crop-chem-docs/corpus/epa_ppls/34704-21.md

# CLEAN CROP THIODAN 3 E.C

- EPA Reg No: **34704-21**
- Registrant: LOVELAND PRODUCTS, INC.
- Signal word: Danger
- Active ingredients: Endosulfan (33.3%)
- Label accepted: 2003-03-27
- Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/034704-00021-20030327.pdf

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3(21/2003 1/8 
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY 
Mr. Scott Baker 
Platte Chemical Company 
P.O. Box 667 
Greeley, CO 80632-0667 
Dear Mr. Baker: 
WASHINGTON, D.C. 20460 
OFFICE OF 
PREVENTION. PESTICIDES 
AND TOXIC SUBSTANCES 
FEB 27 2003 
Subject: Amendment - Update to match use patterns and limitations appearing on source 
material label [delete Leatherleaf Fern, Succulent Ornamentals 
(greenhouse and out-of-doors), Alfalfa (grown for forage), 
Sugar Beets, and Sunflower] 
Thiodan 3 EC 
EPA Registration Number 34704-21 
Your submissions of December 12,2002 and February 27,2003 
The amendment referred to above, submitted in connection with registration under FIFRA 
section 3(c)(7)(a), is acceptable and a stamped copy is enclosed for your records. 
When preparing the finished label, please incorporate the following revisions: 
a. On the front panel, under the product name add "For Agricultural or Commercial Use Only" 
and directly under this add "Not for use or storage in or around residential sites - see 
DIRECTIONS FOR USE / APPLICATION DIRECTIONS for prohibited areas.". 
b. In the ingredients statement, revise ACTIVE INGREDIENTS to ACTIVE INGREDIENT 
since there is only one. 
c. The Hazards to Humans and Domestic Animals text is incomplete. 
After "Fatal (poisonous) if swallowed, inhaled, or absorbed though skin." add "Corrosive. 
Causes irreversible eye damage." Replace "Avoid contact with skin eyes, or clothing." with 
"Do not get in eyes, on skin, or on clothing.". Replace "Do not breathe vapor." with "Do not 
breathe vapor or spray mist. Do not contaminate food or feed. Keep out of reach of domestic 
animals. Food utensils such as measuring cups must not be used for food purposes after use 
in measuring pesticides.". 
d. Update the Statement of Practical Treatment to the First Aid format detailed in PR Notice 
200 I-I. In the If Swallowed advice, be sure to add "or convulsing" after unconscious" in 
the last sentence of that section •

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e. Revise the Note to Physician to read as follows: 
NOTE TO PHYSICIAN 
Endosulfan is a central nervous system stimulant absorbable by mouth, inhalation, or through 
contact with skin. It may cause convulsions. There is no specific antidote. Diazepam I. V. is 
the drug of choice. Barbituric acid derivatives such as Phenobarbital may be used additionally. 
A neuromuscular blocking agent may be used if convulsions persist. This type of drug may be 
used only if complete control of respiration can be maintained. Epinephrine derivatives are 
absolutely contraindicated. This product contains petroleum hydrocarbons (xylene range 
aromatic solvent). Care should be taken to prevent aspiration because of the possibility of 
chemical pneumonia or pulmonary edema due to the organic solvent in the formulation. 
f Please refer to PR Notice 98-9 for updated pesticide respirator recommendation text to 
appear in the PPE listing for applicators and other handlers. 
g. Assuming that the referral "See supplemental label for directions for use in California." refers 
just to the "Procedures for reducing risks of contamination of aquatic ecosystems" (you did 
not submit the supplemental label), then this product would not be adequately labeled for use 
in California since that State has separate requirements related to crops, pests which can be 
claimed, application rates, number of applications permitted, and PHIs. If you refer to one of 
your competitor's labels that bears California labeling, it would show that they either elected 
to register a separate California label or else chose a combination label format that lists each 
crop twice, the first bearing directions and limitation for all states except California and the 
second bearing directions and limitation for use only in California. Either delete the reference 
to use in California and the supplemental label and add "Not for use in California", or if sale in 
California is intended then retain the referral which should be revised to read "This product 
may be use in California by following the specific crop directions indicated for use in that 
State plus the SUPPLEMENTAL LABEL found at the end of this labe1.", add the 
supplemental label to the back of the label, and expand the directions to include both "except 
CA" and "CA only directions" for each crop. 
h. Directly under the heading APPLICATION DIRECTIONS, add "Not of use or storage in or 
around residential sites, including, homes, non-agricultural outbuildings, non-commercial 
greenhouses, recreational vehicles, preschools, day care centers, and not for application to 
humans and pets.". Then, before the current text add "Do not use in undiluted form.". 
