Dockerfile: self-contained image with corpus + Chroma + BM25 baked in. Drawbar's compose pulls + runs without volume mounts. Built from sources.json (labels schema), PRODUCT_NAME=crop_chem by default, HYBRID_SEARCH=true (always-on for production quality). RERANK_URL + OLLAMA_URL get set at compose time. .gitea/workflows/refresh.yml: monthly cron (1st @ 06:00 UTC) does full scrape → reindex → image push. Scrapes Bayer (~30 min) + EPA PPLS row-crop filtered (~7h). Skips reindex+push if no corpus diff. Tags pushed: :latest, :<sha12>, :corpus-<YYYY.MM.DD>. .gitea/workflows/image-only.yml: on-demand or auto on code-only pushes to main (paths: docs_mcp/, rag/, scrape/, requirements.txt, Dockerfile, sources.json). Reindexes from committed corpus, builds image, pushes. ~10 min vs ~9h full refresh. .gitignore: corpus/ now COMMITTED (4,159 labels, 265 MB of .md + sidecars). Lets image-only.yml rebuild indexes without re-scraping. chroma/ + bm25/ still gitignored (regenerable binary indexes). .dockerignore: drops venv, eval results, PLAN/README/CLAUDE.md, deploy/, .git/ — keeps the image lean. corpus + chroma + bm25 explicitly NOT in dockerignore (those go INTO the image). Co-Authored-By: Claude Opus 4.7 (1M context) <noreply@anthropic.com>
39 KiB
NITRO SHIELD IV
- EPA Reg No: 1381-252
- Registrant: WINFIELD SOLUTIONS, LLC
- Signal word: Caution
- Active ingredients: Imidacloprid (40.7%)
- Label accepted: 2016-11-01
- Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/001381-00252-20161101.pdf
PRO^'^ November 1, 2016 Subject: Dear Ms. Mathias: Fas! Track Label Accepr.ab!-? OFFICE OF CHEMICAL SAFETY AND POLLUTION PREVENTION The amended label referred to above, submitted in connection with registration under the Federal Insecticide, Fungicide and Rodenticide Act, as amended, is acceptable. This approval does not affect any conditions that were previously imposed on this registration. You continue to be subject to existing conditions on your registration and any deadlines connected with them. Your release for shipment of the product constitutes acceptance of these conditions. If these conditions are not complied with, the registration will be subject to cancellation in accordance A stamped copy of your labeling is enclosed for your records. This labeling supersedes all previously accepted labeling. You must submit one copy of the final printed labeling before you release the product for shipment with the new labeling. In accordance with 40 CFR 152.130(c), you may distribute or sell this product under the previously approved labeling for 18 months from the date of this letter. After 18 months, you may only distribute or sell this product if it bears this new revised labeling or subsequently approved labeling. “To distribute or sell” is defined under FIFRA section 2(gg) and its implementing regulation at 40 CFR 152.3. Should you wish to add/retain a reference to the company’s website on your label, then please be aware that the website becomes labeling under the Federal Insecticide Fungicide and Rodenticide Act and is subject to review by the Agency. If the website is false or misleading, the product would be misbranded and unlawful to sell or distribute under FIFRA section 12(a)(1)(E). 40 CFR 156.10(a)(5) list examples of statements EPA may consider false or misleading. In addition, regardless of whether a website is referenced on your product’s label, claims made on the website may not substantially differ from those claims approved through the registration process. Therefore, should the Agency find or if it is brought to our attention that a website contains false or misleading statements or claims substantially differing from the EPA approved registration, the website will be referred to the EPA’s Office of Enforcement and Compliance. Label Amendment - Update gloves statement, add a product information section, and other small revisions Product Name: Nitro Shield IV EPA Registration Number: 1381-252 Application Date: 7/18/2016 Decision Number: 519585 Lisa Mathias Product Registration Specialist Winfield Solutions, LLC P.O. Box 64589, MS 5705 St. Paul, MN 55164 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY WASHINGTON, DC 20460/ A \ w
Sincerely, Enclosure with FIFRA section 6. If you have any questions, please contact Jacquelyn Herrick by phone at 703-347-0559, or via email at herrick.iacquelyn@epa.gov. Venus Eagle, Product Manager 01 Invertebrate and Vertebrate Branch 3 Registration Division (7505P) Office of Pesticide Programs Page 2 of 2 EPAReg. No. 1381-252 Decision No. 519585
ACCEPTED GROUP 4 INSECTICIDE 1381-252 Nitro Shield® IV Insecticide For Treatment Of Labeled Crop Seed If Swallowed: If Inhaled: NET CONTENTS: 2.5 GAL (9.46L) W inField 1/1024/6 1 EPA REG. NO. 1381-252 EPA EST. NO. [BAR CODE] [UNITY# __ [LOT #____ DISTRIBUTED BY; WINFIELD SOLUTIONS, LLC P.O. BOX 64589 ST. PAUL, MN 55164-0589 J J KEEP OUT OF REACH OF CHILDREN CAUTION ACTIVE INGREDIENTS: Imidacloprid: 1-[(6-Chloro-3-pyridinyl) methyl]-N-nitro-2-imidazolidinimine .... OTHER INGREDIENTS: .......... TOTAL . 40.7% , 5^3% 100.0% SEE BOOKLET FOR ADDITIONAL PRECAUTIONARY STATEMENTS, COMPLETE DIRECTIONS FOR USE, WARRANTY DISCLAIMER AND LIMITATION OF LIABILITY. Contains 4 lbs active per gallon (480 grams per liter) If On Skin or Clothing: FIRST AID _________________ Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by a poison control center or doctor. Do not give anything by mouth to an unconscious person.________ Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor for treatment advice._____ Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or doctor for further treatment advice. Have the product container or label with you when calling a poison control center or doctor or going for treatment. For additional information in case of medical emergency call toll free 1-877-424-7452. 11/1/2016 Under me Federal insecticide. Fungicide and Rodenikide Ad as amended, (or the peaticleJ* registered urder EPA Reg. No.
