a97107de46
Image rebuild (skip scrape) / build (push) Failing after 1h37m12s
Dockerfile: self-contained image with corpus + Chroma + BM25 baked in. Drawbar's compose pulls + runs without volume mounts. Built from sources.json (labels schema), PRODUCT_NAME=crop_chem by default, HYBRID_SEARCH=true (always-on for production quality). RERANK_URL + OLLAMA_URL get set at compose time. .gitea/workflows/refresh.yml: monthly cron (1st @ 06:00 UTC) does full scrape → reindex → image push. Scrapes Bayer (~30 min) + EPA PPLS row-crop filtered (~7h). Skips reindex+push if no corpus diff. Tags pushed: :latest, :<sha12>, :corpus-<YYYY.MM.DD>. .gitea/workflows/image-only.yml: on-demand or auto on code-only pushes to main (paths: docs_mcp/, rag/, scrape/, requirements.txt, Dockerfile, sources.json). Reindexes from committed corpus, builds image, pushes. ~10 min vs ~9h full refresh. .gitignore: corpus/ now COMMITTED (4,159 labels, 265 MB of .md + sidecars). Lets image-only.yml rebuild indexes without re-scraping. chroma/ + bm25/ still gitignored (regenerable binary indexes). .dockerignore: drops venv, eval results, PLAN/README/CLAUDE.md, deploy/, .git/ — keeps the image lean. corpus + chroma + bm25 explicitly NOT in dockerignore (those go INTO the image). Co-Authored-By: Claude Opus 4.7 (1M context) <noreply@anthropic.com>
745 lines
38 KiB
Markdown
745 lines
38 KiB
Markdown
# DREXEL PARATHION 4 EC.
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- EPA Reg No: **19713-325**
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- Registrant: DREXEL CHEMICAL COMPANY
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- Signal word: Danger
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- Active ingredients: Parathion (45.3%)
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- Label accepted: 1994-10-03
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- Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/019713-00325-19941003.pdf
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---
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(
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(
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Ms. Barbara Brown
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Drexel Chemical Company
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P.O. Box 9306
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Memphis, Tennessee 38190
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Dear Ms. Brown:
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Subject: Corrected Labeling
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Drexel Parathion 4 EC
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oel
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EPA Registration No. 19713-325
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Your Application Dated July 29, 1994
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I.
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The labeling referred to above, submitted in connection with
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registration under the Federal Insecticide, Fungicide, and
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Rodenticide Act, as amended, is acceptable, subject to the comments
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listed below.
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1. Throughout the use directions, the symbol ";",, is missing,
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replaced on the label copies with a slanted plus sign.
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We believe this is a word processing error, rather than
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a change to the directions for use, therefore, in order
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to accept this labeling, we have manually corrected the
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errors. This must be corrected on your final printed
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labels.
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2. In the "Agr icul tural Use Requirements," page 8, the
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symbol for the distance of "%" is also missing due to a
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word processing error. We have also manually corrected
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this error. Please ensure that this is corrected on your
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final printed labeling.
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3 . In the last sentence on page 9, the word "quipped" should
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be "equipped."
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4. In the directions for use on sorghum, change the word
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"completed" to "completely."
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5. The instructions for storage of this product should read
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" ... may exceed 120°F or below 45°F." Please ensure that
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the final printed labeling includes the degree sign,
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rather than an "x".
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I 'J -, ' I' I 1 . l ,
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)
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6. As a reminder, the
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labeling for this
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crossbones symbol.
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front panel of the final printed
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product must bear the skull and
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A stamped copy of the label which we have corrected is
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enclosed for your records. Before you release the product for
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shipment bearing the amended labeling, you must make the
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corrections we have indicated. Additionally, please submit five
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copies of your final printed labeling for our files.
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Enclosure
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Sincerely,
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DAnnis H. Edwards, Jr.
