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crop-chem-docs/corpus/epa_ppls/10182-179.md
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justin a97107de46
Image rebuild (skip scrape) / build (push) Failing after 1h37m12s
docker: production image + Gitea Actions for monthly refresh
Dockerfile: self-contained image with corpus + Chroma + BM25 baked
in. Drawbar's compose pulls + runs without volume mounts. Built from
sources.json (labels schema), PRODUCT_NAME=crop_chem by default,
HYBRID_SEARCH=true (always-on for production quality). RERANK_URL +
OLLAMA_URL get set at compose time.

.gitea/workflows/refresh.yml: monthly cron (1st @ 06:00 UTC) does
full scrape → reindex → image push. Scrapes Bayer (~30 min) +
EPA PPLS row-crop filtered (~7h). Skips reindex+push if no corpus
diff. Tags pushed: :latest, :<sha12>, :corpus-<YYYY.MM.DD>.

.gitea/workflows/image-only.yml: on-demand or auto on code-only
pushes to main (paths: docs_mcp/, rag/, scrape/, requirements.txt,
Dockerfile, sources.json). Reindexes from committed corpus, builds
image, pushes. ~10 min vs ~9h full refresh.

.gitignore: corpus/ now COMMITTED (4,159 labels, 265 MB of .md +
sidecars). Lets image-only.yml rebuild indexes without re-scraping.
chroma/ + bm25/ still gitignored (regenerable binary indexes).

.dockerignore: drops venv, eval results, PLAN/README/CLAUDE.md,
deploy/, .git/ — keeps the image lean. corpus + chroma + bm25
explicitly NOT in dockerignore (those go INTO the image).

Co-Authored-By: Claude Opus 4.7 (1M context) <noreply@anthropic.com>
2026-05-24 12:32:41 -04:00

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# DYFONATE 5 GRANULAR
- EPA Reg No: **10182-179**
- Registrant: SYNGENTA CROP PROTECTION
- Signal word: Warning
- Active ingredients: Fonofos (5%)
- Label accepted: 1985-08-07
- Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/000476-01994-19850807.pdf
---
ACTIVE INGREDIENT:
(5ld~ffer ~hj~ld)
DYFONATE® S-G
C; r" d nul Ii r SOl 1 Ins t: c t 1 C 1 d L'
v-Etnyl S-pn~nyl ~thylrr\()sphonodlth\oat~*
INERT INGREDIfNTS: ............ .
(Contalns S pOlJnds letlV,. ln~red;ent per lUI) P')UiI'JS)
*OHONAH
K t L P II U I U F I< E A C H 0 f CHI Ll) t, :: ~~
I)S .Ij~
9'>.U;
1 Illl • IJ \
WARNING
,l.VISO
P~ECAUCION Al LSUARIO:
-S-r~sTTIT NO l [E -jNG l E S ,
STATEMENT Of PRACTICAL TREATMENT
FOR PESTICIDE EMERGENCY
NO USE ESTE PROIUCTU HASTA
QUE lA lTIQUETA LE HAY~
SIOO EXPL ICADA ,l.r~PL IAMinE.
CALL A PHYSICIAN IMMEDIATELY: If a known exposur~ occurs, or j f
poisonlng is suspected, do not wait for symptoms to develop.
Immediately start the procedures given ~elow and slmultaneo~sly
contact a Poison Cent-cr, a physician, or the nearest hospitcl rH
call collect, day or n1ght, Stauffer Chemical Conlpany (2tl3) !2b-6bll('
or Chemtrec (8UO) 424-9300.
Note: Be sure to advi se the person contacted that the compound 1S
d cholinesterase inhibitor. Describe the type of exposure, the
victim's symptoms, and follow the advice given.
POISON SYMPTOMS - DYFONATE is a highly toxic cholinesterase
inhibitor. Symptoms of poisoning include headache, blurred vision,
weakness, nausea, discomfort in the chest, abdominal cramps, vom­
iting, diarrhea, salivation, sweating and pinpoint pupils.
ALWAYS CALL A PHYSICIAN IN CASE OF SUSPECTED POISONING.
ATROPINE BY INJECTION IS ANTIDOTAL
This product is sold only for uses stated on its label. No express
or impiled license is granted to use or sell this pr0du(t under
a~y patent i~ any country except as speci fied: Country:
United States of America.
[PI\ Re~. No. ~H.-1994
EPA Est. 410-
Lb. NetWt. Ky.
Made in U.S.A. by
STAU~FER CHE~ICAL COMPANY
W~stport, CT 06~Gl-08~O
RS-8~0624
ACCEPTED
AUG 7 1985
I .
