crop-chem-docs/corpus/epa_ppls/352-406.md

DUPONT EPN 3 + 3 EMULSIFIABLE CONCENTRATE

• EPA Reg No: 352-406
• Registrant: CORTEVA AGRISCIENCE, LLC
• Signal word: Danger
• Active ingredients: O-Ethyl O-(p-nitrophenyl) phenylphosphonothioate (31.4%); Methyl parathion (31.4%); Xylene range aromatic solvent (26.14%)
• Label accepted: 1983-11-09
• Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/000352-00406-19831109.pdf

---

N .. Nl USELY WHENEARING TfOllOWING -"") PROT ClIVE EQ '''ENT AN CLOTHING WUI cleln, elvJ if",ty. II IUI,IIUbbel t n. ultlplool Ills. COIl. h.llubbtl boolS 0' 'I,ottbll OVIIlI\oei Illd ulety eo lei .hen h,n lit. rr. ... n' 01 I pI.,n, 11'1" ploducl 'iI'UI I Hbctdt 'UPlII!O' p:IIIIJ 'PIIIOW brtht M,"J!& nIGfurr.en1.n4 .Itll .ldm,/l.slr,1>o1l (lolI!:tll, 11'1.:: U S BfJlt.u 01 M,nts),"d tilt M.llOII,! "'sM:,-(t 01 OcCujuoOlI, S"n .n Hu'l\ ..q WORK SAFETY RULES Not sJigui(l 1101 U$lit 11\ m'IJIIlln IoI~'II: optl.loon Kup. mm.l, 'rod .0 unpl'i)!tclrl Pt'loOIlS oul 01 optllbonlilltn dUlin, I'ulmtnlln~ .h.;e Ihtrt Ii (lllIit' cl dr,,. Do IIOt 'ub'rt' 01 moulh .,Ih h'II~' If ,OU le,1 s>ck'" In, ." STOP .(lfk 'II~ ,Uhelp",hI',OlJ Cal. phJ$lCI'II. C.ft:C 0' I'.osptUl 'trl/!',r4r ... -ty Elpl.,n 11'1.1 Iht ",,"1 hn bun uposed 10 [PN·M,U'I,I'.IIthiOlI combn.bon IfId dtscflbe I'\iscor~""on Aftt' h,sl.", II "1tnluSIJltmfnl at "Kbctl T,ulllltnl, .bovtl'l'Id II • dOCIOI !lnnol cemt. I.kt nctllll 10 cnl( 01 hOSP;111 II'OllAll! BelOit 'tIllDOIII lmrs .• 'Ihtl\tl!l.tlh SCJP Ind .,Itl A) •• U .un n.nds.llct.1Id "IM .ith $O.Ip .nd .,ter belert Il'IlO1,n2. tll,n, 01 dr;n\lnl ,nUWORl.lIk, olf.ll clOlhu.nd Sl\oel 51-",." 101$.111 to.p .nd -alit! Wtar only (Iun clolhn !It II lta'Mi job Do nol lour conl.nuralf\S ClOlhll1l WISh PI4)ltc:u cloth,"~ In;! preltel"t Iql/lptntnl .... h toap .nd •• ttr .flt! IICh us.t Rtll.'>lltOi ,Ilo;,rld ~ cit.ned .rod MIn "pllttil ICcordlnllO lI'11trIKbonl IIlcludtd .,,11 Itspol,lliI NOTICE OF WARRANTY --------, • Ponl u"'flls ,11,1 :1111 plodlltlnl'lelms l~ I/It (.tm.cI!dU(f.pto()(l en Ihe lJt-tllhfltQl.nd IS IU!.OIIlbIy 101 lor I/It PUIp:ls.tS '1IIt;:l 011 Slit" libel Cl'Iy .htn lise.:! ,n '((01.:1)11(' a,11\ Lt d'ff(I'OII1 IlMeI noUII! ul.econ,UoOll5-1t lllIIIposS-t;:t lot/.m>n.le JII "skllll"ertnlt.,nsx,)ltd •. !hlt uSt GIl IlL" PlodLICL (IOpIlIIUIJ.II'.tIft(ot<:ns.« ctMI ul!oI:t!nde;:l cons.tqenc:u mIl ItSU! t!«.us.t of SlICh Iltlol'l " uIIl-.er c~,ton1. Pfts.t!)(f ()I o:tt. mltt""s. 01 (lit D".ntl oJ uw 01 aoCiI~ all 01 .1I.oeb II, butll"4 ~., tl:'fl\ld 01 G-JVc.n\ In 1'10 tl~ 1I)' (lll~;\ b! Ht>t II:!! !