crop-chem-docs/corpus/epa_ppls/1381-252.md

# NITRO SHIELD IV

- EPA Reg No: **1381-252**
- Registrant: WINFIELD SOLUTIONS, LLC
- Signal word: Caution
- Active ingredients: Imidacloprid (40.7%)
- Label accepted: 2016-11-01
- Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/001381-00252-20161101.pdf

---
PRO^'^
November 1, 2016
Subject:
Dear Ms. Mathias:
Fas! Track Label Accepr.ab!-?
OFFICE OF CHEMICAL SAFETY
AND POLLUTION PREVENTION
The amended label referred to above, submitted in connection with registration under the Federal 
Insecticide, Fungicide and Rodenticide Act, as amended, is acceptable. This approval does not 
affect any conditions that were previously imposed on this registration. You continue to be 
subject to existing conditions on your registration and any deadlines connected with them.
Your release for shipment of the product constitutes acceptance of these conditions. If these 
conditions are not complied with, the registration will be subject to cancellation in accordance
A stamped copy of your labeling is enclosed for your records. This labeling supersedes all 
previously accepted labeling. You must submit one copy of the final printed labeling before you 
release the product for shipment with the new labeling. In accordance with 40 CFR 152.130(c), 
you may distribute or sell this product under the previously approved labeling for 18 months 
from the date of this letter. After 18 months, you may only distribute or sell this product if it 
bears this new revised labeling or subsequently approved labeling. “To distribute or sell” is 
defined under FIFRA section 2(gg) and its implementing regulation at 40 CFR 152.3.
Should you wish to add/retain a reference to the company’s website on your label, then please be 
aware that the website becomes labeling under the Federal Insecticide Fungicide and Rodenticide 
Act and is subject to review by the Agency. If the website is false or misleading, the product 
would be misbranded and unlawful to sell or distribute under FIFRA section 12(a)(1)(E). 40 
CFR 156.10(a)(5) list examples of statements EPA may consider false or misleading. In addition, 
regardless of whether a website is referenced on your product’s label, claims made on the 
website may not substantially differ from those claims approved through the registration process. 
Therefore, should the Agency find or if it is brought to our attention that a website contains false 
or misleading statements or claims substantially differing from the EPA approved registration, 
the website will be referred to the EPA’s Office of Enforcement and Compliance.
Label Amendment - Update gloves statement, add a product information section, 
and other small revisions
Product Name: Nitro Shield IV
EPA Registration Number: 1381-252
Application Date: 7/18/2016
Decision Number: 519585
Lisa Mathias
Product Registration Specialist
Winfield Solutions, LLC 
P.O. Box 64589, MS 5705 
St. Paul, MN 55164
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY 
WASHINGTON, DC 20460/ A \ 
w

Sincerely,
Enclosure
with FIFRA section 6. If you have any questions, please contact Jacquelyn Herrick by phone at 
703-347-0559, or via email at herrick.iacquelyn@epa.gov.
Venus Eagle, Product Manager 01 
Invertebrate and Vertebrate Branch 3 
Registration Division (7505P) 
Office of Pesticide Programs
Page 2 of 2
EPAReg. No. 1381-252
Decision No. 519585

ACCEPTED
GROUP 4 INSECTICIDE
1381-252
Nitro Shield® IV
Insecticide For Treatment Of Labeled Crop Seed
If Swallowed:
If Inhaled:
NET CONTENTS: 2.5 GAL (9.46L)
W inField 1/1024/6
1
EPA REG. NO. 1381-252 
EPA EST. NO. 
[BAR CODE]
[UNITY# __
[LOT #____
DISTRIBUTED BY;
WINFIELD SOLUTIONS, LLC
P.O. BOX 64589
ST. PAUL, MN 55164-0589
J
J
KEEP OUT OF REACH OF CHILDREN 
CAUTION
ACTIVE INGREDIENTS:
Imidacloprid: 1-[(6-Chloro-3-pyridinyl) 
methyl]-N-nitro-2-imidazolidinimine .... 
OTHER INGREDIENTS: ..........
TOTAL
. 40.7% 
, 5^3%
100.0%
SEE BOOKLET FOR ADDITIONAL PRECAUTIONARY 
STATEMENTS, COMPLETE DIRECTIONS FOR USE, 
WARRANTY DISCLAIMER AND LIMITATION OF LIABILITY.
Contains 4 lbs active per gallon (480 grams per 
liter)
If On Skin or 
Clothing:
FIRST AID _________________
Call a poison control center or 
doctor immediately for treatment 
advice. Have person sip a glass of 
water if able to swallow.
Do not induce vomiting unless told 
to do so by a poison control center 
or doctor.
Do not give anything by mouth to 
an unconscious person.________
Take off contaminated clothing.
Rinse skin immediately with plenty 
of water for 15-20 minutes.
Call a poison control center or 
doctor for treatment advice._____
Move person to fresh air.
If person is not breathing, call 911 
or an ambulance, then give 
artificial respiration, preferably 
mouth-to-mouth if possible.
Call a poison control center or 
doctor for further treatment advice.
Have the product container or label with you when 
calling a poison control center or doctor or going for 
treatment. For additional information in case of medical 
emergency call toll free 1-877-424-7452.
11/1/2016
Under me Federal insecticide. Fungicide 
and Rodenikide Ad as amended, (or the 
peaticleJ* registered urder 
EPA Reg. No.

