crop-chem-docs/corpus/epa_ppls/19713-252.md

SIMAZINE 90DF

• EPA Reg No: 19713-252
• Registrant: DREXEL CHEMICAL COMPANY
• Signal word: Caution
• Active ingredients: Simazine (90%)
• Label accepted: 2021-11-10
• Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/019713-00252-20211110.pdf

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UNITED STATES ENVIRONMENTAL PROTECTION AGENCY WASHINGTON, DC 20460

OFFICE OF CHEMICAL SAFETY AND POLLUTION PREVENTION

November 10, 2021

Luz G. Chan Registration Manager Drexel Chemical Company P.O. Box 13327 Memphis, TN 38113-0327

Subject: Registration Review Label Amendments for Simazine Incorporating Mitigation Measures from the Interim Decision and the Technical Registrants’ Commitments for the Endangered Species Act (ESA) Biological Evaluation Product Name: SIMAZINE 90DF EPA Registration Number: 19713-252 Application Date: 10/09/2020 Decision Number: 566844

Dear Ms. Chan:

The Agency, in accordance with the Federal Insecticide, Fungicide and Rodenticide Act (FIFRA), as amended, has completed reviewing all the information submitted with your application to support the Registration Review of the above referenced product in connection with the Simazine Interim Decision and with the technical registrants’ commitments for the ESA Biological Evaluation. The Agency has concluded that your submission is acceptable. The label referred to above, submitted in connection with registration under FIFRA, as amended, is acceptable.

Should you wish to add/retain a reference to the company’s website on your label, then please be aware that the website becomes labeling under the Federal Insecticide Fungicide and Rodenticide Act and is subject to review by the Agency. If the website is false or misleading, the product would be misbranded and unlawful to sell or distribute under FIFRA section 12(a)(1)(E). 40 CFR 156.10(a)(5) list examples of statements EPA may consider false or misleading. In addition, regardless of whether a website is referenced on your product’s label, claims made on the website may not substantially differ from those claims approved through the registration process. Therefore, should the Agency find or if it is brought to our attention that a website contains false or misleading statements or claims substantially differing from the EPA approved registration, the website will be referred to the EPA’s Office of Enforcement and Compliance.

A stamped copy of your labeling is enclosed for your records. This labeling supersedes all previously accepted labeling. You must submit one copy of the final printed labeling before you release the product for shipment with the new labeling. In accordance with 40

Page 2 of 2 EPA Reg. No. 19713-252 Decision No. 566844

CFR 152.130(c), you may distribute or sell this product under the previously approved labeling for 18 months from the date of this letter. After 18 months, you may only distribute or sell this product if it bears this new revised labeling or subsequently approved labeling. “To distribute or sell” is defined under FIFRA section 2(gg) and its implementing regulation at 40 CFR 152.3.

If you have any questions about this letter, please contact Anna Senninger at Senninger.Anna@epa.gov .

Sincerely,

Kelly Sherman Chief, Risk Management and Implementation Branch III (RMIB III)

Pesticide Re-Evaluation Division Office of Pesticide Programs U.S. Environmental Protection Agency

Enclosure

Page 1 of 19 For weed control in certain crops and ornamental plantings. ACTIVE INGREDIENT: Simazine ............................................................................................................................. 90.0% OTHER INGREDIENTS: ................................................................................................... 10.0% TOTAL: .............................................................................................................................. 100.0% This product is a water-dispersible granule. KEEP OUT OF REACH OF CHILDREN CAUTION [See FIRST AID Below] [See FIRST AID Below] [See Side (Back) Panel for FIRST AID]; [See Page ___ for FIRST AID] [See Container Labeling for (FIRST AID and) Complete Directions for Use] [See (Attached) Booklet (Container Labeling) for Complete Directions for Use] EPA Reg. No. 19713-252 EPA Est. No. XXXXX-XX[X]-X Net Content: ______Lb. (_____Kg) FIRST AID IF ON SKIN OR CLOTHING: • Take off contaminated clothing. • Rinse skin immediately with plenty of water for 15 to 20 minutes. • Call a poison control center or doctor for treatment advice. IF INHALED: • Move person to fresh air. • If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth, if possible. • Call a poison control center or doctor for further treatment advice. IF SWALLOWED: • Call a poison control center or doctor immediately for treatment advice. • Have person sip a glass of water if able to swallow. • Do not induce vomiting unless told to do so by a poison control center or doctor. • Do not give anything by mouth to an unconscious or convulsing person. IF IN EYES: • Hold eye open and rinse slowly and gently with water for 15 to 20 minutes. • Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. • Call a poison control center or doctor for treatment advice. Have the product container or label with you when calling a poison control center or doctor, or going for treatment. You may also call CHEMTREC at 800-424-9300 for emergency medical treatment information. 252SP-0421*P SIMAZINE GROUP 5 HERBICIDE Simazine 90DF Herbicide 11/10/2021 19713-252

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PRECAUTIONARY STATEMENTS Hazards to Humans and Domestic Animals CAUTION: Harmful if absorbed through skin or inhaled. Avoid contact with skin, clothing, or eyes. Avoid breathing dust. Harmful if swallowed. Causes moderate eye irritation. PERSONAL PROTECTIVE EQUIPMENT (PPE) Mixers and loaders supporting groundboom applications must wear: Coveralls over long-sleeved shirt and long pants; chemical-resistant footwear plus socks; waterproof gloves ; chemical-resistant apron; and wear a minimum of a NIOSH-approved particulate filtering facepiece respirator with any N*, R or P filter OR a NIOSH-approved elastomeric particulate respirator with any N*, R or P filter OR a NIOSH-approved powered air purifying respirator with HE filter. Mixers/loaders/applicators for backpack application to Grapefruit and Oranges must wear: Shoes, Socks, Coveralls worn over long-sleeve shirts and long pants, and waterproof gloves. All other mixers, loaders, applicators, and handlers must wear: Long-sleeved shirt and long pants, shoes plus socks, and waterproof gloves. Follow manufacturer’s instructions for cleaning/maintaining PPE. If no such instructions for washables exist, use detergent and hot water. Keep and wash PPE separately from other laundry. Discard clothing and other absorbent materials that have been drenched or heavily contaminated with this product’s concentrate. Do not reuse them. Applications made by mechanically pressurized handguns to strawberries are restricted to either spot treatment only or mixer/loader/applicators are required to wear shoes, socks, coveralls worn over long sleeve shirt and long pants, and waterproof gloves. ENGINEERING CONTROLS When handlers use enclosed cabs in a manner that meets the requirements listed in the Worker Protection Standard (WPS) for agricultural pesticides [40 CFR 170.240(d)(4-5)], the handler PPE requirements may be reduced or modified as specified in the WPS. USER SAFETY RECOMMENDATIONS Users should: 1) Wash hands before eating, drinking, chewing gum, using tobacco or using the toilet. 2) Remove clothing/PPE immediately if pesticide gets inside. Then wash thoroughly and put on clean clothing. 3) Remove PPE immediately after handling this product. Wash the outside of gloves before removing. As soon as possible, wash thoroughly and change into clean clothing. ENVIRONMENTAL HAZARDS Simazine can travel (seep or leach) through soil and can enter ground water which may be used as drinking water. Simazine has been found in ground water. Users are advised not to apply Simazine to sand and loamy sand soils where the water table (ground water) is close to the surface and where these soils are very permeable; i.e., well-drained. Your local agricultural agencies can provide further information on the type of soil in your area and the location of ground water. This pesticide is toxic to aquatic invertebrates. Do not apply directly to water, to areas where surface water is present, or to intertidal areas below the mean high water mark. Runoff and drift from treated areas may be hazardous to aquatic organisms in neighboring areas, Do not contaminate water when disposing of equipment washwater. Product must not be mixed or loaded within 50 feet or intermittent streams and rivers, natural or impounded lakes and reservoirs. Product must not be applied within 66 feet of points where field surface water runoff enters perennial or intermittent streams and rivers or within 200 feet of natural or impounded lakes and reservoirs. If this product is applied to highly erodible land, the 66-foot buffer or setback from runoff entry points must be planted to crop, or seeded with grass of other suitable crops. Product must not be mixed or loaded, or used within 50 feet of all wells, including abandoned wells, drainage wells, and sinkholes. Operations that involve mixing, loading, rinsing, or washing of this product into or from pesticide handling or application equipment or containers within 50 feet of any well are prohibited, unless conducted on an impervious pad constructed to withstand the weight of the heaviest load that may be positioned on or moved across the pad. Such a pad shall be designed and maintained to contain any product spills or equipment leaks, container or equipment rinse or washwater, and rain water that may fall on the pad. Surface water