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Product Manager 19
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Insecticide-Rodenticide Branch
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Registration Division (7505C)
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•
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•
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RESTRICTED USE PESTICIDE
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Due to very high acute toxicity to
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Humans and Birds
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1
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+---------------------------------------------------------------------+ For retail sale only to certif1ed commercial aer1al applicators or
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persons under their d1rect supervision. For use only by certified
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commerc1al aerial applicators. Direct supervis!on for this product
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is def1ned as the certified commercial applicator being physically
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present during m1xing, loading, repair and cleaning of application
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equipment. Cert1fied commercial applicators must also ensure that
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all persons involved in these activities are informed of the
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precautionary statements.
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+---------------------------------------------------------------------+
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ACTIVE INGREDIENTS:
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DREXEL
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PARATHION 4 EC
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Parathion~ (O,O-diethyl O-p-nitrophenyl phosphorothioate) .
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Related Compounds
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INERT INGREDIENTS:
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TOTAL:
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~Also known as Ethyl Par3th10n
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43.91%
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1.39%
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54.70%
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.100.00%
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Product contalns 4 pounds of Parath10n per gallon.
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KEEP OUT
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DANGER
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PELIGRO
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OF REACH OF CHILDREN
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POISON
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CAN CAUSE DEATH
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Si usted no entiende la etiqueta, busque a alguien para que se la
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explique a usted en detalle. (If you do not understand the label. find
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someone to expla1n lt to you in de:ail).
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EPA REG. NO. 19713-325
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EPA EST. NO. 19713-MS-l
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tltI'i..!>J lh< "f'lCtt:ru,' a,..·. 1'-,' \
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Fr"JlIIII(i. .... ...,. i ft .... ,.",. ,
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fJII ... 'on"~ '. :'". ,t-.. ,,' ..
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ft~,'e"" J <!o~~~ ",',_ ",~.
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j < I 7 I ~ 3: :;1. ~
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,
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•••••• • •• • •• • •
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•••••• • • • • ••
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••••• • • • • •••••
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•• • • •• •••
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• • • • •• • •••
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• • • ••••• •
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•
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• •• •• • ••••
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•••• • ••••
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•
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•
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2
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STATEMENT OF PRACTICAL TREATMENT
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This product is an organophosphate insecticide/miticlde.
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FIRST AID TREATMENT: Call a doctor (phys1clan). clinic or hospital
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immedlately. Explain that the victim has been exposed to parathion and
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describe his condition.
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IF BREATHING HAS STOPPED: Start artificial respiration immediately and
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maintain until doctor sees victim.
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IF SWALLOWED: Call a physician or pOlson control center. Drink 1 or 2
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glasses of water and induce vomiting by touching back of throat with
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finger, cr. ~f available. by administering syrup of ipecac. Do not
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induce vom1ting or glve anything by mouth to an unconSCJ.ous ~erson.
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IN CASE OF CONTACT: Immediately flush eyes or skin w1th pienty of
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water for at least 15 minutes. See doctor lm~ediately.
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NOTE TO PHYSICIAN
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Antidote: Administer atropine sulfate in large doses two to four mg .
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intravenously or 1ntramuscularly as soon as cyanos1s 1S overcome.
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Repeat at 5 to 10 m1nute 1ntervals ~nt11 signs of atropini=ation
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appea~. 2-PAM chloride is also antidotal and may be adminlstered in
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con;unction w1th at~opine. DO NOT GIVE MORPHINE OR TRANQUILIZERS.
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Par3th10n 1S a strong chollneSterase 1nhibltcr affecting the central
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and perlpheral nervous systems anc produc:ng cardiac and resp1rator
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depress:on. At flrst s:gn of pu~monary edema the patient should be
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glven supplemental oxygen and treated symptomatlcally.
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Continued absorpt10n of the pOlson may occur and fatal relapses have
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been reported after 1n1t1al improvement. VERY CLO~E SUPERVISION OF THE
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PATIENT IS INDICATED FOR AT LEAST 48 HOURS .
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( IlST AYlIUBLE CIPI )
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•••••• • •• • •• • •
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•••••• • • • • ••
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••••• • • • • •••••
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••• • •• •••
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• • • • •• • •••
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• • •••••• •
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•
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• •• •• • ••••
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•••• • ••••
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•
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•
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3
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+---------------------------------------------------------------------+
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PRECAUTIONARY STATEMENTS
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DANGER
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HAZARDS TO HUMANS AND DOMESTIC ANIMALS
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POlsonous if swallowed. inhaled. or absorbed through skin or eyes.