USER SAFETY RECOMMENDATIONS
This product is to be used in liquid or slurry treaters only.
Mix thoroughly before use or use the entire container at one time.
Follow manufacturer’s instructions for cleaning/maintaining PRE. If no such instructions for washables exist 
use detergent and hot water. Keep and wash PRE separately from other laundry.
Do not apply this product in a way that will contact workers or other persons, either directly or through drift. 
Only protected handlers may be in the area during application. For any requirements specific to your State 
or Tribe, consult the agency responsible for pesticide regulation.
For use in commercial seed treatment facilities, with the exception of application to barley, borage, canola, 
cotton (delinted seed), crambe, field corn, flax, mustard seed, rapeseed, sorghum, sunflower, triticale, and 
wheat, which may be made either in a commercial seed treatment facility or as an end-use seed treatment 
on agricultural establishments at, or immediately before, planting.
This product is toxic to wildlife and highly toxic to aquatic invertebrates. For terrestrial uses, do not apply 
directly to water, or to areas where surface water is present or to intertidal areas below the mean high 
water mark. Do not contaminate water when disposing of equipment washwaters. Cover or incorporate 
spilled treated seeds.
PRECAUTIONARY STATEMENTS
HAZARDS TO HUMANS AND DOMESTIC ANIMALS
CAUTION; Harmful if swallowed, absorbed through skin or inhaled. Avoid breathing vapor or spray mist. 
Avoid contact with skin, eyes, or clothing.
PERSONAL PROTECTIVE EQUIPMENT (PPE)
Applicators and other handlers must wear:
1. Long-sleeved shirt and long pants,
2. Socks and shoes and
3. Chemical-resistant gloves: barrier laminate, butyl rubber >14 mils, nitrile rubber >14 mils, neoprene 
rubber >14 mils, polyvinyl chloride (PVC) >14 mils, or Viton® >14 mils.
ENVIRONMENTAL HAZARDS
This product is highly toxic to bees exposed to direct treatment or residues on blooming crops or 
weeds. Do not apply this product or allow to drift if bees are foraging the treatment area. Ensure that 
planting equipment is functioning properly in accordance with manufacturer specification to minimize seed 
coat abrasion during planting to reduce dust which can drift to blooming crops or weeds.
Users should
1. Wash hands before eating, drinking, chewing gum, using tobacco or using the toilet.
2. Remove clothing immediately if pesticide gets inside. Then wash thoroughly and put on clean 
clothing.
3. Remove PPE immediately after handling this product. Wash the outside of gloves before removing. 
As soon as possible, wash thoroughly and change clothing.
AGRICULTURAL USE REQUIREMENTS
Use this product only in accordance with its labeling and with the Worker Protection Standard, 40CFR 
part 170. This Standard contains requirements for the protection of agricultural workers on farms, forests, 
nurseries, and greenhouses, and handlers of agricultural pesticides. It contains requirements fortraining, 
decontamination, notification, and emergency assistance. It also contains specific instructions and 
exceptions pertaining to the statements on this label about personal protective equipment (PPE) and
2
DIRECTIONS FOR USE
It is a violation of Federal law to use this product in a manner inconsistent with its labeling.

Do not enter or allow worker entry into treated areas during the restricted entry interval (REI) of 12 hours.
3
1.
2.
3.
4.
restricted-entry interval. The requirements in this box only apply to uses of this product that are covered 
by the Worker Protection Standard.
NITRO SHIELD® IV is an aqueous based flowable concentrate formulation with a proprietary formulation 
that is intended to reduce seed dusting off and help reduce viscosity.
To delay insecticide resistance consider;
• Avoiding the consecutive use of NITRO SHIELD® IV or Group 4 insecticides that have a 
similar target site of action, on the same insect/mite species.
• Using tank-mixtures or premixes with insecticides/acaricides from different target site of 
action Groups as long as the involved products are all registered for the same use and 
have different sites of action,
• Basing insecticide/acaricide use on a comprehensive IPM program.
• Monitoring treated insect/mite populations for loss of efficacy.
• Contacting your local extension specialist, certified crop advisors, and/or Winfield 
Solutions, LLC representative for herbicide resistance management and/or integrated pest 
management recommendations for specific site and resistant pest problems.
RESISTANCE MANAGEMENT RECOMMENDATIONS
Nitro Shield IV contains a Group 4 Insecticide. Insect/mite biotypes with acquired resistance to 
Group 4 insecticides/acaricides may eventually dominate the insect/mite population if Group 4 
insectides/acaricides are used repeatedly in the same site or in successive years as the primary 
method of control for targeted species. This may result in partial or total loss of control of those 
species by Nitro Shield IV or other Group 4 insecticides/acaricides.
USE RESTRICTIONS
• Do not use as a planter (hopper) box treatment.
• California: Only for use in commercial seed treatment facilities, not allowed for “on farm” use.
• On Farm Treatment; Do not apply this product through any type of irrigation system.
• Do not use treated seed for feed, food, or oil purposes.
• Excess treated seed may be used for ethanol production only if (1) by-products are not used for 
livestock feed and (2) no measurable residues of pesticides remain in the ethanol by-products that 
are used in agronomic practice.
• Store away from feeds and foodstuffs.
• Treated seed must be planted into the soil at a depth greater than 1 inch.
• Treated seeds exposed on soil surface may be hazardous to wildlife. Cover or collect treated seeds 
that are spilled during handling.
PRE required for early entry to treated areas that is permitted under the Worker Protection Standard and 
that involves contact with anything that has been treated, such as plants, soil, or water is;
Coveralls,
Chemical-resistant gloves: barrier laminate, butyl rubber >14 mils, nitrile rubber >14 mils, neoprene 
rubber >14 mils, polyvinyl chloride (PVC) >14 mils, or Viton® >14 mils.
Shoes plus socks.
Protective eyewear.
PRODUCT INFORMATION
NITRO SHIELD® IV is a neo-nicotinoid class insecticide intended to provide post planting residual control 
of labeled insects during the critical germination stage of growth.
Exception: If the seed is treated with the product and the treated seed is soil-injected or soil­
incorporated, the Worker Protection Standard, under certain circumstances, allows workers to enter the 
treated area if there will be no contact with anything that has been treated.

