crop-chem-docs/corpus/epa_ppls/8033-124.md

TOPSIN M 85 WDG

• EPA Reg No: 8033-124
• Registrant: NIPPON SODA CO., LTD.
• Signal word: Caution
• Active ingredients: Thiophanate-methyl (85%)
• Label accepted: 2009-12-15
• Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/073545-00015-20091215.pdf

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) UNITED STATES ENVIRONMENTAL PROTECTION AGENCY WASHINGTON, D.C. 20460 Mr. Timothy M. Formella Agent for Nisso TM LLC United Phosphorus, Illc. 630 Freedom Business Center, Suite 402 King of Prussia, PA 19406 OFFICE OF PREVE~nON. PESnCIDES AND TOXIC SUBSTANCES DEC 1 5 2009 Subject: Label Notification(s) for Pesticide Registration Notice 2007-4, 2001-5 and 98-10 Dear Registrant: The Agency is in receipt of your Application(s) for Pesticide Notification under Pesticide Registration Notice (PRN) 2007-4,2001-5, and 98-10 dated October 16,2009 for: EPA Registration 73545-15 Topsin M 85 WDG The Registration Division (RD) has conducted a review of this request for applicability under PRN 2007-4 ,2001-5, and 98-10, and finds that the label change(s) requested falls within the scope ofPRN 2007-4, 2001-5 and 98-10.The label has been date-stamped ''Notification'' and will be placed in our records. Please be reminded that 40 CFR Part 156.140(a)(4) requires that a batch code, lot number, or other code identifying the batch of the pesticide distributed and sold be placed on nonrefillable containers. The code may appear either on the label (and can be added by non-notificationiPR Notice 98-10) or durably marked on the container itself. If you have any questions, please call me directly at 703-305-6249 or Banza Djapao of my staff at 703-305-7269. Sincerely, 't -- ~ Linda Arrington Notifications & Minor Formulations Team Leader Registration Division (7505P) Office of Pesticide Programs

Please read instructions on reverse before compleung form. Form Approved, OMS No. 2070-0060, Approval expires 05-31-98 ~ EPA United States 0 Registration opp Identifier Number 0 Environmental Protection Agency 0 Amendment Washington, DC 20460 ~ Other: Application for Pesticide - Section I

1. Company/Product Number 2. EPA Product Manager 3. Proposed Classification 73545-15 Shaja Joyner
2. Company/Product (Name) PM# lZl None D Restricted Topsin M 85WDG 1
3. Name and Address of Applicant (Include ZIP Code) 6. Expedited Review. In accordance with FIFRA Section 3(c)(3) Nisso TM LLC d/b/a United Phosphorus, Inc. (b)(I), my product is similar or identical in composition and labeling 630 Freedom Business Center, Suite 402 to: King of Prussia, PA 19406 EPA Reg. No. , D Check if this is a new address Product Name Section - II _. _DO 0 Amendment - Explain below. o Final printed labels in respU"J .!.U\d 0 Resubmission in response to Agency letter dated o "Me Too" APpication DEC 1 5 2009 ~ Notification - Explain below. o Other - Explain below Explanation: Use additional page(s) if necessary. (For Section I and Section II.) Notification of label change per PR Notices 2007-4 and 2001-5, and PR Notice 98-10. This notification is consistent with the guidance in PR Notices 2007-4 and 2001-5, and the requirements of EPA's regulations at 40 CFR §§ 152.46, 156.10, 156.140, 156.144, 156.146, and 156.156. No other changes have been made to the labeling or the Confidential Statement of Formula for this product. I understand that it is a violation oU8 U.S.C. Sec. 1001 to willfully make any false statement to EPA. I further understand that if the amended label is not consistent with the requirements of 40 CFR §§ 152.46, 156.10, 156.140, 156.144, 156.146, and 156.156, this product may be in violation of FIFRA and I may be subiect to enforcement action and penalties under sections 12 and 14 of FIFRA. Section - III
4. Material This Product Will Se PackaQed In: Child-Resistant Packaging Unit Packaging Water Soluble Packaging 2. Type of Container DYes' DYes o Yes o Metal ~ No ~ No ~ No o Plastic If "Yes" No. per If "Yes" No. per o Glass *Certification must Unit Packaging wgt. container Package wgt. container ~ Paper be submitted o Other
5. Location of Net Contents Information 4. Size(s) Retail Container 5. Location of Label Directions ~ Label o Container 2 Ib paper bags ~ On Label o On labeling accompanying product
6. Manner in Which Label is Affixed to Product o Lithograph o Other: l'8J Paper glued o Stenciled Section -IV
7. Contact Point (Complete items directly below for identification of individual to be contacted, if necessary, to process this application) Name Title Telephone No. (Include Area Timothy M. Formella Senior Registration Manager Code) " :> 61'D491 :2813 Certification .) .J ,,!, ) " 6. Dae Application I certify that the statements I have made on this form and all attachments thereto are true, accurate and complete. 01 :J') Reeei'Jod acknowledge that any knowingly false or misleading statement may be punishable by fine or imprisonment or both ~ r ~ (Stamped) under applicable law. .) .J J, J J .J ) ) J :J j .J ) 2'1~ ?~
8. Title ) l .J .J ) J \ - ~. Senior Registration Manager i) :J J J .J U .) ..) J J ~I J J ~) .l ,)
9. iyped NamE!:, 5. Date .- :> od J ) J Timothy M. Formella It( cJOU? J.J J.; .J J.J d 'J .) " .!a .. :.; EPA Form 8570-1 (Rev. 8-94) PrevIous editions are obsolete Whlte- EPA File Copy (onglnal) .) Yelo)w- Applicant Copy J J .J ... , J .J .J

