a97107de46
Image rebuild (skip scrape) / build (push) Failing after 1h37m12s
Dockerfile: self-contained image with corpus + Chroma + BM25 baked in. Drawbar's compose pulls + runs without volume mounts. Built from sources.json (labels schema), PRODUCT_NAME=crop_chem by default, HYBRID_SEARCH=true (always-on for production quality). RERANK_URL + OLLAMA_URL get set at compose time. .gitea/workflows/refresh.yml: monthly cron (1st @ 06:00 UTC) does full scrape → reindex → image push. Scrapes Bayer (~30 min) + EPA PPLS row-crop filtered (~7h). Skips reindex+push if no corpus diff. Tags pushed: :latest, :<sha12>, :corpus-<YYYY.MM.DD>. .gitea/workflows/image-only.yml: on-demand or auto on code-only pushes to main (paths: docs_mcp/, rag/, scrape/, requirements.txt, Dockerfile, sources.json). Reindexes from committed corpus, builds image, pushes. ~10 min vs ~9h full refresh. .gitignore: corpus/ now COMMITTED (4,159 labels, 265 MB of .md + sidecars). Lets image-only.yml rebuild indexes without re-scraping. chroma/ + bm25/ still gitignored (regenerable binary indexes). .dockerignore: drops venv, eval results, PLAN/README/CLAUDE.md, deploy/, .git/ — keeps the image lean. corpus + chroma + bm25 explicitly NOT in dockerignore (those go INTO the image). Co-Authored-By: Claude Opus 4.7 (1M context) <noreply@anthropic.com>
402 lines
20 KiB
Markdown
402 lines
20 KiB
Markdown
# GUSTAFSON CAPTAN 400
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- EPA Reg No: **264-931**
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- Registrant: BAYER CROPSCIENCE, LLC
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- Signal word: Danger
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- Active ingredients: Captan (37.4%)
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- Label accepted: 2011-02-22
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- Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/000264-00931-20110222.pdf
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---
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r(
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UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
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WASHINGTON, D.C. 20460
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Larry R. Hodges
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Bayer CropScience LP
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2 T.W. Alexander Drive
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Research Triangle Park, NC 27709
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SUBJECT: Amended Registration
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OFFICE OF CHEMICAL
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SAFETY AND POLLUTION PREVENTION
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FEB 2 2 2011
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Captan 400 Seed Protectant Agricultural Fungicide
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EPA Reg. No. 264-931; Decision # 444457
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Your Submission Dated January 13, 2011
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Dear Mr. Hodges:
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The amended labeling referred to above, submitted in connection with registration under
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the Federal Insecticide Fungicide and Rodenticide Act (FIFRA), as amended to make changes
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per PRN 2007-4 has been reviewed and found acceptable. A copy ofthe label stamped
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"accepted" is enclosed.
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Submit one copy of your final printed labeling before you release the product for
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shipment.
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If you have any questions regarding this correspondence, contact Rose Kearns of my staff
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by phone at 703-305-5611 or via email at kearns.rosemary@epa.gov or myself at 703-308-9443
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or via email at kish.tony@epa.gov.
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Enclosure
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C A PTA N 400 Seed Protectant Agricultural
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Fungicide
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Contains 4lbs. Captan and related derivatives per U.S. gallon at 68°F.
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ACTIVE INGREDIENTS (% by weight):
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*Captan ..........................................................................................................•.............................................................. 37.40%
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Related Derivatives ......................................................................................................................................................... 0.85%
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INERT INGREDIENTS: ................................................................................................................................................ 61.75%
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TOTAL 100.00%
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*N-trichloromethylthio-4-cyclohexene-1 ,2-dicarboximide
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E.P.A Reg. No. 264-931 E.P.A Est.
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KEEP OUT OF REACH OF CHILDREN
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DANGER PELIGRO
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Si Usted no entiende la etiqueta, busque a alguien para que se la explique a Usted en detalle. (If you do not understand
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the label, find someone to explain it to you in detail.)
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For MEDICAL And TRANSPORTATION Emergencies ONLY Call 24 Hours A Day 1-800-334-7577
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For PRODUCT USE Information Call1-866-99BAYER (1-866-992-2937)
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FIRST AID
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IF IN EYES: • Hold eye open and rinse slowly and gently with water for 15-20 minutes.
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• Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye.
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• Call a poison control center or doctor for treatment advice.
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IF SWALLOWED: • Call a poison control center or doctor immediately for treatment advice.
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• Have person sip a glass of water if able to swallow.
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• Do not induce vomiting unless told to do so by a poison control center or doctor.
