crop-chem-docs/corpus/bayer/luna-tranquility.md

Luna Tranquility Fungicide

• Product class: fungicide
• EPA Reg No: 264-1085
• Active ingredients: Pyrimethanil, Fluopyram
• Source: https://www.cropscience.bayer.us/crop-protection/fungicide/luna-tranquility-fungicide
• Label PDF: https://cs-assets.bayer.com/is/content/bayer/Luna_Tranquility_Label1etpdf

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US61380432I (210127Iv4) LABMC LUNA TRANQUILITY 2.5 GAL US colors: cmyk 05/03/23 (Label Coordinator: Mark Schmidt) Net Contents: 2.5 Gallons US61380432I 210127Iv4 05/23 Produced for Bayer CropScience LP 800 N. Lindbergh Blvd. St. Louis, MO 63167 Luna Tranquility is a registered trademark of Bayer Group. ©2023 Bayer Group. All rights reserved. Broad spectrum fungicide for control of plant diseases. Berry, low growing, except cranberry, subgroup 13-07G; Bushberry subgroup 13-07B; Caneberry subgroup 13-07A; Fruit, pome, group 11-10; Ginseng; Lemons; Onion, bulb, subgroup 3-07A; Onion, green, subgroup 3-07B; Tomato; Vegetable, tuberous and corm, subgroup 1C. ACTIVE INGREDIENT: FLUOPYRAM* .................................................. 11.3% PYRIMETHANIL* ................................................ 33.8% OTHER INGREDIENTS: .......................................... 54.9% TOTAL: 100.0% Contains 1.04 lbs FLUOPYRAM and 3.12 lbs PYRIMETHANIL per gallon *(CAS Numbers 658066-35-4 and 53112-28-0) EPA Reg. No. 264-1085 KEEP OUT OF REACH OF CHILDREN CAUTION See additional precautionary statements and directions for use on label. GROUP GROUP 9 7 FUNGICIDE FUNGICIDE PYRIMETHANIL FLUOPYRAM

1 FIRST AID IF SWALLOWED: • Call a poison control center or doctor immediately for treatment advice. • DO NOT induce vomiting unless told to do so by a poison control center or doctor. • Have person sip a glass of water if able to swallow. • DO NOT give anything by mouth to an unconscious person. IF ON SKIN:

• Take off contaminated clothing. • Rinse skin immediately with plenty of water for 15-20 minutes. • Call a poison control center or doctor for treatment advice. IF INHALED: • Move person to fresh air. • If person is not breathing, call 911 or an ambulance, and then give artificial respiration, preferably mouth-to-mouth if possible. • Call a poison control center or doctor for further treatment advice. For MEDICAL Emergencies Call 24 Hours A Day 1-800-334-7577. In case of emergency call toll free the Bayer CropScience Emergency Response Telephone No. 1-800-334-7577. Have a product container or label with you when calling a poison control center or doctor, or going for treatment. NOTE TO PHYSICIAN: Treat Symptomatically. For PRODUCT USE Information Call 1-866-99BAYER (1-866-992-2937) PRECAUTIONARY STATEMENTS HAZARDS TO HUMANS AND DOMESTIC ANIMALS CAUTION Harmful if swallowed, absorbed through skin or inhaled. Avoid contact with skin, eyes, or clothing. Avoid breathing vapor or spray mist. Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, or using tobacco. Remove and wash contaminated clothing before reuse. Personal Protective Equipment (PPE): Applicators and other handlers must wear long-sleeved shirt and long pants, shoes plus socks, and chemical-resistant (including nitrile or butyl) gloves. User Safety Requirements Follow manufacturer’s instructions for cleaning/maintaining PPE. If no such instructions exist for washables, use detergent and hot water. Keep and wash PPE separately from other laundry. ENGINEERING CONTROL STATEMENTS: When handlers use closed systems, enclosed cabs, or aircraft in a manner that meets the requirements listed in the Worker Protection Standard (WPS) for agricultural pesticides 40 CFR 170.240(d)(4-6), the handler PPE requirements may be reduced or modified as specified in the WPS. USER SAFETY RECOMMENDATIONS Users should: • Remove clothing/PPE immediately if pesticide gets inside. Then wash thoroughly and put on clean clothing. • User should remove PPE immediately after handling this product. Wash the outside of gloves before removing. As soon as possible, wash thoroughly and change into clean clothing. ENVIRONMENTAL HAZARDS For terrestrial uses: DO NOT apply directly to water, or to areas where surface water is present or to intertidal areas below the mean high water mark. DO NOT contaminate water when disposing of equipment wash water or rinsate. This product may impact surface water quality due to runoff of rain water. This is especially true for poorly draining soils and soils with shallow ground water. This product is classified as having high potential for reaching surface water via runoff for several months or more after application. A level, well-maintained vegetative buffer strip between areas to which this product is applied and surface water features including ponds, streams, and springs will reduce the potential loading of Fluopyram. Runoff of this product will be reduced by avoiding applications when rainfall or irrigation is expected to occur within 48 hours. Sound erosion control practices will reduce this product’s potential to reach aquatic sediment via runoff.