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shall not be allowed to either flow over or from the pad which means the pad must be self-contained. The pad shall be sloped to facilitate material removal. An unroofed pad shall be of sufficient capacity to contain at a minimum 110% of the capacity of the largest pesticide container or application equipment on the pad. A pad that is covered by a roof of sufficient size to completely exclude precipitation from contact with the pad shall have a minimum containment of 100% of the capacity of the largest pesticide container or application equipment on the pad. Containment capacities as described above shall be maintained at all times. The above-specified minimum containment capacities do not apply to vehicles when delivering pesticide to the mixing/loading sites. Additional State imposed requirements regarding well-head setbacks and operation containment must be observed. One of the following restrictions must be used in applying Simazine to tile-outletted terraced fields containing standpipes: • Do not apply within 66 feet of standpipes in tile-outletted terraced fields. • Apply this product to the entire tile-outletted terraced field and immediately incorporate it to a depth of 2 to 3 inches in the entire field. • Apply this product to the entire tile-outletted terraced field under a no-till practice only when a high crop residue management practice is practiced. High crop residue management is described as a crop management practice where little or no crop residue is removed from the field during and after crop harvest. NON-TARGET ORGANISMS ADVISORY STATEMENT This product is toxic to plants and may adversely impact the forage and habitat of non-target organisms, including pollinators in areas adjacent to the treated site. Protect the forage and habitat of non-target organisms by following label directions intended to minimize spray drift. DIRECTIONS FOR USE It is a violation of Federal law to use this product in a manner inconsistent with its labeling. ANY USE OF THIS PRODUCT IN AN AREA WHER E USE IS PROHIBITED IS A VIOLATION OF FEDERAL LAW. ENDANGERED SPECIES It is a Federal offense to use any pesticide in a manner that results in an unauthorized “take” (e.g., kill or otherwise harm) of an endangered species under the Endangered Species Act section 9. When using this product, you must follow the measures contained in the Endangered Species Protection Bulletin for the area in which you are applying the product. You must obtain a Bulletin no earlier than six months before using this product. To obtain Bulletins, consult http://www.epa.gov.espp/, call 1-844-447-3813, or email ESPP@epa.gov. You must use the Bulletin valid for the month in which you will apply the product. Before using this product, you must consult the Simazine Watershed Information Center (SWIC) to determine whether the use of this product is prohibited in your watershed. SWIC can be accessed through www.Simazine-watershed.info or 1-888-365-2874. If the SWIC indicates that use of this product is prohibited in your watershed, you may return this product to your point of purchase or contact Drexel Chemical Company for a refund. Failure to follow the “DIRECTIONS FOR USE” and “USE PRECAUTIONS AND RESTRICTIONS” on this label may result in crop injury, poor weed control and/or illegal residues. Do not apply this product through any type of irrigation system. Do not apply this product in a way that will contact workers or other persons, either directly or through drift. Only protected handlers may be in the area during application. For any requirements specific to your State or Tribe, consult the agency responsible for pesticide regulation. AGRICULTURAL USE REQUIREMENTS Use this product only in accordance with its labeling and with the Worker Protection Standard (WPS), 40 CFR Part 170. This standard contains requirements for the protection of agricultural workers on farms,

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forests, nurseries, greenhouses and handlers of agricultural pesticides. It contains requirements for training, decontamination, notification and emergency assistance. It also contains specific instructions and exceptions pertaining to the statements on this label about Personal Protective Equipment (PPE) and restricted entry interval (REI). The requirements in this box only apply to uses of this product that are covered by the WPS. For Christmas trees, do not enter or allow worker entry into treated areas during the REI of 48 hours. For all other crops and use patterns, do not enter or allow worker entry into treated areas during the REI of 12 hours. Exception: If the product is soil-injected or soil-incorporated, the WPS, under certain circumstances, allows workers to enter the treated area if there will be no contact with anything that has been treated. PPE required for early entry to treated areas that is permitted under the WPS and that involves contact with anything that has been treated, such as plants, soil or water is: Coveralls, shoes plus socks and waterproof gloves. NON-AGRICULTURAL USE REQUIREMENTS The requirements in this box apply to uses of this product that are NOT within the scope of the WPS for agricultural pesticides (40 CFR Part 170). The WPS applies when this product is used to produce agricultural plants on farms, forests, nurseries or greenhouses. Do not enter or allow others (including children or pets) to enter treated areas until sprays have dried. USE INFORMATION IMPORTANT: Read the entire “DIRECTIONS FOR USE” and the “WARRANTY—CONDITIONS OF SALE” before using this product. Apply this herbicide before weeds emerge or after removal of weed growth. This product controls a wide variety of annual Broadleaf and Grass weeds when used at selective rates in agricultural crops and ornamental plantings. Where a range of application rates is given, use the low rate on coarser textured soil and soil lower in organic matter; use the high rate on finer textured soil and soil higher in organic matter. To avoid spray drift, do not apply under windy conditions. Avoid spray overlap, as crop injury may result. Since this product enters weeds mainly through their roots, moisture is needed to move it into the root zone. Very dry soil conditions and lack of rainfall following application may necessitate shallow cultivation. This product is noncorrosive to equipment, non-flammable and has low electrical conductivity. USE SITE RESTRICTION Not for use in the States of Alaska, Hawaii or in the U.S. territories (American Samoa, Guam North Mariana Islands, Puerto Rico and the U.S Virgin Islands). WEED RESISTANCE MANAGEMENT For resistance management, this product is a Group 5 mode of action herbicide. Any weed population may contain or develop plants naturally resistant to this product and other Group 5 mode of action herbicides. The resistant biotypes may dominate the weed population if these herbicides are used repeatedly in the same field. Appropriate resistance management strategies should be followed. To delay herbicide resistance, take one or more of the following steps: xRotate the use of this product or other Group 5 herbicides within a growing season sequence or among growing seasons with different herbicide groups that control the same weeds in a field. xUse tank mixtures with herbicides from a different group if such use is permitted; where information on resistance in target weed species is available, use the less resistance-prone partner at a rate that will control the target weed(s) equally as well as the more resistance-prone partner. Consult your local extension service or certified crop advisor if you are unsure as to which active ingredient is currently less prone to resistance. xAdopt an integrated weed-management program for herbicide use that includes scouting and uses historical information related to herbicide use and crop rotation, and that considers tillage (or other mechanical control methods), cultural ( e.g., higher crop seeding rates; precision fertilizer application method and timing to favor the crop and not the weeds), biological (weed-competitive crops or varieties) and other management practices. xScout after herbicide application to monitor weed populations for early signs of resistance development. Indicators of possible herbicide resistance include: (1) failure to control a weed species normally controlled by the herbicide at SIMAZINE GROUP 5 HERBICIDE

