a97107de46
Image rebuild (skip scrape) / build (push) Failing after 1h37m12s
Dockerfile: self-contained image with corpus + Chroma + BM25 baked in. Drawbar's compose pulls + runs without volume mounts. Built from sources.json (labels schema), PRODUCT_NAME=crop_chem by default, HYBRID_SEARCH=true (always-on for production quality). RERANK_URL + OLLAMA_URL get set at compose time. .gitea/workflows/refresh.yml: monthly cron (1st @ 06:00 UTC) does full scrape → reindex → image push. Scrapes Bayer (~30 min) + EPA PPLS row-crop filtered (~7h). Skips reindex+push if no corpus diff. Tags pushed: :latest, :<sha12>, :corpus-<YYYY.MM.DD>. .gitea/workflows/image-only.yml: on-demand or auto on code-only pushes to main (paths: docs_mcp/, rag/, scrape/, requirements.txt, Dockerfile, sources.json). Reindexes from committed corpus, builds image, pushes. ~10 min vs ~9h full refresh. .gitignore: corpus/ now COMMITTED (4,159 labels, 265 MB of .md + sidecars). Lets image-only.yml rebuild indexes without re-scraping. chroma/ + bm25/ still gitignored (regenerable binary indexes). .dockerignore: drops venv, eval results, PLAN/README/CLAUDE.md, deploy/, .git/ — keeps the image lean. corpus + chroma + bm25 explicitly NOT in dockerignore (those go INTO the image). Co-Authored-By: Claude Opus 4.7 (1M context) <noreply@anthropic.com>
741 lines
44 KiB
Markdown
741 lines
44 KiB
Markdown
# CARNIVORE HERBICIDE
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- EPA Reg No: **1381-249**
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- Registrant: WINFIELD SOLUTIONS, LLC
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- Signal word: Caution
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- Active ingredients: MCPA, 2-ethylhexyl ester (27.3%); Bromoxynil octanoate (25.48%); Fluroxypyr 1-methylheptyl ester (10.08%)
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- Label accepted: 2022-12-19
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- Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/001381-00249-20221219.pdf
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---
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UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
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WASHINGTON, DC 20460
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OFFICE OF CHEMICAL SAFETY
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AND POLLUTION PREVENTION
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December 19, 2022
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Diana Williams
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Registration Specialist
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Winfield Solutions, LLC
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P.O. Box 64589
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St. Paul, MN 55164-0589
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Subject: Registration Review Label Amendments Incorporating Mitigation Measures from
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the Interim Decisions for Bromoxynil, Fluroxypyr, and MCPA and the National
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Marine Fisheries Services’ (NMFS) Biological Opinion on the Effects of
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Bromoxynil on Pacific Salmonids
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Product Name: CARNIVORE HERBICIDE
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EPA Registration Number: 1381-249
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Application Dates: 9/8/21, 9/17/2021, and 2/21/2022
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Decision Numbers: 578344, 578555, 582192, and 589178
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Dear Diana Williams:
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The Agency, in accordance with the Federal Insecticide, Fungicide and Rodenticide Act
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(FIFRA), as amended, has completed reviewing all the information submitted with your
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application to support the Registration Review of the above referenced product in connection
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with the Bromoxynil, Fluroxypyr, and MCPA Interim Decisions. The Agency has concluded that
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your submission is acceptable.
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This letter also addresses the label mitigation resulting from the NMFS’ Biological Opinion on
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the effects of Bromoxynil on Pacific salmonids. The Agency has concluded that your submission
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is also acceptable. The label referred to above, submitted in connection with registration under
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FIFRA, as amended, is acceptable.
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Should you wish to add/retain a reference to the company’s website on your label, then please be
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aware that the website becomes labeling under the Federal Insecticide Fungicide and Rodenticide
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Act and is subject to review by the Agency. If the website is false or misleading, the product
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would be misbranded and unlawful to sell or distribute under FIFRA section 12(a)(1)(E). 40
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CFR 156.10(a)(5) list examples of statements EPA may consider false or misleading. In addition,
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regardless of whether a website is referenced on your product’s label, claims made on the
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website may not substantially differ from those claims approved through the registration process.
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Therefore, should the Agency find or if it is brought to our attention that a website contains false
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or misleading statements or claims substantially differing from the EPA approved registration,
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the website will be referred to the EPA’s Office of Enforcement and Compliance.
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Page 2 of 2
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EPA Reg. No. 1381-249
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Decision No. 578344, 578555, 582192, and 589178
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A stamped copy of your labeling is enclosed for your records. This labeling supersedes
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all previously accepted labeling. You must submit one copy of the final printed labeling
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before you release the product for shipment with the new labeling. In accordance with 40
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CFR 152.130(c), you may distribute or sell this product under the previously approved
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labeling for 12 months from the date of this letter. After 12 months, you may only
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distribute or sell this product if it bears this new revised labeling or subsequently
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approved labeling. “To distribute or sell” is defined under FIFRA section 2(gg) and its
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implementing regulation at 40 CFR 152.3.
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If you have any questions about this letter, please contact Quinn Gavin at gavin.quinn@epa.gov.
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Sincerely,
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Linda Arrington, Branch Chief
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Risk Management and Implementation Branch 4
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Pesticide Re-Evaluation Division
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Office of Pesticide Programs
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Enclosure
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MCPA, FLUROXYPYR GROUP 4 HERBICIDE
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BROMOXYNIL GROUP 6 HERBICIDE
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Carnivore ® Herbicide
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For selective postemergence control of perennial and annual broadleaf weeds and volunteer potatoes
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in wheat, barley, or oats not under-seeded with a legume, Conservation Reserve Program (CRP) and
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Fallowland
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ACTIVE INGREDIENTS:
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MCPA-EHE: 2-methyl-4-chlorophenoxyacetic acid, 2-ethylhexyl ester* …………………………… 27.30%
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Octanoic acid ester of bromoxynil (3,5-dibromo-4-hydroxybenzonitrile)** ………………………… 25.48%
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Fluroxypyr 1-methylheptyl ester ((4-amino-3,5-dichloro-6-fluoro-2-pyridinyl)oxy)
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Acetic acid, 1-methylheptyl ester *** …………………………………………………………………… 10.08%
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OTHER INGREDIENTS: …………………………………………………………………………………. 37.14%
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TOTAL ………………… ……………………………………………………………………………………… 100.00%
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Contains petroleum distillates
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Equivalent to:
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* MCPA acid …………………………………………… 17.5%, 1.67 Ib/gal
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**Bromoxynil …………………………………………… 17.5%, 1.67 lb/gal
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***Fluroxypyr acid ……………………………………… 7.0%, 0.67 Ib/gal
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KEEP OUT OF REACH OF CHILDREN
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CAUTION
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FIRST AID
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If swallowed x Immediately call a poison control center or doctor.
