crop-chem-docs/corpus/epa_ppls/264-341.md

LARVIN THIODICARB INSECTICIDE 75 WP

• EPA Reg No: 264-341
• Registrant: BAYER CROPSCIENCE, LLC
• Signal word: Warning
• Active ingredients: Thiodicarb (75.2%)
• Label accepted: 1993-06-25
• Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/000264-00341-19930625.pdf

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, , \ r) l PI d Inllr1Jcllonl on ,.".,.. t»ton completing fOrm .... , .. Form ~5!oved OMB No 2070.()()60 Approval expires 11-30-93 . United StaleS Environmental Protoction Agency opp loonllhcr Numoor (A) &EPA ()rfu;e of Peslieide Prog<ams (H7505C) § .eg.s.nIt'on Washinglon, DC 20460 X Amendment 196645 Application for Pesticide: Other Section I

1. CompenylProduct Number 2. EPA Product Manager 3. Proposed Classifica~on 264-341 Dennis Edwards ~None D Restricted 4. CompanylProducl (Name) LARVIN brand Thiodicart PMt Insecticide 75WP Wettable Powder 19
2. Name and Address 01 Appficant (/ncluds ZIP Code) 6. Expedhed Review. In accordance wh FIFRA Section 3(c)(3) Rhone-Poulenc Ag Company (b)(i), my product is similar or identical in composion and labeling 2 1. W. Alexander Drive to: RTP. NC 27709 EPA Reg. No. D Check if /his is a new 8'**"ss Product Name Section II ~ Amendment· Explain below Final printed labels in response to r-- Agency letter dated I Resubmission in response to Agency letter dated "Me Too" Application. :!J Notification· Explain below. r-- Other • explain below. Explanation: Use addtional pagels) if necessary. (For section I and Section II.) Notification per PR Notice 88-6. This is to certify that this notification meets every requirement of PR Notice 88-6. STATEMEN1:~~~~ Notification of compliance with PR Notice 93-3. LABELING APPLICATION TO WATER. DAT£. 1,,/2q7~;J Section III I ,
3. 1I.tert.s Thla Product WI" lie Pac:Uged In: Child-Resi.lant Packaging Unit Packaging Water Solubfe Packaging 2 Type of Container B Ves' aves Bves ~r Plaslie No No No Glass If 'Ves: No. par If "Yes: No. per Paper • CertlflCllflon must be Un Package wgl. container Package wgl. container Other (Specify) ~ 1
4. location of Net Conlenls Information 4. Size(s) of Reta~ Container 5. location of label Oirections Dlabel o Container BOn label • On labe~ng accomDanyinO bl'bduci
5. Manner In Which label Is Affixed To Product §raph D Other ( ) : .. :. Paparglued •••• 0 0 0 0 Stenciled 00 0 ••••• Section IV 00
6. Conlact Poinl (Complere if","s drecy below fo, identificalion of ind,,;{jJa! 10 be contactfJd, if necessary, to process this aPi-Goo!,?,) ••• c • ~ Name nla Telephone No., (1'JClu,OO Aretl f:/,ddj Patricia L. Kwiatkowski Associate Registration , , , • , . , Manager 919-549-231 t Ct' • , • , .. - Certification 6. pate' "Aolocal"", ••••• I certify that the statements I have made on this form and arlattaehmenlS thereto %;1 ..... ' accurate and complete R .... t..t.i\ed • • •• .. I acknowtedge that any knowingly false or misleading slatement may be punisha by fine or imprisonmenl or (St."'ped) both under applicabfe law Iw aMe ~ /J/ (j, 3 T,~e A{LW, ~,'I, 1 ' Associate Registration Manager ~ Typed Name ,/ 5 Date Patricia L. Kwiatkowski June 25, 1993 EPA Fonn 1570·1 IR..,.12-90) Prevtou. edlion. ar. oil ...... While· EPA Fole Co or: tnal py ( ~ Vellow· A pol """,I co

