a97107de46
Image rebuild (skip scrape) / build (push) Failing after 1h37m12s
Dockerfile: self-contained image with corpus + Chroma + BM25 baked in. Drawbar's compose pulls + runs without volume mounts. Built from sources.json (labels schema), PRODUCT_NAME=crop_chem by default, HYBRID_SEARCH=true (always-on for production quality). RERANK_URL + OLLAMA_URL get set at compose time. .gitea/workflows/refresh.yml: monthly cron (1st @ 06:00 UTC) does full scrape → reindex → image push. Scrapes Bayer (~30 min) + EPA PPLS row-crop filtered (~7h). Skips reindex+push if no corpus diff. Tags pushed: :latest, :<sha12>, :corpus-<YYYY.MM.DD>. .gitea/workflows/image-only.yml: on-demand or auto on code-only pushes to main (paths: docs_mcp/, rag/, scrape/, requirements.txt, Dockerfile, sources.json). Reindexes from committed corpus, builds image, pushes. ~10 min vs ~9h full refresh. .gitignore: corpus/ now COMMITTED (4,159 labels, 265 MB of .md + sidecars). Lets image-only.yml rebuild indexes without re-scraping. chroma/ + bm25/ still gitignored (regenerable binary indexes). .dockerignore: drops venv, eval results, PLAN/README/CLAUDE.md, deploy/, .git/ — keeps the image lean. corpus + chroma + bm25 explicitly NOT in dockerignore (those go INTO the image). Co-Authored-By: Claude Opus 4.7 (1M context) <noreply@anthropic.com>
359 lines
21 KiB
Markdown
359 lines
21 KiB
Markdown
# DREXEL DEFOL 750
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- EPA Reg No: **19713-486**
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- Registrant: DREXEL CHEMICAL COMPANY
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- Signal word: Caution
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- Active ingredients: Sodium chlorate (52%)
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- Label accepted: 2015-04-21
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- Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/019713-00486-20150421.pdf
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---
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UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
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WASHINGTON, DC 20460
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Notification Label Acceptable v.20150320
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OFFICE OF CHEMICAL SAFETY
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AND POLLUTION PREVENTION
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April 21, 2015
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Luz G. Chan
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Registration Manager
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Drexel Chemical Company
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P.O. Box 13327
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Memphis, TN 38113-0327
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Subject: Notification per PRN 98-10 – Revising First Aid statement etc.
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Product Name: Drexel Defol 750
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EPA Registration Number: 19713-486
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Application Date: April 1, 2015
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Decision Number: 503212
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Dear Ms. Chan:
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The Agency is in receipt of your Application for Pesticide Notification under Pesticide
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Registration Notice (PRN) 98-10 for the above referenced product. The Registration Division
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(RD) has conducted a review of this request for its applicability under PRN 98-10 and finds that
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the action requested falls within the scope of PRN 98-10.
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The label submitted with the application has been stamped “Notification” and will be placed in
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our records.
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If you have any questions, you may contact Shanta Adeeb at 703-347-0502 or via email at
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adeeb.shanta@epa.gov.
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Sincerely,
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Reuben Baris, Product Manager 25
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Herbicide Branch
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Registration Division (7505P)
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Office of Pesticide Programs
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Page1of7
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Skokokojdd
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ACTIVE INGREDIENT:
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Sodium chlorate.............................................................................................................................. 52.0%
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OTHER INGREDIENTS: ……..................................................................................................... 48.0%
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TOTAL: .........................................................................................................................................100.0%
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This product contains 7.5 pounds of Sodium chlorate per gallon.
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KEEP OUT OF REACH OF CHILDREN
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CAUTION
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6HH),567$,'%HORZ
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SHAKE WELL BEFORE USING
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[Optional: Recirculate Contents Before Use]
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EPA Reg. No. 19713-486
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EPA Est. No. 19713-XX-XXX Net Content:______
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FIRST AID
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IF IN EYES:
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• Hold eye open and rinse slowly and gently with water for 15 to 20 minutes.
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• Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye.
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• Call a poison control center or doctor for treatment advice.
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IF SWALLOWED:
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• Call a poison control center or doctor immediately for treatment advice.
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• Have person sip a glass of water if able to swallow.
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• Do not induce vomiting unless told to do so by a poison control center or doctor.
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• Do not give anything by mouth to an unconscious or convulsing person.
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IF ON SKIN OR CLOTHING:
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• Take off contaminated clothing.