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x Do not induce vomiting unless told to by a poison control center or doctor.
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x Do not give any liquid to the person.
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x Do not give anything by mouth to an unconscious person.
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If on skin or
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clothing
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x Take off contaminated clothing.
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x Rinse skin immediately with plenty of water for 15 to 20 minutes.
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x Call a poison control center or doctor for treatment advice.
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If in eyes x Hold eye open and rinse slowly and gently with water for 15 to 20 minutes.
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x Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye.
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x Call a poison control center or doctor for treatment advice.
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HOT LINE NUMBER: Have the product container or label with you when calling a poison control center or
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doctor, or going for treatment. In case of health emergency, call toll-free 1-877-424-7452.
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NOTE TO PHYSICIAN: Contains petroleum distillate. Vomiting may cause aspiration pneumonia.
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See booklet for additional PRECAUTIONARY STATEMENTS, COMPLETE DIRECTIONS FOR USE,
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WARRANTY DISCLAIMER AND LIMITATION OF WARRANTY.
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EPA Reg. No. 1381-249 EPA Est. No. ______
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Distributed By NET CONTENTS____GALS.
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Winfield Solutions, LLC
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P.O. Box 64589, St. Paul, MN 55164-0589
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2/1014/2
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Dec 19, 2022
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1381-249
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2
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PRECAUTIONARY STATEMENTS
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HAZARDS TO HUMANS AND DOMESTIC ANIMALS
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CAUTION: Harmful if swallowed. Causes moderate eye irritation. Avoid contact with eyes, skin or clothing. Wash
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thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco or using the toilet.
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PERSONAL PROTECTIVE EQUIPMENT (PPE):
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Some materials that are chemical-resistant to this product are listed below.
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Mixers, loaders, applicators, flaggers, and other handlers must wear:
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x Long-sleeved shirt and long pants
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x Chemical-resistant gloves made of barrier laminate, butyl rubber (> 14 mils), nitrile rubber (> 14 mils), or viton (> 14
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mils) for cleaning equipment and mixing/loading
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x Chemical-resistant apron for cleaning equipment and mixing/loading
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x Shoes plus socks
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x Protective eyewear
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Discard clothing and other absorbent materials that have been drenched or heavily contaminated with this product’s
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concentrate. Do not reuse them. Follow manufacturer’s instructions for cleaning/maintaining PPE. If no such instructions
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for washables exist, use detergent and hot water. Keep and wash PPE separately from other laundry.
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To reduce exposure to residues, wash the spray rig, tractor, and all other equipment used to handle or apply this product
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with water daily or before using the equipment for any other purpose.
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ENGINEERING CONTROLS: When handlers use closed systems, enclosed cabs, or aircraft in a manner that meets the
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requirements listed in the Worker Protection Standard (WPS) for agricultural pesticides [40 CFR 170.240 (d) (4-6)], the
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handler PPE may be reduced or modified as specified in the WPS.
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Handlers must use closed mixing loading systems during mixing/loading liquids for aerial applications to fallowland and to
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high-acreage field crops including barley, oats and wheat.
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USER SAFETY RECOMMENDATIONS
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Users should:
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• Wash hands before eating, drinking, chewing gum, using tobacco or using the toilet.
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• Remove clothing/PPE immediately if pesticide gets inside. Then wash thoroughly and put on clean clothing. If pesticide
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gets on skin, wash immediately with soap and water.
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• Remove PPE immediately after handling this product. Wash the outside of gloves before removing. As soon as possible,
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wash thoroughly and change into clean clothing.
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ENVIRONMENTAL HAZARDS
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This pesticide is toxic to fish, aquatic invertebrates and aquatic plants. Do not apply directly to water, or to areas where
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surface water is present or to intertidal areas below the mean high water mark. Do not contaminate water when cleaning
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equipment or disposing of equipment washwater or rinsate. Drift and runoff may be hazardous to aquatic organisms in
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water adjacent to treated areas. Runoff of this product will be reduced by avoiding applications when rainfall is forecast to
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occur within 48 hours.
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GROUND WATER ADVISORY
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This product is known to leach through soil into groundwater under certain conditions as a result of label use. This product
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may leach into groundwater if used in areas where soils are permeable, particularly where the water table is shallow.”
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SURFACE WATER ADVISORY
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This product may impact surface water quality due to runoff of rainwater. This is especially true for poorly draining soils
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and soils with shallow ground water.
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This product is classified as having high potential for reaching surface water via runoff for several months or more after
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application.
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A level, well-maintained vegetative buffer strip between areas to which this product is applied and surface water features
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such as ponds, streams, and springs will reduce the potential loading of MCPA from runoff water and sediment. Runoff of
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this product will be reduced by avoiding applications when rainfall or irrigation is expected to occur within 48 hours.
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3
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NON-TARGET ORGANISM ADVISORY
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This product is toxic to plants and may adversely impact the forage and habitat of non-target organisms, including
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pollinators, in areas adjacent to the treated site. Protect the forage and habitat of non-target organisms by following label
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directions intended to minimize spray drift.
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Reporting Ecological Incidents
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To report ecological incidents, including mortality, injury, or harm to plants and animals, call 1-855-494-6343.