2 This chemical has properties and characteristics associated with chemicals detected in ground water. This chemical may leach into groundwater if used in areas where soils are permeable, particularly where the water table is shallow. DIRECTIONS FOR USE It is a violation of federal law to use this product in a manner inconsistent with its labeling. Read entire label before using this product. STOP - READ THE LABEL BEFORE USE DO NOT apply this product in a way that will contact workers or other persons, either directly or through drift. Only protected handlers may be in the area during application. For any requirements specific to your State or Tribe, consult the agency responsible for pesticide regulation. Not for sale, distribution, or use in Nassau and Suffolk counties, New York except as permitted under FIFRA 24(c), Special Local Need registration. AGRICULTURAL USE REQUIREMENTS Use this product only in accordance with its labeling and with the Worker Protection Standard, 40 CFR part 170. This Standard contains requirements for the protection of agricultural workers on farms, forests, nurseries, and greenhouses, and handlers of agricultural pesticides. It contains requirements for training, decontamination, notification, and emergency assistance. It also contains specific instructions and exceptions pertaining to the statements on this label about personal protective equipment (PPE) and restricted entry interval. The requirements in this box only apply to uses of this product that are covered by the Worker Protection Standard. DO NOT enter or allow worker entry into treated areas during the restricted-entry interval (REI) of 12 hours. PPE required for early entry to treated areas that is permitted under the Worker Protection Standard and that involves contact with anything that has been treated, including plants, soil, or water is: coveralls over long-sleeved shirt and long pants, socks and shoes, and chemical-resistant gloves made of any waterproof material including natural rubber ≥ 14 mils. PRODUCT INFORMATION LUNA TRANQUILITY®: • is a broad-spectrum fungicide with preventative, systemic, and curative properties labeled for the control or suppression of certain crop diseases. • is formulated as a suspension concentrate (SC). • is labeled on the following: Berry, low growing, except cranberry, subgroup 13-07G; Bushberry subgroup 13-07B; Caneberry subgroup 13-07A; Fruit, pome, group 11-10; Ginseng; Lemons; Onion, bulb, subgroup 3-07A; Onion, green, subgroup 3-07B; Tomato; Vegetable, tuberous and corm, subgroup 1C. USE RESTRICTIONS DO NOT apply more than the maximum yearly rate for each specific crop from any combination of products containing FLUOPYRAM or PYRIMETHANIL. FUNGICIDE RESISTANCE MANAGEMENT (FRAC) For resistance management, please note that LUNA TRANQUILITY contains both a Group 7 and Group 9 fungicide. Any fungal population may contain individuals naturally resistant to LUNA TRANQUILITY and other Group 7 or Group 9 fungicides. A gradual or total loss of pest control may occur over time if these (fungicides) are used repeatedly in the same fields. Appropriate resistance-management strategies should be followed. To delay fungicide resistance, take one or more of the following steps: • Rotate the use of LUNA TRANQUILITY or other Group 7 or Group 9 fungicides within a growing season sequence with different groups that control the same pathogens. • Use tank mixtures with fungicide from a different group that are equally effective on the target pest when such use is permitted. Use at least the minimum application rate as labeled by the manufacturer. • Adopt an integrated disease management program for fungicide use that includes scouting, uses historical information related to pesticide use, and crop rotation, and which considers host plant resistance, impact of environmental conditions on disease development, disease thresholds, as well as cultural, biological and other chemical control practices. • Where possible, make use of predictive disease models to effectively time fungicide applications. Note that using predictive models alone is not sufficient to manage resistance.

3 • Monitor treated fungal/bacterial populations for resistance development. • Contact your local extension specialist or certified crop advisor for any additional pesticide resistance-management and/or IPM recommendations for specific crops and pathogens. • For further information or to report suspected resistance contact Bayer CropScience at 1-866-99BAYER (1-866-992-2937). You can also contact your pesticide distributor or university extension specialist to report resistance. MANDATORY SPRAY DRIFT Aerial Applications • For aerial applications, do not apply when wind speeds exceed 15 mph at the application site. If the wind speed is greater than 10 mph, the boom length must be 65% or less of the wingspan for fixed wing aircraft and 75% or less of the rotor diameter for helicopters. Otherwise, the boom length must be 75% or less of the wingspan for fixed-wing aircraft and 90% or less of the rotor diameter for helicopters. • Do not release spray at a height greater than 10 ft above the ground or vegetative canopy, unless a greater application height is necessary for pilot safety. • Applicators must use ½ swath displacement upwind at the downwind edge of the field. • Do not apply during temperature inversions. Airblast applications • Sprays must be directed into the canopy. • Do not apply when wind speeds exceed 15 miles per hour at the application site. • User must turn off outward pointing nozzles at row ends and when spraying outer row. • Do not apply during temperature inversions • Ground Boom Applications • Apply with the nozzle height recommended by the manufacturer, but no more than 4 feet above the ground or crop canopy. • Applicators are required to use a medium or coarser droplet size (ASABE S572. I). • Do not apply when wind speeds exceed 15 miles per hour at the application site. • Do not apply during temperature inversions. SPRAY DRIFT ADVISORIES THE APPLICATOR IS RESPONSIBLE FOR AVOIDING OFF-SITE SPRAY DRIFT BE AWARE OF NEARBY NON-TARGET SITES AND ENVIRONMENTAL CONDITIONS. IMPORTANCE OF DROPLET SIZE An effective way to reduce spray drift is to apply large droplets. Use the largest droplets that provide target pest control. While applying larger droplets will reduce spray drift, the potential for drift will be greater if applications are made improperly or under unfavorable environmental conditions. Controlling Droplet Size -Ground Boom • Volume - Increasing the spray volume so that larger droplets are produced will reduce spray drift. Use the highest practical spray volume for the application. If a greater spray volume is needed, consider using a nozzle with a higher flow rate. • Pressure - Use the lowest spray pressure recommended for the nozzle to produce the target spray volume and droplet size. • Spray Nozzle - Use a spray nozzle that is designed for the intended application. Consider using nozzles designed to reduce drift. Controlling Droplet Size –Aircraft • Adjust Nozzles -Follow nozzle manufacturers recommendations for setting up nozzles. Generally, to reduce fine droplets, nozzles should be oriented parallel with the airflow in flight. BOOM HEIGHT-Ground Boom • For ground equipment, the boom should remain level with the crop and have minimal bounce. RELEASE HEIGHT – Aircraft • Higher release heights increase the potential for spray drift. SHIELDED SPRAYERS • Shielding the boom or individual nozzles can reduce the uniform deposition of the spray on the target area. TEMPERATURE AND HUMIDITY • When making applications in hot and dry conditions, use larger droplets to reduce effects of evaporation.