4
TANK MIXTURES
• It is the pesticide user’s responsibility to ensure that all products in a tank mix are registered for the 
intended use.
• Users must follow the most restrictive directions and precautionary language of all products used in the 
mixture.
• All tank mixes must be pre-tested to determine physical compatibility between formulations.
• This product can be mixed with fungicide products that are labeled for use on the same crops as NITRO 
SHIELD® IV.
• Do not exceed labeled dosage rates.
• This product cannot be mixed with any product containing a label prohibition against such mixing.
STORED SEED PROTECTION
To protect stored seed of crops listed on this label apply a minimum of 1.0 fluid ounce of NITRO SHIELD® 
IV per 100 pounds of seed. Pests controlled by this application include Indian Meal Moth {Plodia
inteipunctella), Rice Weevil {Sitophilus oryzea), Red Flour Beetle {Thbiolium castaneum), and Lesser
• Dispose of all excess treated seed. Leftover seed may be double sown around the headland or 
buried away from water sources in accordance with local requirements.
• Do not contaminate water bodies when disposing of planting equipment wash water.
• In the event of crop failure or harvest of a crop grown from NITRO SHIELD® IV treated seed, the field 
may be replanted immediately to artichoke, barley. Brassica (cole) leafy vegetables, borage, canola, 
cilantro, corn (field or sweet), cotton, crambe, cranberry, cucurbits, eggplant, flax, groundcherry, leafy 
petiole vegetables, leafy vegetables, legume vegetables (succulent or dried), mustard seed, oats,
okra, pepinos, pepper, popcorn, potato, rapeseed, sorghum, soybean, strawberry, sugarbeets, 
sunflower, tomatillo, tomato, triticale, turnip greens, root and tuber vegetables, watercress, and 
wheat. For cereals, including buckwheat, millet, rice and rye and for safflower, the minimum plant 
back interval is 30 days from the date NITRO SHIELD® IV treated seed was planted. Cover crops for 
soil building or erosion control may be planted at any time, but do not graze or harvest for food or 
feed. For all other crops not listed on an imidacloprid label, or for crops for which no imidacloprid 
tolerance for the active ingredient has been established, a 12-month plant-back interval must be 
observed.
• Do not allow children, pets or livestock to have access to treated seed.
• The maximum application rate (all imidacloprid uses; seed treatment, foliar application, soil 
application) per acre per year for imidacloprid is 0.4 lb. Do not use more than 0.4 lb. (181.44 g) 
imidacloprid per acre per calendar year.
• Do not apply a neonicotinoid insecticide within 45 days of planting seed treated with NITRO SHIELD® 
IV.
• Notification of the crop rotational restriction must be conveyed to the grower by appropriate seed tag 
labeling or bag printing on all seed units.
• The purchaser of this product is responsible for ensuring that all seeds treated with this product are 
adequately dyed with a suitable color to prevent its accidental use as food for man or feed for 
animals. Refer to 21 CFR, Part 2.25. Any dye or colorant added to treated seed must be cleared for 
use under 40 CFR, Part 180.1001. Federal regulations have established official tolerances for certain 
pesticide residues. In order that residues on food and forage crops will not exceed established 
tolerances, use only at labeled rates.
• Treated seed must not be used for or mixed with food or animal feed or processed for oil. Seed 
commercially treated with NITRO SHIELD® IV must be labeled in accordance with all applicable 
requirements under the Federal Seed Act.
• Labels for commercially treated seed should include the following addition to the Environmental 
Hazards statements:
Exposed treated seed may be hazardous to birds. Dispose of all excess treated seed and 
seed packaging by burial away from bodies of water. Cover or incorporate spilled treated 
seeds.
• Rape greens grown and harvested from NITRO SHIELD® IV treated seed must not be used for 
human and feed consumption. Rapeseed grown and harvested from treated seed is only for 
industrial uses and cannot be used for edible oil or any other human/feed consumption.