--- - -- - -- ---
It" w a I I 0 wed, i 111111 e t1 1 j t " I j Y lJ e '<"I (. r a I 9 I " s s "S 0 fWd ~ "r a 11 din u u c e
V01i1i-tin 9 by P I a c i n ~ all 11 ye r .J 11 t 11 <' b a c k 0 t the vic t i III ''0 ton Y II (> •
(;lve fluids untl1 vOlllitus is clear. Do nut induct! VGllll:lny or ~lve
,j n y t h i n 9 by m I) u t ~l t 0 a n u 1) ~ () n ':l C 1 ,) 'I S 0 reo r) v U 1 5 i n ~ per S (J n •
,!,r_ ~~~~rl.-t act, flu <, h VI i t h I J rye d '" 1IHl t s 0 f run 11 i n ~ wa t e rIo r I ~
·'Ilrlutes. '<,'Inove contalllinatt'G clouling and shoes. Get medical
ltt~ntion. Wash clothing bef)fe re-use.
for eye contact, immediately flush "yes witn large 31"ounts of running
water for at least 15 minutes. Hold eyelid, apart to insure rinsing
01 tne entire surface ot the eye and I ids with water. Get medical
J t tent ion immedi ately.
1f inhaled, remove to fresh air. If not ~reathing, clear victil~'s
aTr'Way and start mouth-to-mouth artlticial respiration.
If breathing is difficult, give oxygen, preferably with a physician'S
advice. Get meolcal attention im~lediately'.
INFORMATION FOR MEOICAl PERSO~~EL
;n1tlal measures inclUde remov3i 0; secretlons, nalntenance ot
a ~atent airway, and if necessary, artiflcidl respiration. "hen
cyanosis is relieved, atrJpine by inJec:ion is antldotal and may
be administered ln lar'de therdp"utic doses, repeated as necessary
to the point of tolerance. If symptolns warrant further treat~ent,
2-PAM (Protopam Chloride) has shown util ity as adjunctive ther~py.
~ever use morphine. Continued absorption at the pOlson may occur,
resulting in fatal relapse after initial improve:nent; very close
supervision of the patient is indicated for at least 48 to 72
hours.
Do not transport or store Dyfonate 5-G with food or feed intended
for human or animal consumption.
I N CASE OF SP ILL
ISOLATE the spill.
HOLD this package, other cargo and vechicles involved.
IMM~DIATELY TELEPHONE (24-hour service) for elnergency
assist~nce 8UO-424-9300.
PRECAUTIONAR~ STATEMENTS
HAZARDS TO HUMANS AND OOMESTIC ANIMALS
WARNING
:~ i\Y BE FAT A L I F 5 Ii A L l(J \,,- '), I:m ,\L E [) I) K ;\ B S 0 R S L D T ~ k Li U (; liT H [ SKI:4o
RAPIDLY A~SORl)lD THRU'Jr;'1 ~tr';KI". Oil :lUT r;~T IN THE EYE,), lJ'~
SKIN, OR O~ CLllTHU~:j. AV, \THI~G OF [JUST.
.
Wt' Ir ~'U:):)··~' s\()V~'), snol''.) , ~JrU~t~r:Ll\l(' .:l(jthins; and \jOq<Jitl~, .-tn,"1
hdnl1I1fl'; 'lr applyin,:) .
.oJd:,tl fl~~jlt!S. ,lrms, ano idel: tn()r'<Ju\jnlj '.(j1th soa~ aO(J watt"lr .1tt,'1
nan c1 1 1 rt,~ 1 n d bet 0 r e edt i n ~l 0 r s m 0 kin (_~ . K 0 uti n ely s how P r () r ~ ,: t. n e
d ~ t (l r w'i () r J n J was hal 1 c lot h i n Ij wit fl. J 0 a p d n d hot w a :: ~: r :) .) ~ j r e
r ., IJ S 1 n 9 . Inc a s e 0 f con t act, I iii f' e d i J t t' I y r e I~ 0 vee 0 n tam ina " "':
c lot n 1 n ~ d r, d was h tho r a u y h I y W 1 t h s a a Dan d wa t e r .
00 not transport or store OYFONAlE 5-G wi t~ any food or fe;>o
intended for human or anlmal consui~ptlon.
~ot for use or storage in or around the home.
REENTRY STATEMENT
Do not enter treated areas for 24 hours after appliration unless
apprOi,ri ate protect i ve cl othi ng is worn ••
oecouse c '"taln states may reyuire more restrictive ree1:ry
i n t e r val s 'J r v a rio usc r 0 pst rea tea w 1 t h t his pro d u c t, con S 'J 1 t
your State, ·'oartment of Agrlculture for Turther lnformatlofl.
Do not apply t~is product in such a manner as to di rectly or
through dr i ft e;:pose workers or otner persons. The area be; n'j
treated must De vacated by unprotected persons.
Do not apply or allow to df'ift to areas occupled by beneficial
animals or onto adjoining food, flber or pasture crops. Do
net contaminate food or feed.
