crop-chem-docs/corpus/epa_ppls/352-694.md

TENN-COP 5E

• EPA Reg No: 352-694
• Registrant: CORTEVA AGRISCIENCE, LLC
• Signal word: Caution
• Active ingredients: Copper salts of fatty and rosin acids (58%)
• Label accepted: 2003-10-21
• Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/001812-00381-20031021.pdf

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18/;. - 31 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY WASHINGTON, D.C. 20460 W.A. Hawkin,. Jr .. Ph.D. Senior Regi-.lraliul1 Manager Copper Products. Insecticides and State Affairs Griffin L.L.'.' P.O. Box 1817 Valdosta. (j\ 31603-1847 Subject: I"enn-Cop® 5E EPA Reg. No. 1812-381 Y l)Ur amendment dated July 31,2003 Dear Dr. Ha\ kins: OFFICE OF PREVENTION, PESTICIDES AND TOXIC SUBSTANCES The amended bilel referred to above, submitted in connection with registration under the Federal Insecticide. J'ungicide and Rodenticide Act as amended is acceptable provided the following change is made: Add the ,(atement "Contains petroleum distillates, xylene or xylene range aromatic solvent" immediatelv below the ingredient statement as a footnote to the inert ingredients. One copy or the label stamped "Accepted with comments" is enclosed for your records. Please submit one copy of the linal printed label that incorporates the required changes before the product is released for shipment. If you have an) questions. please contact Robert Westin by phone at (703) 305-5721 or via email at westin.robcrt:{l I.?pa.gov. Enclosure Sincerely, Cynthia Giles-Parker Productanager(22) Fungicide Branch Registration Division (7505C)

07/231O~ Tenn-Cop!\1 5E g38l s03a FUNGICIDE/BACTERICIDE EMULSIFIABLE LIQUID Active Ingredient Copper salts offatty and rosin acids* ................ 58.0% Inert Ingredients ................................. 42.0% Total ......................................... 100.0% A-CCfCT'HO"D with C.OMMENTS In EPA l..£J±.ey ill>_J: (X...-1 ?-I ).00) (* Metallic Copper equivalent 5.14%) KEEP OUT OF REACH OF CHILDREN CAUTION .. :. ·· ... ,,:,1, 'J'~ <281 ' .. " .. at..,.;..; ··:·;--=-=ATEMENT OF PRACTICAL TREATMENT IF Opt..t SKIN. \Vdsh with pieHty of soap dnd walcI. Get 1I1cdicai attention. IF S"llALLO,lED. Dlillk PIOlllptly a lalge quantity DEutilk, egg whites, 01 gelatitt solutiOll, 01, iflhesc die not avaHablc, drink large quantities of wate!. Do not induce voruiting as it 11m, cause aspitatioll fJlICUllloniu. Avoid alcohol. Call a physician inllnediateiy. IF INIIALED. RCIllO"C victiul to flesh ail. ffnol bzcatiting, give rutificiailespitatioll, preferably [lIOULlltOI1lOuth. Get l11cdical atteutioll. IF IN EYES. Flush eyes with plenty of watel. Call a physician ifinitation persists. NOTE TO PHYSICIAN. FIRST AID IF ON SKIN OR • Take off contaminated clothing. CLOTHING: • Rinse skin immediately with plenty of water for 15 to 20 minutes. • CaB a poison control center or doctor for treatment advice. IF SWALLOWED: • Immediately caB a poison control center or doctor. • Do not induce vomiting unless told to do so by a poison control center or doctor. • Do not give any liquid to the person. • Do not I!ive anvthinl! bv mouth to an unconscious oerson. IF INHALED: • Move person to fresh air. • If person is not breathing, caB911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth, if possible. • Call a poison control center or doctor for further treatment advice. Griffin L.L. ( FP I Reg. So. /8/2-38/ File Name: g38/s03a 117:113 Page I or ~()

IF IN EYES: • Hold eye open and rinse slowly and gently with water for 15 to 20 minutes. • Remove contact lenses, if present, after ihe fIrSt five minutes, then continue rinsing eye. • Call a poison control center or doctor fortreatll1ent advice. Have the product container or label with you when calling a poison controlcter or doctor, or going for treatment. For medical emergencies involving this product, call ton free 1-888-324-7598. NOTE TO PHYSICIAN: Contains petroleum distillate - vonutingfuay cause aspiration pneumonia. See Label for Additional Precautions and Directions for use. GRIFFIN L.L.C. Valdosta, GA 31601 Griffin L.L. C. EPA Reg. No. 1812·381 Net Contents: ___ _ [End of Front Panel] File Name: g38/s03a 07103 EPA REG. NO. 1}2~381 EPA EST. NO. • ... ~ • . , . ) • · . ~ .. , • • .. ~. , • • • · , . . ' "" Poge 2 of 26 . .

PRECAUTIONARY STATEMENTS HAZARDS TO HUMANS (AND DOMESTIC ANIMALS) CAUTION Contains petroleum distillates. Causes skin irritation and moderate eye irritation. Hannful if swallowed. ubsorbed through the skin or inhaled. Avoid contact with skin, eyes or clothing. Avoid breathing spray mist. Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals. PERSONAL PROTECTIVE EQUIPMENT Applicators and other handlers must wear:

• Coveralls over short-sleeved shirt and short pants
• Chemical resistant gloves such as nitrile rubber, neoprene rubber or polyvinyl chloride
• Chemical resistant headgear for overhead exposure
• Chemical resistant apron when cleaning equipment, mixing, or loading
• Protective eyewear
• Shoes plus socks Discard clothing and other absorbent materials that have been drenched or heavily contar:llm:td with this product's concentrate. Do not reuse them. Follow manufacturer's instructions for cleaning/maintaining PPE. Ifno such instructions for washables, use detergent and hot water. Keep and wash PPE separately from other laundry. Engineering Controls Statement: When handlers use closed systems, enclosed cabs, or aircraft in a manner that meets the requirements listed in the Worker Protection Standard (WPS) for agricultural pesticides [40 CFR 170.240 (d) (4-6)], the handler PPE requirements maybe reduced or modified as specified in the WPS. USER SAFETY RECOMMENDATIONS Users should:
• Wash hands before eating, drinking, chewing gum, using tobacco or using the toilet.
• Remove clothing immediately if pesticide gets inside. Then wash thoroughly and put on clean clothing. ENVIRONMENTAL HAZARDS This pesticide is toxic to tish and aquatic organisms. Do not apply directly to water, or to areas where surbce water is present or to intertidal areas below the mean high water mark. Do not contaminate water when disposing of equipment washwaters. Griffin LLC hp·/ Rcs;;_ So. fSI2-3fi! File Name: g381s03a 07/0J !'age 3 of 2fj