EARLY-SEASON PROTECTION AGAINST SUCKING INSECTS
CROP COMMENT
19.2-32.0
16.0 Suppression only.
16.0-32.0
Safflower Wireworms 16.0-32.0
Sunflower 16.0-32.0
Use Restrictions:
5
Grain Borer {Rhizopertha dominica). If seed being treated is known to have existing pest infestation 
fumigation may be necessary prior to bagging.
Canola, Rapeseed and Mustard Seed (For end-use application at agricultural establishments): 
Shake product well before making slurry and apply using a HCBT or Batch Treater. May be diluted with an 
approved fungicide for disease control. Treat 14 of seed with 14 of slurry then add remainder of seed and 
slurry and continue mixing until all seeds are covered.
Flax, Sunflower, Crambe and Borage (For end-use application at agricultural establishments): 
To provide early-season protection of seedlings against wireworms, seed corn maggots, and flea beetles 
apply using an HCBT or a Batch Treater at 16.0 fl. oz. per hundredweight of seed.
To provide early-season protection, 
apply as a commercial seed treatment 
at 0.25-0.50 mg a.i. per seed (one fl. 
oz. of NITRO SHIELD® IV contains
14.2 grams of imidacloprid)
OIL SEED CROP GROUP^ ___
PEST
To provide early season protection, 
apply as a commercial seed treatment 
at 0.25 - 0.5 mg a.i. per seed (one fl. 
oz. of NITRO SHIELD® IV contains
14.2 grams of imidacloprid)_________
Suppression only.
To provide early-season protection, 
apply as a commercial seed treatment 
at 0.25-0.50 mg a.i. per seed (one fl. 
oz. of NITRO SHIELD® IV contains
14.2 grams of imidacloprid)_________
Suppression only.
For on-farm treatment. 
Suppression only.
Flax, crambe, 
and borage
Use higher listed rate when pest 
populations are above historical levels. 
Suppression only.
Use higher listed rate when pest 
populations are above historical levels.
Canola, 
Rapeseed, 
and Mustard 
Seed
Wireworms, 
Seed com 
maggots, 
Flea beetles
Aphids, 
Flea beetles 
Lygus Bugs 
(including Lygus 
spp),
Seedpod Weevil 
larvae (including 
Ceutorhynchus 
assimilis'), 
Wireworms 
Wireworms, 
Seed com 
maggots,
Flea beetles
RATE 
(fluid ounces per 
hundredweight
_____seed)_____
12.8-32.0

PEST COMMENT
Field corn
*Suppression only.
6
• Rape greens grown and harvested from NITRO SHIELD® IV treated seed must not be used for human 
and feed consumption. Rapeseed grown and harvested from treated seed is only for industrial uses 
and cannot be used for edible oil or any other human/feed consumption.
• Do not graze or feed livestock on treated areas for 45 days after planting.
Field Corn (For end-use application at agricultural establishments):
Not registered for use in California
Shake product well before making slurry and apply using a HCBT or Eight-Bag Batch Treater. May be 
diluted with an approved fungicide for disease control. Mix slurry so that rate is 8 - 10 fluid ounces per 50 
pound bag of seed. Treat 14 of seed with 14 of slurry then add remainder of seed and slurry and continue
(1) In areas of heavy to severe com 
rootworm populations, protection will 
not be adequate. Use only in areas of 
light to moderate corn rootworm 
populations. Consult your State 
Agricultural Extension Service on 
levels of com rootworm populations
(2) Reduces early season feeding 
damage.
(3) Will reduce feeding damage 
caused by leaf feeding black 
cutworms that are 1/2 inch or less in 
length.
Corn root worm 
(including Northern,
Western, Southern 
and Mexican) (1), 
Flea beetle. 
Chinch bug, 
Southern green 
stinkbug.
White grub, 
Seed corn maggot*. 
Th rips. 
Wireworm*, 
Corn leaf aphid, 
Imported fire ant. 
Southern corn leaf 
beetle.
Billbug (2), 
Grape colaspis (2), 
Black cutworm (3) 
Flea beetle.
Chinch bug. 
Seed corn maggot*. 
Th rips.
Wireworm*, 
Corn leaf aphid, 
Imported fire ant. 
Grape colaspis (2), 
White grub_________
Seed corn maggot 
(seed protection only)*, 
Wireworm
(seed protection only)*. 
Flea beetle (through 1 
leaf stage). 
Imported fire ant. 
White grub (4)
(4) Reduces feeding damage during 
emergence and seedling stages.
3.35 
(Equivalent to 0.60 
milligrams ai per 
kernel)
0.90 
(Equivalent to 0.16 
milligrams ai per 
kernel)
RATE 
(fluid ounces per 
80,000 units of 
_____seed)_____ 
7.5
(equivalent to 1.34 
milligrams ai per 
kernel)
FIELD CORN SEED: 
CROP

