application proposing them. If your product is currently suspended. the acceptance of this labeling amendment does not affect the suspension in any way. WHAT YOU NEED TO DO NEXT: Send to EPA one (1) copy of the final printed labeling: • BEFORE selling or distributing any produci bearing the final printed labeling AND • WITHIN one year from date of this acceptance. ?A:l ~cI8b" n.- n ....... _..,.c.-..... __ 'ClC!------

Page 2 Submit the fmal printed labeling via the U.s. Postal Service to: Document Processing Desk (FIN-LABEL) Office of Pesticide Programs (7505C) U.s. EnvironmeDtal Protection Agency 401 M Street, SW Washington, D.C. 2046().()()(}1 Hand or courier deliveries of final printed labeling may be made to: Attachment Document Processing Desk (FIN-LABEL) Office of Pesticide Programs Room 266A, Crystal MalI 2 1921 Jefferson Davis Highway Arlington, V A 22202 Sincerely,

REGISTRATION CODE 0211-000 PACKAGE SIZE e· 1 GALLON JUGS/CARTON ASSURE®or5 HERBICIDE EMULSIFIABLE COf!CENTAATE ACTIVE INGREDIENT IY WEIGHT 2;4·((2-quincJ111iny1)y)Jropionic acid, eIhyI esIer ..................................................... 9.5%' INEAT INGREDIENTS .......................................................................................................................................•...... 90.5%' THIS PRODUCT CONTAINS THE TOXIC INERT INGREDIENT PHENOL. Contains pelroleum cistillales. 'Equivalent 10 0.8 pounds ai per gallon. EPA Reg. No. 352-441 KEEP OUT OF REACH OF CHILDREN CAUTION TOTAl ........... l00% U.S. Pal 4,629,493 Ji--., , lSi;, PRECAUnONARY STATEMENTS "-.ler "" F".,oJ .. ""hide, r-...,... . lod.lIII..... " .. HAZARDS TO HUMANS AND DOMESnC ANIMAL:· .. ' .:Jo: .r:~'r.:, CAUTION! MAY IRRITATE EYES, NOSE, THROAT AND SKIN. 3s-,".<ly7 Awid breathing vapors or spray mist. A.oid contact with skin, eyes and clothing. In case of contact, immediately flush eyes or skin with plenty of water. Get medical aHentlOl1 ~ skin irritation persim. For medical emergencies Involving !his product. ClllIOIt fr .. ,-1OO-44,·3637. PERSONAL PROTECnVE EQUIPMENT Some materials that are chemical-resistant to this product are sted below. If you want more options, follow the instructiOnS for category G on an EPA chemical-resistance category selection chart. Appllcltors and other handlers must wear: Lono-sleeve sflirt and long pants. Chemicakesistant gloves, such as barrier laminate or VHon. Shoes plus socks. Follow manufacturer's instructions for cleanirvmaintaining PPE. If no such instructions fOI washes. use detergent and hoi water. Keep and wash PPE separately from Other laundry. USER SAFETY RECOMMENDAnONS USERS SHOULD: Wash hands betore eating, drinking, chewing gum, using tobacco or using the tOilet. Remove clothing immediately n pesticide gets inside. Then wash Ihoroughly and put on clean clothing. ENGINEERING CC)NTROL STATEMENTS When handlers use closed systems, enclosed cabs, or aircraI in a namer \ltal meets \he requirements listed in the WOIker PrOlection Standard (WPS) tor agricuhlllll pesticides f40 CFR 1*1170240 (d)(4-6)J, the harder PPE requirements may be reduced or modified as specified in !he WPS. ENVIRONMENTAL HAZARDS Do not IIIlPIY cirecty to water or wetlands. Do not contaminate water by cIeaniIg of equipment or cisposaI of waste. PHYSICAL AND CHEMICAL HAZARDS Combustible. Keep away from heat, spa!IIs, Ind open lames. Keep container closed. 1