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PHYSICAL AND CHEMICAL HAZARDS
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Do not mix or allow coming in contact with oxidizing agents. Hazardous chemical reaction may occur.
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DIRECTIONS FOR USE
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It is a violation of Federal law to use this product in a manner inconsistent with its labeling.
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Do not apply this product in a way that will contact workers or other persons, either directly or through drift. Only protected
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handlers may be in the area during application. For any requirement specific to your State or Tribe, consult the agency
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responsible for pesticide regulation.
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Endangered Species Protection Requirements
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It is a Federal offense to use any pesticide in a manner that results in an unauthorized “take” (e.g., kill or otherwise harm)
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of an endangered species and certain threatened species, under the Endangered Species Act section 9. When using this
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product, you must follow the measures contained in the Endangered Species Protection Bulletin for the area in which you
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are applying the product. You must obtain a Bulletin no earlier than six months before using this product. To obtain
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Bulletins, consult http://www.epa.gov/espp/, call 1-844-447-3813, or email ESPP@epa.gov. You must use the Bulletin
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valid for the month in which you will apply the product.
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AGRICULTURAL USE REQUIREMENTS
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Use this product only in accordance with its labeling and with the Worker Protection Standard, 40 CFR Part 170. This
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standard contains requirements for the protection of agricultural workers on farms, forests, nurseries, and greenhouses,
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and handlers of agricultural pesticides. It contains requirements for training, decontamination, notification, and emergency
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assistance. It also contains specific instructions and exceptions pertaining to the statements on this label about personal
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protective equipment (PPE) and restricted-entry intervals. The requirements in this box only apply to uses of this product
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that are covered by the Worker Protection Standard.
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Do not enter or allow worker entry into treated areas during the restricted-entry interval (REI) of 24 hours, with the
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exception of grass. For grass, do not enter or allow worker entry into treated areas during the restricted-entry interval
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(REI) of 2 days.
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PPE required for early entry to treated areas that is permitted under the Worker Protection Standard and that involves
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contact with anything that has been treated, such as plants, soil, or water, is coveralls, chemical-resistant gloves
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made of barrier laminate, butyl rubber (> 14 mils), nitrile rubber (> 14 mils), or viton (> 14 mils), shoes plus socks, and
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protective eyewear.
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NON-AGRICULTURAL USE REQUIREMENTS
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The requirements in this box apply to uses of this product that are NOT within the scope of the Worker Protection
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Standard for agricultural pesticides (40 CFR part 170). The WPS applies when this product is used to produce
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agricultural plants on farms, forests, nurseries, or greenhouses. When applied to on-farm non-cropland, keep unprotected
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persons out of treated areas until sprays have dried.
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PRODUCT INFORMATION
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This product provides selective postemergence control of perennial and annual broadleaf weeds and volunteer potatoes
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in wheat, barley, or oats not under-seeded with a legume, Conservation Reserve Program (CRP) and Fallowland.
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4
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WEED RESISTANCE MANAGEMENT
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Carnivore Herbicide contains both Group 4 herbicides (MCPA and Fluroxypyr) and a Group 6 herbicide (Bromoxynil). Any
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weed population may contain plants naturally resistant to Group 4 and/or Group 6 herbicides. The resistant biotypes may
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dominate the weed population if these herbicides are used repeatedly in the same field. Appropriate resistance-
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management strategies should be followed.
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To delay herbicide resistance, take one or more of the following steps:
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x Rotate the use of this product or other Group 4 and Group 6 herbicides, within a growing season sequence or
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among growing seasons, with different herbicide groups that control the same weeds in a field.
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x Use tank mixtures with herbicides from a different group if such use is permitted; where information on resistance in
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target weed species is available use the less resistance-prone partner at a rate that will control the target weed(s)
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equally as well as the more resistance-prone partner. Consult your local extension service or certified crop advisor if
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you are unsure as to which active ingredient is currently less prone to resistance.
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x Adopt an integrated weed-management program for herbicide use that includes scouting and uses historical
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information related to herbicide use and crop rotation, and that considers tillage (or other mechanical control
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methods), cultural (e.g., higher crop seeding rates; precision fertilizer application method and timing to favor the
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crop and not the weeds), biological (weed-competitive crops or varieties) and other management practices.
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x Scout fields prior to application to identify the weed species present and their growth stage to determine if the
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intended application will be effective.
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x Scout fields after herbicide application to monitor weed populations for early signs of resistance development.
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Indicators of possible herbicide resistance include:
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o Failure to control a weed species normally controlled by the herbicide at the dose applied, especially if
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control is achieved on adjacent weeds.
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o A spreading patch of non-controlled plants of a particular weed species.
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o Surviving plants mixed with controlled individuals of the same species.
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If resistance is suspected, prevent weed seed production in the affected area by an alternative herbicide from a
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different group or by a mechanical method such as hoeing or tillage. Prevent movement of resistant weed seeds to
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other fields by cleaning harvesting and tillage equipment when moving between fields, and planting clean seed.
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x If a weed pest population continues to progress after treatment with this product, discontinue use of this product,
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and switch to another management strategy or herbicide with a different mode of action, if available.
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x Contact your local extension specialist, certified crop advisors, and/or Winfield Solutions, LLC representative for
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pesticide resistance management and/or integrated weed management recommendations for specific crops and
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resistant weed biotypes.
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x For further information or to report suspected resistance, contact your Winfield Solutions, LLC representative .
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USE PRECAUTIONS
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x Do not allow spray drift to come in contact with or apply this product directly to susceptible broadleaf plants or
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broadleaf crops, including but not limited to the following: alfalfa, canola, cotton, edible beans, grapes, lentils, lettuce,
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mustard, peas, potatoes, radishes, soybeans, sugar beets, sunflowers, tobacco or tomatoes.
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USE RESTRICTIONS
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x Do not apply more than 2.4 pints of this product per acre per year.
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x Handlers must use closed mixing loading systems during mixing/loading liquids for aerial applications to fallowland
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and to high-acreage field crops including barley, oats and wheat.
