Dockerfile: self-contained image with corpus + Chroma + BM25 baked in. Drawbar's compose pulls + runs without volume mounts. Built from sources.json (labels schema), PRODUCT_NAME=crop_chem by default, HYBRID_SEARCH=true (always-on for production quality). RERANK_URL + OLLAMA_URL get set at compose time. .gitea/workflows/refresh.yml: monthly cron (1st @ 06:00 UTC) does full scrape → reindex → image push. Scrapes Bayer (~30 min) + EPA PPLS row-crop filtered (~7h). Skips reindex+push if no corpus diff. Tags pushed: :latest, :<sha12>, :corpus-<YYYY.MM.DD>. .gitea/workflows/image-only.yml: on-demand or auto on code-only pushes to main (paths: docs_mcp/, rag/, scrape/, requirements.txt, Dockerfile, sources.json). Reindexes from committed corpus, builds image, pushes. ~10 min vs ~9h full refresh. .gitignore: corpus/ now COMMITTED (4,159 labels, 265 MB of .md + sidecars). Lets image-only.yml rebuild indexes without re-scraping. chroma/ + bm25/ still gitignored (regenerable binary indexes). .dockerignore: drops venv, eval results, PLAN/README/CLAUDE.md, deploy/, .git/ — keeps the image lean. corpus + chroma + bm25 explicitly NOT in dockerignore (those go INTO the image). Co-Authored-By: Claude Opus 4.7 (1M context) <noreply@anthropic.com>
20 KiB
PROPANIL 80 EDF
- EPA Reg No: 9779-338
- Registrant: WINFIELD SOLUTIONS, LLC
- Signal word: Caution
- Active ingredients: Propanil (80%)
- Label accepted: 1996-05-14
- Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/009779-00338-19960514.pdf
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PROPANIL OEDF
For post-emergence control of weeds in rice and small grains
ACTIVE INGREDIENT
Propanil (3 ',4 '-Oichloropropionanilide) . . . . . . .•...••...
INERT INGREDIENTS ..................•......•..•.•.........
Total
KEEP OUT 'OF REACH OF CHILDREN
CAUTION
STATEMENT OF PRACTiCAl. TREATMENT
IF Ifrl EYES: Rush eyes with plenty of water, Can a physician if irritation persists.
IF ON SKlN: Wash with pfenty of soap and water. Get medical attention if irritaUon persists.
80.0%
~
100.0%
IF INHALED: Remove
In EPA LeUer Dated
MAY ! 4 1996 Ei')'('p'st:No. 9779-A~-13
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L 95.ictim to fresh air. If not breathing, give artificial respiration, preferably mouth-to-mouth. Gel medical attention.
PRECAUTIONARY STATEMENTS
CAUTION
HAZARDS TO HUMANS AND DOMESTIC ANIMALS
Causes eye irritation. Do not get in eyes, on skin, or on clothing, Wash thoroughly with soap and w:':Iter after handling. AVoid
breathing spray mist.
PERSONAL PROTECTIVE EQUIPMENT
Applicators and other handlel'S must wear !ongleeved shirt and long pants, waterproof gloves, s.hoes plus socks, and protective
eycwE'ar.
Discard dothing and other ab$orbent matenals that have been drenched or heavIly contaminated with this product's concentrate. Do
not reLJse them. Follow manufacturets instructions for cleanIng maintainfng PPE. It no such instructions for washables, use detergent
and hot water. Keep and wash PPE separately from other laun(hy,
When handlers use closed s.ystems, enclosed cabs, or aircran: tn a manner that meets the requirements listed in the Worker Protection
Standard (WPS) for agricultural pesticides [40 CFR 170.240 (d) (4.-6», the handler PPE requirements may be r(7duced or modified
as specified in the WPS .
USER SAFETY RECOMMENDATIONS
Us.er should wash hands. before eating, drinking, chewing gum, using tobacco or using the toilet. Remove clothing immediately
if pef.tjcide gets inside. Then wash thoroughly and put on clean clothing. Remove PPE immediately after handling thi$ product.
Wash the outside of gloves before removing, As soon as possible, wash thoroughly and change Into clean clothing . . _--'
Read Additional PRECAUnONAR1JilA.TEMENTS.
ACCEI'TEU
EPA Reg. No, 9779-
Manufactured For
RIVERSIDE/TERRA CORPORATION
P.O. Box 6000, Sioux City, Iowa 51'102-6000
R;Vf!}f'SJd" Serves AgriculturfJ, Agricultu,r;, Serves Everyon&.
