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crop-chem-docs/corpus/epa_ppls/100-1318.md
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# DURIVO
- EPA Reg No: **100-1318**
- Registrant: SYNGENTA CROP PROTECTION, LLC
- Signal word: No Signal Word
- Active ingredients: Thiamethoxam (17.5%); Chlorantraniliprole (8.8%)
- Label accepted: 2014-10-29
- Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/000100-01318-20141029.pdf
---
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
WASHINGTON, DC 20460
OFFICE OF CHEMICAL SAFETY
AND POLLUTION PREVENTION
October 29, 2014
Sharlyne S. Pyles
Syngenta Crop Protection, LLC
P.O. Box 18300
Greensboro, NC 27419
Subject: Label Amendment Removal of 28-day application timing window, addition of
NYS specific restriction language, and revision of container handling language
Product Name: Durivo
EPA Registration Number: 100-1318
Application Date: 8/21/14
Decision Number: 494818
Dear Ms. Pyles:
The amended label referred to above, submitted in connection with registration under the Federal
Insecticide, Fungicide and Rodenticide Act, as amended, is acceptable.
A stamped copy of your labeling is enclosed for your records. This labeling supersedes all
previously accepted labeling. You must submit one copy of the final printed labeling before you
release the product for shipment with the new labeling. In accordance with 40 CFR 152.130(c),
you may distribute or sell this product under the previously approved labeling for 18 months
from the date of this letter. After 18 months, you may only distribute or sell this product if it
bears this new revised labeling or subsequently approved labeling. “To distribute or sell” is
defined under FIFRA section 2(gg) and its implementing regulation at 40 CFR 152.3.
Your release for shipment of the product constitutes acceptance of these conditions. If these
conditions are not complied with, the registration will be subject to cancellation in accordance
with FIFRA section 6. If you have any questions, you may contact Jennifer Urbanski at 703-347-
0156 or via email at urbanski.jennifer@epa.gov.
Enclosure
Sincerely,
Venus Eagle, Product Manager 01
Invertebrate-Vertebrate Branch 3
Registration Division
Office of Pesticide Programs
1
(Booklet)
Not for sale, sale into, distribution, and/or use in Nassau, Suffolk, Kings, and Queens
counties of New York State.
Durivo®
GROUP 4A 28 INSECTICIDE
Insecticide
For control of listed insect pests infesting specified crops
Active Ingredient:
Thiamethoxam
1 ............................................................................................ 17.5%
Chlorantraniliprole2 ......................................................................................... 8.8%
Other Ingredients: 73.7%
Total: 100.0%
1CAS No. 153719-23-4
2CAS No. 500008-45-7
Durivo is a soluble concentrate containing 1.67 lb of thiamethoxam and 0.835 lb
chlorantraniliprole per gallon.
KEEP OUT OF REACH OF CHILDREN.
Si usted no entiende la etiqueta, busque a alguien para que se la explique a usted en detalle.
(If you do not understand the label, find someone to explain it to you in detail.)
See additional precautionary statements and directions for use in booklet.
EPA Reg. No. 100-1318
EPA Est. XXXXX
SCP 1318 MAS 0911
____________
Net Contents
10/29/2014
100-1318
2
PRECAUTIONARY STATEMENTS
HOT LINE NUMBER
For 24 Hour Medical Emergency Assistance (Human or Animal) or
Chemical Emergency Assistance (Spill, Leak, Fire, or Accident),
Call
1-800-888-8372
Have the product container or label with you when calling a poison control center
or doctor, or going for treatment.
Hazards to Humans and Domestic Animals
Personal Protective Equipment
Applicators and other handlers must wear:
x Long-sleeved shirt and long pants
x Chemicalresistant gloves Category C such as barrier laminate; butyl rubber t14
mils; nitrile rubber t14 mils; neoprene rubber t14 mils; polyvinyl chloride (PVC) t14
mils; or Viton
® t 14 mils
x Shoes plus socks
Follow manufacturers instructions for cleaning/maintaining PPE. If no such instructions
exist for washables, use detergent and hot water. Keep and wash PPE separately from
other laundry.
Engineering Control Statements
When handlers use closed systems, enclosed cabs, or aircraft in a manner that meets
the requirements listed in the Worker Protection Standard (WPS) for agricultural
pesticides [40 CFR 170.240(d)(4-6)], the handler PPE requirements may be reduced or
modified as specified in the WPS.
User Safety Recommendations
Users should:
x Wash hands before eating, drinking, chewing gum, using tobacco, or using the toilet.
x Remove clothing/PPE immediately if pesticide gets inside. Then wash thoroughly
and put on clean clothing.
3
Environmental Hazards
This pesticide is toxic to wildlife and highly toxic to aquatic invertebrates, oysters and
shrimp. Do not apply directly to water, or to areas where surface water is present, or to
intertidal areas below the mean high water mark. Drift or runoff from treated areas may
be hazardous to aquatic organisms in neighboring areas. Do not contaminate water
when cleaning equipment or disposing of equipment wash water. This product is highly
toxic to bees exposed to direct treatment on blooming crops or weeds and may cause
possible effects to pollinators from exposure to translocated residues in blooming crops.
Do not apply this product or allow it to drift to blooming crops or weeds while bees are
foraging in/or adjacent to the treatment area.
x Surface Water Advisory
This product may impact surface water quality due to spray drift and runoff of rain
water. This is especially true for poorly draining soils and soils with shallow ground
water. This product is classified as having high potential for reaching surface water
via runoff for several months after application. A level, well-maintained vegetative
buffer strip between areas to which this product is applied and surface water
features such as ponds, streams, and springs will reduce the potential loading of
thiamethoxam water from runoff water and sediment. Runoff of this product will be
reduced by avoiding applications when rainfall is forecast to occur within 48 hours.
(See manual at the following Internet address:
http://www.wsi.nrcs.usda.gov/products/W2Q/pest/core4.html)
x Ground Water Advisory
This product has properties and characteristics associated with chemicals detected
in ground water. This chemical may leach into the ground water if used in areas
where soils are permeable, particularly where the water table is shallow.
