justin
a97107de46
Image rebuild (skip scrape) / build (push) Failing after 1h37m12s
Dockerfile: self-contained image with corpus + Chroma + BM25 baked in. Drawbar's compose pulls + runs without volume mounts. Built from sources.json (labels schema), PRODUCT_NAME=crop_chem by default, HYBRID_SEARCH=true (always-on for production quality). RERANK_URL + OLLAMA_URL get set at compose time. .gitea/workflows/refresh.yml: monthly cron (1st @ 06:00 UTC) does full scrape → reindex → image push. Scrapes Bayer (~30 min) + EPA PPLS row-crop filtered (~7h). Skips reindex+push if no corpus diff. Tags pushed: :latest, :<sha12>, :corpus-<YYYY.MM.DD>. .gitea/workflows/image-only.yml: on-demand or auto on code-only pushes to main (paths: docs_mcp/, rag/, scrape/, requirements.txt, Dockerfile, sources.json). Reindexes from committed corpus, builds image, pushes. ~10 min vs ~9h full refresh. .gitignore: corpus/ now COMMITTED (4,159 labels, 265 MB of .md + sidecars). Lets image-only.yml rebuild indexes without re-scraping. chroma/ + bm25/ still gitignored (regenerable binary indexes). .dockerignore: drops venv, eval results, PLAN/README/CLAUDE.md, deploy/, .git/ — keeps the image lean. corpus + chroma + bm25 explicitly NOT in dockerignore (those go INTO the image). Co-Authored-By: Claude Opus 4.7 (1M context) <noreply@anthropic.com>
341 lines
18 KiB
Markdown
341 lines
18 KiB
Markdown
# SUTAZINE + SELECTIVE HERBICIDE
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- EPA Reg No: **10182-248**
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- Registrant: SYNGENTA CROP PROTECTION
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- Signal word: Danger
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- Active ingredients: Butylate (56.8%); Atrazine (14.2%)
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- Label accepted: 1993-10-19
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- Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/010182-00248-19931019.pdf
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---
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UDited State. SDviron-eatal Protection Agency
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••• hiDgtOD. D.C. 20.'0
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Wayne R Hillebrecht
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ZBNECA INC
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ZBNECA AG PRODUCTS
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ocr1 9 9B
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NEW MURPHY ROAD & CONCORD PIKE BOX 751
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WI~INGTON DE 19897
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Office of
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Pr_tlon. , .. tiel ... _
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TOlIle s.at_ ..
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Subject: Label Amendment Submission of 06/18/93
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in Compliance with WPS Labeling Requirements
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EPA Reg No. 10182-248
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SUTAZINE + SELECTIVE HERBICIDE
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Dear Registrant:
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The labeling cited above and Submitted in connection
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with registration under the Federal Insecticide. Fungicide.
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and Rodenticide Act. as amended. is accepted subject to the
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comments listed below.
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Based on your certification. the Agency has accepted
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only those changes to your labeling which are necessary to
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comply with PR Notices 93-7 and 93-11. which reflect the WPS
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labeling requirements of 40 CFR part 156. subpart K. Any
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other labeling changes submitted in connection with this
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amendment application and not directly related to compliance
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with PR Notice 93-7 or 93-11 have neither been reviewed nor
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accepted by the Agency. If you wish to make any such
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changes. you must submit a separate amendment application
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proposing them. If your product registration is currently
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suspended. a~ceptance of this labeling amendment does not
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affect the suspension in any way.
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A copy of your proposed labeling stamped "Accepted with
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comments" is attached. Make any required changes described
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in the attached and_send three copies of final l~beling as
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soon as it is available to:
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/) /-c..-
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I~
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1:2....