, ILl . 881fi'
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ENVIRONMENTAL HAZARDS
This pesticide Is tox)c to fish. Drift and runoff from treated areas may be hazardous to aquatic organisms in neighbolinQ areas. 00
not apply directly to water, or to areas where surface water is present or to. intertidal areas below the mean high water mari<. Do not
c.ontaminate water ;,.,fum disposing or equipment washwaters.
DiRECTIONS FOR USE
It is a viof3;tion of Federal law to use this product in a manner inconsistent with itS labelln.g.
Do not apply this product in a way that wi" contact workers. or other persons, either dlrectty or through drift, Only protected handlers
may be in the area during applicatton. For any requirements. speclrlc to your State or TMbe. consult the agency responsible for
pesticide regulations.
Do not apply this product through any type of irrigation system.
Water drained from treated rice fields must not be used,to irrigate other crops or relea.sed within 112 mile upstream ofa potable water
intake in flowing water (i.e .• river, stream. etc.) or within 112 mile of a potable water intake in a standing body of water such as a Jake,
pond or reservoir. .
00 not drain water from treated fields Into areas where catfish farming is practiced.
Do not apply to fields. where commercial crayfish farming is practiced and do not drain water from treated fields into areas where
crayfish farming is practiced.
AGRICULTURAL USE REQUIREMENTS
Use this product enly in accordance Wfth its labeling and with the Worker Protection Standard. 40 CFR part 170. This Standard
contains requirements for the- protection of agricultural workers on farms, forests, nurseries, and greenhouses, and handlers of
agricultural pesticides, It contains requirements for training. decontamination, notification, and emergency assistance. It also
J:ontains specific ins.truct!ons and exceptions pertaining to the statements on this label about personal protective equipment
(PPE), and restncted-entry intervat. The requirements in !hi.s box only apply to uses of this product that are covered by the
Worker Protectio~ Standard.
Do not enter or allow worker entry into treated areas during the res.tricted enby interval (REI) of 24 hou($..
PPE required for earty entry to treated areas that i$ permitted under the Worker Protection Standc.ard and that Involves contact
with anything that has been treated, such as pfants. soil, or water, is: covera[ls, waterproof gloves. shoes plus. socks and
protective eyeweac
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STORAGE AND DISPOSAL
DO NOT CONTAMINATE WATER, FOOD, OR FEED BY STORAGE OR DISPOSAL
STORAGE
Store in a dry location away from children, animals, foods, feeds, seeds, or other agricultural chemicals. Handle in accordance with
information given under PRECAUTIONARY STATEMENTS. In the event of spillage or leakage, scrape up material and dispose of
in accordance with information given under DISPOSAL. Repackage and relabel useable product in a sound container. In case of
fire or other emergency, report at once by toll-free telephone to 800-424-9300,
DISPOSAL
PESTICIDE' DISPOSAL: Wastes resulting from the use of this product may be disposed of on $ite or at an approved waste dposal
facility .
CONTAINER DISPOSAL: Completely empty bag into application eqUipment. Then dispose of empty bag in a sanitary landfill or by
incineration, or, if allowed by state and toeal authorities, by burning. If bumed, stay out of smoke.
GENERAL INFORMATION
PROPANll eOEDF ii: a post-emergence herbicide fur the control of many grasses and broadleafweeds in rice fields, and 'lher,hnk
mixed with MCPA, on s.mall grains (s.ee the "Sma" Grain" section for specific crops), n may be applied by either ground or aefi'il.:.p,ray
eqUipment atter dilution and thorough agitation with water. PROPANllaOEOF is not a hormone-type herbiqkjf}.,.b,ul kilts suscerttible
plants by direct contact. Thorough spray coverage of weeds is necessary for best resutts. ) •
PROPANIt. 80EDF should be applied when weeds and grasses are small (See directions for use for spelfi,:cr.)s) Us~ oniy' on
rice fields which have been drained of flood water. Balds to be treated shOUld be inspected frequently befofethe applicaH?n of
PROPANIt. 80EDF to in$ur( that grass is at the proper stage of growth (1 to 3 leaf stage with an occasional;4 (ejJf plant).-' J J
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ATTENTION: Neyer apply PROPANll SCE-OF except as recommended on this Jiilbel because use in any other way rna .. ; re,$-Olt in
damage or injury to persons, animals, or crops, or other unintended consequences.
Do not apply to any crops other than rice, spring barley, durum or hard red spring wheat.