The recommendation for ground application in a minimum of 10 gallons of water per acre 
should add "on vegetable or row crops (unless otherwise noted)". For aerial application, the 
recommendation should be changed from "a minimum of 1 gallon of finished spray per acre 
on deciduous trees and vines" to "a minimum of 1 gallon of finished spray per acre on 
vegetable and field crops (unless otherwise noted) and a minimum of 20 gallons of finished 
spray per acre on fruit and nut trees and on vines". 
i. Delete the unsupported crops Alfalfa (grown for forage), Sugar Beets, and Sunflower. 
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J. A number of crops do not have the correct current Pre-Harvest Intervals. For Cucumbers, 
Melons, and Summer and Winter Squash the PHIs should be 2 days rather than 0 days For 
Potatoes, Sweet Corn, and Sweet Potatoes the PHIs should be I day rather than 0 days. 
For Tomatoes, the PHI should be 2 days rather than 1 day. 
k. Current Endosulfan end-use products include specified limits as to the amount of active 
ingredient (and of actual product) permitted on a given crop per year for all uses. These 
limitations, together with overall notes, such as livestock feeding prohibitions or the number 
of permitted applications, should appear at the end of a given crop's directions and should be 
set apart either as bulleted items or if you choose running text format they should be 
preceded by "For All Uses:". Please refer to the enclosed sample label for assistance in add 
these limitations for crops already approved for your product. Please do not add crops which 
may appear on the sample label but which are not currently approved for your product. 
1. For Barley, Oats, Rye, Wheat revise the pest entry from Army Cutworm to Armyworms, 
Cutworms. Change the feeding limitation to read "to livestock" rather than "to dairy animals 
or animals being finished for slaughter". Also, add an overall limitation to 2 applications per 
year. 
m. For Broccoli, etc. add an overall limitation of 4 applications per year. 
n. For Carrots, revise the overall limitation to I application per year. 
o. For Celery (7 day PHI) revise the overall limitation to 2 applications per year. For Celery 
(4 day PHI) revise the overall limitation to 1 application per year. 
p. For Cucumbers, etc. specifY a limit of 6 applications per year (Note- use in California will be 
limited to 3 per year). 
q. For Eggplants, specifY a limit of 2 applications per year (N ote- use in California will be 
limited to 1 per year). 
r. For Peas, revise the crop entry to read "Peas (succulent, excludes seed crop)". Change the 
limitation to read "per year" rather than "during the fruiting period". 
s. For Peppers, add a limit of2 applications per year. 
t. For Potatoes, add a limit of 6 applications per year. 
u. For Spinach, add per year" to the limitation. 
v. For Strawberries, add a limit of3 applications per year. 
w. For Sweet Com, change the spray interval to 5 days and add a limit of 5 applications per 
year.

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X. For Sweet Potatoes, add a limit of3 applications per year. 
y. For Tobacco, add a limit of 6 applications per year. 
z. For Tomatoes, add a limit of 6 applications per year. 
aa. For Apples, add a limit of2 applications during the fiuiting period and 3 applications per 
year (Note - use in California will be limited to 2 applications per year). Also, please note the 
maximum allowed rate of application is 3 113 qts. per acre. 
bb. For Cherry, revise the limitation to read "per year" rather than "after shuck split". 
cc. For Peaches, Apricots, and Nectarines, revise the ,imitation to read "per year" rather than 
"during the fruiting period". 
dd. For Cherry, Peach, and Plum Nursery Stock Dip, replace "Wear rubber gloves when 
dipping." with "Full personal protective equipment (PPE) requirements for applicators 
also apply to this dipping operation." . 
ee. For Grapes, add a limit of3 applications per year. 
fr. For Pears, what is meant by the entry "The rate for a foliar treatment on stink bug control is 
30 days"? This is especially confusing given the next sentence ''Do Not apply more than once 
per season.". ClarifY or revise the directions for this crop per the enclosed sample label. 
Add an overall limitation of2 applications per year (the separate use-dependent limitations 
will not appear). Be sure to add the note about aerial application. 
gg. For Pecans, add a limit of2 applications per year. 
hh. Separate the directions for use on ornamentals from the food crops and add the heading 
"Ornamental Trees and Shrubs (Commercially grown outdoors in nurseries only)". 
Please submit 5 copies of labeling bearing the above revisions as soon as it becomes available. 
Thank you for your prompt cooperation in this regard. 