M'ORTANT Injury 10 Of loss of desirable "M Of vegelltion may IlSUlllrom lail\lfe 10 obIeM IIIe following: Do noIlPPfy Of chin Of lush equipmenI on Of ,... desirable Irees Of planls. Of on lfelS wIlE'~ IIIeir rools may extend. or in IocaIionS where the dlernicalmay be WIShed Of moved infO conIIcI will fIeir roofs. Do noI use on lawns. WIlks. ctiveways. tennis ccuts. Of IirniIIr Ifas. Prevenl drifl 01 SIl'ay 10 desirable plants. Do not contaminate arrt body 01 waler. Keep Irom COIIIaCI with fertilizers. inseclicides. fungicides. Ind seeds during 1Iorage. Thoroughly "lAJfitaItOn equ..-immedialefy aIIer use. Use caution when handling "" IIeI1Iicide as iIXidoolal SIIifIs Of splashes may hIfm the I'rIish on pIirIIed equipmert DIRECTIONS FOR USE n is I violation 01 federal law 10 use !his produCt in I _ imlSislenl with its labeling. 00 not apply 1his product in a 'njlhal will cmact worIcelS or other persons. either directly or through drift. Only prlXected handlers may be in the area during appIicaion. For any requirements specific to your State or Tribe. consuh tile agency responsible for pesticide regufation. AGRICULTURAL USE REQUIREMENTS Use this proc1JCI only in acccwdance willi iIs labeling and will tile Worker PrlXection Slandard. 40 CFR pa1170. This Standard contains requirements for the protection of agricultural worIcers on farms. forests. nlJ'series. and greenhouseS.1r1d handlers of agricuhural pestiCides. It contains requiremenls for training. dec:ontMlination. notification. and emergency assistanCe. It also contains specific instructions and exceptions pertaining to the statements :lIl this label about personal protective equ;pment(PPE) Ir1d restrided-entry interval. The requirements in 1his box only appfy to uses of this product that are CO\Iefed by the Worker Prection Standard. 00 noI enter or allow worker entry into treated areas during the restricted entry interval (REI) of 12 hours. PPE required for early entry to treated weas that is permitted under the Worker PrOlection Standard IM1d that irMlIves confact with anything that has been treated. such as plants. SOil. or water. is: Coveralls. ChemicaJ.resistant gloves. such as barrier laminate or Viton. Shoes plus socks. Do noIlIAlI'!!his produCt IIrtxq1I11'f Iype 01 irrigation sysIem. "Assure" should be used only in ICOOIdanoe .... r_1datioI1S on !his libel Of in ~ IdJIished Ou fIonllibCOilll*dlblS. Ou Pont will not be responsille lor losses Of dIrnages ~ trom the .... 01 lois proo1M:I in my manner noI specibIIy ' ..... liloeoodedl¥ Ou I'brt GENERAL WFORIIATION "Assure" ill aeIecWe posIemergetlCe herbicide rec:ornnoeoded lor foe c:onWI 0I1IIIIU8I and perennial ",asses in ~ Ind IIOMIOp Ifas. "Assure" does noI oonJroI sedges Of br1 weeds. Applied It recommended rates and timingS "Assure" Herbicide will control emerged grasses. Subsequent flushes 01 grass weeds require Idditional "ea'''IeIIf 2 "i.F Most QIIII CIOPI. including