PEST COMMENTS
^Suppression only.
4.0-8.0
2.0-4.0
1.0-2.0
8.0
CROP COMMENT
0.16-0.32 Suppression only.
Grasshopper1.5-3.0
7
mixing until all seeds are covered. After sluny treatment, the addition of dry talc at the rate of % -1 ounce
per 50 pounds of seed is recommended to minimize risk of moisture buildup in the planter.
Popcorn 
(commercial 
seed treatment)
Use Restriction:
• Do not graze or feed livestock on treated areas for 45 days after planting.
Use Restriction:
• Do not graze or feed livestock on treated areas for 45 days after planting.
Flea beetle,
Early-season corn
Mix slurry so that it is applied at a rate 
of 16 - 20 fl. oz. of diluted solution per 
hundredweight of seed.
Reduces possible yellow dwarf virus disease 
from aphid vectoring.
SWEET CORN AND POPCORN SEED: 
CROP
CEREAL GRAIN SEEDS^ ___
PEST
Use the higher listed rate to increase time of 
protection and/or when insect pressure is 
heavy.________________________________
Treated seed may be planted as a 50 to 60 foot 
border around the perimeter of the field to help
Sweet Corn
(commercial 
seed treatment) lleaf aphid,
Use the higher listed rate to increase time of 
protection and/or when insect pressure is 
heavy.
Wheat, Barley,
Oats, Rye, 
Triticale
Aphids 
(including Bird 
cherry-oat,
English grain. 
Greenbug, and 
Russian wheat 
aphid), 
Hessian fly 
Wireworm
Seed corn maggot*. 
Wireworm* 
Imported fire ant, 
Early-season corn 
eaf aphid. 
Seed corn maggot*, 
Wireworm* 
Imported fire ant. 
Seed corn maggot 
(seed protection)*. 
Wireworm 
(seed protection)* 
Wireworm 
(seed protection)* 
Flea beetles
RATE
(fluid ounces 
per
hundredweight 
seed)
1.0-3.0
RATE 
(fluid ounces per 
hundredweight seed)
8.0

damage fromseason
PEST COMMENT
‘Suppression only.
PEST COMMENT
8
Consult your local agricultural extension agent 
for grasshopper control information specific to 
your area.
Sorghum (For end-use application at agricultural establishments):
Shake product well before making slurry and apply using a HCBT or Eight-Bag Batch Treater. May be 
diluted with an approved fungicide for disease control. Mix slurry so that rate is 8 - 10 fluid ounces per 50 
pound bag of seed. Treat 14 of seed with 14 of slurry then add remainder of seed and slurry and continue 
mixing until all seeds are covered. After slurry treatment, the addition of dry talc at the rate of % -1 ounce 
per 50 pounds of seed is recommended to minimize risk of moisture buildup in planter.
Use Restriction:
• Do not graze or feed livestock on treated areas for 45 days after planting.
Use Restriction:
• Do not graze or feed livestock on treated areas for 45 days after planting.
Wheat, Barley, Triticale (For end-use application at agricultural establishments):
Make application using a Total Slurry Treater (TST), Farmer Applied Seed Treater (F.A.S.T.), or other on- 
farm seed treating equipment capable of accurately applying low rates of NITRO SHIELD® IV. Apply 1.0- 
3.0 fl. oz. per hundredweight of seed. NITRO SHIELD® IV may be mixed with a fungicide product for 
protection against disease. NITRO SHIELD® IV may be applied to seed previously treated with a fungicide. 
In this case, dilution is necessary.
Use Restriction:
• Do not graze or feed livestock on treated areas for 45 days after planting.
Use Restriction:
• Do not graze or feed livestock on treated areas for 45 days after planting.
Thorough coverage is necessary for 
optimal control.
minimize early 
grasshoppers.
RATE 
(fluid ounces per 
hundredweight seed)
Aphids (including 
Com leaf, English 
grain, Greenbug, 
and Yellow sugar 
cane aphid).
Chinch bugs.
Imported Fire ants. 
Wireworms*
Use the higher listed rate to increase time of 
protection and/or when insect pressure is 
heavy.
Sorghum,
Millet
SORGHUM AND MILLET SEED: 
CROP
COTTON SEED TREATMENT: 
CROP
RATE 
(fluid ounces per 
hundredweight seed) 
8.0

CROP COMMENT
‘Suppression only.
PEST COMMENT
Soybean
‘Suppression only.
VEGETABLE SEED TREATMENT:
9
Cotton 
(Delinted 
Seed Only)
Seed corn maggot‘ 
Soybean aphid, 
Bean leaf beetle
Will suppress the spread of certain plant 
viruses.
Use Restriction:
• Do not graze or feed livestock on treated areas for 45 days after planting.
Use Restriction:
• Do not graze or feed livestock on treated areas for 45 days after planting.
{1) On a unit of pelleted sugar beet seed 
with a weight ratio of 2:1 pelleting mixture 
to raw seed (seed count 100,000 seed - 
approximately 1 kilogram by weight).
If applying to non-pelleted raw seed, do 
not exceed a rate of 3.0 fluid ounces per 
100,000 seed (approximately 1 Kg by 
weight).
For protection of planted seeds. Use the 
higher listed rates to provide increased 
length of protection and for heavy insect 
pressure.
SUGAR BEET SEED TREATMENT: 
PEST
SOYBEAN SEED TREATMENT: 
CROP
Use Restriction:
• Do not graze or feed livestock on soybean forage or hay.
NITRO SHIELD® IV can be used as an 
over treatment.
Regardless of the type of application 
(seed treatment, soil or foliar) do not apply 
more than a total of 0.4 lb. of imidacloprid 
per acre per calendar year.
Cotton (Delinted Seed Only) (For end-use application at agricultural establishments):
Shake product well before making slurry and apply using a HCBT or Eight-Bag Batch Treater. May be 
diluted with an approved fungicide for disease control. Mix slurry so that rate is 8 - 10 fluid ounces per 50 
pound bag of seed. Treat 14 of seed with 14 of slurry then add remainder of seed and slurry and continue 
mixing until all seeds are covered.
Sugar Beets 
(commercial 
seed 
treatment)
Thrips, 
Aphids
Whitefly,
Aphids/Leafhoppers 
(including vectors that 
may spread Curly top 
and Yellow mosaic 
virus).
Root aphid,
Thrips,
Wireworms‘
16.0
(Equivalent to 0.375 
milligram active 
ingredient per seed)
RATE 
(fluid ounces per 
hundredweight 
_____seed)_____
2.0-4.0
RATE
(fluid ounces 
per 
seed unit) (1) 
3.0 - 6.25