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the dose applied, especially if control is achieved on adjacent weeds; (2) a spreading patch of non-controlled plants of a particular weed species; (3) surviving plants mixed with controlled individuals of the same species. If resistance is suspected, prevent weed seed production in the affected area by an alternative herbicide from a different group or by a mechanical method such as hoeing or tillage. Prevent movement of resistant weed seeds to other fields by cleaning harvesting and tillage equipment when moving between fields and planting clean seed. xIf a weed pest population continues to progress after treatment with this product, discontinue use of this product, and switch to another management strategy or herbicide with a different mode of action, if available. xContact your local extension specialist or certified crop advisors for additional pesticide resistance-management and/or integrated weed-management recommendations for specific crops and weed biotypes. xFor further information or to report suspected resistance, contact Drexel Chemical Company representatives at (901) 774-4370. ANNUAL WEEDS CONTROLLED Alyssum Annual bluegrass Annual morningglory Annual ryegrass Barnyardgrass (Watergrass) Burclover Carelessweed Carpetweed Common chickweed Crabgrass (Digitaria spp.) Downy brome (Cheatgrass) Fall panicum Fiddleneck Filaree Fireweed Fivehook bassia Flora’s paintbrush Florida pusley Foxtails Goosegrass Groundsel Henbit Junglerice Knawel (German moss) Common lambsquarters Nightshade Pepperweed Pigweed Pineappleweed Prickly lettuce Common purslane Ragweed Rattail fescue Redmaids Russian thistle Shepherdspurse Signalgrass (Brachiaria spp.) Silver hairgrass Smartweed Spanishneedles Speedwell Tansymustard Wild mustard Wild oats Witchgrass Yellowflower pepperweed APPLICATION PROCEDURES Ground Application: Use conventional ground sprayers equipped with nozzles that provide accurate and uniform application. Be certain that nozzles are uniformly spaced and the same size. Calibrate sprayer before use and recalibrate at the start of each season and when changing carriers. Unless otherwise specified, use a minimum of 20 gallons of spray mixture per acre. Use a pump with capacity to 1) maintain 15 to 45 psi at nozzles, 2) provide sufficient agitation in tank to keep mixture in suspension, and 3) to provide a minimum of 20% bypass at all times. Use centrifugal pumps which provide propeller shear action for dispersing and mixing this product. The pump should provide a minimum of 10 gallons per minute per 100 gallon tank size circulated through a correctly positioned sparger tube or jets. Use screens to protect the pump and to prevent nozzles from clogging. Screens placed on suction side of pump should be 16-mesh or coarser. Do not place a screen in the recirculation line. Use 50-mesh or coarser screens between the pump and boom, and where required, at the nozzles. Check nozzle manufacturer’s recommendations. For band applications, calculate amount to be applied per acre as follows: band width in inches X broadcast rate = amount needed row width in inches per acre per acre USE RESTRICTIONS x Applications made by mechanically pressurized handguns are restricted to spot treatment only for the following uses: Berry and Small fruits (Blackberries, Blueberries, Cranberries, Grapes, Loganberries, Lowbush blueberries, Raspberries); Citrus (Grapefruit, Lemons, Oranges); Nursery Ornamentals; Pome fruits (Apples, Pears); Stone fruits (Cherries [sweet, tart], Nectarines, Peaches, Plums); Tree Nuts

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(Almonds, Filberts, Macadamia nuts, Pecans, Walnuts); Tropical and Subtropical fruits (Avocados, Olives); Sweet corn. x Applications made by mechanically pressurized handguns to Strawberries are restricted to either spot treatment only OR mixers/loaders/applicators ar e required to wear shoes, socks, coveralls worn over long sleeve shirts and long pants, and waterproof gloves. x Aerial Application - Application by air is prohibited. MANDATORY SPRAY DRIFT MANAGEMENT SPRAY DRIFT GROUND BOOM APPLICATIONS: x User must only apply with the release height recommended by the manufacturer, but no more than 4 feet above the ground or crop canopy. x Applicators are required to use a coarse or coarser droplet size (ASABE S572). x Do not apply when wind speeds exceed 10 mph at the application site. x Do not apply during temperature inversions. x User must maintain a 15 foot (4.6 m) in-field downwind buffer (in the direction in which the wind is blowing) from the edge of streams and rivers as well as the high-tide line for all estuarine/marine environments. SPRAY DRIFT ADVISORIES THE APPLICATOR IS RESPONSIBLE FOR AVOIDING OFF-SITE SPRAY DRIFT. BE AWARE OF NEARBY NON-TARGET SITES AND ENVIRONMENTAL CONDITIONS. IMPORTANCE OF DROPLET SIZE An effective way to reduce spray drift is to apply large droplets. Use the largest droplets that provide target pest control. While applying larger droplets will reduce spray drift, the po tential for drift will be greater if applications are made improperly or under unfavorable environmental conditions. Controlling Droplet Size - Ground Boom • Volume- Increasing the spray volume so that larger droplets are produced will reduce spray drift. Use the highest practical spray volume for the application. If a greater spray volume is needed, consider using a nozzle with a higher flow rate. • Pressure- Use the lowest spray pressure recommended for the nozzle to produce the target spray volume and droplet size. • Spray Nozzle- Use a spray nozzle that is designed for the intended application. Consider using nozzles designed to reduce drift. BOOM HEIGHT – GROUND BOOM For ground equipment, the boom should remain level with the crop and have minimal bounce. SHIELDED SPRAYERS Shielding the boom or individual nozzles can reduce spray drift. Consider using shielded sprayers. Verify that the shields are not interfering with the uniform deposition of the spray on the target area. TEMPERATURE AND HUMIDITY When making applications in hot and dry conditions, use larger droplets to reduce effects of evaporation. TEMPERATURE INVERSIONS Drift potential is high during a temperature inversion. Temperature inversions are characterized by increasing temperature with altitude and are common on nights with limited cloud cover and light to no wind. The presence of an inversion can be indicated by ground fog or by the movement of smoke from a ground source or an aircraft smoke generator. Smoke that layers and moves laterally in a concentrated cloud (under low wind conditions) indicates an inversion, while smoke that moves upward and rapidly dissipates indicates good vertical air mixing. WIND Drift potential generally increases with wind speed. AVOID APPLICATIONS DURING GUSTY WIND CONDITIONS. Applicators need to be familiar with local wind patterns and terrain that could affect spray drift.

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HANDHELD TECHNOLOGY APPLICATIONS Take precautions to minimize spray drift. MIXING PROCEDURES: All Uses: 1) Be sure sprayer is clean and not contaminated with any other materials or crop injury or sprayer clogging may result. 2) Fill tank one-fourth full with clean water, nitrogen solution or complete fluid fertilizer. 3) Start agitation. 4) Be certain that the agitation system is working properly and creates a rippling or rolling action on the liquid surface. 5) Pour product directly from bag into tank. 6) Continue filling tank until 90% full. Increase agitation, if necessary, to maintain surface action. 7) Add tank mix herbicide(s) after this product is thoroughly suspended. 8) Finish filling tank. Maintain agitation to avoid separation of materials. 9) Empty tank as completely as possible before refilling to prevent buildup of emulsifiable concentrate residue from possible tank mix herbicides. 10) If an emulsifiable concentrate film starts to build up in tank, drain it and clean with strong detergent solution or solvent. 11) Clean sprayer thoroughly immediately after use by flushing system with water containing a detergent. COMPATIBILITY TEST: To determine the tank mix compatibility of this product with liquid fertilizer, crop oil, spreaders or recommended pesticides, use this test method. Nitrogen solutions or complete fluid fertilizers may replace all or part of the water in the spray in Corn. Since liquid fertilizers can vary, even within the same analysis, check compatibility each time before use. Be especially careful when using complete suspension or fluid fertilizers as serious compatibility problems are more apt to occur. Commercial application equipment may improve compatibility in some instances. Check compatibility using the following procedure:

1. Add 1 pint of fertilizer to each of 2 one-quart glass jars with tight lids.
2. To one of the jars, add one-fourth teaspoon of a compatibility agent approved for this use (one-fourth teaspoon is equivalent to 2 pt./100 gal. of spray). Cap and shake until mixed. Examples of compatibility agents include Compex ®, MIX™, and Unite®.
3. To both jars, add the appropriate amount of herbicide(s). If more than one herbicide is used, add them separately with dry herbicides first, flowables next and emulsifiable concentrates last. After each addition, cap and shake until thoroughly mixed. The appropriate amount of herbicides for this test follows (assuming a spray volume of 25 gal./A): Dry Herbicides: For each pound per acre, add 1.5 tsp. to each jar. Fluff up wettable powder products before measuring. Liquid Herbicides: For each pint per acre, add 0.5 tsp. to each jar. For a spray volume other than 25 gallons per acre, change the teaspoons added to each jar as follows: 25 gallons × number of teaspoons given above = teaspoons to desired gallons of spray volume per acre add to each jar
4. After adding all ingredients, put lids on and tighten. Shake jars vigorously for one minute. Let the mixtures stand for 15 minutes and then look for separation, large flakes, precipitates, grease, gels, medium to heavy oily film on the jar or other signs of incompatibility. Determine if the compatibility agent is needed in the spray mixture by comparing the two jars. If either mixture separates, but can be remixed readily, the mixture probably can be sprayed as long as good agitation is used. If the mixtures are incompatible, test the following methods of improving compatibility: (a) slurry the dry herbicide(s) in water before additions, or (b) add one-half of the compatibility agent to the fertilizer and the other half to the emulsifiable concentrate or flowable herbicide before addition to the mixture. If still incompatible, do not use the materials mixed in the same spray tank. PERENNIAL CROP REPLANTING To avoid crop injury, observe the following precautions:

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If replanting Perennial crops, do not apply this product in the year preceding planting of these crops. FRUIT AND NUT CROPS Apply the spray to the orchard or vineyard floor avoiding contact with fruit, foliage or stems. Specified rates are based on broadcast treatment. For band applications or spot applications around Fruit or Nut trees, reduce the broadcast rate of this product and water per acre in proportion to the area actually sprayed. Use Precautions and Restrictions (All Fruit and Nut Crops). (To avoid crop injury): 1) Apply only to orchards or groves where trees have been established 12 months or more unless specified differently. 2) Make only one application per year, except as noted otherwise. 3) Do not use on Gravelly, Sand or Loamy sand soil. 4) Immediately following application, limit overhead sprinkler irrigation to 0.5 inch. ALMONDS, NECTARINES, PEACHES (CA Only) 1.1 to 2.2 pounds of this product per treated acre must be applied in a 2 to 4 feet band on each side of the tree row before weeds emerge in late Fall or early Winter. Weeds controlled by 1.1 pounds of this product include Burclover, Common chickweed, Shepherdspurse and Wild mustard. Apply only once per year. Use Precautions and Restrictions: 1) Do not apply more than 2 pounds a.i. (2.2 lb. of this product) per acre per calendar year. 2) Do not apply more than once per calendar year. 3) Do not treat trees established in the grove less than 3 years. 4) Do not treat the Mission (Texas variety) variety of Almonds. 5) Do not apply to Almond trees propagated on Plum rootstocks. 6) Do not replant Almonds, Nectarines or Peaches in treated soil for 12 months after treatment. 7) Do not apply on soil with less than 1% organic matter. 8) Do not treat areas where water will accumulate. APPLES, PEARS, TART CHERRIES Apply 2.2 to 4.4 pounds of this product per acre. Use Precautions and Restrictions: 1) Do not apply more than 4 pounds a.i. (4.4 lb. of this product) per acre per calendar year. 2) Do not apply more than once per calendar year. 3) For Apples, the preharvest interval is 150 days. AVOCADOS (CA and FL Only) Apply 2.2 to 4.4 pounds of this product per acre after final preparation of grove. Use Precautions and Restrictions: 1) Do not apply more than 4 pounds a.i. (4.4 lb. of this product) per acre per calendar year. 2) Do not apply more than once per calendar year. 3) Do not apply on Gravelly sand or Loamy sand soil. BLUEBERRIES AND CANEBERRIES (Blackberries, Boysenberries, Loganberries, Raspberries) Apply 2.2 to 4.4 pounds of this product per acre in the Spring or as a split application of 2.2 pounds per acre in the Spring plus 2.2 pounds per acre in the Fall in a minimum of 40 gallons of water per acre. On plantings less than 6 months old, use half the above rate. To control Quackgrass, apply 4.4 pounds per acre in the Fall or split the application applying 2.2 pounds per acre in the Fall plus 2.2 pounds per acre in the Spring, when Quackgrass is actively growing. Use Precautions and Restrictions: 1) Do not apply more than 4 pounds a.i. (4.4 lb. of this product) per acre per calendar year. 2) Do not apply more than twice per calendar year. 3) To avoid illegal residues, do not apply when fruit is present. CRANBERRIES MA: Apply up to 4.4 pounds of this product per acre either before Spring growth begins or in the Fall after harvest. Other areas: Apply 2.2 pounds per acre before Spring growth begins.

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Use Precautions and Restrictions: 1) In MA, do not apply more than 4 pounds a.i. (4.4 lb. of this product) per acre per calendar year. In all other areas, do not apply more than 2 pounds a.i. (2.2. lb. of this product) per calendar year. 2) Do not apply more than once per calendar year. FILBERTS Apply 2.2 to 4.4 pounds of this product per acre in the Fall or apply a split application of 2.2 pounds per acre in the Fall plus 2.2 pounds per acre in the Spring. Use Precautions and Restrictions: 1) Do not apply more than 4 pounds a.i. (4.4 lb. of this product) per acre per calendar year. 2) Do not apply more than twice per calendar year. 3) If trees are planted on a hillside, excessive soil erosion may result from the elimination of weeds. 4) Do not apply when Nuts are on the ground during the harvest period or illegal residues may result. GRAPES Apply 2.2 to 4.4 pounds of this product per acre any time between harvest and early Spring. Use Precautions and Restrictions: 1) Do not apply more than 4 pounds a.i. (4.4 lb. of this product) per acre per calendar year. 2) Do not apply more than twice per calendar year. 3) Do not use in vineyards established less than three years or crop injury may occur. GRAPEFRUIT, LEMONS, ORANGES AZ (Lemons and Oranges only): Apply a split application of 1.75 pounds of this product per acre in the Spring plus 1.75 pounds in the Fall. Use Precautions and Restrictions: 1) Do not apply more than 1.6 pounds a.i. (1.75 lb. of this product) per acre per application. 2) Do not apply more than 3.2 pounds a.i. (3.5 lb. of this product) per acre per calendar year. 3) This product can be applied once during the Fall and once during the Spring. CA (Grapefruit, Lemons, Oranges): Apply 2.2 to 4.4 pounds of this product per acre in a single application or apply 2.2 pounds per acre in the Fall and 2.2 pounds per acre in the Spring. Use Precautions and Restrictions: 1) Do not apply more than 4 pounds a.i. (4.4 lb. of this product) per acre per calendar year. 2) Do not apply more than twice per calendar year. 3) Do not use in the Imperial, Coachella or Palo Verde Valleys or crop injury may occur. FL (Grapefruit and Oranges only): Broadcast 4.4 pounds of this product to weed-free soil once during the Spring and/or once during the Fall to control weeds expected to emerge during these periods. Apply prior to emergence of weeds. If weeds have emerged, apply in tank mixture with a contact herbicide. Use precaution to keep the treatment off of the foliage, fruit or trunk of Citrus trees. Use Precautions and Restrictions: 1) Do not apply more than 4 pounds a.i. (4.4 lb. of this product) per acre per application. 2) Do not apply more than 8 pounds a.i. (8.8 lb. of this product) per acre per year. 3) This product can be applied once during the Fall and once during the Spring. For control of difficult weeds such as Balsamapple and Spanishneedles, and for partial control of Honeyvine milkweed, apply no more than 8.8 pounds of this product as a single application in the Spring as a 50% band application. The amount of this product applied per acre of field must not exceed 4 pounds a.i. (4.4 lb. of this product). Apply once in the Spring growing season between January and April. Do not make a Fall application of this product if this treatment was used in the Spring. When emerged weeds are present, apply this product in tank mixture with a recommended contact herbicide. Follow all directions, precautions, limitations, etc. on the tank mix product. TX (Grapefruit and Oranges only): Apply up to 4.4 pounds of this product per acre. Use Precautions and Restrictions: 1) Do not apply more than 4 pounds a.i. (4.4 lb. of this product) per acre per calendar year. 2) Do not apply more than twice per calendar year. USE PRECAUTIONS AND RESTRICTIONS (ALL AREAS TO AVOID CROP INJURY): 1) Do not use in nurseries. 2) Do not apply to bedded Grapefruit, Lemons or Oranges [except for FL Grapefruit and Oranges]. 3) Do not apply to trees under stress from freeze damage for one year after the freeze. 4) Do not exceed 4.4 pounds of this product per acre per year on grove planted trees 1 year old or less. Note: Dark-red Grapefruit hybrids, e.g. “Star Ruby”, have a higher risk of crop injury than non-dark-red types.

