crop-chem-docs/corpus/epa_ppls/100-1164.md

AMISTAR FUNGICIDE

• EPA Reg No: 100-1164
• Registrant: SYNGENTA CROP PROTECTION, LLC
• Signal word: Caution
• Active ingredients: Azoxystrobin (80%)
• Label accepted: 2009-11-27
• Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/000100-01164-20091127.pdf

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c UNITED STATES ENVIRONMENTAL PROTECTION AGENCY WASHINGTON, D.C. 20460 Ms Pat Dinnen Syngenta Crop Protection P.O.BOX 18300 Greensboro, NC 27419 OFFICE OF PREVENTION, PESTICIDES Al'D TOXIC SlJBSTANCES Subject: Label Notification(s) for Pesticide Registration Notice 2007-4 Dear Registrant: The Agency is in receipt of your Application(s) for Pesticide Notification under PestiCide Registration Notice (PRN) 2007-4 dated September 25,2009 for: EPA Registration 100-1164 Amistar ® Fungicide The Registration Division (RD) has conducted a review of this request for applicability under PRN 2007-4 and finds that the label change(s) requested falls within the scope of PRN-2007-4. The label has been date-stamped "Notification" and will be placed in our records. Please be reminded that 40 CFR Part 156. 140(a)(4) requires that a batch code, lot number, or other code identifying the batch ofthe pesticide distributed and sold be placed on nonrefillable containers. The code may appear either on the label (and can be added by non­ notificationlPR Notice 98-10) or durably marked on the container itself. If you have any questions, please contact me directly at 703-305-6249 or Banza Djapao of my staff at 703-'305-7269. Sincerely, Linda Arrington Notifications & Minor Formulations Team Leader Registration Division (7505P) Office of Pesticide Programs '/fo3

Please read instructions on reverse before completing form. 611 U(-' 1 States ~ Reg;,(lon OPP Identifier Number &EPA Environmentili Protection Agency Amenament Notification Washington, DC 20460 x Other Application for Pesticide - Section I

1. CompanylProduct Number 2. EPA Product Manager 3. Proposed Classification 100·1164 Tony Kish
2. Company/Product (Name) PM# ~ None D Restricted Amistar Fungicide 22
3. Name and Address of Applicant (Include ZIP Code) 6. Expedited Review. In accordance with FIFRA Section 3(c)(3) (b)(i), Syngenta Crop Protection, Inc. my product is similar or identical in composition and labeling to: P. O. Box 18300 Greensboro, NC 27419 EPA Reg. No. C:=J Check if this is a new address Product Name Section -II o Amendment - Explain below. D Final printed labels in rel':nnnl':A tn A'TlElN Agency letter dated nu 111"1"4 0 Resubmission in response to Agency letter dated D "Me Too" Application. m Notification - Explain below. D Other - Explain below. NOV 272009 Explanation: Use additional page(s) if necessary. (For Section I and Section 11.). Notification of label change per PR Notice 2007-4. This Notification is consistent with the guidance of PR Notice 2007-4 and the requirements of EPA's regulations at 40 CFR §§156.10, 156.140, 156.144 156.146, and 156.156. No other changes have been made to the labeling or the Confidential Statement of Formula for this product. I understand that it is a violation of 18 U.S.C. Sec. 1001 to willfully make any false statement to EPA. I further understand that if the amended label is not consistent with the requirements of 40 CFR §§156.10, 156.140, 156.144, 156.146, and 156.156, this product may be in violation of FIFRA and I may be subject to enforcement action and penalties under sections 12 and 14 of FIFRA. Syngenta is amending the Storage and Disposal section of the label by Notification according to the directions stated in PR Notice 2007-4. Section - III
4. Material This Product Will Be Packaged In: Child-Resistant Packaging Unit Packaging Water Soluble Packaging 2. T~ Conla;n" BYes' 5j Yes 5j Yes Metal No x No x No x Plastic Glass 'Certification must If "Yes" No. per If "Yes" No. per Paper be submitted Unit Packaging wgt. Container Unit Packaging wgt. container Other (SpeCify)
5. Location of Net Contents Information 4. Size(s) Retail Container 5. Location of Label Directions 1.25 lb. and 7.5 lb. ~ On Label m Label o Container On Labeling accompanying product
6. Manner in Which Label is Affixed to Product § Uthogrnph W Other Pressure Sensitive Paper glued Stenciled Section -IV
7. Contact Point (Complete items directly below for identification of individual to be contacted, if necessary, to process this application.) Name I Title I Telephone No. (Include Area Code) Pat Dinnen Label Group Leader 336-632-2494 Certification 6. ~ ;late J\pplication I certify that the statements I have made on this form and all attachments thereto are true, accurate and comRietb~ < ~. cF:ect!ived I acknowledge that any knowingly false or misleading statement may be punishable by fine or imprisonment 0;' c l , (Stamped) both under applicable law. l l ( C (,
8. Signature 3. Title ... v .... '- L . ( , C t. '- t. ( l· Regulatory Specialist , l p().C~ ( l l l l L L L L (. l. l l CC L ~-
9. Date 4. Typed Name l L L tel C c. Pat Dinnen September 25, 2009 LlCL r. u <. c C <. <.. ( <.

synIe nta FedEx September 25, 2009 Document Processing Desk (NOTIF) Office of Pesticide Programs (7504P) u.s. Environmental Protection Agency Room S-4900, One Potomac Yard 2777 South Crystal Drive Arlington, VA 22202-4501 Attention: Ms. Linda Arrington SUBJECT: AMISTAR® FUNGICIDE EPA REG. NO. 100-1164 ( Syngenta Crop Protection;inc. P.O. Box 18300 Greensboro, NC 27419-8300 www:syngenta.com NOTIFICATION OF LABEL CHANGE PER PR NOTICE 2007-4 Syngenta Crop Protection, Inc. is submitting Notification for Amistar Fungicide, EPA Reg. No. 100-1164. Syngenta is amending the Storage and Disposal section of the label by Notification according to the directions stated in PR Notice 2007-4. Attached are: • One copy of the label with the changes clearly marked • One unmarked copy of the label • A CD of the unmarked copy of the label for "Electronic Comparison and Review" • Certificate with Respect to Label Integrity Form • Completed EPA Form 8570-1 Thank you in advance for approving this Notification. If you have any questions, please contact me at 336- 632-2494. Sincerely, Pat Dinnen Label Group Leader Regulatory Affairs Enclosures C (. L l (. (. c (. t.- o L U C C L l C CC(CCL l L l L L L L L L L l Cl..L(l LL 1,. L l l L L (.. t, L L L leu l cC ( .. L L L L

c Certification with Respect to Label Integrity Version: 9/11/02 I certify that the information (including, but not limited to, text, tables, and graphics) contained in the electronic file identified below by file name and submitted with this certification is the same information as that on the paper copies of these documents included with this submission. Electronic file name 100-1164 000100-01164.20090924.AMISTAR_PRN2007-4_SEP2009.pdf I certify that the statements that I have made on this form are true, accurate, and complete. I acknowledge that any knowingly false or misleading statements may be punishable by fine or imprisonment or both under applicable law. Signature Pat Dinnen Name (typed) Label Group Leader Title September 25, 2009 Date l (C ( l. r Lee (, l:" (, C C OL 0..: L C <. l .. C l (, l l. l . L l t l, l ( l (<. l l l. L <. l <- l l l. t <. (. ( <.. l t ( l. t. t· 1. J C (. l I.. t l L (.. l ( <- L- I.. L C l t.: t ( t c

-" ( Amistar® Fungicide Broad spectrum fungicide for control of plant diseases Active Ingredient: Azoxystrobin: methyl (E)-2-{2-[6-(2-cyanophenoxy) c: Page 1 of 59 Amistar NonFICATION NOV 272009 pyrimidin-4-yloxyJphenyl}-3-methoxyacrylate* ..................................................................... 80.0% Other Ingredients: 20.0% Total: 100.0% Contains 0.80 lb. a.i.llb. product *IUPAC KEEP OUT OF REACH OF CHILDREN. CAUTION See additional precautionary statements and directions for use inside booklet. Reformulation is prohibited. See individual container labels for repackaging limitations. EPA Reg. No. 100-1164 EPA Est. Product of Formulated in the 1.25 pounds, 7.50 pounds Net Weight! U.S. Standard Measure c " !'; C L>

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If swallowed • • • • If inhaled • • • If on skin or • clothing • • If in eyes • • • ( FIRST AID Page 2 of 59 Amistar Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by a poison control center or doctor. Do not give anything by mouth to an unconscious person. Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth to mouth if possible. Call a poison control center or doctor for further treatment advice. Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor for treatment advice. Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. Have the product container or label with you when calling a poison control center or doctor, or going for treatment. HOT LINE NUMBER For 24 Hour Medical Emergency Assistance (Human or Animal) or Chemical Emergency Assistance (Spill, Leak, Fire, or Accident), Call 1-800-888-8372 PRECAUTIONARY STATEMENTS Hazards to Humans and Domestic Animals CAUTION HARMFUL IF swallowed or inhaled. Avoid breathing spray mist. Wash thoroughly with soap and water after handling. Remove and wash contaminated clothing before reuse. Personal Protective Equipment (PPE) Some materials that are chemically resistant to this product are listed below. If you want more options follow the instructions for Category A on an EPA chemical resistance category selection chart. Applicators and other handlers must wear: • Long-sleeved shirt and long pants • Chemical-resistant gloves made of any waterproof material such as polyvinyl chloride, nitrile rubber or butyl rubber • Shoes plus socks

( User Safety Requirements Page 3 of 59 Amistar Follow manufacturer's instructions for cleaning/maintaining PPE. If no such instructions are available; for washables, use detergent and hot water. Keep and wash PPE separately from other laundry. When handlers use closed systems, enclosed cabs, or aircraft in a manner that meets the requirements listed in the Worker Protection Standard (WPS) for agricultural pesticides (40 CFR 170.240 (d)(4-6), the handler PPE requirements may be reduced or modified as specified in the WPS. IMPORTANT: when reduced PPE is worn because a closed system is being used, handlers must be provided all PPE specified above for "applicators and other handlers" and have such PPE immediately available for use in an emergency, such as a spill or equipment breakdown. User Safety Recommendations Users should: • Wash hands before eating, drinking, chewing gum, using tobacco or using the toilet. Wash thoroughly with soap and water after handling. • Remove clothing immediately if pesticide gets inside. Then wash thoroughly and put on clean clothing. • Remove PPE immediately after handling this product. Wash the outside of gloves before removing. As soon as possible, wash thoroughly and change into clean clothing. Environmental Hazards The active ingredient, azoxystrobin, in this product can be persistent for several months or longer. Azoxystrobin has degradation products which have properties similar to chemicals which are known to leach through soil to ground water under certain conditions as a result of agricultural use. Use of this chemical in areas where soils are permeable, particularly where the water table is shallow, may result in ground water contamination. This pesticide is toxic to freshwater and estuarine/marine fish and aquatic invertebrates. Do not apply directly to water except as specified on this label. For terrestrial uses, do not apply directly to water, or to areas where surface water is present or to intertidal areas below the mean high-water mark. Drift and runoff may be hazardous to aquatic organisms in neighboring areas. Do not contaminate water when disposing of equipment washwater or rinsate. Notify State and/or Federal authorities and Syngenta immediately if you observe any adverse environmental effects due to use of this product.

(-- '. CONDITIONS OF SALE AND LIMITATION OF WARRANTY AND LIABILITY Page 4 of 59 Amistar NOTICE: Read the entire Directions for Use and Conditions of Sale and Limitation of Warranty and Liability before buying or using this product. If the terms are not acceptable, return the product at once, unopened, and the purchase price will be refunded. The Directions for Use of this product should be followed carefully. It is impossible to eliminate all risks inherently associated with the use of this product. Crop injury, ineffectiveness or other unintended consequences may result because of such factors as manner of use or application, weather or crop conditions, presence of other materials or other influencing factors in the use of the product, which are beyond the control of SYNGENTA CROP PROTECTION, Inc. or Seller. All such risks shall be assumed by Buyer and User, and Buyer and User agree to hold SYNGENTA and Seller harmless for any claims relating to such factors. SYNGENTA warrants that this product conforms to the chemical description on the label and is reasonably fit for the purposes stated in the Directions for Use, subject to the inherent risks referred to above, when used in accordance with directions under normal use conditions. This warranty does not extend to the use of the product contrary to label instructions, or under conditions not reasonably foreseeable to or beyond the control of Seller or SYNGENT A, and Buyer and User assume the risk of any such use. SYNGENTA MAKES NO WARRANTIES OF MERCHANTABILITY OR OF FITNESS FOR A PARTICULAR PURPOSE NOR ANY OTHER EXPRESS OR IMPLIED WARRANTY EXCEPT AS STATED ABOVE. To the extent allowed by State law, neither Syngenta or Seller shall be liable for any incidental, consequential or special damages resulting from the use or handling of this product. THE EXCLUSIVE REMEDY OF THE USER OR BUYER, AND THE EXCLUSIVE LIABILITY OF SYNGE NT A AND SELLER FOR ANY AND ALL CLAIMS, LOSSES, INJURIES OR DAMAGES (INCLUDING CLAIMS BASED ON BREACH OF WARRANTY, CONTRACT, NEGLIGENCE, TORT, STRICT LIABILITY OR OTHERWISE) RESULTING FROM THE USE OR HANDLING OF THIS PRODUCT, SHALL BE THE RETURN OF THE PURCHASE PRICE OF THE PRODUCT OR, AT THE ELECTION OF SYNGENTA OR SELLER, THE REPLACEMENT OF THE PRODUCT. SYNGENTA and Seller offer this product, and Buyer and User accept it, subject to the foregoing Conditions of Sale and Limitation of Warranty and Liability, which may not be modified except by written agreement signed by a duly authorized representative of SYNGENT A.