USER SAFETY RECOMMENDATIONS This product is to be used in liquid or slurry treaters only. Mix thoroughly before use or use the entire container at one time. Follow manufacturer’s instructions for cleaning/maintaining PRE. If no such instructions for washables exist use detergent and hot water. Keep and wash PRE separately from other laundry. Do not apply this product in a way that will contact workers or other persons, either directly or through drift. Only protected handlers may be in the area during application. For any requirements specific to your State or Tribe, consult the agency responsible for pesticide regulation. For use in commercial seed treatment facilities, with the exception of application to barley, borage, canola, cotton (delinted seed), crambe, field corn, flax, mustard seed, rapeseed, sorghum, sunflower, triticale, and wheat, which may be made either in a commercial seed treatment facility or as an end-use seed treatment on agricultural establishments at, or immediately before, planting. This product is toxic to wildlife and highly toxic to aquatic invertebrates. For terrestrial uses, do not apply directly to water, or to areas where surface water is present or to intertidal areas below the mean high water mark. Do not contaminate water when disposing of equipment washwaters. Cover or incorporate spilled treated seeds. PRECAUTIONARY STATEMENTS HAZARDS TO HUMANS AND DOMESTIC ANIMALS CAUTION; Harmful if swallowed, absorbed through skin or inhaled. Avoid breathing vapor or spray mist. Avoid contact with skin, eyes, or clothing. PERSONAL PROTECTIVE EQUIPMENT (PPE) Applicators and other handlers must wear:
- Long-sleeved shirt and long pants,
- Socks and shoes and
- Chemical-resistant gloves: barrier laminate, butyl rubber >14 mils, nitrile rubber >14 mils, neoprene rubber >14 mils, polyvinyl chloride (PVC) >14 mils, or Viton® >14 mils. ENVIRONMENTAL HAZARDS This product is highly toxic to bees exposed to direct treatment or residues on blooming crops or weeds. Do not apply this product or allow to drift if bees are foraging the treatment area. Ensure that planting equipment is functioning properly in accordance with manufacturer specification to minimize seed coat abrasion during planting to reduce dust which can drift to blooming crops or weeds. Users should
- Wash hands before eating, drinking, chewing gum, using tobacco or using the toilet.
- Remove clothing immediately if pesticide gets inside. Then wash thoroughly and put on clean clothing.
- Remove PPE immediately after handling this product. Wash the outside of gloves before removing. As soon as possible, wash thoroughly and change clothing. AGRICULTURAL USE REQUIREMENTS Use this product only in accordance with its labeling and with the Worker Protection Standard, 40CFR part 170. This Standard contains requirements for the protection of agricultural workers on farms, forests, nurseries, and greenhouses, and handlers of agricultural pesticides. It contains requirements fortraining, decontamination, notification, and emergency assistance. It also contains specific instructions and exceptions pertaining to the statements on this label about personal protective equipment (PPE) and 2 DIRECTIONS FOR USE It is a violation of Federal law to use this product in a manner inconsistent with its labeling.