United Phosphorus, Inc. Qctober 16,2009 VIA: United Parcel Service Document Processing Desk (NOTIF) Linda Arrington Office of Pesticide Programs (7504P) US. Environmental Protection Agency Room S-4900, One Potomac Yard 2777 South Crystal Drive Arlington, VA 22202-4501 RE: Notification Regarding PR Notices 2007-4 and 2001-5 Topsin M 5D EPA Reg. No. 73545-12 Topsin M 5G EPA Reg. No. 73545-14 Topsin M85WDG EPA Reg. No. 73545-15 Q¢!ir Ms,.' AriingtQn: . tJni~~d:Pl1Qspliqtus; Inc. as agent for Niso TM LLC hereby notifies the Agency of our intent to revise the labels fQr.:ii.i.frnbe·ofo,!,lr 'registered pesticide products containing the active ingredient thiopanate-methyl. '.tJiS~!:l:aH~·;';!fliions include revision of the Storage and Disposal text in ordeno comply with the ::'req.41: .. ,l"""~~'" of'I?R):'J"Qtice.?007-4 regarding Labeling Revisions Required by the Final R,u,le "Pesticide M~'mgerrierit and Disposal; Staila:ds fQ'r· Pesticide Containers and Containment." In a.ddition, per the Agency gtiidance in .pRN9!,ice 2001-5, th Fungicide Resistance Action Committee (FRAC) m,ode of action group code has been agdedt<J'Jhe first page of these labels. The warranty statement,s on tWo of these labels (73545-14 and 73545-15) have 1:0 been moqified. These changes are consistent with the notification provisions ofPR Notice 98-10 and EPA regulations at 40 CFR'152.46. Epclosed please find the following materials for each of the four products to support these registration notifi9ations:

1. Comple~e'(i Application for Pesticide Registration (EPA Form 8570-1)
2. A "red"liried" copy of the amended label showing the revisions being made
3. A clean copy version of the revised label
4. CD witb,th¢Jabels in electronic format (file names: 073545-00012.20091016.pdf,073545- 000.14:@Q91016.pdf, and 073545-00015.20091016.pdf) . 5. Com,pleieo Ceftificationwith Respect ,to Label Integrity form. ,. If yo~ h:ave a.ny qustions on this submission please call me at 610-491-2813 or email at : •• :.: )tim.foimeJlii@tiniphos.com. : .: . .... :.:1'; ._,... .. ",,' ,1< •••••• Sin,reI, , "~ _ J/~ '.)2, k .. IJIJ TirriO~~~~~ iella enior Regitrton Manager " .. • • • • •• ••••• • • • • ••••• • • •••••• • •••• ., . •••• • • • • 0 •••• • • •• •• • • ••• • •••• • • •••• • •• •• • ••••

I' ) TOPSIN@ M 85WDG THIOPHANATE-METHYL FUNGICIDE 85% Water Dispersible Granule NOTIFICATION DEC 1 5 2009 ACTIVE INGREDIENT: Thiophanate-methyl (dimethyl [I ,2-phenylene )-bis(iminocarbonothioyl)] bis[ carbamate])* .......................................................................................... 85.0% INERT INGREDIENTS: ................................................................................. 15.0% TOTAL ......................................... I00.0%

• Also known as dimethyl 4, 4'-0-phenylenebis[3-thioallophanate] TOPSIN is a registered trademark of Nippon Soda Company, Ltd., and is licensed to NISSO TM LLC, and is covered by one or more of the following U.S. Patents: 3,769,308; 3,856,847; 4,020,095; and 4,029,813. FIRST AID If on skin or clothing: KEEP OUT OF REACH OF CHILDREN CAUTION • Take off contaminated clothing. • Rinse skin immediately with plenty of water for 15-20 minutes. • Call a poison control center or doctor for treatment advice. If in eyes: • Hold eye open and rinse slowly and gently with water for 15-20 minutes. • Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. • Call a poison control center or doctor for treatment advice. If swallowed: • Call a poison control center or doctor immediately for treatment advice. • Have person sip a glass of water if able to swallow. • Do not induce vomiting unless told to by a poison control center or doctor. • Do not give anything by mouth to an unconscious person. If inhaled: • Move person to fresh air. • Ifperson is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. • Call a poison control center or doctor for further treatment advice. Have the product container or label with you when calling a poison control center or doctor or goin:J .,' for treatment. Contact the Rocky Mountain Poison Control Center at 1-866-767-5089 for emergenoy") f) medical treatment information. ' J :J)J'''>;):J .)')J1 ) J 'J EPA Registration No. 73545-15 EPA Establishment No. :: <) ~ ------~--U-J NET WEIGHT: ____ Pounds ( ____ Kgs) Batch/Lot No. Sold by: United Phosphorus, Inc. 630 Freedom Business Center, Suite 402 King of Prussia, P A 19406 Page 1 J J ..> ) ) J ) J .) .J .) ',) ) ) J J .) -----,., vr----..,-;v- ) J :J.) J ) .) ) J ..> ,) ..> .J ) J J J.) J ) ) J .) J ).) J J .J.J ) ) ).I) )

PRECAUTIONARY STATEMENTS HAZARDS TO HUMANS AND DOMESTIC ANIMALS CAUTION Hannful if absorbed through skin. Causes moderate eye irritation. A void contact with eyes, skin, or clothing. Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals. Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco or using the toilet. Remove and wash contaminated clothing before reuse. PERSONAL PROTECTIVE EQUIPMENT (PPE) Some materials that are chemical-resistant to this product are made of any waterproof material. If you want more options, follow the instructions for category A on an EPA chemical-resistance category selection chart. Handlers mixing, loading, and applying this product as a dip (including application of product in Kaolinite clay to conifer seedling roots) must wear: • Coveralls over long-sleeved shirt and long pants, • Chemical-resistant gloves, • Chemical-resistant footwear plus socks, • A chemical resistant apron. All other mixers, loaders, applicators, and other handlers must wear: • Long-sleeved shirt and long pants, • Shoes plus socks, • Chemical-resistant gloves for all mixers and loaders and for applicators using hand held equipment. User Safety Requirements Follow manufacturer's instructions for cleaning/maintaining PPE. lfno such instructions for washables exist, use detergent and hot water. Keep and wash PPE separately from other laundry. Discard clothing and other absorbent materials that have been drenched or heavily contaminated with this product's concentrate. Do not reuse them. ENGINEERING CONTROLS When handlers use enclosed cabs in a manner that meets the requirements listed in the Worker Protection Standard (WPS) for agricultural pesticides [40 CFR 170.240(d)(4-6)], the handler PPE requirements may be reduced or modified as specified in the WPS. ~ J 0 ) .) r-------------------------------------------------------------------r}J»'J ) ,) :) .) J J ~) ::J ."} ) USER SAFETY RECOMMENDATIONS ,) ).) I Users should wash hands before eating, drinking, chewing gum, using tobacco,'~or sig the) 0" .J .) ) -) ) ) ) J J ")} ) tuoilet. h ld I hin !PPE . d' I 'f ""d '"d Th 'h) 'h :h1 J sers s ou remove c ot g unme late y 1 pestlcl e gets IllSl e. en was . t oroug r I ,) • )))).) ;)O·J·) and put on clean clothing. ~ ~ " I Users should remove PPE immediatel after handlin this roduct. Wash the outsldf of IOVe5 J " Page 2 ).J.) ) J ,) .J ,.1 .) ) ) ) .,