Written or oral warnings must be given to workers who are expected
to be in a treated area or in an area about to be treat~d wlth
thlS product. Oral warnings must be given if there is reason to
believe that written warnings cannot be understood by workers.
When oral warnings are given, warnlngs shall be given in a
language customarily understOOd by workers and must indicate
the specitlc perlod of time that treated areas ~ay not be
e n t ere d wit h .) u t pro t e c t i ve c lot h i n 9 . 0 r a 1 war n i n 9 s nlu S tal 5 'J
lnclude approprlate first ald lnstcuctlons in case of aCCldcctal
exposlJre. These instructions are given ln the STATEMENT OF
PRACTICAL TREATMENT at the beginnlng of this laDel.
'.ritten warnings must include the following informatlon, "W:\P~~I~iG.
A r f' oJ t r f! ate d w 1 thO Y" 0 NAT E 10 A 9 ric u I t u r a lin 5 e c t 1 C 1 d P 0 r' ::.] t r 0 f
ap~llcation). 00 not enter treated areas for 2~ hours after
application unless appropriate protective clothing is -..,orn (or
other reentry interval if your state has a more rpstrictive
I n t r> r val for t h 1 S P r f) r1 u c t ) • l t ace 1 den t dIe x J () S IJ r P f) C cur <; ,
f 0 I J 0 w the i () s t rue t i ') r s bpI 0 w ." (W r itt e n w d r n 1 n 'J S '" IJ S t 1 C Iud p
t h.. S T ;\ T E M E .~ T iJ F P R ,\ C TIC ~ L T R l ,\ T M!:. N T 'J I 'I f' edt t, n f' h P', ' n n 1 n rJ tJ f
thiS lahf'l.j
IJYFONAlic ~-(j
ENViKONMEN~Al P~lCAUTIONS
T his p ': S t 1 C 1 ,1" 1 S t '1 xl': to f 1 'i h "n ,j w i I d : 1 f,' . B i r d ') f f' (' din (J 1 n
t r e ,J ted a r" i S :'1" j ':)" ,1 1 I t' (1 • K ('11 () V t' U I' C () v'' r Q ran 'J 1 e 5 1 t s P 1 lIs
o c cur. K u n rl 0 t ~ r U· 1 :. r t~ J t r~ dar e a S iilo y t)·~ h 0 Z a r do U s tot 1 S n 1 ~
neighborin.] ari',";. no not apply directly to water or wetlands.
00 not cuntilHllrldt<: ... ater by cleaning of e'1uipment or disposal ot
waste. For yUljance contact your regional office of the EPA.
Apply this pro(1uct only as specified on the label.
GENERAL PRECAUTiONS
Read all directions before using.
00 not apply to any crop, or in any manner not specified on this
label. Do not rotate wit~ carrots.
SOIL INSECTS CONTROLLED
Cabbage Maggot (Hjle~ya hrassicae)
Garden Sympnylan :Scutlgerella immac~lata)
Northern C'.lrn ?oob,orm (Diabrotica longlcorC'iis)
Onion Maggot (Hylemya antiqua)
Southern Corn Rootworm (Diabrotica undeciHlp~nctata howardl
Western Corn Rootworm (Diabrotica virgifera)
Wireworms:
Corn fJireworm (Melanotus communis)
Pacific Coast fJireworm (Limonium canus)
Southern Potato Wireworm (Conoderus falli)
Sugar Beet Wireworm (Limonius californicus)
Tobacco Wl rewarm (Conoderus vespertinus)
Western Field Wireworm (Limonius infuscatus)
Wheat Wireworm (Agrlotes milncus)
Ctenicera lobaco
OalOP1US pallidu<;
DIRECTIO~S FOR USE AND RECOMMENDATIONS
It is a wiolatlon of ~ederal law to use this product ln a manner
inconsistent wlth its labelin'].
ASPAKAGUS: (Cailt"r01] Unly) For control 01 Garden Sym~hjlans.
apply 60 to ZIlO pOlln'!s per Jcre, broadcdst. Incorporate intI)
the 5011 witt1 stiln'Jard c'Jltivation equipment. 00 not hanpst
for 18 months.
UYFJNATl 'J-G ~ .
COLE CRUPS: (For S~e~ Unly) ~or control at Cabbdge Maggot
jJrTo r t a and a t t h f' t i 111 e 'J t .; t' e ,1 i n y 0 r t ra r. S p I ant i n 9 . " rio r
to seedliny or transplantir.g, apply 4U pounds per acre, bruad-
cast, and ir'corporate int.] the soil Dy ,jiSCln~. llo not use
treated crop> for food or feed purposes.
RADISH: For control of Cabbage Maggot prior to and at time
of seeding or trinsf)lantlng. Prior to <;eediny or transplanting,
apply 40 pounds per acre, broadcast, and inCJr~orate lnto th~
soil by disciny.