Physical or Chemical Hazards
Do not use, pour, spill, or store near heat or open flame.
4
CONDITIONS OF SALE AND LIMITATION OF WARRANTY AND LIABILITY
NOTICE: Read the entire Directions for Use and Conditions of Sale and Limitation of
Warranty and Liability before buying or using this product. If the terms are not
acceptable, return the product at once, unopened, and the purchase price will be
refunded.
The Directions for Use of this product must be followed carefully. It is impossible to
eliminate all risks inherently associated with the use of this product. Crop injury,
ineffectiveness or other unintended consequences may result because of such factors
as manner of use or application, weather or crop conditions, presence of other materials
or other influencing factors in the use of the product, which are beyond the control of
SYNGENTA CROP PROTECTION, LLC or Seller. TO THE EXTENT PERMITTED BY
APPLICABLE LAW, Buyer and User agree to hold SYNGENTA and Seller harmless for
any claims relating to such factors.
SYNGENTA warrants that this product conforms to the chemical description on the label
and is reasonably fit for the purposes stated in the Directions for Use, subject to the
inherent risks referred to above, when used in accordance with directions under normal
use conditions. To the extent permitted by applicable law: (1) this warranty does not
extend to the use of the product contrary to label instructions or under conditions not
reasonably foreseeable to or beyond the control of Seller or SYNGENTA, and (2) Buyer
and User assume the risk of any such use. To the extent permitted by applicable law,
SYNGENTA MAKES NO WARRANTIES OF MERCHANTABILITY OR OF FITNESS
FOR A PARTICULAR PURPOSE NOR ANY OTHER EXPRESS OR IMPLIED
WARRANTY EXCEPT AS WARRANTED BY THIS LABEL.
To the extent permitted by applicable law, in no event shall SYNGENTA be liable for
any incidental, consequential or special damages resulting from the use or handling of
this product. TO THE EXTENT PERMITTED BY APPLICABLE LAW, THE
EXCLUSIVE REMEDY OF THE USER OR BUYER, AND THE EXCLUSIVE LIABILITY
OF SYNGENTA AND SELLER FOR ANY AND ALL CLAIMS, LOSSES, INJURIES
OR DAMAGES (INCLUDING CLAIMS BASED ON BREACH OF WARRANTY,
CONTRACT, NEGLIGENCE, TORT, STRICT LIABILITY OR OTHERWISE)
RESULTING FROM THE USE OR HANDLING OF THIS PRODUCT, SHALL BE THE
RETURN OF THE PURCHASE PRICE OF THE PRODUCT OR, AT THE ELECTION
OF SYNGENTA OR SELLER, THE REPLACEMENT OF THE PRODUCT.
SYNGENTA and Seller offer this product, and Buyer and User accept it, subject to the
foregoing Conditions of Sale and Limitation of Warranty and Liability, which may not be
modified except by written agreement signed by a duly authorized representative of
SYNGENTA.
5
DIRECTIONS FOR USE
It is a violation of Federal law to use this product in a manner inconsistent with its
labeling. Read entire label before using this product.
Do not apply this product in a way that will contact workers or other persons, either
directly or through drift. Only protected handlers may be in the area during application.
For any requirements specific to your State or Tribe, consult the agency responsible for
pesticide regulation.
RESTRICTIONS
x Do not treat plants grown for transplanting.
x Not for use in nurseries, plant propagation houses, or greenhouses by commercial
transplant producers on plants being grown for transplanting.
x Use this product only in commercial and farm settings.
x Not for use in home plantings.
x Not for use on ornamental plants or plants being grown for ornamental purposes.
x Do not apply to crops grown from thiamethoxam-treated seed.
The following restrictions are required to permit use of Durivo in the State of New York:
x Do not apply within 100 feet of a water body (lake, pond, river, stream, wetland, or
drainage ditch).
x Aerial application of this product is prohibited.
x This product is classified as restricted in New York State.
x Not for sale, sale into, distribution, and/or use in Nassau, Suffolk, Kings, and Queens
counties of New York State.
x In New York State, do not exceed a total of 0.188 lb ai of thiamethoxam-containing
products per acre per growing season. This seasonal load restriction for New York
State does not supersede any lower seasonal load specified in the Crop Use
Directions.
AGRICULTURAL USE REQUIREMENTS
Use this product only in accordance with its labeling and with the Worker Protection
Standard, 40 CFR Part 170. This Standard contains requirements for the protection of
agricultural workers on farms, forests, nurseries, and greenhouses, and handlers of
agricultural pesticides. It contains requirements for training, decontamination,
notification, and emergency assistance. It also contains specific instructions and
exceptions pertaining to the statements on this label about personal protective
equipment (PPE) and restricted-entry interval. The requirements in this box only apply
to uses of this product that are covered by the Worker Protection Standard.
Do not enter or allow worker entry into treated areas during the restricted-entry
interval (REI) of 12 hours.
6
PPE required for early entry to treated areas that is permitted under the Worker
Protection Standard and that involves contact with anything that has been treated, such
as plants, soil, or water, is:
x Coveralls
x Chemical-resistant gloves, Category C, such as barrier laminate; butyl rubber t 14
mils; nitrile rubber t 14 mils; neoprene rubber t 14 mils; polyvinyl chloride (PVC) t
14 mils; or Viton
® t 14 mils
x Shoes plus socks
FAILURE TO FOLLOW DIRECTIONS AND PRECAUTIONS ON THIS LABEL MAY
RESULT IN CROP INJURY, POOR INSECT CONTROL, AND/OR ILLEGAL
RESIDUES.
INFORMATION
Durivo is a systemic insecticide that controls key lepidopteran insects and listed sucking
and chewing insect pests in vegetables. When Durivo is applied to the soil, it is readily
taken up by the roots of germinating seedlings or transplants and is rapidly translocated
throughout the plant. Because of its systemic activity, Durivo provides excellent
residual control of key insect pests in vegetables.