Before applying PROPANIL 8OEDF. make sure the spray equipment is properly calibrated to avoid over~ or under-trcatmcnt
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Do not apply PROPANIL 80EDF under windy conditions which will aUow drift to adjacent susceptible crops such as beans, soybeans.
cotton, satnower. cucurbits, vegetabs. orchards, and other sensitive crops, WInd velocity greater than 5 miles per hour wiH often
cause applications to be streaked and give less than maximum herbicidal control.
USE RESTRICTIONS ON RICE
To avoid excessiVe residu(ts at har .... est. do not apply after the end of iillering for the: rico variety being trea!e-d. Co not ::cppty more
than a maximum of six pounds active ingredient per acre in a single appHcatlon or exceed eight pounds of actiVe ingredient per acre
total dosage per ,season. Do Not Apl2.ti.£B.Ql aOEQF wtthin fourteen (14) day. before of after insecticide applications becau$e
serious da mage to rice may occur. Do Not Apptv ...f.B.Q£A..BIL 80EDF to rice fields that were planted wtth rice seed treated wjth bird
repellents containing methiocarb.
RICE
WEEDS CONTROLLED
"8amyardgrass (Watergrass)
Echi/1ochlOll crus-gaiN or Echinochloa colonum
8rachiaris
BrachilJria spp.
Crabgrass, large
Digitsrig sanguinllJis
Croton, wooly
Croton capitatus
Cuny Indigo
Aeschynomene v/rgfnica
Foxtail
Setaria spp,
Goosegrass
Eleusinct indica
Gulf cockspur
Echinochloa crus·pavonis
Hoorahgrass
Fimbristylis mifiaceae
Mexican weed
. Cllperonia t;lIstanaofofia
Paragrass
Panicum pupuTascens
Pigweed, redroot
Amaranthus retroflexus
Redweed
MeJochl. corchorifolia
Cuny Dock
Rumex crlspus
Spearhead
Rhynchospora corniculate
Tall Indigo or Coffee Bean (Hemp eesbania)
Sesbania e:ialtata
Texas Minet (Texas panicom)
Panicum t&xanum
Wtregrass (Spikerush)
Eleocharis spp.
"In Isolated instances, b1ot'lpe& of bamyardgra$S may develop that cannot be effectively controlled by propanil
alone. Where these biotypes are known or sU$pected to be pres.ent, and are found in a mixed weed population
in which Propanil is effectNe, a tank mixture of Propanil80EDF herbicide with either Pro~ or Bokl-ro*SEC
is recommended to control bamyardgr3ss (up to the 3 leaf stage). These tank mixtures may r.edl,.(ce crop
tolerance and are applied at the users r!sk. Read and observe ai1label directions betcrc IJsing. V'.Jhen tank
mixing, aJv.lays read aU indl .... idual manufacturer's labels. In interpreting all labels for tank mlxtIJres, the most
restrictivc situations must pply
The addition of spray additives such as crop oil concentrates and nanionic surfactants to Propanil 80EDF and
Propanil80EOF tank mixes can Improve corol of problem weeds. Riverside Activate Plus TU at 1 ~ 2 pints per
100 gallons of water or Rh'erside Prime oiF at 0.5 to 1.0 pint per acre are recommended. Addition of $pray
addltivcscan reduce crop tolerance to Propanll80EDF under certain conditions and sho-ukj always be considered,
Nways follow label directions. concerning use of surfactants and crop oils. for an products used in a tankmix with
Propanil80EDF.
Arrowhead
Sagittaria spp.
6ermudagrass
Cynodon dactylon
Cattail
Typha latifolia
Oucksalad
Heteranth"rlJ urifo.'n1
Rood levels. If necessary, nelda may be flushed prior to treatment to produce uniform grass genninatiOn. 'Ir:rielo'$~are l'lusti'e(f prior
to treatment, Rush in sufficient time so that grass and rice are growing vigorously at time of treatment. Wate'r .i'ludld be drainea'from
ooids before spraying so that grasses and weeds are futty exposed to the spray.pp_,
WEEDS NOT CONTROlED
Johnsongrasa
Sorghum halepense
Nutgrass
Cyperus spp.
Red Rice
Oryza $lItiVa
Sprangletop
Leptoch/oa spp
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Rice fields should be we-t! prepared and free of large clods to obtain unlfonn germination of grasses and weedS. and insu!'s
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PROPANIL eOEDf acts only on grasses and weeds which have already germinated. (Maximum activity u!.uaUy is not apparent until
5 to 7 days af.er application.) To prevent more weeds from germinating after treatment, fields should be ftooded within 24 hours after
spraying, or as soon as possible al'ter 24 hQurs. Flooding after spraying win improve the grass control after PROPANIL SOEDF
treatment. In eases where nooding of the field would not be complete wrthin seven days or tess after application of PROPANIL SOEDF,
it is best to treat a. portion of the field, floed that treated portion, and thon treat the remaindr. This wilf heIRPJv~=!t~!!,statJon of
weeds and grasses. Hloher rates 5 - 7.5 Ibs. may be necessary on the remaInder since the grass wilt be more mature.