c DIRECTIONS FOR USE Page 5 of 59 Amistar It is a violation of Federal law to use this product in a manner inconsistent with its labeling. Use of Amistar through airblast application equipment on grapes is prohibited in the following townships and boroughs of Erie County, Pennsylvania: North East, Harborcreek, Lawrence Park, Erie, Presque Isle, MillCreek, Fairview, Girard and Springfield. This prohibition is intended to help eliminate phytotoxicity problems with apples observed in this geographic location. FAILURE TO FOLLOW THE USE DIRECTIONS AND PRECAUTIONS ON THIS LABEL MAY RESULT IN PLANT INJURY OR POOR DISEASE CONTROL. Do not apply this product in a way that will contact workers or other persons, either directly or through drift. Only protected handlers may be in the area during application. For any requirements specific to your State or Tribe, consult the agency responsible for pesticide regulation. AGRICULTURAL USES AGRICULTURAL USE REQUIREMENTS Use this product only in accordance with its labeling and with the Worker Protection Standard, 40 CFR part 170. This Standard contains requirements for the protection of agricultural workers on farms, forests, nurseries, and greenhouses, and handlers of agricultural pesticides. It contains requirements for training, decontamination, notification, and emergency assistance. It also contains specific instructions and exceptions pertaining to the statements on this label about personal protective equipment (PPE), notification to workers, and restricted-entry interval. The requirements in this box only apply to uses of this product that are covered by the Worker Protection Standard. Do not enter or allow worker entry into treated areas during the restricted entry interval (REI) of 4 hours. PPE required for early entry to treated areas that is permitted under the Worker Protection Standard and that involves contact with anything that has been treated, such as plants, soil or water is: • Coveralls • Chemical-resistant gloves made of any waterproof material such as polyvinyl chloride, nitrile rubber or butyl rubber • Shoes plus socks

NON-AGRICULTURAL USES NON-AGRICULTURAL USE REQUIREMENTS Page 6 of 59 Amistar The requirements in this box apply to uses of this product that are NOT within the scope of the Worker Protection Standard for agricultural pesticides (40 CFR Part 170). The WPS applies when this product is used to produce agricultural plants on farms, forests, nurseries, or greenhouses. The area being treated must be vacated by unprotected persons. Do not treat areas while unprotected humans or domestic animals are present in the treatment areas. Because certain states may require more restrictive reentry intervals, consult your State Department of Agriculture for further information. Do not allow entry into treatment area until area that was treated with Amistar is dry. GENERAL INFORMATION Amistar is a broad spectrum, preventative fungicide with systemic and curative properties recommended for the control of many important plant diseases. Amistar may be applied as a foliar spray in alternating spray programs or in tank mixes with other registered, crop protection products. All applications should be made according to the use directions that follow. GENERAL USE PRECAUTIONS Do not plant the following crops for a period of 12 months (unless an azoxystrobin product is registered for use on that crop): sorghum, barley, buckwheat, millet, oats, rye, wild rice, non­ grass animal feeds (alfalfa, clover), sugarcane, triticale and wheat. A plantback interval (PBI) of 36 days is required for Leafy Vegetables (Except Brassica) group; Brassica, Leafy Greens subgroup; Vegetables, Root subgroup; Vegetable (Tuberous and Corm) subgroup; and Vegetables, Leaves of Root and Tuber group. Azoxystrobin is registered for use on all other rotated crops and all other crops may be planted immediately after the last treatment. Do not use for disease control in food crops grown in greenhouses. Use for disease control in greenhouses for non-agricultural uses on plants (listed on this label) are permitted. ATTENTION Amistar is. extremely phytotoxic to certain apple varieties. AVOID SPRAY DRIFT. Extreme care must be used to prevent injury to apple trees (and apple fruit). . DO NOT spray Amistar where spray drift may reach apple trees. DO NOT spray when conditions favor drift beyond area intended for application. Conditions which may contribute to drift include thermal inversion, wind speed and direction, sprayer nozzle/pressure combinations, spray droplet size, etc. Contact your State extension agent for spray drift prevention guidelines in your area.

c , -. Page 7 of 59 Amistar DO NOT use spray equipment which has been previously used to apply Amistar to spray apple trees. Even trace amounts can cause unacceptable phytotoxicity to certain apple and crabapple varieties. AVOIDING SPRAY DRIFT IS THE RESPONSIBILITY OF THE APPLICATOR. Amistar has demonstrated some phytotoxic effects when mixed with products that are formulated as EC's. These effects are enhanced if applications are made under cool, cloudy conditions and these conditions remain for several days following application. In addition, adjuvants that contain some form of silicone have also contributed to phytotoxicity. INTEGRATED PEST (DISEASE) MANAGEMENT Amistar should be integrated into an overall disease and pest management strategy whenever the use of a fungicide is required. Cultural practices known to reduce disease development should be followed. The DIRECTIONS FOR USE section in this label identifies specific IPM recommendations for each crop. Consult your local agricultural authorities for additionallPM strategies established for your area. Amistar may be used in State Agricultural Extension advisory (disease forecasting) programs which recommend application timing based on environmental factors favorable for disease development. RESISTANCE MANAGEMENT Amistar (azoxystrobin) is a Group 11 fungicide. The mode of action for Amistar is the inhibition of the 00 (quinone outSide) site within the electron transport system as well as disruption of membrane synthesis by blocking demethylation [Group 11]. Fungal pathogens can develop resistance to products with the same mode of action when used repeatedly. Because resistance development cannot be predicted, use of this product should conform to resistance management strategies established for the crop and use area. Consult your local or State agricultural authorities for resistance management strategies that are complementary to those in this label. Resistance management strategies may include alternating and/or tank-mixing with products having different modes of action or limiting the total number of applications per season. Syngenta Crop Protection encourages responsible resistance management to ensure effective long-term control of the fungal diseases on this label. Follow the crop specific resistance management recommendations in the directions for use. If no resistance recommendation on number of applications is specified in the directions for use, follow the recommendations in the table below. If planned total number of fungicide 1 2 3 4 5 6 7 8 9 10 11 12 applications per crop is: Recommended Solo Qol fungicide 1 1 2 2 2 2 2 3 3 3 3 4 sprays Recommended Qol fungicide sprays in 1 2 2 2 2 3 3 4 4 5 5 6 mixture (tank-mix or formulated)

C' Page 8 of 59 Amistar In situations requiring multiple sprays, develop season long spray programs for Group 11 (aol) fungicides. In crops where two sequential Group 11 fungicide applications are made, they should be alternated with two or more applications of a fungicide that is not in Group 11. If more than 12 applications are made, observe the following guidelines: • When using a 001 fungicide as a solo product, the number of applications should be no more than 1/3 (33%) of the total number of fungicide applications per season. • For 001 mixes in programs in which tank mixes or pre mixes of 001 with mixing partners of a different mode of action are utilized, the number of aol containing applications should be no more than ~ (50%) of the total number of fungicide application per season. • In programs in which applications of aol are made with both solo products and mixtures, the number of 001 containing applications should be no more than ~ (50%) of the total number of fungicide applied per season. If a Group 11 fungicide is applied to the seed or soil, do not make another application with a Group 11 fungicide for at least 3 weeks. SPRAYING/MIXING Amistar may be applied with all types of spray equipment commonly used for making ground and aerial applications. Do not apply Amistar through any type of ultra low volume (ULV) spray system. Proper adjustments and calibration of spraying equipment to give good canopy penetration and coverage is essential for good disease control. The higher rates in the rate range and/or shorter spray intervals may be required under conditions of heavy infection pressure, highly susceptible varieties, or when environmental conditions conducive to disease exist. For ground applications, apply Aniistar in sufficient water volume for adequate coverage and canopy penetration. For aerial applications to non-orchard crops, apply Amistar in a minimum of two gallons of water per acre. For aerial applications in orchard crops, apply Amistar in a minimum of ten gallons of water per acre. Where feasible ground application should be used because it provides better canopy penetration and coverage. To prepare spray solution, partially fill the spray tank with clean water and begin agitation. Add the specified amount of Amistar to the tank, allowing time for good dispersion, then add an adjuvant, if recommended. If tank mixes are required, product should be added to the spray tank in the following order: WG or dry flowable formulations, wettable powders and flowable (aqueous suspensions) products. Finish filling the tank to the desired volume to obtain the proper spray concentration. Maintain agitation throughout the spraying operation. Do not allow spray mixture to stand overnight or for prolonged periods. Make up only the amount of spray required for immediate use. Sprayers should be thoroughly cleaned immediately after application. Amistar is compatible with many commonly used fungicides, liquid fertilizers, herbicides, insecticides and biological control products. If tank mixes are desired, observe all directions, precautions, and limitations on labeling of all products used. Consult compatibility charts or your local or State agricultural or turf authorities for compatibility information.

Page 9 of 59 Amistar Amistar is incompatible with many fertilizers when low water volumes are used for in-furrow applications. Cold temperatures and water quality exacerbate these compatibility problems. Conduct a physical compatibility test as described in the paragraph below before making a field application. Do not combine Amistar in the spray tank with pesticides, surfactants or fertilizers, unless compatibility charts or your own prior use has shown that the combination is physically compatible, effective and non-injurious under your conditions of use. If physical compatibility is unknown, the following procedure should be followed: Pour the recommended proportions of the .products into a suitable container of water, mix thoroughly and allow to stand at least twenty (20) minutes. If the combination remains mixed or can be re-mixed readily, the mixture is considered physically compatible. SPRAY DRIFT MANAGEMENT ATTENTION Amistar is extremely phytotoxic to certain apple varieties. AVOID SPRAY DRIFT. Extreme care must be used to prevent injury to apple trees (and apple fruit). DO NOT spray Amistar where spray drift may reach apple trees. DO NOT spray when conditions favor drift beyond area intended for application. Conditions which may contribute to drift include thermal inversion, wind speed and direction, sprayer nozzle/pressure combinations, spray droplet size, etc. Contact your State extension agent for spray drift prevention guidelines in your area. DO NOT use spray equipment which has been previously used to apply Amistar to spray apple trees. Even trace amounts can cause unacceptable phytotoxiCity to certain apple and crabapple varieties. AVOIDING SPRAY DRIFT IS THE RESPONSIBILITY OF THE APPLICATOR. Do not apply when weather conditions favor drift from treated areas to non-target aquatic habitat. APPLICATION INSTRUCTIONS Apply Amistar at rates and timings as described in this label. Directions for Use Through Sprinkler and Drip Chemigation Systems Spray Preparation: Chemical tank and injector system should be thoroughly cleaned. Flush system with clean water.

Use Precautions for Sprinkler and Drip Irrigation Applications Page 10 of 59 Amistar Drip Irrigation: Amistar may be applied through drip irrigation systems for soil-borne disease control. The soil should have adequate moisture capacity prior to drip application. Terminate drip irrigation at fungiCide depletion from the main feed supply tank or after 6 hours from start, whichever is shorter. For maximum efficacy, subsequent irrigation (water only) should be delayed for at least for 24 hours following drip application. Sprinkler Irrigation: Apply this product through sprinkler irrigation systems including center pivot, lateral move, end tow, side [wheel] roll, traveler, big gun, solid set, or hand move irrigation systems. Do not apply this product through any other type of irrigation system except as specified on this label. Apply with center pivot or continuous-move equipment distributing 1/2 acre-inch or less during treatment. In general, use the least amount of water required for proper distribution and coverage. If stationary systems (solid set, hand lines or wheel lines other than continuous­ move) are used, this product should be injected into no more than the last 20-30 minutes of the set. Do not apply when winds are greater than 10-15 mph to avoid drift or wind skips. Do not apply when wind speed favors drift beyond the area intended for treatment. Plant injury, lack of effectiveness, or illegal pesticide residues in the crop can result from non-uniform treated water. Thorough coverage of foliage is required for good control. Good agitation should be maintained during the entire application period. If you have questions about calibration you should contact State Extension Service specialist, equipment manufacturers or other experts. The system must contain a functional check valve, vacuum relief valve, and low pressure drain appropriately located on the irrigation pipeline to prevent water-source contamination from backflow. The pesticide injection pipeline must contain a functional, automatic, quick-closing check valve to prevent the flow of fluid back toward the injection pump. The pesticide injection pipeline must also contain a functional, normally closed, solenoid­ operated valve located on the intake side of the injection pump and connected to the system interlock to prevent fluid from being withdrawn from the supply tank when the irrigation system is either automatically or manually shut down. The system must contain functional interlocking controls to automatically shut off the pesticide injection pump when the water pump motor stops. The irrigation line or water pump must include a functional pressure switch which will stop the water pump motor when the water pressure decreases to the point where pesticide distribution is adversely affected. Systems must use a metering pump, such as a positive displacement injection pump (e.g., diaphragm pump) effectively designed and constructed of materials that are compatible with pesticides and capable of being fitted with a system interlock.

c·· -'. ( Page 11 of 59 Amistar Allow sufficient time for pesticide to be flushed through all lines and all nozzles before turning off irrigation water. A person knowledgeable of the chemigation system and responsible for its operation, or under the supervision of the responsible person, shall shut tbe system down and make necessary adjustments should the need arise. Do not connect an irrigation system (including greenhouse systems) used for pesticide application to a public water system unless the pesticide label-prescribed safety devices for public water systems are in place. Specific Instructions for Public Water Systems