4 TEMPERATURE INVERSIONS • Drift potential is high during a temperature inversion. Temperature inversions are characterized by increasing temperature with altitude and are common on nights with limited cloud cover and light to no wind. The presence of an inversion can be indicated by ground fog or by the movement of smoke from a ground source or an aircraft smoke generator. Smoke that layers and moves laterally in a concentrated cloud (under low wind conditions) indicates an inversion, while smoke that moves upward and rapidly dissipates indicates good vertical air mixing. • Avoid applications during temperature inversions. WIND • Drift potential generally increases with wind speed. AVOID APPLICATIONS DURING GUSTY WIND CONDITIONS. Applicators need to be familiar with local wind patterns and terrain that could affect spray drift. Handheld Technology Applications • Take precautions to minimize spray drift. APPLICATION INFORMATION Ground Application For optimum disease control, apply in sufficient water to ensure thorough coverage of foliage, bloom, and fruit. Aerial Application For aerial application equipment, a minimum of 10 gallons of water per acre for tree crops and 2 gallons of water per acre for field and vegetable crops is required. Air-Blast Application Air-assisted or air-blast sprayers move spray droplets into the crop canopy using a forced-air system. The fan must be set up to deliver only enough air volume to penetrate the canopy and provide good coverage. Adjust deflectors or other aiming devices to direct spray only to the target area. Equip sprayers with nozzles that provide accurate and uniform application. Greenhouse Application LUNA TRANQUILITY may be used on tomatoes and strawberries and other low-growing berries (except cranberries) as foliar applied treatment only in greenhouses with good resistance management programs. See crop-specific use directions. Crop safety has not been confirmed on all cultivars. Plant compatibility testing is advised when first using under your greenhouse conditions. LUNA TRANQUILITY is physically compatible with most commonly used fungicide, herbicide, insecticide, and foliar nutrient products. However, the compatibility of LUNA TRANQUILITY with all potential tank-mix partners has not been fully investigated. For compatibility testing, please refer to directions in the “Spray mixing and compatibility” section. For greenhouse uses apply only in well-ventilated plastic tunnel houses or glass houses. Ventilate for at least 2 hours after application. Prevent intense sunlight exposure for several hours after application. Solutions must be used within one day of mixing. Chemigation Application Apply this product only through center pivot, motorized-lateral move, traveling gun, and solid set or portable (wheel move, side roll, end tow, or hand move) irrigation systems. DO NOT apply this product through any other type of irrigation system. Crop injury, lack of effectiveness, or illegal pesticide residues in the crop can result from non-uniform distribution of treated water. If you have questions about calibration, you must contact State Extension Service specialists, equipment manufacturers or other experts. A person knowledgeable of the chemigation system and responsible for its operation or under the supervision of the responsible person, must shut the system down and make necessary adjustments if the need arises. LUNA TRANQUILITY Fungicide has not been sufficiently tested when applied through irrigation systems to assure consistent product performance for all labeled uses. The following application techniques are provided for user reference but DO NOT constitute a warranty of fitness for application through sprinkler irrigation equipment. DO NOT connect an irrigation system (including greenhouse systems) used for pesticide application to a public water system, unless the pesticide label prescribed safety devices for public water systems are in place. ‘Public water system’ means a system for the provision to the public of piped water for human consumption if such system has at least 15 service connections or regularly serves an average of at least 25 individuals daily at least 60 days out of the year. Chemigation systems connected to public water systems must contain a functional, reduced-pressure zone (RPZ), back flow preventer or the functional equivalent in the water supply line upstream from the point of pesticide introduction. As an alternative to the RPZ, the water from the public water system must be discharged into a

5 reservoir tank prior to pesticide introduction. There must be a complete physical break (air gap) between the flow outlet end of the fill pipe and the top or overflow rim of the reservoir tank of at least twice the inside diameter of the fill pipe. The pesticide injection pipeline must contain a functional, automatic, quick-closing check valve to prevent the flow of fluid back toward the injection pump. Pesticide injection pipeline must contain a functional, normally closed, solenoid-operated valve located on the intake side of the injection pump and connected to the system interlock to prevent fluid from being withdrawn from the supply tank when the irrigation system is either automatically or manually shut down. The systems must contain functional interlocking controls to automatically shut off the pesticide injection pump, either when the water pump motor stops, or (where there is no water pump) when the water pressure decreases to the point where pesticide distribution is adversely affected. Systems must use a metering pump, like a positive displacement injection pump (e.g., diaphragm pump) effectively designed and constructed of materials that are compatible with pesticides and capable of being fitted with a system interlock. DO NOT apply when wind speed favors drift. Spray mixture in the chemical supply tank must be agitated at all times, otherwise settling and uneven application may occur. Apply pesticide continuously for the duration of the water application. For mixing instructions, please refer to directions in the “Spray mixing and compatibility” section. This product may be used through two basic types of irrigation systems as outlined in Sections A and B below. The system must contain a functional check valve, vacuum relief valve, and low-pressure drain appropriately located on the irrigation pipeline to prevent water source contamination from back flow. Determine which type of irrigation system is in place, then refer to the appropriate directions provided below for each type. See crops section on the label for required treatment rates and additional use information. A. Center Pivot, Motorized-Lateral Move and Traveling Gun Irrigation Equipment For injections of pesticides, these continuously moving systems must use a positive displacement injection pump of either diaphragm or piston type and be constructed of materials that are compatible with pesticides. They must also be capable of being fitted with a system interlock and capable of injection at pressures approximately 2-3 times those encountered within the irrigation water line. Venturi applicator units cannot be used on these systems. Thoroughly mix required amount of this product for acreage to be covered into same amount of water used during calibration and inject into system continuously for one revolution or run. Mixture in the chemical supply tank must be continuously agitated during the injection run. Shut off injection equipment after one revolution or run, but continue to operate irrigation system until this product has been cleared from the last sprinkler head. B. Solid-Set, Portable (Wheel Move, Side Roll, End Tow, or Hand Move) Irrigation Equipment With stationary systems, an effectively designed in-line Venturi applicator unit is preferred to support even and quick distribution. However, a positive-displacement pump can also be used. For solid set systems, determine acreage covered by sprinkler. Fill the tank of injection equipment with water and adjust flow to use contents over 30 to 45 minutes. Mix desired amount of this product for acreage to be covered with water so that the total mixture of this product plus water in the injection tank is equal to the quantity of water used during calibration. Provide chemical supply tank agitation sufficient for mixing until chemigation is completed. Operate entire system at normal pressures directed by the manufacturer of injection equipment used, for amount of time established during calibration. This product can be injected during the irrigation cycle or as a separate application. SPRAY MIXING AND COMPATIBILITY It is the pesticide user’s responsibility to ensure that all products are registered for the intended use. Read and follow the applicable restrictions and limitations and directions for use on all product labels involved in tank mixing. Users must follow the most restrictive directions for use and precautionary statements of each product in the tank mixture. Begin with clean spray equipment and add one-half of the required amount of water to the spray or mixing tank and start agitation. Add the required quantity of fungicide and the tank-mix partner, if applicable, to the water and complete filling with water to the required total volume. Follow the directions of your State Cooperative Extension Service for tank mixing with other products. Follow the order beginning first with water conditioners, water soluble packaging (wait for it to completely dissolve), wettable powders and water-dispersible granular products, liquid flowables and suspension concentrates, emulsifiable concentrates, and adjuvants last. Maintain agitation throughout spraying. DO NOT allow spray mixture to remain in the tank overnight or for long periods during the day without agitation. When tank mixing with other pesticides, observe the more restrictive label limitations and precautions.