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oacuaent Proce •• inq Desk (FIB-LABEL)
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Office of "aticide Proqr... (B-7504C)
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u. s. BnVironaental Protection Agency
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401 II street sw
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Washinqton, DC 20460-0001
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Hand or courier deliveries of final labels aay be .ada to:
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nocuaent Processing Desk (FIB-LABEL)
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Roo. 266A Crystal Mall 2
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1921 Jefferson Davis Highway
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Arlinqton, VA 22202
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Please correct the typographical errors circled on the draft
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before printing final labeling.
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In your final labeling the "Agricultural Use Requir .. ents"
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text" .ust be contained in a clearly separate box. This box .ay
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be set apart by a line, by another graphical device, by a
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different color background, or in any other way that clearly
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distinguishes it fro. surrounding text.
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incerely,
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'-.......~.~Q.. oepu.y Chief
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R gistration Support Branch
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R gistration Division (H7505W)
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1 ,
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~n: 10182-248
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Analyet ~ nte: Ond8r Stat..-nt of practical 7rea~nt reference to r..aval and cleaning of
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cont .. inated clothing ehould be deleted.
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RESTRICTED USE PESTICIDE
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PIIg8 1 or 9 ~ ') l.t
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SUTAZlNE+ C'vIIIIiner '1
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SUT248C.RSC - RS-081793C
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Ground end ..... "lit Conoeme
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For retail sale to and use only b>i Certified AppIIcatots. or persons under their dIr8ct
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supervision. and only for those uses covered by the CertIfIed AppIlcato(s certiflc:at..A'I.
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This product is a restricted use herbidde due to ground and surface water conc:ema. Users
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must read and follow all precautionary statements and Instructions for use In order to minimize
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potential for atrazine to reach ground and sulfaca water.
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SUTAZlNE8+
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Selective Herbicide
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A Preplant !ncorporated Herbicide for Control of
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AMual Grass and Broadleaf Weeds in FIeld. aw.)8t, POP. and Silage Com
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AcnVE INGREDIENTS:
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Butyl'lte:
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5-ethyl diisobutylthiocarbamate .....•.......•.........•••..•........... 56.80%
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Atrazine:
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2-chlor0-4-(ethylamino )-6-(isopropylamino)-s-ttiazine • • . . . • • • • . • . • • . • . • • . • . . . . 13.90%
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Related triazines .......•...•.••..•.....•...•.•..••..•...•.......••.. 0.30%
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INERT INGREDIENTS: . . . . . . . . • . . • • . . . . . . . . • • . . • . • • . . . . . • • . . . . . . . •. 29.m
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Total . . . . . . . . . . . . . . . . . . . . . . . . • • . . . . . . . . . . . 100.00%
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Contains 4.8 pounds S-ethyl diisob'Jtylthiocarbamate and 1.2 pounds atrazine active ingredient
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per gallon.
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EPA Reg. No. 10182-248
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EPA Est No. ~Ol82-
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KEEP OUT OF REACH OF CHLDREN
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DANGER
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PEUGRO
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Net Contents:
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SI ustecl no entiende Ia etlqueta. busque a a1gulen para que te IItxp11qUe • usted en deIaIIe· .
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(If you do not understand the label, find SOtrI8OM toexplall:\l.~ ~.~~.)
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Made In U.S.A.
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ZENECA A2 Productl
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ZENECA Inc.
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Wilmington, DE 19897
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Acx:unu
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.... 00 .. 1""
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I .... A 1_ DMe4
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('v1 I. ~
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FIRST :JD
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Page 2 S' ~ J<"
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SUTAZlNE+ ContaMr 1
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SUT248C.RSC· RS-081793C
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STATEMENT OF PRAcnCAL TREATMENT
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H a known exposure occurs or Is tllISpeded, Inmedlalllv ItaJt lie procedlna given below. "
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further treatment Is required, CO!'tact a Polson Control Center, a phyIIcIIn, or lie nearest
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hospital.
