a97107de46
Image rebuild (skip scrape) / build (push) Failing after 1h37m12s
Dockerfile: self-contained image with corpus + Chroma + BM25 baked in. Drawbar's compose pulls + runs without volume mounts. Built from sources.json (labels schema), PRODUCT_NAME=crop_chem by default, HYBRID_SEARCH=true (always-on for production quality). RERANK_URL + OLLAMA_URL get set at compose time. .gitea/workflows/refresh.yml: monthly cron (1st @ 06:00 UTC) does full scrape → reindex → image push. Scrapes Bayer (~30 min) + EPA PPLS row-crop filtered (~7h). Skips reindex+push if no corpus diff. Tags pushed: :latest, :<sha12>, :corpus-<YYYY.MM.DD>. .gitea/workflows/image-only.yml: on-demand or auto on code-only pushes to main (paths: docs_mcp/, rag/, scrape/, requirements.txt, Dockerfile, sources.json). Reindexes from committed corpus, builds image, pushes. ~10 min vs ~9h full refresh. .gitignore: corpus/ now COMMITTED (4,159 labels, 265 MB of .md + sidecars). Lets image-only.yml rebuild indexes without re-scraping. chroma/ + bm25/ still gitignored (regenerable binary indexes). .dockerignore: drops venv, eval results, PLAN/README/CLAUDE.md, deploy/, .git/ — keeps the image lean. corpus + chroma + bm25 explicitly NOT in dockerignore (those go INTO the image). Co-Authored-By: Claude Opus 4.7 (1M context) <noreply@anthropic.com>
470 lines
16 KiB
Markdown
470 lines
16 KiB
Markdown
# PARATHION-METHYL PARATHION 6-3
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- EPA Reg No: **5481-152**
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- Registrant: AMVAC CHEMICAL CORPORATION
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- Signal word: Danger
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- Active ingredients: Methyl parathion (28.8%); Parathion (57.2%)
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- Label accepted: 1974-04-18
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- Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/005481-00152-19740418.pdf
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---
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~~
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~l
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l DANGER-POISON
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PRECAUTIONS
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CAN Kill YOU IF SWAllOWED
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This product can kill you it swailowed
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even In 5m3!1 amounts spray milt may
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be fatal :f swallowed.
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-
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CAN Kill YOU BY
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SKIN CONTACT
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This product can kill you if touched by
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hands or spilled or splashed on skin,
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in eyes or on clothing (liquid Koe~
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through clothes!.
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CAN KILL YOU IF BREATHED
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1'1ls product can ~.tli you If vapors, or
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sprJy miol are breathed
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POISONOUS TO FISH AND WILDLIFE
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T"" ~rortuct is iom to fish. birds, and oth~1 wildlife. Birds feed
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Ing on treJted areas may be killed. Keep out 01 any body of water
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Do i'ot apply where runoff is likely 10 occur. Do not apply whe"
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"'cather conditions fJvor drift from areas treated. Do not contam·
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. ·IJte "'3ter by cleilnlng of equipment. or disposal of wastes. Shrimp
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;;rd crab milV be killej at appllcatl~n rates recommended on th!~
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111),' Do !lei apply ,.here these ;lre Import3nt resources Apply
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\1'1: pr001lCt onlf 3S specified on this label.
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USE ONLY WHEN WEARING THE FOLLOWING
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PROTECTIVE EQUIPMENT AND CLOTHING
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oJ" .r ",ter pro,,! pJnt5 coat. hat, rubber boots or rubher over
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" ,}, "'8at '.liet'l goggles ,J, Wear mask or feSplt3tof ap
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:'-ie:' L, t'ce US Bureau of Mines for parathion protection
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: -i"lr he:,,; 1d:j r ilU'21 '1itlhn gloves
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EPA REG. NO. 5481-152-AA
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EPA EST 5481-CA-l 0374
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AMVAC CHEMICAL CORP.