PHYSICAL OR CHEMICAL HAZARDS Combustible. Do not use or store near heat or open flame. DIRECTIONS FOR USE It is a violation of Federal Law to use this product in a manner inconsistent with its labeling. Do not apply this product in a way that will contact workers or other persons, either directly or through drift. Only protected handlers may be in the area during application. For any requirements specific to your State or Tribe, consult the agency responsible for pesticide regulation. AGRICULTURAL USE REQUIREMENTS Use this product only in accordance with its labeling and with the Worker Protection Stan'.h~<j, 40 CFR part 170. This Standard contains requirements for protection of agricultural worer (In farms, forests, nurseries, and greenhouses and handlers of agricultural pesticides. It contains requirements for training, decontamination, notification, and emergency assistance. It alsc contains specific instructions and exceptions pertaining to the statements on this label aboul personal protective equipment (PPE) and restricted-entry interval. The requirements in tt.is Lor; only apply to uses of this product that are covered by the Worker Protection Standard. Do not enter or allow worker entry into treated areas during the restricted-entry interval (REI) of 12 hours. PPE required for early entry to treated areas that is permitted under the Worker Protection Standard and that involves contact with anything that has been treated, such as plants, soil, or water, is:

• Coveralls over short-sleeved shirt and short pants
• Chemical resistant gloves such as nitrile rubber, neoprene rubber or polyvinyl chloride
• Chemical resistant headgear for overhead exposure
• Protective eyewear
• Shoes plus socks NON-AGRICULTURAL USE REQUIREMENTS The requirements in this box apply to uses of this product that are not within the scope of the Worker Protection Standard for agricultural pesticides (40 CFR Part 170). The WPS applies when this product is used to produce agricultural plants on farms, forests, nurseries or greenhouses. Keep unprotected persons out of treated area until sprays have dried. Griffin L.L.(", EPA Re~, .Vo. 1812-381 File Name: g38Js03a 07103 Page.J of 2fi

STORAGE AND DISPOSAL Do not contaminate water, food or feed by storage or disposal. PESTICIDE STORAGE: Store in a cool, dry, secure place away from fire or open flame. Keep container closed and reseal after use. Product is not damaged by freezing, but preferably store at temperatures above 32° F. Ifspilled, use absorbent materials and dispose of in an approved landfill. PESTICIDE DISPOSAL: Pesticide wastes are toxic. Improper disposal of excess pesticide, spray mixture or rinsate is a violation of Federal Law. If these wastes cannot be disposed of by use according to label instructions, contact your State Pesticide or Environmental Control Agency, or the Hazardous Waste representative at the nearest EPA Regional Office for guidance. CONTAINER DISPOSAL: Triple rinse (or equivalent). Then offer for recycling or reconditioning, or puncture and dispose of in a sanitary landfill, or by other procedures approved by state and local authorities, or plastic containers by incineration, or, if allowed by state and local authorities, by burning. Ifburned, stay out of smoke. GENERAL INSTRUCTIONS Tenn-Cop 5E may be applied up to day of harvest. Tenn-Cop 5E may be applied as an aerial, ground dilute or ground concentrate spray unless specifically directed otherwise in the specific crop use directions. The per acre use rate of Tenn-Cop 5E is applicable fOI" both dilute and concentrate spraying. Depending upon the equipment used and the specific crop, the spray volume applied per acre will differ. Refer to Minimum Recommended Spray Volume Table. Complete spray coverage is essential to assure optimum performance from Tenn-Cop 5E. When treating by aerial application or with low volume application equipment, unless you have had specific previous experience, it is advisable to test for compatibility and tolerance to crop injury prior to full scale commercial utilization. Consult the Tenn-Cop 5E label for specific rates and timing of application by crop. Where application rates and intervals are provided in a range (e.g. 4 to 6 pints and 7 to 10 days), higher rates and shorter intervals are recommended when rainfall is heavy and/or disease pressure is high. Use the higher rates for large mature tree crops. SPECIAL PRECAUTIONS

• Tenn-Cop 5E should not be applied in a spray solution having a pH ofless than 6.5 as phytotoxicity may occur.
• Do not tank mix Tenn-Cop 5E with Aliette® fungicide for use on any registered crops or Griffin L.L.C EPA Reg. No. 1812·381 File Name: g38Js03a 07103 Page5 of 26

ornamentals unless appropriate precautions have been taken to buffer the spray solution because severe phytotoxicity may result. Do not tank mix with products containing diazinon or thiophanate-methyl or with che1ated or liquid fertilizers. Use in accordance with the most restrictive oflabellimitations and precautions. No label dosage rates should be exceeded. This product cannot be mixed with any product containing a label prohibition against such mixing.