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• Rinse skin immediately with plenty of water for 15 to 20 minutes.
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• Call a poison control center or doctor for treatment advice.
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Have the product container or label with you when calling a poison control center or doctor, or going for
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treatment. You may also contact CHEMTREC at 800-424-9300 for emergency.
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486SPͲ0315*P
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Defol® 750
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Defoliant/Desiccant with Fire Retardant
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19713-486
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04/21/2015
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Page2of7
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PRECAUTIONARY STATEMENTS
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Hazards to Humans and Domestic Animals
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CAUTION: Causes moderate eye irritation. Avoid contact with eyes or clothing.
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PERSONAL PROTECTIVE EQUIPMENT (PPE)
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Some materials that are chemical-resistant to this product are made of any waterproof material such as
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polyethylene or polyvinyl chloride. If you want more options, follow the instructions for category A on an
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EPA chemical-resistance category selection chart.
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All mixers, loaders, applicators, and other handlers must wear: Long-sleeved shirt and long pants,
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shoes, and socks.
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Follow manufacturer’s instructions for cleaning/maintaining PPE. If no such instructions for washables
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exist, use detergent and hot water. Keep and wash PPE separately from other laundry.
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Discard clothing and other absorbent materials that have been drenched or heavily contaminated with
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this product's concentrate. Do not reuse them.
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See engineering controls for additional requirements.
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Enclosed Cockpits/Cabs: Applicators must use an enclosed cockpit or enclosed cab that meets the
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requirements listed in the Worker Protection Standard (WPS) for agricultural pesticides [40 CFR 170.240
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(d)(6)].
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USER SAFETY RECOMMENDATIONS
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Users should: 1) Wash hands before eating, drinking, chewing gum, using tobacco or using the toilet.
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2) Remove clothing/PPE immediately if pesticide gets inside. Then wash thoroughly and put on clean
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clothing. 3) Remove PPE immediately after handling this product. Wash the outside of gloves before
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removing. As soon as possible, wash thoroughly and change into clean clothing.
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ENVIRONMENTAL HAZARDS
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Do not apply directly to water or to areas where surface water is present or to intertidal areas below the
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mean high water mark. Do not apply when weather conditions favor drift from areas treated. Do not
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contaminate water when disposing of equipment washwater or rinsate.
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DIRECTIONS FOR USE
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It is a violation of Federal law to use this product in a manner inconsistent with its labeling. Do not apply
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this product through any type of irrigation system. Do not apply this product in a way that will contact
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workers or other persons, either directly or through drift. Only protected handlers may be in the area during
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application. For any requirements specific to your State or Tribe, consult the agency responsible for
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pesticide regulation.
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AGRICULTURAL USE REQUIREMENTS
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Use this product only in accordance with its labeling and with the Worker Protection Standard (WPS), 40
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CFR Part 170. This standard contains requirements for the protection of agricultural workers on farms,
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forests, nurseries, greenhouses and handlers of agricultural pesticides. It contains requirements for
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training, decontamination, notification and emergency assistance. It also contains specific instructions
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and exceptions pertaining to the statements on this label about personal protective equipment (PPE) and
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restricted entry interval (REI). The requirements in this box only apply to uses of this product that are
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covered by the WPS.
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Do not enter or allow worker entry into treated areas during the REI of 12 hours.
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PPE required for early entry to treated areas that is permitted under the WPS and that involves contact
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with anything that has been treated, such as plants, soil or water is: Coveralls, shoes and socks, and
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chemical-resistant gloves made of any waterproof material.
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Page3of7
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APPLICATION
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DEFOL 750 may be applied by aircraft or ground equipment. It is essential that the foliage be thoroughly
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covered. The specified dilution rates should be carefully observed. A non-ionic surfactant such as Surf-Ac®
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820 or an emulsifiable crop oil such as Peptoil™ may enhance the results. This product should not be mixed
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with insecticides or other organic materials, unless specifically recommended, because a fire or explosion
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may result.
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Precautions should be taken to avoid having spray or spray drift contact adjacent crops or desirable
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vegetation or they may be defoliated. Equipment should be washed before and after use and care should
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be taken so that product does not dry in tank or on spray nozzles. Washwater should not be allowed to
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contact desirable vegetation.
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When using this product under dry land conditions, injury may occur to rotational crops.