6 LUNA TRANQUILITY is physically compatible with most commonly used fungicide, herbicide, insecticide, and foliar nutrient products. However, the compatibility of LUNA TRANQUILITY with all potential tank-mix partners has not been fully investigated. If tank mixing with other pesticides is desirable, conduct a jar test with the volumes and rates typically used in agricultural application. Using a small container of water, add the proportionate amounts of the products: wettable powders and water-dispersible granular products first, then liquid flowables, and emulsifiable concentrates last. After thoroughly mixing, let stand for at least 15 minutes. Look for signs of separation, globules, sludge, flakes, or other precipitates. Physical compatibility is indicated if the combination remains mixed or can be remixed readily. The crop safety of all potential tank-mixes with LUNA TRANQUILITY has not been tested on all crops. Before applying any tank-mixture not specified on this label, safety to the target crop needs to be confirmed on a small portion of the crop to be treated to ensure an adverse response will not occur. PRODUCT RESTRICTIONS AND LIMITATIONS DO NOT apply more than the maximum yearly rate for each specific crop from any combination of products containing FLUOPYRAM or PYRIMETHANIL. ROTATIONAL CROP RESTRICTIONS Areas treated with this product may be replanted immediately following harvest with any crop for which there is a registered use of FLUOPYRAM and PYRIMETHANIL. This includes: Almonds; Berry, low growing, except cranberry, subgroup 13-07G; Bushberry subgroup 13-07B; Caneberry subgroup 13-07A; Lemons; Fruit, pome, group 11-10; Fruit, small vine climbing, except fuzzy kiwifruit, subgroup 13-07F; Ginseng; Onion, bulb, subgroup 3-07A; Onion, green, subgroup 3-07B; Pistachios; Peach subgroup 12-12B; Plum subgroup 12-12C; Tomato subgroup 8-10A; Vegetable, root, except sugarbeet, subgroup 1B; Vegetable, tuberous and corm, subgroup 1C. The following crops may be replanted after 30 days after the last application of LUNA TRANQUILITY: Alfalfa; Brassica, Head and Stem, Subgroup 5A; Brassica Leafy Greens, Subgroup 5B; Carrot; Cherry subgroup 12-12A; Cottonseed subgroup 20C; Dill seed; Fruit, citrus, group 10-10; Grain, cereal, group 15 (except corn and rice) which include: barley, buckwheat, millet (pearl and proso), oats, rye, sorghum, teosinte, triticale, and wheat; Corn, field, grain; Corn, pop, grain; Corn, sweet; Herb subgroup 19A; Hop, dried cones; Leafy greens subgroup 4A; Leaf petioles subgroup 4B (except watercress); Legume Vegetables (except cowpea and dried peas); Melon subgroup 9A; Nut, tree, group 14-12; Peanut; Pepper/Eggplant subgroup 8-10B; Rapeseed subgroup 20A; Soybean; Squash/cucumber subgroup 9B; Sugarbeet, roots; Sugarcane (in region 3), Sunflower subgroup 20B. DO NOT rotate to crops other than those listed above. SPECIFIC CROP DIRECTIONS Berry, low growing, except cranberry, subgroup 13-07G Bearberry; Bilberry; Blueberry, Lowbush; Cloudberry; Lingonberry; Muntries; Partridgeberry; Strawberry; cultivars, varieties, and/or hybrids of these. Disease Control Application Rate Application Instructions Gray mold (Botrytis cinerea) Powdery mildew (Sphaerotheca macularis) 16 - 27 fl oz/acre (0.130 - 0.220 lbs fluopyram/acre) (0.391 - 0.659 lbs pyrimethanil/acre) Apply at the critical timings for disease control. Refer to University and/or extension guidelines for best application timings. When disease pressure is severe, use the higher rates and/or shorter intervals. Disease Suppression Application Rate Application Instructions Rhizopus fruit rot (Rhizopus spp.) Phomopsis leaf blight and fruit rot (Phomopsis obscurans) Leaf spot (Mycosphaerella fragariae) 27 fl oz/acre (0.220 lbs fluopyram/acre) (0.659 lbs pyrimethanil/acre) Apply at the critical timings for disease suppression. Refer to University and/or extension guidelines for best application timings. When disease pressure is severe, use the shorter intervals.