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x When applying this product, do not contaminate water used for domestic purposes or irrigation ditches.
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x Do not apply this product through any type of irritation system (i.e., chemigation).
|
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x Unless otherwise noted, if replanting is required, within 120 days after application, plant only crops listed on this label
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or federally approved supplemental labeling.
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x Aerial application to fallowland is prohibited within 25 feet of residential areas (e.g., homes, schools, playgrounds,
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shopping areas, hospitals, etc.).
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x Holding time restriction : This product is persistent and may be present in plant materials for over 30 days after
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application. Do not use treated plant material or manure from animals that have grazed or consumed forage from
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treated areas for compost, mulch, or mushroom spawn until 30 days after application.
|
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x Livestock cleanout period : Animals that have been fed fluroxypyr treated forage must be fed forage free of
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fluroxypyr for at least 3 days before they are moved off the treated property.
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5
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MANDATORY SPRAY DRIFT MANAGEMENT
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Ground Boom Applications
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x User must only apply with the release height recommended by the manufacturer, but no more than 4 feet above the
|
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ground or crop canopy.
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x Applicators are required to select the nozzle and pressure that deliver a medium or coarser droplet size (ASABE
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S572).
|
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x Do not apply when wind speeds exceed 10 miles per hour at the application site.
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x Do not apply during temperature inversions.
|
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|
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x Do not release spray at a height greater than 10 ft above the ground or vegetative canopy, unless a greater
|
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application height is necessary for pilot safety.
|
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x Applicators must use ½ swath displacement upwind at the downwind edge of the field.
|
||
x Do not apply when wind speeds exceed 10 miles per hour at the application site.
|
||
x Applicators are required to select the nozzle and pressure that deliver a medium or coarser droplet size (ASABE S572
|
||
and S641) for all applications.
|
||
x The distance of the outer most nozzles on the boom must not exceed 75% of the length of the wingspan
|
||
or 90% of the rotor diameter
|
||
x Do not apply during temperature inversions.
|
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|
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Boomless Ground Applications
|
||
• Applicators are required to select the nozzle and pressure that deliver a medium or coarser droplet size (ASABE
|
||
S572) for all applications.
|
||
• Do not apply when wind speeds exceed 10 miles per hour at the application site.
|
||
• Do not apply during temperature inversions.
|
||
|
||
SPRAY DRIFT ADVISORIES
|
||
THE APPLICATOR IS RESPONSIBLE FO R AVOIDING OFF-SITE SPRAY DRIFT. BE AWARE OF NEARBY NON-
|
||
TARGET SITES AND ENVIRONMENTAL CONDITIONS.
|
||
|
||
Importance of Droplet Size
|
||
An effective way to reduce spray drift is to apply large droplets. Use the largest droplets that provide target pest control.
|
||
While applying larger droplets will reduce spray drift, the potential for drift will be greater if applications are made
|
||
improperly or under unfavorable environmental conditions.
|
||
|
||
Controlling Droplet Size – Ground Boom
|
||
x Volume - Increasing the spray volume so that larger droplets are produced will reduce spray drift. Use the
|
||
highest practical spray volume for the application. If a greater spray volume is needed, consider using a
|
||
nozzle with a higher flow rate.
|
||
x Pressure - Use the lowest spray pressure recommended for the nozzle to produce the target spray volume
|
||
and droplet size.
|
||
x Spray Nozzle - Use a spray nozzle that is designed for the intended application. Consider using nozzles
|
||
designed to reduce drift.
|
||
|
||
Controlling Droplet Size – Aircraft
|
||
x Adjust Nozzles - Follow nozzle manufacturers’ recommendations for setting up nozzles. Generally, to reduce
|
||
fine droplets, nozzles should be oriented parallel with the airflow in flight.
|
||
|
||
Boom Height – Ground Boom
|
||
For ground equipment, the boom should remain level with the crop and have minimal bounce.
|
||
|
||
Release Height - Aircraft
|
||
Higher release heights increase the potential for spray drift.
|
||
|
||
Shielded Sprayers
|
||
Shielding the boom or individual nozzles can reduce spray drift. Consider using shielded sprayers. Verify that the shields
|
||
are not interfering with the uniform deposition of the spray on the target area.
|
||
|
||
Boomless Ground Applications
|
||
Setting nozzles at the lowest effective height will help to reduce the potential for spray drift .
|
||
|
||
6
|
||
Handheld Technology Applications
|
||
Take precautions to minimize spray drift.
|
||
|
||
Temperature and Humidity
|
||
When making applications in hot and dry conditions, use larger droplets to reduce effects of evaporation.
|
||
|
||
Temperature Inversions
|
||
Drift potential is high during a temperature inversion. Temperature inversions are characterized by increasing temperature
|
||
with altitude and are common on nights with limited cloud cover and light to no wind. The presence of an inversion can be
|
||
indicated by ground fog or by the movement of smoke from a ground source or an aircraft smoke generator. Smoke that
|
||
layers and moves laterally in a concentrated cloud (under low wind conditions) indicates an inversion, while smoke that
|
||
moves upward and rapidly dissipates indicates good vertical air mixing.
|
||
|
||
Wind
|
||
Drift potential generally increases with wind speed. AVOID APPLICATIONS DURING GUSTY WIND CONDITIONS.
|
||
Applicators need to be familiar with local wind patterns and terrain that could affect spray drift.
|
||
|
||
LOADING AND HANDLING INSTRUCTIONS
|
||
2.5 Gallon Containers
|
||
Take special care when mixing and loading this product. Place hands on the container in such a way as to avoid possible
|
||
drip or splash.
|
||
30 Gallon and Bulk Containers
|
||
If you will handle a total of 60 gallons or more of this product per day, you must use a mechanical transfer system for all
|
||
mixing and loading operations. If this product is packed in a 30 gallon drum, you must use a mechanical transfer system
|
||
which terminates in a drop-free hard coupling which may be used only with a spray or mix tank which has been fitted with
|
||
a compatible coupling. If you do not presently own or have access to a mechanical transfer system with this type of
|
||
coupling, contact your dealer for information on how to obtain such a system or to modify your present system. When
|
||
using a mechanical transfer system, do not remove or disconnect the pump or probe from the container until the container
|
||
has been emptied and rinsed. The pump or probe system must be used to rinse the empty container and to transfer the
|
||
rinsate directly to the mixing or spray tank.