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SPRAY DRIFT MANAGEMENT
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A variety of factors including weather conditions (e.g., wind direction, wind speed, temperature, relative
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humidity) and method of application can influence pesticide drift. The applicator must evaluate all factors
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and make appropriate adjustments when applying this product.
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Wind Speed
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Do not apply at wind speeds greater than 15 mph.
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Droplet Size
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Apply as a medium or coarser spray (ASAE Standard 572).
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Temperature Inversions
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If applying at wind speeds less than 3 mph, the applicator must determine if: a) conditions of temperature
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inversion exist, or b) stable atmospheric conditions exist at or below nozzle height.
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Do not make applications into areas of temperature inversions or stable atmospheric conditions.
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Other State and Local Requirements
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Applicators must follow all state and local pesticide drift requirements regarding application of sodium
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chlorate. Where states have more stringent regulations, they must be observed.
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Equipment
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All application equipment must be properly maintained and calibrated using appropriate carriers or
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surrogates.
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Additional Requirements for Aerial Applications
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1. The boom length must not exceed 75% of the wingspan or 90% of the rotor blade diameter.
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2. Release spray at the lowest height consistent with efficacy and flight safety. Do not release spray at a
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height greater than 10 feet above the crop canopy unless a greater height is required for aircraft safety.
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3. When applications are made with a crosswind, the swath must be displaced downwind. The applicator
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must compensate for this displacement at the up and downwind edge of the application area by adjusting
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the path of the aircraft upwind.
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Additional Requirement for Groundboom Application
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Do not apply with a nozzle height greater than 4 feet above the crop canopy.
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DEFOLIATION
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Ideally, defoliation is favored on clear, calm, sunny days with high temperatures and high humidity. If rain
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is anticipated within 24 hours, application should be delayed whenever possible. Defoliation may be slowed
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when daytime temperatures are below about 60°F and with some crops, especially with vigorous varieties,
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regrowth can occur.
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In order to obtain acceptable defoliation results, the crop must be fully mature. In most cases, the signs of
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maturity include:
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1. A slight discoloration of the foliage is apparent, often with a yellowish or reddish tinge.
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2. Vegetative growth has slowed or ceased, with little or no secondary growth.
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3. A slight downward pull on a leaf gives a clean break from the stalk.
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Page4of7
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Adequate fertility, ample soil moisture, good insect control and good weed control also favor defoliation.
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Plants which have been under stress as from drought or insect pressure give less reliable results because
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tough, wilted or damaged leaves do not permit the proper uptake of the chemical and tend to inhibit the
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formation of an abscission layer. Typically, under such circumstances, the leaves are desiccated but do not
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drop, which in turn, often causes problems with excessive trash during harvesting.
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For crops where there is a heavy canopy of foliage, obtaining thorough coverage is sometimes difficult.
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Whenever practical, the use of ground equipment should be considered. The higher dilution rates should
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be used and any other available methods employed which will assure that the plants are completely covered
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all the way to the bottom leaves. If coverage is incomplete, a second application may be necessary in order
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to defoliate the lower leaves and to prevent secondary growth.
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DESICCATION
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When the objective is to reduce crop moisture or to desiccate weeds prior to harvest, most of the points
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discussed under “DEFOLIATION” are applicable. Incomplete coverage will give erratic results, especially
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with vines such as Morningglory where the slender stems may be sheltered from the spray by the crop
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canopy, leaving the vines succulent and tough so they will become entangled in the harvesting machinery.
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Once again, larger spray volume will encourage more complete coverage and more reliable desiccation.
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CROPS
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Crop Rate Per Acre (qts.) Water (gals.)
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Chili peppers 1.6 to 4 Air: 5 to 15
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Ground: 20 to 40
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SPECIFIC DIRECTIONS: Apply 10 days before harvest. To be used on Peppers for processing only.
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Consult a processor before applying.
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Corn 3.2 Air: 5 to 7
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Ground: 10 to 20
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SPECIFIC DIRECTIONS: Use as a harvest aid to desiccate trashy weeds in early maturing Corn. Apply
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at least 14 days before anticipated harvest date. Use the low dilution rates when weeds are small and
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the crop canopy is fairly open. Desiccation of Morningglory and other vines may be erratic. DO NOT
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graze treated fields or feed fodder, forage or residual grain within 14 days of application.