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Rapldly absorbed through skln. Do not breathe vapors. Do not get ~n
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eyes or on skln or clothing.
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CAN KILL IF SWALLOWED: This product can kill you if swallowed. Even
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in small amounts spray mlst may be fatal If swallowed.
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CAN KILL BY SKIN CONTACT: This product can klll you if touched by
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hands or spilled or splashed on skln. In ~yes or on clothing (llquid
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,goes through clothes).
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:CAN KILL IF BREATHED: ThlS prOQUCL can k~ll you if vapors or spray
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:mlst are breathed.
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:PERSONAL PROTECTIVE EQUIPMENT
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:Some materials that are chenl1cai-reslstant to th1S product are
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:llsted below. If you want more options. follow the instructions for
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:category G on an EP~ chem1cal res1stant category selection chart.
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:M1xers and Loader3 (who must use the closed s~stem described
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:elsewhere on th1S label) must wear: Coveralls over loeg-sleeved
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:shlrt a~d long pants. ChemIcal-res1stant gloves. such as Barr1er
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Lam1nate or V1toe. Chem1cal-res1staet footwear plus s~cks. Chemical
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reSls:ant a~ron. Protectlve eyewe\r. 1~ the closed system 1S
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pressurl:ed. and Chemlca~-resistant headJear for cverheac exposure
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Applicators !pllots In enclosed cockpits! ~ust wear:
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Long-sleeved sh1rt and long pants. and Shoes plus socks
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In add1:10n. pllots must wear chemical-reslstant gloves. such as
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BarrIer Laminate or Viton when enterlng or leaving an a1rcraft
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contam:nated w1th pestlc1de residues. If taken into the COCkP1t. the
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gloves m~st be kept in an enclosed container to prevent
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contamlnation of the ins1de of the COCkP1t.
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:All other hdndlers. Includ1ng persons who (1) repair. clean. or
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:~alnta1n the p!rts of mlx1ng. loadIng. or appllcat10n eqUIpment that
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;mai' ccnLu:1 resldues. (2~ clean up sp1lls. (3) handle open
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:contalners. cr (4) dlspcse of thlS pesticide. must wear: Chemical
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:reslstant prOLect:ve SUlt. Chemlcal reSIstant gleves. such as
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:3arrler Lamlnate or Viton. Chemlcal-reslstant IooLwear plus socks.
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:ProtecLlve eyewear. Chemlcal-resistant headgear for overhead
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:exposur~. and a respirator wlth elther an organic vapor removing
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:car~rIdge WILh 3 prefilter approved fer pestlcldes IMSHA/NIOSH
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:approval number pref1x TC-23C). or a canlster approved for
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;pestlcldes (MSHA/NIOSH approval number preflx TC-14GI.
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+---------------------------------------------------------------------+
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•••••• • •• • •• • •
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•••••• • • • • ••
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••••• • • • • •••••
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••• • •• •• •
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• • • • •• • •••
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• • • ••••• •
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•
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• •• •• • ••••
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•••• • ••••
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•
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•
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4
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+--------------------------------_._-----------------------------------+ User Safety Requirements
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Users must:
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Provide mechanical exhaust ventllation, if product is handled
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indoors.
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Discard clothlng and other absorbent materlals that have been
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drenched or heavily contaminated with this product's concentrate. Do
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not reuse them.
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Clean respirators and replace cartridges or canlsters according to
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instructions included with the resplrators.
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Replace gloves frequently.
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Keep and wash PPE (coveralls, gloves, footwear, a?rons, protecti'fe
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eyewear, etc.) separately from all ether laund~y. Wash FPE after
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eac~ day's use, following the manc£acturer's directions. If no such
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instructlons, use detergent and hot wate~. Store PPE separately from
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personal clothing.
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Keep personal worK clothlng (long-sleev&d shirts,' long pants, and
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socks) worn while perform1ng mixing, loadlng, application, and other
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handl1ng and early entry tasks separate from hcusehold articles.