wheat. bIrIey. rye. oils. sorghum. rice and corn Ir. highly IeIIsitive to "Allure" Herbicide Ind III direct or indirect oonllCt (auch IS spray drift) Ihould be 1'IOided. When not in use. keep container closed 10 prevent evaporalion or loss through spillage. BIOLO~;CAL ACTIVITY "Assure" is a eyslemic herbicide wt.ih is rapidly absorbed and translocated Irom the trelted foIilge 10 the roots and other growing points 01 the plant. Treated plants show reduced growth Ind loss 01 compelili<eness. EIIIy chlorosis/necros;, 01 the younger pllnt tissues is lollowed by a progressive degradation 01 the remaining loliage. In general. these symptoms ar8 observed in one to three wHl<s depending on the grass species treated and the environmental conditions. APPLICATION INFORMATION· GENERAL TIMING TO WEEDS Apply "Assure" Herbicide postemergence 10 actively growing grasses according to the rate charts below. Applications made to 9rass planls slressed due 10 insulfocienl moisture Of cold temperatures. or to grass plants exceeding the stage 01 growth recommended in the rate table may resuH in unsatisfactory control. In arid regions where irrigation is used. apply "Assure" HerbiCide as soon as possible after an irrigation. GEOGRAPHIC RECOMMENDATIONS The grasses controlled by "Assure" and the rates needed lor conlrol diller by geographic location. A clescriplion 01 the area boundarieS is as Iolows: AREA I - (ArtiS wfth Adeqult. Allnllfl) Encompasses mosl 01 the easlern hall 01 the United Siaies. II is characterized as having adequale raintall 10 support crop production and generally dOes not require irrigalion during Ihe growing season. States included in area I are; Alabama. Arkansas. Connecticut. Delaware. Florida. Georgia. Illinois. Indiana. Iowa. Kansas (broadly delined IS easl 01 Interstate 135). Kenlucky. LouiSiana. Maine. Maryland. Massachusehs. Michigan. Minnesota. Mississippi. Missouri. Nebraska (broadly deli ned as easl 01 State Highway 183). New Hampshire. New Jer&ey. New York. North Caroina. North Dakota. Ohio. Oklahoma (broadly delined as east 01 Inlers!ate 35). Pennsylvania. Rhode l$land. South Carolina. South Dakota. Tennessee. Texas (broadly defoned IS east 01 fnlerstale 35). Vermonl. Virginia. Wesl Virginia. and Wisconsin AREA. -jArid Conditions) Esses the _fern portion 01 lour states west olllle Mississippi rNer. It is chiIIacteriZed as having ariel condiIions and in many locations requires irrigation cloring fie IP'owing season." States included in area II are; Kansas (broacIy defined IS west ollnlerltate 135). Nebraska (broady defined as west 01 State Highway 183). Oklahoma (broacIy defoned as west oIlnJerslate 35) Ind Texas (broacly defined as west olJnterstale 35). .. Nole: AppIicalions 01 "Assure" herbicide should be made to aclively growing grasses. "I field is to recei¥e an irrigaloon. wait until Ifter the irrigation to apply "Assure" HeIticide. [IESl l1l1UIU c.~ \