Sincerely, 
George T. LaRocca 
Product Manager 13 
Insecticide Branch 
Registration Division (7S0SC) 
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THIODAN® 
3EC 
KEEP OUT OF REACH OF CHILDREN 
DANGER ~ POISON 
PELIGRO !liD 
a.-. ........... _---. ............................ . ................ ,.. ............................................ . . ,....~ 
See _tor 8ddltlonal PlllClllltlonary_ 
NCIT FOR USE OR STORAOE IN OR AROUND THE HOllE 
EPA REO. NO. 34704-21 
EPA EST. NO. :rn.c,t,.1 
NET CONTENTS 2 GALS. (7.56 L) 
4ID1 ~ ... Rt9...a T.M.of ........ M:? EXPQI5Ya5 
PRECAUTIONARY STATEMENTS 
HAZARDS TO HUMANS AND DOMESTIC ANIMALS 
DANGER 
_~IW __ .lnhalod."' ___ ._ 
--__ ._ordolhing.Do"", __ . 
STATEMENT OF PRACTICAL TREATMENT 
• ... IiCMld. Calla ph)'aic:_ Of ~ CoriIot Cemor iron I C\Imety. DO IIOr INDUCE Q1111in; ._ GlM< 11 ... ..- io nat __ \A>mlting 
..., <;OUa U!>iroIion pneumonia. H • io _ 'D _ -'ling 
.. ViI::h'n one 01 two g .... ot WIler WId inaett linger in bec:kaf UuuIIl. Do ... __ ling or giw _hIng t>r _ 'D on .........,.,.. 
........ _ __ _ .. Iruh air. H _. nat _hing, gM _ .......... GoI __ .-.. 
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~ ... .,., 
_ ..... _Eq.lpmen~ 
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__ andiongponla,chom_;_ oucII .. _ 
__ '" Won, _Cai<ooIoiant _ pU _ -"'" __ Iheadgelrtor __ .. ~ 
- ..... _ cleaning equipmon!, 1IIbdng. or loIding. and I 
__ oiIhorlnorgonic_~QIIridgowllh.pro_ 
_tor __ IUSIWNIOSH __ pnr"=I. 
.. " ____ ... peSl_ IUSHMlIOSH oppnwal nu_ 
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DIooord .... tw\g and oIhe, abaorbenl ...... rt&Io ,l1li '-been 0ncOled 
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USER SAFETY RECOMMENDATIONS __ ill: 
____ • clrinldng.-";gum ..... 0;_ ... 
ueing 1M D6et.. _cIoIhlng .. In\. .. ' .. S ..... oty., • ......- __ Tloon __ • 
""IIhIY ond ""' ... _ cIoIloInQ. 
__ PPE into. diololy -1IIndIIn; III. pnoducI. _ \he DUI· IIiIo cI gicMI _ ..........mg. ,. _ .. ~ __ • 
~lyandc/lanilO .... -. _Ing . 
ENVIRONMENTAL HAZARDS Thio prad&od ..... Ioliolo. _ and ___ lMding an 
__ maybe-.Do .... IppIy---­____ Shrtmpand_...,.be_.~ ... 
.... aeweswnendeQ an thia abel. 00 NIl ~ ...... 1iah,1t'Pnp. GAb. 
... _ oqUlolic lito ... "'- __ Thio produc:I ..... no! be 
UNd An .... 1IIIIheq impel on ItveIdenId endangered tpeC_ .. ..-y. 
ConIact you>' SIao Filn and Boone ~ _1ppIying _ produc:I. 
Applt Ihil pn>dud only ulpOdfiocIon'loolobei. Do not IppIy -It 10 
__ \0 lieu whore aurtac:e waiel ia ~n1., IK ., inlet\1daI ...... 
Deklwthemea.n high __ mark. 0.. tolhe Nkof rvnoft and drift. CIa nor IppIy _ • disllnOo 01300 .... d _ .. _ .. ...,.,. ancI __ 
...... Donal applylD any .... notapecffied on tho '-bet. Do no!. conam~ 
NI8 ""bydMning DI equipmwllor~of"""" 
Tbia peI&icII::Ie .. lIlak: \obMa ~ todired applc.uon. ~~,"Il 1;""g 
8houid t. limed \0 coincide with perioda s minimum taN 1ICIMly, u&U1iI"J __ .... _Ing andllrlymcoming • 
PHYSICAL. OR CHEMICAL HAZARDS 
00 nalUM tI Axe ...,. holt 01 open nuno. 
DIRECTIONS FOR USE 
It ... 'liDlliianoi federal_IOu." praQ,Ic:l in. manner ~ 
wiIh iIa Iobo~ng . Do .... IppIy .... produc:Iln I _ , .... will ___ '" _ 
__ d~ '" IhrOUgh drill. Only proIO<Ied hiIndIooft may be 
in u.. .,. .. during appdCT'bn. . 
f1>r OIly .............. opedfoo: .. )OiI' SIa10 .. 1Iibe, _ \he -"'Y __ tor ___ 1.1I0I\. 