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• Do not give anything by mouth to an unconscious person. ecce
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c
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IF INHALED: Move person to fresh air.
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,"ecL
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• c c
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• If person is not breathing, call 911 or an ambulance, then give artificial respirati2\1~ j)',Gferably
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mouth-to-mouth if possible.
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CLL[(C c
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l C C
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• Call a poison control center or doctor for treatment advice. c c' c c
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(' { C C C
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CCCLCC C
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IFON SKIN OR • Take off contaminated clothing. c c
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c c co c
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CLOTHING: c c c
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• Rinse skin immediately with plenty of water for 15-20 minutes. eeL L C C C C
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l L
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L L /.... t.. t- C
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• Call a poison control center or doctor for treatment advice. "
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Note to Physician: Probable mucosal damage may contraindicate the use of gastric lavage.
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L L <- .. <. c
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L
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In case of emergency call toll free the BayerCropScience Emergency Response telephone No. 1-800~334-<;"577.
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(
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Have a product container or label with you when calling a poison control center or doctor, or going for treatment.
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See additional precautionary statements.
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PRECAUTIONARY STATEMENTS
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HAZARDS TO HUMANS AND DOMESTIC ANIMALS
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DANGER
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Corrosive. Causes irreversible eye damage. Harmful if swallowed or inhaled. May cause allergic skin reactions. Do not
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get in eyes. Wear goggles or face shield when handling. Avoid contact with skin and clothing. Wash thoroughly with
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soap and water after handling and before eating, drinking, chewing gum, or using tobacco or the toilet. Remove and
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separately launder clothing before reuse.
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f··
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PERSONAL PROTECTIVE EQUIPMENT (PPE):
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Some materials that are chemical-resistant to this product are barrier laminate, nitrile rubber or neoprene rubber. If you
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want more options, follow the instructions for category E on an EPA chemical-resistance category selection chart.
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All mixers, loaders, applicators and other handlers must wear:
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-long-sleeved shirt and long pants or a coverall that covers all parts of the body except the head, hands and feet
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-shoes plus socks
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-chemical resistant gloves made of any waterproof material such as barrier laminate, nitrile rubber or neoprene rubber
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-chemical resistant apron
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Follow manufacturer's instructions for cleaning / maintaining PPE. If no such instructions for washables, use detergent
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and hot water. Keep and wash PPE separately from other laundry.
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User Safety Recommendations
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• Users should wash hands before eating, drinking, chewing gum, using tobacco or using the toilet.
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• Users should remove clothingiPPE immediately if pesticide gets inside. Then wash thoroughly and put on clean
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clothing.
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• Users should remove PPE immediately after handling this product. Wash the outside of gloves before removing. As
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soon as possible, wash thoroughly and change into clean clothing.
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• Clothing and protective equipment heavily contaminated or drenched with captan must be destroyed according to
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state and local regulations.
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• AFTER WORK: Take off all clothes and shoes. Shower using soap and water. Do not wear contaminated clothing.
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Wash protective clothing and equipment with soap and water after each use. Personal clothing worn during use must
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be laundered separately from household articles.
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Engineering Controls
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When handlers use closed systems designed by the manufacturer to enclose the pesticide to prevent it from contacting
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handlers or other people AND the system is functioning properly and is used and maintained in accordance with the
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manufacturer's written operating instructions, the handlers need only wear long-sleeve shirt, long pants, chemical
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resistant gloves, shoes, and socks. However, the respirator must be immediately available for use in an emergency, such
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as a spill or equipment breakdown. C C C C C
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ecce
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ENVIRONMENTAL HAZARDS c c
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ClC<':CC
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This pesticide is toxic to fish. Do not apply directly to water, or to areas where surface water is preserH or to intertidal
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areas below the mean high water mark. Do not contaminate water by cleaning of equipment ~,. 'j~&r;.osal of wa'stes. In the
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event that treated seeds are spilled and cannot be salvaged, completely cover them with soil.c ~. L , C ~ C
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CCCCCL (.
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C ,
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IMPORTANT SEED TAG INFORMATION:
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c c
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C (, l C L L l C
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The Federal Government and most states have seed laws or regulations requiring an appr(jJ)(i&f~' caution sfatement be
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affixed to bags containing treated seeds, such as: : , ( , ~ c
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Treated Seed: Do not Use for Food, Feed or Oil Purposes. , (
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eLleLe
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Seed that has been treated with this product that is then packaged and offered for sale or distribution must contain the
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following labeling:
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This bag contains seed treated with captan. To avoid possible adverse health effects, when opening this bag to load the
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treated seed, wear long-sleeved shirt, long pants, shoes plus socks, chemical resistant gloves, NIOSH-approved dust -
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mist respirator (dust mist filtering respirator with MSHAINIOSH approval number prefix TC-21 C, or a NIOSH approved
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respirator with any N2, R, P, or HE filter) and eye protection.