I before removing. As soon as possible, wash thoroughly and change into clean clothing. ENVIRONMENTAL HAZARDS Do not apply directly to water or areas where surface water is present or to intertidal areas below the mean high water mark. Runoff from treated areas may be hazardous to aquatic organisms in neighboring areas. Do not contaminate water when disposing of equipment wash water. DIRECTIONS FOR USE It is a violation of Federal law to use this product in a manner inconsistent with its labeling. Do not apply this product in a way that will contact workers or other persons, either directly or through drift. Only protected handlers may be in the area during application. For any requirements specific to your State or Tribe, consult the agency responsible for pesticide regulation. Do not apply when wind speed favors drift beyond the area intended for treatment. AGRICULTURAL USE REQUIREMENTS Use this product only in accordance with its labeling and with the Worker Protection Standard, 40 CFR part 170. This Standard contains requirements for the protection of agricultural workers on farms, forests, nurseries, and greenhouses, and handlers of agricultural pesticides. It contains requirements for training, decontamination, notification, and emergency assistance. It also contains specific instructions and exceptions pertaining to the statements on this label about personal protective equipment (PPE), and restricted-entry interval. The requirements in this box only apply to uses of this product that are covered by the Worker Protection Standard. Do not enter or allow worker entry into treated areas during the restricted entry interval (REI). Exemption: The Worker Protection Standard, under certain circumstances, allows workers to enter the treated area if there will be no contact with anything that has been treated. Do not enter or allow workers entry into treated areas during the restricted-entry interval (REI). The REI for each crop is listed in the directions for use associated with that crop. PPE required for early entry to treated areas that is permitted under the Worker Protection .'») ) .) Standard and that involves contact with anything that has been treated, such as plants, soil, o) ) ) water, is: 'J :J • Coveralls over long-sleeved shirt and long pants, • Chemical-resistant gloves made of any waterproof material, • Chemical-resistant footwear plus socks, • Chemical-resistant head ear for overhead ex osures. Page 3 J»)'JJJ J ) J '1 :.- J J ) J ) ,) ) J ) .>..> ) ) J .} " ) J J .:1 ,) I.' ) ) ) J ) ,-__ J _') ) ..... ,' ) ~ ')"J J.).) J') ) } ) .J ) ) , , ) ) j )

GENERAL INSTRUCTIONS AND INFORMATION Apply TOPSIN M 85WDG with ground or aerial equipment, using sufficient volume of spray to provide thorough coverage. Continuous agitation is required to keep the material in suspension. United Phosphorus, Inc. does not recommend tank mixes with highly alkaline pesticides, such as Bordeaux mixture or lime sulfur. No claim of compatibility with other pesticides is implied. Use the higher rate under conditions of severe disease pressure. Also, see local State Extension Service recommendations for application schedules. Use the LBS/ACRE rate for concentrate sprays (less than 400 gallons on apples and pears, less than 300 gallons on stonefruit). Use the LBSIIOO GAL rate for dilute ground applications. For aerial applications, use a minimum of 5 gallons/ A spray mix for row crops, and a minimum of 10 gallons/A spray mix for tree crops. For ground applications use a minimum of20 gallons/A spray mix for row crops and 30 gallons/A spray mix for tree crops. Higher spray volume will generally result in better coverage and better disease control. Lack of control when using below minimum spray volumes is solely at the risk of the applicator/user, including use of electrostatic sprayers. Use on non-bearing tree fruit and tree nuts: TOPSIN M 85WDG may be used for control of the diseases listed on the label for these crops during the non-bearing years of new plantings, and on nursery stock. All use directions and limitations must be followed, except for the PHI, which is not applicable. Begin applications as disease is first observed or expected. Tank mixing with a protectant fungicide is strongly recommended for resistance management. Chemigation instructions are presented at the end of the application rate tables .. Do not apply through any irrigation system unless these instructions are followed. RESISTANCE MANAGEMENT: To avoid the development of tolerant or resistant strains of fungi, TOPSIN M 85WDG should always be tank-mixed with a fungicide of different chemistry, andlor a fungicide of different chemistry should be alternated with TOPSIN M 85WDG at each application. DO NOT USE PRODUCTS CONTAINING THIABENDAZOLE OR OTHER PRODUCTS CONTAINING THIOPHANATE-METHYL IN COMBINATION, IN ROTATION, OR AS A SUBSTITUTE FOR TOPSIN M 85WDG AS THEY ARE OF SIMILAR CHEMISTRY AND WILL CONTRIBUTE TO THE DEVELOPMENT OF RESISTANCE. If after using TOPSIN M 85WDG as recommended, and the treatment is not effective, a tolerant or resistant strain of fungi may be present. Discontinue the use of TOP SIN M 85WDG for at least one season. As long as these precautions are followed, TOPSIN M 85WDG can be useful for disease control, even if resistant strains are present. Page 4

