Dockerfile: self-contained image with corpus + Chroma + BM25 baked in. Drawbar's compose pulls + runs without volume mounts. Built from sources.json (labels schema), PRODUCT_NAME=crop_chem by default, HYBRID_SEARCH=true (always-on for production quality). RERANK_URL + OLLAMA_URL get set at compose time. .gitea/workflows/refresh.yml: monthly cron (1st @ 06:00 UTC) does full scrape → reindex → image push. Scrapes Bayer (~30 min) + EPA PPLS row-crop filtered (~7h). Skips reindex+push if no corpus diff. Tags pushed: :latest, :<sha12>, :corpus-<YYYY.MM.DD>. .gitea/workflows/image-only.yml: on-demand or auto on code-only pushes to main (paths: docs_mcp/, rag/, scrape/, requirements.txt, Dockerfile, sources.json). Reindexes from committed corpus, builds image, pushes. ~10 min vs ~9h full refresh. .gitignore: corpus/ now COMMITTED (4,159 labels, 265 MB of .md + sidecars). Lets image-only.yml rebuild indexes without re-scraping. chroma/ + bm25/ still gitignored (regenerable binary indexes). .dockerignore: drops venv, eval results, PLAN/README/CLAUDE.md, deploy/, .git/ — keeps the image lean. corpus + chroma + bm25 explicitly NOT in dockerignore (those go INTO the image). Co-Authored-By: Claude Opus 4.7 (1M context) <noreply@anthropic.com>
17 KiB
DIAZINON METHOXYCHLOR INSECTICIDE
- EPA Reg No: 5905-239
- Registrant: HELENA AGRI-ENTERPRISES, LLC, D/B/A HELENA CHEMICAL COMP
- Signal word: Caution
- Active ingredients: Methoxychlor (20%); Diazinon (10%)
- Label accepted: 1995-11-02
- Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/005905-00239-19951102.pdf
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(A) . United States Environmental Protection Agency
§ Registration
OPP Identifier Number
ft EPA'" Office 01 Pesticide PrognIms (H7505C)
,
:!WJ: Washington, DC 20460 Amendment
~7 . Application for Pesticide: x Other 210290
Section I
- CompanylProduct Number 2, EPA Product Manager 3. Proposed Classification 5905-239 GEORGE LAROCCA [i] None D Restricted -
- CompanylProduct (Name) PMI DIAZINON-METHOXYCHLOR INSECTICIDE 15
- Name and Address 01 Applicant {Include ZIP Code} 6, expedited Review. In accordance w~h FIFRA Section 3(c)(3) HELENA CHEMICAL COMPANY (b)(i), my product is similar or identical in composition and labeling 6075 POPLAR AVENUE, SUITE 500 to: MEMPHIS, TN 38119 EPA Reg. No. o Chock if this is a new address Product Name Section II
- Rnal printed labels in response to Amendment - Explain below
- f-- Agency lener dated Resubmission in response to Agency letter dated
- "Me Too" Application. -.X Notification - Explain below. f-- Other - e"'l-Jlain below Explanation: Use additional pagels) if necessary. (For section I and Section II ) RESPONSE TO AGENCY LETTER OF SEPTEMBER 25, 1995 REGARDING UNSUPPORTED USES ON PRODUCT REGISTRATIONS CONTAINING METHOXYCHLOR. HELENA CHEMICAL COMPANY WILL BE DELETING C~BERRIES FROM THIS LABEL. Section III
- Materfaf This Product Will 8e Packag~d In: Child-Resistant Packaging Unit Packaging Water Soluble Packaging 2. Type of Container Byes' a Yes BYes ~=r PlastIC No No No Glass II "Yes," No. per II "Yes," No. par Paper Other (Specify) • Certification must be Unit Package wgt. container Package wgt. container sub I
- Location 01 Net Contents Information 4. Size(s) 01 Retail Container 5. Location of Label Directions o Label o Container BOn Label On Labehng accompanying product
- Manner In Which Label Is Affixed To Product § Lithograph D Other ( . ____ 1 Paper glued Stenciled Section IV
- Contact Point (Complete items direcdy below lor identiflcaoon 01 individual to be contacted, if necessary, to process this application.)