For best performance, always follow these directions:
x Durivo can be applied to the soil during planting or transplanting as an in-furrow
spray, transplant hole drench, or narrow surface band above the seedline. In
addition, Durivo can be applied after planting or transplanting through drip
chemigation, as a hill drench, root zone shank application, or directed post-
emergence application. When making post-emergence applications, direct the
application at the base of the plant for optimum root uptake.
x The application methods described above allow the insecticide to be absorbed by
plant roots. Although Durivo is rapidly taken up by plant roots and rapidly moves
throughout the plant, the use of sufficient water volume and root zone placement will
ensure that the chemical contacts the roots, resulting in optimal uptake and
performance.
x Durivo is a selective insecticide, and is compatible with integrated pest management
programs.
x In addition to control of key insect pests on this label, Durivo may aid in the
suppression of other pests. Suppression can mean either inconsistent control (good
to poor), or consistent control at a level below that generally considered acceptable
for commercial control.
x Durivo is safe for listed crops when used in accordance with this label.
7
RESISTANCE MANAGEMENT
GROUP 4A 28 INSECTICIDE
Some insect pests are known to develop resistance to products after repeated use.
Because resistance development cannot be predicted, the use of this product should
conform to sound resistance management strategies established for the crop and use
area. Syngenta encourages responsible product stewardship to ensure effective long-
term control of the insects on this label.
Durivo contains a Group 4A insecticide (thiamethoxam, belonging to the neonicotinoid
class of chemistry) and a Group 28 insecticide (chlorantraniliprole, belonging to the
diamide class of chemistry). Insect biotypes with acquired or inherent resistance to
Group 4A or Group 28 insecticides may eventually dominate the insect population if
Group 4A or Group 28 insecticides are used repeatedly as the predominant method of
control for targeted species. This may result in partial or total loss of control of those
species by Durivo or other Group 4A or Group 28 insecticides.
If resistance to this product develops in your area, this product, or other products with a
similar mode of action, may not provide adequate control. If poor performance cannot
be attributed to improper application or extreme weather conditions, a resistant strain of
insect may be present. If you experience difficulty with control and resistance is a
reasonable cause, immediately consult your local company representative or
agricultural advisor for the best alternative method of control for your area.
In order to maintain susceptibility to these classes of chemistry:
x Avoid using Group 4A and/or Group 28 insecticides exclusively for season-long
control of insect species with more than one generation per crop season.
x For insect species with successive or overlapping generations, apply Durivo or other
Group 4A and/or Group 28 insecticides using a “treatment window” approach. A
treatment window is a period of time as defined by the stage of crop development
and/or the biology of the pests of concern. Within the treatment window, depending
on the length of residual activity, there may either be single or consecutive
applications (seed treatment, soil, foliar, unless otherwise stated in the Directions for
Use) of the Group 4A and/or Group 28 insecticides. Do not exceed the maximum
Durivo allowed per growing season.
x Following a treatment window of Group 4A and/or Group 28 insecticides, rotate to a
treatment window of effective products with a different mode of action before making
additional applications of Group 4A and/or Group 28 insecticides.
x A treatment window rotation, along with other IPM practices for the crop and use
area, is considered an effective strategy for preventing or delaying a pests ability to
develop resistance to these classes of chemistry.
x If resistance is suspected, do not reapply Durivo or other Group 4A or Group 28
insecticides.
Other Insect Resistance Management (IRM) practices include:
8
x Incorporating IPM techniques into your insect control program.
x Monitoring treated insect populations for loss of field efficacy.
x Using tank-mixtures or premixes with insecticides from a different target site of
action group as long as the involved products are all registered for the same crop
outlet and effective rates are applied.
For additional information on Insect Resistance Management:
x Contact your local extension specialist, certified crop advisor and/or product
manufacturer for additional insect resistance management recommendations.
x Visit the Insecticide Resistance Action Committee (IRAC) on the web at
http://www.irac-online.org/.
APPLICATION PROCEDURES
SOIL APPLICATION
Select spray nozzles or metering orifices which will provide accurate and uniform
deposition. Durivo can be applied to the soil during planting or transplanting as an in-
furrow spray, transplant hole drench, or narrow surface band above the seedline. In
addition, Durivo can be applied after planting or transplanting through drip chemigation,
as a hill drench, as a root zone shank application, or as a directed post-emergence
application. When making post-emergence applications, direct the application at the
base of the plant for optimum root uptake.
The application methods described above allow the insecticide to be absorbed by plant
roots. Although Durivo is rapidly taken up by plant roots and rapidly moves throughout
the plant, the use of sufficient water volume and root zone placement will ensure that
the chemical contacts the roots, resulting in optimal uptake and performance.
To help ensure accuracy, calibrate sprayer before each use. For information on spray
equipment and calibration, consult sprayer manufacturers and/or State Extension
Service specialists.
Do not apply Durivo as a broadcast foliar spray with ground or aerial equipment.
Drip (trickle) Chemigation
Applications of Durivo alone or in combination with other pesticides registered for
application through drip irrigation systems may be applied in irrigation water at rates
specified on this label. This product may be applied only through drip type irrigation
systems. Do not apply Durivo through any other type of irrigation system. Do not allow
pooling of irrigation water.
9
Directions for Specified Irrigation Systems
Uniform Water Distribution and System Calibration
The irrigation system must provide uniform distribution of treated water. Crop injury,
lack of effectiveness, or illegal pesticide residues in the crop can result from non-
uniform distribution of treated water. The system must be calibrated to uniformly apply
the rates specified. If you have questions about calibration, contact State Extension
Service specialists, equipment manufacturers, or other experts. A person
knowledgeable of the chemigation system and responsible for its operation, or under
the supervision of the responsible person, shall shut the system down and make
necessary adjustments should the need arise.
Dilute Durivo in the solution tank at a ratio of at least 5 parts of water to one part of
Durivo. Injecting a larger volume of a more dilute solution will usually result in a more
accurate calibration of the metering equipment. Meter the insecticide into the irrigation
water during the irrigation cycle.