Do not enter or allow worker entry into treated areas during the restricted entry interval (REI) of 12 hours. 3 1. 2. 3. 4. restricted-entry interval. The requirements in this box only apply to uses of this product that are covered by the Worker Protection Standard. NITRO SHIELD® IV is an aqueous based flowable concentrate formulation with a proprietary formulation that is intended to reduce seed dusting off and help reduce viscosity. To delay insecticide resistance consider; • Avoiding the consecutive use of NITRO SHIELD® IV or Group 4 insecticides that have a similar target site of action, on the same insect/mite species. • Using tank-mixtures or premixes with insecticides/acaricides from different target site of action Groups as long as the involved products are all registered for the same use and have different sites of action, • Basing insecticide/acaricide use on a comprehensive IPM program. • Monitoring treated insect/mite populations for loss of efficacy. • Contacting your local extension specialist, certified crop advisors, and/or Winfield Solutions, LLC representative for herbicide resistance management and/or integrated pest management recommendations for specific site and resistant pest problems. RESISTANCE MANAGEMENT RECOMMENDATIONS Nitro Shield IV contains a Group 4 Insecticide. Insect/mite biotypes with acquired resistance to Group 4 insecticides/acaricides may eventually dominate the insect/mite population if Group 4 insectides/acaricides are used repeatedly in the same site or in successive years as the primary method of control for targeted species. This may result in partial or total loss of control of those species by Nitro Shield IV or other Group 4 insecticides/acaricides. USE RESTRICTIONS • Do not use as a planter (hopper) box treatment. • California: Only for use in commercial seed treatment facilities, not allowed for “on farm” use. • On Farm Treatment; Do not apply this product through any type of irrigation system. • Do not use treated seed for feed, food, or oil purposes. • Excess treated seed may be used for ethanol production only if (1) by-products are not used for livestock feed and (2) no measurable residues of pesticides remain in the ethanol by-products that are used in agronomic practice. • Store away from feeds and foodstuffs. • Treated seed must be planted into the soil at a depth greater than 1 inch. • Treated seeds exposed on soil surface may be hazardous to wildlife. Cover or collect treated seeds that are spilled during handling. PRE required for early entry to treated areas that is permitted under the Worker Protection Standard and that involves contact with anything that has been treated, such as plants, soil, or water is; Coveralls, Chemical-resistant gloves: barrier laminate, butyl rubber >14 mils, nitrile rubber >14 mils, neoprene rubber >14 mils, polyvinyl chloride (PVC) >14 mils, or Viton® >14 mils. Shoes plus socks. Protective eyewear. PRODUCT INFORMATION NITRO SHIELD® IV is a neo-nicotinoid class insecticide intended to provide post planting residual control of labeled insects during the critical germination stage of growth. Exception: If the seed is treated with the product and the treated seed is soil-injected or soil incorporated, the Worker Protection Standard, under certain circumstances, allows workers to enter the treated area if there will be no contact with anything that has been treated.
4 TANK MIXTURES • It is the pesticide user’s responsibility to ensure that all products in a tank mix are registered for the intended use. • Users must follow the most restrictive directions and precautionary language of all products used in the mixture. • All tank mixes must be pre-tested to determine physical compatibility between formulations. • This product can be mixed with fungicide products that are labeled for use on the same crops as NITRO SHIELD® IV. • Do not exceed labeled dosage rates. • This product cannot be mixed with any product containing a label prohibition against such mixing. STORED SEED PROTECTION To protect stored seed of crops listed on this label apply a minimum of 1.0 fluid ounce of NITRO SHIELD® IV per 100 pounds of seed. Pests controlled by this application include Indian Meal Moth {Plodia inteipunctella), Rice Weevil {Sitophilus oryzea), Red Flour Beetle {Thbiolium castaneum), and Lesser • Dispose of all excess treated seed. Leftover seed may be double sown around the headland or buried away from water sources in accordance with local requirements. • Do not contaminate water bodies when disposing of planting equipment wash water. • In the event of crop failure or harvest of a crop grown from NITRO SHIELD® IV treated seed, the field may be replanted immediately to artichoke, barley. Brassica (cole) leafy vegetables, borage, canola, cilantro, corn (field or sweet), cotton, crambe, cranberry, cucurbits, eggplant, flax, groundcherry, leafy petiole vegetables, leafy vegetables, legume vegetables (succulent or dried), mustard seed, oats, okra, pepinos, pepper, popcorn, potato, rapeseed, sorghum, soybean, strawberry, sugarbeets, sunflower, tomatillo, tomato, triticale, turnip greens, root and tuber vegetables, watercress, and wheat. For cereals, including buckwheat, millet, rice and rye and for safflower, the minimum plant back interval is 30 days from the date NITRO SHIELD® IV treated seed was planted. Cover crops for soil building or erosion control may be planted at any time, but do not graze or harvest for food or feed. For all other crops not listed on an imidacloprid label, or for crops for which no imidacloprid tolerance for the active ingredient has been established, a 12-month plant-back interval must be observed. • Do not allow children, pets or livestock to have access to treated seed. • The maximum application rate (all imidacloprid uses; seed treatment, foliar application, soil application) per acre per year for imidacloprid is 0.4 lb. Do not use more than 0.4 lb. (181.44 g) imidacloprid per acre per calendar year. • Do not apply a neonicotinoid insecticide within 45 days of planting seed treated with NITRO SHIELD® IV. • Notification of the crop rotational restriction must be conveyed to the grower by appropriate seed tag labeling or bag printing on all seed units. • The purchaser of this product is responsible for ensuring that all seeds treated with this product are adequately dyed with a suitable color to prevent its accidental use as food for man or feed for animals. Refer to 21 CFR, Part 2.25. Any dye or colorant added to treated seed must be cleared for use under 40 CFR, Part 180.1001. Federal regulations have established official tolerances for certain pesticide residues. In order that residues on food and forage crops will not exceed established tolerances, use only at labeled rates. • Treated seed must not be used for or mixed with food or animal feed or processed for oil. Seed commercially treated with NITRO SHIELD® IV must be labeled in accordance with all applicable requirements under the Federal Seed Act. • Labels for commercially treated seed should include the following addition to the Environmental Hazards statements: Exposed treated seed may be hazardous to birds. Dispose of all excess treated seed and seed packaging by burial away from bodies of water. Cover or incorporate spilled treated seeds. • Rape greens grown and harvested from NITRO SHIELD® IV treated seed must not be used for human and feed consumption. Rapeseed grown and harvested from treated seed is only for industrial uses and cannot be used for edible oil or any other human/feed consumption.