CROP PEST COMMENTS
**Suppression only
8.0
10
Seed com maggot**,
Wireworm**
Use Restrictions:
• Do not graze or feed livestock on treated areas for 45 days after planting.
• *Seed-and-pod vegetable seed treated in California must be destined for planting in states other than 
California and is not to be planted in California.
Rate Fluid ounces per 1000 row feet 
0.4
Use Restrictions:
• Do not apply more than 10.0 fluid ounces per acre (0.31 lb active ingredient per acre) NITRO
SHIELD® IV per crop season when making seed piece treatment applications.
• Do not use treated seed pieces for food, feed, fodder or processing for oil.
• Do not apply any subsequent in furrow application of any imidacloprid product following a seed piece 
treatment.
Rate Fluid ounces per 100 lbs of Seed 
0.2-0.4
Rate Fluid ounces per acre* 
4.0-8.0
Wireworm**,
Bean leaf beetle. 
Imported fire ant, 
Aphid
Rate Fluid ounces per acre 
8.0
POTATO SEED PIECE TREATMENT: 
Pest Controlled__________
Aphids, Colorado potato
beetle, Flea
beetles, Leafhoppers, Potato
psyllid.
Wireworms {seed piece 
protection) ________
Pest/Disease Suppressed
Symptoms of Potato leaf roll 
virus (PLRV), Potato yellows,
Net necrosis_____________
Application Instructions:
Apply specified dosage as a diluted spray onto seed pieces using a shielded spray system. Dilute with 3 
parts water, or less, to 1 part NITRO SHIELD® IV. Agitate or stir spray solution as needed. Fungicidal or 
inert absorbent dusts may be applied after NITRO SHIELD® IV application. Apply only in areas with 
adequate ventilation or in areas that are equipped to remove spray mist or dust. Plant seed pieces as 
soon as possible after treating avoiding prolonged exposure of NITRO SHIELD® IV treated seed pieces to 
sunlight and in accordance with specifications of your local Extension service.
*Based on a seeding rate of 2000 lbs per acre
Adzuki Bean, Asparagus Bean, Broad Bean 
(Succulent Or Dry), Catjang Bean, Chinese 
Longbean, Field Bean, Guar Bean, 
Jackbean, Kidney Bean, Lablab Bean, Lima 
Bean (Succulent or Dry), Moth Bean 
(Succulent or Dry), Mung Bean, Navy Bean, 
Pinto Bean, Rice Bean, Runner Bean, Snap 
Bean, Sword Bean, Tepary Bean, Urd Bean, 
Wax Bean, Yardiong Bean, Blackeyed Pea 
(Succulent or Dry), Chickpea, Cowpea 
(Succulent or Dry), Crowder Pea, Dwarf Pea, 
Edible-Pod Pea, English Pea, Field Pea, 
Garden Pea, Green Pea, Pigeon Pea 
(Succulent or Dry), Snow Pea, Southern Pea 
(Succulent or Dry), Sugar Snap Pea, Grain 
Lupin, Sweet Lupin, White Lupin, White 
Sweet Lupin, Lentil*
Carrot
RATE 
(fluid ounces 
per
hundredweight 
seed) 
2.0-4.0