~~,~~~:it :!Iu~~~~~~ :!e',i1"~~~I.fJ.I£S ~~~IIi:R;I~~~f :WcfH't,ecl'}~ OR fITNESS fOR A PA:.IICUL.lR PuRPOSE NOR ANY OIliER [lPR(SS OR IIolPlIEO WJ.RFU.NT't UCEPI AS STATED AlIOH A DIRECTIONS FOR USE lI.s, 'tlobwn C1l ftderlili. 10 ust I~.S j)/oduct ,n I manntl ,nconS>ltenl .,lh ,ts bw1,n, Du '0111 (PM 3.3Ins.tc!>CoCIt uld be stdonJr,nlCCOldlnce .'lhlfCC/!'.lI'tndlltOII5011t'stlbtl 01111 stpml' liubilShtd O Ponl ftcOtl"IIIUldlbollS hl,l.b!t IhrOu,n .:<11 dulus Du 'onl ri' nol be luponllblt 101 !.:1m, 01 dlllliin ruull'lIllrl)fOl Ult oilM j)/ooucl ,n In, maMer not S!>Kllleally It(ommtnd'td br Ov Po"1 USfI "Sumes IU ,.sk, ",oolled •. 11'1 s;,o(1'I ? I'IONtcomrnftdN Ust. SPUl 'IE,WIIOt-f,n SPill link ""10 1121n el.ll,' .1M Int prO'lllmO\lnt I (PII)·3. al'1ll., thtn flO tilt IP", link .1\1'1 .,Ifl .11,', st," '1,11\ln, Conl,nllt 10 'l,lIIt .:"l,!t UI,nl .... PUCAIIO.-EPM 3"3 :'UJ be ,ppld by I.ound 01 WIIIIPptubon Wlrtn mlk,nl !'ou"" Ippbclboft. ,,,pJy tht Itcommtndfd dOSli! In ,llrul 311110ns OI.Jltl Ptllt/t. us,n iu "mnl .aler 10 I"'lood conllet or the 100"£t rOt Uli.s lP;k'uoft. \IW 3 to \0 Ilkn~ {II .,ttl Ott lUe Wire" I dOSJlt WItt IS "ytn. UI.e tht Ioatl uln on 11111'. younl lnISOl.l\eltlnsedlnlfSl'OOn is ,l'It use ttle billie' nln M IlIlt 01 nUlu" pllnls or .hUt Ins.tel rnlUl,loon IS hthy ...:: UI'fSlAU'E".nlll I I .. ltd ..... .UlAU"'Q"'1 ·b •• 110 c "OSlllfAua AIfA Ibtlvd iWI SlrtItenrru.-fIStetoon .."p , J ,,""0, 0' 'ftlled IIw T.u,I'DUI£ rOt conOI-Ih.s product mlJ til IIn\ m,u1J .'thG"eclon- u·.rulld.18 "Ect. hnda'- "Spt. DuPonIUnnllt. 01 OuPonl hnn,lt'l When USrnlllltl.e j)/coCIucts 1fI11,n. 11111. obstn •• n mllittons llId p'KI",bon: .hlCh .pptu on the Ilbe:, Use Ihe nit tfCOll'lmend'\oOns 1M IppllC.lIon timlllil11)1 Ih' Insect P'st ,1111 IS 10 be (onl'ollej n 1IIItd on Ihts.t IJbels 11.'. ___ u.c....t., """"" .. , ... , ...... w .. 1 __ U1l\o. ... ,' l " .... ,"'''' ....... ''''t.''''''w:.t; ...... ~ .... ,,' ..: ........ \ ; 1 ((on (h.;-ihf.:;I-{; i; . ., ! _ ...... __ • ___ 04& _____ .. ____________________________ _ [BESl AVAILABLE COPY I , sl'rc IMI): lABEL 10' ""_'GER, S1JLL & CR' RESTRICTI For retail sale to and use only by supervision and only for those use: <[UPON)) INSECTICIDE E 1 Gallon Contains 3 Lb by Isomer Specl ACTIVE INGREDIENTS .... ___ . __ . _ ... EPN (O-Ethyl O{p-nltrophenylll Methyl Paralhion (O,O-Dimethyl (Related Comp Xylene Range Aromatic Solvent. INERT INGREDIENTS ......... ___ .. .. (UI" IoAN:;tofr;;o'r I '7-7 ~ STATEMENT OF PRII,crICII,L 11 1.,1I0w.d: Call a DhSIClan Of Poison ConI,oI C waltl and Induce varn,"ng by touching back 01 I~ 'Iom,trllg or g,e an1",ng by moulh to an unconscio If Inhl!ecI: R",mo-."e "om uD(lsu'e Ind hl\1l pllie paloent is roOt bleath,ng. slart .rtlfici.1 lespirllion tblng by mOUln 10 an unconsCIOUS pe'SOI'I. In ea •• 01 conllC: ... ash slltn .ilh plenty 01 SOIp .uter fOI 15 m,nules and gel mtdiCl1 ,1IIlention; " CIO!funlil belore It use ATROPINE IS AN ANTIDOTE-SEEX ME AT ONCE IN All CASES OF SUSPfCl " .'Inln, '7mplom. Ippdt {see WARNING "MI ...... _ IJ-l/3 NET E. I. DU PONT DE NEMOURS & CO- I