EARLY-SEASON PROTECTION AGAINST SUCKING INSECTS CROP COMMENT 19.2-32.0 16.0 Suppression only. 16.0-32.0 Safflower Wireworms 16.0-32.0 Sunflower 16.0-32.0 Use Restrictions: 5 Grain Borer {Rhizopertha dominica). If seed being treated is known to have existing pest infestation fumigation may be necessary prior to bagging. Canola, Rapeseed and Mustard Seed (For end-use application at agricultural establishments): Shake product well before making slurry and apply using a HCBT or Batch Treater. May be diluted with an approved fungicide for disease control. Treat 14 of seed with 14 of slurry then add remainder of seed and slurry and continue mixing until all seeds are covered. Flax, Sunflower, Crambe and Borage (For end-use application at agricultural establishments): To provide early-season protection of seedlings against wireworms, seed corn maggots, and flea beetles apply using an HCBT or a Batch Treater at 16.0 fl. oz. per hundredweight of seed. To provide early-season protection, apply as a commercial seed treatment at 0.25-0.50 mg a.i. per seed (one fl. oz. of NITRO SHIELD® IV contains 14.2 grams of imidacloprid) OIL SEED CROP GROUP^ ___ PEST To provide early season protection, apply as a commercial seed treatment at 0.25 - 0.5 mg a.i. per seed (one fl. oz. of NITRO SHIELD® IV contains 14.2 grams of imidacloprid)_________ Suppression only. To provide early-season protection, apply as a commercial seed treatment at 0.25-0.50 mg a.i. per seed (one fl. oz. of NITRO SHIELD® IV contains 14.2 grams of imidacloprid)_________ Suppression only. For on-farm treatment. Suppression only. Flax, crambe, and borage Use higher listed rate when pest populations are above historical levels. Suppression only. Use higher listed rate when pest populations are above historical levels. Canola, Rapeseed, and Mustard Seed Wireworms, Seed com maggots, Flea beetles Aphids, Flea beetles Lygus Bugs (including Lygus spp), Seedpod Weevil larvae (including Ceutorhynchus assimilis'), Wireworms Wireworms, Seed com maggots, Flea beetles RATE (fluid ounces per hundredweight seed) 12.8-32.0
PEST COMMENT Field corn Suppression only. 6 • Rape greens grown and harvested from NITRO SHIELD® IV treated seed must not be used for human and feed consumption. Rapeseed grown and harvested from treated seed is only for industrial uses and cannot be used for edible oil or any other human/feed consumption. • Do not graze or feed livestock on treated areas for 45 days after planting. Field Corn (For end-use application at agricultural establishments): Not registered for use in California Shake product well before making slurry and apply using a HCBT or Eight-Bag Batch Treater. May be diluted with an approved fungicide for disease control. Mix slurry so that rate is 8 - 10 fluid ounces per 50 pound bag of seed. Treat 14 of seed with 14 of slurry then add remainder of seed and slurry and continue (1) In areas of heavy to severe com rootworm populations, protection will not be adequate. Use only in areas of light to moderate corn rootworm populations. Consult your State Agricultural Extension Service on levels of com rootworm populations (2) Reduces early season feeding damage. (3) Will reduce feeding damage caused by leaf feeding black cutworms that are 1/2 inch or less in length. Corn root worm (including Northern, Western, Southern and Mexican) (1), Flea beetle. Chinch bug, Southern green stinkbug. White grub, Seed corn maggot. Th rips. Wireworm*, Corn leaf aphid, Imported fire ant. Southern corn leaf beetle. Billbug (2), Grape colaspis (2), Black cutworm (3) Flea beetle. Chinch bug. Seed corn maggot*. Th rips. Wireworm*, Corn leaf aphid, Imported fire ant. Grape colaspis (2), White grub_________ Seed corn maggot (seed protection only), Wireworm (seed protection only). Flea beetle (through 1 leaf stage). Imported fire ant. White grub (4) (4) Reduces feeding damage during emergence and seedling stages. 3.35 (Equivalent to 0.60 milligrams ai per kernel) 0.90 (Equivalent to 0.16 milligrams ai per kernel) RATE (fluid ounces per 80,000 units of seed) 7.5 (equivalent to 1.34 milligrams ai per kernel) FIELD CORN SEED: CROP
PEST COMMENTS ^Suppression only. 4.0-8.0 2.0-4.0 1.0-2.0 8.0 CROP COMMENT 0.16-0.32 Suppression only. Grasshopper1.5-3.0 7 mixing until all seeds are covered. After sluny treatment, the addition of dry talc at the rate of % -1 ounce per 50 pounds of seed is recommended to minimize risk of moisture buildup in the planter. Popcorn (commercial seed treatment) Use Restriction: • Do not graze or feed livestock on treated areas for 45 days after planting. Use Restriction: • Do not graze or feed livestock on treated areas for 45 days after planting. Flea beetle, Early-season corn Mix slurry so that it is applied at a rate of 16 - 20 fl. oz. of diluted solution per hundredweight of seed. Reduces possible yellow dwarf virus disease from aphid vectoring. SWEET CORN AND POPCORN SEED: CROP CEREAL GRAIN SEEDS^ ___ PEST Use the higher listed rate to increase time of protection and/or when insect pressure is heavy.