1. Public water system means a system for the provision to the public of piped water for human consumption if such system has at least 15 service connections or regularly serves an average of at least 25 individuals daily at least 60 days out of the year.
2. Chemigation systems connected to public water systems must contain a functional, reduced-pressure zone, back-flow preventer (RPZ) or the functional equivalent in the water supply line upstream from the point of pesticide introduction. As an option to the RPZ, the water from the public water system should be discharged into a reservoir tank prior to pesticide introduction. There shall be a complete physical break (air gap) between the outlet end of the fill pipe and the top or overflow rim of the reservoir tank of at least twice the inside diameter of the fill pipe.
3. The pesticide injection pipeline must contain a functional, automatic, quick-closing check valve to prevent the flow of fluid back toward the injection pump.
4. The pesticide injection pipeline must contain a functional, normally closed, solenoid­ operated valve located on the intake side of the injection pump and connected to the system interlock to prevent fluid from being withdrawn from the supply tank when the irrigation system is either automatically or manually shut down.
5. The system must contain functional interlocking controls to automatically shut off the pesticide injection pump when the water pump motor stops, or in cases where there is no water pump, when the water pressure decreases to the point where pesticide distribution is adversely affected.
6. Systems must use a metering pump, such as a positive displacement injection pump (e.g., diaphragm pump) effectively designed and constructed of materials that are compatible with pesticides and capable of being fitted with a system interlock.
7. Do not apply when wind speed favors drift beyond the area intended for treatment. SOILBORNE/SEEDLING DISEASE CONTROL Amistar can provide control of many soilborne diseases if applied early in the growing season. Specific applications for soilborne diseases include in-furrow applications and banded applications applied over the row, either shortly after plant emergence or during herbicide applications or cultivation. These applications will provide control of pre or postemergence damping off and diseases that infect plants at the soil-plant interface. The use of either type of application depends on the cultural practices in the region. In some

Page 12 of 59 Amistar locations, one type of application may provide better disease control than the other, depending on the timing of the disease epidemic. Seedling diseases are generally controlled by in-furrow applications while banded applications are more effective against soilborne diseases that develop later in the season. Consult your local expert to get some guidance regarding application type. For banded applications, apply Amistar prior to infection as a directed spray to the soil, using single or multiple nozzles, adjusted to provide thorough coverage of the lower stems and the soil surface surrounding the plants. Band width should be limited to 7 inches or less. Apply Amistar at a rate of 0.125-0.25 oz. product (0.10-0.20 oz. a.i. )/1000 row feet (for banded applications on 22-inch rows the maximum application rate is 0.165 oz'/1 000 row feet). These applications come into contact with the foliage and are counted as foliar applications when considering resistance management. They may be applied during cultivation or hilling operations to provide soil incorporation. For in-furrow applications, apply Amistar as an in-furrow spray in 3-15 gallons of water at planting. Mount the spray nozzle so the spray is directed into the furrow just before the seed are covered. Use the higher rate when the weather conditions are expected to be conducive for disease development, if the field has a history of pythium problems, or if minimumllow till programs are in place. IN-FURROW APPLICATION RATES RATE PER 1000 ROW FEET PRODUCT PER ACRE (oz.) oz. product oz. a.i. 22" rows 30" rows 32" rows 34" rows 36" rows 38" rows 40" rows 0.125 0.10 3.00 2.20 2.00 1.90 1.80 1.70 1.60 0.188 0.15 4.50 3.30 3.00 2.88 2.70 2.60 2.45 40" = 13,068 row ft., 38" = 13,754 row ft., 36" = 14,520 row ft., 34" = 15,374 row ft., 32" = 16,315 row ft., 30" = 17,424 row'ft., and 22" = 23,760 row ft.lAcre

Directions for Use Use Rate oz. productlA Crop Target Diseases (lb. a.i.lA) Almonds Alternaria leaf and fruit spot 2-5 (Alternaria alternata) (0.10-0.25) Anthracnose (Col/etotrichum acutatum) Leaf blight (Seimatosporium lichenicola) Leaf rust (Tranzschelia discolor) Scab (Cladosporium carpophilum) Shothole (Wilsonomyces carpophilus) Brown rot blossom blight 4-5 (Monilinia laxa, M. fructicola) (0.20-0.25) Page 13 of 59 Amistar Remarks Integrated Pest {Disease} Management: Amistar should be integrated into an overall disease management strategy that .includes selection of varieties with disease tolerance, removal of plant debris in which inoculum overwinters and proper timing and placement of irrigation. Resistance Management: Follow the resistance management guidelines in the Resistance Management Section. Do not apply more than two sequential applications of Amistar or other Group 11 fungicides before , alternation with a fungicide that is not in Group 11. Application Directions: Amistar applications should begin prior to disease development and continue throughout the season following the resistance management guidelines. Applications may be made by ground, air (minimum 15 GPA) or chemigation. Amistar may be applied by air only at growth stages prior to and including 5 weeks after petal fall. An adjuvant may be added at recommended rates. For anthracnose, scab and shothole, begin applications prior to disease development and continue at 10-14 day intervals throughout the season. For blossom blight, begin applications at early bloom and continue through petal fall. Specific Use Restrictions: Do not apply more than 1.5 Ibs. a.i.lA per season of azoxystrobin-containing products. Do not apply within 28 days of harvest. ) -......j W-

Use Rate oz. product/A Crop Target Diseases (lb. a.i./A) Artichoke, globe Ramularia leaf spot 3.5-5.0 (Ramularia cynarae) (0.18-0.25) Remarks Page 14 of 59 Amistar Integrated Pest {Disease} Management: Amistar should be integrated into an overall disease management strategy that includes varieties with disease tolerance, proper timing of irrigation and removal of plant debris in which inoculum overwinters. Resistance Management: Follow the resistance management guidelines in the Resistance Management Section. Do not apply more than one application of Amistar or other Group 11 fungicides before alternation with a fungicide that is not in Group 11. Application Directions: Begin applications prior to or in the early stages.' of disease development, and continue as needed throughout the season at a 2-3 week interval, up to and including the day of harvest. Do not apply at less than 7-day intervals. Applications may be made by ground, air or chemigation. For ground applications, apply in 50-200 gallons of water per acre to obtain coverage without excessive runoff. For aerial applications, apply in a minimum of 5 gallons of water per acre. An adiuvant may be added at recommended rates. Specific Use Restrictions: Do not apply more than 1.5 Ibs. a.i.IA per season of azoxystrobin-containing products. May be applied the day of harvest (0 day PHI). i------' , I -ex? ~

Use Rate oz. producUA Crop Target Diseases (lb. a.i.lA) Asparagus Stemphyllium purple spot 2-5 (Stemphyllium vesicarium) (0.10-0.25) Page 15 of 59 Amistar Remarks Integrated Pest {Disease) Management: Amistar should be integrated into an overall disease management strategy that includes varieties with disease tolerance, proper timing of irrigation and removal of plant debris in which inoculum overwinters. Resistance Management: Follow the resistance management guidelines in the Resistance Management Section. Do not apply more than one application of Amistar or other Group 11 fungicides before alternation with a fungicide that is not in Group 11. Application Directions: Amistar applications should begin prior to ! disease development and continue throughout the season on a 7-14 day . schedule, following the resistance management guidelines. Applications may be made by ground, air or chemigation. An adjuvant may be added at recommended rates. Use a minimum of 10 gallons of water per acre by ground, and minimum of 3 gallons per acre by air. An adjuvant may be added at recommended rates. Specific Use Restrictions: Do not apply more than 1.5 Ibs. a.i.IA per season of azoxystrobin-containing products. Do not apply within 100 days of harvest (100 day PHI). /-­i ~ W

, Use Rate oz. producUA Crop Tal"9_et Diseases (lb. a.i.lA) Bananas Black sigatoka 1.7-2.6 Plantains (Mycosphaerella fijiensis) (0.09-0.135) Yellow sigatoka (Mycosphaerella musico/a) Post Harvest Applications: 200-400 ppm Crown rot/Crown mold solution (Colletotrichum musae, Fusarium pallidoroseum, Acremonium spp., Ceratocystis paradoxa, Glomerella cingulata, Penicillium spp.) Page 16 of 59 Amistar Remarks Integrated Pest (Disease} Management: Amistar should be integrated into an overall disease management strategy that includes canopy management through removal of suckers, proper plant spacing, selection of varieties with disease tolerance, removal of plant debris in which inoculum overwinters, and good surface water drainage. Resistance Management: Follow the resistance management guidelines in the Resistance Management Section. Do not apply more than two sequential applications of Amistar or other Group 11 fungicides before alternation with a fungicide that is not in Group 11. I ~ Application Directions: Amistar applications should begin prior to disease development and continue throughout the season every 12-14 days following the resistance management guidelines. Applications may be made by ground, air or chemigation. An adjuvant may be added at recommended rates. Apply Amistar as a single application of a 200-400 ppm solution to achieve good coverage. The application may be made as a spray, dip or may be painted onto the cut ends of the bananas. Application of the 200 ppm rate is appropriate for short distance transportation (e.g. within the USA). When a longer time in transport is expected (export), use the 300- 400 ppm rate. If alum (1 % v/v) is added to the spray solution, stir the suspension frequently as sedimentation and flocculation may occur. Addition of a non-ionic surfactant (0.10% v/v) may improve the compatibility of this mixture. Specific Use Restrictions: Do not apply more than 1.08 Ibs. a.i.lA per season of azoxystrobin-containing products. May be applied the day of harvest. (1 '§ -'CS"'" ..})

Use Rate oz. productlA Crop Target Diseases (lb. a.i.IAl Barley Kernel blight 2-4 (Alternaria spp.) (0.10-0.20) Leaf rust (Puccinia horde!) Net blotch 3-4 (Pyrenophora teres) (0.15-0.20) Barley stripe (Pyrenophora graminea) Powdery mildew 4 (Erysiphe graminis f. sp. hordei} (0.20) Stagonospora blotch (Stagonospora nodorum) Specific Use Restrictions: Do not apply until after forage stage (Feekes 6 or Zadok's 31). Do not apply later than Feekes growth stage 10.5 (Zadok's growth stage 59). Do not harvest treated barley for forage. Do not apply more than 0.40 lb. a.i.lA per season of azoxystrobin-containing products. Do not apply within 14 days of harvest for hay. Do not apply within 45 days of harvest for grain and straw. Page 17 of 59 Amistar Remarks Integrated Pest (Disease} Management: Amistar should be integrated into an overall disease management strategy that includes proper selection of varieties with disease tolerance, proper timing and placement of irrigation, removal of plant debris in which inoculum overwinters, plant residue management, and crop rotation. Resistance Management: Follow the resistance management guidelines in the Resistance Management Section. Do not apply more than two sequential applications of Amistar or other Group 11 fungicides before alternation with a fungicide that is not in Group 11. Do not make more than 2 applications of Amistar or other Group 11 fungicide per ( season. Application Directions: Amistar should be applied prior to disease development from jointing (Feekes 6 or Zadok's 31) up to late head emergence (Feekes 10.5 or Zadok's 59). Applications may be made by ground, air or chemigation. A crop oil concentrate adjuvant may be added at 1.0% v/v to optimize efficac~. /~. ! <:U

~

Crop Target Diseases Berries, Botryosphaeria canker Bushberry subgroup (Botryosphaeria spp.) Powdery mildew Blueberry (Sphaerotheca spp.) Currant Septoria blight Elderberry (Septoria spp.) Gooseberry Mummyberry Huckleberry (Vaccinium spp.) Including all cultivars and/or hybrids of Alternaria fruit rot these (Alternaria spp.) Phomopsis stem canker Lingonberry (Phomopsis vaccinii) Juneberry Anthracnose fruit rot Salal (Col/etotrichum gloeosporoides) Use Rate oz. producUA (lb. a.i.lA) 2-5 (0.10-0.25) Remarks Page 18 of 59 Amistar Integrated Pest {Disease} Management: Amistar should be integrated into an overall disease management strategy that includes varieties with disease tolerance, proper timing of irrigation and removal of plant debris in which inoculum overwinters. Resistance Management: Follow the resistance management guidelines in the Resistance Management Section. Do not apply more than two sequential applications of Amistar or other Group 11 fungicides before alternation with a fungicide that is not in Group 11. Application Directions: Amistar applications should begin prior to 1 disease development and continue throughout the season on a 7-14 day .J schedule, following the resistance management guidelines. Applications may be made by ground, air or chemigation. An adjuvant may be added at recommended rates. Specific Use Restrictions: Do not apply more than 0.75 lb. a.i.lA per season of azoxystrobin-containing products. May be applied the day of harvest. ,/""""\ ~ -

Crop Target Diseases Berries, Botryosphaeria canker Cane berry subgroup (Botryosphaeria dothidea) Anthracnose Blackberry (Space/oma necator) Bingleberry (E/sinoe veneta) Boysenberry Powdery mildew Dewberry (Sphaerotheca macu/aris) Lowberry Leaf spot Marionberry (Septoria rUbi) Olallieberry (Sphaerulina rubi) Youngberry Colletotrichum rot Loganberry (Colletotrichum g/oeosporioides) Red and black raspberry Spur blight Including all cultivars and/or hybrids of (Didymella app/anata) these Rosette or double blossom of blackberries (Cercosporella rubi) Use Rate oz. productlA (lb. a.i.lA) 2-5 (0.10-0.25) Page 19 of 59 Amistar Remarks Integrated Pest (Disease) Management: Amistar should be integrated into an overall disease management strategy that includes varieties with disease tolerance, proper timing of irrigation and removal of plant debris in which inoculum overwinters. Resistance Management: Follow the resistance management guidelines in the Resistance Management Section. Do not apply more than two sequential applications of Amistar or other Group 11 fungicides before alternation with a fungicide that is not in Group 11. Application Directions: Begin applications at onset of disease and : continue as required until harvest. Make applications on a 7-14 day schedule. Use a minimum water volume of 10 gal. per acre by ground and a minimum of 3 gal. by air. Specific Use Restrictions: Do not apply more than 1.5 Ibs. a.i.lA per season of azoxystrobin-containing products. May be applied the day of harvest (0 day PHI). '\ ~