Using Water from Public Water Systems: DO NOT APPLY DURIVO THROUGH
ANY IRRIGATION SYSTEM PHYSICALLY CONNECTED TO A PUBLIC WATER
SYSTEM. Public water system means a system for the provision to the public of piped
water for human consumption, if such system has at least 15 service connections or
regularly serves an average of at least 25 individuals daily at least 60 days out of the
year. Durivo may be applied through irrigation systems, which may be supplied by a
public water system only if the water from the public water system is discharged into a
reservoir tank prior to pesticide introduction. There shall be a complete physical break
(air gap) between the outlet end of the fill pipe and to top or overflow rim of the reservoir
tank of at least twice the inside diameter of the fill pipe. Before beginning chemigation,
always make sure that the air gap exists and that there is no blockage of the overflow of
the reservoir tank.
Any irrigation system using water supplied from a public water system must also meet
the following requirements.
Operating Instructions FOR DRIP IRRIGATION SYSTEMS
1. The system must be calibrated to uniformly apply the rates specified. If you have
questions about calibration, contact State Extension Service specialists, equipment
manufacturers, or other experts.
2. The system must contain a functional check-valve, vacuum relief valve, and low-
pressure drain appropriately located on the irrigation pipeline to prevent water
source contamination from backflow.
10
3. The pesticide injection pipeline must contain a functional, automatic, quick-closing
check-valve to prevent the flow of fluid back toward the injection pump.
4. The pesticide injection pipeline must also contain a functional, normally closed,
solenoid-operated valve located on the intake side of the injection pump and
connected to the system interlock to prevent fluid from being withdrawn from the
supply tank when the irrigation system is either automatically or manually shut down.
5. The system must contain functional interlocking controls to automatically shut off the
pesticide injection pump when the water pump motor stops.
6. The irrigation line or water pump must include a functional pressure switch, which
will stop the water pump motor when the water pressure decreases to the point
where pesticide distribution is adversely affected.
7. Systems must use a metering pump, such as a positive displacement injection pump
(e.g., diaphragm pump, or a Venturi injector), effectively designed and constructed of
materials that are compatible with pesticides and capable of being fitted with a
system interlock.
8. The pesticide injection pipeline must be on the downstream (field) side of the system
filters to avoid potential pesticide off-site contamination or misapplication as a result
of the filter back-flushing process.
9. Have a dedicated pesticide injection tank for chemigation purposes rather than tank-
mixing pesticides with fertilizers or other non-pesticide chemigation products. This
reduces the potential for incompatibility issues which could result in misapplication.
10. Make Durivo injections into the center of the water pipe for a thorough and quick
mix. This can be accomplished with an “injection tube” which should contain a check
valve.
Application Instructions
Durivo must be applied on the schedule specified in the Crop Use Directions, not
according to the drip irrigation schedule. The following calibration and application
techniques are provided for user reference, but do not constitute a warranty of fitness
for application through drip type irrigation equipment. Check with state and local
regulatory agencies for potential use restrictions before applying any agricultural
chemicals through irrigation equipment.
1. Each run of the irrigation system must be calibrated separately to determine the time
it takes water to move through the system and to make sure all emitters in the
system are putting out the same amount of water.
2. Use only pressure injection or Venturi equipment.
11
3. Determine the area to be treated in each irrigation run.
4. Measure the output of each of the emitters or drip tubes closest to and farthest from
the injection point.
5. For calibration, substitute a concentrated detergent (such as Wisk) for the Durivo
mixture in the injector (solution) tank. It is important to use the same volume of
soap solution as the planned volume of Durivo solution when calibrating the
system. The detergent will bubble as it leaves the emitters. The time period over
which the bubbles occur should be checked for both the closest and farthest
emitters. If these times are not within 2 minutes of each other, adjust the dilution
ratio and/or the injection rate.
Step-by-Step Calibration and Application Instructions
1. Before starting to calibrate, operate the system until all of the emitters are putting out
at equal flow rates or until the system is operating at full pressure.
2. Make up an indicator solution of detergent or fertilizer, using the same rate of
indicator as the planned volume of Durivo to be used in the mix.
3. Set the injector to apply the indicator solution at the injection rate to be used in the
actual Durivo application.
4. Attach a 12-inch length of flexible tubing over the emitter closest to the injection
point, another 12-inch length over the emitter farthest away. Monitor both emitters to
determine the time intervals that the indicator solutions are observed.
5. Begin injecting the indicator solution. Direct the flow from the flexible tubes into a
small container. Begin timing when the indicator solution is first detected. Stop
timing when the indicator solutions are no longer detected in the container.
6. If the period of detection of the indicator solution between the near and far emitter is
within 2 minutes, comparable coverage will be obtained. If they are not, make
adjustments by increasing the dilution ratio, using more water per part of Durivo, or
adjust the injector to a slower flow rate.
7. Once the system is calibrated, dilute the needed amount of Durivo with water and
any other tank mix partners in the injection tank at a minimum dilution of 15 parts
water to 1 part Durivo. Follow the directions for mixing and equipment set up in the
Mixing Procedures section of this label for complete details.
8. Do not begin to inject Durivo into the system until all emitters are producing equal
flow rates, or until the system is at full pressure.
12
9. Inject the Durivo solution into the system in the middle of the irrigation set in ½-1
inch of irrigation water.
MIXING PROCEDURES
Prepare no more injector tank mixture than is needed for the immediate operation.
Thoroughly clean drip irrigation equipment before using this product. Vigorous agitation
is necessary for proper dispersal of the product. Maintain maximum agitation
throughout the drip irrigation operation. Do not let the injector tank mixture stand
overnight in the injector tank. Flush the drip irrigation equipment thoroughly following
each use and apply the rinsate to a previously treated area. Keep product container
tightly closed when not in use.
Durivo Alone: Add 1/2 of the required amount of water to the mix tank. With the
agitator running, add the Durivo to the tank. Continue agitation while adding the
remainder of the water. Begin application of the solution after the Durivo has
completely dispersed into the mix water. Maintain agitation until all of the mixture has
been applied.
Durivo + Tank Mixtures: Add 1/2 of the required amount of water to the mix tank.
Start the agitator running before adding any tank mix partners. Add tank mix partners in
this order: products packaged in water-soluble packaging, wettable powders, wettable
granules (dry flowables), liquid flowables such as Durivo, liquids and emulsifiable
concentrates. Always allow each tank mix partner to become fully dispersed before
adding the next product. Provide sufficient agitation while adding the remainder of the
water. Maintain agitation until all of the mixture has been applied.