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IF SWALLOWED: Invnediately give several g'Mses of water and InclJce vomiting by gagging
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the victim with a finger placed on the back of the victim's tof9Je. GIve fluids until vomitus Is
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clear. "victitn Is unconscious or convulsing, do not Induce vomiting or give anything I7f
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mouth. .
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IF IN EYES: Immediately flush the eyes with plenty of running waler for at least 15 minutes.
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Hold the eyelids apart during flushing to ensure rinsing of the entire surface of the eye and
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lids with water. Can a physician.
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IF ON SKIN: Flush affected areas with plenty cf water for several minutes. Remove and
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clean any contaminated dothing and shoes. Get medical !\ttentior! if skin irritation occurs.
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IF INHALED: Remove to fresh air. Seek medeal attention if respiratory Irritation occurs or
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breathing becomes diffICUlt.
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FOR 24-HOUR EMERGENCY MEDICAL ASSISTANCE, CALL 1-ac;o.F·A-S-T ... ·E·D
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(327-8633).
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FOR CHEMICAL EMERGENCY: Spill, leak, fire, exposure, or .ccldent call CHEMTREC
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1-800-424-9300.
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SUTAZlNE+ c!:! ' i /2-
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SUT248C.~PC • RS-081793C
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PRECAUllONARY STATEMENTS
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HAZARDS TO HUIIANI AND DOIIUTIC AI".ALI
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DANGER
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CORROSIVE. CAUSES IRREVERSIBLE EYE DAMAGE. HARMFUL IF SWALLOWED. Avoid
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contact with skin. eyes. and clothing. Avoid breathing spray mist. Wee. laillaa. MM,
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Ilevee. Mil ,Irate_e alalli"l ','." .... lIli ... 'Ne8h akiR 'MII aa811 Mil WIlIar iRMa"ptpl)'
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aile. 18 .. 1881 Flush eyes with water.
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ge .. et apllly thie llradllet iR slIeA a Ffl8RRe. 88 Ie diraetly e. "fill. IIAft "''Il8e we".fI er
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ether pefleM.
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l:Isef9 are reqtlirell te weer 19R1I81e8\'e ahilts BAli leRIIIIBRte er eql:livaleRl •• aMI_ .981B1Ml
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III9\lea, Mil tl9etS ~te",re9fed~. IR edditiaR, pera9R1!1 IIW9H911 iR .... iRgIIeadi ... 8IIe_9fl8
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8Fe FeqtliFed 19 1189 I'Ie8'('1 dlily .ePRigel reaielBRl 1119'/18 a, .. eallreRe 1119¥8a BRd 8 fa .... ield
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a. 11911g1ea,
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Personal Protective Equipment
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Applicators and other handlers must wear:
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• Long-sleeved shirt and long penis
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• Waterproof gloYes
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.. Chemical-resistant f'tvool!"-w-lear plus sodcs
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• Protective eyewear
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Discard dothing and other absorbent materials that have been drenched or heavily
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contaminated with this product's concentrat9. Do not reuse them. FoI\c)w manufac:turefs
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Instructions for cleaninglmalntainlng PPE. If no such Instructions for washables. use det"lfrtlget-Il
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end hot water. Keep and washPPE separately 'rom other laundry.
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When handlers use closed systems. enclosed e8bs. or aircraft In a manne; 1hat meets ...
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requirements listed In the Worker Protection Standard (WPS) for agriQJlluraJ pestiCIdes (40
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CFR 170.240(d)(4-6}). the hanclerPPE requlren~nts may be reduced Ofmodif\eduu Ipec:Iied In the WPS. ... ..... . ...
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U~S~~R~mm~~
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Users should:
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• Wash hands before eating. drinking. chewing gum. using tobacco or USIng the Id1II.
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• Remove CIoIhIng Immediately If pesticide gets inside. Then wash thOfOugt)Iyand .,.. ,9i'
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clean t:othing.