Do not graze or feed livestock on treated areas for 45 days after planting.
ROTATIONAL PLANT-BACK INTERVALS*
PLANT-IMMEDIATE PLANT-BACK
11
THE FEDERAL SEED ACT REQUIRES THAT BAGS CONTAINING TREATED SEEDS SHALL BE 
LABELED WITH THE FOLLOWING STATEMENTS;
Soybean
Strawberry 
Sugarbeet 
Sunflower
Tomatillo
Tomato 
Triticale
Turnip greens
Watercress
Wheat
THE U.S. ENVIRONMENTAL PROTECTION AGENCY REQUIRES THE FOLLOWING STATEMENTS 
ON BAGS CONTAINING SEEDS TREATED WITH NITRO SHIELD® IV;
• This seed has been treated with imidacloprid insecticide.
• Do not use for feed, food or oil purposes.
SEED BAG LABELING REQUIREMENTS
Seed commercially treated with this product must be labeled in accordance with all applicable 
requirements of the Federal Seed Act. The user of this product is responsible for ensuring that the seed 
bag meets all requirements under the Federal Seed Act.
ROTATIONAL CROPS
Treated areas may be replanted with any crop specified on an imidacloprid label, or any crop for which a 
tolerance exists for the active ingredient, as soon as practical following the last application. The following 
plant-back intervals must be observed for listed crops;
• Pollinator Precautions; Imidacloprid is highly toxic to bees exposed to direct treatment or residues on 
blooming crops or weeds. Ensure that planting equipment is functioning properly in accordance with 
manufacturer specification to minimize seed coat abrasion during planting to reduce dust which can 
drift to blooming crops or weeds.
• Do not graze or feed livestock on treated areas for 45 days after planting Oil Seed Crops (canola, 
rapeseed, mustard seed, flax, crambe, borage, safflower and sunflower). Corn (field, sweet and 
popcorn). Cereal Grains (wheat, barley, oats, rye, and triticale). Sorghum and Millet, Cotton, Sugar 
Beet, Vegetable Seed (beans, peas, and carrots) and Potatoes. For soybeans, do not graze or feed 
livestock forage or hay.
• Store away from feeds and foodstuffs.
• Wear long-sleeved shirt, long pants and chemical-resistant gloves when handling treated seed.
• Treated seeds exposed on soil surface may be hazardous to wildlife. Cover or collect treated seeds 
that are spilled during handling.
• Treated seed must be planted into the soil at a depth of greater than 1 inch.
• Dispose of all excess treated seed. Leftover seed may be double sown around the headland or 
buried away from water sources in accordance with local requirements.
* Cover crops for soil building or erosion control may be planted any time, but do not graze or harvest for 
food or feed.
* For all other crops not listed on an Imidacloprid label, or for crops for which no tolerance for the active 
ingredient has been established, a 12-month plantback interval must be observed.
Artichoke
Barley 
Brassica (cole)
leafy vegetable
Borage
Canola 
Cilantro 
Corn, Field 
Corn, Sweet 
Cotton
Crambe
Cranberry
Cucurbits 
Eggplant 
Flax
Groundcherry
Leaf petiole 
vegetables
Leafy vegetables 
Legume vegetables 
(succulent or dried, 
including soybean)
Mustard seed
Oats 
Okra 
Pepinos 
Pepper 
Popcorn 
Potato 
Rapeseed
Root and Tuber 
Vegetables
Sorghum
30-DAY
BACK
Cereals, including
buckwheat 
millet 
rice 
rye
Safflower

12
Pressure rinse as follows (all sizes): Empty the remaining contents into application equipment or a mix 
tank and continue to drain for 10 seconds after the flow begins to drip. Hold container upside down over 
application equipment or mix tank or collect rinsate for later use or disposal. Insert pressure rinsing nozzle 
in the side of the container, and rinse at about 40 PSI for at least 30 seconds. Drain for 10 seconds after 
the flow begins to drip.
(non-refillable <5 gallons): Triple rinse as follows; Empty the remaining contents into application 
equipment or a mix tank and drain for 10 seconds after the flow begins to drip. Fill the container % full with 
water and recap. Shake for 10 seconds. Pour rinsate into application equipment or a mix tank or store 
rinsate for later use or disposal. Drain for 10 seconds after the flow begins to drip. Repeat this procedure 
two more times.
(non-refillable >5 gallons): Triple rinse as follows; Empty the remaining contents into application 
equipment or a mix tank. Fill the container % full with water. Replace and tighten closures. Tip container 
on its side and roll it back and forth, ensuring at least one complete revolution, for 30 seconds. Stand the 
container on its end and tip it back and forth several times. Empty the rinsate into application equipment 
or a mix tank or store rinsate for later use or disposal. Repeat this procedure two more times.
STORAGE AND DISPOSAL
PROHIBITIONS: Do not contaminate water, food or feed by storage, disposal, or by cleaning of equipment. 
Do not reuse empty container. Open dumping is prohibited.
PESTICIDE STOf^GE: Store in a cool place. Do not store in direct sunlight. Protect from freezing 
temperatures.
PESTICIDE DISPOSAL: Wastes resulting from the use of this product may be disposed of on site or at an 
approved waste disposal facility.
CONTAINER DISPOSAL:
Non-refillable containers (1,2.5,30 & 55 gallon): Do not reuse or refill this container. Offer for recycling, 
if available. Triple rinse or pressure rinse container (or equivalent) promptly after emptying.
• Do not contaminate water bodies when disposing of planting equipment wash water.
• Dispose of seed packaging in accordance with local requirements.
• In the event of crop failure or harvest of a crop grown from NITRO SHIELD® IV treated seed, the field 
may be replanted immediately to artichoke, barley, borage. Brassica (cole) leafy vegetables, canola, 
cilantro, corn (field or sweet), cotton, crambe, cranberry, cucurbits, eggplant, flax, groundcherry, leafy 
petiole vegetables, leafy vegetables, legume vegetables (succulent or dried), mustard seed, oats,
okra, pepinos, pepper, popcorn, potato, rapeseed, sorghum, soybean, strawberry, sugarbeet, 
sunflower, tomatillo, tomato, triticale, turnip greens, root and tuber vegetables, watercress, and 
wheat. For cereals, including buckwheat, millet, rice and rye and for safflower, the minimum plant 
back interval is 30 days from the date NITRO SHIELD® IV treated seed was planted. Cover crops for 
soil building or erosion control may be planted at any time, but do not graze or harvest for food or 
feed. For all other crops not listed on an imidacloprid label, or for crops for which no imidacloprid 
tolerance for the active ingredient has been established, a 12 month plant-back interval must be 
observed.
• Do not allow children, pets, or livestock to have access to treated seed.
• The maximum application rate (all imidacloprid uses; seed treatment, foliar application, soil 
application) per acre per year for imidacloprid is 0.4 lb. Do not use more than 0.4 lb. (181.44 g) 
imidacloprid per acre per calendar year.
• This seed has been treated with X mg imidacloprid per seed.
• Do not apply a neonicotinoid insecticide within 45 days of planting seed treated with NITRO SHIELD® 
IV.
• Excess treated seed may be used for ethanol production only if (1) by-products are not used for 
livestock feed and (2) no measurable residues of pesticides remain in the ethanol by products that 
are used in agronomic practice.
• Rape greens grown and harvested from NITRO SHIELD® IV treated seed must not be used for human 
and feed consumption. Rapeseed grown and harvested from treated seed is only for industrial uses 
and cannot be used for edible oil or any other human/feed consumption.