|
||
|
||
MIXING INSTRUCTIONS
|
||
This product may be applied in tank mixtures with additive products such as surfactants, adjuvants and drift control
|
||
agents, and with most commonly used grass herbicides, at specified rates, as long as tank mixing is not prohibited by the
|
||
label(s) of the tank mix partner and the tank mix partner products are labeled for the timing and method of application for
|
||
the use site to be treated. Observe all restrictions and precautions that appear on the labels of those products. If
|
||
compatibility with another product is not known, perform a small-scale (jar) test to determine compatibility (see instructions
|
||
below). When an adjuvant is to be used with this product, Winfield Solutions, LLC recommends the use of a Chemical
|
||
Producers and Distributors Association certified adjuvant.
|
||
|
||
Note: When adding ingredients to the mixture, allow time for each ingredient to be thoroughly mixed before adding the
|
||
next. Be sure to agitate spray mixture before use if allowed to stand after mixing.
|
||
|
||
1. Fill spray tank with water equal to 1/2 to 3/4 of the required spray volume and start agitation.
|
||
2. Add the recommended amount of this product.
|
||
3. Add any grass herbicides, surfactants, adjuvants or drift control agents according to the respective manufacturer's
|
||
instructions.
|
||
4. Agitate during final filling of the spray tank with water and maintain sufficient agitation during application to ensure
|
||
uniformity of the spray mixture.
|
||
|
||
Tank Mix Compatibility (Jar) Test
|
||
1) Mix the desired tank mix ingredients in their relative proportions in a clear glass quart jar with lid.
|
||
2) Invert the jar containing the mixture several times and observe the mixture for approximately 1/2 hour.
|
||
3) If the mixture balls-up, forms flakes, sludges, gels, oily films or layers, or other precipitates, it is not
|
||
|
||
compatible and the tank mix combinations should not be used.
|
||
|
||
7
|
||
APPLICATION INFORMATION
|
||
Broadleaf Weeds Controlled or Suppressed
|
||
Bedstraw (cleavers)
|
||
Bindweed, field†
|
||
Bindweed , hedge
|
||
Buckwheat, spp.
|
||
Canola, volunteer
|
||
Chamomile, corn
|
||
Chickweed
|
||
Clover, white
|
||
Cocklebur
|
||
Cockle, cow
|
||
Coffeeweed
|
||
Devilsclaw
|
||
†
|
||
Fiddleneck
|
||
Flax, volunteer
|
||
Fumitory
|
||
Grape spp.
|
||
Gromwell, corn
|
||
Groundsel
|
||
Hemp dogbane
|
||
Henbit
|
||
Horsetail, field
|
||
†
|
||
Horseweed (marestail)
|
||
Jimsonweed
|
||
Knawel
|
||
Knotweed
|
||
Kochia
|
||
1
|
||
Ladysthumb
|
||
Lambsquarters
|
||
Mallow, common†
|
||
Mallow, venice
|
||
Marshelder
|
||
|
||
Mayweed
|
||
Morning glory
|
||
Mustard spp. †
|
||
Nightshade spp.
|
||
Pennycress, field
|
||
†
|
||
Pepperweed
|
||
Pigweed spp.
|
||
|
||
Poppy, horned
|
||
Potato, volunteer†
|
||
Prickly lettuce
|
||
Puncturevine
|
||
Purslane, common
|
||
Radish, wild
|
||
Ragweed, common
|
||
Rocket spp.
|
||
Sage, lanceleaf
|
||
Sesbania, hemp
|
||
Shepherd’s purse
|
||
Smartweed spp.
|
||
Sowthistle, annual
|
||
Sunflower
|
||
Tarweed
|
||
Thistle, Russian
|
||
Velvetleaf
|
||
Waterhemp, tall
|
||
|
||
†Indicates Suppression Only - Suppression is a reduction in weed competition (reduction is population or vigor) as
|
||
compared to untreated areas. The degree of weed control and duration of effect may vary with weed size, density,
|
||
application rate, coverage, and growing conditions before, during and after treatment.
|
||
|
||
1) Includes biotypes that are herbicide-resistant or tolerant.
|
||
|
||
Weeds germinating after spraying will not be controlled.
|
||
|
||
Management of Kochia Biotypes
|
||
Research indicates many biotypes of kochia may occur within a single field and while kochia biotypes can vary in their
|
||
susceptibility to this product, in general all biotypes will be suppressed or controlled at the labeled rate of 1 to 1-1/2 pint s
|
||
per acre. A shift to more tolerant biotypes within a field may occur if this product is applied at rates lower than
|
||
recommended.
|
||
|
||
Best Practices for Resistance Management
|
||
Extensive populations of dicamba-tolerant kochia have been identified in certain small grain and corn production
|
||
regions (such as Chouteau, Fergus, Liberty, Toole, and Treasure counties in the state of Montana). For optimal
|
||
control of dicamba-tolerant kochia in these counties, apply this product at the rate of 1-1/2 pints per acre.
|
||
|
||
To minimize selection pressure and preserve the utility of this product for control of dicamba-tolerant kochia biotypes,
|
||
this product should be rotated with products that do not contain dicamba.
|
||
|
||
Application Timing
|
||
Only weeds that have emerged at the time of application will be controlled so be sure to apply to actively growing weeds.
|
||
Weed control may be reduced and the risk of crop injury (at all stages of growth) may increase if extreme growing
|
||
conditions (such as drought or near-freezing temperatures) occur prior to, at, or following application. Control may be
|
||
decreased if target plant foliage is wet at the time of application. Applications of this product are rainfast within 1 hour af ter
|
||
application.