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When using formulations that do not contain dye, to comply with 21 CFR Chapter 1, Section 2.25, all grain seed treated
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with an economic poison must be colored to distinguish and prevent subsequent inadvertent use as a food for man or
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feed for animals.
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2
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DIRECTIONS FOR USE
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It is a violation of Federal law to use this product in a manner inconsistent with its labeling. Not for use on agricultural
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establishments in hopper-box, planter-box, slurry-box or other seed-treatment applications at or immediately before
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planting.
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STORAGE AND DISPOSAL
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Do not contaminate water, food or feed by storage, disposal or cleaning of equipment.
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PESTICIDE STORAGE
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Store in a cool, dry location. Do not store in direct hot sunlight. After prolonged storage in intense cold, allow product to return to
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approximately 25°F before using.
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PESTICIDE DISPOSAL
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Pesticide wastes are acutely hazardous. Improper disposal of excess pesticide, spray mixture, or rinsate is a violation of Federal Law. If
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these wastes cannot be disposed of by use according to label instructions, contact your State Pesticide or Environmental Control
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Agency, or the Hazardous Waste representative at the nearest EPA regional office for guidance
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CONTAINER DISPOSAL
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Rigid, Non-refillable containers small enough to shake (I.e., with capacities equal to or less than 5 gallons).
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Non-refillable container. Do not reuse or refill this container. Offer for recycling, if available. Triple rinse or pressure rinse container (or
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equivalent) promptly after emptying.
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Triple rinse as follows: Empty the remaining contents into application equipment or a mix tank and drain for 10 seconds after the flow
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begins to drip. Fill the container 1,4 full with water and recap. Shake for 10 seconds. Pour rinsate into application eqUipment or a mix
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tank or store rinsate for later use or disposal. Drain for 10 seconds after the flow begins to drip. Repeat this procedure two more times.
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Pressure rinse as follows: Empty the remaining contents into application equipment or a mix tank and continue to drain for 10 seconds
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after the flow begins to drip. Hold container upside down over application equipment or mix tank or collect rinsate for later use or
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disposal. Insert pressure rinSing nozzle in the side of the container, and rinse at about 40 PSI for at least 30 seconds. Drain for 10
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seconds after the flow begins to drip.
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Once container is rinsed, offer for recycling if available, or puncture and dispose of in a sanitary landfill or incineration, or if allowed by
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state and local authorities, by burning. If burned stay out of smoke.
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Rigid Non-refillable containers that are too large to shake (i.e., with capacities greater than 5 gallons or 50 Ibs)
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Non-refillable Containers
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Non-refillable containers - Do not reuse or refill this container. After emptying product from container, either return container to Bayer
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CropScience per instructions from Bayer CropScience Customer Service Center (1-800-527-4781), or rinse and either recycle or
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dispose of the container as follows:
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(';LCG
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C C
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Bottom Discharge IBC (e.g. - Schuetz Caged IBC or Snyder Square Stackable) 0" G <-
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Pressure rinsing the container before final disposal is the responsibility of the person disposing of the container. To pressure: rinse the
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container before final disposal, empty the remaining contents from the IBC into application eqUipment or mix tank. Raise ttfe
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c
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60ttom of
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the IBC by 1.5 inches on the side which is opposite of the bottom discharge valve to promote more comgl~teclJr.9duct rem~lal.
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Completely remove the top lid of the IBC. Use water pressurized to at least 40 PSI to rinse all interior PCl21iorT3. ~ontinLLouslYcpump or
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drain rinsate into application equipment or rinsate collection system while pressure rinsing. Continue pre~~~r.r /hnsing f~F 2 ',l',iliutes or
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until rinsate becomes clear. Replace the lid and close bottom valve. c c co cc c
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(: C
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CL C
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Top Discharge IBC, Drums. Kegs (e.g.- Snyder 120 Next Gen, Bonar B120, Drums. and Kegs) 0.: C ~ C C L
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Triple rinsing the container before final disposal is the responsibility of the person disposing of the contaifl&(-. 'To triple rinse 'the
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container before final disposal, empty the remaining contents from this container into application eqUipment or mix tanl{ fllt6A
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container at least 10 percent full with water. Agitate vigorously or recirculate water with the pump for 2 minutes. Rinse all interior
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surfaces. Pour or pump rinsate into application equipment or rinsate collection system. Repeat this procedure two mor~ till1~~.L'
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Once container is rinsed, offer for recycling if available or puncture and dispose of in a sanitary landfill, or by incineration.