LARVIN® brandThiodicarb Insecticide 75WP WETTABLE POWDER ACTIVE INGREDIENT THIODICARB: Dimethyl N, N' (thiobis [(methylimlno) cartlonyloxy)) bis (ethanimidothioate) ............................. 75.2% INEINGREDI~~ ................................................................................................................................ 24.R EPA Realstratlon No. 264-341 EPA Establlshmont No. 3125-MQ·01 KEEP OUT OF REACH OF CHILDREN WARNING AVISO LA USUARIO: Si usted no lee ingles, no use este producto hasta que la etiqueta Ie haya sido explicada ampliamente. (TO THE USER): If you cannot read English, do not use this product until the label has been fully explained to you.) For PROPUCT 1LSE. Information Call 1-800-334-9745. For MEPICAL And TRANSPORTATION Emergencies ONLY Call 24 Hours A Day 1-800-334-7577. STATEMENT OF PRACTICAL TREATMENT IF SWALLOWED: Drink t or 2 glasses of water and induce vomrting by touching back of throat whh finger. Never give anything by mouth to an unconscious or convulsing person. Call a physician and follow General advice listed below. IF IN EYES: Flush eyes with plenty of water. Get medical attention if irritation persists. IF ON SKIN: Wash thoroughly with soap and water. IF INHALED: Call a physician and follow General advice listed below GENERAL Contact a physician immediately in all cases of suspected poisoning. If breathing stops, establish an airway, start .ortijicial resporation. and provide oxygen. Make certain to remove all sources of continuing contam;nation. Remove clothing and wash skin and hair immediately wrth large amounts of water. Transport the patient to a physician or hospital immediately and SHOW A COPY OF THIS LABEL TO THE PHYSICIAN. NOTE TO PHYSICIAN LARVIN thiodicarb is an oxime carbamate insecticide, which IS a cholinesterase Inhibitor. Overexposure to this substance may cause toxic signs and symptoms due to stimulation of the cholinergic nervous system. These effects of overexposure are spontaneously and rapidly reverSible. Specdic treatment consists of parenteral atropine sulfate. Caution should be maintained to prevent ove, atropinization. Mild cases may be given 1 to 2 mg intramuscularly every 10 minutes until full atropinizatIOn has been achieved and repeated thereafter whenever symptoms reappear. Severe cases should be given 2 to 4 mg Intravenously every 10 minutes until fully atropinized, then intramuscularly every 30 to 60 minutes to maintain the effect for at least 12 hours. Dosages for children should be approproately reduced. Complete recovery from overexposure IS to be expected wrthin 24 hours. Narcotics and other sedatives should not be used. Further. drugs like 2-PAM (pyridine-2-aldoXime methiodide) are NOT recomn'ended unless organophosphate IntoxicatIOn is also suggested. To aid in confirmation of a diagnosis, urine samples should be obtained wrth,n 24 hours of exposure and immediately frozen. Analyses will be arranged by RhOne-Poulenc Ag Company. ConsunatlOn on therapy can be obtained at all hours by calling the Rh6ne-Poulenc emergency number: 1 -!l00-334-7577 . PRECAUTIONARY STATEMENTS WARNING HAZARDS TO HUMANS AND DOMESTIC ANIMALS ••• • •••• • •• •• • • •• • • ••••• • •• • • •••••• • • •• ••• ••••• May be harmful or fatal If swallowed or Inhaled. May be harmful If absorbed through the skl~. May be ,rrrtating t(, ey~ and m;l¥~~e mild skin sensrtization. Do not take internally. Avoid contact With skin. eyes or clothing. Avoid breathing spray fll'st:': • . . .. . Wear long-sleeved clothing While uSing. Remove contaminated clothing daily: wash before reuse. Wash exposed sk,n thorowh soap and water alter 'Jse and before eating or smoking. l)iscontlnue use d allergiC reaction oc·curs. • ••• • •• •• • •••• • • • •• •• •• •••••• • • •• ••