• This product may be reactive on masonry and metal surfaces such as galvanized roofing. Avoid contact with metal surfaces. Do not spray on cars, houses, lawn furniture, etc.
• Environmental conditions such as extended periods of wet weather, acid rain, etc. which alter the pH of the leaf surface may affect the performance ofTenn-Cop 5E resulting in possible phytotoxicity or loss of effectiveness.
• Agricultural chemicals may perform in an unpredictable manner when tank mixed, especially where several products are involved. Reduced effect on pests or crop injury may occur. Unless recommended on this label or by a statellocal expert, it is advisable to test for compatibility and potential crop injury prior to commerical use of a new tank mix; otherwise, tank mixing should not be undertaken.
• It must be determined if proper application equipment is available and if waste associated with its use can be properly handled. Agricultural chemicals are often reactive with the materials used in the construction of application equipment, such as aluminum, rubber and synthetic materials. This factor should be taken into consideration when selecting proper application equipment. It is necessary that all application equipment be thoroughly flushed with clean water after each day's use.
• Do not apply this product through any irrigation (chemigation) system using aluminum parts or components as damage to the system may occur. Such application is prohibited regardless of whether the irrigation system i~ flushed with water after use of this product.
• Apply this product only through one or more of the following types of systems: sprinkler, including center pivot, lateral move, traveler, big gun, or plastic pipe solid set system(s) which contain no aluminum parts or components. Do not apply this product through any other type of irrigation system.
• While volume is important in obtaining full spray coverage, often factors such as foliage density, environmental conditions and sprayer calibration have a greater impact. Always be sure that sprayers are calibrated to spray equipment manufacturer's specifications and environmental conditions are within those recommended by State and local regulatory authorities.
• When mixing, fill spray tank one-half full with water. Add Tenn-Cop 5E slowly to tank while hydraulic or mechanical agitation is operating and continue filling with water. When mixing with other products, wettable powders should be added first, followed in Griffin L.L. C. EPA Reg. No. 1812-381 File Name: g381s03a 07103 Poge 6 of 26

order by flowables and then emulsifiable concentrates, including Tenn-Cop 5E. Spreaders, stickers, nutrients, etc. should be added last. If compatibility is in question, use the Compatibility Jar Test before mixing a whole tank or contact your chemical supplier. Observe all precautions and limitations on the labels of all products used in mixtures. CROP CLASSIFICATION FIELD CROPS: Corn (Field), Peanut and Sugar Beet. SMALL FRUITS: Blackberry, Boysenberry, Dewberry, Loganberry, Raspberry and Strawberry. TREE CROPS: Apple, Avocado, Cherry (Sour), Citrus, Mango, Nectarine, Olive, Peach, Pecan, Walnut. VEGETABLES: Bean, Beet, Broccoli, Brussels Sprout, Cabbage, Cantaloupe, Carrot, Cauliflower, Celery, Cucumber, Lettuce, Muskmelon, Onion/Garlic, Pea, Pepper, Potato, Pumpkin, Spinach, Squash, Tomato and Watermelon. VINES: Grape. GREENHOUSE AND SHADE HOUSE CROPS: Tenn-Cop 5E may be used in greenhouses and shadehouses to control diseases on any crop on this label where physiology allows greenhouse or shadehouse culture. ORNAMENTALS: Species as listed. Minimum Recommended Spray Volume (Gallons Per Acre) When Applying Tenn-Cop 5E Aerial Ground Dilute Concentrate Citrus 10 800 100· Field Crops 3 20 Ornamentals 10 100 50 Small Fruits 5 150 50 Tree Crops 10 400 50 Vegetables 3 20 Vines 5 150 50

• Pesticide application equipment such as Curtec® or other similar sprayers which are capable of obtaining thorough coverage at low volumes may be used at as low as 20 gpa of spray volume. Griffin L.L.c. EPA Reg. No. 1812-381 File Name; g38/s03a 07103 Page 7 of 26

The following specific instructions are based on general application procedures. The recommendations of the State Agricultural Extension Service should be closely followed as to timing, frequency and number of sprays per season. FIELD CROPS Crop Disease Rate/Acre Use Instructions Com (Field) Southern Leaf 3 pts. Apply at first sign of disease. Repeat Blight (North at 10 to 20 day intervals or as needed Central States only) until com is mature. Peanut Sc1erotinia Blight, 8-18 pts. Apply at emergence, tea cup size and Stem Rot (broadcast) first bloom which are generally (suppression) 3-6 pts 10 to 14 day intervals. Use the high (l8-inch band) rate in fields with a history of severe disease. For most effective control, continue with the leaf spot spray program which follows. Leaf Spot, 3-4 pts. Apply at first sign of disease, usually Web Blotch 25 to 40 days after emergence. Repeat at 7 to 10 day intervals or as needed up to day of harvest. In tank mixes, apply 1 Y, pints of Tenn-Cop 5E plus 1 pint of Equus 720 or 2 to 3 pints ofTenn-Cop 5E with the recommended rate of other recommended, compatible fungicides. If Sclerotinia is a problem, make first application 10 to 14 days after the last Sclerotinia spray and continue until harvest. Use higher rates ofTenn-Cop 5E in leaf spot sprays when leaf spot is heavy or when Sclerotinia blight and stem rot infection is expected to be heavy. When above treatments are applied through an overhead sprinkler, be sure that good coverage is achieved. Sugar Beet Cercospora Leaf 3 pts. Apply at first sign of disease. Spot, Tenn-Cop 5E can be mixed with 2 Powdery Mildew pounds of sulfur (wettable or Griffin LL.C. EPA Reg. No. 1812·381 File Name: g38Js03a 07103 Page 8 of 26

----- -- -- ---- - -~~-~~~--- SMALL FRUITS Crop Disease Rate/Acre Blackberry. Anthracnose, 4-6 pts. Boysenberrv. Cane Spot, Dewberry. Leaf Spot, Loganberry. Yellow Rust Raspberry Strawberry Leaf Spot, 3-4 pts. Scorch TREE CROPS Crop Disease Rate Apple Fire Blight 2Y>-3 pIS. per 100 gal. (spray volume) Uri/Jin LL.(· :'."1'.-1 /in!,. .'0, /8/2-38/ File /'/ame: g381s03a t1owable) per acre. Repeat applications ofTenn-Cop 5E alone every 7 days or the Tenn-Cop 5E-sulfur tank mix every 10 to 14 days, depending on disease pressure. Use Instructions Apply when leaf buds begin to open. Repeat when t10wer buds show white and continue at 10 to 14 day intervals or as needed until harvest. Also make a post-harvest spray after pruning but before fall rains using 4 quarts per 100 gallons. Apply beginning when new growth starts and repeat at 7 to 10 day intervals or as needed until harvest. Use Instructions Tank mix Tenn-Cop 5E with recommended rate of Manzate 75DF or other recommended, compatible fungicide. Spray at silver tip and bud break and repeat on 3 to 5 day intervals or as needed up to petal fall. Use the lower rate if disease pressure is light and higher rate when conditions favor disease development. NOTE: Tenn-Cop 5E may cause severe russeting of Golden Delicious and similar susceptible apple varieties. Preferred use is on non-bearing trees or on processing varieties where fruit finish is not a concern. Treatment after leaves emerge may cause limited (}7,D3 P,H!,l' () ot' :!(i