Crop Diseases Rate Rate Remarks Lbs of Lb/lOO Product/ Gal Acre/ application Almonds Brown Rot Blossom 0.8 - 1.2 Apply as needed between pink bud Blight and petal fall. Do not enter (Monilinia sp.) Topsin M 85WDG may be applied or allow Scab (Cladosporium) alone at pink bud for Brown Rot worker entry control. For all other applications, into treated Jacket Rot (Monilinia, Topsin M 85WDG should be areas during Sc1erotinia, Botrytis) applied with a contact fungicide the restricted Leaf Blight such as Ziram 76DF for broad- entry interval (Seimatosporium) spectrum control and disease (REI) of3 resistance management. days. Do not apply more than 2.4 Ibs product (2.1 Ibs ai)/ A/vear. Apples Apple Scab 0.6- 0.8 0.17-0.2 Apply at 5- to 10-day intervals from (Venturia) (in CA use green tip through petal fall; continue Do not enter Black Pox* 1.2) at 7- to 14-day intervals in cover or allow (Helminthosporium sprays. worker entry papulosum) Do not apply more than 3.2 lbs into treated Flyspeck product (2.8 lbs ai)/ A/year. areas during (Zygophiala) Pre-harvest interval: 1 day the restricted Powdery Mildew Follow resistance management entry interval (Podosphaera) guidelines under Directions for Use. (REI) of2 Sooty Blotch days. (Gloeodes sp.) Black Rot (Botryosphaeria obtusa) Brooks Fruit Spot (Mycosphaerella) White Rot* (Botryosphaeria dothidia) Pre-Harvest use to control Post-Harvest Diseases on Apples Storage Rot 0.8 Apply as a pre-harvest spray within Blue Mold 2 weeks to 3 days of harvest. (Penicillium Through coverage of the fruit is expansum) required. Application closer to Gray Mold (Botrytis harvest may provide better efficacy. cinerea) For resistance management, do not Bulls-Eye Rot use a benzimidazole fungicide (i.e. Page 5

Crop Diseases Rate Rate Remarks Lbs of LbllOO Product! Gal Acre/ application (Neofabraea spp.) Mertect®) post-harvest following Topsin M 85WDG pre-harvest application. Application of a non- benzimidazole post-harvest fungicide such as Penbotec™ or Scholar® will provide additional protection from post-harvest diseases. Do not apply more than 3.2 lbs of product (2.8 lbs a.i.)/A/year. Pre-harvest interval: 1 day Beans, dry Gray Mold 1.2 - 1.6 For one application: Apply when and (Botrytis) 100% of plants have at least one succulent White Mold open bloom or when conditions are (Sclerotinia) favorable for disease development. Including: Anthracnose OR OR Lima bean (Colletotrichum) 0.8 -1.2 For multiple applications: Make the Snap bean first application when 10% to 30% Kidney bean of plants have at least one open Mung bean bloom and follow with sequential Navy bean applications on a 4 to 7-day interval. Pinto bean Apply prior to the development of Wax bean disease for best results. Broad bean Do not apply more than 3.2 lbs Fava bean Asparagus product (2.8 lbs ai)/ Alyear. bean Preharvest interval: California only, Blackeyed 14 days for succulent beans, 28 days pea for dry beans and lima beans. Cowpea Pre-harvest interval: all other Sweet lupine States, 14 days for succulent beans White lupine and lima beans, 28 days for dry White Sweet beans. lupine Grain lupine Chickpea Garbanzo bean Do not enter or allow worker entry into treated Page 6

Crop Diseases Rate Rate Remarks Lbs of Lb/lOO Product/ Gal Acre/ application areas during the restricted entry interval (REI) of24 hours for succulent beans and 3 days for dry beans. Canola, White Mold 0.8 -1.6 in a Apply at 20% to 50% flowering for Crambe Sclerotinia Stem Rot single single application. (Sclerotiorum application In North sclerotiorum) OR OR Dakota, 0.8 per Apply twice with the first Minnesota, application application at 20% to 30% flowering and Montana when and the second application at 40% to (east of applying 50% flowering. Interstate 15 twice only) Pre-harvest interval: 40 days Do not enter Do not apply more than 1.6 Ibs of or allow product (1.4 lbs a.i.)/ A/year. worker entry into treated Thorough coverage of the flowers, areas during stems, and branches is essential for the restricted control of white Mold. entry interval (REI) of24 hours. Cucurbits: General Information Do not apply more than 2.4 Ibs Cantaloupe, product (2.11bs ai)/A/year. Casaba, Pre-harvest interval: 1 day. Cucumbers, Acremoniurnl 0.4 Apply in-furrow, on top of the seeds Melons, Pumpkins, Cephalosporium at planting. Do not use less than 10 Summer and Hypocotyl Rot gallons of water per acre. Winter Squash, 'and Watermelons Page 7

Crop Diseases Rate Rate Remarks Lbs of Lb/lOO Product/ Gal Acre/ application Anthracnose* 0.4 Begin applications when plants (Colletotrichum) begin to run or when disease first Do not enter Gummy Stem Blight* appears, and repeat at 7- to 14-day or allow (Didymella) intervals as needed. worker entry Powdery Mildew For Target Spot, use at 7-day into treated (Erysiphe, intervals as needed. areas during Sphaerotheca, the restricted Podosphaera) entry interval Target Spot* (REI) of24 (Corynespora) hours. Belly Rots* Apply in sufficient volume to allow (Rhizoctonia, 0.4 runoff to the soil. Fusarium) Will not control Pythium or Phytophthora. Suppression of Vine 0.4 For disease suppression, apply at 14 Decline day intervals, beginning at (Monosporascus) emergence and continuing to Charcoal Rot harvest. (Macrophomina) Applications weekly or biweekly, beginning 4-6 weeks prior to harvest will also offer suppression, but may not be as effective as a season-long program. Garlic Penicillium Clove Rot 0.8 Completely immerse garlic cloves in (clove Ib/lOO suspension for at least 5 minutes. treatment) gallons Continuously agitate the solution tank by hydraulic or mechanical means. After treatment, remove cloves from solution and drain. Dry cloves after treatment and prior to planting. Grapes General Information Do not apply more than 3.21bs of product (2.8 lbs a.i.)/ A/year. Do not enter Pre-harvest interval: 14 days or allow Follow resistance management worker entry guidelines under Directions for Use. into treated WEST OF THE 0.8 - 1.2 Apply at first bloom and repeat 14 areas during the restricted ROCKY days later or as needed if severe entry interval MOUNTAINS: disease conditions exist. Make an Bunch Rot (Botrytis) additional application 3 to 4 weeks Page 8