ENVIRONMENTAl CONDITIONS Conditions conducive to healthy, actively growing ptants optimize the perl:1rmance of "Assure". ~ made to ~ wtIic/1 are stressed due to insufficient moisture may result in unsatisfactory control. Grass weeds nder this condition lrequenMy become less sensitive to helbicicle acti\i!y. Delay application until the stress passes. Do not apply H rain is expected within t hour of application as control may be unsatisfactory. SPRAY ADOITIVES ALWAYS INCLUDE A SPRAY ADJUVANT WITH APPLICATIONS OF "ASSURE". UNess otherwise Orected, seIed one at the adjuvants isted below. Ground Appticltions: Crop oil concentrate at a rate (concentration) of 1.0% vlv (4 quarts per 100 gallons of spray solution). OR Nonionic surfactant at a rate (concentration) of 0.25% vlv (1 quart per 100 gallons of spray solution). Aerial Appticltion: Crop oil concentrate at a rate (concentration) of 0.5% vlv (2 quarts per 100 gallons of spray solution). OR Nonionic surfactant at a rate (concentration) of 0.25% vlv (1 quart per 100 gallons of spray so1ution). Petroleum oil concentrates should be of good quality and contain a minimum of IS" emutslleflsuractart. Nonionic surlactlnts should contain .. least 80% a;live ingredienL Do not use vegetab1e (crtIP origin) oils as 1IJIlIY.quvant or c.rier with "Assure". USE ONlY EPA APPR:lVED OIL CONCENTRATES AND SURFACTANTS. CULTIVATION Cuftivation cMing or within 7 days before or 7 days after an appication of "Assure" may r in UllSl.'tisfactJry controt. Cultivation may put WIsse5 under gess by pruning roots, thus making controt more di~ to oIWI. IIOTATIONAL CROP GUIDELINES Do not rotate to crops other than soybeans within 120 days after app1ication. 3 APPlICATION EQUIPMENT· GENERAL IPRAYTANKPRERATK* It is importlnt thlt spray equipment il clean Ind free of existing pesticide deposits before using "Assure". Follow the cleanup procedures specified on the label of the product previously sprayed. GROUND APPLICATION (See SPRAY DRIFT) Bl'OIdcIlt Appl1tlon: Use fiat fan or hollow cone nozzles at 260 psi. Do not use ftood, rlin drop, whirl chamber or othe! nozzle types which product COlrse, Ilrge sprlY droplets or controlled droplet applicator (COA) type nozzles IS poOl weed control or excessive spray drih may resuH. Use a minimum of 10 gaUons of water per acre in Area I (adequate rainfall'). Use I minimum of 15 gallons of wate! per acre in Area II (arid conditions'). Do not exceed 40 galans of wate! pet acre in Area I or Area II. For proper spray c_age adjust the boom and nozzle height according to the specilications listed by the nozzle manufacture!. Bind Applltlons: For band application, use proportionately less. Carefully calibrate the band applicator to not exceed tha 1abe1ed rate or injury may occur. To avoid impropet use of band application equipment carefully Iotlow the manufacturers instructions for nozzle types, nozzle orientation, distance of the nozzles from the crop and weeds, spray volumes, calibration and spray pressure. For additional information on o"ow banders see Du Pont's bulletin, "Application Accuracy - Row Bander3-. AERIAL APPLICATION (See SPRAY DRtFT) Use nozzle types and arrangements that will provide for optimum spray distribution and maximum coverage. Use a minimum of three gallons of water per acre in Area I (adequate rainfall') Use a minimum of 5 gallons of water in Area II (arid conditions'). Do not apply during a temperature inversion condition, when winds are gusty, or when other conditions will favor poOl coverage and/or off target spray movement. , A description of the area boundaries is included. SPRAYER CLEANUP Thoroughly clean application equipment immediately aher use. Flush tank, pump, hoses, and boom with several changes ot water atter removing nozzle tips and screens (clean these parts separately). Failure to thoroughly clean the equipment may resuit in injury to subsequently sprayed grass crops. When "Assure" is tank mixed with other pesticides all sprayer cleanup procedures should be examined and the most rigorous cleanup procedure should be foIowed. SPECIFIC USES· SOYBEANS RESTRICTKS Do not gtaze treated fie1ds or har¥est for forage or hay. Do not apply more than 40 ounces of product pet acre per season. CIIOP RESPONSE Minor leal spotting may occur to spreyed loliage under certain environmental conditions. New qrowth and crop yields are unaffected. TIMING OF APPLICATKS "Assure" may be apptied to soybeans any time prior to 80 days before harvest. Do not IppIy lher pod set. Best resu~s Ire obtained when "Assure" is applied to grasses that are young Ind ICtively growing. Applications made to grassI's that are larger than the size indocated below, or to grasses under stress may result in unsatislactory control.