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LOS ANGELrS, CALIFORNIA 90023
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NET CONTENTS:
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PARATHION·METHYL PARATHION 6-3
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Organophosphorus Insecticide Emulsifiable Liquid
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ACTIVE INGREDIENTS
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Par ath 10 n '0 O·ctreth yl O·p·nl tr lphe ny I phosp "orothlOate j
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O,O·dlmeth'll Op·nitrophenyl r)G :Ihorothlodte
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57.2 DC
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288 0 0
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70 0 0
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70 0 0
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)(ylene range Aromatic Solven
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INFRT INGREDIENTS
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P,l r ,'I r r', (j ri
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. ,
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POISON
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: eM KIll YOU ~
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'i _" , - - : ...' -
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n" NG' ER ...-M ~
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Keep Out of Reach of Children
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NOT FOR HOME USE
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S,," .In!.llnt; ,tatenlent dnd other precautlnns 01
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'Ii'" and bJck ~anlls
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WORK. SAFETY RUlE5
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~.e~p all unprotected pe r S0ns and children away
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from Treated area or where there IS danger vI
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d'lft
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Dc nDt rub ele, ~r rrouth tilth hanns. If you feel
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s".' In any way, STOP work and get help right
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a"';Jj Cali 3 doctor !physiCianl. clinic ~r hospital
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immediately Explain tha! the victim has heen
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nposed to parathion and describe his condition
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After !Irst aid is given Isee First Aid Treatment
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Section: ;lnd if a doctor cannot come. take the
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vlctllll to a cl:nic or hospital
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IMPORTANT! Before removing glovrs, wa'h them
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"'Ith soap and waler Alw]y> wash hands, face and
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arm', With soap and water before smoking, eatlRI(
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or drlllkloR AFTER WORK. take off illl work clothes
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'10 shoes Show!', using soap and water. Wear
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I ni)' ~Iean clothes when leaving job Do not wear
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ronLlmlnated clolliing Wash protective rl;'lning
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;J[]rl protective eQI'ipment With 503" dnd water
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,lftcr each use Resi.;;~:~: :~::,I:: Ile rleaned and
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fl:ter repla',ed accord!"1( to instructions induden
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Nlth reSpllator
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TOTAL 1000 0 0
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POISON SIGNS (Symptoms)
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Parathion is a very dangerous poison, It rapidly
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enters the body on contact with all skin surfaces
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and eyes. Clothing wet with this material mus~ be
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removed immediately. EJposed persons must re
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ceIVe prompt medical treatment or they mly die,
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Some of the signs and symptoms of pOisoning are:
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P.eadache, nausea. vomiting, cramps, weakness,
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blurred vision, pin·point pupils, tightness in chest,
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labored breathing, nervousness. sweating, water·
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ing 01 eyes, drooling or frothing of mouth and
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nose, muscle spasms and coma.
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FIRST AID TREATMENT
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Call a doctor (phy~ician), cliniC or hospital im·
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mediately, Explain that the ~ictim has been ex
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posed to parathion and describe his condition.
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If breathing has stopped. start artificial respira
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tion immediately and maint~in until doctor sees
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victim.
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if swallowed and Victim is awake {conscious) make
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him vomit quickly, Induce vomiting b)' .ticking
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flcger down throal or by givirg soapy or strong
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s;:lt, water to drink. Repeat until vomit is clear.
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Never give anything by mouth to an unconscious
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person Have victim lie down and keep quiet. See
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doctor imlr,ediately
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J~1 cale of contact, immediately flush eyes or skin
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wltr plenty 01 water for at least 15 minutes while
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rc',;oving contaminated cloth;ng and shoes. See
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.. o~tor Immediately .
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NOTE TO PHYSICIAN
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Antidote - - administer atropllie sulfate in !ar~e
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10ses. TWO to FOUR mg. Intravenously or intra
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rnd~cularly as soon as cyanosIs is overcome. Re·
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~eat at 5 to llJ minute intervals until signs of
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atropinization apoear. 2 PAM chloride is al>o anti'
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jotal and may be admtrlstered In conjunction
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w,!h atropine DO NOT GIVE ~'ORPHINE OR TRAN·
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QUILIZERS Parathion IS a strang cholinesterase
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Inhibitor affecting the central and perip~eral
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'!UVGUS srstems and producing edrdlac and res
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plfJtnry jepression. At first Slr;n of pulmonary
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e!lema. the patient should be plv~n supplemental
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ot'lgen and treated symptomc"'cally. Continued
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absorption of the pOison may occur and fatJI
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relapse, have been reported al'u inltia! Improve·
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Illen! VFRY CLOSE SUPERVISION OF THE PATlfNT
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IS INDICATED FOR AT LEAST 48 HOURS.