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,After ear:h d:W of use, ' ... ash work cloth:ng separately from household
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:art1cles.
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+---------------------------------------------------------------------+
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+_uu_uu __ uuu ___________________________ lIUT AVAIlABLE eM]
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User Safety Recommendat10ns
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Users should:
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Not rub eyes or mouth with hands.
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STOP work and get help r1ght away, if yeu feel sick ln any W37· See
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F1rst A1j (Pract1cal Treatment) sectlon of th1S latel. Call a doctor
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(phys1c1an;. Cl1~lC, or hOspltal 1mmediately. Explain that the
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V1Ctl~ has tee~ e:'posed to parathlon and descrlbe h1S condltio~.
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Aiter flr~t a1d 1S glven (3ee F1rst Ald Treatment Seetlon) and If a
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doctor cannot come. take vlctlm to cl:nlc or hospltal .
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:Wash hands before eatlng, drink1ng, cnewlng gum, uSlng tobacco. or
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:uslng the tOllet.
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:Remove cloth:ng lmmedlately 1f pest1clee gets lDside. Then wash
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:thoroughly and put on clean clothing.
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:P&move PP3. all w~r~ clothlng, and footwear lmmediately after
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:handllng thlS product. Wash the outslee of gloves with soap and
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'water befere removlng, Shower using soat· a~d w~ter. Wear only clean
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clothlng when leavlng Job--do not wear contaminated clothing.
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The Nat lonal Pes tlC lde Te lecommunica t l0n Network (NPTN) is .<1vpi lable
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for recommendatlons regarding pOlsonlDg hlanagement •• M~rge!'.<;'.·
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trea:ment, and o::her ~ni::lrmation regardlng the tox::ci!'t! of •
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parathlon. The toll-free number for NPTN ~s 1-800-~58-'378.. • . ef!.. ••• • ••
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Repeated exposures to Chollnesterase Inhlbltors sucn:at ar~ • ••
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contained in this product may. w::.tr.cut warning, causeo·prolM~
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susceptiblll::Y to very small doses ot any chollnes~~~ie lhhibitor.
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Persons worklng wlth thls product should have freque~~·blood·tests
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:of thelr chollnesterase levels. Ii the cholineste~ase leve~ :(~lls
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:below a critical pOlnt. no further exposure should be allow~Q.~ntil
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:it has been determined by means of blood tests that the •• :.
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:cholinesterase level has returned to normal. Before using this
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:product, consult the Agricultural Extension SerVlce or Experlmental
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:Station for specific recommendations regarding such blood tests.
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+
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+---------------_._------------------------------------_._--------------+
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•
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•
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5
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POISON SIGNS (Symptoms)
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Parat~ion is a very dangerous poison. It rapidly ~nters the body on
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contact wIth all skin surfaces and eyes. Clothing wet with this
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material must be removed immediately. Exposed persons must receive
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prompt medical treatment or they may die.
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Some of the SIgns and symptoms of poisonlng are: Headache, nausea,
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vom1ting, cramps, weakness, blurred vision, pin-point pupils,
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tight~ess in chest, labored breathing, nervousness, sweating, watering
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of eyes, drooling or frothing of mouth and nose, muscle spasms and
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coma.
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ENVIRONMENT~L HAZARDS
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This pesticide is highly toxic to figh, aquatic invertebrates, and
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wildlife. Birds in treated area may be kIlled. ShrImps and other
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aquatIc o~ganisms may be killed at recommended appllcation ratea. For
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terrestrial uses, do not apply directly to water, to areas where the
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su~face water is present, or to intertidal areas below the mean high
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water mar~. Runoff and drift from target areas may be hazardous to
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~quatlc organisms in adjacent aquatic SItes. Do no~ contaminate water
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when disposiag of eqUIpment washwaters. ThlS product is extremely
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tO~lC to bees exposed to direct treatment or residues on blooming
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crops or weeds. Do not apply th1S product or allow It to dri~t to
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bloom~ng crop or weeds 1f bees are v~s~:lng the treatment area.
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PHYSICAL AND CHEMICAL HAZARDS
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Do not use or store near heat or open flame.