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t Remove PPE immediately after hlnclinO tNi product.. Wash the outIIcM o(~,,~,t
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fIrnOYIng. As soon as possible. WISh \hO!'OuOhIY and Changllnto .deil\ CIOII~
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ENVIRONMENTAL HAZARDS
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Atrazine leeches read'ily and accepted label rates h.ve been found to resun In contamination
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of water lIupp1le1 by way of groundwater. Theretor.. uselS are adIIlMd to avoid use of
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atrazine In well-dralned 1OiII, partlculal1y In areas having ll~ groundwater tables,
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Plige" 7 ~ I 2-
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SUTAZlNE+ Conbliner "'b
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SUT248C.RSC • RS-081793C
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GroundWater contamination may be recU:ed boJ cIIdng and fIooItng of pennIIn8flt lquld bulk
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atcnge lites with M Impermeable rna1e11al.
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ThIs JI s alk:ide Is Ddc to aquaIIc llweltebtlls I Do noIlPIJIy clrarlly ID ...., or to -
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where surface water II present, or to intertidal .,... below the mMII hIItI water maJtt. Runoff
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and drift from treated areas may be hIzardouIlD aqulJlc organIama In ~ areas. Do
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not contaminate water when dIspoaIng 01 equipment wathWldel's.
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DlAICTIONS FOA USE
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PIgeS
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SUT AZlNE+ Canlllner
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SUT248C.RSC • R8-081793C
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• II I vldllkIn of FedIrII ... to Ull til pIOCU:t In I manner NeW I' Ill."" II 1M ....
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Refef to attached booklet for use clrections.
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GENERAL INFORMAnON
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SUTAZINE®+ seIectivG llerbicide is a selective herbicide which Is mixed Into the soil for
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control of weeds Usted In Table 1 of attached booklet SUTAZlNE+ controls ennual grasses
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and broadleaves as their seeds germinate by interfering with normal germination p.nd seedling
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development It does not control established 'MIeds.
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GENERAL USE PRECAUTIONS
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~ Read an label directions before using.
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• lliis product is intended for preplant or preemergence application only. No
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postemergence use is permitted.
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• Failure to strictly follow label directions may result in exceeding the maximum annual
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atrazine use rates as stipulated by the Environmental Protection Agency.
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• Where sequential postemergence treatments with appropriately registered products
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containing atrazine are necessary, do not exceed a total of 2.5 pounds active ingreclent
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atrazine per acre per calendar year.
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• This product may not be mbced'loaded or used within 50 feet of aI weIIa, including
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abandoned wells, drainage wells, and link holes. this pruduct may not be mixed or
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loaded within 50 feet of intflrmittent streams and Itvers, natural or impounded lakeland
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reservoirs. This product may not be applied aertany or by ground within 66 feet of the
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;K)ints where field surface water runoff entel'l perennial :If Intermittent atreama and rlvel'l
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or within 200 feet around natural or Impounded lakes and reservoirs. "lhil product II
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applied to highly eroclble land, lie 66 foot buffer or 1et-bKk from runoff points must be
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planted to crop or .eeded with grail or other IUItIbIe crop.
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• Do not apply this procb:t through any type of irrIgIIIon l'jltem.
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• The maximum application rat. for com II 2.5 poundIlIruint IdIve ingrtclitl.l per acre
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per CIIendar yell.
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• ThIs product conlIIna Ilrazint and .... may not control .... eII .... .,. knOwn or
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IUIptcttd to be trllZlnt r .. Iliint.
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,.8 a
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SlITAZlNE+ COlltllller I j ,~
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SUT248C.RSC • R8-081793C "1
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• SUTAZlNE+ II ~ for use only on minerai loiii or thole loiii contU*Ig ....
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than 10% orgInic mdIr.
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• SUTAZlNE+ IhouId not be ueed on milo or 8OI'ghum.
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• SUTAZlNE+ IhouId not be used on com lied Itock IUCh u areedell. FoundIIIori, or
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mc:r-.