SIGNS AND SYMPTOMS OF OVEREXPOSURE: Salivation, Watery eyes, Pinpoint eye pupils, Blurred vision, Muscle trem:"s, Cifficult breathing, ExceSSive sweating, Abdominal cramps, Nausea, Voming, Diarrhea, Weakness, Headache. In severe cases, convulsions, unconSCiousness and respiratory failure may'lCCur. ANTIDOTE STATEMENT ATROPINE SULFATE IS HIGHLY EFFECTIVE AS AN ANTIDo.TE. See NOTE TO. PHYSICIAN. ENVIRONMENTAL HAZARDS Far tan..uial u .... do not IIPPIY directly to water, or to areas where surface water is prasent or to intertidal areas befow the mean higll water mark. Do not apply when weather conditions favor drift from area treated. This product is toxic to bees exposed to direct treatment. Do not apply when bees are actively visiting the treatment area. DIRECTIONS FOR USE It I. a vlolallon of Federal Law to usa this product In a manner Inconslstant with Its labanng. Read enllre label before ualng this product. Do not use LARVIN'" 75WP except as directed on this label or on other Rhone·Pouler,,, Ag Company supplemental labeling for this product. GENERAL WORKER PROTECTION STATEMENTS Do not apply this product in such a manner as to directly or through drrtt expose workers or other persons. The area being treated must be vacated by unprotected persons. Do not enter treated areas without protective clothing until sprays have dried. Because certain states may require more restrictive reentry Intervals for various crop tr&ated with this product. consult your State Department of Agricutture for further information. Written or oral warnings must be given to workers who are expected to be in a treated area or in an area about to be treated with this product. Advise workers to stay out of fields during applicatlUn and until sprays have dried. Regulc.r long-sleeved wO'k clothing should be worn when working in treated fields. See Precautionary Statement, Statement of Practical Treatment and Note to Phyalclan for information on accidental exposures. When oral warnings are given, warnings shall be given in a language customarily understood by workers. o.ral warnings must be given rt there is reason to believe that written warnings cannot be understood b~ workers. Written warnings must include the following information: appropriate signal word (WARNING), area treated with LARVIN brand Thiodicarb Insecticide 75WP, date of application, appropriate protective clothing, appropriate reentry interval, rt applicable. STORAGE: Do not store in or around the home. Store unused product In a cool. ventilated. dry. locked area. Do not allow prolonged storage in areas where temperatures frequently exceed t 15"F (46°C). Do not contaminate lood, water or feed by storage or disposal. NEVER TRANSFER THIS PROOUCT TO. ANOTHER CONTAINER FOR STORAGE. PESTICIDE DISPOSAL: WaSles ;esuiting f;om lhe use of this product may be disposed of on Me or at an approved waste disposal facility. DISPOSAL: REUSE EMPTY Co.NTAINERS. Completely ACCIDENTS: In case of a major spoil of LARVIN'" Thiodicarb InsectICide 75WP: TELEPHONE (24 HOURS A DAY) IN THE USA 1-800-334-7577. In case of minor spills or leaks follow all precautions indicated above and cleanup Immediately. Soak up With sitS~. earth or other suitable material and dispose of wastes and broken or empty containers in a landfill approved for pesticide use. • •••••• •••• • •• • •• • • •• • •••••• • • • •• • •• • • •• • ••• • •• •• • • • •• •• • ••• • • • • •• •• •• ••••• • • ••••• • •••••• • • •• •••••• • • •• ••