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Cotton 1.6 to 3.2 Air: 5 to 10
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Ground: 10 to 20
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SPECIFIC DIRECTIONS: Apply no later than 7 days before harvest. The Cotton plants should be mature
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with the youngest bolls expected to make Cotton being at least 30 days old. Thorough coverage is
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essential. DO NOT graze treated fields or feed gin waste to livestock. DO NOT apply more than 3.2
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quarts per acre per application. A maximum of one application per year is permitted, except in California,
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where a maximum of two applications per year is permitted.
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Dry beans 3.2 Air: 5 to 10
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Ground: 10 to 20
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SPECIFIC DIRECTIONS: Thorough coverage is essential. Make application 7 to 10 days before
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anticipated harvest, longer if temperatures are cool. DO NOT graze treated fields or feed treated fodder
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or forage to livestock.
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Flax 3.2 Air: 5 (min.)
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Ground: 10 (min.)
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SPECIFIC DIRECTIONS: Use as a harvest aid to desiccate trashy weeds and to reduce moisture in the
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mature crop. Apply 7 to 10 days before anticipated harvest date. Activity of the spray will be enhanced
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by addition of a good non-ionic surfactant at the rate of 1 quart per 100 gallons of spray. DO NOT graze
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treated fields or feed treated foliage and fodder for 14 days after application.
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Page5of7
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Crop Rate Per Acre (qts.) Water (gals.)
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Grain sorghum 2.4 to 3.2 Air: 5 to 10
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Ground: 10 to 20
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SPECIFIC DIRECTIONS: To reduce the moisture content of the grain while the crop is standing, apply
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7 to 10 days before harvest. Use the lower rates when grain moisture is low and the weather is clear and
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dry. Use the higher rate when conditions for desiccation are poor.
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Guar beans 3.2 Air: 5 to 10
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Ground: 10 to 20
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SPECIFIC DIRECTIONS: Use to facilitate harvest and reduce moisture in the fully mature seed heads.
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Make application 7 to 10 days before anticipated harvest date. DO NOT graze treated fields or feed
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treated fodder or forage to livestock.
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Potatoes 3.2 Air: 5 to 10
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Ground: 10 to 20
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SPECIFIC DIRECTIONS: To defoliate plants and facilitate harvest, apply 10 days before harvest. DO
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NOT apply under conditions of extreme heat during the middle of the day.
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Rice 2.4 to 3.2 Air: 5 (min.)
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Ground: 10 to 20
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SPECIFIC DIRECTIONS: Use to facilitate harvest and reduce moisture in the fully mature seed heads
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and to desiccate immature Red rice in mature White rice. Use the lower rate when crop conditions and
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weather are right to enhance rapid drying. Apply 7 to 10 days before anticipated harvest. To avoid drift,
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do not apply during windy weather. Thorough coverage of the crop is essential to achieve good results.
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DO NOT graze treated fields or feed treated straw or crop residues within 14 days of application.
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Safflower 3.2 Air: 5 to 10
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Ground: 20 to 30
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SPECIFIC DIRECTIONS: Use to facilitate harvest and reduce moisture in the fully mature seed heads.
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Make application 7 or more days before normal harvest when Safflower heads are fully mature. DO NOT
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graze treated fields or feed treated forage.
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Southern peas 3.2 Air: 5 to 10
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Ground: 10 to 20
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SPECIFIC DIRECTIONS: Thorough coverage is essential. Make application 7 to 10 days before
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anticipated harvest, longer if temperatures are cool. DO NOT graze treated fields or feed treated fodder
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or forage to livestock.
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Soybeans 3.2 Air: 5 (min.)
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Ground: 20 (min.)
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SPECIFIC DIRECTIONS: Use as a harvest aid to dry weeds in early maturing Soybeans and to facilitate
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the harvest. Make application 7 to 10 days before anticipated harvest date when beans are mature and
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ready for harvest. DO NOT graze treated fields or feed treated forage.
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Sunflowers 3.2 Air: 5 to 10
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Ground: 20 to 30
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SPECIFIC DIRECTIONS: Use to facilitate harvest and reduce moisture in fully mature seed heads. When
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applying by ground, apply with a high clearance sprayer. Make application 7 or more days before normal
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harvest when Sunflower heads are fully mature. DO NOT apply later than 7 days before harvest. DO
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NOT graze treated fields or feed treated forage within 14 days of application.
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Wheat 3.2 Air: 5 (min.)
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Ground: 10 (min.)
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SPECIFIC DIRECTIONS: Use as desiccant on Wheat. DO NOT apply more than 3.2 quarts per acre.