Avocado Cheny (Sour) Citrus Mango Olive (/r~ffin LL C Anthracnose, Blotch (Ccrcospora Leaf Spot) Bacterial Canker (Pseudomonas s:vringae), Leaf Spot Brown Rot Blossom Blight Melanose Red Algae Anthracnose Olive Leaf Spot (Peacock Spot) 6 qts./acre 3 pts.!! 00 gal. (spray volume) 3 pts.!! 00 gal. (spray volume) 1'/8 -I Y, gal. in 10 gal. water (Aerial) 3 qts.!500 gal. water (Ground) 1 y, gal. in 500 gal. water 6 qts.!acre 6-9 qts.!acre U J J Reg. So 18/2-38/ File Name: g38Js03a defoliation of young leaves. Apply when bloom buds begin to swell. Repeat monthly until September. Apply in spring as buds begin to swell. Repeat at bud burst and weekly thereafter or as needed for up to 6 sprays. In fall apply a spray at both 10% and 80% leaffall. NOTE: Sprays after leaf emergence may cause some defoliation. Apply at popcorn, full bloom and at petal fall. During wet weather additional bloom sprays may be necessary. Apply I to 3 weeks after petal fall and repeat 4 weeks later. NOTE: Do not apply with oil as some defoliation may occur. Apply in spring as a preventative spray. Repeat in late summer to control new algae colonies. NOTE: Do not apply with oil as some defoliation may occur. Beginning when panicles are 2 inches long, apply weekly until fruit are set. Make additional applications monthly through September. Apply before fall rains begin. Make a second application in late winter or early spring before bud swell if disease is severe. fi7/03 I'age j(} 0/ _'(i /1/"1

J1~" Peach, Blossom Brown 6-9 qts.!acre Apply at leaffall and repeat in late Nectarine Rot, dormant up to bud swell and at pink Leaf Curl, bud. May be mixed and used with Shot Hole dormant spray oil. Do not apply after full bloom. Bacterial Spot 3 pts.!IOO gal. Apply at late dormant but no later water than late bud swell. y.; pt./ I 00 gal. Apply as a post-bloom cover spray. water Do not make more than 6 applications. NOTE: Slight defoliation and spotting ofleaves may occur. Pecan Phytophthora Blight 3-5 pts.!acre Begin application when nuts begin to (Shuck Rot, Kernel form and repeat at 10 to 21 day Rot), intervals or as needed through Zonate Leaf Spot September. Use higher rate and (suppression) narrower intervals during wet periods. Walnut Bacterial Blight 2 Yz gal./500 Apply beginning when leaflets start gal. water per to unfold and before 1 % pistillate acre blooms. Repeat weekly or as needed, especially during rainy periods. Four pints per 100 gallons of water is equal to 2 Yz gallons in 500 gallons of water per acre. VEGETABLES Crop Disease Rate/Acre Use Instructions Bean (Green, Bacterial Blight 3 pts. Apply by air, ground or sprinkler Dry) irrigation equipment beginning at trifoliate and continue at 7 to 10 day intervals or as needed up to day of harvest. Use 7 day intervals during wet weather. Beet Cercospora Leaf 3 pts. Apply at first sign of disease. Repeat (Red Table) Spot at 7 to 10 day intervals or as needed up to day of harvest. Griffin L.L. C. EPA Reg. No. 1812-381 File Name: g381s03a 07103 Page II of 26

Broccoli. Altemaria Blight. Y. pt. Apply beginning when disease is Brussels Downy Mildew expected and repeat at 7 to 10 day Sprout, intervals or as needed. Cauli flower NOTE: A slight reddening of older leaves may occur, especially in late fall. Do not spray when plants are under environmentally stressful conditions. Do not add spreader- stickers to spray. Cabbage Altcmaria Blight, I Y, pts. Apply beginning when disease is Downy Mildew expected and repeat at 7 to 10 day intervals or as needed. NOTE: A slight reddening of older leaves may occur, especially in late fall. Do not spray when plants are under environmentally stressful conditions. Do not add spreader- stickers to spray. Carrot Early Blight, 3-4Yz pts. Apply 2 weeks before disease usually Late Blight, appears. Repeat at 7 to 10 day Leaf Spot intervals or as needed up to day of harvest. Celery Bacterial Blight, 3 pts. Apply at first sign of disease. Repeat Early Blight at 7 to 10 day intervals or as needed up to day 0 f harvest. If disease pressure is heavy, use 3 pints tank mixed with recommended rates of Equus 720 or other recommended, compatible fungicide. Cucurbits Altemaria Blight, 3 pts. Apply 2 weeks before disease (Cantaloupe. Angular Leaf Spot, normally appears. Repeat at 7 to 10 Cucumber. Downy Mildew, day intervals or as needed up to day Muskmelon. Powdery Mildew, of harvest. Pumpkin. Scab Squash. Watermeloll) Lettuce Downy Mildew I Y,-3 pts. Apply at first sign of disease. Repeat at 7 to 10 day intervals or as needed (iri(fin LL. (' iT. I R'''! . .'0.1812-381 File ,Vame: g381s03a (}7/0J !'age 12 of ::6