If the rice is too small to maintain a neod on the fleW, treatment should 00 delayed unbl rice Is large enough. The grass may then
be farge enough to require 5 - 7.5 Ib$. of PROPANll80EDF. Avoid treatment if rain threatens within 8 houR or If high winds may
cause uneven application c)r drift.
In case of unseasonably coofweather, higher rates (5 - 7.5IbaJacre) of PROPANIL 8O€DF may be necessary. The number of leaves
of barnyard or watergrass determine the til'llt' and amount of PROPANfL 80EDF to spray, regardless of the size of the rice.
The temperature a few days before and after applying PROPANll 80EDF herbicide has an important bearing on the weed kimng
activity. The actiVity increase .. 3S dally maximum temperature'S increase above 75°F and decreases as the daily maximum
temperatures decline below 7SoF. 00 not apply PROPANIL 8OEOF herbicide when ma)('nnum temperatures have been or are
expee1:ed to stay below 6S
G
F or to go -above 100. low temperaruce at Ume of application is not 90 important as long aa it warms
up later during the day.
The grower should inspect fields frequently to determine p.roper time of application. The ideal application time is when most
bamyardgras8 has one to three leaves, with only an occasional plant having four leaves. During drought conditions grasses may reach
the three leaf stage while still quite short or stunted, so special attention to stage of growth is necessary In those situations to avoid
grasses becoming foo mature for be$t resWts.
Apply 3.75 ~ 5.0 Ibs. of PROPANll 80EDF per acre when most grass has reached the one to three feaf stage, Use 5.0 - 7.5Ibs. of
PROPANIL 80EDF per acre ifgrasscs are targer, with most in the four to six leaf stage. Mix PROPANll80EDFthoroughly with water
for spraying, w:.ing vigorous. mechanical agitation. For AERIAL APPLICATION dilute the proper amount of PROPANIL SOEDF with
10 to 12 gallons of water per acre If humidities are low, increse to 12 to 15 gallons of water per acre. For GROUND EQUIPMENT
dilute the prl)per afnollnt of ?ROPMIL 80EOF with 15 to 25 gallons of water per acre. Lesser amounts of water onli3n give inadeqtlate
coverage and may cause poor resutts.
If fields eannot be completely drained $0 that all of the grass is exposed, a higher dosage of PROPANIL 80EDF (5 ~ 7.5IbsJacre)
must be used,
NOTE: VVhcn PROPANfL 80EDF is. applied, especially after the fourth Icarstage of growth aftho rice, under some conditions, visible
leaf injury on rice may result However, the rice pl-dnts quick~:I outgrow such injur/ when caused by the later applications.
USE IN CALIFORNIA ONLY 1fJhere rice fields are not completely drained.
To control watcrgrass, appy PROPANll 80EDF 30 to 45 days after planting, before rice is fulJ tiller-cd, ..... 'hen watergrass extends 6
to a inches above water surface. If rice has a deep ncod, water leve! may be lowered to 3-4 inches over highest part of field to expose
6-8 inches of water grass. ('M"1en lowering water level, do so slowly to avoid pulling down rice plants.) Use 5 Ibs. pe( acre .f mostgrnss
has developed 3-5 leaves, ue 6.25 Ibs. if most gra&s has 5-6 leaves, and u'Se 7.5Ibs. per acre if most gran has 7 or more leaves.
Apply in no less than 10-12 gallons of water. using a medium-fine spray. If higher water level is desired after treating, refiooding may
be &tarted 12 hours afte( treatment
USE RESTRICTIONS ON SMALL GRAINS
If another herbicide is required, a 3-day interval should be allowed,between the application of a PropaniVMCPA combination and the
other herbiCide.
Grain crops that hive been or will be treated with PropaniVMCPA combination should not be treated with carbamate insecticid"!'\ '1' Ich
as carbaryl (Sevirf), mettlOmyl (Lannate-,,), or organophosphates (methyl paratl'lion, Guthiorf) or severe Injury or kill may 'r"'I·tt" If
iii foliar insecticide is nec-es.sary, malathion can be safely applied 14 days before or after treatment.