Name Title Telephone No. (inell/de Area Code)
. ( " ....
BEVERLEY NEALE REGISTRATION SPECIALIST 901-537':'8611
• < · '
Ll( Certification 6. (,ato Application . Received' . ... " I certify thatlhe statements I have made on this form and all attachments thereto are true, accurate and complete. .. • • I acknowledge that any knowingfy false or misleading statement may be punishable by fine or imprisonment or (Stamped) • both under applicable faw I ( ( •• • . , . .. 2 Siglh..... • ..L ClJ! • - Tide • • • • .. .. " ..... J~~ · () • . 0 .... , REGISTRATION SPECIALIST 0 00 \ 0 • 0
- Typed Name lj , 5. Date I o ' . • • " . .. 0 .1EVERLEY NEALE OCTOBER 26, 1995
- _ .. -
pry ~~ ~IS PRODUCT MUST NOT BE USED ON GOLF COURSES AND SOD FARMS ~ ~STRICTED USE PESTICIDE Due to Avian and Aquatic Toxicity For retail sale to and use only by Certified Applicators or persous under their direct supervision and only for those uses covered by the Certified Applicator's Certification '---- ~ l-;;;AZINON® - METHOXYCHLOR INSECTICIDE /This product contains Diazinon aD and Methoxychlor ~or control of insects on vegetables and small fruits ACTIVE INGREDIENTS: *Methoxychlor: l,l,1,-trichloro-2, 2-bis(p-methoxyphenyl) ethane ..... . Diazinon: O,O-Diethyl 0-(2,isopropyl-6-methyl-4-pyrimidinyl) phosphorothiate .................................................. . INERT INGREDIENTS: ....................................................... . TOTAL ................................ . 20.0% 10.0% 70.0% 100.0%
- Equivalent to 17.5% 2,2-bis(p-methoxyphenyl)-l,l,I,-trichloro ethane and 2.4%
other isomers and reaction products.
Contains Petroleum distillate
~r----------------------------------------------------------------------------'
KEEP OUT OF REACH OF CHILDREN - l.;l POW . .+ ~~
CAUTION - 1& POu.u- ~fU-
PRECAUCION AL USARIO: Si us ted no lee ingles, no use este producto hasta
que Ie etiqueta haya sido explicado ampliamente.
i
See Inside Booklet for Additional Precautionary Statements
EPA REG. NO.: 5905-239
EPA EST. NO.: First letters of
product batch code indicate
prodUCing establishment:
5905-GA-l=CG 5905-AR-l=WA
5905-CA-l=KC 5905-IA-l=DI
5905-FL-l=TF
MANUFACTURED BY ;J
HELENA CHEMICAL COMPANY
MF.MPHIS, TN. 38137_
NET CONTENTS:
...
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l
PRECAUTIONARY STATEMENTS
~ HAZARDS TO HUMANS AND DOMESTIC ANIMALS
.ru. d AUTION - 18 PO ptJ
Causes eye irritation. Avoid contact with eyes. skin and clothing. Wash
thoroughly with soap and water after handling. Harmful if swallowed. inhaled.
or absorbed through skin. Avoid breathing vapors or spray mist. Do not
contaminate food or feed. Remov( contaminated clothing and wash before reuse.
May cause contact sensitization following repeated contact with skin in
susceptible individuals. Avoid repeated contact with skin. If sensitization
reactions result consult a physician.
~ . Do
not apply to water that will be used for recreational purpose and humar. and , ,
livestock consumption. Shrimp and crab may be killed at applicatio~'r&t~s
recommended on this label. Do not apply where fish. shrimp. crab, and,other
aquatic life are important resources.