Crop Diseases Rate Rate Remarks Lbs of Lb/IOO Product/ Gal Acre/ application (REI) of2 Powdery Mildew before harvest or when sugar begins days. (Uncinula) to build; repeat 14 days later if conditions favorable for disease persist. For Powdery Mildew continue applications through the season. Use in combination or rotation with a sulfur product such as Microthiol® Disperss® andlor other systemic fungicides. EAST OF THE 0.6 -1.2 Apply when foliage first develops ROCKY and repeat at 14 to 21-day intervals MOUNTAINS: as needed. Bitter Rot (Melanconium) Black Rot (Guignardia) Powdery Mildew (Uncinu1a) Phomopsis Cane and Leaf Spot (Phomopsis) Bunch Rot (Botrytis) 0.8 - 1.2 Apply at first bloom and repeat 14 days later or as needed if severe disease conditions exist. Make an additional application 3 to 4 weeks before harvest or when sugar begins to build; repeat 14 days later if conditions favorable for disease persist. Do not use where resistant strains of Botrytis are present. Onions* White Rot 1.6 Spray directly into the open furrow Garlic (Sclerotium broadcast at the time of planting seed, sets or (In furrow) cepivorum) bulbs. Not for this use through any type of irrigation system. Do not enter Do not apply more than 1.6 lbs or allow product (1.4 lbs ai)/ Alyear. worker entry into treated areas during the restricted Page 9

Crop Diseases Rate Rate Remarks Lbs of LbllOO Product/ Gal Acre/ application entry interval (REI) of3 days. Peanuts Early Leaf Spot 0.4 Begin applications when disease (Cercospora) first appears and repeat at 14-day Do not enter Late Leaf Spot intervals as needed. or allow (Cercsoporidium) Do not apply more than 1.6 Ibs worker entry Rust (Puccinia) product (1.4 Ibs ai)/ A/year. into treated Limb Rot Pre-harvest interval: 14 days. areas during (Rhizoctonia) Topsin M 85WDG should not be the restricted Web Blotch used alone. Use only in combination entry interval (Ascochyta) with a non-benzimidazole fungicide (REI) of24 such as Penncozeb® 75DF hours. (mancozeb) at 1 1/2 Ib per acre or chlorothalonil. Follow resistance management ·1 guidelines under Directions for Use. I Pears I Pear Scab (Venturia) 0.8 0.2 Apply at 5 to 10-day intervals from Sooty Blotch green tip through petal fall; continue Do not enter (Gloeodes) at 7 to 14-day intervals in the cover or allow Flyspeck (Zygophiala) sprays. worker entry Powdery Mildew Do not apply more than 3.2 lbs of into treated (Podosphaera) product (2.8 Ibs a.i.)/ A/year. areas during Leaf Spot (Fabraea) Pre-harvest interval: 1 day the restricted Follow resistance management entry interval guidelines under Directions for Use. (REI) of2 Pre-Harvest use to control Post-Harvest Diseases on Pears days. Storage Rot 0.8 Apply as a pre-harvest spray within Blue Mold 2 weeks to 3 days of harvest. (Penicillium Thorough coverage of the fruit is expansum) required. Application closer to Gray Mold (Botrytis harvest may provide better efficacy. cinerea) For resistance management, do not Bulls-Eye Rot use a benzimidazole fungicide (i.e. (Neofabraea spp.) Mertect®) post-harvest following Topsin M 85WDG pre-harvest application. Application of a non-benzimidazole post-harvest fungicide such as Penbotec™ or Scholar® will provide additional protection from Page 10

Crop Diseases Rate Rate Remarks Lbs of Lb/IOO Product/ Gal Acre/ application post-harvest diseases. Do not apply more than 3.2 Ibs of product (2.8 Ibs a.i.)/ A/year. Pre-harvest interval: 1 day Pecans Brown Spot 00.8 Begin applications when first leaves (Cercospora) are showing and repeat at 3- to Do not enter Downy Spot 4-week intervals until shuck split. or allow (Mycosphaerella) Do not apply after shuck split. worker entry Liver Spot Do not apply more than 2.5 lbs into treated (Gnomonia) product (2.1 lbs a.i.)/ A/year. areas during Powdery Mildew the restricted (Microsphaera) entry interval Scab Follow resistance management (REI) of3 (Fusicladium) guidelines under Directions for Use. days. Stem End Blight (Botryosphaeria) Zonate Leaf Spot (Cristulariella) Pistachios Shoot Blight 1.2 - 1.6 Apply at bloom. (Botrytis, Apply in a minimum of 100 gallons Do not enter Botryosphaeria) per acre by ground or 20 gallons per or allow acre by air. worker entry For aerial application, fly over every into treated row or center. areas during Do not apply more than 1.6 lbs of the restricted product (1.4 lbs a.i.)/A/year. entry interval (REI) of3 days. Potatoes White Mold 0.8 - 1.2 Make first application just prior to (Sclerotinia row closure. Repeat the application Do not enter sclerotiorum) within 7 to 14 days and at 7- to 14- or allow day intervals if conditions for worker entry disease development are favorable. into treated Thorough coverage of the flowers, areas during stems, and branches is essential for the restricted disease control. entry interval (REI) of2 Do not apply more than 3.2 Ibs of days. product (2.8 lbs a.i.)/A/year. Pre-harvest interval: 21 days Page 11