Note: When using Durivo in tank mixtures, add all products in water-soluble packaging
to the tank before any other tank mix partner, including Durivo. Allow the water-soluble
packaging to completely dissolve and the product(s) to completely disperse before
adding any other tank mix partner to the tank.
If using Durivo in a tank mixture, observe all directions for use, crop/sites, use rates,
dilution ratios, precautions, and limitations that appear on the tank mix product label.
Do not exceed any label dosage rate, and follow the most restrictive label precautions
and limitations. Do not mix this product with any product that prohibits such mixing.
Tank mixtures or other applications of products referenced on this label are permitted
only in those states in which the referenced products are labeled.
Compatibility: Durivo is compatible with most commonly used pesticides and
nutritional sprays. However, since it is not possible to test all possible mixtures, the
user should pre-test to insure the physical compatibility and lack of phytotoxic effect of
any proposed mixtures with Durivo. To determine the physical compatibility of Durivo
with other products, use a jar test, as described below.
13
Using a quart jar, add the proportionate amounts of the products to 1 qt. of water. Add
wettable powders and water-dispersible granular products first, then liquid flowables,
and emulsifiable concentrates last. After thoroughly mixing, let stand for at least 5
minutes. If the combination remains mixed or can be remixed readily, it is physically
compatible. Once compatibility has been proven, use the same procedure for adding
required ingredients to the injector tank.
The crop safety of all potential tank mixes on all crops has not been tested. Confirm the
safety to the target crop before applying any tank mixture not specified on this label.
CROP USE DIRECTIONS
Crop Pest Rate Per Acre Per Application
Brassica (Cole) Leafy Vegetables
Head & Stem Brassica
Broccoli
Broccoli, Chinese (gai lon)
Brussels sprouts
Cabbage
Cabbage, Chinese (napa)
Cabbage, Chinese mustard
(gai choy)
Cauliflower
Cavalo broccolo
Kohlrabi
Leafy Brassica Greens
Broccoli raab (rapini)
Cabbage, Chinese (bok choy)
Collards
Kale
Mizuna
Mustard greens
Mustard spinach
Rape greens
Aphids
Beet Armyworm
Cabbage Looper
Cabbage Webworm
Corn Earworm
Diamondback Moth
Fall Armyworm
Flea Beetles
Imported Cabbageworm
Southern Cabbageworm
Thrips
Whiteflies
Yellowstriped Armyworm
10.0 13.0 fl oz/A
Use Restrictions
x Maximum Durivo Allowed per Growing Season: Do not exceed a total of 13.0 fl oz/A
(0.257 lb ai/A) of Durivo or 0.172 lb ai of thiamethoxam-containing products or 0.2 lb ai of
chlorantraniliprole-containing products per acre per growing season.
x Application Rate: Use lower rates for short residual control and higher rates within the
listed rate range for long residual control. See rate conversion chart for rate per 1000 linear
feet.
x Application Number: Make only one soil application per crop season.
x Application Timing and Method: Apply specified dosage in sufficient water volume using
one of the following methods:
14
1. Apply to the soil during planting or transplanting as an in-furrow spray or transplant hole
drench at the seeding or transplant depth, or a narrow surface band above the seedline
during planting. For surface-banded applications, incorporate to the seeding depth with
sufficient sprinkle or drip irrigation within 24 hours.
2. Apply after planting or transplanting as a hill drench or directed post-emergence
application using sufficient water volume to ensure incorporation into the root zone.
When making post-emergence applications, direct the application at the base of the
plant for optimum root uptake.
3. In drip (trickle) chemigation
4. Shanked into the root zone after establishment or transplanting using fertilizer knives or
other similar equipment. After application, incorporate with enough irrigation to move the
chemical to the root zone.
For planting systems where multiple rows are planted on beds, apply Durivo according to
one of the above methods.
x Pre-Harvest Interval (PHI): 30 Days
Refer to Resistance Management section.
15
Crop Pest Rate Per Acre Per Application
Cucurbit Vegetables
Chayote
Chinese waxgourd
Citron melon
Cucumber
Gherkin
Gourd, edible (hyotan, cucuzza,
hechima, Chinese okra)
Momordica species (balsam
apple, balsam pear,
bittermelon, Chinese
cucumber)
Muskmelon (hybrids and/or
cultivars of Cucumis melo)
includes true cantaloupe,
cantaloupe, casaba,
Crenshaw melon, golden
pershaw melon, honeydew
melon, honey balls, mango
melon, Persian melon,
pineapple melon, Santa
Claus melon, and snake
melon)
Pumpkin
Squash: summer (crookneck
squash, scallop squash,
straightneck squash,
vegetable marrow, zucchini)
and
winter (butternut squash,
calabaza, hubbard squash,
acorn squash, spaghetti
squash)
Watermelon (includes hybrids
and/or varieties of Citrullus
lanatus)
Aphids
Cucumber Beetles
1
Flea Beetles
Leafhoppers
Leafminers
1
Melonworm
Pickleworm
Thrips
Whiteflies
10.0 13.0 fl oz/A
Use Restrictions
x Maximum Durivo Allowed per Growing Season: Do not exceed a total of 13.0 fl oz/A
(0.257 lb ai/A) of Durivo or 0.172 lb ai of thiamethoxam-containing products or 0.2 lb ai of
chlorantraniliprole-containing products per acre per growing season.
x Application Rate: Use lower rates for short residual control and higher rates within the
listed rate range for long residual control. See rate conversion chart for rate per 1000 linear
feet.
x Application Number: Make only one soil application per crop season.
16
x Application Timing and Method: Apply specified dosage in sufficient water volume using
one of the following methods:
1. Apply to the soil during planting or transplanting as an in-furrow spray or transplant hole
drench at the seeding or transplant depth, or a narrow surface band above the seedline
during planting. For surface-banded applications, incorporate to the seeding depth with
sufficient sprinkle or drip irrigation within 24 hours.