•••• • • •
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•
•TATEMENT OF PRACTICAL TREATMENT
IF IN EYES: Flush with plenty of water. Get medical attention if irritation
develops or persists.
IF ON SKIN: Wash with plenty of soap and water. Get medical attention if
irritation develops or persists.
IF SWALLOWED: DO NOT INDUCE VOMITING. Call a physician or poison control
center immediately. Do not give anything by mouth to an unconscious or con
vulSing person.
IF INED: Remove victim to fresh air. Give artificial respiration. if
necessary. to aintain breathing. (Do not give mouth-to-mouth resuscitation
if exposure is due to swallowing). Get medical attention.
NOTE TO PHYSICIAN: Atropine is antidotal for organic phosphate poisoning
and should be given intravenously in relatively large amounts. 2-4 mg (1/30
to 1/15 grain) at 5 to 10 minute intervals until the patient is atropinized.
2-PAM may be given in severe cases. Give supportive therapy as needed.
Lavage stomach if ingested. Solvent may present aspiration hazard.
ItR.ci C ENVIRONMENTAL HAZARDS
This pesticide is highly toxic to birds. fish. and wildlife icluding water
fowl. Birds and waterfowl feeding or drinking on treated areas may be
killed. Because of the migratory habits of certain Aclantic Coast waterfowl.
do not apply this product in Nassau County. New York between November 1 and
M?y 20. Do not exceed maximum permitted label rates. Rates above those
recommended significantly increase potential hazards to birds and waterfowl.
Avoid overlapping of sprays. Where irrigation (watering) is recommended
apply a minimum of 0.25 inch of water immediately after application. Stop
irrigation before pudding occurs. Keep out of lakes. streams. ponds. tidal
marshes and estuaries (except for effluence from treated watercress :bepf
This pesticide is highly toxic to bees exposed to direct treatment or
residues on blooming crops or weeds. Do not apply this pesticide or allow
it to drift to blooming crops or weeds if bees are visiting the treatment
area.
Fto.dLpHYSICAL OR CHEMICAL HAZARDS
Do not use, pour, spill, or store near heat or pen flame .
.ru.d LPIRECTIONS FOR USE
It is a violation of federal law to use this product in a manner inconsistent with
it s la be lj.hg.
~ en warnings must include the following information: "CAUTION. Ar.ea'lleated
with Diazinon-Methoxychlor on (date of application). Do not enter wit~out
appropriate personal protective equipment for 24 hours after applicat{HEMIGATION PROHIBITION
Do not apply this product through any type of irrigation system.
rt..Ld [}JORK SAFETY RULES
REPEATED EXPOSURES TO CHOLINESTERASE INHIBITORS SUCH AS ARE CONTAINED IN THIS
PRODUCT MAY, WITHOUT WARNING, CAUSE PROLONGED SUSCEPTIBILITY TO VERY SMALL DOSES
OF ANY CHOLINESTERASE INHIBITOR.
Do not rub eyes or mouth with hands. If you feel sic'· in any way STOP work and get
help right away. See Practcal Treatment Section of chis label.
PERSONAL PROTECTIVE EQUIPMENT:
Long-sleeved shirts; long-legged pants; shoes and sock; and chemical-resistant
gloves.
~ L-REENTRY STATEMENT
Twenty-four hours must elapse between the time of application and the time a
worker enters or is allowed to enter the treated area unless the person entering
the treated area is wearing the personal protective equipment listed above.
Because certain states may require more restrictive reentry intervals for varj
crops treated with this product, consult your State Department of Agriculture.
further information.
Written or oral warnings must be given to workers who are expected to be in a
treated area or in'ln area ahout to be treated with this product. Oral warnings
must be given which inform workers of areas or fields that may not be entered
without specific personal protective equipment for 24 hours after application and
appropriate actions to take as described under Precautionary Statements on this
label. When oral warnings are given, warnings shall be given in a language
customarily understood by workers. Oral warnings must be given if there is
reason to believe that written \larnings cannot be u"derstood by worker.s ..