-'''''"''''''~'. - ... ".",,-- I 'fJJ-7 up to day of harvest. Full season use of the 3 pint rate may result in some yellowing ofleaf margins on some varieties. Use lower rate when disease pressure is low or on copper sensitive varieties of iceberg head lettuce. Bacterial Soft Rot, 3 pts. Apply at first sign of disease. Repeat Bottom Rot at 7 to 10 day intervals or as needed (Hawaii only) up to day of harvest. Onion, Bacterial Soft Rot, 3 pts. Apply at first sign of disease or when Garlic Downy Mildew, conditions favor disease. Repeat Gray Mold, every 7 days or as needed up to day Neck Rot of harvest. Pea Bacterial Blight, 3-4 pts. Apply at first sign of disease or when Powdery Mildew conditions favor disease development. Repeat every 7 days up to day of harvest. Pepper Bacterial Spot, 3-4Y, pts. Apply 2 weeks before disease Cercospora Leaf normally appears. Repeat at 7 to 10 Spot day intervals up to day of harvest. Control of bacterial spot may be enhanced by adding the recommended rate of Manzate 75DF or other recommended, compatible fungicides to the tank mix. Potato Early Blight, 3 pts. Apply beginning when weather Late Blight conditions favor disease development and repeat every 7 days or as needed up to day of harvest. Spinach Anthracnose, 3-4 pts. Apply 2 weeks before disease Cercospora Leaf normally appears. Repeat at 7 to 10 Spot, day intervals or as needed up to day Downy Mildew of harvest. Tomato Anthracnose, 3 pts. Apply at first sign of disease. Repeat Bacterial Speck, at 7 to 10 day intervals or as needed Bacterial Spot, up to day of harvest. Control of Earl y Blight, bacterial speck and bacterial spot Grtffin L. L. ( . /;P j Reg ,'0, '812381 Fife Name: g381s()3a 07/0J !'age 13 ot' Hi

Grape Septoria Leaf Spot Disease Black Rot (suppression), Downy Mildew, Powdery Mildew VINES Rate/Acre 1 Y, -4Y, pts. may be enhanced by adding the recommended rate of Manzate 75DF or other recommended, compatible fungicides to the tank mix. Use Instructions For dilute spray, mix 1 Y, pints Tenn-Cop 5E per 100 gallons of water, or for concentrate sprays mix 3 to 4Y, pints in 20 to 250 gallons of water and apply to I acre. Begin applications when new growth is Y2 inch long. Repeat every 7 to 10 days or as needed throughout the growing season. NOTE: Do not mix with lime. Certain varieties and hybrids may be slightly sensitive to copper sprays, resulting in marginal leaf bum. GREENHOUSE AND SHADEHOUSE CROPS Notice to User: Tenn-Cop 5E may be used in greenhouses and shadehouses to control diseases on crops which appear on this label. The grower should bear in mind that the sensitivity of crops grown in greenhouses and shadehouses differs greatly from crops grown under field conditions. Neither the manufacturer nor seller has determined whether or not Tenn-Cop 5E can be used safely on all greenhouse and shadehouse grown crops. The user should determine ifTenn-Cop 5E can be used safely prior to commercial use. In a small area, apply the recommended rates to the plants in question, Le., foliage, fruit, etc., and observe for 7 to 10 days for symptoms of phytotoxicity prior to commercial use. Apply Tenn-Cop 5E according to specific rates given for those crops elsewhere on this label. One tablespoon of Tenn-Cop 5E per gallon is equivalent to 3 pints per 100 gallons. One tablespoon per 1,000 square feet is equivalent to one pint per acre. Tenn-Cop 5E should be applied in adequate water for thorough coverage of plant parts. Begin application at first sign of disease and repeat at 7 to 14 day intervals or as needed; use shorter interval during periods when severe disease conditions persist. Griffin LL. C EPA Reg. No. /811·381 File Name: g38Js03a 07103 Page 14 of 26

.. --, .-. -,,, .. ""'"",'"-""--""' .......•• __ ..... . ORNAMENTALS Use Tenn-Cop SE for control of bacterial and fungal diseases of foliage, flowers and stems on ornamentals in greenhouses, shadehouses, outdoor nurseries and outdoor landscape plantings. For ornamental plants, apply as a thorough cover spray using 3 pints ofTenn-Cop SE in 100 gallons of water. Spray foliage and stems to run-off. For application to small areas, use one tablespoon of Tenn-Cop SE per gallon of water. One tablespoon of Tenn-Cop 5E per gallon is equivalent to 3 pints per 100 gallons of water. Begin application at first sign of disease and repeat at 7 to 14 day intervals or as needed; use shorter interval during periods of frequent rains or when severe disease conditions persist. Tenn-Cop 5 E may be used alone or in combination with other fungicides registered for use on ornamentals as a maintenance spray. Use in accordance with the most restrictive oflabel limitations and precautions. No label dosage rates should be exceeded. This product cannot be mixed with any product containing a label prohibition against such mixing. Notice to User: Plant sensitivities to Tenn-Cop SE have been found to be acceptable for the specific genera and species listed on this label under the conditions tested. However, phytotoxicity may occur. Due to the large number of species and varieties of ornamental and nursery plants. and the wide range of growing conditions, it is impossible to test every one for sensitivity to Tenn-Cop SE. Neither the manufacturer nor seller has determined whether or not Tenn-Cop 5E can be safely used on ornamental or nursery plants not listed on this label. The user should determine if Tenn-Cop SE can be used safely prior to commercial use. In a small area, apply the recommended rates to the plants in question, i.e., bedding plants, foliage, etc., and observe for 7 to 10 days for symptoms of phytotoxicity prior to commercial use. NOTE: This product may be reactive on masonry and metal surfaces such as galvanized roofing. Avoid contact with metal surfaces. Do not spray on cars, houses, lawn furniture, etc. Scientific N arne Aglaonema Aglaonema spp. Althea (Rose of Sharon) Hibiscus syriacus Andromeda, Japanese Pieris japonica Aralia Dizygotheca elegantissima Arborvitae Thuja spp. Gr!ffin LL. (' FP·r Re'l,. _Vo, /811-38/ File Name: g38/s03a (17/03 Disease Bacterial Leaf Spot Bacterial Leaf Spot Leaf Spots, Twig Blight Alternaria, Cercospora Leaf Spot, Xanthomonas Leaf Spot Alternaria Twig Blight, Cercospora Leaf Blight I'a:~t' 15 of 20