2. Apply after planting or transplanting as a hill drench or directed post-emergence
application using sufficient water volume to ensure incorporation into the root zone.
When making post-emergence applications, direct the application at the base of the
plant for optimum root uptake.
3. In drip (trickle) chemigation
4. Shanked into the root zone after establishment or transplanting using fertilizer knives or
other similar equipment. After application, incorporate with enough irrigation to move the
chemical to the root zone.
For planting systems where multiple rows are planted on beds, apply Durivo according to
one of the above methods.
x Pre-Harvest Interval (PHI): 30 Days
x Pest Control:
1Suppression.
Refer to Resistance Management section.
17
Crop
Pest
Rate Per Acre Per Application
Fruiting Vegetables
Eggplant
Groundcherry
Pepino
Peppers:
bell, chili, cooking
pimento, and sweet
Tomatillo
Tomato
Aphids
Beet Armyworm
Colorado Potato Beetle
Fall Armyworm
Flea Beetles
Hornworm species
Leafhoppers
Leafminers
1
Loopers
Potato Psyllid
Southern Armyworm
Thrips
Tomato Fruitworm
Tomato Pinworm
Whiteflies
Yellowstriped Armyworm
10.0 13.0 fl oz/A
Use Restrictions
x Maximum Durivo Allowed per Growing Season: Do not exceed a total of 13.0 fl oz/A
(0.257 lb ai/A) of Durivo or 0.172 lb. a.i. of thiamethoxam containing products or 0.2 lb ai of
chlorantraniliprole-containing products per acre per growing season.
x Application Rate: Use lower rates for short residual control and higher rates within the
listed rate range for long residual control. See rate conversion chart for rate per 1000 linear
feet.
x Application Number: Make only one soil application per crop season.
x Application Timing and Method: Apply specified dosage in sufficient water volume using
one of the following methods:
1. Apply to the soil during planting or transplanting as an in-furrow spray or transplant hole
drench at the seeding or transplant depth or a narrow surface band above the seedline
during planting. For surface-banded applications, incorporate to the seeding depth with
sufficient sprinkle or drip irrigation within 24 hours.
2. Apply after planting or transplanting as a hill drench, or directed post-emergence
application using sufficient water volume to ensure incorporation into the root zone.
When making post-emergence applications, direct the application at the base of the
plant for optimum root uptake.
3. In drip (trickle) chemigation
4. Shanked into the root zone after establishment or transplanting using fertilizer knives or
other similar equipment. After application, incorporate with enough irrigation to move the
chemical to the root zone.
For planting systems where multiple rows are planted on beds, apply Durivo according to
one of the above methods.
x Pre-Harvest Interval (PHI): 30 Days
x Pest Control:
1Suppression
Refer to Resistance Management section.
18
Crop Pest Rate Per Acre Per Application
Leafy Vegetables
Amaranth
Arugula (roquette)
Cardoon
Celery
Celery, Chinese
Celtuce
Chervil
Chrysanthemum:
edible- leaved and
garland
Corn Salad
Cress: garden and
upland (yellow rocket,
winter cress)
Dandelion
Dock (sorrel)
Endive (escarole)
Fennel, Florence (finochio)
Lettuce: head and leaf
Orach
Parsley
Purslane:
garden and winter
Radicchio (red chicory)
Rhubarb
Spinach including New
Zealand
and Vine (Malabar,
Indian)
Swiss chard
Aphids
Beet Armyworm
Cabbage Looper
Corn Earworm
Diamondback Moth
Fall Armyworm
Flea Beetles
Imported Cabbageworm
Leafhoppers
Leafminers
1
Whiteflies
10.0 13.0 fl oz/A
19
Use Restrictions
x Maximum Durivo Allowed per Growing Season: Do not exceed a total of 13.0 fl oz/A
(0.257 lb ai/A) of Durivo or 0.172 lb ai of thiamethoxam-containing products or 0.2 lb ai of
chlorantraniliprole-containing products per acre per growing season.
x Application Rate: Use lower rates for short residual control and higher rates within the
listed rate range for long residual control. See rate conversion chart for rate per 1000 linear
feet.
x Application Number: Make only one soil application per crop season.
x Application Timing and Method: Apply specified dosage in sufficient water volume using
one of the following methods:
1. Apply to the soil during planting or transplanting as an in-furrow spray or transplant hole
drench at the seeding or transplant depth or a narrow surface band above the seedline
during planting. For surface-banded applications, incorporate to the seeding depth with
sufficient sprinkle or drip irrigation within 24 hours.
2. Apply after planting or transplanting as a hill drench, or directed post-emergence
application using sufficient water volume to ensure incorporation into the root zone.
When making post-emergence applications, direct the application at the base of the
plant for optimum root uptake.
3. In drip (trickle) chemigation.
4. Shanked into the root zone after establishment or transplanting using fertilizer knives or
other similar equipment. After application, incorporate with enough irrigation to move the
chemical to the root zone.
For planting systems where multiple rows are planted on beds, apply Durivo according to
one of the above methods.
x Pre-Harvest Interval (PHI): 30 Days
x Pest Control:
1Suppression
Refer to Resistance Management section.
20
Crop Pest Rate Per 1,000 Plants
Tobacco
Aphids
0.6 1.6 fl oz/1,000 plants
Flea Beetles
Japanese Beetle
Tomato Spotted Wilt Virus
(TSWV) Suppression of
symptoms
1.0 1.6 fl oz/1,000 plants
Thrips (Suppression)
1.0 fl oz/1,000 plants
Mole Crickets
Tobacco Budworm
Tomato Hornworm
Tobacco Hornworm
Thrips
Whiteflies
Wireworms
1.6 fl oz/1,000 plants
Use Restrictions:
x Application Timing: Make only one soil application per season.
x Application Rate: Use lower rates for short residual control and higher rates within the
listed rate range for long residual control.
x Application Method: Apply at transplant using the method described below. Apply
specified dosage in sufficient water volume to ensure uniform application.