• GENERAL INFORMATION LARVIN" 75WP is a wenable powder concentrate formulation of Thiodicarb Insecticide that readily disperses i" water for purposes of spraying by ground or air equipment. Directions on this label are based on tests and field experience relating to effectiveness, impact on environment and residues remaining in food and feed. READ THE ENTIRE LABEL AND OBSERVE ALL LABEL DIRECTIONS AND PRECAUTIONS BEFORE USE. GENERAL DIRECTIONS SPRAY PREPARATION Remove oil, rust, scale, pesticide residues and other foreign matter from sprayer and strainer. Flush with clean water. Use 50 mesh screens or Iotted strainers in spray system. To prepare for spraying, fill tank approximately one-naH full of water. Add LARVIN" 75WP InsecticiC:e and mix thoroughly by nechanical or hydraulic agitation. Finish filling tank with water to desired volume and thoroughly mix. Do not store spray mixture for prolonged periods. If tank-mixes are to be used, LAAVIN" 75WP must be fully dispersed in water first, followeU by the addl·ion of the Intended tank-mix material. APPLICATION Begin application when insect populations :each recognized economic threshold levels. Consult the Cooperative Extension Service, Professional Consuttants or other qualdied authorities to determine appropriate threshold levels for treatment in your area. Apply a minimum finished spray volume of 3 gallons per acre by air or 15 gallons per acre by ground for sweet corn. Repeat application as needed to maintain control. Use higher dcsage rates for heavier infestations or larger larvae. Use lower rates for light to moderate infestations. To clean the sprayer after use, drain and fluc.h with water. DIRECTIONS FOR USE THROUGH SPRINKLER IRRIGATION SYSTEMS Apply this product only through sprinkler Irrigation systems including center pivot and solid set. Do not apply this product through any other type of irrigation system. SPRAY PREPARATION Remove scale, pesticide residues, and other foreign matter from the chemical tank and entire injector system. Flush with clean water. APPLICATION INSTRUCTIONS First prepare a suspension of LARVIN" brand Thiodicarb Insecticide 75WP in a mix tank. Fill tank with 112 to 3/4 the deSired amount of water. Stan mechanical or hydraulic agitation. Add the required amount of LARVIN" brand 75WP, and then the remaining volume of water. (Suspension concentrations using the appropriate dosage per acre recommended on this label of LARVIN" brand 75WP per t to 4 gallons of water are rocommended).Then set sprinkler to deliver O.t to 0.3 inch of water per acre. Stan sprinkler and undormly inject the suspension of LARVIN" brand 75WP into the ;rrigatlOn water line so as to deliver the desired rate per acre. The suspension of LARVIN" brand 75WP should be injected with a positive displacement pump into the main line ahead of a right angle turn to insure adequate mixing. If you should have any other questrons about calibration, you should contact State ExtenSion Service specia,ists, equipment manufacturers or other expens. NOTE: When treatment with LAAVIN" brand Thiodicarb Insecticide 75WP has been completed, further field irrigation over the treated area should be avoided for 24 to 48 hours to prevent washing the chemical off the crop. GENERAL PRECAUTIONS FOR APPLICATIONS THROUGH SPRINKLER IRRIGATION SYSTEMS Maintain continuous agitation in mix tank dUring mixing and application to assure a undorm suspension. Greater accuracy in calibration and distributIOn Will be achieved by injecting a larger volume of a more dilute solution per unit time. The system must contain a functional check valve. vacuum relief valve, and low pressure uain appropriately located on the irrigation pipeline to prevent water source contamination irom backilow. The pesticide Injection pipeline must contain a functional, automatic, quick-closlng check valve to prevent the flow of fluid back toward the injection pump. The pesticide injection pipeline must also contain a functional, normally closed solenoid-operated valve :ocated on the intake Side of the injection pump and connected to the system interlock to prever,t fluid from being withdrawn from the supply tank when the irrigation system is either automatically or manually shutdown. The system must contain functional interlocking controls to automatically shut off the pesticide Injection pump when the water pump motor stops. The irrigation line or water pump must include a functional pressure SWitch which will stop the water pump motor when the water pressure decreases to the point where pesticide distribution is adversely affected. Systems must use a metering pump, such as a positive displacement injection pump (e.g., diaphragm pump) effectively designed and constructed of materials that are compatible with pesticides and capable of being fitted with a system Interlock. Do not apply when wind speed.Clvors drift beyond the area Intended for treatment. • •••••• Do not apply when wind speed favors drift. when system connection or fittings leak, whpn nozzles do not provld~~rirC:.,", distrllut,on er when lines containing the product must be dismantled and drained. ••• •••••• • •• Croo Inlury, lack of effectiveness, or illegal pesticide reSidues In the crop may result from non-undorm distributiolIf trwated water." • • ••• ••••• Allow suffiCient time for pestiCide to be flushed through all lines and all nozzles before turning off IIIIgallon .... ater. A !JOrs.n • • •••• knowledgeable of the chemlgatlon system and responsible for Its operation shall shut the system down an .... ke necessary adjustments should the need arise. • ••• : • •••••• Do not connect an irrigation system (Including greenhouse systems, used for pesticide applicatIOn to a public waterystem unl!l!;.tPte label-prescribed safety deVICes for public waler supplies are In place. • •• •• • •••• • • • • • •• •• •••••• • • •• ••

COMPATIBILITY

LARVIN" 75WP, when diluted w~h ai' equal volume of water, is p ,ysically compatible with a wide range of commonly used spray

products, but the full range of compatibil~ies under local conditions s not known. Therefore, it is essential that before using any tank

mixture of LARVIN" 75WP Insecticide, the compatibility of the IT.ixture be established. Add a small amount of LARVIN" 75WP

Insecticide to an equal volume of water in a small container and th'.n add the other pesticide or spray product and mix thoroughly. DO

NOT USE MIXTURES THAT CURDLE, PRECIPITATE, OR GREJ,SE. THIS PRODUCT IS NOT MISCIBLE WITH VEGETABLE OIL

DILUENTS. TANK MIXlURES SHOULD BE USED WITHIN 6 HOUF.S AFTER MIXING.

NOTE: LARVIN Thiodicarb Insecticide is hydrolytically sensitive co degradation of active ingredient by strong acids, strong bases, and

certain heavy metal oxides and satts of certain fungicides such us Maneb, Mancozeb, Copper Count N·8, and Bordeaux mixture. DO

NOT USE lARVIN 75"'WP INSECTICIDE IN SPRAY MIXTURES WITH THE ABOVE METAL PRODUCTS. DO NOT ADD LARVIN" 75WP

TO WATER WITH pH VALUES BELOW 3.0 OR ABOVE 8.5. H necessary, water should be buffered within this range before adding

LARVIN" Thiodicarb Insecticide

RECOMMENDED USES

DOSAGE PER ACRE

POUNDS FLUID

CROP INSECT ACTIVE OUNCES SPECIFIC DIRECTIONS

Sweet Corn Corn earworm 0.5 0.66 Insects attacking silks and ears:

(Fresh Market Only) European corn borer to to Apply at 1·7 day intervals starting