Aster Azalea l' Beech Begonia Bougainvillea Boxwood Camellia Camphor Tree Canna Camation 1/ Cedar Chinese Tallow Tree Chrysanthemum II Cotoneaskr (iritf/n LL (. !:'/',·I Reg. So, 1812-381 Aster spp. Rhododendron spp. Fagus spp. Begonia semperflorens Bougainvillea spectabilis BuXl/s spp. Camellia japonica. C. sasanqua Cinnamomum camphora Canna spp. Dianthus spp. Cedrus spp. Sapium sebiferum Chrysanthemum morifolillm Cotoneaster spp. File Name: g38/s()3a 07/03 Downy Mildew. Leaf Spots Botrytis Blight, Cercospora Leaf Spot, Phytophthora Dieback, Powdery Mildew Leaf Spots Anthracnose, Bacterial Leaf Spot (Xanthomonas spp., Erwinia spp., Pseudomonas spp.), Powdery Mildew Anthracnose, Bacterial Leaf Spot Leaf Spots Anthracnose, Bacterial Leaf Spot, Phytophthora Dieback Pseudomonas Leaf Spot Pseudomonas Leaf Spot Alternaria Blight, Botrytis Blight, Pseudomonas Leaf Spot Tip Blight Bacterial Leaf Spot (Xanthomonas spp., Pseudomonas spp.) Bacterial Blight, Botrytis Blight, Pseudomonas Leaf Spot, Septoria Leaf Spot Botrytis Blight [)age j (i or 36

Islt? Crabapple Malus spp. Fire Blight Cypress Cupressus spp. Twig Blight Dahlia Dahlia pinnata Alternaria Leaf Spot, Botrytis Gray Mold, Cercospora Leaf Spot Delphinium Delphinium spp. Leaf Spots Dianthus Dianthus spp. Bacterial Soft Rot, Bacterial Spot Dogwood Comus florida Anthracnose Douglas Fir Pseudotsuga menziesii Rhabdocline Needlecast Dracaena Dracaena marginata Bacterial Leaf Spot Dumb Cane Dieffenbachia spp. Bacterial Leaf Spot Dusty Miller Senecio cineraria Bacterial Leaf Spot (Pseudomonas cichorii) Echinacea Echinacea spp. Bacterial Leaf Spot (Pseudomonas cichorii) Elm, Chinese Ulmus parvifolia Xanthomonas Leaf Spot Euonymus Euonymus spp. Anthracnose, Botrytis Blight Fern, Boston Nephrolepis exaltata Bacterial Leaf Spot Fern, Holly Cyrtomium fa/catum Pseudomonas Leaf Spot Fig, Weeping Ficus benjamina Bacterial Leaf Spot Filbert (Ornamental) Cory/us spp. Filbert Blight Gardenia Gardenia jasminoides Alternaria Leaf Spot, Bacterial Blight, Botrytis Bud Rot, Cercospora Leaf Spot Griffin L L C. EPA Reg. No. 1812-381 File Name: g38Js03a 0710J Page 17 of 26

19/?-1 Geranium Pelargonium spp. Alternaria Leaf Spot, Botrytis Gray Mold, Cercospora Leaf Spot Gladiola Gladiolus spp. Alternaria Leaf Spot, Anthracnose, Bacterial Leaf Blight, Botrytis Gray Mold Golden R1J1 Tree Koelreuteria paniculata Bacterial Leaf Spot Grape Iv\ Cissus spp. Bacterial Leaf Spot Hawthorn Crataegus spp. Fire Blight Hibiscus :±' Hibiscus spp. Bacterial Leaf Spot Holly Ilex spp. Bacterial Blight, Leaf Spots Honeylocllst Gleditsia triacanthos Bacterial Leaf Spot Hydrangc:! Hydrangea spp. Leaf Spots, Powdery Mildew Impatiens Impatiens sa/lerana Bacterial Leaf Spot Indian H\Vthorn if Raphiolepis indica Anthracnose, Entomosporium Leaf Spot Iris fl.1 Iris spp. Bacterial Leaf Spot Ivy (English. Algerian) 11 Hedera helix, H. canariensis Xanthomonas Leaf Spot Ixora Ixora coccinea Leaf Spots Juniper Juniperus spp. Anthracnose, Cedar Apple Rust, Cercospora Needle Blight, Twig Blight Lantana Lantana camera Bacterial Leaf Spot Leyland CYllrcss X Clipressocyparis leylandii Cercospera Needle Blight Griffin LL. (. 1:1' I Reg. "'0. 1812-38/ File Name: g381s03a OJ.'(J3 Page 18 ot' 26

Lilac Lily, Easter ;,; Linden Loblolly Bay Loquat Magnolia Mandevilla Maple Marigold Mountain-Ash Mulberry (Ornamental) Narcissus Nephthytis Oak Oak, Laurel Oleander Oregon Grapeholly Griffin L. L. C I:p., Rtf,f.!. So. 181]-381 Syringa spp. Lilium longiflorum Tilia spp. Gordonia lasianthus Eriobotrya japonica Magnolia spp. Mandevilla spp. Acer spp. Tagetes spp. Sorb us spp. Morus spp. Narcissus spp. Syngonium podophyllum Quercus spp. Quercus laurifolia Nerium oleander Mahonia acquifolium File //ame: g38/s03a 07/0] Cercospora Leaf Spot Botrytis Blight Anthracnose, Leaf Blight Anthracnose Colletotrichum spp., Entomosporium maculata Algal Leaf Spot, Anthracnose, Bacterial Leaf Spot Anthracnose Anthracnose, Leaf Spots, Pseudomonas Leaf Blight Alternaria Leaf Spot, Botrytis Leaf Rot, Cercospora Leaf Spot, Flower Rot Fire Blight Bacterial Leaf Spot Leaf Blight Bacterial Leaf Spot Anthracnose, Leaf Spots Algal Leaf Spot (Cephaleuros virescens) Bacterial Leaf Spot, Fungal Leaf Spot Leaf Spots Page /9 oj" 26

Pachysandra Palm, Date Palm, European Fan Palm, Parlor Palm, Queen Palm, Washingtonia Peach (Flowering) JI Pear (Flowering) Pentas (Egyptian Star) Peony Periwinkle Philodendron Phlox Photinia (Red Tip) Pine Pistachio Plantain Lily Q/ Plum (Flowering) 3.1 Griffin L.L.c. EPA Reg. No. 1812·381 Pachysandra procumbens Phoenix canariensis Chamaerops humilis Chamaedorea elegans Arecastrum romanzoJfianum Washingtonia robusta Prunus spp. Pyrus calleryana Pentas spp. Paeonia spp. Catharanthu.5 roseus, Vinca spp. Philodendron selloum Phlox spp. Photinia x fraserii. P. glabra Pinus spp. Pistacia chinensis Hosta spp. Prunus spp. File Name: g38Js03a 07/03 Volutella Leaf Blight Pestalotia Leaf Spot Pestalotia Leaf Spot Bacterial Leaf Spot Exosporium Leaf Spot, Phytophthora Bud Rot Pestalotia Leaf Spot Bacterial Blast, Brown Rot, Fire Blight Fire Blight, Leaf Spot Bacterial Leaf Spot (Xanthomonas spp.) Botrytis Blight Phomopsis Stem Blight Bacterial Blight, Bacterial Leaf Spot Alternaria Leaf Spot Anthracnose, Entomosporium Leaf Spot Diplodia Tip Blight, Dothistroma Needle Blight Anthracnose Bacterial Leaf Spot Bacterial Blast, Brown Rot, Page 20 of 26