) ) Crop Diseases Rate Rate Remarks Lbs of LbllOO Product/ Gal Acre/ application May be tank mixed with Penncozeb (mancozeb) for Early and Late Blight control. Soybeans General Information Do not apply more than 1.6 lbs product (1.4 lbs a.i.)/A/year. Do not enter Pre-harvest interval: 21 days. or allow Do not graze or feed treated vines or worker entry hay to livestock. into treated Anthracnose Apply from full bloom to when pods areas during the restricted (Colletotrichum) 0.4 - 0.8 are 1/8" to 114" in length. Make a entry interval Brown Spot second application 14 to 21 days (REI) of24 (Septoria) later. Do not make the second hours. Frogeye Leaf Spot application later than 14 days after (Cercospora) pods average 1/4" in length or when Pod and Stem Blight beans form in the pod. Use the high (Diaporthe, rate under severe disease pressure. Phomopsis) FOR SEED BEANS ONLY---For Purple Seed Stain seed quality, make a single (Cercospora) application at the high rate (0.8 lb per acre) when beans form in the pod. 0.8 FOR SEED BEANS ONLY - For seed quality, make a single application when beans form in the pod. White Mold 0.6-0.8 Make one application at early bloom (Sclerotinia) (R-l to R-2 stage) followed by a second application 14 days later if conditions are favorable for continued disease pressure. Thorough coverage of the flowers, stems, and branches is essential for disease control. Use a minimum of 5 gallons water/ A by air. Aerial Blight 0.8 Make initial application when (suppression) disease threatens and repeat 14-21 days later if needed. Page 12

~) Crop Diseases Rate Rate Remarks Lbs of Lb/IOO Product/ Gal Acre/ application Stone Fruit General Infonnation Do not apply more than 3.2 lbs of product (2.8 lbs a.i.)/A/year. Do not enter Pre-harvest interval: 1 day or allow Follow resistance management worker entry guidelines under Directions for Use. into treated areas during the restricted entry interval (REI) of2 days.

• Apricots Brown Rot Blossom 0.8 - 1.2 0.25-0.4 Apply at early bloom (red bud). Blight (in CA use Make a second application at full Fruit Brown Rot 1.2) bloom. (Monilinia) If needed under severe disease pressure, apply additional sprays at 10- to 14-day intervals between full bloom and final pre-harvest sprays.
• Cherries Brown Rot Blossom 0.8 - 1.2 0.25-0.4 Apply at early bloom (early sweet and Blight (in CA use popcorn). Make a second application sour Fruit Brown Rot 1.2) at full bloom. (Monilinia) If needed under severe disease pressure, apply additional sprays at 10- to 14-day intervals between full bloom and final pre-harvest sprays. Cherry Leaf Spot 0.9 - 1.2 0.3-0.4 Applications may be made at petal (Coccomyces) fall or before (when leaves first unfold) and at first, second, and third cover at 10- to 14-day intervals and one spray 14 to 21 days after harvest. Powdery Mildew 0.8 - 1.2 0.25-0.4 Apply at early bloom (early (Podosphaera, (in CA use popcorn). Make a second application Sphaerotheca) 1.2) at full bloom. PLUS PLUS PLUS 0.9 - 1.2 0.3-0.4 Apply at shuck fall and first cover.
• Nectarines Brown Rot Blossom 0.8 - 1.2 0.25-0.4 Apply at early bloom (Pink bud). Page l3

Crop Diseases Rate Rate Remarks Lbs of Lb/IOO Product/ Gal Acre/ application Blight (in CA use Make a second application at full Fruit Brown Rot 1.2) bloom if conditions favor disease (Monilinia) development. If needed under severe disease pressure, apply additional sprays at 10- to 14-day intervals between full bloom and final pre-harvest sprays.

• Peaches Brown Rot Blossom 0.8 - 1.2 0.25-0.4 Apply at early bloom (Pink bud). Blight (in CA use Make a second application at full Fruit Brown Rot 1.2) bloom if conditions favor disease (Monilinia) development. If needed under severe disease pressure, apply additional sprays at 10- to 14-day intervals between full bloom and final pre-harvest sprays. Peach Scab 0.8 - 1.2 0.25-0.4 Apply at early bloom (pink bud). (Cladosporium) (in CA use Make a second application at full 1.2) bloom if conditions favor disease development. PLUS PLUS PLUS 0.9 -1.2 0.3-0.4 Apply at shuck split and at first cover sprays.
• Plums and Brown Rot Blossom 0.8 - 1.2 0.25-0.4 Apply at early bloom (green tip). Prunes Blight (in CA use Make a second application at full Fruit Brown Rot 1.2) bloom. (Monilinia) If needed under severe disease pressure, apply additional sprays at 10- to 14-day intervals between full bloom and final pre-harvest sprays. Black Knot 0.8 - 1.2 0.25-0.4 Apply at pre-bloom, petal fall, and at (Dibotryon) (in CA use first, second, and third cover sprays 1.2) at 10- to 14-day intervals. Leaf Spot 0.8 - 1.2 0.25-0.4 Applications may be made at petal (Coccomyces) (in CA use fall, shuck split, and at first, second, 1.2) and third cover sprays at 10- to 14-day intervals and I spray 14 to 21 days after harvest. Strawberries General Information Do not apply more than 3.2 lbs of product (2.8 lbs a.i.)/A/year. Pre-harvest interval: 1 day Page 14

) Crop Diseases Rate Rate Remarks Lbs of Lb/lOO Product! Gal Acre/ application Do not enter Follow resistance management or allow guidelines under Directions for Use. worker entry Crown Rot* 0.6-0.8 Begin applications after into treated areas during (Colletotrichum spp.) establishment of the transplants and the restricted continue through first bloom at 10 to entry interval Suppression only 14-day intervals. Use the high rate (REI) of24 if the fields have a history of hours. Colletotrichum crown rot and/or conditions are favorable for development of the disease. Will not control Phytophthora species. Fruit Rot 0.6- 0.8 Begin applications at early bloom (Botrytis) and continue at 7- to 10-day Leaf Blight intervals. Use the higher rate under (Dendrophoma) conditions of severe disease Leaf Scorch pressure. (Diplocarpon) Powdery Mildew (Sphaerotheca) Sugar Beets General Information Do not apply more than 2.5 lbs of product (2.1 lbs a.i.)/ Alyear. Do not enter Pre-harvest interval: 21 days or allow Follow resistance management worker entry guidelines under Directions for Use into treated Cercospora Leaf Spot 0.4 - 0.8 Apply when conditions become areas during (Cercospora) favorable for disease development the restricted before the disease appears and entry interval follow with a non-benzimidazole (REI) of24 fungicide within 14 days of hours. application or as needed. Topsin M 85WDG should be tank mixed with a protectant fungicide such as Penncozeb® or Super Tin® when resistant strains of Cercospora are present in the field. For areas east of the Rocky Mountains: Do not make more than one application of Topsin M 85WDG per season for Cercospora Leaf Spot. Page lS