7 Restrictions: • DO NOT apply more than 54.7 fl oz of LUNA TRANQUILITY (0.446 lb fluopyram and 1.336 lb pyrimethanil) per acre per year. • Maximum number of applications per year when applied at 16 fl oz/acre (0.130 lbs fluopyram and 0.391 lbs pyrimethanil per acre): 3 • Max. Single use rate: 27 fl oz/acre (0.220 lbs fluopyram and 0.659 lbs pyrimethanil per acre) • Apply using ground, aerial, or chemigation equipment. • Regardless of formulation or method of application, DO NOT apply more than 0.446 lbs fluopyram or 2.1 lbs pyrimethanil per acre per year, including soil and foliar uses. • DO NOT apply LUNA TRANQUILITY within 1 day of harvest. • Minimum interval between applications: 7 Day(s) • To limit the potential for development of disease resistance to these fungicide classes, DO NOT make (field and greenhouse use) more than 2 sequential applications of LUNA TRANQUILITY or any Group 7 or Group 9 containing fungicide before rotating with a fungicide from a different Group. Caneberry subgroup 13-07A and Bushberry subgroup 13-07B Caneberry subgroup: Blackberry; Loganberry; Raspberry, Red And Black; Wild Raspberry; cultivars, varieties, and/or hybrids of these. Bushberry subgroup: Aronia Berry; Blueberry, Highbush; Blueberry, Lowbush; Buffalo Currant; Chilean Guava; Currant, Black; Currant, Red; Elderberry; European, Barberry; Gooseberry; Cranberry, Highbush; Honeysuckle, Edible; Huckleberry; Jostaberry; Juneberry; Lingonberry; Native Currant; Salal; Sea Buckthorn; cultivars, varieties, and/or hybrids of these. Disease Control Application Rate Application Instructions Powdery mildew (Sphaerotheca spp.) Monilinia blight and mummy berry (Monilinia spp.) Alternaria leaf spot and fruit rot (Alternaria spp.) 13.6 - 27 fl oz/acre (0.111 - 0.220 lbs fluopyram/acre) (0.332 - 0.659 lbs pyrimethanil/acre) Apply at the critical timings for disease control. Refer to University and/or extension guidelines for best application timings. When disease pressure is severe, use the higher rates and/or shorter intervals. Gray mold (Botrytis cinerea) Leaf spot and blotch (Mycosphaerella spp.) (Septoria spp.) 16 - 27 fl oz/acre (0.130 - 0.220 lbs fluopyram/acre) (0.391 - 0.659 lbs pyrimethanil/acre) Apply at the critical timings for disease control. Refer to University and/or extension guidelines for best application timings. When disease pressure is severe, use the higher rates and/or shorter intervals. Restrictions: • DO NOT apply more than 54.7 fl oz of LUNA TRANQUILITY (0.446 lb fluopyram and 1.336 lb pyrimethanil) per acre per year. • Maximum number of applications per year when applied at 13.6 fl oz/acre (0.111 lbs fluopyram and 0.332 lbs pyrimethanil per acre): 4 • Max. Single use rate: 27 fl oz/acre (0.220 lbs fluopyram and 0.659 lbs pyrimethanil per acre) • Apply using ground, aerial, or chemigation equipment. • Regardless of formulation or method of application, DO NOT apply more than 0.446 lbs fluopyram or 2.1 lbs pyrimethanil per acre per year, including soil and foliar uses. • May be applied the day of harvest. • Minimum interval between applications: 7 Day(s) • To limit the potential for development of disease resistance to these fungicide classes, DO NOT make more than 2 sequential applications of LUNA TRANQUILITY or any Group 7 or Group 9 containing fungicide before rotating with a fungicide from a different Group.

8 Fruit, pome, group 11-10 Apple; Azarole; Crabapple; Loquat; Mayhaw; Medlar; Pear; Pear, Asian; Quince; Quince, Chinese; Quince, Japanese; Tejocote; cultivars, varieties and/or hybrids of these. Disease Control Application Rate Application Instructions Grey mold1 (Botrytis cinerea) Scab (Venturia spp.) Powdery mildew (Podosphaera leucotricha) 11.2 - 16 fl oz/acre (0.091 - 0.130 lbs fluopyram/acre) (0.273 - 0.391 lbs pyrimethanil/acre) Apply at the critical timings for disease control. Refer to University and/or extension guidelines for best application timings. When disease pressure is severe, use the higher rates and/or shorter intervals. Restrictions: • DO NOT apply more than 54.7 fl oz of LUNA TRANQUILITY (0.446 lb fluopyram and 1.336 lb pyrimethanil) per acre per year. • Maximum number of applications per year when applied at 11.2 fl oz/acre (0.091 lbs fluopyram and 0.273 lbs pyrimethanil per acre): 4 • Max. Single use rate: 16 fl oz/acre (0.130 lbs fluopyram and 0.391 lbs pyrimethanil per acre) • Apply using ground, aerial, or chemigation equipment. • Regardless of formulation or method of application, DO NOT apply more than 0.446 lbs fluopyram or 1.6 lbs pyrimethanil per acre per year, including soil and foliar uses. • DO NOT apply LUNA TRANQUILITY within 72 days of harvest. • Minimum interval between applications: 7 Day(s) • To limit the potential for development of disease resistance to these fungicide classes, DO NOT make more than 2 sequential applications of LUNA TRANQUILITY or any Group 7 or Group 9 containing fungicide before rotating with a fungicide from a different Group. 1Not for use in CA without a supplemental label. Ginseng1 Disease Control Application Rate Application Instructions Alternaria blight (Alternaria panax) Botrytis blight (Botrytis cinerea) Powdery mildew (Erysiphe spp.) 16 - 27 fl oz/acre (0.130 - 0.220 lbs fluopyram/acre) (0.391 - 0.659 lbs pyrimethanil/acre) Apply at the critical timings for disease control. Refer to University and/or extension guidelines for best application timings. When disease pressure is severe, use the higher rates. Restrictions: • DO NOT apply more than 54.7 fl oz of LUNA TRANQUILITY (0.446 lb fluopyram and 1.336 lb pyrimethanil) per acre per year. • Maximum number of applications per year when applied at 16 fl oz/acre (0.130 lbs fluopyram and 0.391 lbs pyrimethanil per acre): 3 • Max. Single use rate: 27 fl oz/acre (0.220 lbs fluopyram and 0.659 lbs pyrimethanil per acre) • Apply using ground, aerial, or chemigation equipment. • Regardless of formulation or method of application, DO NOT apply more than 0.446 lbs fluopyram or 2.1 lbs pyrimethanil per acre per year, including soil and foliar uses. • DO NOT apply LUNA TRANQUILITY within 30 days of harvest. • Minimum interval between applications: 7 Day(s) • To limit the potential for development of disease resistance to these fungicide classes, DO NOT make more than 2 sequential applications of LUNA TRANQUILITY or any Group 7 or Group 9 containing fungicide before rotating with a fungicide from a different Group. 1Not for use in CA without a supplemental label.