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MACADAMIA NUTS Apply 2.2 to 4.4 pounds of this product in 50 gallons of water per acre before harvest and just prior to weed emergence. Use Precautions and Restrictions: 1) Do not apply more than 4 pounds a.i. (4.4 lb. of this product) per acre per calendar year. 2) Do not apply more than once per calendar year. 3) To avoid illegal residues, do not apply when nuts are on the ground during the harvest period. OLIVES Apply 2.2 to 4.4 pounds of this product per acre following grove preparation in the Fall. Repeat annually in mid-Winter. Use Precautions and Restrictions: 1) Do not apply more than 4 pounds a.i. (4.4 lb. of this product) per acre per calendar year. 2) Do not apply more than once per calendar year. PEACHES, PLUMS, SWEET CHERRIES Apply 1.75 to 4.4 pounds of this product per acre in late Fall to early Spring prior to weed emergence. Use Precautions and Restrictions: 1) Peaches: Use only in AR, LA, MO, OK, TX and states East of the Mississippi River to avoid crop injury. For CA, see specific directions in the section “ALMONDS, NECTARINES AND PEACHES [CA ONLY]”. Do not apply more than 4 pounds a.i. (4.4 lb. of this product) per acre per calendar year. Do not apply more than once per calendar year. 2) Plums and Sweet Cherries: Use only in MO and states East of the Mississippi River, except TN to avoid crop injury. Do not apply more than 4 pounds a.i. (4.4 lb. of this product) per acre per calendar year. Do not apply more than once per calendar year. PECANS Apply 2.2 to 4.4 pounds of this product per acre before weeds emerge in the Spring. Use Precautions and Restrictions: 1) Do not apply more than 4 pounds a.i. (4.4 lb. of this product) per acre per calendar year. 2) Do not apply more than once per calendar year. 3) Do not use West of the Pecos river in TX, or in AZ, CA, or NM. 4) Do not make applications to transplanted trees that have been established less than two years in the grove to avoid crop injury. 5) To avoid illegal residues, do not apply when nuts are on the ground. 6) Do not allow animals to graze treated areas. STRAWBERRIES (OR and WA Only) For control of Chickweed, Groundsel, Mustard and Shepherdspurse, broadcast 1.1 pounds of this product per acre. In fields where overhead irrigation is used to activate this product, apply after harvest at time of bed renovation. In fields where overhead irrigation is not available, apply during early October through November. Use Precautions and Restrictions: 1) Do not apply more than 1 pound a.i. (0.9 lb. of this product) per acre per calendar year. 2) Do not apply more than once per calendar year. 3) Make only one application per growing season. 4) Do not apply within 4 months after transplanting. WALNUTS Apply 2.2 to 4.4 pounds of this product per acre. Leveling and furrowing operations after application will lessen effectiveness of weed control. Use Precautions and Restrictions: 1) Do not apply more than 4 pounds a.i. (4.4 lb. of this product) per acre per calendar year. 2) Do not apply more than once per calendar year. 3) To avoid illegal residues, do not apply when nuts are on the ground. TANK MIXING OR SEQUENTIAL APPLICATION

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When tank-mixing or sequentially applying Simazine and/or Atrazine or products containing either active ingredient, the total pounds of Simazine and/or Atrazine applied must not exceed the specified maximum rate per calendar year. TANK MIX COMBINATIONS FOR FRUIT AND NUT CROPS TANK MIXTURE WITH BROMACIL 80W FOR GRAPEFRUIT AND ORANGES (FL Only): This product tank mixed with Bromacil 80W will control Balsamapple, Black nightshade, Carpetweed, Crabgrass, Cudweed, Dayweed, Florida pusley, Horseweed, Pepperweed, Pigweed, Poorjoe, Ragweed, Rattlebox, Spanishneedles and Sandbur. This mixture will also give partial control of Bermudagrass, Bahiagrass, Pangolagrass, Paragrass and Torpedograss. Apply 4.4 pounds of this product plus the specified label rate of Bromacil 80W per acre beneath trees in a minimum of 40 gallons of water per acre before or soon after weed growth begins. Use precaution to keep the spray off of the foliage, fruit or trunk of Citrus trees. Temporary yellowing of Citrus leaves may occur following treatment. Follow use and precautionary directions on the Bromacil label. Use Precautions and Restrictions (To avoid crop injury): 1) Do not use in nurseries or where trees are under stress from freeze damage for one year after the freeze. 2) Do not use on soil with less than 1% organic matter or on poorly drained soil. 3) Do not treat trees planted in irrigation furrows. 4) Do not treat diseased trees such as those with foot rot. 5) Do not use in groves interplanted with other trees or desirable plants, nor in home Grapefruit or Orange plantings or in areas where roots of other valuable plants or trees may extend. 6) Treated areas may be planted to Citrus trees one year after application. 7) Do not rotate to other crops within two years after application. To avoid illegal residues, apply only once per year and avoid contact with foliage and fruit with spray or mist. TANK MIXTURE WITH GRAMOXONE ®: This combination is effective in the following Fruit and Nut crops for kill of existing vegetation and for residual control of the annual Broadleaf and Grass weeds claimed for this product applied alone. This combination is also effective for top-kill and suppression of perennial weeds. In FL, this mixture may be applied in Spring or Fall to emerged weeds. Use this tank mixture on the following crops: Almonds (CA Only) Apples Avocados (CA & FL1 Only) Cherries (Tart & Sweet2) Filberts Grapefruit (CA & TX Only) Grapes Lemons (AZ & CA Only) Macadamia nuts Olives Oranges3 Peaches4 Pears Pecans Plums2 Walnuts SPECIFIC DIRECTIONS: Apply the rate given under the appropriate crop on this label plus the specified labeled rate of Gramoxone in 50 to 200 gal. (30 to 50 gal. for Pecans) of water per acre to the orchard floor avoiding contact with fruit, foliage or stems. Add a nonionic surfactant at 0.5 pt./100 gal. of spray. Apply when weeds are succulent and new growth is 1 to 6 inches tall. For mature Woody weeds or difficult to control Perennial weeds, retreat or spot treat with Gramoxone if regrowth occurs. Add this product to the spray tank first (refer to "MIXING PROCEDURES” section of this label), then add Gramoxone and add the surfactant last. Provide constant agitation during mixing and application to keep the mixture in suspension. Refer to the labels of both products for further directions, specific weeds controlled and precautions and limitations on each crop. 1 In Avocados in FL, this tank mix also controls Balsamapple vine, Rattail amaranth. At the higher specified rate of each herbicide, it suppresses Coral vine. 2 Limited to MO and states East of the Mississippi River, except TN. 3 In Oranges in FL, apply 4.4 lb. of this product per acre per application. Do not exceed 8.8 lb. of this product per calendar year. 4 Limited to AR, CA. LA, MO, OK, TX and states East of the Mississippi River. As appropriate, refer to the sections: “ALMONDS, NECTARINES AND PEACHES (CA ONLY)” or “PEACHES, PLUMS AND SWEET CHERRIES” for the rate of this product and other information.

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Use Precautions and Restrictions (To avoid crop injury):

1. Apply the tank mix only once per year. 2) Use shield for young trees or vines. TANK MIXTURE WITH IMITATOR® PLUS OR ROUNDUP® OR TOUCHDOWN® BRAND HERBICIDES This tank mixture is effective in Grape vineyards and in the following bearing or non-bearing tree crops for control of existing vegetation and for residual control of the annual Broadleaf and Grass weeds claimed for this product applied alone. This combination is also effective for partial control of perennial weeds contacted by the spray mixture during application. Use this tank mixture on the following crops: Almonds** (CA Only) Apples* Avocados* (CA & FL Only) Cherries (Tart & Sweet****

Filberts** Grapefruit*** (CA, FL & TX) Grapes* Lemons* (AZ & CA Only) Macadamia nuts** Oranges*** (AZ, CA, FL & TX) Peaches**** 2 Pears* Pecans** Plums**** 1 Walnuts** SPECIFIC DIRECTIONS: Use the specified rate given elsewhere on this label for this product applied alone to the crop being treated. Add to the spray tank the specified rate of Roundup or Imitator Plus or Touchdown brand product per acre depending on weeds present and their growth stage. Also, add an agriculturally approved nonionic surfactant at 0.5% by volume of spray solution. Apply the mixture in 10 to 40 gal. of water per acre as a post-emergence spray to the weeds at the appropriate weed growth stage given on the Roundup or Imitator Plus label. Add this product to the spray tank first, then add Roundup or Imitator Plus or Touchdown brand herbicides. Provide constant agitation during mixing and application to keep the mixture in suspension. Refer to “APPLICATION PROCEDURES” section of this label for further directions. Refer to labels of both herbicides for further directions, specific weeds controlled, precautions and limitations on each crop. USE PRECAUTIONS AND RESTRICTIONS (To avoid crop injury): Take extreme care to avoid contact of herbicide solution, spray, drift or mist with foliage or green bark of trunk, branches, suckers, fruit, or other parts of trees or vines. Observe use precautions on both this product and Roundup or Imitator Plus or Touchdown labels for each crop involved.