Do not spray a PropanillMCPA tank miX on spring bav. dUruJ'Th or hard..J:ed spring wheat [fthe field was te.a!e.d.e preylous year
with soU-applied systemic organophosphes (Counte?, Dfsystorf';'Thimer") or that has been treated at ptanng t:nK.:with $o.iI,appld
s.ystemic insecticides (Oisyston, Furadart, Thimet). , • , , , , " . , '
Do not mix or apply a PropaniVMCPA combination with any other pesticide, spray adjuvant or with furtilizer except as s'1ecifipa!Jy
recommended on this label. . , " ,
Do not graze treated crop or cut rof green chop feed.
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SMALL GRAINS
(Hard Red Spring VVheat, Durum Wheat. and Spring Barley in North Dakota. South Dakota, Minnesota, and Montana)
WEEDS CONTROLLED
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Weed Controlled Seedling Stage·
Pigeongrass 1 to 3 leaf
Foxtail, green (Setaria viridis) 1 to 3 Ie.f
Foxtail, yellow (Setaria Iete&Cens) 1 to 4 leaf
Buckwheat, wild (Potygonum conYoivulus) 1 to 4 lea'f
Kochia ..... (Kochfa scoparia) 1 to 4 leaf
Lambsquarters, common (Chenopodium album) 1 to 4 leaf
Mustard, wild (Brasslc:a kaber) 1 to 4 leaf
Pigweed, prostrate (Amaranthus bntoides) 1 to 4 leaf
Pigweed, redroot (Amaranthus retrollexus) 1 to 4 leaf
"'Refers to weed seedling stages for control. Pigeongrass greater than the 3 leaf stage or listed broadleat weeds beyond the 4 $eaf
stage will not be controlled.
""SuppreMion ~ may cause spotting, stunting or death of kochia not exceeding the 4 leaf stage.
A Propana 80EDFIMCPA tani< mix is recommended for control of susceptible weed seedlings when applied as a single post
emergence application at the rate of 1.2-1.42 Ibs. Propantl80EDF plus g..11 oz. of either MCPA LV Eeter or SEE® MCPA LV Ester
per acre {3.7Ibs. af. per gallon). The lower rate shoukl be applied when weed eeedlings are growing under favorable s.oil moisture
condftions. The higher rates are recommended when heavy weed pressure is present or less than favorable soil moisture conditions
exist. Do not apply when soil moisture levels are deeper than 1.5 inches from the soil surface and actNe plant growth stops.
The addition of a crop oil concentrate such as Riverside Prime Oil at a rate of 1 pint per acre to Propanil 80EDF is required to
achieve consistent weed control.
A PropaniliMCPA tank mix is most eRective in controJnng foxtail if spray applications are made when the majortty orthe emerged foxtail
are in the 2 to 3 reaf stage. Effectiveness declines rapidly as the 4th leaf of the foxtail begins to emerge. Fields should be checked
frequently for emerging foxtait starting 2 to 2 112 weeks after planting.
This tank mi:< may causa temporary yetlowing or tip browning to the leaves of the grain crop 2 to 5 days. after application. The effects
are temporary and usually win disappear 10 to 14 days after application. New leaves win have normal green color, Application under
adverse growing condition$ may result in greater crop injury and slower recovery. Do not apply ir frO$t Is expected within 24 hours
or when temperatures are above 85
1l
F, especfalty with drying Winds.
AppHcations should be made only to actively growing (healthy) grain crops in the seedling stages recommended below:
Crop Seedling Stage
Hard Red Spring Wheat 2 to 5 leaf
Durum Wheat 2 to 4 leaf
Spring Baney 2 to 4 leaf
For ground application use a minimum of 10 gallons of water per acre and for aerial appUcation usc 5 gallons. of water per acre.
Pro......fl' • Counter and Thimct are trademarks of American Cyanamid Company
Bolero is a trademark of Kumiai Chemical Industry Co., Ltd.
Activate Plus TV and Prime Oi(lP are trademarks of Terra International. Inc.
Sevin'; Is a trademark of Rhone Poulenc, Inc.
lannafe® fs a tradema~ of E.!. duPont de Nemous & Co.
Guthion: and Disyston are trademark$ of Bayer Corp,
Furadan !s a trademar1< of FMC Corp.
NOTICE; SeJlerwarrants that the productconkmns to its chemical descnptionand is reasonably fit rorthe purp;,,:stated Oli ~~ ~t.·el
when used in accordance with directions under normal conditions of use, but neither this warranty nor "ny other warranty of
merchantability or fitnes.s for a parUcular purpose, express or implied, extends to the use of this product contrarY i& labei instructions,
or under abnormal condrtions, or under conditions not reasonably foreseeable to Seller, and Buyer assumes the risk of any ~u('.h',~~e.