Writn. In
case of accidental exposure, flush eyes or skin with pl,.nty of water. C&ll a:·":":
physician if irritation persists. Remove and wash contaminated clothing befor "
reuse."
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Store at temperatures
storage or disposal.
n..J DTORAGE AND DISPOSAL
above 32°F. Do not contaminate
Open dumping is prohibited.
water, food, or feed by
PESTICIDE: Pesticide wastes are toxic. Improper disposal of excess pesticide,
spray mixture, or rinsate is a violation of federal law. If these wastes cannot
be disposed of by use according to label instructions, contact your State Pesticide
or Environmental Control Agency or the Hazardous Waste Representative at the
nearest EPA Regional Office for guidance.
CONTAINER: Triple rinse (or equivalent). Then offer for recycling or reconditioning,
or puncture and dispose of in a sanitary landfill or by other approved state and
local procedures.
ru.& LGENERAL INFOR11ATION
Diazinon-Methoxychlor is an emulsifiable solution which is to be diluted with water.
When ground applications are to be made dilute Diazinon-Methoxychlor with water
according to the Directions for Use section.
Diazinon-Methoxychlor is intended for use against insect pests of agricultural crops
and should not be used in barns or dwellings. Applications should be repeated as
necessary to maintain control.
rr.....& DIRECTIONS FOR USE
SMALL FRUIT INSECTS:
For the control of the insects on the following crops, apply 2-1/2 qts. per 100
gal. of water per acre as a thorough cover spray when insects first appear.
Repeat applications at 7-10 day intervals as infestations warrant.
CRANBERRIES: Cranberry Fruitworms, Leafhoppers, Spittlebugs:
within 14 days of harvest.
Do not apply
GRAPES: Flea Bettles, Grape Berry Moths, Grape Leaf Folders, Grape Leaf Skeletonizers,
Japanese Beetles, Leafhoppers, Pacific Mites, Rose Chafers: For Grape Berry Moths,
apply as a post-bloom cover spray and repeat 10 days later; make third and fourth
applications at 10 day intervals if necessary.
Do not apply within 14 days of harvest.
i
NOTE: The California Department of Agriculture has set a 5-day reentry interval
for Diazinon R on grapes. Five da:'s should lap;e between the time of application
and the time a worker may enter the field to enage in any activity requiring
substantial contact with treated foliage. When a mixture of two or more organic
phosphate pestiCides are appli£d in combination, the interv31 should be prolonged
by adding to the largest applicable interval an additional 50% of that interval.
STRAWBERRIES: Aphids, Flea Bep.tles, Spittleburgs, Strawberry Leaf BeetJ.es,. Straw
berry Leaf Rollers, Strawbery Weevils, Two-Spotted Mites: Do not app).y" within
5 days of harvest.
VEGETABLE INSECTS:
For the control of the insects on the following crops, use 2-1/2 qts. per acre
in sufficient water fOl thorough coverage. Begin treatment at first sign of
insect infestation and repeat at 7-10 day intervals as infestation waraus.
. . • . -
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GJ.J.. ~ PYYlS .357 ~
BROCCOLI: Aphids, Imported Cabbageworms, Diamondback Moths, Flea Beetles: Do
not apply within 14 days of harvest.
CABBAGE: Aphids. Imported Cabbageworms, Diamondback Moths, Flea Beetles: Do
not apply within 7 days of harvest.
CAULIFLOWER: Aphids, Imported Cabbageworms, Diamondback Moths, Flea Beetles:
Do not apply within 7 days of harvest.
CARROTS: Aphids, Leafhoppers: Do not apply within 10 days of harvest or 14 days
if tops are used for food or feed.