Crop Diseases Rate Rate Remarks Lbs of Lb/lOO Product! Gal Acrel application Powdery Mildew 0.4 - 0.8 Apply as soon as disease symptoms (Erysiphe) appear and follow with a non- benzimidazole fungicide at a 14-day interval as needed. Topsin M 85WDG can be tank mixed with sulfur products such as Microthiol® Disperss® at 5 to 10 Ibs/A for additional disease control and resistance management. Triticale and Foot Rot, 0.8 Apply in a single application by air Fall-seeded Strawbreaker, or ground after tillering but before Wheat Eye Spot stem elongation has begun. Use (Pseudocercosporella) sufficient water to obtain thorough For this use coverage. in Idaho, Do not apply more than 0.8 lb of Oregon, and product (0.7Ib a.i.)INyear. Washington Do not cut for hay within 90 days of ONLY application. Do not allow livestock to graze in Do not enter treated areas before harvest. or allow worker entry into treated areas during the restricted entry interval (REI) of24 hours.

• Not for thIS use III CalIfornIa NOTE: Dilute sprays are not to exceed maximum rate per acre. DIRECTIONS FOR USE ON CONIFERS (Not for this use in California) CROP DISEASE RATE (Lbl A), DIRECTIONS MINIMUM GALLONAGE Conifers Tip Blight 0.81b/A Apply at bud break. (Pine) (Diplodia) 100 gallA Repeat 10 to 14 days later, Austrian just before needles emerge Red from sheath; repeat again Page 16

Scots Christmas Trees (Fir) Douglas Swiss Needle Cast (Phaecryptopus) Rhabdocline Needle Cast • Add a spreader/sticker to improve coverage. 0.81b/A 50 gallA ~) 10 to 14 days after needle emergence. Do not apply more than 2.5 Ibs of product (2.1 Ibs a.i.)1 Alyear. Apply initially in early May. Repeat at 4 week intervals. Do not apply more than 4 lbs of product (3.5 lbs a.i.)1 Alyear. • Use minimum gallonage with mist-blower types of sprayers and higher gallonage with conventional sprayers. • Do not graze livestock in treated areas. • Do not enter or allow worker entry into treated areas during the restricted entry interval (REI) of 12 hours. Conifers (seedling treatment) Longleaf Loblolly Longleaf Slash Brown Needle Blight (Scirrhi a) Fusarium and Rhizoctonia Root Rot 1 oz product per 9.5 oz. dry Kaolinite clay for seedling roots 2 oz. product per 500z. Kaolinite clay, plus enough water to make a slurry Wet seedling roots in clean water, then apply Topsin M 85WDGIKaolinite mixture to wet roots. Do not apply mixture to seedling foliage. Thoroughly cover seedling roots with Topsin M 85WDGIKaolinite slurry. Do not apply mixture to seedling foliage. • During treatment, avoid excessive drying of roots or exposure to temperatures greater than 90° F or less than 32° F. • Topsin M 85WDG does not control Pythium or Phytophthora. • Do not enter or allow worker entry into treated areas during the restricted entry interval (REI) of 12 hours. DIRECTIONS FOR USE THROUGH CHEMIGATION SYSTEMS USE IN CALIFORNIA BY CHEMIGA TION ONLY FOR BEANS, CUCURBITS (CANTALOPE, CASABA, CUCUMBERS, MELONS, PUMPKINS, SQUASH, WATERMELONS), PEANUTS, SOYBEANS, STRAWBERRIES, AND SUGAR BEETS. GENERAL INSTRUCTIONS Apply this product only through sprinkler irrigation systems including center pivot, lateral move, end tow, side (wheel) roll, traveler, big gun, solid set or hand move; or drip (mini-micro sprinklers, strip Page 17

tubing, trickle) irrigation systems. Do not apply this product through any other type of irrigation system. Crop injury, lack of effectiveness, or illegal pesticide residues in the crop can result from nonuniform distribution of treated water. If you have any questions about calibration, you should contact State Extension Service specialists, equipment manufacturers or other experts. A person knowledgeable of the chemigation system and responsible for its operation, or under the supervision of the responsible person, shall shut the system down and make necessary adjustments should the need arise. Do not connect chemigation system to any public water system. Public water system means a system for the provision of piped water for human consumption if such a system has at least 15 service connections or regularly serves an average of at least 25 individuals daily at least 60 days out of the year. SYSTEM REQUIREMENTS Systems utilizing a pressurized water and pesticide injection system must meet the following requirements: The system must contain a functional check valve, vacuum relief valve, and low pressure drain appropriately located on the irrigation pipeline to prevent water source contamination from backflow. The pesticide injection pipeline must contain a functional, automatic, quick-closing check valve to prevent the flow of fluid back toward the injection pump. The pesticide injection pipeline must also contain a functional, normally closed, solenoid-operated valve located on the intake side of the injection pump and connected to the system interlock to prevent fluid from being withdrawn from the supply tank when the irrigation system is either automatically or manually shut down. The system must contain functional interlocking controls to automatically shut off the pesticide injection pump when the water pump motor stops. The irrigation line or water pump must include a functional pressure switch which will stop the water pump motor when the water pressure decreases to the point where pesticide distribution is adversely affected. . Systems must use a metering pump, such as a positive displacement injection pump (e.g., diaphragm pump) effectively designed and constructed of materials that are compatible with pesticides and capable of being fitted with a system interlock. APPLICATION INSTRUCTIONS Observe the requirements in the System Requirements section above. Apply TOPSIN M only through systems containing anti-syphon and check valves designed to prevent water source contamination or overflow of the mix tank and containing interlocking controls between the metering device and the water pump to insure simultaneous shut-off. Maintain a gentle continuous agitation in mix tank during mixing and application to assure a uniform suspension. Greater accuracy in calibration and distribution will be achieved by injecting a larger volume of a more dilute suspension per unit time. Application of more than recommended quantities of irrigation water per acre may result in decreased product performance. Do not apply when wind speed favors drift, when system connections or fittings leak, when nozzles do not provide uniform distribution or when lines containing the product cannot be flushed and must be dismantled and drained. In a center pivot system, block the nozzle set nearest the well/pivot/injection unit to prevent spray being applied to this area. Where sprinkler distribution patterns do not overlap sufficiently, unacceptable disease control may result. Allow sufficient time for pesticide to be flushed through all lines and all nozzles before turning off irrigation water. TOPSIN M may be applied in conjunction with chemically neutral liquid fertilizers. Application in conjunction with highly alkaline fertilizers, such as aqueous ammonia, may cause a degradation of the pesticide, resulting in reduced performance and should be avoided. Page 18