~ . Uol

Crop Target Diseases Brassica Alternaria leaf spot Head and Stem subgroup (Alternaria spp.) Downy mildew Broccoli (Peronospora parasitica) Chinese broccoli [gai Ion] Brussels sprouts Cabbage Chinese cabbage [napa] Chinese mustard cabbage [gai choy] Cauliflower Cavalo broccolo Kohlrabi Including allcultivars and/or hybrids of these Use Rate oz. productlA (lb. a.i./A) 2-5 (0.10-0.25) Remarks Page 20 of 59 Amistar Integrated Pest (Disease} Management: Amistar should be integrated into an overall disease management strategy that includes varieties with disease tolerance, proper timing of irrigation and removal of plant debris in which inoculum overwinters. Resistance Management: Follow the resistance management guidelines in the Resistance Management Section. Do not apply more than one application of Amistar or other Group 11 fungicides before alternation with a fungicide that is not in Group 11. Application Directions: Amistar applications should begin prior to \ disease development and continue throughout the season on a 7-14 day ! schedule, following the resistance management guidelines. Applications may be made by ground, air or chemigation. An adjuvant may be added at recommended rates. Use a minimum of 10 gallons of water per acre by ground, and minimum of 3 gallons per acre by air. Specific Use Restrictions: Do not apply more than 1.5 Ibs. a.i.lA per season of azoxystrobin-containing products. M~ be applied the day of harvest (0 day PHI). - (~ I ~ ~

Crop Target Diseases Brassica White rust Leafy Greens subgroup (Albugo candida) Black spot Broccoli raab (Alternaria spp.) Cabbage, Chinese Cercospora leaf spot Collards (Cercospora spp.) Kale Mizuna Mustard greens Mustard spinach Rape greens Including all cultivars and/or hybrids of these Soilborne Diseases Seedling root rot, basal stem rot (Rhizoctonia so/anI) Use Rate oz. productlA (lb. a.i.JAl 2-5 (0.10-0.25) 0.125-0.25 oz. /1000 row feet Remarks Page 21 of 59 Amistar Integrated Pest {Disease} Management: Amistar should be integrated into an overall disease management strategy that includes varieties with disease tolerance, proper timing of irrigation and removal of plant debris in which inoculum overwinters. Resistance Management: Follow the resistance management guidelines in the Resistance Management Section. Do not apply more than one application of Amistar or other Group 11 fungicides before alternation with a fungicide that is not in Group 11. Application Directions: Amistar applications should begin prior to disease development and continue throughout the season on a 7-14 day schedule, following the resistance management guidelines. Applications may be made by ground, air or chemigation. An adjuvant may be added at recommended rates. For soilborne/seedling disease control, see directions and rates under GENERAL INFORMATION section. Specific Use Restrictions: Do not apply more than 0.75 lb. a.i.lA per season of azoxystrobin-containing products. May be applied the day of harvest (0 day PHI). /~ ~ -~

Crop Target Diseases

Bulb Vegetables Foliar Diseases

Cladosporium leaf blotch

Garlic (Cladosporium allii)

Leek Purple blotch

Onion, bulb (Alternaria porri)

Onion, green Rust

Welch onion (Puccinia allii)

Shallot White rot

(Sclerotium cepivorum)

Downy mildew

(Peronospora destructor)

Botrytis leaf blight

(Botrytis aclada)

Soilborne Diseases

Rhizoctonia damping-off

(Rhizoctonia solani)

Use Rate

oz. productiA

(lb. a.i.lAi

2-4

(0.10-0.20)

3-5

(0.15-0.25)

0.125-0.25

oz.l1000 row

feet

Page 22 of 59

Amistar

Remarks

Integrated Pest {Disease} Management: Amistar should be integrated

into an overall disease management strategy that includes selection of

varieties with disease tolerance, optimum plant populations, proper

fertilization, plant residue management, crop rotation and proper timing

and placement of irrigation.

Resistance Management: Follow the resistance management guidelines

in the Resistance Management Section. Do not apply more than one

application of Amistar or other Group 11 fungicides before alternation with

a fungicide that is not in Group 11.

Application Directions: For downy mildew, make preventative applications on a 5-7 day schedule. For all other diseases, Amistar applications should begin prior to disease development and continue throughout the season every 7-14 days following the resistance management guidelines. Applications may be made by ground, air or chemigation. If applications are made by air, the higher rates should be used for adequate control. An adjuvant may be added at recommended rates. Mixtures of Amistar with insecticides and silicone adjuvants should be tested for crop safety before application to the crop. For soilborne/seedling disease control, see directions under GENERAL INFORMATION section. If the application is an in-furrow application, the spray should be made just prior to seed placement so that the majority of the chemical is under the seed. This will reduce the potential for phytotoxicity, especially if fertilizer is added to the application. Specific Use Restrictions: Do not apply more than 1.5 Ibs. a.i.lA per season of azoxystrobin-containing products. May be applied the day of harvest (0 day PHI). ,~ .I 9...l CS"' ~ ~

Use Rate oz. producUA Crop Target Diseases (lb. a.i.lA) Canola Blackleg 2-5 (see Oilseed Crops for additional (Leptosphaeria maculans) (0.10-0.25) information) Alternaria blackspot (Alternaria spp.) Sclerotinia stem rot (Sclerotinia sclerotiorum) Specific Use Restrictions: ge Ret make a~~lisatieRs lateF tl=laR Q§% raetal fall {eEl sta!iJe}. Do not apply more than 0.45 lb. aJ.lA per season of azoxystrobin-containing products. Do not apply within 30 days of harvest. Page 23 of 59 Amistar Remarks Integrated Pest {Disease}Management: Amistar should be integrated into an overall disease management strategy that includes selection of varieties with disease tolerance, certified seed, seed treatment and crop rotation. Resistance Management: Follow the resistance management guidelines in the Resistance Management Section. Do not apply more than one application of Amistar or other Group 11 fungicides before alternation with a fungicide that is not in Group 11. Application Directions: In general, apply 2 oz of Amistar at early bud : followed by 5 oz at about 45 days before harvest. A third application of 2 oz may be made 30 days before harvest. Specifically for blackleg, Amistar applications should be made at the 2-4 leaf stage. For Alternaria or Sclerotinia, 5.0 oz. productlA should be applied at 10-25% flowering (3-7 days following first flower). Use the higher rate under heavy disease pressure or when conditions are favorable for disease. For control of Alternaria alone, 2.6 oz. productlA may be applied at pod stage (approximately 95% petal fall). Applications may be made by ground, air or chemigation. Use a minimum of 10 gallons of water per acre for ground apj>lications. / ~ -----. $

Use Rate oz. productlA Crop Target Diseases (lb. a.i.lA) Carrot Early blight 3-6.5 (Cercospora carotae) (0.15-0.33) Late blight (Alternaria dauci) White mold (Sclerotium ro/fsii) For additional diseases, see Vegetables, root, subgroup Soilborne Diseases 0.125-0.25 oz. Rhizoctonia root rot /1000 row feet (Rhizoctonia solani) Page 24 of 59 Amistar Remarks Integrated Pest {Disease} Management: Amistar should be integrated into an overall disease management strategy that includes selection of varieties with disease tolerance, optimum plant populations, proper fertilization, plant residue management, crop rotation and proper timing and placement of irrigation. Resistance Management: Follow the resistance management guidelines in the Resistance Management Section. Do not apply more than one application of Amistar or other Group 11 fungicides before alternation with a fungicide that is not in Group 11. " Application Directions: Amistar applications should begin prior to disease development and continue throughout the season every 7-14 days following the resistance management guidelines. Applications may be made by ground, air or chemigation. An adjuvant may be added at recommended rates. For soilborne/seedling disease control, see directions and rates under GENERAL INFORMATION section. Specific Use Restrictions: Do not apply more than 2.0 Ibs. a.i.lA per season of azoxystrobin-containing products. May be applied the day of harvest (0 day PHI). .~ ~ §

Use Rate oz. productlA Crop Target Diseases (lb. a.i.lA) Celery Early blight 3-5 (Cercospora apii) (0.15-0.25) Late blight (Septoria apico/a) For additional diseases, see Leafy Vegetables Soilborne Diseases 0.125-0.25 oz. Rhizoctonia root rot /1000 row feet JRhizoctonia so/ani) Page 25 of 59 Amistar Remarks Integrated Pest {Disease} Management: Amistar should be integrated into an overall disease management strategy that includes selection of varieties with disease tolerance, optimum plant populations, proper fertilization, plant residue management, crop rotation and proper timing and placement of irrigation. Resistance Management: Follow the resistance management guidelines in the Resistance Management Section. Do not apply more than one application of Amistar or other Group 11 fungicides before alternation with a fungicide that is not in Group 11. ! Application Directions: Amistar applications should begin prior to disease development and continue throughout the season every 7-14 days following the resistance management guidelines. Applications may be made by ground, air or chemigation. An adjuvant may be added at recommended rates. For SOilborne/seedling disease control, see directions and rates under GENERAL INFORMATION section. Specific Use Restrictions: Do not apply more than 1.5 Ibs. a.i.JA per season of azoxystrobin-containing products. May be applied the day of harvest (0 day PHI). ,~ SD ,..G ~. ~

Use Rate oz. productlA Crop Target Diseases (lb. a.i.lA) Christmas Trees Diplodia tip blight 2-5 (Dip/odia pinea) (0.10-0.25) Lophodermium needlecast (Lophodermium pinastrt) Swiss needlecast (Phaeocrytopus gaumannit) Page 26 of 59 Amistar Remarks Integrated Pest {Disease) Management: Amistar should be integrated into an overall disease management strategy that includes selection of varieties with disease tolerance and removal of plant debris in which inoculum may overwinter. Resistance Management: Follow the resistance management guidelines in the Resistance Management Section. Do not apply more than two sequential applications of Amistar or other Group 11 fungicides before alternation with a fungicide that is not in Group 11. Application Directions: Amistar applications should begin prior to disease development and continue throughout the season at 7-21 day ) intervals following the resistance management guidelines. Applications may be made by ground. air or chemigation. An adjuvant may be added at recommended rates. Specific Use Restrictions: Do not apply more than 2.0 Ibs. a.i.lA per season of azoxystrobin-containing products. / .......... . .).) ~ ~

Use Rate oz. productiA Crop Target Diseases (lb. a.i.lA) Citrus Fruit Greasy spot 4-5 (Mycosphaere/la citri) (0.20-0.25) Calamondin Melanose Citron (Diaporthe citri) Citrus hybrids Scab Grapefruit (Elsinoe fawcettii) Kumquat Albinism Lemon (Alternaria alternata pv citrt) Lime Post bloom fruit drop (PFD) Mandarin (Co/letotrichum acutatum) Orange (sour and sweet) Alternaria leaf and fruit spot Pummelo (Alternaria citri) Satsuma mandarin Penicillium decays Tangerine Green mold, Whisker mold, Including all cultivars and/or hybrids suppression of Blue mold of these (PeniCillium spp.) Diplodia stem-end rot (Diplodia natalensis) Phomopsis stem-end rot (Phomopsis citrii) Specific Use Restrictions: Do not use Amistar in citrus plant propagation nurseries. Do not apply more than1.5 Ibs. a.i.lA per season of azoxystrobin-containing products. May be applied the day of harvest (0 dayPHI). Page 27 of 59 Amistar Remarks Integrated Pest {Disease} Management: Amistar should be integrated into an overall disease management strategy that includes selection of varieties with disease tolerance, removal of plant debris in which inoculum overwinters, and proper timing of irrigation. Resistance Management: Follow the resistance management guidelines in the Resistance Management Section. Do not apply more than two sequential applications of Amistar or other Group 11 fungicides before alternation with a fungicide that is not in Group 11. Do not make more than four applications of Amistar or other Group 11 fungicide per season. { Application Directions: Amistar applications should begin prior to i disease development and continue throughout the season on 7-21 day intervals following the resistance management guidelines. Under conditions that favor severe disease epidemiCS, the higher application rates should be used. Applications may be made by ground, air or chemigation. An adjuvant may be added at recommended rates. A horticultural spray oil should be used to improve control of greasy spot. Do not use Amistar in citrus plant propaQation nurseries. '\ '-Y --4S' V

Crop Target Diseases Corn Rust (Puccinia sorghi) Field Pop Anthracnose leaf blight Sweet (Colletotrichum graminico/a) (Includes Seed Production) Gray leaf spot (Cercospora sorghi) Northern corn leaf blight (Setosphaeria turcica) Northern corn leaf spot (Cochiliobo/us carbonum) Southern corn leaf blight (Cochliobo/us heterostrophus) Eye spot (Aureobasidium zeae) Soilborne Diseases Rhizoctonia root and stalk rot (Rhizoctonia so/ani) Use Rate oz. productlA (lb. a.i.lA) 2-3 (0.10-0.15) 3-5 (0.15-0.25) 0.125-0.25 oz. /1000 row feet Page 28 of 59 Amistar Remarks Integrated Pest {Disease} Management: Amistar should be integrated into an overall disease management strategy that includes selection of varieties with disease tolerance, optimum plant populations, proper fertilization, plant residue management, crop rotation, and water management practices. Resistance Management: Follow the resistance management guidelines in the general use precaution section. Do not apply more than two sequential applications of Amistar or other Group 11 fungicides before alternation with a fungicide that is not in Group 11. For field corn and field corn grown for seed, do not make more than two (2) applications per season. ') Application Directions: For gray leaf spot, apply Amistar at the onset of disease. A second application may be required 14 days later if disease pressure persists. For all other diseases, Amistar applications should begin prior to disease development and may continue throughout the season every 7-14 days following the resistance management guidelines. Applications may be made by ground, air or chemigation. An adjuvant may be added at recommended rates. For soilborne/seedling disease control, see directions and rates under GENERAL INFORMATION section. Specific Use Restrictions: Do not apply more than 2.0 Ibs. a.i.lA per season of azoxystrobin-containing products. Do not apply within 7 days of harvest. ,.--." i ~