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Refillable Containers
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Refillable container. Refill this container with pesticide only. Do not reuse this container for any
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other purpose. Do not remove tamper evident cables or one way valves or clean the container if the container is equipped with one way
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valves and refilling or returning is planned. After emptying product from container, either return container to Bayer CropScience per
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instructions from Bayer CropScience Customer Service Center (1-800-527-4781) or rinse and either recycle or dispose of the container
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as follows:
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BoHom Discharge IBC (e.g, - Schuetz Caged IBC or Snyder Square Stackable)
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Pressure rinsing the container before final disposal is the responsibility of the person disposing of the container. Cleaning before refilling
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is the responsibility of the refiller. To pressure rinse the container before final disposal, empty the remaining contents from the IBC into
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application equipment or mix tank. Raise the bottom of the IBC by 1.5 inches on the side which is opposite of the bottom discharge
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3
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valve to promote more complete product removal. Completely remove the top lid of the IBC. Use water pressurized to at least 40 PSI to
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rinse all interior portions. Continuously pump or drain rinsate into application equipment or rinsate collection system while pressure
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rinsing. Continue pressure rinsing for 2 minutes or until rinsate becomes clear. Replace the lid and close bottom valve.
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Top Discharge IBC. Drums. Kegs (e.g. - Snyder 120 Next Gen. Bonar B120. Drums. and Kegs)
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Triple rinsing the container before final disposal is the responsibility of the person disposing of the container. Cleaning before refilling is
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the responsibility of the refiller. To triple rinse the containers before final disposal, empty the remaining contents from this container into
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application equipment or mix tank. Fill the container at least 10 percent full with water. Agitate vigorously or recirculate water with the
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pump for 2 minutes. Rinse all interior surfaces. Pour or pump rinsate into application equipment or rinsate collection system. Repeat this
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procedure two more times.
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Once container is rinsed, offer for recycling if available or puncture and dispose of in a sanitary landfill or by incineration.
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TREATED SEED DISPOSAL
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To dispose of out-of-date or otherwise unmarketable seed which has been treated with captan for seed protectant
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purposes: Broadcast and lightly incorporate seed into field soils using disc or other suitable implement. If rate of captan
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contained on the seed is unknown, have seed analyzed by a qualified analytical laboratory to determine. Do not plant
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seed at a seeding rate which will result in the application of more than 32 pounds of captan per acre per year. Any
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resulting crop may be destroyed by chemical or mechanical means, or, if useful for food or feed purposes, may be
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harvested for that use.
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Read all directions before using and use only as specified on this label.
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DIRECTIONS: Thoroughly mix the recommended amount of Captan 400 Seed Protectant into the required amount of
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water for the slurry treater equipment and dilution rate to be used. Clean equipment thoroughly between operations.
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IMPORTANT: Before using - stir thoroughly to mix contents or use entire container at one time. Do not combine colloidal
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suspensions, wettable powder or emulsifiable concentrates unless previous experience assures compatibility.
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Refillable Containers
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End users are authorized to remove tamper evident cables as required to remove the product from the container unless the container is
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equipped with one way valves and refilling or returning is planned. If this is the case, end users are not authorized to remove tamper
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evident cables, one way valves or clean container. See Container Disposal instructions under Storage and Disposal.
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PRODUCT INFORMATION:
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Captan 400 Seed Protectant is a flowable concentrate especially formulated for the treatment of seed prior to storage and
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planting to protect seed from molds and other fungi causing storage loss and to protect seed from ~~~qborne and
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soilborne fungi which cause seed decay, damping-off and seedling blights. c c C (, C
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CCEPTE
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FEB 2 2 2011
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Under the Pederallnsecticide,
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Fungici~, and Rodenticide Act,
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as amended. for the pes&acic1e
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. stered under rep .
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EPA Reg. No. J
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l t- C (" C (
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t.. C (
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I.' (.