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DIRECTIONS FOR USE
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It is a viol at 1011 of Federal :aw to use :hlS product in a manner
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lncons13t3nt wl~h ItS labellng.
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For any requlr~ments speciflc t: your State or ~ri~e. c~~s~lt the
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age~c1 r~spcnslble for P03tlc~de regulat!cn.
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APPL:CATION RESTRICTIONS
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Aerlal Appllca:ion Only: Et~yl parathioc may only Cd applled aerlal 1.
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and only by a certlfled commerclal appllcator as deflned In FlFRA
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2(e)[3). HUMAN FLAGGERS ARE STRICTLY PROHIBITED DURING AERIAL
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A?PLICATICN.
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No Spray or Drlft Cn Any Person: Do not apply this produ:t :n a way
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that will contact any perso~, elther dlrectly or throug~ drlft. Durlng
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applicatlon keep ALL persJns out oi (1: the treated area plus any area
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withln 100 feet of the treated area, and (2) any additional area where
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there is a dang~r of drift. Keep all llvestock and pets away from
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treated area and where there IS danger of drift.
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Areas Where _ Appllcatlon Is PrOhlbIted: Do not apP\I •• ~~lS i'::~~ct
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wlthln 100 teet of bUlldlngs. putil ~ r,oads, or boctl~ :of water. Do no:
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apply wlthin 100 feet of property lines, unless tne owner pt ~he
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adjacent property has given prlor wrltten consent ·t~·'he ~~~cation
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and has been informed of the tlmlng of the appllcat·~h and t~e
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appropr late entry restr lctlons. ••••• : ••••• • • Crop LimItatlons: ThlS product must not be applle~.~~·any c£op other
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than alfalfa, barley, cern, cotton, sorghum. soybeans, s~t1~wer, and
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wheat. Any treated crop \nust b8 harvested only by mechani~'~ means.
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Hand harvesting of treated crop IS prohlbi ted. : •••
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Chemigation Prohibited: Do not apply thIS product through'any type of
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irrigatlon system.
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[BEST AVAIlABLE c.d]
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•
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•
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6
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Drift Reduction Measures: Do not apply thlS product if the wind
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exceeds 10 miles per hour. Apply only from nozzles located not more
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than 75% of the distance from the center of the aircraft to the wing
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tip of helicopter rotor tip .
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• ••••• • •• • •• • •
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•••••• • • • • ••
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••••• • • • • •••••
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• •• • •• •• •
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•
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• • • •• • •••
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• • •••••• •
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•
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• •• •• • ••••
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•••• • ••••
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•
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•
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• I
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7
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+---------------------------------------------------------------------+
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AGRICULTURAL USE REQUIREMENTS
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Use this product only in accordance w1th 1tS label1ng and with the
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Worker Protection Standard, 40 CFR 170. Th1S Standard conta1ns
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requ1rements for the protection of agricultural workers on farms,
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forests, nurser1es, and greenhou3es, and handlers of agricultural
|
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pesticides. It contains requirements for tralnir.g, decontamination,
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,notification, and emergency assistance. It also contains specific
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||
:instruct1ons pertaining to the statements 1n this labeling about
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:personal protective equ1pment, restricted-entry intervals, and
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:notificat1on to workers. The requirements in this box only apply to
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:uses of th1S product that are covered by the Worker Protection
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||
'Standard (WPS)
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IMPORTANT: The except10ns 1n the WPS pertaining to personal
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protective equipment, restricted-entry intervals. and notification
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to workers do NOT apply when this product is used.