COLLARDS: Aphids. Corn Earworms, Diamondback Moths. Flea Beetles, Harlequin
Cabbage Bugs, Imported Cabbageworms: Do not apply within 14 days Df harvest.
CORN: Fall Armyworms, Flea Beetles. Grasshoppers, Japanese Beetles. Rose Chafers:
Do not apply within 7 days of harvest. Do not feed treated corn to livestock.
Do not apply tc corn during the pollen shed period.
CUMCLERS: Apl ids, Cucumber Beetles, Serpentine Leaf Miners, Thrips: Do not
apply within 7 ays of harvest.
KALE: Aphids, Corn Earworms, Diamondback Moths, Flea Beetles. Harlequin Cabbage
Bugs: Do not apply within 14 days of harvest.
LETTUCE: Aphids, Dipterous Leaf Miners. Leafhoppers: Do not apply within
14 days of harvest.
MELONS (Cantaloupes, Muskmelons, Watermelons): Aphids. Cucumber Beetles, Leaf
hoppers, Melon Worms, Mites, Serpentine Leaf Miners, Thrips: Do not apply
within 3 days of harvest.
PEAS (SUCCULENT VARIETIES ONLY): Aphids, Pea Weevils: Do not apply within 7 days
of harvest. Do not graze or feed treated peas vines or pea hay to livestock.
Foliar application to peas: Do not apply if the crop or weeds in the treatment
area are in bloom.
POTATOES: Aphids, Banded Cucumber Beetles, Blister Beetles, Colorado Potato
Eeetles, Dipterous Leaf Miners, Flea Beetles, Leafhoppers, Southern Armyworms:
Do not apply within 35 days of harvest.
Note: Do not apply to commercially grown potatoes which will be hand-harvested.
Radishes: Aphids. Dipterous Leaf Miners, Flea Beetles: Do not apply within 10
days of harvest.
i
SQUASH (Summer and Winter):
Vine Borers: Do not apply
10 days of harvest.
Aphids. Cucumber Beetles, Leafhoppers, Mites, Squash
to winter squash within 3 days or summer squash within
TOMATOES: Aphids. Blister Beetles, Dipterous Leaf Miners. Fall Armyworms, Flea
Beetles, Japanese Beetles. Tomato Fruitworms: Do not apply within 1 day of harest.
TURNIPS: Aphids, Dipterous Leaf Miners, Flea Beetles: Do not apply withiq 10 days
of harvest or 14 days if tops are to be used as food 0r feed. • .
• ••••• • •• • •
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Pm..s 357~~.
CONDITIONS OF SALE LIMITED WARRANTY
AND LIMITATIONS OF LIABILITY AND REMEDIES
The directions on this label are believed to be reliable and should be
followed carefully. Insufficient control of pests and/or injury to the
crop to which the product is applied may result from the OCCurrence of
extraordinary or unusual weather conditions, the failure to follow the
label directions, or good application practices, all of which are beyond
the control of Helena (the "Company") or seller. In addition, failure to
follow label directions may cause injury to crops, animals, man or the
environment. The Company warrants that this product conforms to the
chemical description on the label and is reasonably fit for the purpose
referred to in the directions for use subject to the factors noted above
which are beyond the control of the Company. The Company makes no other
warranties or representations of any kind, express or implied, concerning
the product, including no implied warranty of merchantibility Or fitness
for any particular purpose, and no such warranty shall be implied by law.
The exclusive remedy against the Company for any cause of action relating to
the handling or use of this product is a claim for damage and in no event
shall damages or any other recovery of any kind against the Company
exceed the price of the product which causes the alleged loss, damage,
injury, or other claim. The Company shall not be liable and any and all
claims against the Company are waived fo~ special, indirect, incidental, or
consequential damages or expense of any nature, including, but not limited
to, loss of profits or income.
The Company and the seller offer this product and the buyer and user accept
it, Subject to the foregoing conditions of sale and limitation of warranty,
liability and remedies.
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