Use Rate oz. productlA Crop Target Diseases (lb. a.i.lA) Cotton Rhizoctonia seedling blight In-furrow (Rhizoctonia so/ani) 0.125-0.25 oz. pythium seedling blight /1000 row feet (Pyfhium aphanidermatum) (0.10-0.20 oz. a.i. per 1000 row feet) Specific Use Restrictions: Make only one application per use season. Page 29 of 59 Amistar Remarks Integrated Pest 'Disease} Management: Amistar should be integrated into an overall disease management strategy that includes selection of varieties with disease tolerance, optimum plant populations, proper fertilization, plant residue management, crop rotation and proper water management. Application Directions: Apply Amistar as an in-furrow spray in 3-7 gallons of water at planting. Mount the spray nozzle so the spray is directed into the furrow just before the seed are covered. Use the higher rate when the weather conditions are expected to be conducive for disease development, if the field has a history of pythium problems, or if minimumllow till programs are in place. See GENERAL INFORMATION section for table illustrating total fluid ounces per acre with various row spacinQs. ~> ~ ~

Page 30 of 59 Amistar Cr~ Cranberry Target Diseases Cotton ball (Monilia oxycocci) Lophodermium twig blight (Lophodermium spp.) Fruit rots (Physalospora vaccinii) (Glomerella cingulata) (Coleophoma empetri) Use Rate oz. productlA (lb. a.i.lA) 2-5 (0.10-0.25) Specific Use Restrictions: May be applied up to three days prior to harvest (3-day PHI). Do not apply more than 1.5 Ibs. a.i.lA per season of azoxystrobin-containing products. Do not treat cranberry fields used for aquaculture of fish and crustacea. Remarks Integrated Pest (Disease) Management: Amistar should be integrated into an overall disease management strategy that includes selection of varieties with disease tolerance, optimum plant populations, proper fertilization, plant residue management, crop rotation and proper water management. Resistance Management: Follow the resistance management guidelines in the Resistance Management Section. Do not apply more than two sequential applications of Amistar or other Group 11 fungicides before alternation with a fungicide that is not in Group 11. Application Directions: Begin applications at 5-10% bloom for fruit rot, cottonball, and twig blight. Continue applications on a 7-14 day schedule if conditions are favorable for disease development. Applications may be made by ground, chemigation or air. Do not apply when weather conditions favor drift from treated areas to non-target aquatic habitat. Applicators should use care in making applications near non-target aquatic habitats. Do not apply to flooded crop. Do not allow release of irrigation or flood water to non-target aquatic habitat for at least 14 days after the last application. r,"",,\ ) ~ -~

Crop Target Diseases Cucurbits Anthracnose (Col/etotrichum lagenarium) Cantaloupe Belly rot Chayote (Rhizoctonia solant) Chinese-waxgourd Downy mildew Cucumber (Pseudoperonospora cubensis) Gourds Gummy stem blight Honeydew (Didymel/a bryoniae) Melons Leaf spots Momordica spp. (Alternaria spp., Cercospora spp.) (bitter melon, balsam apple) Myrothecium canker Muskmelon (Myrothecium roridum) Watermelon Plectosporium blight Pumpkin (Plectosporium tabacinum) Squash Powdery mildew Zucchini (Sphaerotheca fuliginea, Including cultivars and/or hybrids of (Erysiphe cichoracearum) these Soilborne diseases Rhizoctonia root rot (Rhizoctonia solani) Use Rate oz. productiA (lb. a.i.lA) 2-5 (0.10-0.25} 0.125-0.25 oz. /1000 row feet Page 31 of 59 Amistar Remarks Integrated Pest {Disease} Management: Amistar should be integrated into an overall disease management strategy that includes selection of varieties with disease tolerance, optimum plant populations, proper fertilization, plant residue management, crop rotation and proper timing and placement of irrigation. Resistance Management: Follow the resistance management guidelines in the Resistance Management Section. Do not apply more than one application of Amistar or other Group 11 fungicides before alternation with a fungicide that is not in Group 11. Do not make more than four (4) foliar applications of Amistar or other Group 11 fungicides ) per crop per acre per year. Application Directions: For both downy and powdery mildew, make applications on a 5-7 day schedule. For belly rot control, the first application should be made at the 1-3 leaf crop stage with a second application just prior to vine tip over or 10-14 days later whichever occurs first. For all other diseases, Amistar applications should begin prior to disease development and continue throughout the season every 7-14 days following the resistance management guidelines. Applications may be made by ground, air or chemigation. An adjuvant may be added at recommended rates. Amistar should not be tank mixed with CDC, MSO or silicon adjuvants. Amistar should not be tank mixed with Malathion, Kelthane®, Thiodan®, Phaser®, Lannate®, Lorsban®, M-Pede® or Botran®. For soilborne/seedling disease control, see directions and rates under GENERAL INFORMATION section. Specific Use Restrictions: Do not apply more than 1.5 Ibs. a.i.IA per season of azoxystrobin-containing products. , .~ Do not apply within 1 day of harvest. i l \ -

Use Rate oz. productlA Crop Target Diseases {lb. a.i.JA) Grapes Downy mildew 3.2-5.0 Including Muscadines (P/asmopara vitico/a) (0.16-0.25) Phomopsis cane and leaf spot (Phomopsis vitico/a) Powdery mildew (Uncinu/a necator) Black rot (Guignardia bidwellil) Suppression: Botrytis bunch rot (Botrytis cinerea) Page 32 of 59 Amistar Remarks Integrated Pest {Disease} Management: Amistar should be integrated into an overall disease management strategy that includes canopy management through pruning and thinning, proper selection of varieties with disease tolerance, proper timing and placement of irrigation and removal of plant debris in which inoculum overwinters. Resistance Management: Follow the resistance management guidelines in the Resistance Management Section. Do not apply more than two sequential foliar applications of Amistar or other Group 11 fungicides before alternating with a fungicide that is not in Group 11. Application Directions: Amistar applications should begin prior to ---~ disease development and continue throughout the season every 10-14 days following the resistance management guidelines. Applications may be made by ground, air or chemigation. An adjuvant may be added at recommended rates. ATTENTION Amistar is extremely phytotoxic to certain apple varieties. AVOID SPRAY DRIFT. Extreme care must be used to prevent injury to apple trees (and apple fruit). DO NOT spray Amistar where spray drift may reach apple trees. DO NOT spray when conditions favor drift beyond area intended for application. Conditions which may contribute to drift include thermal inversion, wind speed and direction, sprayer nozzle/pressure combinations, spray droplet size, etc. Contact your State extension agent for spray drift prevention guidelines in your area. DO NOT use spray equipment which has been previously used to apply Amistar to spray apple trees. Even trace amounts can cause unacceptable phytotoxicity to certain apple and crabapple varieties. I ~ AVOIDING SPRAY DRIFT IS THE RESPONSIBILITY OF THE , APPLICATOR. Specific Use Restrictions: Do not apply more than 1.5 Ibs. a.i.IA per season of azoxystrobin-containing products. Do not apply within 14 days of harvest. 'tf W

Use Rate oz. productlA Crop Ta'llet Diseases (lb. a.i.lA) Grasses Rust 2-5 (grown for seed) (Puccinia spp.) (0.10-0.25) Powdery mildew (Erysiphe graminis) Ergot stem diseases Remarks Page 33 of 59 Amistar Integrated Pest {Disease} Management: Amistar should be integrated into an overall disease management strategy that includes varieties with disease tolerance, proper timing of irrigation, crop rotation, and fertility. Resistance Management: Follow the resistance management guidelines in the Resistance Management Section. Do not apply more than two sequential applications of Amistar or other Group 11 fungicides before alternation with a fungicide that is not in Group 11. Application Directions: Amistar applications should begin prior to disease development and continue throughout the season on a 10-14 day i schedule, following the resistance management guidelines. Applications may be made by ground, air or chemigation .. An adjuvant may be added at recommended rates. Specific Use Restrictions: Do not apply more than 1.5 Ibs. a.i.lA per season of azoxystrobin-containing products. May be applied up to 8 days prior to harvest (swathing). o ~ ~

Crop Herbs & Spices (except black pepper) Allspice; Angelica; Anise (seed); Anise, star; Annatto; Balm {lemon balm); Basil; Borage; Burnet; Camomile; Caper (buds); Caraway; Caraway, black; Cardamom; Cassia (buds); Catnip; Celery seed; Chervil (dried); Chive; Chive, Chinese; Cinnamon; Clary; Clove (buds); Coriander (cilantro or Chinese parsley) (leaf); Coriander (seed); Costmary; Culantro (leaf and seed); Cumin; Curry (leaf); Dill (seed); Dillweed; Fennel, common; Fennel, Florence (seed); Fenugreek; Grains of paradise; Horehound; Hyssop; Juniper (berry); Lavender; Lemongrass; Lovage (leaf and seed); Mace; Marigold; Marjoram; Mustard (seed), Nasturtium; Nutmeg; Parsley (dried); Pennyroyal; Pepper, white; Poppy seed; Rosemary; Rue; Saffron; Sage; Savory, summer and winter; Sweet bay; Tansy; Tarragon; Thyme; Vanilla; Wintergreen; Woodruff; Wormwood Use Rate oz. productlA Target Diseases (lb. a.i.lA) Corynespora blight 2-5 (Corynespora cassiicola) (0.10-0.25) Dill blight (Cercosporidium punctum) Phoma blight (Passa/ora puncta) Remarks Page 34 of 59 Amistar Integrated Pest {Disease} Management: Amistar should be integrated into an overall disease management strategy that includes varieties with disease tolerance, proper timing of irrigation and removal of plant debris in which inoculum overwinters. Resistance Management: Follow the resistance management guidelines in the Resistance Management Section. Do not apply more than two sequential applications of Amistar or other Group 11 fungicides before alternation with a fungicide that is not in Group 11. Application Directions: Amistar applications should begin at the onset of disease development and continue throughout the season on a 7 day schedule, following the resistance management guidelines. Applications may be made by ground only. An adjuvant may be added at recommended rates. Use a minimum of 30 gallons of water per acre. Specific Use Restrictions: Do not apply more than 1.5 Ibs. a.i.lA per season of azoxystrobin-containing products. May be applied the day of harvest (0 day PHI). • ~ ~

Crop Leafy Vegetables (except brassica) Amaranth Arugula Cardoon Celery Celtuce Chervil Chrysanthemum, edible Coriander, leaves (Cilantro) Corn salad Cress Dandelion Dock Endive Fennel Lettuce, head and leaf Orach Parsley Purslane Radicchio Rhubarb Spinach Swiss Chard Including cultivars and/or hybrids of these Target Diseases Foliar Diseases Alternaria leaf spot (Alternaria sonchi, A. spp.) Cercospora leaf spot (Cercospora spp.) Anthracnose (Microdochium panattonianum, Colletotrichum dematium) Septoria leaf spot (Septoria petroselini) Use Rate oz. productlA (lb. a.i.lA) 2-5 (0.10-0.25) Remarks Page 35 of 59 Amistar Integrated Pest (Disease) Management: Amistar should be integrated into an overall disease management strategy that includes selection of varieties with disease tolerance, optimum plant populations, proper fertilization, plant residue management, crop rotation and proper timing and placement of irrigation. Resistance Management: Follow the resistance management guidelines in the Resistance Management Section. Do not apply more than one application of Amistar or other Group 11 fungicides before alternation with a fungicide that is not in Group 11. White rust ./'-...... 'Albu ooccidentalis Application Directions: For both downy and powdery mildew, make Downy mildew 4-5 preventative applications on a 5-7 day schedule. For all diseases, (Bremia lactucae) (0.20-0.25) Amistar applications should begin prior to disease development and Powdery mildew continue throughout the season every 7-14 days following the resistance (Eyrisiphe cichoracearum) management guidelines. Applications may be made by ground, air or chemigation. An adjuvant may be added at recommended rates. Soilborne Diseases Webb blight, Bottom rot, Crater rot, Root rot (Rhizoctonia solani) 0.125-0.25 oz. /1000 row feet A TIENTION: Applications of Amistar to leafy vegetable foliage have contributed to foliar phytotoxicity under certain circumstances. Proceed with caution with regard to tank mixes and adjuvants when treating leafy vegetables with Amistar. Amistar must not be tank mixed on leaf lettuce with AMBUSH®WP, Pounce®WP, Aliette®, Warrior®with Zeon™ Technology, or on other product that may increase the penetration of Amistar into the leaf surface, such as, but not limited to, silicone wetters. For soilborne/seedling disease control, see directions and rates under GENERAL INFORMATION section. \ SpeCific Use Restrictions: Do not apply more than 1.5 Ibs. a.i.lA per season of azoxystrobin-containing products. May be ~plied the day of harvest (0 day Pfil). I:. .}J ~