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c
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( L C fl (. C
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C
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l. C
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" l Let. l,
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c
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L (", C C C
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1.., L C {, (~
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L
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~, L t.. '. 1,<
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C. (; (:
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( ,
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C. (. t l C (
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4
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sIr
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r (
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CAPlAN 400
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Approved Application Rate
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Fl. Oz. Captan 400 per 100 Ibs. of Seed
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SEED
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Alfalfa, clover, lespedeza, trefoil
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Beans (snap, dry, cowpeas)
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Beets (garden)
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Cereal grains (for seed and seedling rots - not for bunt, smut)
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Barley, rye
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Oats
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Wheat
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Cole crops (broccoli, Brussels sprouts, cabbage, cauliflower)
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Corn
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Field
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Sweet
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Cotton
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Acid delinted
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Reginned, fuzzy
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Cucumber, cantaloupe
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Crucifers (mustard, radish, rape, turnips)
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Flax
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Grasses
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Peanuts
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Peas, lentils
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Peppers
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Sorghum (hulled) for kernel smut
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Soybeans
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Spinach
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Squash, pumpkin, watermelon, muskmelon
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Sugarbeet
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West
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East
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Sunflowers
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Swiss chard
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RANGE
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5-8
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2-3
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8-12
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2-3
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2-4
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1 % - 4
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1-2
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1 % -2%
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2-4
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2 % - 5
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3 % - 7
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2 % - 3
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1-2
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2-3%
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5-8%
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3-6
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2%
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2-3
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1 %-4%
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{...!.~
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1 Y2~' 2 1/2:i
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... (; {" c C (.
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4£..6 " r, c 'I
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1 l'" C ",2' ,I 12 r '
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,.""(""\..:-':-'.
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6
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12
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2-4
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10- 12
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(. f. c: C
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'. \~
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t ( " C C f
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C
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,_ C
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\ I. C I,. C /,-:
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c <- c
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c '.
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l l l l < t.
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5
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IMPORTANT: READ BEFORE USE
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Read the entire Directions for Use, Conditions, Disclaimer of Warranties and Limitations of Liability before using this
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product. If terms are not acceptable, return the unopened product container at once.
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By using this product, user or buyer accepts the following Conditions, disclaimer of Warranties and Limitations of Liability.
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Treatment of highly mechanically damaged seed, or seed of known low vigor and poor quality, may result in reduced
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germination andlor reduction of seed and seedling vigor. Treat and conduct germination tests on a small portion of seed
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before committing the total seed lot to a selected chemical treatment. Due to seed quality conditions beyond the control of
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Bayer CropScience, no claims are made to guarantee germination of carry-over seed.
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CONDITIONS: The directions for use of this product are believed to be adequate and must be followed carefully.
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However, it is impossible to eliminate all risks associated with the use of this product. Crop injury, ineffectiveness or other
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unintended consequences may result because of such factors as weather conditions, presence of other materials, or the
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manner of use or application, all of which are beyond the control of Bayer CropScience.
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DISCLAIMER OF WARRANTIES: TO THE EXTENT CONSISTENT WITH APPLICABLE LAW, BAYER CROPSCIENCE
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MAKES NO WARRANTIES, EXPRESS OR IMPLIED, OF MERCHANTABILITY OR OF FITNESS FOR A PARTICULAR
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PURPOSE OR OTHERWISE, THAT EXTEND BEYOND THE STATEMENTS MADE ON THIS LABEL. No agent of Bayer
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CropScience is authorized to make any warranties beyond those contained herein or to modify the warranties contained
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herein. TO THE EXTENT CONSISTENT WITH APPLICABLE LAW, BAYER CROPSCIENCE DISCLAIMS ANY LIABILITY
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WHATSOEVER FOR SPECIAL, INCIDENTAL OR CONSEQUENTIAL DAMAGES RESULTING FROM THE USE OR
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HANDLING OF THIS PRODUCT.
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LIMITATIONS OF LIABILITY: TO THE EXTENT CONSISTENT WITH APPLICABLE LAW, THE EXCLUSIVE REMEDY
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OF THE USER OR BUYER FOR ANY AND ALL LOSSES, INJURIES OR DAMAGES RESULTING FROM THE USE OR
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HANDLING OF THIS PRODUCT, WHETHER IN CONTRACT, WARRANTY, TORT, NEGLIGENCE, STRICT LIABILITY
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OR OTHERWISE, SHALL NOT EXCEED THE PURCHASE PRICE PAID, OR AT BAYER CROPSCIENCE'S ELECTION,
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THE REPLACEMENT OF PRODUCT.
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NOTICE TO BUYER
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Purchase of this material does not confer any rights under patents governing this product or the use thereof in countries
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outside of the United States.
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NET CONTENTS:
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Produced for
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~B Bayer CropScience
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Bayer CropScience LP
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P.O. Box 12014, 2 T.W. Alexander Drive
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Research Triangle Park, North Carolina 27709
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1-866-99BA YER (1-866-992-2937)
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CAPTAN SEED PROTECTANT AGRICULTURAL FUNGICIDE(PENDING) 01/13/2011
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