FIELD, SWEET AND PUP CORN: For control of ~orthern and Western
Corn Rootworms, apply 15 to 20 pounds per acre in a 6 to 8 inch
band at time of planting over' corn rows 38-40 inches apart.
Incorporate into the Ulp 1/2 to 1 inch of soi; by making appli­
cation ahead of press Wheels, or by use of special covering
devices, or by dragging a short length of chain behind the
press wheels.
For control of illrewor,ns ln corn, a~ply 60 ,J0Unds per acre,
broadcast, prior to planting and incorporate into the soil
by discing.
For control of symp"ylans in corn, apply 40 pounds per acre,
broadcast, prior to ~lanting and incorpor3 t e l~tO the soil
by discir,g.
IRISH POTATOES:
per acre. Apply
discing prior to
For can t r a 1 a f fI ire"" a r 'n S ,
broadcast and incorporate
planting.
apply eo pounds
into the <oil by
BULB ONIONS: For control of Onion Maggot, apply as a furrow
treatment at time of seedlng. Based on a 20" row spacing apply
at a rate of 20 IDS. per acre (20 lbs. per 26,109 ft. of row,
2 lb. per 2,610 ft. of row, 3/4 lb. per 1,000 ft. of row).
May be used on all soi 1 types,
PEANUTS: For control of Rootworms, apply 40 pounds per acre
in an 18 inch band over the peanut rows 36 inches apart. Apply
just prior to peg'.)ing and incorporate lightly into the soil
with cultivation equipment.
SUGAR BEETS: For control of ;,'Heworms, apply 80 pounds per
acre broadcast prior to planting and inc~r~orate into the 5011
by 1iscing.
';,'EET POTATOfS: For control of {lirewor,ns in the southeastern
states, apply 40 p[)un,ls p~r acre broadcast and soi 1 incor~ordte
by discin'] prior to plantlng. For control of Wireworms in
other geographical locdtlons apply 80 pounds per acre broadcast.
TOBACCO: For control .Jf ~irewor;ns as list"d ,lbl)vi>, apply 20
to 40 pounds per acre, broadcast, prior to plantin1, dnd incor­
porat p ieto the 5011 by discin').
') .
~ K U H I f) I i I U ~~ S : Don 0 t L: I) rl t a III 1 nat c wa t t' r, f 0 0 rj 1 0 r i- .~ cd by s tor a ~ e
.~-.
o f' t] 1 '; P (I S J 1. J P (> n d u :~l pin ~~ 1 S prO h 1 bit e tj •
STORAGE: lJ 0 not t r ens·' 0 r tor s tor e w 1 t han y fa 0 (j 0 r f t' P a i n ten d ,? d
tor hunlan or dl110lal c r)nSumpt1on.
around the home.
;~ot tor use or '>tori"J" 1n or
PESTICIDE DISPOSAL: Wastes resultiny from the use ot this product
may be disposed of on site or at an approved waste disposal faci: ity.
C 0 tn A I N E R DIS P 0 SAL: C 01:1 pIe tel y em p t Y b a 9 1 n t I) a ~ p 1 i cat ion e q J i p-
~ent. Then dispose of empty bag in a sanitary landfi 1 1 or Dy
incineration, or if allowed by State and local alJthorities, by
burning. If burned, stay out of smoke.
\OTICE - REAO CAREfULLY
cOrWITIor,s OF SALE: Stauffer (and seller) offer(s) this product
tor sale Subject cO, ~nd buyer and all users are deemed to h",ve
acc~pt"d, the followin'J conditions of sale and warranty wh1Cli
may only De varle~ ~y written agreement of a duly authorized
representative of StaUffer.
'~ARRANTY LIMITATIO:: Stauffer warrants that this product conforms
to the chem1cal des·cription on the label and is reasonably fit
for the purposes referred to in the di rections for use on the
label subject to the inherent risks referred to below. Stauffer
makes no other express warranties: THERE:S NO IMPLIED WARRANTY
OF MERCHANTABILITY and there are no warranties whiCh extend
beyond the description on the label hereof.
INHERENT RISKS: The directions for use of this product are believ('d
to be rellable and Should be followed carefully. However, it 1S
1mposs1ble to eliminate all risks associated with use. Buyer
assumes all risks assoc1ated with use or appl ication of this
produc~ contrary to label instructions or resulting from extra­
ordinary weathLr conditions.
LIM I T A T lOr! [) F L I A B I LIT Y: Inn 0 cas e s h a lIS tau f fer bel 1 ~ b 1 (' tor
spec-1al, 1ndirect or conspqupntial damagps rl?sultiny f~o:n the
use or handi1n,] of thlS product and no cla1m of any kind snail
be yreater 1n amount than the purchase price of the product in
r~Sp~(t of whlCh su(h ddmagp~ ~re claimed.