Poinsettia Pothos Powder PufTPlant Pyracanth a Rhododendron Rose 11 Snapdragon Spathe Flower Spirea Spruce Sycamore Tatarian Honeysuckle Tulip Umbrella Tree Verbena Viburnum Viola (Pansy, Violet) Willow GrilJin LL ( . i:P-/ [«('g. Vo. 1812-381 Euphorbia pulcherrima Scindapsus spp, Calliandra spp. Pyracantha spp. Rhododendron spp. Rosa spp. Antirrhinum majus Spathiphyllllm spp. Spiraea spp. Picea spp. Platanus occidentalis Lonicera tatarica Tulipa spp. SchefJlera spp. Verbena spp. Viburnum odoratissimum, V plicatllm, V suspensum Viola spp. Salix spp. File Name: g38/s03a 07103 Fire Blight Botrytis Blight, Powdery Mildew Bacterial Leaf Spot Bacterial Leaf Spot Fire Blight, Scab Alternaria Flower Spot Black Spot, Powdery Mildew Anthracnose, Dieback, Downy Mildew Bacterial Leaf Spot Fire Blight Needle Casts Anthracnose, Leaf Spots Bacterial Leaf Spot Anthracnose, Botrytis Blight Bacterial Leaf Spot Xanthomonas Leaf Spot Anthracnose Downy Mildew Anthracnose Page 21 of 26

Yew Taxus spp. Needle Blight Yucca (Adam's Needle) Yucca spp. Cercospora Leaf Spot, Septoria Leaf Spot Zinnia Zinnia spp. Leaf Spots 11 Discoloration of blooms may occur on certain varieties or colors of these plants. To avoid this problem, do not spray just before or during flower period. 21 Apply Tenn-Cop 5E at 5 to 6 pints per 100 gallons of water. J/ Apply dormant through bloom only. 11 Hibiscus - Do not apply to plants in flower. 2/ For Indian Hawthorn use 4 to 5 pints per 100 gallons of water. fl.1 Some cultivars may be sensitive to Tenn-Cop 5E. NOTE: Phytotoxicity may depend on varietal differences. Ifunfamiliar with the use ofTenn­ Cop 5E, apply the recommended rate to a few plants and observe after 7 to 10 days for symptoms of phytotoxicity. GENERAL CHEMIGATION INSTRUCTIONS Do not apply this product through any irrigation (chemigation) system using aluminum parts or components as damage to the system may occur. Such application is prohibited regardless of whether the irrigation system is flushed with water after use of this product. Apply this product only through one or more of the following types of systems: sprinkler, including center pivot, lateral move, traveler, big gun, or plastic pipe solid set system(s) which contain no al uminum parts or components. Do not apply this product through any other type of irrigation system. Crop injury, lack of effectiveness or illegal pesticide residues in the crop can result from non-unifonn distribution of treated water. If you have questions about calibration, you should contact State Extension Service specialists. equipment manufacturers or other experts. Do not connect an irrigation system (including greenhouse systems) used for pesticide application to a public water system unless the pesticide label prescribed safety devices for public water systems are in place. Griffin LL C I:'P..I Reg. No. /812-381 File Name: g38/s03a Ol/OJ Page 2 2 (~r 16

A person knowledgeable of the chemigation system and responsible for its operation, or under the supervision of the responsible person, shall shut the system down and make necessary adjustments should the need arise. CHEMIGATION SYSTEMS CONNECTED TO PUBLIC WATER SYSTEMS Public water system means a system for the provision to the public of piped water for human consumption if such system has at least 15 service connections or regularly serves an average of at least 25 individuals daily at least 60 days out of the year. Chemigation systems connected to public water systems must contain a functional, reduced­ pressure zone, backflow preventer (RPZ) or the functional equivalent in the water supply line upstream from the point of pesticide introduction. As an option to the RPZ, the water from the public water system should be discharged into the reservoir tank prior to pesticide introduction. There shall be a complete physical break (air gap) between the outlet end of the fill pipe and the top or overflow rim of the reservoir tank of at least twice the inside diameter of the fill pipe. The pesticide injection pipeline must contain a functional, automatic, quick-closing check valve to prevent the flow of fluid back toward the injection pump. The pesticide injection pipeline must contain a functional, normally closed, solenoid-operated valve located on the intake side of the injection pump and connected to the system interlock to prevent fluid from being withdrawn from the supply tank when the irrigation system is either automatically or manually shut down. The system must contain functional interlocking controls to automatically shut off the pesticide injection pump when the water pump motor stops, or in cases where there is no water pump, when the water pressure decreases to the point where pesticide distribution is adversely affected. Systems must use a metering pump, such as a positive displacement injection pump (e.g., diaphragm pump) effectively designed and constructed of materials that are compatible with pesticides and capable of being fitted with a system interlock. Do not apply when wind speed favors drift beyond the area intended for treatment. NOTE: It must be determined if proper application equipment is available and if waste associated with its use can be properly handled. Agricultural chemicals are often reactive with the materials used in the construction of application equipment such as aluminum, rubber and synthetic materials. This factor should be taken into consideration when selecting proper application equipment. It is necessary that all application equipment be thoroughly flushed with clean water after each day's use. When mixing, fill nurse tank half full with water. Add Tenn-Cop 5E slowly to tank while hydraulic or mechanical agitation is operating and continue filling with water. When mixing Griffin L.L. C. EPA Reg. No. 1812-381 File Name: g38Js03a 07103 Page 23 of 26