|
||
|
||
Effect of Temperature on Herbicidal Activity
|
||
The herbicidal activity of this product is influenced by weather conditions. Optimum herbicidal activity requires active plant
|
||
growth and temperatures between 55°F to 75°F. Reduced efficacy will occur when temperatures are below 45°F or
|
||
above 85°F. Weed control and crop tolerance may be reduced if frost occurs before or shortly after application (3 days).
|
||
|
||
Spray Coverage
|
||
Use sufficient spray volume to provide thorough coverage and a uniform spray pattern. For best results (and to minimize
|
||
spray drift), apply in a spray volume of 8 gallons or more per acre by ground and 3 or more gallons of total spray volume
|
||
per acre by air. Spray volume should be increased as weed density and vegetative canopy increase in order to obtain
|
||
equivalent weed control; however, do not exceed 40 gallons per acre total spray volume. Rather than increasing boom
|
||
pressure, decrease spraying speed or use larger nozzle tips to increase spray volume.
|
||
|
||
8
|
||
|
||
Use only nozzle types and spray equipment designed for herbicide application. To reduce spray drift, be sure to follow the
|
||
precautions under the heading, “Spray Drift Management”.
|
||
|
||
Adjuvants
|
||
To improve weed control, a high-quality adjuvant labeled for use on growing crops may be used. An adjuvant can
|
||
optimize herbicidal activity when applications are made at lower carrier volumes, under conditions of cool temperature,
|
||
low relative humidity or drought, or to small, heavily pubescent kochia. When an adjuvant is to be used with this product,
|
||
Winfield Solutions, LLC recommends the use of a Chemical Producers and Distributors Association certified adjuvant.
|
||
|
||
Spot Treatments
|
||
Only apply using a calibrated boom sprayer using the directions below:
|
||
Application rates in the table below are based on an area of 1,000 square feet.
|
||
Mix the amount of this product (fluid ounces or ml) corresponding to the desired broadcast rate in one or more gallons of
|
||
spray. To calculate the amount of this product required for larger areas, multiply the table value (fluid ounces or ml) by
|
||
the area to be treated in “thousands” of square feet. An area of 1,000 square feet is approximately 10.5 X 10.5 yards
|
||
(strides) in size.
|
||
For example: If the area to be treated is 3,500 square feet, multiply the table value by 3.5 (calc. 3,500 ÷ 1,000 + 3.5).
|
||
|
||
Broadcast Rate Conversion Table for Spot Treatments
|
||
Broadcast Rate
|
||
(Pints per Acre)
|
||
Carnivore™ per Gallon
|
||
(Fluid Ounces (ml))
|
||
1 0.37 (11)
|
||
1-1/2 0.55 (16.3)
|
||
2 0.74 (22)
|
||
|
||
Application Rates
|
||
In general, the application rates at the lower end of the specified rate range will be efficacious when applied to susceptible
|
||
weed species with young, succulent growth. Use the higher rates within the rate range when applying to less sensitive
|
||
species, perennials, and under conditions where control is more difficult (e.g., when plants are stressed due to drought or
|
||
extreme temperatures, in dense weed stands and/or the weeds are larger). Higher rates will also be needed to control or
|
||
suppress weeds in areas where competition from crops is not present (e.g., fallowland).
|
||
|
||
Sprayer Cleanup
|
||
To avoid injury to desirable plants, before applying other chemicals with the equipment used to apply this product, all
|
||
equipment must be thoroughly cleaned.
|
||
1. After applying this product, flush and rinse application equipment with water thoroughly, disposing of the water
|
||
according to the disposal instructions in this label. All rinse water must be disposed of in compliance with local,
|
||
state and federal guidelines.
|
||
2. Hose down the interior surfaces of the tank, flushing the tank, hoses, boom and nozzles with clean water for 10
|
||
minutes.
|
||
3. Fill the tank with water and recirculate for 15 minutes.
|
||
4. Spray part of the mixture through the hoses, boom and nozzles and drain the tank.
|
||
5. Remove the nozzles and screens and clean separately.
|
||
6. If the spray equipment will be used on crops other than those labeled for this product, repeat steps 1 and 2 and
|
||
thoroughly wash the outside of spray tank and the boom.
|
||
|
||
WHEAT, BARLEY, OATS
|
||
Application Timing
|
||
To control listed broadleaf weeds, apply as a postemergence broadcast treatment to actively growing wheat, barley or
|
||
oats from the 2-leaf stage up to and including flag leaf emergence (Zadoks scale 39). Because only weeds that have
|
||
emerged at the time application will be controlled, be sure to apply when weeds are actively growing but before weeds are
|
||
8 inches tall or vining.
|
||
|
||
For perennial weeds (such as Canada thistle), apply when the majority of the basal leaves have emerged from the soil up
|
||
to bud stage to obtain season-long control.
|
||
|
||
To suppress volunteer potatoes, apply before potato plants are 4 inches tall.
|
||
|
||
9
|
||
Broadcast Application Rates
|
||
For complete listing of weeds controlled or suppressed, refer to the “Broadleaf Weeds Controlled or Suppressed” section.
|
||
|
||
For seedlings of susceptible species <4 inches tall: Apply 1 pint per acre.
|
||
|
||
For seedlings of susceptible species 4 to 8 inches tall or vining: Apply 1-1/2 pints per acre.
|
||
|
||
For volunteer potatoes: Apply 1-1/2 pints per acre.
|
||
|
||
Note: Kochia seedlings less than 4 inches tall (including ALS resistant biotypes) will be controlled using the 1 pint per acre
|
||
rate. However, when conditions for control are less favorable, such as under drought or cool temperature, a rate of 1-1/2
|
||
pints per acre will provide more consistent control of kochia seedlings 1 to 4 inches tall. For more consistent control of
|
||
small kochia, apply when the plants are at least 1 inch tall. A rate of 1-1/2 pints per acre should be used for optimal
|
||
control of dicamba tolerant kochia populations (refer to the “Management of Kochia Biotypes” in the “Broadleaf Weeds
|
||
Controlled or Suppressed” section above).