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F05T TREATED AREA
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'.on .ult your qate Agf!clJitur;ll ExtenSIon Sr'vlce
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bpernnent Slation regarding postiil~ treated
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.1rpa~
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RECOMMENDATIONS
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C,pe, 11.1'''. p.1rll'l for use illrl'cll0'15 :11111 ''''u!:lIllell
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Ii dlOll'
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USE PRECAUTIONS
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',' ,', t, 1- .., :jf, d', " fl t J ,
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!! . '". :\1 " ,! f1, j y)'" t I! f'
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CONTAINER DISPOSAL , f' .. : fl 1,1; i: 1-':
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'. ,J .. jlp i' .' ! t ,,,' r,' ';' .
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T', .',., • ",iIP'
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.; ,
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" (if '1· " "l ~r (,r "J,.:'t:f: I, . i_'
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DIRECTIONS FOR USE
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: ~ i
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::-: ,(,I;"~ >', ·".:de bi Jitdyt or groun1j r,'J,'d:r i ;i;,~'Ti;r"t t •
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t •• -.-"~ Dt" .1i'Tl'i ,',!\:\ ~,c) flE !PDfCy'cd pr~:t'?ctl\.'l· r·,::,.;: ;:~lt L !,,'
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.,", ., ' .... in: hdf L : r-,l .,;,': i-:'t POLJ! :,r'f'(. f ;:d 3!l1!.·,~nt c/ 't1I(J P'Ci.j j' ~
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1'-'7"0 f1f":l{lrly fi!:f~'j <:,p"a./ t:-l!1~ ~~~{i:nt,iin agitation rj:Flr';, flliin.; ,inr!
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(:";';1'.":) - ;.P'dt:',f'C (I,.-.,:! ';' rrpr] rr;t finf·r Pun ~/1 tl if) f f'! 'P
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. ! .. " !,,(,~ i, ,-:'~ L,':{· ;;itt~ f-''''L\diJbic !t
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r
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;'j;i1) n~ .',,·:tabh' rr ".'
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) i .. 11!~·_-; j"F',' :,c. p_per:,-,"Ir,-, ~l"lS ~r(.'·~.'en phl::..I~--J , ('r"'T'p,~! L',·
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j '.~ . !~p 'ri [J'J!lt, ;·:.1,,'-', t;1(,- ".'1, -I' -!'IJ: t-'n1 cj is 1fIJL t' (:,trn' -:',.
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;,,::t!.lt)" ~_,'--,", ~,:r .',"t;·, :~t tt:,j; ~ ;",!:f 'f t';tJl ... 'j",. '. tn'" 3,]r: 1
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r < ~ ~ ~
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'> ," "U',-;
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;'1':1>;' i-':, :", ... ~ ,r"_l '.' .. ;',"",,'c, LI;'-,!~'jt:c. :;'
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, !
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, ' J'1j~, '_J!:::.J J/I.j, t:i'~]1 'vater ~,p~ ,.\
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. ' ,: . t.., ' . L,' :j f ~_. ,j'! G' r':1 .
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, ..
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f
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- .), ;' n
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'", .... -
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, .. r·' 'i_'f_> " i ~
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i •
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;,;, J!
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'.
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, ' c . , ,I) .
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i' :+
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I.
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J ,- :.
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'" ., ,
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"
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TERr,11NAL USE OATES
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" .
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\. r ," r T ~, Q I r .. _1
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,', .' , , ,:,
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ALFAlfA. CLOVtR. ~RASS VUCH
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, .'; . j , .;
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I' ',' :)., : f .. ' ,
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"
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.,
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,! [ . I· .... ,
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': " Nol~
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'.
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. ; , .. i t , .
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CARROTS
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eLLERY, '.
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,... ,. , .
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.!. ~. '. ~
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COLE L~}PS ,B,JL
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• r,1
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. ",
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COllARDS, KALE,
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~'.,'i[it' ",~-,;~-.,~i-,
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,; t! i :1' ,:,n')
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· ,',.' t ' -' I "~":': LJ t i
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. ,.' [~t,': r;! i t
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, 1, ' ~ 1 4
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CORN (Sweet), /,r,
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r L!