Crop Target Diseases legume Vegetables, dry and Bean rust succulent: (Uromyces appendiculatus) Anthracnose Bean (Lupinus spp.) (includes grain (Col/etotrichum lindemuthianum) lupin, sweet lupin, white lupin, and Alternaria leaf spot white sweet lupin) (Alternaria alternata) Bean (Phaseolus spp.) (includes field Ascochyta leaf spot bean, kidney bean, lima bean, navy (Ascochyta phaseolorum) bean, pinto bean, runner bean, snap Rust bean, tepary bean, wax bean) (Phakopsora spp.) Bean (Vigna spp.) (includes adzuki Southern blight bean, asparagus bean, blackeyed pea, (Sclerotium ro/fsii) cow pea, catjang, Chinese longbean, Webb blight Crowder pea, moth bean, mung bean, (Rhizoctonia solani) rice bean, southern pea, urd bean, Ascochyta blight yardlong bean) (Mycosphaerel/a pinodes) Broad bean (fava bean) (Vicia faba) Ascochyta leaf and pod spot Chickpea (garbanzo bean) (Cicer (Ascochyta spp.) arietinum) Alternaria blight Guar (Cyamopsis tetragonoloba) (Alternaria spp.) Jackbean (Canavalia ensiformis) Soilborne diseases Lablab bean (hyacinth bean) (Lablab Rhizoctonia root rot purpureus) Lentil (Lens esculenta) (Rhizoctonia solant) Pea (Pisum spp.) (includes dwarf pea, edible-pod pea, English pea, garden pea, green pea, field pea, snow pea, sugar snap pea) Pigeon pea (Cajanus cajan) Sword bean (Canavalia gladiata) Use Rate oz. productlA (lb. a.i.JA) 2 10.10) 2-5 (0.10-0.25) 0.125-0.25 oz. 11000 row feet Page 36 of 59 Amistar Remarks Integrated Pest (Disease} Management: Amistar should be integrated into an overall disease management strategy that includes selection of varieties with disease tolerance, proper timing and placement of irrigation, crop rotation and crop residue management. Resistance Management: Follow the resistance management guidelines in the Resistance Management Section. Do not apply more than two sequential applications of Amistar or other Group 11 fungicides before alternation with a fungicide that is not in Group 11. -Application Directions: Amistar applications should begin prior to disease development and continue throughout the season every 7-14 days following the resistance management guidelines. Use the higher rates under severe disease pressure. Applications may be made by ground, air or chemigation. An adjuvant may be added at recommended rates. For rust, use of a non-ionic surfactant is recommended. For soilborne/seedling disease control, see directions and rates under GENERAL INFORMATION section. Conduct a seed safety test with your crop before making in-furrow applications. " Specific Use Restrictions: Do not apply more than 1.5 Ibs. a.i.lA per season of azoxystrobin-containing products. Not for use on Austrian Winter Peas or any other field pea cultivars intended for livestock feeding only. Not for use on any cowpea cultivars intended for livestock feeding only. For use on soybeans, please refer to the soybean crop directions for use. Do not apply within 14 days of harvest of Dry Legume Vegetables (dry bean and dry pea seeds). May be applied the day of harvest for succulent beans and peas. c§ s. ~

Use Rate oz. productlA Crop Target Diseases (lb. a.i.JA) Mint Rust 2-5 (Fresh or for processing into mint oil) (Puccinia menthae) (0.10-0.25) Powdery mildew (Erysiphe spp.) Soilborne Diseases 0.125-0.25 oz. Seedling root rot, basal stem rot /1000 row feet (Rhizoctonia solam) Page 37 of 59 Amistar Remarks Integrated Pest {Disease) Management: Amistar should be integrated into an overall disease management strategy that includes varieties with disease tolerance, proper timing of irrigation and removal of plant debris in which inoculum overwinters. Resistance Management: Follow the resistance management guidelines in the Resistance Management Section. Do not apply more than two sequential applications of Amistar or other Group 11 fungicides before alternation with a fungicide that is not in Group 11. Application Directions: Amistar applications should begin prior to disease development and continue throughout the season on a 7-10 day , ") schedule, following the resistance management guidelines. Applications may be made by ground, air or chemigation. An adjuvant may be added at recommended rates. For soilborne/seedling disease control, see directions and rates under GENERAL INFORMATION section. Specific Use Restrictions: Do not apply more than 0.75 lb. a.i.IA per season of azoxystrobin-containing products. For fresh mint, may be applied the day of harvest. For processed mint, do not apply within 7 days prior to harvest. I ,~ ~ ~­ ~

Crop Target Diseases Oilseed Crops Downy mildew (Plasmppora halstedii, Cram be Plasmopora helianthl) Flax Mustard, Indian Alternaria leaf spot Mustard, Field (Alternaria spp.) Mustard, Black Rapeseed Rapeseed, Indian Safflower Sunflower Use Rate oz. productlA (lb. a.i.lA) 2-5 (0.1-0.25) Page 38 of 59 Amistar Remarks Integrated Pest (Disease} Management: Amistar should be integrated into an overall disease management strategy that includes varieties with disease tolerance and crop rotation to reduce plant debris in which inoculum overwinters. Resistance Management: Follow the resistance management guidelines in the Resistance Management Section. Do not apply more than two sequential applications of Amistar or other Group 11 fungicides before alternation with a fungicide that is not in Group 11. Application Directions: Apply 2 oz of Amistar at early bud followed by 5 ! oz at about 45 days before harvest. A third application of 2 oz may be ) made 30 days before harvest. Applications may be made by ground, air or chemigation. Use a minimum of 10 gallons of water per acre for ground applications. Specific Use Restrictions: Do not apply more than 0.45 lb. a.i.lA per season of azoxystrobin-containing products. Do not apply within 30 days of harvest. ~ 1 ..-C ~

Crop Target Diseases Peanuts Soil-borne diseases - early season (in furrow application) Aspergillus crown rot (Aspergillus niger) pythium damping off (pythium spp.) Stem rotlWhite mold suppression (Sclerotium ro/fsii) Soil-borne diseases - mid-late season Rhizoctonia peg and pod rot (Rhizoctonia solant) Stem rotIWhite mold (Sclerotium ro/fsii) Suppression only: pythium pod rot (Pythium myriotylum) Cylindrocladium black rot (Cylindocladium crotalariae) Foliar diseases Early leaf spot (Cercospora arachidicola) Late leaf spot (Cercosporidium personatum) Rust (Puccinia arachidis) Webb blotch (Phoma arachidicola) Use Rate oz. productlA (lb. a.i.lA) 0.125-0.25 oz. /1000 row feet 4-8 (0.20-0.40) 2-6 (0.10-0.30) Page 39 of 59 Amistar Remarks Integrated Pest {Disease} Management: Amistar should be integrated into an overall disease management strategy that includes selection of varieties with disease tolerance, proper timing and placement of irrigation, crop rotation and crop residue management. Resistance Management: Follow the resistance management guidelines in the Resistance Management Section. Do not apply more than two sequential applications of Amistar or other Group 11 fungicides before alternation with a fungicide that is not in Group 11. Application Directions: Apply Amistar in-furrow at planting for control of r various seedlseedling diseases including early season suppression of ' stem rot. See directions and rates under GENERAL INFORMATION section. Amistar should be applied at approximately 60 and 90 days after planting as a foliar application. This application regime may be applied earlier in the season if environmental conditions favor disease development. These two applications of Amistar will provide protection against the soil borne diseases and will also provide control of the foliar diseases listed for a 10-14 day period after each spray. Under heavy disease pressure and/or where there is high rainfall and/or irrigation, use 6-8 oz.lA. For light disease pressure and dry environmental conditions (non-irrigated, low rainfall), use 4-8 oz.lA. For control of Pythium, a rate of 8 oz.lA is required. Additional applications of other fungicides on a leaf spot application schedule will be required to provide season-long disease control of the leaf spot diseases. Applications may be made by ground, air or chemigation. An adjuvant may be added at recommended rates. For foliar disease control only, a lower rate of Amistar may be applied on a 10-14 day interval. - Specific Use Restrictions: Do not apply more than 0.80 lb. aj.lA per season of azoxystrobin-containing products. Do not apply within 14 days of harvest. -C ~ ~

Use Rate oz. productlA Crop Target Diseases (lb.a.i.lA) Pecans Anthracnose 2-4 (G/omerella cingulata) (0.10-0.20) Scab (Cladosporium caryigenum) Page 40 of 59 Amistar Remarks Integrated Pest {Disease} Management: Amistar should be integrated into an overall disease management strategy that includes selection of varieties with tolerance to disease and removal of plant debris in which inoculum overwinters. Resistance Management: Follow the resistance management guidelines in the Resistance Management Section. Do not apply more than two sequential applications of Amistar or other Group 11 fungicides before altemation with a fungicide that is not in Group 11. Application Directions: Amistar applications should begin prior to disease development and continue throughout the season on 7-21 day ') intervals following the resistance management guidelines. Applications may be made by ground, air or chemigation. An adjuvant may be added at recommended rates. Specific Use Restrictions: Do not apply more than 1.2 Ibs. a.i.lA per season of azoxystrobin-containing products. Do not a~ within 45 days of harvest. /~ $- .}l

Crop Target Diseases Pepper Powdery mildew (Sphaerotheca spp.) Bell Pepper Anthracnose Non-Bell Pepper (Col/etotrichum spp.) Sweet Non-Bell Pepper Eggplant Okra See specific directions for use for Tomatoes Soilborne Diseases Seedling root rot, basal stem rot (Rhizoctonia solani) Use Rate oz. productlA (lb. a.i.lA) 2-5 (0.10-0.25) 0.125-0.25 oz. /1000 row feet Page 41 of 59 Amistar Remarks Integrated Pest {Disease} Management: Amistar should be integrated into an overall disease management strategy that includes varieties with disease tolerance, proper timing of irrigation and removal of plant debris in which inoculum overwinters. Resistance Management: Follow the resistance management guidelines in the Resistance Management Section. Do not apply more than one application of Amistar or other Group 11 fungicides before alternation with a fungicide that is not in Group 11. I Application Directions: Amistar applications should begin prior to disease development and continue throughout the season on a 7-14 day ) schedule, following the resistance management guidelines. Applications may be made by ground, air or chemigation. An adjuvant may be added at recommended rates. For soilborne/seedling disease control, see directions and rates under I , GENERAL INFORMATION section. I Specific Use Restrictions: Do not apply more than 1.0 lb. a.i.lA per season of azoxystrobin-containing products. May be applied the day of harvest. '~ ~ --~

Use Rate oz. productiA Crop Target Diseases (lb. a.i.lA) Pistachios Alternaria late blight 2-5 (Alternaria alternata) (0.10-0.25) Botryosphaeria panicle and shoot blight (Botryosphaeria dothidea) Septoria leaf spot (Septoria pistaciarum) Page 42 of 59 Amistar Remarks Integrated Pest (Disease} Management: Amistar should be integrated into an overall disease management strategy that includes selection of varieties with disease tolerance and removal of plant debris in which inoculum overwinters. Resistance Management: Follow the resistance management guidelines in the Resistance Management Section. Do not apply more than two sequential applications of Amistar or other Group 11 fungicides before alternation with a fungicide that is not in Group 11. Application Directions: Amistar applications should begin prior to r I disease development and continue throughout the season on 7-21 day intervals following the resistance management guidelines. Applications may be made by ground, air or chemigation. An adjuvant may be added at recommended rates. Specific Use Restrictions: Do not apply more than 1.5 Ibs. a.i.lA per season of azoxystrobin-containing products. Db not apply within 7 days of harvest. ,~ .....c ~ ~

Crop Potatoes Ta!Ilet Diseases Early blight (Alternaria solam) Late blight (Phytophthora infestans) Black dot (Colletotrichum coccodes) Powdery mildew (Erysiphe cichoracearum) Soilborne Diseases Black scurf (Rhizoctonia solani) Silver scurf (Helminthosporium solani) Black dot (Colletotrichum coccodes) Use Rate oz. productlA {lb. a.i.lA~ 2.0-6.5 (0.10-0.33) 0.125-0.25 oz. /1 000 row feet Page 43 of 59 Amistar Remarks Integrated Pest (Disease) Management: Amistar should be integrated into an overall disease management strategy that includes removal of plant debris in which inoculum overwinters, selection of varieties with tolerance to disease, clean certified seed, seed piece treatment, and disease forecasting. Resistance Management: Follow the resistance management guidelines in the Resistance Management Section. Do not apply more than one application of Amistar or other Group 11 fungicides before alternation with a fungicide that is not in Group 11. Application Directions: Early blight - For a 7-day application schedule, I' use Amistar 2 oz. product! A. If the interval is increased to 14 days, use the 4 oz. product!A rate. Late blight - Apply Amistar at 4 oz. product!A on a 7-day schedule. Initiate late blight applications in a preventative schedule prior to disease development according to local practices. If late blight symptoms develop or conditions favor disease switch immediately to a non-Group 11 fungicide, using a 5-day schedule. Addition of a spreader/sticker may improve coverage. For all other diseases, Amistar applications should begin prior to disease development and continue throughout the season every 7-14 days following the resistance management guidelines. Use the high rate and the shorter interval if disease epidemics are severe. Applications may be made ~~round, air or chemigation. For soilborne/seedling disease control, see directions and rates under GENERAL INFORMATION section. \ Specific Use Restrictions: Do not apply more than 2.0 Ibs. a.i.lA per season of azoxystrobin-containing products. Do not apply within 14 days of harvest. ~ ~ ~