________________________________ Treated seed may be planted as a 50 to 60 foot border around the perimeter of the field to help Sweet Corn (commercial seed treatment) lleaf aphid, Use the higher listed rate to increase time of protection and/or when insect pressure is heavy. Wheat, Barley, Oats, Rye, Triticale Aphids (including Bird cherry-oat, English grain. Greenbug, and Russian wheat aphid), Hessian fly Wireworm Seed corn maggot*. Wireworm* Imported fire ant, Early-season corn eaf aphid. Seed corn maggot*, Wireworm* Imported fire ant. Seed corn maggot (seed protection). Wireworm (seed protection) Wireworm (seed protection)* Flea beetles RATE (fluid ounces per hundredweight seed) 1.0-3.0 RATE (fluid ounces per hundredweight seed) 8.0
damage fromseason PEST COMMENT ‘Suppression only. PEST COMMENT 8 Consult your local agricultural extension agent for grasshopper control information specific to your area. Sorghum (For end-use application at agricultural establishments): Shake product well before making slurry and apply using a HCBT or Eight-Bag Batch Treater. May be diluted with an approved fungicide for disease control. Mix slurry so that rate is 8 - 10 fluid ounces per 50 pound bag of seed. Treat 14 of seed with 14 of slurry then add remainder of seed and slurry and continue mixing until all seeds are covered. After slurry treatment, the addition of dry talc at the rate of % -1 ounce per 50 pounds of seed is recommended to minimize risk of moisture buildup in planter. Use Restriction: • Do not graze or feed livestock on treated areas for 45 days after planting. Use Restriction: • Do not graze or feed livestock on treated areas for 45 days after planting. Wheat, Barley, Triticale (For end-use application at agricultural establishments): Make application using a Total Slurry Treater (TST), Farmer Applied Seed Treater (F.A.S.T.), or other on- farm seed treating equipment capable of accurately applying low rates of NITRO SHIELD® IV. Apply 1.0- 3.0 fl. oz. per hundredweight of seed. NITRO SHIELD® IV may be mixed with a fungicide product for protection against disease. NITRO SHIELD® IV may be applied to seed previously treated with a fungicide. In this case, dilution is necessary. Use Restriction: • Do not graze or feed livestock on treated areas for 45 days after planting. Use Restriction: • Do not graze or feed livestock on treated areas for 45 days after planting. Thorough coverage is necessary for optimal control. minimize early grasshoppers. RATE (fluid ounces per hundredweight seed) Aphids (including Com leaf, English grain, Greenbug, and Yellow sugar cane aphid). Chinch bugs. Imported Fire ants. Wireworms* Use the higher listed rate to increase time of protection and/or when insect pressure is heavy. Sorghum, Millet SORGHUM AND MILLET SEED: CROP COTTON SEED TREATMENT: CROP RATE (fluid ounces per hundredweight seed) 8.0
CROP COMMENT ‘Suppression only. PEST COMMENT Soybean ‘Suppression only. VEGETABLE SEED TREATMENT: 9 Cotton (Delinted Seed Only) Seed corn maggot‘ Soybean aphid, Bean leaf beetle Will suppress the spread of certain plant viruses. Use Restriction: • Do not graze or feed livestock on treated areas for 45 days after planting. Use Restriction: • Do not graze or feed livestock on treated areas for 45 days after planting. {1) On a unit of pelleted sugar beet seed with a weight ratio of 2:1 pelleting mixture to raw seed (seed count 100,000 seed - approximately 1 kilogram by weight). If applying to non-pelleted raw seed, do not exceed a rate of 3.0 fluid ounces per 100,000 seed (approximately 1 Kg by weight). For protection of planted seeds. Use the higher listed rates to provide increased length of protection and for heavy insect pressure. SUGAR BEET SEED TREATMENT: PEST SOYBEAN SEED TREATMENT: CROP Use Restriction: • Do not graze or feed livestock on soybean forage or hay. NITRO SHIELD® IV can be used as an over treatment. Regardless of the type of application (seed treatment, soil or foliar) do not apply more than a total of 0.4 lb. of imidacloprid per acre per calendar year. Cotton (Delinted Seed Only) (For end-use application at agricultural establishments): Shake product well before making slurry and apply using a HCBT or Eight-Bag Batch Treater. May be diluted with an approved fungicide for disease control. Mix slurry so that rate is 8 - 10 fluid ounces per 50 pound bag of seed. Treat 14 of seed with 14 of slurry then add remainder of seed and slurry and continue mixing until all seeds are covered. Sugar Beets (commercial seed treatment) Thrips, Aphids Whitefly, Aphids/Leafhoppers (including vectors that may spread Curly top and Yellow mosaic virus). Root aphid, Thrips, Wireworms‘ 16.0 (Equivalent to 0.375 milligram active ingredient per seed) RATE (fluid ounces per hundredweight seed) 2.0-4.0 RATE (fluid ounces per seed unit) (1) 3.0 - 6.25