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• SUTAZlNE+ CM be used on produdIon eeed com.
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• Do not contMllnat. irrigation water used for crops oller '*' com or water used for
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domestic purposes.
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• Do not apply SUTA:!INE+ before prelrrigatlon In 1nigUId ......
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• Do not dow SUTAZI~E+ tt o::ontaminat. feed or food.
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• SUTAZlNE+ should not be stored near seeds. f.rtllz ..... or foodstuffs.
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• AI containers of SL'TAZINE+ should be kept tightly ckJud when not In use.
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• 00 not use In Arizona or 10 southernrno.t counties In c.IifornIa.
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• Applied according to clrections and under normal growing condItIonI, SUTAZlNE+ wi. not
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harm the treated crop. During germination and ear1y stages of growth, extended periods
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of unusually cold and wet or hot and dry weather, Insec:t or pbnt disease attack. canyov.r
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pesticide residues, the use of certain soil applied systemic insecticides, Improperly placed
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fertilizers or soil insecticides may create abnormal c:oncIIIons that wellken crop seedlings.
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SUTAZINE+ used under these abnorm'd concltions could re.ouIt In crop Injury.
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• Make only one application per crop.
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• After treatment with SUTAZINE+, do not plant any crop except com until.,. foIIowio-,g year
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or Injury may occur.
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• 00 not apply SUTAZlNE+ after June 10.
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• Folowing com harvest, thoroughly Invert soil by deep discing or plowing In !he , .. or .arly
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spring to minimize Injury potential to rotational spring seeded crops.
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• Com or soybeans may be planted the spring season folowlng "".tme .. l
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• Small gl'lllnl may be planted 15 months following trutment.
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• AI Other atrazlne sensitive crops may be planted 1 a ",ouU .. after epJIIc:allQII.
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• ~ury may occur to soybeans II. year foIowIng com when planted In north CI"I'" Ind
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northwest 1owa,1OUth cenlral.nd IOUtIwnt MInn •• a4a. northem Nebruka and ~
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South Dakota on tolls having ... reoua lUlface '-ytr.
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P-oe 7 /-jl.t
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SUTAZlNE+ Container
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SUT248C.RSC • RS-081793C
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• Where there .nt llatellocal requlrementa regardng atruIne UI8 (Including lower mulmum
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rat .. and/or higher set-backs) which .nt clfferent from the label, the mont
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NIIrIdhI...".,.... ~'IiIIIPPIY.
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Pilge 8 It "\ 1.2..
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SUTAlINE+ ContaIner 1
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SUT248C.RSC • R8-081793C
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STORAGE AND DISPOSAL
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pROlftlTlONl: Do nat CUI ...... d I ..... food. or ..., ." ItorIIDI or dIpa II' Open
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dumping Is prohibited. 00 not ,.,.. empty COI'ItU1er.
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STORAGE: Keep container tightly cIoIed when noIln &lie. Do not ItOM rlelr •• da. feltilzera,
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or food stuffs. Can be stonId at temperatures as low .. mhJs 3O·F.
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PESTICIDE DISPOSAL: Rinse spray eqWpmenI. Pesticide ...... arellCUtely hazardous.
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Improper clspouJ of excess pestic:Ide, apray mbdure, or rtnsate Is a violation of Federallaw.
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If these wastes cannot be disposed of by use according to label instructions, contad your
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State Pesticide or Environmental Control "ct, or the HazardouS Waste Representallve at
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the nearest EPA Regional Office for guidance.
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CONTAINER DISPOSAL:
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Metal: Triple rinse (or equivalent): then offer for recycling or reconcitioning, or puncture and
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dispose of In a sanitary landfill, or by other procedures approved by State and local
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authorities.
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PI •• tlc: Triple rinse (or equivalent): then offer for recycling or reconditioning, or puncture and
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dispose of in a sanitary 1andf1U, or by incineration, or, if allowed by State and local aulhOi ities,
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by buming. If burned, stay out of smoke.