1. Soil Treatment: Mix appropriate amounts of Durivo in water and drench transplants as
they are being placed in the ground.
x Maximum Durivo Allowed per Growing Season: Do not exceed a total of 10.0 fl oz/A
(0.188 lb ai/A) of Durivo or 0.125 lb ai of soil-applied thiamethoxam-containing products or
0.2 lb ai of chlorantraniliprole-containing products per acre per growing season.
x Tomato Spotted Wilt Virus (TSWV) is vectored by thrips and controlling or suppressing
thrips can help to reduce TSWV. Use the higher rate within the listed rate range where
TSWV pressure is higher.
x Do not use an adjuvant with applications of Durivo to tobacco.
Refer to Resistance Management section.
21
Durivo Conversion Chart for Drip Linear Application
20” 30” 34” 36” 38” 40” 46” 60” 72” 78” 80” 84” Row
Spacing
26,136 17,424 15,374 14,520 13,756 13,068 11,363 8,712 7,260 6,702 6,534 6,223 Linear
Ft/A
Rate
(oz/A) Rate in ounces. of product per 1,000 linear feet for specified row spacing and rate per acre lb ai/A
10.0 0.38 0.57 0.65 0.69 0.73 0.77 0.88 1.15 1.38 1.49 1.53 1.61 0.195
11.0 0.42 0.63 0.72 0.76 0.80 0.84 0.97 1.26 1.52 1.64 1.68 1.77 0.215
12.0 0.46 0.69 0.78 0.83 0.87 0.92 1.06 1.38 1.65 1.79 1.84 1.93 0.234
13.0 0.50 0.75 0.85 0.90 0.95 0.99 1.14 1.49 1.79 1.94 1.99 2.09 0.254
ROTATIONAL RESTRICTIONS
Any cover crop planted for erosion control or soil improvement may be planted as soon
as practical following the last application. However, the cover crop may not be grazed
or harvested for food or feed. For all other rotational crops intended for food or feed,
the plant-back intervals listed below must be observed.
Immediate Plant-Back Interval:
Brassica (cole) leafy vegetables; cucurbit vegetables; fruiting vegetables, leafy
vegetables, cotton, Root and Tuber Vegetables (Crop Group 1) except beet, sugar.
30-Day Plant Back Interval:
Alfalfa, Legume vegetables (Crop Group 6), soybean, barley, wheat, sorghum, peanuts
and strawberry.
120-Day Plant-Back Interval:
Tops of Root and Tuber Vegetables (Crop Group 2), Bulb Vegetables (Crop Group 3),
Cereal Grains (Crop Group 15) except alfalfa, wheat, cowpea, pea, field, okra.
12-month Plant-Back Interval:
All other crops.
22
STORAGE AND DISPOSAL
Do not contaminate water, food, or feed by storage or disposal.
Pesticide Storage
Store in a cool, dry place.
Pesticide Disposal
Pesticide wastes may be toxic. Improper disposal of unused pesticide, mixture, or rinse
water is a violation of Federal law. If these wastes cannot be used according to label
instruction, contact your State Pesticide or Environmental Control Agency, or the
Hazardous Waste representative at the nearest EPA Regional Office for guidance in
proper disposal methods.
For minor spills, leaks, etc., follow all precautions indicated on this label and clean up
immediately. Take special care to avoid contamination of equipment and facilities during
cleanup procedures and disposal of wastes. In the event of a major spill, fire, or other
emergency, call 1-800-888-8372, day or night.
Container Handling [less than or equal to 5 gallons]
Non-refillable container. Do not reuse or refill this container. Triple rinse container (or
equivalent) promptly after emptying. Triple rinse as follows: empty the remaining
contents into application equipment or a mix tank and drain for 10 seconds after the flow
begins to drip. Fill the container ¼ full with water and recap. Shake for 10 seconds.
Pour rinsate into application equipment or a mix tank or store rinsate for later use or
disposal. Drain for 10 seconds after the flow begins to drip. Repeat this procedure two
more times. Offer for recycling if available or puncture and dispose of in a sanitary
landfill, or by incineration, or by other procedures allowed by state and local authorities.
Container Handling [greater than 5 gallons - bulk]
Refillable container. Refill this container with pesticide only. Do not reuse this container
for any other purpose. Cleaning the container before final disposal is the responsibility
of the person disposing of the container. Cleaning before refilling is the responsibility of
the person refilling. To clean container before final disposal, empty the remaining
contents from this container into application equipment or mix tank. Fill the container
about 10 percent full with water. Agitate vigorously or recirculate water with the pump
for 2 minutes. Pour or pump rinsate into application equipment or rinsate collection
system. Repeat this rinsing procedure two more times. Then offer for recycling if
available or puncture and dispose of in a sanitary landfill, or by incineration, or by other
procedures approved by state and local authorities.
Container Handling [greater than 5 gallons mini-bulk]
Non-refillable container. Do not reuse or refill this container. Triple rinse container (or
equivalent) promptly after emptying. Triple rinse as follows: Empty the remaining
contents into application equipment or a mix tank. Fill the container ¼ full with water.
23
Replace and tighten closures. Tip container on its side and roll it back and forth,
ensuring at least one complete revolution, for 30 seconds. Stand the container on its
end and tip it back and forth several times. Turn the container over onto its other end
and tip it back and forth several times. Empty the rinsate into application equipment or
a mix tank or store rinsate for later use or disposal. Repeat this procedure two more
times. Then offer for recycling if available or puncture and dispose of in a sanitary
landfill, or by incineration, or by other procedures approved by state and local
authorities.
Durivo, the ALLIANCE FRAME, the SYNGENTA logo, and the PURPOSE ICON are
trademarks of a Syngenta Group Company
¤2014 Syngenta
Viton® is a registered trademark of E.I. DuPont de Nemours and Company
For non-emergency (e.g., current product information), call
Syngenta Crop Protection at 1-800-334-9481.
Manufactured for:
Syngenta Crop Protection, LLC
P.O. Box 18300
Greensboro, North Carolina 27419-8300
SCP 1318-MAS 0911
24
(Non-detachable container)
Not for sale, sale into, distribution, and/or use in Nassau, Suffolk, Kings, and Queens
counties of New York State.