|
||
|
||
Spot Applications
|
||
Spot applications may be made using rates and spray volume equivalent to a broadcast application (refer to the “Spot
|
||
Treatment” instructions in the “Application Information” section above).
|
||
|
||
Application Restrictions
|
||
x Do not harvest treated forage or allow livestock to graze treated areas within 45 days of application.
|
||
x Do not apply more than 2.4 pints (38.4 fluid ounces) (0.5 lbs. MCPA acid, 0.5 lbs. Bromoxynil, 0.2 lbs. Fluroxypyr
|
||
acid) of this product per acre per year.
|
||
x Do not apply within 40 days prior to harvesting grain and straw or within 14 days prior to cutting hay.
|
||
x The risk of crop injury at all stages of growth and poor weed control is increased if the application is
|
||
made and extreme growing conditions (such as drought or near freezing temperatures) occur prior to,
|
||
at, and following the application. Reduced weed control may also occur during these conditions.
|
||
x Do not apply when crop canopy covers the weeds as poor control will result.
|
||
|
||
CONSERVATION RESERVE PROGRAM (CRP)
|
||
Application Timing
|
||
Apply at a rate of 1 to 2 pints per acre, depending upon the susceptibility of the weed species. Apply to grasses from the
|
||
3-leaf stage. Unless otherwise specified below, apply when broadleaf weeds are up to the 8-leaf stage, 4 inches in height
|
||
or 2 inches in diameter, whichever comes first.
|
||
|
||
Kochia seedlings less than 4 inches tall (including ALS resistant biotypes) will be controlled using the 1 pint per acre rate.
|
||
However, when conditions for control are less favorable, such as under drought or cool temperature, a rate of 1-1/2 pints
|
||
per acre will provide more consistent control of kochia seedlings 1 to 4 inches tall. For more consistent control of small
|
||
kochia, apply when the plants are at least 1 inch tall. A rate of 1-1/2 pints per acre should be used for optimal control of
|
||
dicamba tolerant kochia populations (refer to the “Management of Kochia Biotypes” in the “Broadleaf Weeds Controlled or
|
||
Suppressed” section above).
|
||
|
||
Application Precautions
|
||
x If legumes are included in CRP area planting, severe injury may occur.
|
||
|
||
Application Restrictions
|
||
x Do not allow livestock to graze in treated areas or feed treated grass to livestock.
|
||
x Crops listed on the Carnivore Herbicide label (wheat, barley, or oats not under-seeded with a legume)
|
||
may be planted within 120 days of application. Do not plant other crops within 120 days of application.
|
||
|
||
FALLOWLAND
|
||
Application Timing
|
||
Apply at a rate of 1 to 2 pints per acre, depending upon the susceptibility of the weed species. Apply to grasses from the
|
||
3-leaf stage. Unless otherwise specified below, apply when broadleaf weeds are up to the 8-leaf stage, 4 inches in height
|
||
or 2 inches in diameter, whichever comes first.
|
||
|
||
Kochia seedlings less than 4 inches tall (including ALS resistant biotypes) will be controlled using the 1 pint per acre rate.
|
||
However, when conditions for control are less favorable, such as under drought or cool temperature, a rate of 1-1/2 pints
|
||
per acre will provide more consistent control of kochia seedlings 1 to 4 inches tall. For more consistent control of small
|
||
|
||
10
|
||
kochia, apply when the plants are at least 1 inch tall. A rate of 1-1/2 pints per acre should be used for optimal control of
|
||
dicamba tolerant kochia populations (refer to the “Management of Kochia Biotypes” in the “Broadleaf Weeds Controlled or
|
||
Suppressed” section above).
|
||
|
||
Application Restrictions
|
||
x Do not make more than two applications per year, with a minimum retreatment interval of 21 days.
|
||
x Do not apply more than 2.4 pints (0.5 lbs. MCPA acid, 0.5 lbs. Bromoxynil, 0.2 lbs. Fluroxypyr acid) of this product
|
||
per acre per year.
|
||
x Do not allow livestock to graze in treated areas or feed treated plant material to livestock.
|
||
x Do not plant any crop until 90 days after application. Within 90 to 120 days after application, plant only crops
|
||
listed on this label (wheat, barley, or oats not under-seeded with a legume). Do not plant other crops within 90 to
|
||
120 days of application.
|
||
|
||
STORAGE AND DISPOSAL
|
||
Do not contaminate water, food or feed by storage or disposal.
|
||
PESTICIDE STORAGE: Store above 10°F or warm and agitate before use.
|
||
PESTICIDE DISPOSAL: Pesticide wastes are toxic. Improper disposal of excess pesticide, spray mixture, or rinsate is a
|
||
violation of Federal Law. If these wastes cannot be disposed of by user according to label instructions, contact your State
|
||
Pesticide or Environmental Control Agency, or the Hazardous Waste representative at the nearest EPA Regional Office
|
||
for guidance.
|
||
CONTAINER DISPOSAL:
|
||
Nonrefillable Containers 5 Gallons or Less: Nonrefillable container. Do not reuse or refill this container. Triple rinse
|
||
container (or equivalent) promptly after emptying. Triple rinse as follows: Empty the remaining contents into application
|
||
equipment or a mix tank and drain for 10 seconds after the flow begins to drip. Fill the container 1/4 full with water and
|
||
recap. Shake for 10 seconds. Pour rinsate into application equipment or a mix tank or store rinsate for later use or
|
||
disposal. Drain for 10 seconds after the flow begins to drip. Repeat this procedure two more times. Then offer for recycling
|
||
or reconditioning, or puncture and dispose of in a sanitary landfill, or by other procedures approved by State and local
|
||
authorities. Plastic containers are also disposable by incineration, or, if allowed by State and local authorities, by burning.
|
||
If burned, stay out of smoke.
|
||
Nonrefillable Containers larger than 5 Gallons: Nonrefillable container. Do not reuse or refill this container. Offer for
|
||
recycling if available. Triple rinse or pressure rinse container (or equivalent) promptly after emptying. Triple rinse as
|
||
follows: Empty the remaining contents into application equipment or a mix tank. Fill the container 1/4 full with water.