9 Lemons1 Disease Suppression Application Rate Application Instructions Alternaria (Alternaria spp.) Penicillium rot (Penicillium spp.) 27 fl oz/acre (0.220 lbs fluopyram/acre) (0.659 lbs pyrimethanil/acre) Apply at the critical timings for disease suppression. Refer to University and/or extension guidelines for best application timing. Restrictions: • DO NOT apply more than 27 fl oz of LUNA TRANQUILITY (0.220 lb fluopyram and 0.659 lb pyrimethanil) per acre per year. • Maximum number of applications per year when applied at 27 fl oz/acre (0.220 lbs fluopyram and 0.659 lbs pyrimethanil per acre): 1 • Max. Single use rate: 27 fl oz/acre (0.220 lbs fluopyram and 0.659 lbs pyrimethanil per acre) • Apply using ground, aerial, or chemigation equipment. • Regardless of formulation or method of application, DO NOT apply more than 0.446 lbs fluopyram or 0.7 lbs pyrimethanil per acre per year, including soil and foliar uses. • Minimum 30-day interval between soil applications. • DO NOT apply LUNA TRANQUILITY within 7 days of harvest. 1Not for use in CA without a supplemental label. Onion, bulb, subgroup 3-07A and Onion, green, subgroup 3-07B Onion, bulb subgroup: Daylily, Bulb; Fritillaria, Bulb; Garlic, Bulb; Garlic, Great-Headed, Bulb; Garlic, Serpent, Bulb; Lily, Bulb; Onion, Bulb; Onion, Chinese, Bulb; Onion, Pearl; Onion, Potato, Bulb; Shallot, Bulb; cultivars, varieties, and/or hybrids of these. Onion, green subgroup: Chive, Fresh Leaves; Chive, Chinese, Fresh Leaves; Elegans Hosta; Fritillaria, Leaves; Kurrat; Lady’s Leek; Leek; Leek, Wild; Onion, Beltsville Bunching; Onion, Fresh; Onion, Green; Onion, Macrostem; Onion, Tree, Tops; Onion, Welsh, Tops; Shallot, Fresh Leaves; cultivars, varieties, and/or hybrids of these. Disease Control Application Rate Application Instructions Botrytis leaf blight, neck rot (Botrytis squamosa) (Botrytis allii) Purple blotch (Alternaria porri) Stemphylium leaf blight / stalk rot1 (Stemphylium vesicarium) 16 - 27 fl oz/acre (0.130 - 0.220 lbs fluopyram/acre) (0.391 - 0.659 lbs pyrimethanil/acre) Apply at the critical timings for disease control. Refer to University and/or extension guidelines for best application timings. When disease pressure is severe, use the higher rates and/or shorter intervals. Cladosporium leaf blotch (Cladosporium allii) 27 fl oz/acre (0.220 lbs fluopyram/acre) (0.659 lbs pyrimethanil/acre) Apply at the critical timings for disease control. Refer to University and/or extension guidelines for best application timings. When disease pressure is severe, use the shorter intervals. Disease Suppression Application Rate Application Instructions White rot (Sclerotium cepivorum) 27 fl oz/acre (0.220 lbs fluopyram/acre) (0.659 lbs pyrimethanil/acre) Apply at the critical timings for disease suppression. Refer to University and/or extension guidelines for best application timings. When disease pressure is severe, use the shorter intervals. Restrictions: • DO NOT apply more than 54.7 fl oz of LUNA TRANQUILITY (0.446 lb fluopyram and 1.336 lb pyrimethanil) per acre per year. • Maximum number of applications per year when applied at 16 fl oz/acre (0.130 lbs fluopyram and 0.391 lbs pyrimethanil per acre): 3 • Max. Single use rate: 27 fl oz/acre (0.220 lbs fluopyram and 0.659 lbs pyrimethanil per acre) • Apply using ground, aerial, or chemigation equipment. • Regardless of formulation or method of application, DO NOT apply more than 0.446 lbs fluopyram or 2.1 lbs pyrimethanil per acre per year, including soil and foliar uses. • DO NOT apply LUNA TRANQUILITY within 7 days of harvest. • Minimum interval between applications: 7 Day(s) • To limit the potential for development of disease resistance to these fungicide classes, DO NOT make more than 2 sequential applications of LUNA TRANQUILITY or any Group 7 or Group 9 containing fungicide before rotating with a fungicide from a different Group. 1Not for use in CA without a supplemental label.

10 Tomato Disease Control Application Rate Application Instructions Early blight (Alternaria solani) Black mold (Alternaria alternata) Gray leaf spot (Stemphyllium spp.) Septoria leaf spot (Septoria lycopersici) Target spot (Corynespora cassiicola) Gray mold1 (Botrytis cinerea) 11.2 fl oz/acre (0.091 lbs fluopyram/acre) (0.273 lbs pyrimethanil/acre) Apply at the critical timings for disease control. Refer to University and/or extension guidelines for best application timings. When disease pressure is severe, use the shorter intervals. Disease Suppression Application Rate Application Instructions Powdery mildew (Oidiopsis taurica / Leveillula taurica) (Sphaerotheca spp.) 11.2 fl oz/acre (0.091 lbs fluopyram/acre) (0.273 lbs pyrimethanil/acre) Apply at the critical timings for disease suppression. Refer to University and/or extension guidelines for best application timings. When disease pressure is severe, use the shorter intervals. Notes: • For greenhouse uses apply only in well-ventilated plastic tunnel houses or glass houses. • Ventilate for at least 2 hours after application. Restrictions: • DO NOT apply more than 54.7 fl oz of LUNA TRANQUILITY (0.446 lb fluopyram and 1.336 lb pyrimethanil) per acre per year. • Maximum number of applications per year when applied at 11.2 fl oz/acre (0.091 lbs fluopyram and 0.273 lbs pyrimethanil per acre): 4 • Maximum single use rate: 11.2 fl oz/acre (0.091lbs fluopyram and 0.273 lbs pyrimethanil per acre) • Apply using ground, aerial, or chemigation equipment. • Regardless of formulation or method of application, DO NOT apply more than 0.446 lbs fluopyram or 1.4 lbs pyrimethanil per acre per year, including soil and foliar uses. • DO NOT apply LUNA TRANQUILITY within 1 day of harvest. • Minimum interval between applications: 7 Day(s) • To limit the potential for development of disease resistance to these fungicide classes, DO NOT make (field and greenhouse use) more than 2 sequential applications of LUNA TRANQUILITY or any Group 7 or Group 9 containing fungicide before rotating with a fungicide from a different Group. 1Not for use in CA without a supplemental label.