NITRO SHIELD® is a registered trademark of Winfield Solutions, LLC.
13
LIMITATION OF LIABILITY
TO THE EXTENT CONSISTENT WITH APPLICABLE LAW, IN NO EVENT SHALL MANUFACTURER OR 
SELLER BE LIABLE FOR SPECIAL, INCIDENTAL, OR CONSEQUENTIAL DAMAGES, OR FOR 
DAMAGES IN THE NATURE OF PENALTIES RELATING TO THE GOODS SOLD, INCLUDING USE, 
APPLICATION, HANDLING, AND DISPOSAL. MANUFACTURER OR SELLER SHALL NOT BE LIABLE 
TO BUYER OR USER BY WAY OF INDEMNIFICATION TO BUYER OR TO CUSTOMERS OF BUYER, 
IF ANY, OR FOR ANY DAMAGES OR SUMS OF MONEY, CLAIMS OR DEMANDS WHATSOEVER, 
RESULTING FROM OR BY REASON OF, OR RISING OUT OF THE MISUSE, OR FAILURE TO FOLLOW 
LABEL WARNINGS OR INSTRUCTIONS FOR USE, OF THE GOODS SOLD BY MANUFACTURER OR 
SELLER TO BUYER. ALL SUCH RISKS SHALL BE ASSUMED BY THE BUYER, USER, OR ITS 
CUSTOMERS. BUYER ’S OR USER ’S EXCLUSIVE REMEDY, AND MANUFACTURER ’S OR SELLER ’S 
TOTAL LIABILITY SHALL BE FOR DAMAGES NOT EXCEEDING THE COST OF THE PRODUCT.
If you do not agree with or do not accept any of directions for use, the warranty disclaimers, or limitations 
on liability, do not use the product, and return it unopened to the Seller, and the purchase price will be 
refunded.
FOR CHEMICAL EMERGENCY: Spill, leak, fire, exposure or accident, call 
CHEMTREC 1-800-424-9300.
Refillable container (250 gallon & bulk): Refill this container with pesticide only. Do not reuse this 
container for any other purpose. Cleaning the container before final disposal is the responsibility of the 
person disposing of the container. Cleaning before refilling is the responsibility of the refiller.
To clean the container before final disposal, empty the remaining contents from this container into 
application equipment or mix tank. Fill the container about 10 percent full with water. Agitate vigorously or 
recirculate water with the pump for 2 minutes. Pour or pump rinsate into application equipment or rinsate 
collection system. Repeat this rinsing procedure two more times.
WARRANTY DISCLAIMER
The directions for use of this product must be followed carefully. TO THE EXTENT CONSISTENT WITH 
APPLICABLE LAW, (1) THE GOODS DELIVERED TO YOU ARE FURNISHED “AS IS ” BY 
MANUFACTURER OR SELLER AND (2) MANUFACTURER AND SELLER MAKE NO WARRANTIES, 
GUARANTEES, OR REPRESENTATIONS OF ANY KIND TO BUYER OR USER, EITHER EXPRESS OR 
IMPLIED, OR BY USAGE OF TRADE, STATUTORY OR OTHERWISE, WITH REGARD TO THE 
PRODUCT SOLD, INCLUDING, BUT NOT LIMITED TO MERCHANTABILITY, FITNESS FOR A 
PARTICULAR PURPOSE, USE, OR ELIGIBILITY OF THE PRODUCT FOR ANY PARTICULAR TRADE 
USAGE. UNINTENDED CONSEQUENCES, INCLUDING BUT NOT LIMITED TO INEFFECTIVENESS, 
MAY RESULT BECAUSE OF SUCH FACTORS AS THE PRESENCE OR ABSENCE OF OTHER 
MATERIALS USED IN COMBINATION WITH THE GOODS, OR THE MANNER OF USE OR 
APPLICATION, INCLUDING WEATHER, ALL OF WHICH ARE BEYOND THE CONTROL OF 
MANUFACTURER OR SELLER AND ASSUMED BY BUYER OR USER. THIS WRITING CONTAINS ALL 
OF THE REPRESENTATIONS AND AGREEMENTS BETWEEN BUYER, MANUFACTURER AND 
SELLER, AND NO PERSON OR AGENT OF MANUFACTURER OR SELLER HAS ANY AUTHORITY TO 
MAKE ANY REPRESENTATION OR WARRANTY OR AGREEMENT RELATING IN ANY WAY TO THESE 
GOODS.