0.75 1.00 when silks first appear and

Armyworms (Florida Only) continuing until silks begin to dry

Western bean cutworm or infestation potential ceases.

follow local recommendations for

proper timing. Whorl or foliage feeders: For best results, use sprays of 15 gallons or more per acre applied by ground equipment using solid or hollow cone nozzles directed into the plant whorl. Also refer to general directions for use. PREHARVEST AND GRAZING USE INFORMATION AND LIMITATIONS To avoid illegal residues in or on: SWEET CORN • After silk initiation, do not exceed 7.5 pounds of active ingredient (10 pounds of LARVIN® 75WP) per acre per season. Do not allow livestock to graze treated fields. Do not feed treated corn silage (green plant) or fodder to livestock. Ears may be harvested on day of last application. FIELD USE CONVERSION TABLE DOSAGE PER ACRE POUNDS ACTIVE FLUID OUNCES 0.25 0.33 0.33 0.44 0.40 0.53 0.45 0.60 0.50 0.66 0.55 0.73 0.60 0.80 065 087 0.70 0.93 0.75 '.00 ACRES TREATED BY 10 LBS. OF LARVIN" 75WP 30.3 22.7 • 18.9 ••• 16.6 • ..... ~ 15.2_ •• :-. . . ~ . ~ 13.7 •• • ..... '" 12.5 • · ~ •• '1.5:· • • • •• re. 10.7- •• • 10.0 • ••••• ••• • • • • •••••• • • • • •• •• • •••• • • • •• •• •• •• •••••• • • •• ••

LIMITED WARRANTY AND DISCLAIMER The manufacturer warrarts (a) that this product corforms to the chemical description on the label: (0) that this product is reasonably fit for the purposes set forth in the directions for use when It IS used In accordance with such dllectlons; and (c) that the directions, warn;r>gs and other statements on this label ate based upon responsible experts' evaluation of reasonable tests of effectiveness, of toxicity to laboratory animals and to plants, and of r .. sidues on food crops, and upon reports of field experiences. Tests have not been made on all varieties or In all states or under all conditions. THE MANUFACTURER NEllliER MAKES NOR INTENDS, NOR DOES IT AUTHORIZE ANY AGENT OR REPRESENTATIVE: TO MAKE, ANY OTHER WARRANTIES, EXPRESS OR IMPLIED, AND IT EXPRESSLY EXCLUDES AND DISCLAIMS ALL IMPLIED WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE. THIS WARRANTY DOES NOT EXTEND TO, AND THE BUYER SHALL BE SOLELY RESPONSIBLE FOR, ANY AND ALL LOSS OR DAMAGE WHICH RESULTS FROM THE' USE OF THIS PRODUCT IN ANY MANNER WHICH IS INCONSISTENT WITH THE LABEL DIRECTIONS, WARNINGS OR CAUTIONS. BUYER'S EXCLUSIVE REMEDY ANLl MANUFACTURER'S OR SELLER'S EXCLUSIVE LIABILITY FOR ANY AND ALL CLAIMS, LOSSES, DAMAGES, OR INJURIES RESULTING FROM THE USE OR HANDLING OF llilS PRODUCT, WHElliER OR NOT BASED IN CONTRACT, NEGLIGENCE, STRICT LIABILITY IN TORT OR OlliERWISE, SHALL BE LIMITED, AT lliE MANUFACTURER'S OPTION, TO REPLACEMENT OF, OR lliE REPAYMENT OF lliE PURCHASE PRICE FOR, lliE QUANTITY OF PRODUCT Willi RESPECT TO WHICH DAMAGES ARE CLAIMED. IN NO EVENT SHALL MANUFACTURER OR SELLER BE LIABLE FOR SPECIAL, INDIRECT OR CONSEOUENTIAL DAMAGES RESUL liNG FROM lliE USE OR HANDLING OF llilS PRODUCT. NOTICE TO THE BUYER Purchase of this material dOGS not confer any rights under patents governing this product or the use thereof in coun!ries C'utside of the United States. RhOne-Poulenc Ag Company P.O. Box t2014, 2 T. W. Alexander Drive Research Triangle Park, !ot1h Carolina 27709 U.S. Pall.nt No.: 4,382,957 LARVIN" is a registered trademri< of RhOne-Poulenc LARVIN" 75WP (M ASTER) NotrtlCatlOn 6125193. • ••• • •••• • • • ., • • •• • • • • • •• • •• • • • • •• • • • •• • • • •••• • • • • • •• .. •••••• • • • • • •••••• • • •• ...... • • ••••• • ........ • • •• •••••• • • •• ••