AREA I (AREAS WITH ADEQUATE RAINFALL)

(See GEOGRAPHIC RECOMMENDATIONS)

SIZE AT ·ASSURE"

APPLICATION OZ

ANNUAL G~ASSES (IICHES) PRODUCTIA

VOIu_ C .. n (ZII ",",,, 6-18 10

S/1aI1of'1I1I (Sorgllum _I 6-'2 '0

-.-.... ~, ,. 2-1 ,0

w.oaPt ... _I'*I1ICUI1I-..n\ 2-1 ,0

CrOlllOO9" (Dac1y""*-ItIIIIJI,,"1 H 14

e." Panocum (PI""um CIocMomoIOorurnl 2-6 ,.

JlIIIIS GIIRI ("'" 2-8 " GMn (Solar .. '1 2-4 '4 _ (,. """,ensl 2-4 '4 Br_1Iy ($IIan'1 2-4 '4 ~(E-.., 2-6' '4 1IcI1grus(- -I 2-8 14 Foold _ (Ctncftrus "''''uS! H ,. SpIf9ll<iP (L ___ , 2-6 14 _CtrUIS Wheat (Tr.um IIStlYUmJ 2-6 14 Bat.., (H .. _ vulgafe, H 14 OIlS (A __ I 2-6 14 Rre (SIcaII .. 11"01 H 14 W"" 01' (A_II'''I 2-6 ,. wo,ngr ... (Plnoc:um _'1 H 14 WOOl', _IS. (E""""I 2-4 14 Ba.nyatGgrISS (E .......... cru'"9I.1 H '6 81 """"'IS. (Braehllr,. plalypllylal H '6 Crlllgri .. Largo (DogoIar .. _Iosl 2-6' 16 SmooII lOogot .... _I 2-li' 16 ./urIgIIre. (E ........... '_i 2-6 '6 Rod Re. (Ory .. U111 ,-4 '6 TillS _um (om_I 2-4 '6 PERENNIAL ASSES BarIrlUdagrISS (C dIC1)Ionl 3'''' ( .. '" 20 106" runners) R"" .... __ as. (SorglUn ""opense. 1().24 20 OuIdIgr ... (Agrowon '1 loW :!Ii W ........ lIuftIy (11_l1li koneJosal " 16 " """"", '" per" ........... mao. -. ~ "'·As'.I1· _ 14 """' .. pr"""'VA '"*' 10 "ISS _ .... IS , BarOllCllgrIS. (3',.,' .. '" 10 6' .unner'l. RIm .... .--ass (f·.10"1. OuIdI"ua W-I'I. W ........ II""" (4'· n Do ... II,III! 40 """'IS '" 11' per .. II PI' )11'. I Lengot\ "' grOWl" SEOUENnALAPPlAnONS WITH POST BROAOLEAF HERBICIDES NOTE: Reduction in grass co'1lrol is posW1e when "Assure" is applied Immediately prior to or sequentially aller an appIation of a post broadeaf herbicide. OIlaerve the following recommendations.

• After applying ·Assure", wa" a minimum of 24 hours before applying a post broadleaf herbicide.
• In fields treated with a post broad leaf herbicide, do not apply "Assure" until grass plants begin to develop new IeMs (genera.y 7 days after the post broadleaf herbicide application). TANK .. X APPL~ATIONS 00 nottallk mil "Assure" Herbicide with any pesticide or spray adjuvant "cept as dlrec(ed in this or other supplemental labeling. 4 AREA. (ARID CONDITIONS) (SH GEOGRAPHIC RECOMMENDATIONS) IIZE AT ·ASSURE" APPLICATION OZ (IICHES) I'RODUCTIA ANNUAL GRASSES _ COIn (ZIII11I)II 6-10 14 -(SorgIIum-1 6-'0 '4 -. ............ ~ .......... , 2-1 '4 Foold _ (CtncIwus -..11 2-6 14 Batny'rGgr'" (EncIWIOCtIIOI CfUSo9I., 2-4 16 St .. ".., SognaIgIua (!rIC ...... P!.1jIIIIyI1I1 '-4 16 urge CrqIua (Oogotana ~ 2-4' '6 F ...... (ia .. ..., 2-4 16 _ (Solaria'I 2-4 16 oNngIeIlCt IE __ I 2-4 16 T Panocurn (Panocum_ml 2-4 20 vou..-s 0".,,,," __ , 2-4 16 Ballfy (HOI wIgaI'l 2·4 16 OIIS(A ..... ' 2·4 16 R,el_"1 2·4 16 PERENNIAL GRASSES BarOllCll,,1SS (C,- dICIyIcPI! 3· ... ( .. '" 24 to 6" ,ynnerS) Aftz .... JoMsongras. (Sorgllum IIaIIponseI '().'6 24 Nil"""", '" per " ..... oce .... _ ........ oppIoc.""" '" ·A ..... • "''''!I '6 """'" prcDrc1lA '"*'10 "ISS _ ...... _ BarIrlUdagr'" (3' ,.. .. '" 10 6' _" RIll ..... __ us (6""0"1. Do ... ",",,40 """'" ""e' per acr. per Mason. I LongtII "' .. gr ...... "Assure· may be tank mixed wilh Ihe following postemergence broadleaf herbicides, ·CIassic·', "Pinnade"I, ·Classic" • "Pinnacle", or '8asagran"2 in soybeans. Refer to ttoe ·Classic", "Pinnacle" or "8asagran" labels for informalion regarding rales, weeds conlrolled, use restrictions, rolalional cropping recommendations, sprayer cleanup use precaulions, and other information. The mosl restriclive provision on erther label wi. apply. INFORMATION ON ANTAGONISM Tank miles of "Assure· with post broadleaf helbicides have shown some reduction in control Of most grass species end failure to conlrol certain other grass species which would otherwi,;e be conlrolled when "Assure" is applied alone. Activity of Ihe posl broadleaf herbicide in Ihe tank mixlure is nol aflected. When tank mixing "Assure" with "Classic", "Pinnacle", "Classic" • "Pinnacle" or "Basagran" antagonism can be minimized by ,ncreasing the recommended rale of "Assure" (as IIsled in Ihe GRASSES ( BEST AVAILABLE con)