AGRiCUL.TURAL. USE REQUIREMENTS Uoe 1Iolo _ only In ocoordonoe _ .. _in; _ wIIh .... 
_POOl ... '" SIIftdInI. 41) CFR port 1'/1). ThiiSIondord_no 
.... _ .... tho pOOIoc:Iion d ogric:ooIIuraI -.. on iInnI, tor· _ .-. and _IQI_ and __ 01 ogricuIWqI piiIII-
c:idDi. h conlllini requiremena tor IraininG, decontamlnatM)n _ .... and ___ ft alto _ opoo:Ifoc:"': 
_ and __ per1aIning 'D .... __ on .... _ 
IIbout peraoM ptcMd:_ eq~nt (pPE), .nd .... lad _i'ICry Inltf~ 
wi. T .. __ lnlhil_ ... ltopplylo _dlhio producIlIIM __t>rtho __ SO&nc1In:I. 
Do ........ or ___ entry ................. during'" ... 
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_ P_ion SIOndard and IhiII ___ 1Od whh onyIhIng 
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Ion~ ohin and long ____ I gO": .... h u 
blnlor 1Im1n .... or vIIon. chemica_on! _, ply. -. PR> 
\ec::liwI1r)"e'I'I'II&r and c:hem~ hudgear tor ~ expo­
...... 
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I nlODAN'" ~ 1::(; 
EPA REG. NO. 34704-21 
STORAGE AND DISPOSAL PIlOllllllTlOHS'Do .... __ -. .. _111' .... « 
~ a,on ....... gla pn>bI>Jt..s. Do .... __ -Do .......... _ whi:h IIIIght .a WMIr _ "" _ 
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THIODAN® 3 EC 
EPA REG. NO. 34704-21 
1',. .... ~ Watt .. ".1) a ..... af ...... , .... , J ..................... prior ID 
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.......~., ... t.nd 
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--- ---
EPA REG. NO. 34704-21 
........... « ....... 
-. .. _­--­__ ,q&t1G)-. ... _ _=_:
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BID: V .. ~ 1'bq&/100 __ Sp'II}'IhIn&I!iJhI1MG *-CItlDiluncwpMr& "",,,wMn ......... ~ .... In 104 
-NOTICE 
PI.IJTE _RANTS lliAT THIS PROOUC'T CONFORMS 10 THE CHEUICAL DESCRIPllOH ON THE LABEL THEREOF AND IS REASONABLY 
FTT FOR TltE PURPOSES STATED ON SUCH LAIIEL ONLY WHEN USED IH ACCORDANCE Wlnl THE DlREClIOHS UNDER NORMAl. USE 
CONDITIONS. IT IS IMPOSSIBLE1O EUMIN.Q"E AI.L RISKS INHEREIffiY ASSOCIAlED Willi 'THE USE OF THIS PRODUCT. CROP II>.IURY 
INEFFECfIIIENES5. OR OIHER UNINTENDED CONSEQUENCES &.lAY RESUiJ' BECAUSE OF SUCH FACTORS AS W£'\'THER CONDITIONS. 
PRESEHCE OF OTHER MATERIALS. OR THE MANNER OF USE OR APPUCATlON. AI.L OF WHICH ARE BE'OOND lliE COIn'ROi. OF PL.Q"TE. 
IH NO CASE SHAI.I. PLATTE BE UABI..E FOR CDHSEOUENlW.. SPECIAl. OR IHDIRECT DAMAGES RESUiJ'IHG FROt.I THE USE OR 
HANDLING OF THIS PRODUCT. ALL SUCH RlSI<S SHAU. BE ASSUIoiED BY nlE BUYER. 
EXCEPT AS EXPRESSLY PRClI/IDED HEREIN. PUJTE MAKl<S NO WAARAN'TlES, GUARANTEES. OR REPRESENT.Q"IONS OF Io}jY KIND, 
ElTHEA EXPRESSED OR IMPUED. DR BY USAGE OF TRADE. STATlITORY OR PlHERWlSE, WIlli REGARD 10 THE PRODUCT SOUl, 
INCWDlNG. BUT NOT UMITED 10. MERCHANTABILITY. FITNESS FOR A PARTICULAR PURPOSE. USE OR EUGIBIUTY OFTHE PRODUCT 
FOR ANY PARTICULAR TRAOE USAGE. BUYER'S OR USER'S E=VE REMEDY. ANO PLATTE'S 'IOTAI. UABIUTY. SHAI.L BE FOR 
DAMAGES NOT EXCEEDING THE COST OF THE PRODUCT. 
FORMULATED FOR 
PLATTE CHEMICAL CO. 
150 SO,IWN STREET FREMONT, NEBRASKA 1i02 .. 5697 
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