11 Vegetable, tuberous and corm, subgroup 1C1 Tuberous and corm vegetables subgroup: Arracacha; Arrowroot; Artichoke, Chinese; Artichoke, Jerusalem; Canna, Edible; Cassava, Bitter And Sweet; Chayote (Root); Chufa; Dasheen; Ginger; Leren; Potato; Sweet Potato; Tanier; Turmeric; Yam Bean; Yam, True. Disease Control Application Rate Application Instructions White mold1 (Sclerotinia sclerotiorum) 11.2 fl oz/acre (0.091 lbs fluopyram/acre) (0.273 lbs pyrimethanil/acre) Apply at the critical timings for disease control. Refer to University and/or extension guidelines for best application timings. When disease pressure is severe, use the shorter intervals. Early blight (Alternaria solani) Brown spot1 (Alternaria alternata) Botrytis leaf spot1 (Botrytis cinerea) Black dot1 (Colletotrichum coccodes) Ascochyta leaf spot1 (Aschochyta cynarae) Powdery mildew1 (Erysiphe cichoracearum) (Leveillula taurica) (Erysiphe spp.) 8.0 - 11.2 fl oz/acre (0.065 - 0.091 lbs fluopyram/acre) (0.195 - 0.273 lbs pyrimethanil/acre) Apply at the critical timings for disease control. Refer to University and/or extension guidelines for best application timings. When disease pressure is severe, use the higher rates and/or shorter intervals. Restrictions: • DO NOT apply more than 54.7 fl oz of LUNA TRANQUILITY (0.446 lb fluopyram and 1.336 lb pyrimethanil) per acre per year. • Maximum number of applications per year when applied at 8.0 fl oz/acre (0.065 lbs fluopyram and 0.195 lbs pyrimethanil per acre): 6 • Max. Single use rate: 11.2 fl oz/acre (0.091 lbs fluopyram and 0.273 lbs pyrimethanil per acre) • Apply using ground, aerial, or chemigation equipment. • Regardless of formulation or method of application, DO NOT apply more than 0.446 lbs fluopyram or 1.4 lbs pyrimethanil per acre per year, including soil and foliar uses. • DO NOT apply LUNA TRANQUILITY within 7 days of harvest. • Minimum interval between applications: 7 Day(s) • To limit the potential for development of disease resistance to these fungicide classes, DO NOT make more than 2 sequential applications of LUNA TRANQUILITY or any Group 7 or Group 9 containing fungicide before rotating with a fungicide from a different Group. 1Not for use in CA without a supplemental label.

12 STORAGE AND DISPOSAL DO NOT contaminate water, food, or feed by storage or disposal. PESTICIDE STORAGE: Store in original container and keep tightly closed when not in use. Store in a cool dry place. Avoid cross-contamination with other pesticides. PESTICIDE DISPOSAL: Pesticide wastes may be toxic. Improper disposal of unused pesticide, spray mixture, or rinse water is a violation of federal law. If these wastes cannot be disposed of by use according to label instruction, contact your State Pesticide or Environmental Control Agency, or the Hazardous Waste representative at the nearest EPA Regional Office for guidance in proper disposal methods. CONTAINER HANDLING: Non-Seed Treatment Products in Non-Refillable Containers Rigid, Non-refillable containers (equal to or less than 5 gallons) Non-refillable container. DO NOT reuse or refill this container. Offer for recycling, if available. Triple rinse or pressure rinse container (or equivalent) promptly after emptying. Triple rinse as follows: Empty the remaining contents into application equipment or a mix tank and drain for 10 seconds after the flow begins to drip. Fill the container 1/4 full with water and recap. Shake for 10 seconds. Pour rinsate into application equipment or a mix tank or store rinsate for later use or disposal. Drain for 10 seconds after the flow begins to drip. Repeat this procedure two more times. Pressure rinse as follows: Empty the remaining contents into application equipment or a mix tank and continue to drain for 10 seconds after the flow begins to drip. Hold container upside down over application equipment or mix tank or collect rinsate for later use or disposal. Insert pressure rinsing nozzle in the side of the container, and rinse at about 40 PSI for at least 30 seconds. Drain for 10 seconds after the flow begins to drip. Once container is rinsed, offer for recycling if available or puncture and dispose of in a sanitary landfill. Dilutable Non-Seed Treatment Products in Rigid Non-refillable Containers that are Too Large to Shake (i.e., with capacities greater than 5 gallons or 50 lbs) Non-refillable container. DO NOT reuse or refill this container. Refer to Bottom Discharge IBC or Top Discharge IBC, Drums, Kegs information as follows. Bottom Discharge IBC (e.g. – Schuetz Caged IBC or Snyder Square Stackable) Pressure rinsing the container before final disposal is the responsibility of the person disposing of the container. To pressure rinse the container before final disposal, empty the remaining contents from the IBC into application equipment or mix tank. Raise the bottom of the IBC by 1.5 inches on the side which is opposite of the bottom discharge valve to promote more complete product removal. Completely remove the top lid of the IBC. Use water pressurized to at least 40 PSI to rinse all interior portions. Continuously pump or drain rinsate into application equipment or rinsate collection system while pressure rinsing. Continue pressure rinsing for 2 minutes or until rinsate becomes clear. Replace the lid and close bottom valve. Once container is rinsed, offer for recycling if available or puncture and dispose of in a sanitary landfill or by incineration.