Use Rate oz. productlA Crop Target Oiseases (lb. a.i.lA} Rice Sheath/Stem Diseases 2-6 Sheath blight (0.10-0.30) (Rhizoctonia solant) Aggregate sheath spot 3-6 (Rhizoctonia oryzae-sativae) (0.15-0.30) Black sheath rot (Gaeumannomyces graminis var. graminis) Sheath spot (Rhizoctonia oryzae) Stem rot (Sclerotium oryzae) Foliar Diseases Brown leaf spot (Cochliobolus miyabeanus) Leaf smut (Entyloma oryzae) Narrow brown leaf spot (Cercospora oryzae) Panicle Diseases Kernel smut (Neovossia barclayana) Panicle blast (Pyricularia grisea) Specific Use Restrictions: Do not treat rice fields used for aquaculture of fish and crustacea. Page 44 of 59 Amistar Remarks Integrated Pest {Disease} Management: Amistar should be integrated into an overall disease management strategy that includes selection of varieties with disease tolerance, optimum plant populations, proper fertilization, plant residue management, crop rotation, and sound water management practices. Resistance Management: Follow the resistance management guidelines in the Resistance Management Section. When Amistar is being applied for panicle blast on continuous rice acreage (no rotation to other crops), no more than two sequential foliar applications of Amistar or L-other Group 11 fungicides should be made over multiple years before alternating with a fungicide with a different mode of action. Do not make more than two (2) foliar applications of Amistar or other Group 11 fungicides per acre per season. Application Directions: Amistar should be applied prior to disease development. Applications may be made by ground, air or chemigation. For aerial application, volumes should be 5-10 GPA. An adjuvant may be added at recommended rates. For sheath blight control, application rates may vary from 3 to 4 oz'/A depending on the growth stage of the rice and the severity of the disease. Consult with your local extension personnel or Syngenta representative for the Syngenta Technical Bulletin on sheath blight control. For other stem/sheath diseases including stem rot, black sheath rot, aggregate sheath spot and sheath spot, apply when disease is less than 4 inches above water line usually between panicle differentiation (PO) +5 days to (PD)+10 days or at initial sign of disease. Under heavy disease pressure and conditions favorable for disease development, a second application may be applied. For foliar and panicle diseases, apply Amistar prior to disease development. Amistar must be applied as a preventative treatment for blast control and applied prior to favorable conditions for blast development. For panicle blast, an application should be applied at mid-boot to boot-split but prior to full head emergence. A second application should be applied when panicles are approximately 60-90% emerged from the boot (7-14 days later). Do not apply when weather conditions favor drift from treated areas to non-target aquatic habitat. Applicators should use care in making applications near non-target aquatic habitats. Do not apply more than 0.70 lb. a.i.lA per season of azoxystrobin-containing products. Do not apply within 28 days of harvest. Do not allow release of irriQation or flood water for at least 14 days after the last application. ....c.. _ClQ ~

Cr~ Soybeans Target Diseases Aerial blight (Rhizoctonia so/ani) IMoved Rust to below] Anthracnose (Colletotrichum truncatum) Alternaria leaf spot (Alternaria spp.) Brown spot (Septoria g/ycines) Cercospora blight and leaf spot (Cercospora kikuchii) Frogeye leaf spot (Cercospora sojina) Pod and Stem blight (Diaporfhe phase%rum) Rust (Phakopsora spp.) Use Rate oz. producUA (I b. a.i.l A) 2-5 (0.10-0.25) Remarks Page 45 of 59 Amistar Integrated Pest (Disease) Management: Amistar should be integrated into an overall disease management strategy that includes selection of varieties with disease tolerance, optimum plant populations, proper fertilization, plant residue management, crop rotation and proper timing and placement of irrigation. Resistance Management: Follow the resistance management guidelines in the Resistance Management Section. Do not apply more than two sequential applications of Amistar or other Group 11 fungicides before alternation with a fungicide that is not in Group 11. Application Directions: Amistar applications should begin prior to disease development. Use the high rates under condition favorable for severe disease pressure, dense plant canopies, or when susceptible varieties are planted. Contact Extension personnel for local economic thresholds and timings for specific diseases in your area. Applications may be made by ground, air or chemigation. Use of a crop oil concentrate or non-ionic surfactant with the lower use rate is recommended. Soybean rust: Amistar may be used at 4 ozlA when tank mixed with a triazole registergd for use on soybean rust. Soilborne Diseases 0.125-0.25 oz. I For soilborne/seedling disease control, see directions and rates under Southem blight /1000 row feet GENERAL INFORMATION section. (Sc/erotium ro/fsii) Rhizoctonia solani (Rhizoctonia so/ani) Specific Use Restrictions: Do not apply more than 1.5 Ibs. a.i.lA per season of azoxystrobin-containing products. Do not make more than one application at 5 oz. product/acre or 0.25 lb. a.i.lA to soybean forage and hay. Do not apply within 14 days of harvest of soybeans (bean). May be applied the day of harvest to soybean forage and hay. ,~~ ..c: ~~

Crop Target Diseases Stone Fruit Scab (Cladosporium carpophilum) Apricot Alternaria spot and fruit rot Cherry, sweet (Alternaria alternata) Cherry, tart Anthracnose Nectarine (Colletotrichum prunicola, Peach C. gloeosporioides) Plum Leaf rust Plumeot (Tranzschelia discolor) Prune Powdery mildew (Sphaerotheca pannosa, Podosphaera clandestina) Shot hole (Wilsonomyces carpophilus) Brown rot blossom blight and Fruit rot (Monilinia fructicola, M. laxa) Use Rate oz. productlA (lb. a.i.JA) 2-5 (0.10-0.25) 4-5 (0.20-0.25) Page 46 of 59 Amistar Remarks Integrated Pest {Disease} Management: Amistar should be integrated into an overall disease management strategy that includes selection of varieties with disease tolerance, removal of plant debris in which inoculum overwinters and pruning to provide sunlight and aeration into the canopy. Resistance Management: Follow the resistance management guidelines in the Resistance Management Section. Do not apply more than two sequential applications of Amistar or other Group 11 fungicides before alternation with a fungicide that is not in Group 11. Application Directions: For brown rot blossom blight, begin applications at early bloom and continue through petal fall. For brown rot on fruit, , Amistar may be applied to fruit up to the day of harvest. For scab, begin applications at petal fall and continue at 7-14 day intervals. For all other diseases, begin application at the onset of disease as a protectant fungicide and continue on a 7-14 day schedule. For peaches only, 3-5 oz. of Amistar may be used for scab control. Applications may be made by Qround, air or chemiQation. Specific Use Restrictions: Do not apply more than 1.5 Ibs. a.i.lA per season of azoxystrobin-containing products. May be applied the day of harvest (0 day PHI). .~\ ~ $

Use Rate oz. productlA Crop Target Diseases (lb. a.i.fA) Strawberry Anthracnose 2-5 (Colletotrichum fragariae) (0.10-0.25) Powdery mildew (Sphaerotheca macufaris) Suppression of Botrytis on the foliage (Botrytis cinerea) Soilborne Diseases 0.125-0.25 oz. Seedling root rot, basal stem rot /1000 row feet (Rhizoctonia so/ant) Specific Use Restrictions: Do not use in plant propagation nurseries. Do not apply more than 1.0 lb. aj.lA per season of azoxystrobin-containing products. May be applied the day of harvest (0 day PHI). Page 47 of 59 Amistar Remarks Integrated Pest {Disease} Management: Amistar should be integrated into an overall disease management strategy that includes varieties with disease tolerance, proper timing of irrigation and removal of plant debris in which inoculum overwinters. Resistance Management: Follow the resistance management guidelines in the Resistance Management Section. Do not apply more than two sequential applications of Amistar or other Group 11 fungicides before alternation with a fungicide that is not in Group 11. Application Directions: Amistar applications should begin prior to ! disease development and continue throughout the season on a 7-10 day ) schedule, following the resistance management guidelines. Applications may be made by ground, air or chemigation. An adjuvant may be added at recommended rates. [Moved paragraph below] For dip applications at transplanting for commercial ber!)l production: For suppression of root and crown rot caused by Colletotrichum spp., mix 1.6-2.6 oz. of Amistar per 100 gals. of water. Dip plants for 2-5 minutes. Plant treated plants as quickly as possible. It is recommended that transplants be washed to remove excess soil prior to dipping. For continued anthracnose control, follow with foliar applications beginning 2-3 weeks after transplant. For soilborne/seedling disease control, see directions and rates under GENERAL INFORMATION section. / \J1 -~

Use Rate oz. productlA Crop Target Diseases (lb. a.i.lA) Tobacco Blue mold 2-4 (Peronospora tabacina) (0.1-0.2) Frog-eye leafspot (Cercospora nicotianae) Target spot (Rhizoctonia so/ani) Specific Use Restrictions: Do not apply more than 0.52 lb. a.i.lA per season of azoxystrobin-containing products. Do not tank mix with Thiodan. May be applied up to day of harvest. Page 48 of 59 Amistar Remarks Integrated Pest (Disease) Management: Amistar should be integrated into an overall disease management strategy that includes proper selection of varieties with disease tolerance, removal of plant debris in which inoculum overwinters, plant residue management, crop rotation and proper timing and placement of irrigation. Resistance Management: Follow the resistance management guidelines in the Resistance Management Section. Do not apply more than one application of Amistar or other Group 11 fungicides before alternation with a fungicide that is not in Group 11. ( Application Directions: Amistar applications should begin prior to disease development or at first indication that blue mold is in the area. Do not apply Amistar as a curative application. If blue mold is present in the field, initiate applications with Acrobat® MZ prior to a Amistar application Apply on a 7-14 day interval with shorter intervals under conditions conducive to disease development. For ground applications, apply Amistar in sufficient water volume for adequate coverage and canopy penetration. For aerial application, volumes should be 10-15 GPA. Applications may be made by ground, air or chemigation. NOTE: Amistar may enhance weather flecking on the leaves of certain tobacco types. This does not affect yield and quality. Tank mixinQ Amistar with insecticides formulated as ECs or containing high amounts of solvents, may cause some crop injury. .'\ ~ ~ ~

Crop Target Diseases Tomatoes Anthracnose (Col/etotrichum coccodes) Black mold (A/ternaria a/ternata) Buckeye rot (Phytophthora spp.) Early blight (Alternaria so/ani) Powdery mildew (Oidiopsis sicu/a) Septoria leaf spot (Septoria /ycopersici) Target spot (Corynespora cassiico/a) Late blight (Phytophthora infestans) Use Rate oz. productlA (lb. a.i.lA) 1.6-2.0 (0.08-0.10) 2 (0.10) Page 49 of 59 Amjstar Remarks Integrated Pest {Disease} Management: Amistar should be integrated into an overall disease management strategy that includes proper selection of varieties with disease tolerance, removal of plant debris in which inoculum overwinters, plant residue management, crop rotation and proper timing and placement of irrigation. Resistance Management: Follow the resistance management guidelines in the Resistance Management Section. Do not apply more than one application of Amistar or other Group 11 fungicides before alternation with a fungicide that is not in Group 11. Application Directions: Amistar applications should begin prior to ! disease development and continue throughout the season following the resistance management guidelines. For late blight, Amistar should be applied at 5-7 day intervals. For all other tomato diseases, Amistar should be applied on 7-21 day intervals. Applications may be made by ground, air or chemigation. Use of an adjuvant may result in severe phytotoxicity. Specific Use Restrictions: Amistar should not be applied until 21 days after transplanting or 35 days after seeding. Do not apply more than 0.60 lb. a.i.lA per season of azoxystrobin-containing products. Mav be applied the day of harvest (0 day PHI). '\ \AI ~ <s--­.Y

Crop Target Diseases Tree Nuts Alternaria leaf and fruit spot (Alternaria alternata) Beechnut Anthracnose Brazil nut (Cofletotrichum acutatum, Butternut Glomerefla cingulata) Cashew Late blight Chestnut (Alternaria alternata) Chinquapin Scab Filbert (Cladosporium carpophilum) Hickory Septoria leaf spot Macadamia (Septoria pistaciarum) Pecan Shothole Walnut (Wilsonomyces carpophilus) Eastern filbert blight Almonds, Pistachios (see specific use (Anisogramma anomale) instructions) Blossom blight (Monilinia laxa, M. fructicola) Use Rate oz. productlA (lb. a.i.lA) 2-4 (0.10-0.20) 4 (0.20) Remarks Page 50 of 59 Amistar Integrated Pest {Disease} Managernent: Amistar should be integrated into an overall disease management strategy that includes selection of varieties with disease tolerance, removal of plant debris in which inoculum overwinters and proper timing and placement of irrigation. Resistance Management: Follow the resistance management guidelines in the Resistance Management Section. Do not apply more than two sequential applications of Amistar or other Group 11 fungicides before alternation with a fungicide that is not in Group 11. Application Directions: Amistar applications should begin prior to disease development and continue throughout the season following the resistance management guidelines. Applications may be made by ground, air or chemigation. An adjuvant may be added at recommended rates. For all other diseases begin applications prior to disease development and continue at 7-21 day intervals throughout the season. For blossom blight, begin applications at early bloom and continue through petal fall. Specific Use Restrictions: Do not apply more than 1.2 Ibs. a.i.lA per season of azoxystrobin-containing products. Do not apply within 45 days of harvest. .~ V\ ~ ~

Cro~

Tropical Fruit

Acerola

Atemoya

Avocado

Biriba

Canistel

Cherimoya

Custard apple

Feijoa

Guava

llama

Jaboticaba

Jackfruit

Longan

Loquat

Lychee

Mango

Papaya

Passionfruit

Pawpaw

Persimmon

Pulasan

Pummello

Rambutan

Sapodilla

Sapote, black

Sapote, mamey

Sapote, white

Soursop

Star apple

Starfruit

Sugar apple

Spanish lime

Tamarind

Uniq fruit

Use Rate

oz. productlA

Target Diseases (lb. a.i.lA)

Anthracnose 2-5

(Col/etotrichum spp.) (0.10-0.25)

Rust

(Puccinia spp.)

Cercospora leaf spot

(Cercospora spp.)

Powdery mildew

(Erysiphe spp.)

Soilborne Diseases 0.125-0.25 oz.

Seedling root rot, basal stem rot /1000 row feet

(Rhizoctonia salam)

Page 51 of 59

Amistar

Remarks

Integrated Pest {Disease} Management: Amistar should be integrated

into an overall disease management strategy that includes varieties with

disease tolerance, proper timing of irrigation and removal of plant debris

in which inoculum overwinters.

Resistance Management: Follow the resistance management

guidelines in the Resistance Management Section. Do not apply more

than two sequential applications of Amistar or other Group 11 fungicides

before alternation with a fungicide that is not in Group 11.

Application Directions: Amistar applications should begin prior to :

disease development and continue throughout the season on a 10-14 day

schedule, following the resistance management guidelines. Applications

may be made by ground, air or chemigation. An adjuvant may be added

at recommended rates.