-) SPRAY PREPARATION: Remove scale, pesticide residues, and other foreign matter from the chemical tank and entire injector system. Flush with clean water. Prepare a suspension of TOPSIN M in a mix tank. Fill the tank with 112 or 3/4 the desired amount of water. Start mechanical or hydraulic agitation. Slowly add the required amount of TOPSIN M and then the remaining volume of water. Sprinkler Irrigation - Notes Observe all System Requirements and Application Instructions above. Set sprinkler system to deliver 0.1 to 1.25 inches of water per acre. Volumes of water higher than this may reduce efficacy. Start sprinkler and then uniformly inject the suspension of TOPSIN M into the irrigation water line so as to deliver the desired rate per acre. The suspension of TOPSIN M should be injected with a positive displacement pump into the main line ahead of a right angle turn to insure adequate mixing. When treatment with TOPSIN M has been completed, do not irrigate the treated area for 24 to 48 hours to prevent washing the chemical off the crop. Do not apply when wind speed favors drift beyond the area intended for treatment. Where sprinkler distributed patterns do not overlap sufficiently, unacceptable disease control may result. Check local restrictions and requirements regarding sprinkler irrigation applications, as they may vary from state to state. Drip (Mini-Micro Sprinklers, Strip Tubing, Trickle) Irrigation - Notes Observe all System Requirements and Application Instructions above. STORAGE AND DISPOSAL Do not contaminate water, food or feed by storage and disposal. PESTICIDE STORAGE: Store in the original container in a dry area. Do not store in a manner where cross-contamination with other pesticides, fertilizers, food or feed could occur. If spilled during storage or handling, sweep up spillage and dispose of in accordance with the Pesticide Disposal instructions listed below. PESTICIDE DISPOSAL: Pesticide wastes are toxic. Improper disposal of excess pesticide, spray mixture, or rinsate is a violation of Federal Law. If these wastes cannot be used according to label instructions, contact your State Pesticide or Environmental Control Agency, or the Hazardous Waste representative at the nearest EPA Regional Office for guidance. CONTAINER HANDLING: Nonrefillable container. Do not reuse or refill this container. Completely empty bag into application equipment by shaking and tapping sides and bottom to loosen clinging particles. Then offer for recycling if available or dispose of empty bag in a sanitary landfill or by incineration or, if allowed by state and local authorities, by burning. If burned, stay out of smoke. IMPORTANT INFORMATION READ BEFORE USING PRODUCT CONDITIONS OF SALE AND LIMITATION OF WARRANTY AND LIABILITY NOTICE: Read the entire Directions for Use and Conditions of Sale and Limitation of Warranty and Liability before buying or using this product. If the terms are not acceptable, return the product at once, unopened, and the purchase price will be refunded. Page 19

) The Directions for Use of this product reflect the opinion of experts based on field use and tests, and must be followed carefully. It is impossible to eliminate all risks associated rvith the use of this product. Crop injury, ineffectiveness or other unintended consequences may result because of such factors as manner of use or application, weather or crop conditions, presence of other materials or other influencing factors in the use of the product, which are beyond the control of United Phosphorus, Inc. or Seller. Handling, storage, and use of the product by Buyer or User are beyond the control of United Phosphorus, Inc. and Seller. All such risks shall be assumed by Buyer and User, and Buyer and User agree to hold United Phosphorus, Inc. and Seller harmless for any claims relating to such factors. TO THE EXTENT CONSISTENT WITH APPLICABLE LAW, UNITED PHOSPHORUS, INC. AND SELLER MAKE NO WARRANTIES OF MERCHANTABILITY OR OF FITNESS FOR A PARTICULAR PURPOSE NOR ANY OTHER EXPRESS OR IMPLIED WARRANTY EXCEPT AS STATED ON THIS LABEL. To the extent consistent with applicable law, United Phosphorus, Inc. or Seller shall not be liable for any incidental, consequential or special damages resulting from the use or handling of this product and THE EXCLUSIVE REMEDY OF THE USER OR BUYER, AND THE EXCLUSIVE LIABILITY OF UNITED PHOSPHORUS, INC. AND SELLER FOR ANY AND ALL CLAIMS, LOSSES, INJURIES OR DAMAGES (INCLUDING CLAIMS BASED ON BREACH OF WARRANTY, CONTRACT, NEGLIGENCE, TORT, STRICT LIABILITY OR OTHERWISE) RESULTING FROM THE USE OR HANDLING OF THIS PRODUCT, SHALL BE THE RETURN OF THE PURCHASE PRICE OF THE PRODUCT OR, AT THE ELECTION OF UNITED PHOSPHORUS, INC. OR SELLER, THE REPLACEMENT OF THE PRODUCT. United Phosphorus, Inc. and Seller offer this product, and Buyer and User accept it, subject to the foregoing conditions of sale and limitations of warranty and of liability, which may not be modified except by written agreement signed by the duly authorized representative of United Phosphorus, Inc. Rev. 10116/2009 Page 20