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FOR BULK AND MINI-BULK CONTAINERS
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CONTAINER DISPOSAL: Reseal container and offer for reconcltionlng, or triple rinse (or
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equivalent) and offer for fectding or recontltioning, or dean in accordance with
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manufacturer's instructions.
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CONTAINER PRECAUTIONS
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Before refining, inspect thoroughly for damage such as cracks, punctures, bulges, dents,
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abrasions, and damaged or wom threads on closure devices.
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REFILL ONLY WITH SUT AZlNE+ selective herbicide. The contents of this container cannot
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be completely removed by cleaning. Refilling with materials other than SUT AZINE+ win resuh
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in contamination and may weaken container.
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After filling and before transporting, check for leaks.
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00 not refiU or transport damaged or leaking container.
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Circulation before dispensing Is required.
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CONTAINER IS NOT SAFE FOR FOOD, FEED, OR DRINKING WATER!
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• Page 9 J.2. .., J:t
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SUTAZlNE+ Container -p
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SUT248C.RSC - RS-061793C
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"PORTANT: R .. d the entire DlAICtions for Use 8fId the CondIIIonI 01 &lie and Warranty
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before using this product.
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CONDITIONS OF SALE AND LMTED WAMIANTY:
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The DIredions fOI Use 01 this product are bellewecl to be raIabIe Iftd IhouId be fob .. d
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carefully. However, It Is Impoesible to elmlnate .. riIkIlnherenlly "Iac:latecl wIIh the use of
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this product. Crop Injury, lneffec:tlvenesl or other unintended c:cnsequences may result
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because of such fadora as timing and method of application, weather II'Id crop concItIons,
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mixture with other chemicals not specIfIcaJIy recommended or other IntIuencIng facten In the
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use of the product, .. 01 which are beyond the control of the....... " such risks IhaII be
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assumed by Buyer and User, and Buyer and User agree to hold SeIer harmless for II'IY
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claims relating to such fadora.
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Seller warrants that this product conforms h> the chemical description on the label and Is
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reasonably fit for the purposes stated on the label, subject to the Inherent risks referred to
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above, when used in accordance with directions under normal cor.ditions of use. ThIs
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Yt1lrranty does not extend to the use of thls product contrary to IIIbeIlnstructions, or under
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abnormal conditions or under conditions not reasonably foreseeable to or beyond the control
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of Seller and Buyer and User assume the risk of any such use. SELLER DISCLAIMS ALL
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OTHER WARRANTIES EXPRESSED OR IMPLIED INCLUDING ANY WARRANTY OF
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FITNESS OR MERCHANTABILITY.
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When Buyer or User claims losses or damages resulting from the use or handling of this
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product (including claims based on contrad, negligence, strict IiabIlty or other legal theories),
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Buyer or USAr must prompUy notify in writing Seller of any claims to be eligible to receive
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either of the remedies set forth below. The EXCLUSIVE REMEDY OF BUYER OR USER and
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the LIMIT OF LIABILITY of Sener will be, at the election of Seller, refund of the purchase price
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paid for product bought, or replacement 01 amount of product used. SELLER SHALL NOT BE
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LIABLE FOR CONSEQUENTIAL, SPECIAL OR INDIRECT DAMAGES RESULTING FROM
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THE USE OR H.ANDLING OF THIS PRODUCT AND SELLER'S SOLE LIABILITY AND
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BUYER'S AND USER'S EXCLUSIVE REMEDY SHALL BE LIMITED TO THE REFUND OF
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THE PURCHASE PRICE.
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This product is sold only for uses stated on Its label. No express or .. -l'Iplied license is granted
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to use or sell this product under any patent In any country except as specified: Country:
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United States of America. Patent No. 4,021,224; 4,137,070.
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SUTAZINEGk is a tradernar1l of a ZENECA Group Company.
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