.cepIion.: GIIOUPI Giant Folllil SedIg JahnaongtUt Rhizome Johnaongrua • '" IbM ...... '" ........ _ III IIOI1h111d, IIIICt '" .... of 'Aaure' IIIIId in '" UAIIlI COImIOLLIOIRATI CHAIIT IICIon. II ~ 0IhIr thin tIIoM IiIIId IbM lit ~ iIcr ... tie .. It ol·Aaw.· by 4 ounces. GfIOUIII Bamyardgrau Broadeal Signllgrul OuIckgrus Smoolh C/Ibgr .. s Woolly Cupgrasa Ber~ IMge Crlbgrus Red Rice T.I., Panicum Wirealem Muhly Yellow Folllil The ....... listed In GROUP II will not III controlltcl br 'Allur,' It Ipplled ... tInIl mil willi post 1If00dlllli IleltliClcltl. To obIain control 01 lhe .. grII'''S tpply 'Assure' IS I .. quenlial Ir.llmenl. • ilher 24 hOUri belore or 7 dlYs loll owing In Ipplication 01 a postemergence broadIeal herbicide. MOTE: Do nolepply 'Assure' in I link mil wilh a poslemergence broadlell herbicide in AREA \I (arid condilions). a$ delined on Ihis label. II grlSS conlrol will nol be Ulisllclory. II bolh grlSS Ind broadeal weed control is desired. make separale appIicalions. "FORMATION OM SPRAY ADJUVANTS When link miling 'Allur,' wilh ·Cllssic·. 'Pinnlcle' "Cllssic' • "Pinnacle' or "IIIsoigIIn' UN 01 I sprey IdjuvInl is required. Select one 01 \he loIIowing: 'AaIuf,' + "Clastic'; For ground II 1M nonionic surllclant II a ra\e 01 02!l" .Iv or CfOP 01 concentrlle II I rale 01 1.a.. v/v. For will application. use nonionic .urlaclanl II • rale 01 0.25" vlv or crop 011 COtICWIIII".1 ralt 01 0.5" vlv. 'AIIure' + "PinnIcIe": For ground or aerial appIica _ nonioftC aurIIcImn "I rail 01 O. 12K 1DO.2S .. vIv. OR USE OF THE HIGHER RAlE OF NONIONIC" SURFACTANT PARTICULARLY UNDER HOT HUMID CONDITIONS MAY INCREASE "Aeaure' + "PinnIcIt· TEMPORARY CROP INJURY.