• Allow a minimum of 14 days between last application and harvest. ** Allow a minimum of 21 days between last application and harvest of these crops. *** Allow a minimum of 1 day between last application and harvest of these crops. **** Allow a minimum of 17 days between last application and harvest of these crops. 1 Plums and Sweet cherries: Limited to MO and states East of the Mississippi River, except TN. 2 Limited to AR, CA, LA, MO, OK, TX and states East of the Mississippi River. For CA, see specific directions in the section “ALMONDS, NECTARINES AND PEACHES (CA ONLY)” TANK MIXTURE WITH SOLICAM® For improved control of such weeds as Clover, Cutleaf eveningprimrose, Dandelion, Henbit, Horseweed or Marestail, Lambsquarters and Puncturevine, apply this product in tank mixture with Solicam DF on the following crops: Grapefruit Lemons Oranges SPECIFIC DIRECTIONS: Apply the specified rate of this product from the use section on this label plus the specified rate of Solicam DF Herbicide (78.6% active ingredient) in 20 to 100 gal. of water per acre. This product plus Solicam may be applied in tank mixture with Gramoxone or Roundup or Imitator Plus. Follow the labeled directions and restrictions of use on labels of herbicides used in mixtures with this product. Use Precautions and Restrictions (To avoid crop injury): Keep this product plus Solicam mixtures from contacting foliage, fruits and stems of Citrus trees during spraying.

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TANK MIXTURE WITH SURFLAN® Use this tank mixture in the following crops for pre-emergence control of all weeds claimed on both labels: Almonds Apples Avocados Caneberries Cherries Filberts Grapefruit Grapes Lemons Oranges Peaches Pears Pecans Plums Walnuts (English) SPECIFIC DIRECTIONS: Apply the rate given for this product under the appropriate crop on this label plus the specified rate of Surflan 75W or Surflan A.S. in 20 to 40 gal. of water per acre. Refer to the Surflan 75W or Surflan A.S. label for complete tank mix directions. Observe all precautions and limitations on this label and Surflan labels. FIELD AND FORAGE CROPS CORN (Field, Sweet) Apply a maximum of 2 pounds a.i. (2.2 lb. of this product) per acre as a single pre-emergence application on soils that are not highly erodible or on highly erodible soils, as defined by the Natural Resources Conservation Service, if at least 30 % of the soil is covered with plant residues. If a second treatment is required following an earlier herbicide application, the total Simazine applied may not exceed 2.5 pounds a.i. (2.7 lb. of this product) per acre per calendar year. Apply a maximum of 1.6 pounds a.i. (1.7 lb. of this product) as a single pre-emergence application on highly erodible soils if <30% of the soil is covered with plant residues. Pre-grazing/Pre-harvest Interval:

1. Field corn – 60 days
2. Sweet corn – 45 days Nitrogen solutions or complete fluid fertilizers may replace all or part of the water as a carrier in the spray. Determine the physical compatibility of this product with fertilizer before use. Refer to the “USE INFORMATION” section of this label for a compatibility test. Do not apply after Corn has emerged as there is danger of liquid fertilizers causing crop injury. PRE-EMERGENCE: Apply before weeds and Corn emerge. Use the appropriate rate specified above. PRE-PLANT: Apply in the Spring after plowing as broadcast at the appropriate rate specified above. Apply before, during or after final seedbed preparation. If soil is tilled or worked after application, avoid deep incorporation. Best results will be obtained when this product is applied within 2 weeks before planting. Under dry weather conditions, pre-plant applications may give better weed control. If weeds develop, particularly under relatively dry conditions, a shallow cultivation will generally result in better weed control. To control Quackgrass: Apply this product as broadcast per acre using the rates specified above during the Fall. Plow two to three weeks later, or if erosion is a problem, delay plowing until Spring. WINTER ANNUAL BROADLEAF CONTROL PRE-EMERGENCE FALL APPLICATION: For pre-emergence control of Winter annual weeds such as Annual bluegrass, Common chickweed, Downy brome, Henbit, Shepherdspurse, Tansymustard, Wild mustard and others, broadcast 1.1 pounds of this product per acre of this product after harvest of the preceding crop and prior to weed emergence on land to be planted to Corn the following year. A tillage operation may precede the application. Do not apply to frozen ground. If this product is used in the Fall Corn weed program, do not exceed 1.67 pounds of this product pre-emergence in the Spring. Use Precautions and Restrictions: 1) Do not apply more than 2.77 pounds of this product per acre to Corn per calendar year. 2) Do not rotate to any crop except Corn until the following year or injury may occur.

3. After harvest, plow and thoroughly till the soil in Fall or Spring to minimize possible injury to Spring- seeded rotational crops, regardless of the rate used. 4) Do not apply pre-plant incorporated in Corn in the High Plains and Intermountain areas of the West (including Central and Western KS, Western NE, Western OK and the Panhandle of TX) where rainfall is sparse and erratic or where irrigation is required. 5) In the

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High Plains and Intermountain areas of the West where rainfall is sparse and erratic or where irrigation is required, use this product to control weeds in Corn only when Corn is to follow Corn or when a crop of untreated Corn is to precede another rotational crop. 6) Injury may occur to Soybeans planted in North- Central and Northwest IA, South-Central and Southwest MN, Northeast NE, Southeast SD and other areas the year following application on soils having a calcareous surface layer. 7) Do not plant Sugar beets, Tobacco, Vegetables (including Dry beans), Spring-seeded small grains or Small-seeded legumes and Grasses the year after an application or injury may occur. Note: Do not graze treated areas or illegal residues may result. TANK MIXTURES ON CORN ATRAZINE: Use this product in a pre-plant or pre-emergence tank mixture with Atrazine 90DF, Atrazine 4L or Atra™-5 for control of many annual weeds, including Carpetweed, Crabgrass, Fall panicum, Foxtail, Lambsquarters, Morningglory, Pigweed, Ragweed and Velvetleaf. When tank mixing or sequentially applying Simazine and/or Atrazine or products containing either active ingredient to Corn, the total pounds of Simazine and/or Atrazine applied must not exceed 2.5 pounds a.i. per acre per calendar year. Refer to the Atrazine label for complete directions. Also, refer to the Atrazine label and the "CORN" section of this label for precautions and limitations. ERADICANE ® OR RAZENCANE®: Use in a pre-plant incorporated tank mixture for control of all weeds claimed on both this product and Eradicane or Razencane labels including partial control (suppression) of Shattercane (Wild cane). Fluid fertilizer may replace all or part of the water in the spray. Check the physical compatibility of mixture with fertilizer before use. Refer to the “USE INFORMATION” section of this label for a compatibility test procedure. Use a minimum of 20 gallons of spray volume per acre. Refer to the Eradicane or Razencane label for incorporation directions. Use the higher rate of this product on Fine textured soil and where heavy Broadleaf infestations are expected. Use the higher rate of Eradicane or Razencane for heavy Bermudagrass and Nutsedge infestations. For partial control (suppression) of Shattercane, broadcast and incorporate immediately before planting the specified rate of this product as listed in the use direction by soil texture for Corn plus the specified label rate of Eradicane or Razencane per acre. For control of the other weeds claimed on both labels, broadcast and incorporate the specified rate of this product as listed in the use direction by soil texture for Corn plus the specified label rate of Eradicane or Razencane per acre. Observe all precautions and limitations on this product and Eradicane or Razencane labels. GRAMOXONE: Use in a tank mixture where Corn will be planted directly in a cover crop, established sod or previous crop residues. This combination controls existing vegetation and provides residual control of the annual Broadleaf and Grass weeds listed under “USE INFORMATION”. Add this product to the spray tank, mix thoroughly with water and then add Gramoxone and a non-ionic surfactant. Provide constant agitation during mixing and application to keep the mixture in suspension. Apply the specified rate of this product as listed in the use direction by soil texture for Corn plus the specified label rate of Gramoxone in 20 to 60 gallons of water per acre as a broadcast spray either before or after planting, but before Corn emerges. Add a non-ionic surfactant at the rate of 0.5 pint per 100 gallons of spray volume. For further information, see “USE INFORMATION”, caution and warning statements, precautions and notes on this product label and the Gramoxone labels. SUTAN ® +: Use in a pre-plant incorporated tank mixture for control of all weeds claimed on both this product and Sutan+ labels including partial control (suppression) of Shattercane (Wild cane). Fluid fertilizer may replace all or part of the water in the spray. Check the physical compatibility of mixture with fertilizer before use. Refer to the “USE INFORMATION” section of this label for a compatibility test procedure. Use a minimum of 20 gallons of spray volume per acre. Refer to the Sutan+ label for incorporation directions. Use the higher rate of this product on Fine textured soil and where heavy Broadleaf infestations are expected. For partial control (suppression) of Shattercane, broadcast and incorporate immediately before planting, the specified rate of this product as listed in the use direction by soil texture for Corn plus the specified label rate of Sutan+ 6.7E per acre. For control of the other weeds claimed on both labels, broadcast and incorporate 1.1 to 2.2 pounds of this product plus the