with other products, wettable powders should be added first, followed in order by flowables and then emulsitiable concentrates, including Tenn-Cop SE. Stickers, spreaders, nutrients, etc. should be added last. If compatibility is in question, use the Compatibility Jar Test before mixing a whole tank. Because of the wide variety of possible combinations which can be encountered, observe all precautions and limitations on the labels of all products used in mixtures. Agitation of the mixture in the nurse tank is recommended. Tenn-Cop 5E should be added through a traveling irrigation system continuously or at the last 30 minutes of solid set o. hand moved irrigation systems. Shut off injection equipment after treatment and continue to operate irrigation system until Tenn-Cop 5E has been cleared from the last sprinkler head. SPRINKLER CHEMIGATION The system must contain a functional check valve, vacuum relief valve, and low pressure drain appropriately located on the irrigation pipeline to prevent water source contamination from backflow. The pesticide injection pipeline must also contain a functional, automatic, quick-closing check valve to prevent the flow of fluid back toward the injection pump. The pesticide injection pipeline must also contain a functional, normally closed, solenoid­ operated valve located on the intake side of the injection pump and connected to the system interlock to prevent fluid from being withdrawn from the supply tank when the irrigation system is either automatically or manually shut down. The system must contain functional interlocking controls to automatically shut off the pesticide injection pump when the water pump motor stops. The irrigation line or water pump must include a functional pressure switch which will stop the water pump motor when the water pressure decreases to the point where pesticide distribution is adversely atTected. Systems must use a metering pump, such as a positive displacement injection pump (e.g., diaphragm pump) effectively designed and constructed of materials that are compatible with pesticides and capable of being fitted with a system interlock. Do not apply when wind speed favors drift beyond the area intended for treatment. NOTE: It must be determined if proper application equipment is available and if waste associated with its use can be properly handled. Agricultural chemicals are often reactive with the materials used in the construction of application equipment such as aluminum, rubber and synthetic materials. This factor should be taken into consideration when selecting proper application equipment. It is necessary that all application equipment be thoroughly flushed with clean water after each day's use. Griffin LL C EPA Reg. No. 1812-381 File Name: g381s03a 07103 Page 24 of 26

-----------------~ -~- - r ( <. When mixing, fill nurse tank half full with water. Add Tenn-Cop SE slowly to tank while hydraulic or mechanical agitation is operating and continue filling with water. When mixing with other products, wettable powders should be added first, followed in order by flowables and then emulsifiable concentrates, including Tenn-Cop SE. Stickers, spreaders, nutrients, etc. should be added last. If compatibility is in question, use the Compatibility Jar Test before mixing a whole tank. Because of the wide variety of possible combinations which can be encountered, observe all precautions and limitations on the labels of all products used in mixtures. Agitation of the mixture in the nurse tank is recommended. Tenn-Cop SE should be added through a traveling irrigation system continuously or at the last 30 minutes of solid set 01 !tmld IlIovcd irrigation systems. Shut off injection equipment after treatment and continue to operate irrigation system until Tenn-Cop SE has been cleared from the last sprinkler head. SPECIAL USE DIRECTIONS FOR SPRINKLER APPLICATION OF TENN-COP 5E To apply Tenn-Cop SE and/or tank mixes with it through a sprinkler irrigation system, apply the recommended rate to each sprinkled acre. Any sprinkler irrigation system must give thorough, complete and uniform coverage for best disease control. Use irrigation and injection equipment that complies with label instructions above. Depending on the type of injection equipment, Tenn-Cop SE may be injected into the irrigation line either undiluted or diluted with water for easier metering. The preferred method is to dilute the required volume ofTenn-Cop SE with an equal or greater volume of water in the supply tank. When mixing, add water to the supply tank first. Then slowly add Tenn-Cop SE to the tank while hydraulic or mechanical agitation is operating. Use sufficient initial agitation to effect mixing, and continue agitation during application. If tank mixed with other compatible products, add them to the water with agitation by first adding wettable powders, flowables and then emulsifiable pesticides, including Tenn-Cop SE. When Tenn-Cop SE is used undiluted, the supply tank must be free of any water residue and no water should enter the tank until Tenn-Cop SE has been completely emptied, as gelling may occur. If gelling occurs, add additional water so that the water volume at least equals the amount ofTenn-Cop SE remaining and mix until gel returns to solution. If this dilution step is necessary, recalibrate injection device to compensate for the dilution. Tenn-Cop SE may be applied with up to I Y:z inches of irrigation water per acre. To avoid runoff, do not exceed irrigation rates for your soil. Griffin LL C. EPA Reg. No. 1812-381 File Name: g38Js03a 07103 Page 25 of 26

r WARRANTY STATEMENT GRIFFIN warrants that this product confonns to the chemical description on the label thereof and is reasonably fit for purposes stated on such label only when used in accordance with directions under nonnal use conditions. It is impossible to eliminate all risks inherently associated with use of this product. Crop injury, ineffectiveness or other unintended consequences may result because of such factors as weather conditions, presence of other materials or the manner of use or application, all of which are beyond the control of GRIFFIN. In no case shall G·RJI1FIN be liable for consequential, special or indirect darnagesresulting from the use or handling of this product. All such risks shall be assumed by the Buyer. The exclusive remedy of any buyer or user of this product for any and all losses, injuries, or damages resulting from or in any way arising from the use, handling, or application of this product, whether in contract, warranty, tort, negligence, strict liability, or otherwise, shall not exceed the purchase price paid for this product or at GRIFFIN'S election, the replacement of this product. GRIFFIN MAKES NO WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE NOR ANY OTHER EXPRESS OR IMPLIED WARRANTY EXCEPT AS STATED ABOVE. Aliette is a registered trademark of Rhone-Poulenc. Curtec is a registered trademark of Curtec Corporation. Equus is a trademark of Griffin L.L.C. Griffin and Design are a registered trademark of Griffin Corporation. Manzate is a registered trademark ofE.1. duPont de Nemours and Company Tenn-Cop is a registered trademark of Griffin Corporation. [Based on EPA stamped accepted label dated January 19, 2001] Griffin LLC EPA Reg. No. 1812-381 File Name: g381s03a 07103 Page 26 of 26