• "CIusic" DO NOT USE CROP OIL CONCENTRATE ORDASIf. -Auvrl· • T ,. .. -:For pund ., •• '6 UII crop oil conOI .. Ia .. • 1 • fll. II 1 qUlrl pel .Ct.. For ..,Iot " ..... _ CICIP" .:w:.",,,, at 1 pwI\ ,.1tIt. SEQUENTIAL APPLICATIONS FOR JOHNSONGRASS CONTROL For conlrol 01 rhizome johnlongrl., in Ih •• llles 01 Allblml. Arkin .... Florida. G.orgi •• Loui.ian •• Meryllnd. Mi •• i •• ippi. T. Virginia. end Will Virginia. 'Alaure' mty be applied 1\ I reOIcId rll, when appIiId in I aequenlill app\ocIlion program. 10 III 24 1ncheI1III. Apply '" IIqUIIIIiII ""':1 of "AIIufI' .. I .... "I 10 OUIIOIIper ItIt when joIwllOftOllll :'II'ow\II hit rtICIItd e to 10 tnchllllllIeIgIrt. Do noltpply "AaIu,,' In , lank rnIJ with poa\ broIdIul herbicidts when IIIIng \Ilia IIduced lilt IIqIIIIItiII eppIicIIion program. IPOTIlMALL ARIA SPRAY REenll.IIDATIONS .. IOYBEANS (AREAl I AND U) .... 314 PllCllllIOIutIon of "AIa:lW' in ...... tor IPOI netrntnl 01 IllllUlIIIiea IUCh • IIOIur:tItr oorn or per.nnlal apecitllUCh I. mllom, john.ongr .... Th' 'plIY .olullon .hould Include I nonphytololic oil concennl. II , .. vlv or I nonionlc IUrlacllnl II O~ vIv. Till! pIan\I on I ~ bull InIuring good_age. 5 0AllUlll" ...... 01 01 -...., ... ....... fUll Coso tau 011 ........ ' .... 1.0 ..... 1.251.11. 0.3'. oz. 12111P1 12-'' 12.' 2$ ....... 20.0 .... 32 ..... •. 0 .... 13_' (I",, (I~ 10 ....... ....... ....... .. ..... (1.$-", 12_' (I pool, 100 ....... M'. oz. 128ft. oz. 32'. oz. 13.."., ~-) (I .,.,.,,) NON,AGRICULTURAL USE REQUIREMENTS 1be requirements in this box IWly 10 uses of this produtllhal IR NOT within the scope of the Worker Proteclion SlIndard for I.riculrural peSlicides (40 eFR Pin 170). The WPS Ipplles when this produci is used 10 produce I,neUIIU .. 1 plants on fums, forests, nurseries, or peenbouses. Weed contrOl in ~Noncrop AreIs" is not within the Kope ofWPS. Keep unprotcc:ted penons 0111 of !relied IRIS unlil sprays have dried. SPECIFIC USES ° NON·CROP AREAS ·Aaw.· .... I .... ncItd lor pGIttmtIgtnCe UIIIgt III control etrIIIin ,... 011 non-oop "" aucII • IIncI _. 1OIdIidtI. tqIlipment ... .... II1II OIIItrainillr .... Apply U III 2.0 pIn\I at·AIIuII· ,. ItIt III tcIivtIy growing grIIItI • !allows: OuIc:IIgrtll - Apply when planll III 8 to 10 1ndItI1II. "nagrow\h OCCUII. make • aecond appIicIlion. Wild 0111- Apply when pIanta III 2 to 81nd1t1111. Additional po.lemergenee Irllimeni. Ir. rtQVired 10 conlrol n" _:gillg pIInIa.

• • l1li1...., we.-01 no .... 11M 10 ftIIr __ .. 4D __ 01 .... per acre. "I tilt nllCltd lilt ol·~ (1.5 • 2.0 pinta per acre) In tilt 1* Icrl IprlY volulllt choltn (10 • 40 gill): Idd I nonphylololic petroleum 011 concenlrall II 1 ~ volumtlvolulllt (4 qulrll per 1 DO pions 01 Wlter) 10 tilt spray mil. Do nol UII vagNble 0lil. Use lilian nozztes ~ thoroughly COVII tilt WNd 1oIiIge. NOTE: Do not IIIow IPIlIJ 10 drift on 10 adjIctnl cropt • Injury 10 plants othtr than ...... willitlly occur. ( ... IPRAY DRIFT) SPRAY DRIFT Do nol .uow IPI'ey 110m either ground or ..,iII equipmenl to drill onto adjlcenl crops or lind. IS injulY 10 other pllinll may OCCUI. When spraying adjlcenllo crOPI Othll than lOybelns. minimize the spray drift pclenlill. Follow these practiceI to minimize IPI'ey drill: o Stop spraying If wind speed becomel IICessive. Sprey drift can OCCUI II wind speeds less than 10 MPH. Do nol apray H sensitive cropsal, downwind. DO NOT SPRAY IF WINDS ARE GUSTY. o High lemperllUfes. drough~ and low relltive humidity increese the possibility 01 spray drift. EXTREME CAUTION MUST BE USED WHEN THESE CONDITIONS ARE PRESENT AND SENSITIVE CROPS OR PLANTS ARE NEARBY. REGARDLESS OF WIND SPEED. ° Do not eppIy when a temperature inversion tlisls. An inversion is chal.ctelized by low ail movement .nd an increne in ail temperatUfe with In increase in altitude. In humid regions, I tog 01 mist mey form. An inversion may be detected by producing a smoke column and checking lor allyering effect. Smoke-produCing devices on airclaft are recommended. II not lure whether inversion conditions are present. conaun with local wuther services before making an sppIication. ° Drift from IllIaI or ground equipment may be further reduced by:

1. Using lalge droplet lize sprays to minimize drift. Do not ule nozzles thaI produce very amaH droplell, such • tHbIast-type nozzles. Nozzlellhoulcl be oriented II an angle between IIrIight down Ind Itraight bact< lor ground applications. For lerill IIJPIicationl orient noulelillraight bad< along the windstream. H uling llood-type nonl" on aircraft, orient tham 10 tpIlY Is produced in direction 01 tilt airltrtam.
2. Jnc:teuing volume 01 spray mil per acre (for eumpIe, 10 GPI' by air, 25 GPI' by ground) by using higher flow rail nozzles.
3. Reduc:iIg pmIIIfe (PSI). Do not IIeeed 40 psi when applying ·AIM~. (VehiI:Ie speed IIIUII also bI rIICIuced to maintain spray milllDlMme per acre.) Consult manufaclurer'1 cataiogI for dellill on correct calibration.
4. Apply • do .. 10 targeI plants • poaibIt whitt ItiI maintaining I good spray Pltltrn. TiiiOiiAiEiNDDiiPOiAir-----;( oF')? STORAGE AND DISPOSAL 11OMGI: Do Il0l''10 iii,,*,,,,,, bIIOw 32 __ F. Do not conIaminIII .... , load or fIICI by ItorIgt or dlIpouI. Kelp from contact with fIrIIIiz.II, lnaactickltl. fuliglc:klll. and MIdI during 1IoIIge. PRODUCT DIIIPOIAL: P I'cldet.spray mixUt, or rinlalllIaI cannot bI!IIed ICCOIdi, to IIIbIIInIN:tonI iIIiII bI dill .... 01 ~, 10 11,-IIiII FtdIIII, .... or local p!OOIIUa CONTAINER DIIPOIAL: _ rinIe (or equivaIInt) and cIIpoae 01 in I unltlry landfill or by incineralion il allowed by SIlt. Ind local auIIoriIiII. NOTiCE TO BUYER: Pulchase 01 this matllial doll not confer Iny righII under PIIInII 01 countries ouIIide 01 tilt United States. NonCE OF WARRANTY Du P!d .... lIaItIis pnxb:t oonlonnl to the dIIIIIicaI ~ on the\lbel fIereoI and 1I-.IlIy It for tilt purpoIM IIaIed on such libel rrit when used in acconIIia with the drecionI under normal use conditions. 1\ II impoIaIbIe to eliminate" riIIcJ !n.'1tretllly lIIOCiated with th. use 01 thil product. CrOP injUfY. ineffectivene .. , or other uninlended consequences may "lull because 01 such lactors as wather condIioIlI, praence 01 other materials, or the manner 01 use or lIlPIicaIion ... 01 whic:h .. beyond fle control 01 Du Pont in no cue shaI 011 Pont bliiable lor c:onaequenUI. special or indirec:I damages resulting from the use or handling 01 this product. AI such risks are assumed by Ihe buyer. DU PONT MAKES NO WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICUlAR PURPOSE NOR ANV OTHER EXPRESS OR IMPUEtI WARRANTY EXCEPT AS STATED ABOYE. AG· 5380 9021 215191 011111 E.L DU PONT DE NEMOURS AND COMPANY, ~LTURAL PRODUCTS, WILlINGTON, DELAWARE 1. e