|
||
Replace and tighten closures. Tip container on its side and roll it back and forth, ensuring at least one complete
|
||
revolution, for 30 seconds. Stand the container on its end and tip it back and forth several times. Turn the container over
|
||
onto its other end and tip it back and forth several times. Empty the rinsate into application equipment or a mix tank or
|
||
store rinsate for later use or disposal. Repeat this procedure two more times. Pressure rinse as follows: Empty the
|
||
remaining contents into application equipment or a mix tank and continue to drain for 10 seconds after the flow begins to
|
||
drip. Hold container upside down over application equipment or mix tank or collect rinsate for later use or disposal. Insert
|
||
pressure rinsing nozzle in the side of the container, and rinse at about 40 psi for at least 30 seconds. Drain for 10 seconds
|
||
after the flow begins to drip. Then offer for recycling if available or puncture and dispose of in a sanitary landfill, or by
|
||
incineration, or, if allowed by state and local authorities, by burning. If burned, stay out of smoke.
|
||
Refillable container larger than 5 gallons: Refillable container. Refill this container with pesticide only. Do not reuse this
|
||
container for any other purpose. Cleaning the container before final disposal is the responsibility of the person disposing
|
||
of the container. Cleaning before refilling is the responsibility of the refiller. To clean the container before final disposal ,
|
||
empty the remaining contents from this container into application equipment or a mix tank. Fill the container about 10%
|
||
full with water and, if possible, spray all sides while adding water. If practical, agitate vigorously or recirculate water wit h
|
||
the pump for two minutes. Pour or pump rinsate into application equipment or rinsate collection system. Repeat this
|
||
rinsing procedure two more times. Then offer for recycling if available or puncture and dispose of in a sanitary landfill, or
|
||
by incineration, or, if allowed by State and local authorities, by burning. If burned, stay out of smoke.
|
||
FOR CHEMICAL EMERGENCY: Spill, leak, fire, exposure, or accident,
|
||
call CHEMTREC 1-800-424-9300.
|
||
|
||
11
|
||
|
||
WARRANTY DISCLAIMER
|
||
The directions for use of this product must be followed carefully. TO THE EXTENT CONSISTENT WITH APPLICABLE
|
||
LAW, (1) THE GOODS DELIVERED TO YOU ARE FURNISH ED “AS IS” BY MANUFACTURER OR SELLER AND (2)
|
||
MANUFACTURER AND SELLER MAKE NO WARRANTIES, GUARANTEES, OR REPRESENTATIONS OF ANY KIND
|
||
TO BUYER OR USER, EITHER EXPRESS OR IMPLIED, OR BY USAGE OF TRADE, STATUTORY OR OTHERWISE,
|
||
WITH REGARD TO THE PRODUCT SOLD, INCLUDING, BUT NOT LIMITED TO MERCHANTABILITY, FITNESS FOR A
|
||
PARTICULAR PURPOSE, USE, OR ELIGIBILITY OF THE PRODUCT FOR ANY PARTICULAR TRADE USAGE.
|
||
UNINTENDED CONSEQUENCES, INCLUDING BUT NOT LIMI TED TO INEFFECTIVENESS, MAY RESULT BECAUSE
|
||
OF SUCH FACTORS AS THE PRESENCE OR ABSENCE OF OTHER MATERIALS USED IN COMBINATION WITH
|
||
THE GOODS, OR THE MANNER OF USE OR APPLICATION, INCLUDING WEATHER, ALL OF WHICH ARE BEYOND
|
||
THE CONTROL OF MANUFACTURER OR SELLER AND ASSUMED BY BUYER OR USER. THIS WRITING
|
||
CONTAINS ALL OF THE REPRESENTATIONS AND AGREEMENTS BETWEEN BUYER, MANUFACTURER AND
|
||
SELLER, AND NO PERSON OR AGENT OF MANUFACTURER OR SELLER HAS ANY AUTHORITY TO MAKE ANY
|
||
REPRESENTATION OR WARRANTY OR AGREEMENT RELATING IN ANY WAY TO THESE GOODS.
|
||
|
||
LIMITATION OF LIABILITY
|
||
TO THE EXTENT CONSISTENT WITH APPLICABLE LAW: IN NO EVENT SHALL MANUFACTURER OR SELLER BE
|
||
LIABLE FOR SPECIAL, INCIDENTAL, OR CONSEQUENTIA L DAMAGES, OR FOR DAMAGES IN THE NATURE OF
|
||
PENALTIES RELATING TO THE GOODS SOLD, INCLUDING USE, APPLICATION, HANDLING, AND DISPOSAL.
|
||
MANUFACTURER OR SELLER SHALL NOT BE LIABLE TO BUYER OR USER BY WAY OF INDEMNIFICATION TO
|
||
BUYER OR TO CUSTOMERS OF BUYER, IF ANY, OR FOR ANY DAMAGES OR SUMS OF MONEY, CLAIMS OR
|
||
DEMANDS WHATSOEVER, RESULTING FROM OR BY REASON OF, OR RISING OUT OF THE MISUSE, OR
|
||
FAILURE TO FOLLOW LABEL WARNINGS OR INSTR UCTIONS FOR USE, OF THE GOODS SOLD BY
|
||
MANUFACTURER OR SELLER TO BUYER. ALL SUCH RISKS SHALL BE ASSUMED BY THE BUYER, USER, OR ITS
|
||
CUSTOMERS. BUYER’S OR USER’S EXCLUSIVE REMEDY, AND MANUFACTURER’S OR SELLER’S TOTAL
|
||
LIABILITY SHALL BE FOR DAMAGES NOT EXCEEDING THE COST OF THE PRODUCT.
|
||
|
||
If you do not agree with or do not accept any of directions for use, the warranty disclaimers, or limitations on liability, do
|
||
not use the product, and return it unopened to the Seller, and the purchase price will be refunded.
|
||
|
||
Carnivore is a registered trademark of Winfield Solutions, LLC.
|