'. " " RATE OF EPN 3+3 (tl'J."OI"'IIP)) Id Itll!"] (1 ... ", :r.I. Cc<'1lnf .1.:"0:1 c.:, ~.ocl.et'ClI {ldl,t!lI! Ibo; s.:vlhefiltlfl Co.II Softr lute.", I) I" ,d Ctl'lf" 1m .~tll 10'0t of I't pllN} ~,.t f;l-;:'II';I­ RIPfllal S III 10 tlll·~ltrrl!1 Ii rl'!~= 00 fII~' .,1""" U !l11l rf JI"'II ~~ ~~~'=Wf,::t~':::;f-;--' I~) I I.''I:!!"';I: !:::':::"'';~'11'1 "II "''".~~~~~~~~~;===~I~'==l ~~r::;:; .::!!~~~~.:: ~':-.:"!I" :': .. \ DI,u.n.(;rou...s &:Ull. "-f'ot., I' p!.['; (eo"'If'O"J"-.:!1 ':"tfo,rr,:;;!r S.il' l1r. 'I~'twor .. '.tlll»o'lt<lll.:f ~ o.b<nt Ct.o</!I. GJrCt" l'rfh,"'". 1~~tKj)/r.t.fd J.:rl-I }I., St..'1lbu£l. Vtlytlbnll tmrPO1I 'rj,. 8Io1iU 8uIl!.lIu-'CI' Bt,-; -:=-!­ T-ol00rte<l $oodtl ,,"'It BEST ~mABLE COpy I'i-CJ!.U:\ I.,\JEL 10\ AClUAL SIZE. en l\ctual label, "It';:;!.}:.. sma (, (ROSSBCl."ES & roIS(N" are printed Red. RESTRICTED USE PESTICIDE For retail sale to and use only by Certified Applicators or persons under their direct supervision and only for those uses covered by the Certified Applicator's certification, ([U PONj) EPN 3+3 INSECTICIDE EMULSIFIABLE CONCENTRAT 1 Gallon Contains 3 Lbs. EPN and 2,85 Lbs, Methyl Parathion by Isomer Specific AOAC Methods 6.400/6,405 ACTIVE INGREDIENTS., .. ,.", .. ".""" """"""""""".""",.""."", 88,94% EPN «('·Ethyl O·[p,nitrophenyl] phonylphosphonothloate) ",""',','" 31,40% Methyl Parathion (O,O,Dimethyl O'p'nitrophenyl phosphorothioate) ,,' . , 29,83% (Related Compounds) " " ." " " " " " " , " "" "" 1.57% Xylene Range Aromatic Solvent ............................. , ......... 26.14% INERT INGREDIENTS ...... "., ... ,"""""""",.,"', .. ,""",.,"""',.,'" 11,06% IUh, I I ----~~~-------- r. eep out of reach of children DANGER .. POISON r; -7 :s: e- 7 , STATEMENT OF PRACTICAL TREATMENT It Iw;alla_ad: Call oS phySIC',)" at POIVYI Control Cenler. Onnk 1 or 2 ,:asses 01 .. attt and I/'Iduce vomiting b~ touch,ng back of throat 'fIllh "flger. 00 not ,nduce vom,long or i<V1i.' an)1h'ng bl ITlDOlh 10 an unton"c'ous pe'n II Inhaled: RerTlO\li.' Iro,,", e.oosu'lI.' and have palu!!II' he (lo-.. n and It",ep qUllel II paloenl .s not breathing start .1<:..1"." reSPIration ImmedIately Never gIVe any­ Ir!'flg br t'T'OUlh 10 olin unconc',"'s petsOon In cue 01 contacl: .... ah Sln ... ·\h plenlr 01 soap and ... aler. 