For soilborne/seedling disease control, see directions and rates under

GENERAL INFORMATION section.

Specific Use Restrictions: Do not apply more than 1.5 Ibs. a.i.IA per season of azoxystrobin-containing products. May be applied the day of harvest (0 day PHI). <n __ V\ <S"" eN

Crop Target Diseases Vegetable, leaves of root and tuber, Foliar Diseases group Alternaria leaf spot Beet, garden and sugar (Alternaria spp., A. alternata) Burdock Ascochyta leaf spot Carrot (Ascochyta cynara e) Cassava, bitter and sweet Rust Celeriac (celery root) (Uromyces betae, Puccinia Chervil, turnip-rooted helianthi) Chicory White rust Dasheen (taro) (Albuqo tragopogonis) Parsnip Cercospora leaf spot Radish (Cercospora betae, C. Radish, oriental (daikon) pastinaceae) Rutabaga Powdery mildew Salsify, black (Erysiphe polygoni, Leveillula Sweet potato taurica) Tanier Soilborne Diseases Turnip Circular spot, Southern blight Yam, true (Sclerotium rolfsii) Rhizoctonia stem canker, Crown rot (Rhizoctonia so/ani) pythium root rot (pythium aphanidermatum) Use Rate oz. productlA (lb. a.i.lA) 2-6.5 (0.10-0.33) 3-5 (0.15-0.25) 0.125-0.25 oz. /1000 row feet Page 52 of 59 Amistar Remarks Integrated Pest {Disease} Management: Amistar should be integrated into an overall disease management strategy that includes selection of varieties with disease tolerance, optimum plant populations, proper fertilization, plant residue management, crop rotation and proper timing and placement of irrigation. Resistance Management: Follow the resistance management guidelines in the Resistance Management Section. Do not apply more than one application of Amistar or other Group 11 fungicides before alternation with a fungicide that is not in Group 11. .- Application Directions: For powdery mildew make preventative applications on a 5-7 day schedule. For all other diseases, Amistar applications should begin prior to disease development and continue throughout the season every 7-14 days following the resistance management guidelines. Applications may be made by ground, air or chemigation. An adjuvant may be added at recommended rates. For soilborne/seedling disease control, see directions and rates under GENERAL INFORMATION section. Specific Use Restrictions: Do not apply more than 2.0 Ibs. a.i.lA per season of azoxystrobin-containing products. May be applied the day of harvest (0 day PHI). ,~ , CA ~ ~ )l

Crop Target Diseases Vegetables, root, subgroup Foliar Diseases Alternaria leaf spot Beet, garden and sugar (Alternaria spp., A. alternata) Burdock Ascochyta leaf spot Carrot (Ascochyta cynarae) Celeriac Rust Chervil, turnip-rooted (Uromyces betae, Puccinia Chicory helianthi) Ginseng White rust Horseradish (Albugo tragQPQ9onis) Parsley, turnip-rooted Cercospora leaf spot Parsnip (Cercospora betae, C. Radish pastinaceae) Radish, oriental Powdery mildew Rutabaga (Erysiphe polygoni, Leveillula Salsify taurica) Salsify, black Salsify, Spanish Soilborne Diseases Skirret Circular spot, Southern blight Turnip (Sc/erotium ro/fsii) Rhizoctonia stem canker, Crown rot (Rhizoctonia so/ani) pythium root rot '(pythium aphanidermatum) Use Rate oz. productlA (lb. a.i.lA) 2-6.5 (0.10-0.33) 3-5 (0.15-0.25) 0.125-0.25 oz. /1000 row feet Remarks Page 53 of 59 Amistar Integrated Pest (Disease} Management: Amistar should be integrated into an overall disease management strategy that includes selection of varieties with disease tolerance, optimum plant populations, proper fertilization, plant residue management, crop rotation and proper timing and placement of irrigation. Resistance Management: Follow the resistance management guidelines in the Resistance Management Section. Do not apply more than one application of Amistar or other Group 11 fungicides before alternation with a fungicide that is not in Group 11. Application Directions: For powdery mildew, make preventative applications on a 5-7 day schedule. For all other diseases, Amistar applications should begin prior to disease development and continue throughout the season every 7-14 days following the resistance management guidelines. Applications may be made by ground, air or chemigation. An adjuvant may be added at recommended rates. For soilborne/seedling disease control, see directions and rates under GENERAL INFORMATION section. Specific Use Restrictions: Do not apply more than 2.0 Ibs. a.i.lA per season of azoxystrobin-containing products. May be applied the day of harvest (0 day PHI). /\ Vt ~ ~

Crop Target Diseases Vegetables, tuberous and corm, Foliar Diseases subgroup Alternaria leaf spot (Alternaria spp., A. Altemata) Arracacha Ascochyta leaf spot Arrowroot (Ascochyta cynara e) Artichoke, Chinese and Jerusalem Rust Canna (Uromyces betae, Puccinia Cassava, edible, bitter and sweet helianthi) Chayote (root) White rust Chufa (Albugo tragopogonis) Dasheen (Taro) Cercospora leaf spot Ginger (Cercospora betae, C. Leren pastinaceae) Potato Powdery mildew Sweet Potato (£rysiphe polygoni, Leveil/ula Tanier taurica) Turmeric Yam, bean Soilborne Diseases Yam, true Circular spot, Southern blight (Sclerotium ro/fsii) Rhizoctonia stem canker, Crown rot (Rhizoctonia so/ani) Pythium root rot (pythium aphanidermatum) Use Rate oz. productlA (lb. a.i.lA) 2-6.5 (0.10-0.33) 3-5 (0.15-0.25) 0.125-0.25 oz. /1000 row feet Page 54 of 59 Amistar Remarks Integrated Pest {Disease} Management: Amistar should be integrated into an overall disease management strategy that includes selection of varieties with disease tolerance, optimum plant populations, proper fertilization, plant residue management, crop rotation and proper timing and placement of irrigation. Resistance Management: Follow the resistance management guidelines in the Resistance Management Section. Do not apply more than one application of Amistar or other Group 11 fungicides before alternation with a fungicide that is not in Group 11. r Application Directions: For powdery mildew,make preventative applications on a 5-7 day schedule. For all other diseases, Amistar applications should begin prior to disease development and continue throughout the season every 7-14 days following the resistance management guidelines. Applications may be made by ground, air or chemiQation. An adjuvant may be added at recommended rates. For soilborne/seedling disease control, see directions and rates under GENERAL INFORMATION section. Specific Use Restrictions: Do not apply more than 2.0 Ibs. a.i.lA per season of azoxystrobin-containing products. Do not apply within 14 days of harvest. /~ , '" ~ ~

Use Rate oz. productlA Crop Target Diseases (lb. a.i.lA) Watercress Cercospora leaf spot 2-5 (Cercospora spp.) (0.10-0.25) Specific Use Restrictions: Do not apply more than 0.93 pound per cutting. Do not apply more than 1.5 Ibs. a.i.lA per season of azoxystrobin-containing products. May be applied up to 7 days prior to harvest. Remarks Page 55 of 59 Amistar Integrated Pest (Disease} Management: Amistar should be integrated into an overall disease management strategy that includes varieties with disease tolerance, insect control and proper fertilization. Resistance Management: Follow the resistance management guidelines in the Resistance Management Section. Do not apply more than two sequential applications of Amistar or other Group 11 fungicides before alternation with a fungicide that is not in Group 11. Application Directions: Amistar applications should begin prior to disease development and continue throughout the season on a 7-10 day / schedule, following the resistance management guidelines. Applications may be made by ground, air or chemigation. An adjuvant may be added at recommended rates. ~ , ~ ~ I,J.l

Use Rate oz. productJA Crop Target Diseases (lb. a.i.lA) Wheat Leaf rust 1.4-4.0 Triticale (Puccinia recondita f.sp. tritici) (0.07-0.20) Stripe rust (Puccinia striiformis) Stem rust (Puccinia graminis) Septoria leaf and Glume blotch (Septoria tritici, Septoria nodorum) Tan spot (Pyrenophora tritici-repentis) Powdery mildew 2.5-3.5 (Erysiphe graminis) (0.125-0.175) Specific Use Restrictions: Do not apply until after forage stage (Feekes 6 or Zadok's 31). Do not apply later than Feekes growth stage 10.5 (Zadok's growth stage 59). Do not harvest treated wheat for forage. Do not apply more than 0.40 lb. a.i.lA per season of azoxystrobin-containing products. Do not apply within 14 days of harvest for hay. Do not apply within 45 days of harvest for grain and straw. Page 56 of 59 Amistar Remarks Integrated Pest {Disease) Management: Amistar should be integrated into an overall disease management strategy that includes proper selection of varieties with disease tolerance, proper timing and placement of irrigation, removal of plant debris in which inoculum overwinters, plant residue management, and crop rotation. Resistance Management: Follow the resistance management guidelines in the Resistance Management Section. Do not apply more than two sequential applications of Amistar or other Group 11 fungicides before alternation with a fungicide that is not in Group 11. Do not make more than 2 applications of Amistar or other Group 11 fungicide per " season. ADDlication Directions: Amistar should be applied prior to disease development from jointing (Feekes 6 or Zadok's 31) up to late head emergence (Feekes 10.5 or Zadok's 59). Applications may be made by ground, air or chemigation. A crop oil concentrate adjuvant may be added at 1.0% v/v to optimize efficacy. /~ \ ~ ~ ~ (JJ

Amistar Rate Conversion Chart Ounces ProductlA Lb. a.i./A 1.0 0.05 1.5 0.08 2.0 0.10 2.5 0.13 3.0 0.15 3.5 0.18 4.0 0.20 4.5 0.23 5.0 0.25 5.5 0.28 6.0 0.30 6.5 0.33 7.0 0.35 7.5 0.38 8.0 , 0.40 ( Page 57 of 59 Amistar Treated Acres/Lb. Product 16.0 10.7 8.0 6.4 5.3 4.6 4.0 3.7 3.2 2.9 2.7 2.5 2.3 2.1 2.0 Amount of Amistar to Mix 100 Gallons for Post-Harvest Applications 100.0 gals. Amistar Spray Use Rate Solution 200 ppm 3.3 oz. 300 ppm 5.0 oz. 400 ppm 6.6 oz.

STORAGE AND DISPOSAL Page 58 of 59 Amistar Do not contaminate water, food or feed by storage or disposal. Open dumping is prohibited. Pesticide Storage Store in original containers only. Keep container closed when not in use. Do not store near food or feed. In case of spill on floor or paved surfaces, sweep and remove to chemical waste storage area until proper disposal can be made if product cannot be used according to the label. Pesticide Disposal Pesticide wastes are acutely hazardous. Improper disposal of excess pesticide, spray mixture, or rinsate is a violation of Federal law. If these wastes cannot be disposed of by use according to label instructions, contact your State Pesticide or Environmental Control Agency, or the Hazardous Waste representative of the nearest EPA Regional Office for guidance. Container DisposalHandling Plastic Containers: Non-refillable container. Do not reuse or refill this container. Offer for recycling if available. Triple rinse container (or equivalent) promptly after emptying . .;. Triple rinse as follows:. Empty the remaining contents into application equipment or a mix tank. Fill the container ~ full with water and recap. Shake for 10 seconds. Pour rinsate into application equipment or a mix tank or store ririsate for later use 'or disposal. Drain for 10 seconds after the flow begins to drip. Repeat this procedure two more times. Then offer for recycling !f availableor reconditioning, or puncture and dispose of in a sanitary landfill. by· incineration. or.Jf alternatives allowed by State and local authorities. by burning. If burned. stay out of smoke. Paper/Box Container: Non-refillable container. Do not reuse or refill this container. Completely empty container into application equipment. Then offer for recycling if available or dispose of dispose of empty container in sanitary landfill, by incineration. or.Jf alternatives allowed by State and local authorities. by burning. If burned. stay out of smoke. FOR BULK AND MINI BULK CONTAlNI5RS CONTAlNI5R DISPOSAL: Reseal container and offer for reconditioning, or triple rinse (or equi'Jalent) and offer for recycling or. reconditioning, or clean in accordance with manufacturer's instructions. CONTAlNI5R PRI5CAUTIONS: Before refiliing, inspect thoroughly for damage, such as cracks, punctures, bulges, dents, abrasions, and damaged or worn .threads on closure devices. RI5Flll ONLY 'J'lITH AMISTAR: The contents of this container cannot be completely removed by cleaning. Refilling with materials other than Amistar 'Jill result in contamination and may weaken container. /\fter filling and before transporting, check for leaks. Do not refill or transport damaged or leaking container. CONTAINER IS NOT SAFE FOR FOOD, FEED OR DRINKING WATER.

r \ Page 59 of 59 Amistar Amistar®, Ambush®, Warrior® with Zeon™ Technology, and the Syngenta logo are trademarks of a Syngenta Group Company. Acrobat® is a trademark of BASF Corporation. Aliette®, and Phaser®are trademarks of Bayer CropScience. Botran® is a trademark of Gowan. Kelthane® and Lorsban® are trademarks of Dow AgroSciences. Lannate® is a trademark of DuPont Crop Protection. M-Pede® is a trademark of Mycogen Corporation. Pounce® is a trademark of FMC Corporation and Agriliance, LLC. Thiodan® is a trademark of Universal Crop Protection Alliance, LLC. ©200X Syngenta Manufactured for: For non-emergency (e.g., current product information), call Syngenta Crop Protection at 1-800-334-9481. Syngenta Crop Protection, Inc. Greensboro, North Carolina 27409 www.syngenta-us.com SCP 1164A- AMI 1164 MAS 0606 - bb - 9-21-09 AMI 1164 MAS 0606 PRN2007-4 NOTIF-SEP2009 - pl- 9/24/09