CROP PEST COMMENTS Suppression only 8.0 10 Seed com maggot, Wireworm** Use Restrictions: • Do not graze or feed livestock on treated areas for 45 days after planting. • Seed-and-pod vegetable seed treated in California must be destined for planting in states other than California and is not to be planted in California. Rate Fluid ounces per 1000 row feet 0.4 Use Restrictions: • Do not apply more than 10.0 fluid ounces per acre (0.31 lb active ingredient per acre) NITRO SHIELD® IV per crop season when making seed piece treatment applications. • Do not use treated seed pieces for food, feed, fodder or processing for oil. • Do not apply any subsequent in furrow application of any imidacloprid product following a seed piece treatment. Rate Fluid ounces per 100 lbs of Seed 0.2-0.4 Rate Fluid ounces per acre 4.0-8.0 Wireworm**, Bean leaf beetle. Imported fire ant, Aphid Rate Fluid ounces per acre 8.0 POTATO SEED PIECE TREATMENT: Pest Controlled__________ Aphids, Colorado potato beetle, Flea beetles, Leafhoppers, Potato psyllid. Wireworms {seed piece protection) ________ Pest/Disease Suppressed Symptoms of Potato leaf roll virus (PLRV), Potato yellows, Net necrosis_____________ Application Instructions: Apply specified dosage as a diluted spray onto seed pieces using a shielded spray system. Dilute with 3 parts water, or less, to 1 part NITRO SHIELD® IV. Agitate or stir spray solution as needed. Fungicidal or inert absorbent dusts may be applied after NITRO SHIELD® IV application. Apply only in areas with adequate ventilation or in areas that are equipped to remove spray mist or dust. Plant seed pieces as soon as possible after treating avoiding prolonged exposure of NITRO SHIELD® IV treated seed pieces to sunlight and in accordance with specifications of your local Extension service. Based on a seeding rate of 2000 lbs per acre Adzuki Bean, Asparagus Bean, Broad Bean (Succulent Or Dry), Catjang Bean, Chinese Longbean, Field Bean, Guar Bean, Jackbean, Kidney Bean, Lablab Bean, Lima Bean (Succulent or Dry), Moth Bean (Succulent or Dry), Mung Bean, Navy Bean, Pinto Bean, Rice Bean, Runner Bean, Snap Bean, Sword Bean, Tepary Bean, Urd Bean, Wax Bean, Yardiong Bean, Blackeyed Pea (Succulent or Dry), Chickpea, Cowpea (Succulent or Dry), Crowder Pea, Dwarf Pea, Edible-Pod Pea, English Pea, Field Pea, Garden Pea, Green Pea, Pigeon Pea (Succulent or Dry), Snow Pea, Southern Pea (Succulent or Dry), Sugar Snap Pea, Grain Lupin, Sweet Lupin, White Lupin, White Sweet Lupin, Lentil Carrot RATE (fluid ounces per hundredweight seed) 2.0-4.0
Do not graze or feed livestock on treated areas for 45 days after planting. ROTATIONAL PLANT-BACK INTERVALS* PLANT-IMMEDIATE PLANT-BACK 11 THE FEDERAL SEED ACT REQUIRES THAT BAGS CONTAINING TREATED SEEDS SHALL BE LABELED WITH THE FOLLOWING STATEMENTS; Soybean Strawberry Sugarbeet Sunflower Tomatillo Tomato Triticale Turnip greens Watercress Wheat THE U.S. ENVIRONMENTAL PROTECTION AGENCY REQUIRES THE FOLLOWING STATEMENTS ON BAGS CONTAINING SEEDS TREATED WITH NITRO SHIELD® IV; • This seed has been treated with imidacloprid insecticide. • Do not use for feed, food or oil purposes. SEED BAG LABELING REQUIREMENTS Seed commercially treated with this product must be labeled in accordance with all applicable requirements of the Federal Seed Act. The user of this product is responsible for ensuring that the seed bag meets all requirements under the Federal Seed Act. ROTATIONAL CROPS Treated areas may be replanted with any crop specified on an imidacloprid label, or any crop for which a tolerance exists for the active ingredient, as soon as practical following the last application. The following plant-back intervals must be observed for listed crops; • Pollinator Precautions; Imidacloprid is highly toxic to bees exposed to direct treatment or residues on blooming crops or weeds. Ensure that planting equipment is functioning properly in accordance with manufacturer specification to minimize seed coat abrasion during planting to reduce dust which can drift to blooming crops or weeds. • Do not graze or feed livestock on treated areas for 45 days after planting Oil Seed Crops (canola, rapeseed, mustard seed, flax, crambe, borage, safflower and sunflower). Corn (field, sweet and popcorn). Cereal Grains (wheat, barley, oats, rye, and triticale). Sorghum and Millet, Cotton, Sugar Beet, Vegetable Seed (beans, peas, and carrots) and Potatoes. For soybeans, do not graze or feed livestock forage or hay. • Store away from feeds and foodstuffs. • Wear long-sleeved shirt, long pants and chemical-resistant gloves when handling treated seed. • Treated seeds exposed on soil surface may be hazardous to wildlife. Cover or collect treated seeds that are spilled during handling. • Treated seed must be planted into the soil at a depth of greater than 1 inch. • Dispose of all excess treated seed. Leftover seed may be double sown around the headland or buried away from water sources in accordance with local requirements.