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specified label rate of Sutan+ 6.7E per acre. Observe all precautions and limitations on this product and Sutan+ labels. NURSERIES AND CHRISTMAS TREE PLANTINGS Apply 2.2 to 3.3 pounds of this product in at least 25 gallons of water per acre after transplanting. Use Precautions and Restrictions: 1) Do not apply more than 3 pounds a.i. (3.3 lb. of this product) per acre per calendar year. 2) Do not apply more than once per calendar year. 3) Do not apply for at least one year after transplanting to avoid plant injury. 4) Except for uses in Christmas tree plantings, all shelterbelt and forestry uses are prohibited. CHRISTMAS TREE PLANTINGS: Remove weed growth before application. Apply 2.2 to 4.4 pounds in at least 25 gallons of water per acre after transplanting. Use the same rate for annual maintenance applications. For Quackgrass control: Apply 4.4 pounds of this product per acre in the Fall or apply a split application of 2.2 pounds per acre in the Fall plus 2.2 pounds per acre in early Spring, after Quackgrass begins growth. Use Precautions and Restrictions: 1) Do not apply more than 4 pounds a.i. (4.4 lb. of this product) per acre per calendar year. 2) Do not apply more than twice per calendar year. 3) Do not use on seedbeds or cutting beds. 4) In CA, OR and WA do not apply to Christmas trees sooner than one year after transplanting. In other areas, do not apply to Christmas trees less than two years of age. 5) Do not use until soil is firmly settled around roots. 6) Do not apply more than once a year, except as directed for Quackgrass control. 7) Except for uses on Christmas tree plantings, all shelterbelt and forestry uses are prohibited. Apply this product to the following species of trees and shrubs, as specified above: Conifers Arborvitae Austrian pine Balsam fir Bishop pine* Blue spruce Douglas fir Fraser fir Hemlock Juniper Knobcone pine* Lodgepole pine (Shore pine) Monterey pine* Mugho pine Norway spruce Red cedar Red pine (Norway pine) Red spruce Scotch pine White cedar White fir White pine White spruce Yew (Taxus spp.) Deciduous Trees and Woody Ornamentals American elm Barberry Bottle brush* Boxelder Bush honeysuckle Caragana Carob* Cotoneaster Dogwood Eucalyptus Holly (Ilex spp.) (max. 3.3 lb./A) Honey locust Oleander* Oregon grape (Mahonia spp.) Palm (max. 2.2 lb./A)* Pieris spp. (max. 3.3 lb./A) Red oak Russian olive Siberian elm

• For CA only SURFLAN® TANK MIX: On Christmas tree plantings, use this tank mix for pre-emergence control of weeds listed on this label and the Surflan 75W (or Surflan A.S.) label. Use on field-grown Conifer species listed on the labels for each herbicide plus Alpine Fir, Black Spruce, Colorado Blue Spruce, Coulter Pine, Engelmann Spruce, Giant Redwood, Grand Fir and Veitchi Fir. Broadcast the mixture as a directed spray to the soil surface or as an overtop spray using 2.2 to 4.4 pounds of this product and the specified label rate of Surflan 75W or Surflan AS. Apply in sufficient water per acre to uniformly treat the area. Follow overtop sprays with sprinkler irrigation to move the herbicide from leaf surfaces to the soil. Remove weed growth before application. Mix weed residues, prunings or trash into the soil, or remove them before

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treatment. Soil should be in good tilth and free of clods at time of application. Shallow cultivation (1 to 2 inches) after treatment will not reduce weed control. Observe all precautions and limitations on this product and Surflan labels. Note: Length of weed control may be reduced when continuous wet soil conditions follow herbicide application. Use Precautions and Restrictions: 1) Do not use on seedbeds or on unrooted cuttings. 2) Do not use in greenhouses or other enclosed areas. TURFGRASSES FOR SOD (FL ONLY) Bermudagrass, Centipedegrass, St. Augustinegrass and Zoysiagrass: Apply 2.2 to 4.4 pounds of this product per acre according to soil texture, as indicated below: Muck or Peat 4.4 lb. Old beds Within 2 days after lifting of sod New beds 3 to 4 days after sprigging or plugging Sandy soil 2.2 lb. Old beds Within 2 days after lifting of sod New beds 7 to 10 days after sprigging or plugging Note: On newly sprigged Turfgrass, temporary slowing of growth may follow application. If weeds regrow, apply an additional 2.2 pounds of this product on Muck or Peat, or 1.1 pounds on Sandy soil. Use Precautions and Restrictions: 1) Do not apply more than 4 pounds a.i. (4.4 pounds of this product) per acre per application. Maximum number of applications per calendar year is two. Maximum total amount per calendar year is 6 pounds a.i. (6.6 pounds of this product) per acre. 2) Do not apply within 30 days prior to cutting or lifting. 3) Do not graze or feed turf clippings to animals, or illegal residues may result. 4) Do not apply in combination with surfactants or other spray additives. 5) This product must be watered-in immediately after application if applied at a rate greater than 2.2 pounds of this product per acre. 6) For use only on warm season Turfgrass (e.g., Bermudagrass, Centipedegrass, St. Augustinegrass and Zoysiagrass) and reasonably free of infestations of insects, nematodes and diseases. TURFGRASSES FOR SOD (In States Except FL) Bermudagrass, Centipedegrass, St. Augustinegrass, Zoysiagrass: Apply 1.1 to 2.2 pounds of this product per acre. Use Precautions and Restrictions: 1) Do not apply to established beds within 2 days after lifting of sod. Do not apply to new beds before 7 to 10 days after sprigging or plugging. 2) Do not apply more than 2 pounds a.i. (2.2 lb. of this product) per application and no more than two applications per calendar year. 3) Do not apply more than 3 pounds a.i. (3.3 lb. of this product) per calendar year. 4) On newly sprigged Turfgrass, hybrid Bermudagrass, non-dormant Bermudagrass or non-dormant Zoysiagrass, temporary slowing of growth and yellowing may occur following application. 5) Use only on Turfgrass reasonably free of infestation of insects, nematodes, and diseases. 6) Do not use north of NC (except in the VA coastal plains) or on soils with pH of above 7.8. 7) Do not use on muck or alkaline soils. 8) Do not apply over the rooting area of trees or ornamentals not listed on this label. 9) Do not seed or overseed with desirable Turfgrass within 4 months before or 6 months after treatment. 10) Do not apply this product to newly seeded grasses until they have overwintered and have well developed rhizome treatment. 11) Do not exceed 2 pounds a.i. (2.2 lb. of this product) within 12 months of seeding grasses. 12) For use only on warm season Turfgrass (e.g., Bermudagrass, Centipedegrass, St. Augustinegrass and Zoysiagrass). Note: Do not graze or feed turf clippings to animals, or illegal residue may result. TURFGRASS FOR FAIRWAYS AND LAWNS* (*Residential Turf on Lawns, Institutional Turf, Parks or Recreational fields)