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! -;;·if .. r, (' n~. b;!g •
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• " -:' ;': ~' : r :r n
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URY aEANS ~pi',cj
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-!,. i dn
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GARDEN PEAS, B
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; J~'"
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GREEN BEANS Ap
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"J'~ \":l,';jPtJ
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LETTUCE Ileaf. Bib
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• 1. . ') ~
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f: pt·, .j' ~,. . j
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P[PPlRL ;·;"'1 I
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POTAIOli. ;·r;tno.
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~)!:ES ret :!'-, ~('Jli
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R[D BEETS; ;\;nds
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'.;1 '::'~1---:'S- ,! top) a
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" i.p,
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il'L I r
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;':.l, .. ; i:'. ''),
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" ORG.HUM ... , e
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UGAR BELTS. ~; h
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s
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ltlMATOES ;s
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T !'""1 iPS
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no warranty,
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w,nranties
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for any pa r
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rn.ltcrial, ex
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Amv.1C's la
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I·METHYL PARATHION 6-3
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)sphorus Insecticide Emulsifi.lble Liquid
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1itr jphenyl phosphorothlo3te!
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I ~ 105phorothIOJt~·
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~7 2°"
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78 8 0
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len
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r:.P i + ": !'" ..
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.AI El
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of Children
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ME USE
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er precautions on
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tUlES
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lnd children away
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lere IS dangr.r of
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hands If you feel
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nd get help right
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clinic or hospital
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! victim has beer.
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ribe his condition
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Irst Aid Treatment
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It come. take the
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~Ioves, wash them
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sh hands, lace and
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re smoking, eatiRg
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III all work clothes
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I and water. Wear
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! job. Do not wear
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lrotective clot~ing
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1 soap and water
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lid be cleaned and
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Itructlons included
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TGTAl
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POISON SiGNS (Symptoms)
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7 0
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0
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"
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7 0 °0
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1 00 0 00
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Parathion is a very dangerous poison. It rapidly
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enters the body on contact with all skin surfaces
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and eyes. Clothing wet with this material must be
|
||
removed immediately. Exposed persons must reo
|
||
celve prompt medical treatment or they may die.
|
||
Some 01 the signs and symptoms of poisoning are:
|
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Headache, nausea, vomitin~, cramps, weakness,
|
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blurred vision, pin·point pupIls, tightness in chest,
|
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labored breathing, nervousness, sweating, water·
|
||
ing 01 eyes, drooling or frothing ~f mouth and
|
||
no se muscle spasms and coma.
|
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FIRST AID TREATMENT
|
||
Call a dnctnr (physician), clinic or hospital im·
|
||
mediately. lxplain that the victim has been ex·
|
||
posed to parathion and describe his condition.
|
||
If breathing has stopped, start artificial respira·
|
||
tlon immediately and maintain until doctor sees
|
||
victim.
|
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If swallowed and victim is awake (conscious) make
|
||
him vomit quickly. Induce v~miting by sticking
|
||
finger down throat or by giving soapy or strong
|
||
salty water to drink. Repeat until vomit is clear.
|
||
Neve; give anything by mouth to an unconscious
|
||
person. Have victim lie down and keep quiet. See
|
||
doctor imrr.ediately.
|
||
In case of contact, immediately flush eyes or skin
|
||
with plenty 01 water 'or at least 15 minutes w~ile
|
||
rrmoving contaminated clothing and shoes. See
|
||
doctor Immediately.
|
||
NOT~ TO PHYS!CIAN
|
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Antidote - administer atropine ,ulfate in large
|
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do,es, TWO to FOUR mg. intrJvp.nously or intra·
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mJscularly as soon as cyanosIs is overcome. Re·
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peat at 5 to 10 rtlrnute interval; until sign~ of
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atropinization app)ar 2·PAM chloride is also anti·
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dot31 and may be administered in conjunction
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w,th atropine. DO NOT GIVE rlORPHINE OR TRAN·
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QUILIZERS Parathion is a strong cholinesterase
|
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inhibitor alfectrng the central and peripheral
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nervcus systems and producing C~rdlaC and res
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plrJtory depression. At Ilrst sign 01 pulmonary
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||
edema, the patient should be given supplemental
|
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oxygen and treated symplomatically. Continued
|
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absorption of the poison may occur and latal
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relapses have been reported after initial improve·
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ment: VERY CLOSE SUPERVISION OF THE PATIENT
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IS INDICATED FOR AT LEAST 48 HOURS
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POST TREATED AREA
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Con5ult your State Agricultural Extens!on Service
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Eipcriment Station reg a r din g posting treated
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areas
|
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RECOMMENDATIONS
|
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",." hLk p.lnci for Ilse direcl'o~s j]n~ rc~ominCIl
|
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[j I r Ions
|
||
USE PRECAUTIONS
|
||
p.'j -,. , .. tJ: ' .. , o·
|
||
n + j~,p!',' '_'r ]'!,:),\, t" c', tJ :J't'c.: -, ....:p., t,y
|
||
'"
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||
'. rj " n, ,~-c, 'J' t). '--(+,('I! :i ,T j v,,:' ,l!f': ::[\ :1' .~ 1 ,- ':
|
||
L ," -, ::'
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||
(r,-lt(1.1 I..'PI-'f' ) "J"" +'l~':~' 'l~,-::I' ,I' J '.' ' •• ". '1 1!:I!."f· _ , • l" r, , __ ~ c jl • ", Ll ( ., ,I , iJ
|
||
CONHINER DISPOSAL I', r",' 'f', f'"':''' "" 'j,' ';'
|
||
',il,! '·r I,,, .~'!" .. ", '_ j,:1 ,.