'Of eyes. fluSh .,Ih .... !('r 101 15- mmutE'S and gel "'('(hcal allel"'Gn; remove and wash c()fIlamlnaled Clotl',ng herete re use g ('" _ •• "0 l~' £010 STORAGE AND DISPOSAL PRECAUTIC HAZAR:>S DOME DANGER MAY 8E FATAL IF. INHALED. EXTREMt TACT. RAPIDLY A8 'EATED UPOSURE INCREASINGLY HA; Do not br.. Do not lei in _ WARNING $YMPTO poisoning produces Msterase aclwily blurred vision. head discomfort in the d' in" slow pulse. mu' NOT' TREATMENT -Atro trll!alment. Adminis' inlravlI!nouslyevery zalion is achill!Ved. palill!nl recovers. Ar bII! necessary. AIIQYIo nll!stll!rasll! inhibitor may bII! used as rll!(. sullatll! Irll!alment. ( ENVIRON Th,s producl is to., 00 not apply dIrK runoH ,s. hkely 10 0 condrtion!> favor dn taminale WOller by ( of wastes.. ! This produe IS. hIl' AtROPINE IS AN ANTIOOTE-SEEK J.~EDlrAl AnENTlDN AT ONCE IN All CASES or SUSPECTEO POISONING " .unin, tJmploml appur t ('(' WARNING SYMPTOMS), ,.:1 mecheal attentIon n apphcatlon. not I eedures. I/J '1 acl,velyvlSI '"I the i 10 cOlI\c,d wllh oe L-____________ __ NET 5 GALLONS P, .. , ....... us. ....,.,....., _ /0,1/3 E, I. DU PONT DE NEMOURS & CO, (INC,), BIOCHEMICALS DEPARTMENT, WILMINGTON, DE PHYSICAL Ar. Keep away from ht­ conlainer clos.ed l

~ , , .c N ," '., ", .lU\L SIZE. ()\ .·\ctulI 1.ll1d. OCES & JUtSO,-.;:" arc rnntc RCt.1. , USE PESTICIDE tilied Applicators or persons under their direct vered by the Certified Applicator's certification, • • • PN 3+3 PRECAUTIONARY STATEMENTS HAZARDS TO HUMANS AND DOMESTIC ANIMALS DANGER :I POISON MAY BE fATAL IF SWALLOWED. POISONOUS IF INHALED. EXTREMElY HAZARDOUS BY SKIN CON. TACT RAPIDLY ABSORBED THROUGH SkiN. RE. PUlEO EXPOSURE MAY. WITHOUT SYMPTOMS. BE INCREASINGLY HAlARDOUS Do nol brNlhe volpor or spr.J1 misl. ULSIFIABLE CONCENTRATE PN and 2,85 Lbs, Methyl Parathion \OAC Methods 6,400/6.405 ? ---? Do no: !tel i" e)-'l5. on skin. or 0" clolhing. WARNING SYMPTOMS - EPU d·1j metn" p,l'ath,on PO ,yo,,'i1. P',.1" : .... ' "'1",'I iIS("'ilt('(1 WIth ant.chot, ne~~('lai' a:! .• I; ... -..,,, mil) "1C!'H1e .... ea ... nes t,,"f';j .." t· .. Il~~pE' r,l.Jed. bdomonal(ril""ps {l,S 7C"mlolt .t', :., '1',',1 {:nsl"( I ,0tI 01 pup'IS. ",",('al ong '., ... rc.'" ' •. ,', 't" 'f'<nO's .......................................... 88.94% rlphosphonolhioate) .............. 31.40% lUrophenyl phosphorolhioate) .... _ 29.83% Is).. ......... ....... 1.57% , ..•................ - ............. 26.140/0 ................................ _ ....... 11.060/0 ISON '<-7 JMENT )nnll 1 or 2 alassn 01 ~ ',n2er Do not Incr",ce on )'Ion and keep qUIet II lately. Neer gIVe any· :er. lor eyes. !lush ",,11'1 n.d wash contammaled mENtiON $ONING ----;j} --""':':":. STORAGE AND DISPOSAL tlN '()l use oj storage 11'1 or arculld It'e' hOme Do no' anlam,n,!e .. ale', !CIOd Of fee,;! 