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Bermudagrass, Centipedegrass, St. Augustinegrass and Zoysiagrass: Apply this product after September 1 (after October 1 for Annual bluegrass) before emergence of Winter annual weeds. Fall applications of this product will control Annual bluegrass, Burclover, Chickweed (Common, Mouseear), Corn speedwell, Henbit, Hop clover, Lawn burweed, Parsley-piert and Spurweed. This product will also control these weeds soon after emergence. For control of Summer annual weeds listed in the “USE INFORMATION” section of this label, also apply this product in late Winter before the weeds emerge. Apply in a minimum of 15 gallons of water per acre or 1 gallon per 1,000 square feet. Irrigate with 0.5 inch of water if rainfall does not occur within 10 days after pre-emergence treatment. Where Annual bluegrass is the major weed, use 1.1 pounds of this product per acre (0.4 oz./1,000 sq. ft.) (1 lb. a.i./A). Use 1.1 to 1.7 pounds per acre (0.4 to 0.6 oz./1,000 sq. ft.) (1.1 to 1.6 lb. a.i./A) to control other weeds. Irrigation of 0.5 inch is required. In the absence of irrigation, use 0.7 pound of this product per acre (0.3 oz./1,000 sq. ft.) (0.65 lb. a.i./A) against Annual bluegrass and other weeds. Do not exceed 1.1 pounds per acre per treatment on newly sprigged Turfgrass or on hybrid Bermudagrass such as Tiflawn, Tifway and Ormond. For continued Summer annual weed control, apply another 1.1 pounds per acre at least 30 days after the previous application, but not after June 1. However, do not make more than two applications of this product per calendar year. Use Precautions and Restrictions: On newly sprigged Turfgrass, hybrid Bermudagrass, non-dormant Bermudagrass or non-dormant Zoysiagrass, temporary slowing of growth and yellowing may occur following application. (To avoid turf injury): 1) For use only on warm season Turfgrass (e.g., Bermudagrass, Centipedegrass, St. Augustinegrass and Zoysiagrass) and reasonably free of infestations of insects, nematodes and diseases. 2) Do not use on golf greens. 3) Do not use North of NC (except may be used in VA Coastal Plains) or on soils with a pH above 7.8. 4) Do not use on Muck or alkaline soils. 5) Do not apply over the rooting area of trees or ornamentals not listed on this label. 6) Do not seed or overseed with desirable Turfgrass within 4 months before or 6 months after treatment. 7) Do not apply this product to newly seeded Grasses until they have over-wintered and have a well-developed rhizome system. 8) Do not apply more than 1.6 pound a.i. (1.7 lb. of this product) per acre (0.6 oz./1,000 sq. ft.) per application with the requirement of 0.5 inch of irrigation OR 0.65 pound a.i (0.7 lb. of this product) per acre (0.3 oz./1,000 sq. ft.) without irrigation. 9) Maximum number of application per calendar year is two. Note: Do not graze or feed Turf clippings to animals or illegal residues may result. TANK MIXTURE WITH IMITATOR PLUS OR ROUNDUP OR TOUCHDOWN: This tank mixture will provide control of emerged Annual weeds and residual control of weeds listed on this label. The combination also will partially control emerged Perennial weeds listed on the Roundup, Imitator Plus or Touchdown label. Add to the spray tank the specified rate of this product noted in the above section for this product alone. Then add the specified label rate of Roundup, Imitator Plus or Touchdown per acre depending on weeds present and their growth stage. Also, add an agriculturally approved non-ionic surfactant at 0.5% by volume of spray solution. Apply the mixture in 10 to 40 gallons of water per acre as a post-emergence spray at the appropriate weed growth stage given on the Roundup, Imitator Plus or Touchdown label. Provide constant agitation during mixing and application to keep the mixture in suspension. Refer to the “APPLICATION PROCEDURES” section of this label for further directions. Refer to the labels of both herbicides for specific non-crop sites, rates, weeds controlled and further directions, precautions and limitations.

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STORAGE AND DISPOSAL Do not contaminate water, food or feed by storage or disposal. PESTICIDE STORAGE: Storage should be under lock and key and secure from access by unauthorized persons and children. Storage should be in a cool, dry area away from any heat or ignition source. Do not stack over 2 pallets high. Move bags carefully so as not to tear or puncture. Do not move containers from one area to another unless they are securely sealed. Keep containers tightly sealed when not in use. Do not allow bags to become wet or store near water supplies, food, feed and fertilizer to avoid contamination. Store in original container only. If the contents are leaking or material is spilled, follow these steps:

1. Collect and place in suitable containers for disposal.
2. Wash area with soap and water to remove remaining pesticide.
3. Follow washing with clean water rinse.
4. Do not allow runoff to enter sewer or contaminate water supplies.
5. Dispose of waste as indicated below. PESTICIDE DISPOSAL: Wastes resulting from the use of this product may be disposed of on site or at approved waste disposal facility. CONTAINER DISPOSAL: Nonrefillable Container (fl exible-bag-all weights): Nonrefillable container. Do not reuse or refill this container. Completely empty bag into application equipment by shaking and tapping sides and bottom to loosen clinging particles. Offer for recycling, if available. Dispose of empty container in a sanitary landfill or by incineration, or, if allowed by State and local authorities, by burning. If burned, stay out of smoke. Nonrefillable Container (rigid-fifty lb. or less): Nonrefillable container. Do not reuse or refill this container. Offer for recycling, if available. Clean container promptly after emptying. Triple rinse as follows: Empty the remaining contents into application equipment or a mix tank. Fill the container one-fourth full with water and recap. Shake for 10 seconds. Pour rinsate into application equipment or a mix tank or store rinsate for later use or disposal. Drain for 10 seconds after the flow begins to drip. Repeat this procedure two more times. Dispose of empty container in a sanitary landfill or by incineration, or, if allowed by State and local authorities, by burning. If burned, stay out of smoke. Nonrefillable Container (rigid-greater than fifty lb.): Nonrefillable container. Do not reuse or refill this container. Offer for recycling, if available. Clean container promptly after emptying. Triple rinse as follows: Empty the remaining contents into application equipment or a mix tank. Fill the container one-fourth full with water. Replace and tighten closures. Tip container on its side and roll it back and forth, ensuring at least one complete revolution, for 30 seconds. Stand the container on its end and tip it back and forth several times. Turn the container over onto its other end and tip it back and forth several times. Empty the rinsate into application equipment or a mix tank or store rinsate for later use or disposal. Repeat this procedure two more times. Dispose of empty container in a sanitary landfill or by incineration, or, if allowed by State and local authorities, by burning. If burned, stay out of smoke. Refillable Container: Refillable container. Refill this container with pesticide only. Do not reuse this container for any other purpose. Cleaning the container before final disposal is the responsibility of the person disposing of the container. Cleaning before refilling is the responsibility of the refiller. To clean the container before final disposal, empty the remaining contents from this container into application equipment or mix tank. Fill the container about 10 percent full with water. Agitate vigorously or recirculate water with the pump for 2 minutes. Pour or pump rinsate into application equipment or rinsate collection system. Repeat this rinsing procedure two more times.

Page 19 of 19 WARRANTY—CONDITIONS OF SALE THE DIRECTIONS FOR USE of this product are based upon tests believed reliable. Follow directions carefully. Timing and method of application, weather and crop conditions, mixtures with other chemicals not specifically recommended and other influencing factors in the use of this product are beyond the control of the Seller. To the extent consistent with applicable law, Buyer assumes all risks of use, storage and handling of this material not in strict accordance with directions given herewith. To the extent consistent with applicable law, in no case shall the Manufacturer or the Seller be liable for consequential, special or indirect damages resulting from the use or handling of this product when such use and/or handling is not in strict accordance with directions given herewith. The foregoing is a condition of sale by the Seller and is accepted as such by the Buyer. Manufactured By [For]: [Made in _______] The DREXEL logo is a registered trademark of Drexel Chemical Company. All other brand names, product names, or trademarks belong to their respective holders.