|
||
DIRECTIONS FOR USE
|
||
:<,~: r3:",n (.l" be r:dde bi arrua'( Gr ground pc<\rr equ,pment b,
|
||
:' ~,"ed ;1L';Sllfif'f'1 cnly USing apDrO"ied protect!,.'t f<;Ulp;i, .. ;rt DC) not
|
||
1~;:!i \\in~ t':JiHi f~l,I~,~;~(:nt POL:f ~['ei.lhe(i awount of thiS product
|
||
iii!:; :~parh' 7: it'J s~;'{j,/ Ljn~ ~'f~a:ntdif1 dbitatllw riU! !:l~~ fl!itng and
|
||
sway'!']? ~:~,e'jL, :';', U~)e;) screen no! t:ner ~h.]n SO ;:ie:,r1 In entire
|
||
·'.'i'~t,,·;, Dr, net CJmb,fli' ,',Ith erll:'s:f!.1ble il~U;ds or •• ... ettJblr pO .... ,·
|
||
'-~','-) l.~de s r"f:'.!Cil~' !"perit,~1cf~ IUS piCi~en physlcJi[-~' corTlpatlb;e
|
||
,1: _~ '-.l~e t'J p<~flL :.:.'d~) ti;c!,)ugh!y' 'llit ernU:Slflab:e CGfl~_l'ntratps
|
||
./ :.c~Llb:F- rl-,,'ij(·r~~ .·i'~:-' :!t !i_·as! f1:llf r:f tr.',t 1 ',,,a!ri bpforp adding
|
||
t h ,:, ['[ubct
|
||
R' :"t~ :~JP1(:h- t.~,jl~/r!;':_-;lt jii j (cr1~:-'" t"~ DiSrt";arge ir:~lirij ,o.Jste in
|
||
:_ • ,n n, n-: ")p i.J",L, --: ,l!c:l .1,,,,,:.,' f:r,:n v\,1:er ~UP~):;p.s
|
||
,':,r;J! ,,·~tl!j[l d'~,',l;(i :)" '" j,j:, Ly' fx:r,pr:enCf'd Per~,'~:nn~i 'JSln~; ap
|
||
;,:',-,,_ '.~ )L1\-'~~ i_ j "f "',-,'" ~ ... d i\.·.jf~ ()' f;,-'_·ur~c1 t~l.j;;;n~cnt
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||
, -. j': on:: f:'~",,;'-
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||
• ~- .; 'r, c, ;- , J •
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"
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. ,.' - '-".' .'
|
||
:_1"
|
||
Rt·'.r
|
||
. .
|
||
, .
|
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fERMINAL USE DAHS
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COllARDS, KALE, M:.ISTARD GREENS. SPINACH
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CORN (Sweet); ~rrnY.·.nrrY1(;. F:w aftT",',', "11S ; r :'if" "' i'e_ 1 f'f
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MeXIC<l;1 bean beet:es. red spider m,tes . 1 ! pt ::' '~ays
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NOTICE: Amvac Chemical Corporation makes
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no w,Hranty, express or implied, including the
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warranties of merchantability and/or fitness
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for any particular purpose, concerning this
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m,lterial, except those which arc contained on
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Amvac's label.
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-----------------------------------------
|