- Cover crops for soil building or erosion control may be planted any time, but do not graze or harvest for food or feed.
- For all other crops not listed on an Imidacloprid label, or for crops for which no tolerance for the active ingredient has been established, a 12-month plantback interval must be observed. Artichoke Barley Brassica (cole) leafy vegetable Borage Canola Cilantro Corn, Field Corn, Sweet Cotton Crambe Cranberry Cucurbits Eggplant Flax Groundcherry Leaf petiole vegetables Leafy vegetables Legume vegetables (succulent or dried, including soybean) Mustard seed Oats Okra Pepinos Pepper Popcorn Potato Rapeseed Root and Tuber Vegetables Sorghum 30-DAY BACK Cereals, including buckwheat millet rice rye Safflower
12 Pressure rinse as follows (all sizes): Empty the remaining contents into application equipment or a mix tank and continue to drain for 10 seconds after the flow begins to drip. Hold container upside down over application equipment or mix tank or collect rinsate for later use or disposal. Insert pressure rinsing nozzle in the side of the container, and rinse at about 40 PSI for at least 30 seconds. Drain for 10 seconds after the flow begins to drip. (non-refillable <5 gallons): Triple rinse as follows; Empty the remaining contents into application equipment or a mix tank and drain for 10 seconds after the flow begins to drip. Fill the container % full with water and recap. Shake for 10 seconds. Pour rinsate into application equipment or a mix tank or store rinsate for later use or disposal. Drain for 10 seconds after the flow begins to drip. Repeat this procedure two more times. (non-refillable >5 gallons): Triple rinse as follows; Empty the remaining contents into application equipment or a mix tank. Fill the container % full with water. Replace and tighten closures. Tip container on its side and roll it back and forth, ensuring at least one complete revolution, for 30 seconds. Stand the container on its end and tip it back and forth several times. Empty the rinsate into application equipment or a mix tank or store rinsate for later use or disposal. Repeat this procedure two more times. STORAGE AND DISPOSAL PROHIBITIONS: Do not contaminate water, food or feed by storage, disposal, or by cleaning of equipment. Do not reuse empty container. Open dumping is prohibited. PESTICIDE STOf^GE: Store in a cool place. Do not store in direct sunlight. Protect from freezing temperatures. PESTICIDE DISPOSAL: Wastes resulting from the use of this product may be disposed of on site or at an approved waste disposal facility. CONTAINER DISPOSAL: Non-refillable containers (1,2.5,30 & 55 gallon): Do not reuse or refill this container. Offer for recycling, if available. Triple rinse or pressure rinse container (or equivalent) promptly after emptying. • Do not contaminate water bodies when disposing of planting equipment wash water. • Dispose of seed packaging in accordance with local requirements. • In the event of crop failure or harvest of a crop grown from NITRO SHIELD® IV treated seed, the field may be replanted immediately to artichoke, barley, borage. Brassica (cole) leafy vegetables, canola, cilantro, corn (field or sweet), cotton, crambe, cranberry, cucurbits, eggplant, flax, groundcherry, leafy petiole vegetables, leafy vegetables, legume vegetables (succulent or dried), mustard seed, oats, okra, pepinos, pepper, popcorn, potato, rapeseed, sorghum, soybean, strawberry, sugarbeet, sunflower, tomatillo, tomato, triticale, turnip greens, root and tuber vegetables, watercress, and wheat. For cereals, including buckwheat, millet, rice and rye and for safflower, the minimum plant back interval is 30 days from the date NITRO SHIELD® IV treated seed was planted. Cover crops for soil building or erosion control may be planted at any time, but do not graze or harvest for food or feed. For all other crops not listed on an imidacloprid label, or for crops for which no imidacloprid tolerance for the active ingredient has been established, a 12 month plant-back interval must be observed. • Do not allow children, pets, or livestock to have access to treated seed. • The maximum application rate (all imidacloprid uses; seed treatment, foliar application, soil application) per acre per year for imidacloprid is 0.4 lb. Do not use more than 0.4 lb. (181.44 g) imidacloprid per acre per calendar year. • This seed has been treated with X mg imidacloprid per seed. • Do not apply a neonicotinoid insecticide within 45 days of planting seed treated with NITRO SHIELD® IV. • Excess treated seed may be used for ethanol production only if (1) by-products are not used for livestock feed and (2) no measurable residues of pesticides remain in the ethanol by products that are used in agronomic practice. • Rape greens grown and harvested from NITRO SHIELD® IV treated seed must not be used for human and feed consumption. Rapeseed grown and harvested from treated seed is only for industrial uses and cannot be used for edible oil or any other human/feed consumption.