0) slOla,e Of ("SDUI DOM dumD­ "'g IS p'Chtlhed e .(,de. sJray .... " IlJ'(' (\r "nser water t I cannJ. tJp used a':e'I1''''i t label, '.II:'>l ...... "s\ t.t d,scosed 01 accor mil \0 ede'al or at'",oed Siale Dr edufes unde. Sub. I'lie C cl Ihe ReSOlJrce C ,ervaloOll a'lrj RtcO"ot.)' Act Do not relle conlaln(" '''P'e ',,,se (or eQu'alenl). DlH>Clul(,. ,a,nj Jj' .. we ot m a !.arlltaly iandl 11. CI b~ oth(,r aDD'oved 51alC and tOCdl pto ',~ IV . GALLONS r._ ... , • , BIOCHEMICALS DEPARTMENT, WILMINGTON, DE NOTE TO PHYSICIAN TR(ATMENT .'o!, ;,·w ,>"i't(' shoxo',", be UNI lor , .... '.".,! A:". ,. ~~ ... <t:-d!('d Ct-es. I 2 !O 2 () m ."tr., .. ":",,, ,'.P'. I::'" .1'lm',,.,ulesunt,'lullal' .... -.-'." ;a!'-" , d ".· ... ,1 ',',I,nll"" .llre-pon'lalocn unto! It,l' ['J',,,,: ,,":- ... ' ,-t,":'iI' 'e~n"JI'on C' O(),gel"l md1 • {' r .. ··.··.'-.·, ' ... N-. '"-tt>.,, ""pUSh'(':O ary (tlo'. r_I'!'" H(, .,.,' ~ , ....... !,I 'e(Q\er. IS aSSured 2 i>I.' mo!, t,·-, ut'_' .I~ ·f·;" ... ,! 1,-. uro;"em('nllt1 a:'cc,"(' lJll.,t' '·{'.ll",t·Ll r . r(,: tJe nl()<llh'lle ENVIRONMENTAL HAZARDS 1.--• ., ; . :..1 .• ,' ., l.. " '".,t, !.,'d'>. "nd other .... ](J:.le r,c "d al.l';, ,1,',', !. 10 "'A(" DJ not apply .... hp.(' 'lo'" ·I! ,I t' .• k .'i; ..... Do "O! .lrc-I)' oAhen "'ca:'"'e' co"d-: .. )', '4,·' -" t' "r.m ilre· 1'10',:1 .. " Do n:lt CO,'1 lafT""d:'" ... }' ••• I;. ""''''!I . (,,1" [,m(,n! Cf d'OOSill cl ... -.Ips 1 to. (",1.l;" ., h"I:' ", 1.1,,-,( to). l>e .... o:.p..)d IQd-'('cl <IN'''- II",, t, ",: "l-I') 'h 1·'odCI .... .rp bE't'!o,}.(, ,KI",·' ••. ~ """ I. ··.·.1I"'''''1.1 •• ,il/l ,n'" .1cpl.(at·r,·1s 10:> '- .. -.' • !'J ... P. . '. 1-. ,,' ''',n".rt"", he .1Chvllr PHYSICAL AND CHEMICAL HAZARDS j'PI) .loA1 ',:, ., '.",' "'d''''S 41'd "'"f'0 ILme K('(,l> t,)"!,j,"'" ,.<.: :.~ ...... ,,> ":!('IJ-I'~f' ~;>"I.raho" POISON

( 2. 3. 4. 5. 6. waterproof hood; a protectiv~ suit or coveralls of a lIon-permcClble, non-cloth material covering the body from ankles to wrists; lig.ltwpight f unlined J natural rubber boots at least mid-calf in lengch; full-face respirators are recommended; half-fae respirators and goggles are required. Aerial applicators in positive pressure cockpits and other applicators in comparable ground equipment with appropriate filters at all air intakes need not comply with these protective clothing requirements. uman flagger prohibited unless in totally enclosed vehicles. Do not apply this product whf:n weather conditions favor drift from treated areas. REErRY STATEME' - Do nt er.tcr