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DO NOT harvest wheat within 3 days of application.
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Page6of7
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STORAGE AND DISPOSAL
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Do not contaminate water, food or feed by storage or disposal.
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PESTICIDE STORAGE: Storage should be under lock and key and secure from access by unauthorized
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persons and children. Storage should be in a cool, dry area away from any heat or ignition source. Do
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not stack over 2 pallets high. Move containers by handles or cases. Do not move containers from one
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area to another unless they are securely sealed. Keep container tightly sealed when not in use. Keep
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away from any puncture source. Avoid storage near water supplies, food, feed and fertilizer to avoid
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contamination. Store in original containers only. Unloading storage and work areas must be as clean as
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possible to prevent contamination if spilled. If the contents are leaking or material is spilled, follow these
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steps:
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1. Contain spill. Absorb with a material such as sawdust, clay granules or dirt.
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2. Collect and place in suitable containers for disposal.
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3. Wash area with soap and water to remove remaining pesticide.
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4. Follow washing with clean water rinse.
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5. Wash contaminated clothing immediately.
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6. Do not allow runoff to enter sewer or contaminate water supplies.
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7. Dispose of waste as indicated below:
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PESTICIDE DISPOSAL: Wastes resulting from the use of this product must be disposed of on site or at
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an approved waste disposal facility.
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CONTAINER HANDLING:
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Nonrefillable Container (rigid material; less than 5 gallons): Nonrefillable container. Do not reuse or
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refill this container. Offer for recycling, if available. Clean container promptly after emptying. Triple rinse
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as follows: Empty the remaining contents into application equipment or a mix tank and drain for 10
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seconds after the flow begins to drip. Fill the container one-fourth full with water and recap. Shake for 10
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seconds. Pour rinsate into application equipment or a mix tank or store rinsate for later use or disposal.
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Drain for 10 seconds after the flow begins to drip. Repeat this procedure two more times. Dispose of
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empty container in a sanitary landfill or by incineration, or, if allowed by State and local authorities, by
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burning. If burned, stay out of smoke.
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Nonrefillable Container (rigid material; 5 gallons up to < 250 gallons): Nonrefillable container. Do
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not reuse or refill this container. Offer for recycling, if available. Clean container promptly after emptying.
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Triple rinse as follows: Empty the remaining contents into application equipment or a mix tank. Fill the
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container one-fourth full with water. Replace and tighten closures. Tip container on its side and roll it
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back and forth, ensuring at least one complete revolution, for 30 seconds. Stand the container on its end
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and tip it back and forth several times. Turn the container over onto its other end and tip it back and forth
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several times. Empty the rinsate into application equipment or a mix tank or store rinsate for later use or
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disposal. Repeat this procedure two more times. Dispose of empty container in a sanitary landfill or by
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incineration, or if allowed by State and local authorities, by burning. If burned, stay out of smoke.
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Refillable Containers (> 250 gallons & Bulk): Refillable container. Refill this container with pesticide
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only. Do not reuse this container for any other purpose. Cleaning the container before final disposal is
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the responsibility of the person disposing of the container. Cleaning before refilling is the responsibility
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of the refiller. To clean the container before final disposal, empty the remaining contents from this
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container into application equipment or mix tank. Fill the container about 10% full with water. Agitate
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vigorously or recirculate water with the pump for 2 minutes. Pour or pump rinsate into application
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equipment or rinsate collection system. Repeat this rinsing procedure two more times.
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Page7of7
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WARRANTY—CONDITIONS OF SALE
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OUR DIRECTIONS FOR USE of this product are based upon tests believed reliable. Follow directions
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carefully. Timing and method of application, weather and crop conditions, mixtures with other chemicals
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not specifically directed and other influencing factors in the use of this product are beyond the control of the
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Seller. To the extent consistent with applicable law, Buyer assumes all risks of use, storage and handling
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of this material not in strict accordance with directions given herewith. To the extent consistent with
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applicable law, in no case shall the Manufacturer or the Seller be liable for consequential, special or indirect
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damages resulting from the use or handling of this product when such use and/or handling is not in strict
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accordance with directions given herewith. The foregoing is a condition of sale by the Seller and is accepted
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as such by the Buyer.
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Manufactured By: Defol, Surf-AC, Peptoil and the Drexel logo are trademarks or registered trademarks of Drexel Chemical Company.
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