NITRO SHIELD® is a registered trademark of Winfield Solutions, LLC. 13 LIMITATION OF LIABILITY TO THE EXTENT CONSISTENT WITH APPLICABLE LAW, IN NO EVENT SHALL MANUFACTURER OR SELLER BE LIABLE FOR SPECIAL, INCIDENTAL, OR CONSEQUENTIAL DAMAGES, OR FOR DAMAGES IN THE NATURE OF PENALTIES RELATING TO THE GOODS SOLD, INCLUDING USE, APPLICATION, HANDLING, AND DISPOSAL. MANUFACTURER OR SELLER SHALL NOT BE LIABLE TO BUYER OR USER BY WAY OF INDEMNIFICATION TO BUYER OR TO CUSTOMERS OF BUYER, IF ANY, OR FOR ANY DAMAGES OR SUMS OF MONEY, CLAIMS OR DEMANDS WHATSOEVER, RESULTING FROM OR BY REASON OF, OR RISING OUT OF THE MISUSE, OR FAILURE TO FOLLOW LABEL WARNINGS OR INSTRUCTIONS FOR USE, OF THE GOODS SOLD BY MANUFACTURER OR SELLER TO BUYER. ALL SUCH RISKS SHALL BE ASSUMED BY THE BUYER, USER, OR ITS CUSTOMERS. BUYER ’S OR USER ’S EXCLUSIVE REMEDY, AND MANUFACTURER ’S OR SELLER ’S TOTAL LIABILITY SHALL BE FOR DAMAGES NOT EXCEEDING THE COST OF THE PRODUCT. If you do not agree with or do not accept any of directions for use, the warranty disclaimers, or limitations on liability, do not use the product, and return it unopened to the Seller, and the purchase price will be refunded. FOR CHEMICAL EMERGENCY: Spill, leak, fire, exposure or accident, call CHEMTREC 1-800-424-9300. Refillable container (250 gallon & bulk): Refill this container with pesticide only. Do not reuse this container for any other purpose. Cleaning the container before final disposal is the responsibility of the person disposing of the container. Cleaning before refilling is the responsibility of the refiller. To clean the container before final disposal, empty the remaining contents from this container into application equipment or mix tank. Fill the container about 10 percent full with water. Agitate vigorously or recirculate water with the pump for 2 minutes. Pour or pump rinsate into application equipment or rinsate collection system. Repeat this rinsing procedure two more times. WARRANTY DISCLAIMER The directions for use of this product must be followed carefully. TO THE EXTENT CONSISTENT WITH APPLICABLE LAW, (1) THE GOODS DELIVERED TO YOU ARE FURNISHED “AS IS ” BY MANUFACTURER OR SELLER AND (2) MANUFACTURER AND SELLER MAKE NO WARRANTIES, GUARANTEES, OR REPRESENTATIONS OF ANY KIND TO BUYER OR USER, EITHER EXPRESS OR IMPLIED, OR BY USAGE OF TRADE, STATUTORY OR OTHERWISE, WITH REGARD TO THE PRODUCT SOLD, INCLUDING, BUT NOT LIMITED TO MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE, USE, OR ELIGIBILITY OF THE PRODUCT FOR ANY PARTICULAR TRADE USAGE. UNINTENDED CONSEQUENCES, INCLUDING BUT NOT LIMITED TO INEFFECTIVENESS, MAY RESULT BECAUSE OF SUCH FACTORS AS THE PRESENCE OR ABSENCE OF OTHER MATERIALS USED IN COMBINATION WITH THE GOODS, OR THE MANNER OF USE OR APPLICATION, INCLUDING WEATHER, ALL OF WHICH ARE BEYOND THE CONTROL OF MANUFACTURER OR SELLER AND ASSUMED BY BUYER OR USER. THIS WRITING CONTAINS ALL OF THE REPRESENTATIONS AND AGREEMENTS BETWEEN BUYER, MANUFACTURER AND SELLER, AND NO PERSON OR AGENT OF MANUFACTURER OR SELLER HAS ANY AUTHORITY TO MAKE ANY REPRESENTATION OR WARRANTY OR AGREEMENT RELATING IN ANY WAY TO THESE GOODS.