Durivo®
GROUP 4A 28 INSECTICIDE
Insecticide
For control of listed insect pests infesting specified crops
Active Ingredient:
Thiamethoxam
1 ............................................................................................ 17.5%
Chlorantraniliprole2 ......................................................................................... 8.8%
Other Ingredients: 73.7%
Total: 100.0%
1CAS No. 153719-23-4
2CAS No. 500008-45-7
Durivo is a soluble concentrate containing 1.67 lb of thiamethoxam and 0.835 lb
chlorantraniliprole per gallon.
KEEP OUT OF REACH OF CHILDREN.
Si usted no entiende la etiqueta, busque a alguien para que se la explique a usted en
detalle. (If you do not understand the label, find someone to explain it to you in detail.)
See additional precautionary statements and directions for use in booklet.
AGRICULTURAL USE REQUIREMENTS
Use this product only in accordance with its labeling and with the Worker Protection
Standard, 40 CFR part 170. Refer to supplemental labeling under “Agricultural Use
Requirements” in the Directions for Use section for information about this standard
EPA Reg. No. 100-1318
EPA Est. XXXXX
SCP 1318-MAS 0911
____________
Net Contents
25
PRECAUTIONARY STATEMENTS
Hazards to Humans and Domestic Animals
HOT LINE NUMBER
For 24-Hour Medical Emergency Assistance (Human or Animal) or
Chemical Emergency Assistance (Spill, Leak, Fire, or Accident),
Call
1-800-888-8372
Have the product container or label with you when calling a poison control center
or doctor, or going for treatment.
Environmental Hazards
This pesticide is toxic to wildlife and highly toxic to aquatic invertebrates, oysters and
shrimp. Do not apply directly to water, or to areas where surface water is present, or to
intertidal areas below the mean high water mark. Drift or runoff from treated areas may
be hazardous to aquatic organisms in neighboring areas. Do not contaminate water
when cleaning equipment or disposing of equipment wash water. This product is highly
toxic to bees exposed to direct treatment on blooming crops or weeds and may cause
possible effects to pollinators from exposure to translocated residues in blooming crops.
Do not apply this product or allow it to drift to blooming crops or weeds while bees are
foraging in/or adjacent to the treatment area.
STORAGE AND DISPOSAL
Do not contaminate water, food, or feed by storage or disposal.
Pesticide Storage
Store in a cool, dry place.
Pesticide Disposal
Pesticide wastes may be toxic. Improper disposal of unused pesticide, mixture, or rinse
water is a violation of Federal law. If these wastes cannot be used according to label
instruction, contact your State Pesticide or Environmental Control Agency, or the
Hazardous Waste representative at the nearest EPA Regional Office for guidance in
proper disposal methods.
For minor spills, leaks, etc., follow all precautions indicated on this label and clean up
immediately. Take special care to avoid contamination of equipment and facilities during
cleanup procedures and disposal of wastes. In the event of a major spill, fire, or other
emergency, call 1-800-888-8372, day or night.
26
Container Handling [less than or equal to 5 gallons]
Non-refillable container. Do not reuse or refill this container. Triple rinse container (or
equivalent) promptly after emptying. Triple rinse as follows: empty the remaining
contents into application equipment or a mix tank and drain for 10 seconds after the flow
begins to drip. Fill the container ¼ full with water and recap. Shake for 10 seconds.
Pour rinsate into application equipment or a mix tank or store rinsate for later use or
disposal. Drain for 10 seconds after the flow begins to drip. Repeat this procedure two
more times. Offer for recycling if available or puncture and dispose of in a sanitary
landfill, or by incineration, or by other procedures allowed by state and local authorities.
Container Handling [greater than 5 gallons bulk]
Refillable container. Refill this container with pesticide only. Do not reuse this container
for any other purpose. Cleaning the container before final disposal is the responsibility
of the person disposing of the container. Cleaning before refilling is the responsibility of
the person refilling. To clean container before final disposal, empty the remaining
contents from this container into application equipment or mix tank. Fill the container
about 10 percent full with water. Agitate vigorously or recirculate water with the pump
for 2 minutes. Pour or pump rinsate into application equipment or rinsate collection
system. Repeat this rinsing procedure two more times. Then offer for recycling if
available or puncture and dispose of in a sanitary landfill, or by incineration, or by other
procedures approved by state and local authorities.
Container Handling [greater than 5 gallons mini-bulk]
Non-refillable container. Do not reuse or refill this container. Triple rinse container (or
equivalent) promptly after emptying. Triple rinse as follows: Empty the remaining
contents into application equipment or a mix tank. Fill the container ¼ full with water.
Replace and tighten closures. Tip container on its side and roll it back and forth,
ensuring at least one complete revolution, for 30 seconds. Stand the container on its
end and tip it back and forth several times. Turn the container over onto its other end
and tip it back and forth several times. Empty the rinsate into application equipment or
a mix tank or store rinsate for later use or disposal. Repeat this procedure two more
times. Then offer for recycling if available or puncture and dispose of in a sanitary
landfill, or by incineration, or by other procedures approved by state and local
authorities.
Refer to Surface Water Advisory, Ground Water Advisory, Physical or Chemical
Hazards and Chemigation sections in booklet.
Durivo and the Syngenta logo are trademarks of a Syngenta Group Company
¤2014 Syngenta
Manufactured for:
Syngenta Crop Protection, LLC
P.O. Box 18300
Greensboro, North Carolina 27419-8300
27
SCP 1318-MAS 0911
Durivo 1318 MAS 0911 AMEND AUG2014-HI pl 8/19/14
000100-01318.20140819.DURIVO_AMEND_AUG2014-HI.pdf
Durivo 1318 MAS 0911 AMEND AUG2014-CLEAN pl 8/19/14
000100-01318.20140819.DURIVO_AMEND_AUG2014.pdf
Durivo 1318 MAS 0911 AMEND AUG2014 Version B-HI pl 10/23/14
000100-01318.20140819B.DURIVO_AMEND_AUG2014-HI.pdf
Durivo 1318 MAS 0911 AMEND AUG2014 Version B-CLEAN pl 10/23/14
000100-01318.20140819B.DURIVO_AMEND_AUG2014.pdf