treated areas for 48 hours unless appropriate protective clothing is worn. Because certaj.n states may require more restrictive reentry intervals for various crops tr.?ated with this product, consult you State Department of Agriculture for further information. Written or oral warnings must be given to workers who are expected to be in a treated area or in an area about to be treated with this product. When oral warnIngs are given, warnings shall be given in a language customarily understood by workers. Oral warnings must be given if there is reason to believe that written warr.ings cannot be understood by workers. Written (or oral) warnings must include the following information: "DANGER-POISON". Area treated with EPN 3+3 on (date of applicatin). Do not enter treated areas without appropriate protective clothing for 48 hours. If warning symptoms appear, refer to Statement of Practical Treatment on front pane] of label and seek medical attention at oncc. Do not apply to blooming cotton if hces are visiting the treatment area. Do not apply to corn durin~ the pollen-shed period if bees are visiting the treatment area. IA C C E i·'T-·'~ DI \ NOV 091983 Under the Federal Ir...eeticl:: ..... Fungicide. and Rodenllcido Ac~ I as amonded, for tho pesticide rogistered undo~-J. EPA Re •. No. .;>~ - Ob

7 •• 8. PELIGRO Precaucion al usuario: Si usted no lee ingles, no use esfe productc hast a que la etiqueta haya sido cxplicado ampliamcntc. STORAGE Store product in original rontaincr only, away from other pesticides, fertilizer, food t or feed. DISPOSAL Do not c0nta~inatc water, food, or feed by 5 t or age or disposal. Pesticide wastes arc acutely hazardous. Improper disposal of excess pesticide, spray mixture, or rinsatc is a violation of Federal Law. If these wastes cannot be disposed of by use according to label instructions, contact your State l-'estict.d!> or Environmental Control Agency. or the Hazardous aste RepresentativC' at the nearest EPA E2gional Office for guidance. Triple rinse (or equivalent) the container. Then offer for recycling or reconditioning, or pun(: ture and dispose of in a sanitary landfill, or, if allowed by state and local authorities. by burning. If b:J-rn{'d. stay out of sme>'\t.e. 9. Do not apply this product in sUlh a manner as to directly or through drift expos workers, other persons, or animals. Th(' area being treated must be vacated by unprotecu·d pprsons. 10. -:.'(1"0 L? </ This product is highly toxic to bees exposed to direct treatment or residues on blooming crops or weeds. Do not apply this product or allow it to drift to blooming crops or weeds ii, bc:es are visiting the treatment area.