13 IMPORTANT: READ BEFORE USE Read the entire Directions for Use, Conditions, Disclaimer of Warranties and Limitations of Liability before using this product. If terms are not acceptable, return the unopened product container at once. By using this product, user or buyer accepts the following Conditions, Disclaimer of Warranties and Limitations of Liability. CONDITIONS: The directions for use of this product are believed to be adequate and must be followed carefully. However, it is impossible to eliminate all risks associated with the use of this product. Crop injury, ineffectiveness or other unintended consequences may result because of such factors as weather conditions, presence of other materials, or the manner of use or application, all of which are beyond the control of Bayer CropScience. All such risks shall be assumed by the user or buyer. DISCLAIMER OF WARRANTIES: TO THE EXTENT CONSISTENT WITH APPLICABLE LAW, BAYER CROPSCIENCE MAKES NO OTHER WARRANTIES, EXPRESS OR IMPLIED, OF MERCHANTABILITY OR OF FITNESS FOR A PARTICULAR PURPOSE OR OTHERWISE, THAT EXTEND BEYOND THE STATEMENTS MADE ON THIS LABEL. No agent of Bayer CropScience is authorized to make any warranties beyond those contained herein or to modify the warranties contained herein. TO THE EXTENT CONSISTENT WITH APPLICABLE LAW, BAYER CROPSCIENCE SHALL NOT BE LIABLE FOR SPECIAL, INCIDENTAL OR CONSEQUENTIAL DAMAGES RESULTING FROM THE USE OR HANDLING OF THIS PRODUCT. LIMITATIONS OF LIABILITY: TO THE EXTENT CONSISTENT WITH APPLICABLE LAW, THE EXCLUSIVE REMEDY OF THE USER OR BUYER FOR ANY AND ALL LOSSES, INJURIES OR DAMAGES RESULTING FROM THE USE OR HANDLING OF THIS PRODUCT, WHETHER IN CONTRACT, WARRANTY, TORT, NEGLIGENCE, STRICT LIABILITY OR OTHERWISE, SHALL NOT EXCEED THE PURCHASE PRICE PAID, OR AT BAYER CROPSCIENCE’S ELECTION, THE REPLACEMENT OF PRODUCT. LUNA TRANQUILITY is specially formulated and sold by Bayer CropScience LP for the control of various pathogens according to the directions on this label. The purchase price of LUNA TRANQUILITY includes a prepaid license under which purchaser agrees to employ the purchased quantity of LUNA TRANQUILITY only for the above-specified uses and to provide notice of the terms and conditions of this license to any subsequent purchaser. Uses of LUNA TRANQUILITY other than those specified on this label are not licensed through the purchase of this product. Bayer, Bayer Cross and Luna Tranquility® are registered trademarks of Bayer Group.

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US61380432I (210127Iv4) LABMC LUNA TRANQUILITY 2.5 GAL BASE US colors: black 05/03/23 (Label Coordinator: Mark Schmidt) STORAGE AND DISPOSAL DO NOT contaminate water, food, or feed by storage or disposal. PESTICIDE STORAGE: Store in original container and keep tightly closed when not in use. Store in a cool dry place. Avoid cross-contamination with other pesticides. PESTICIDE DISPOSAL: Pesticide wastes may be toxic. Improper disposal of unused pesticide, spray mixture, or rinse water is a violation of federal law. If these wastes cannot be disposed of by use according to label instruction, contact your State Pesticide or Environmental Control Agency, or the Hazardous Waste representative at the nearest EPA Regional Office for guidance in proper disposal methods. CONTAINER HANDLING: Non-Seed Treatment Products in Non-Refillable Containers Rigid, Non-refillable containers (equal to or less than 5 gallons) Non-refillable container. DO NOT reuse or refill this container. Offer for recycling, if available. Triple rinse or pressure rinse container (or equivalent) promptly after emptying. Triple rinse as follows: Empty the remaining contents into application equipment or a mix tank and drain for 10 seconds after the flow begins to drip. Fill the container 1/4 full with water and recap. Shake for 10 seconds. Pour rinsate into application equipment or a mix tank or store rinsate for later use or disposal. Drain for 10 seconds after the flow begins to drip. Repeat this procedure two more times. Pressure rinse as follows: Empty the remaining contents into application equipment or a mix tank and continue to drain for 10 seconds after the flow begins to drip. Hold container upside down over application equipment or mix tank or collect rinsate for later use or disposal. Insert pressure rinsing nozzle in the side of the container, and rinse at about 40 PSI for at least 30 seconds. Drain for 10 seconds after the flow begins to drip. Once container is rinsed, offer for recycling if available or puncture and dispose of in a sanitary landfill. Produced for Bayer CropScience LP 800 N. Lindbergh Blvd. St. Louis, MO 63167 Luna Tranquility is a registered trademark of Bayer Group. ©2023 Bayer Group. All rights reserved. US61380432I 210127Iv4 05/23 FIRST AID IF SWALLOWED: • Call a poison control center or doctor immediately for treatment advice. • DO NOT induce vomiting unless told to do so by a poison control center or doctor. • Have person sip a glass of water if able to swallow. • DO NOT give anything by mouth to an unconscious person. IF ON SKIN: • Take off contaminated clothing. • Rinse skin immediately with plenty of water for 15-20 minutes. • Call a poison control center or doctor for treatment advice. IF INHALED: • Move person to fresh air. • If person is not breathing, call 911 or an ambulance, and then give artificial respiration, preferably mouth-to-mouth if possible. • Call a poison control center or doctor for further treatment advice. For MEDICAL Emergencies Call 24 Hours A Day 1-800-334-7577. In case of emergency call toll free the Bayer CropScience Emergency Response Telephone No. 1-800-334-7577. Have a product container or label with you when calling a poison control center or doctor, or going for treatment. NOTE TO PHYSICIAN: Treat Symptomatically. For PRODUCT USE Information Call 1-866-99BAYER (1-866-992-2937) PRECAUTIONARY STATEMENTS HAZARDS TO HUMANS AND DOMESTIC ANIMALS CAUTION Harmful if swallowed, absorbed through skin or inhaled. Avoid contact with skin, eyes, or clothing. Avoid breathing vapor or spray mist. Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, or using tobacco. Remove and wash contaminated clothing before reuse. DIRECTIONS FOR USE It is a violation of federal law to use this product in a manner inconsistent with its labeling. Read entire label before using this product. STOP - READ THE LABEL BEFORE USE LUNA TRANQUILITY® Broad spectrum fungicide for control of plant diseases. Berry, low growing, except cranberry, subgroup 13-07G; Bushberry subgroup 13-07B; Caneberry subgroup 13-07A; Fruit, pome, group 11-10; Ginseng; Lemons; Onion, bulb, subgroup 3-07A; Onion, green, subgroup 3-07B; Tomato; Vegetable, tuberous and corm, subgroup 1C. ACTIVE INGREDIENT: FLUOPYRAM* .......................................................... 11.3% PYRIMETHANIL* ........................................................ 33.8% OTHER INGREDIENTS: .................................................. 54.9% Contains 1.04 lbs FLUOPYRAM and 3.12 lbs PYRIMETHANIL per gallon TOTAL: 100.0% *(CAS Numbers 658066-35-4 and 53112-28-0) EPA Reg. No. 264-1085 KEEP OUT OF REACH OF CHILDREN CAUTION See additional precautionary statements and directions for use on label. GROUP GROUP 9 7 FUNGICIDE FUNGICIDE PYRIMETHANIL FLUOPYRAM NET CONTENTS: 2 1/2 GALLONS