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Restrictions on En:ry to Treated Areas:
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Do not enter or allow any person to enter into entry-restri~ted
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areas (treated areas plus areas within 100 feet of treated areas)
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:dur~ng tie restr1cted entry 1nterval IRSI) of 3 days (6 days for
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:oornl and dur:ng ar.y longer per10d of time prescribed by State law
|
||
:or regulatlcn. Entry lnto entry-restricted are,s i 1nc:ud:ng e~rly
|
||
:entry that would otierWlse be permitted under the W?S) by any person
|
||
. 13 ~ROHIBITSD. except for per30ns wto are (11 handlers performing
|
||
;crop-advlscr tasks or 12 workers ~erformlng :rrigation-related
|
||
;tasks.
|
||
:Restr:ctlona for All Persons Who Enter Entry-Restrlcted
|
||
:~hen any person enters the treated areas or within 10C feet of the
|
||
:trea:ed area before the explrat:on of REI all of the followlng
|
||
:requlrements must be complied wlth:
|
||
:1' ~c entry 15 per~ltted. except for persons whc are performing
|
||
: ·:rcp-ad'lls::r tasks or 1rr1g.3.tlon-related task3.
|
||
:. ~o ~er£on ~s a~lcwed to ente~ or remal~ 1n entry-restrl~t~d ar~as
|
||
: jurlng ap~i:catlon and untll ~eur (4) hcur3 a~ter appl1cat1on :s
|
||
:c')mploate .
|
||
:3) No persen 15 allcwed to rema~n 1n 3ny entrl-rest~lcted area for a
|
||
~tot~l of mc~e than ~ne (I) hour In any 24-hour ~ariod,
|
||
:4\ Eac~ p~r30n must wear th~ par3~nal prJtectlve ~qulpment 3peClfied
|
||
:foc ~arl! entry on thIS label.
|
||
:5 Each p~r30n must be prOVIded the p[ote~t1ons In the WPS and in
|
||
:t~1S label:ng. :i the two reqUirements are not Identlcal, the
|
||
:=~qulr~~en~s t~a~ ar~ t~e mcst restrlctive must be f~llowed.
|
||
:6i Each per30n. except owners of the farm and members of their
|
||
:lmmedlate fam:ly. must have rece1ved tra1ning as follows:
|
||
: a' Currently cert1f1ed as an appl1~ator of restr1cted-use.··.·.
|
||
P~3t1.Cld-?:;, OR : •• :-: •••
|
||
d . • •• - • : (b i Cucrent:y tr:H:1e as a nandler ur.der the requlI'emellts 0;' tpe
|
||
: 'f'.-J?S. CR •••••• • •• •• •••• : l·c \ ::'-l~rentli' tra:ned as a 'Nor~er und~r the requ1reftlAr1t3 Qf the WPS
|
||
: an·j. ~n a·!dlt:C:1. 15 ::..nfcrmec: (L how t.o P'.lt on. us.~_ •• and t·cr~~· off
|
||
:P?~ ~orrectiv. (I:) about t~e Importance of Washlna th&rouoh}y after
|
||
~.... -:remo·/lr.g PFE. and ,1:1: ho'" to prevent. recognIze, and glv~.e!).rrect
|
||
: fIrs: ald for heat Illness. • •••
|
||
I ••••
|
||
• •
|
||
+----------------------------------------------------- -----~~~--------+
|
||
(lEST AlAlUILE eM]
|
||
|
||
•
|
||
•
|
||
8
|
||
+---------------------------------------------------------------------+
|
||
:AGRICULTURAL USE REQUIREMENTS (Continued)
|
||
(7) Before entering the entry-restricted area, each person must have
|
||
read the product labeling or been infermed ln a manner the person
|
||
can unders~and 0: all the requlrements of all labellng requlrements
|
||
related to safe use of the pest1c1de, includ1ng signal word. human
|
||
hazard precautions, first a1d instruct1ons, symptoms of poisonlng,
|
||
and personal protect1ve equ1pment requirements for early entry.
|
||
(3) Appropriate measures to prevent heat illness must be taken for
|
||
each person.
|
||
(9) Each person must be provided a decontamination site that is
|
||
reasonably access:ble and is withln ~mile of that persen.
|
||
(Exception: if the site where the person is working lS more than ~
|
||
mile from tne nearest p01nt reachable by vehicle, the
|
||
decontamlnation slte may be at the access pClnt.) Each
|
||
decontam1nation Sl~e must conta1n an adequate supply of soap and
|
||
s:ngle-use towels and an adequate amount of water fer routine
|
||
washlng, emergency eyeflush1ng, and emergency whole body washing .
|
||
The ~ater mU3t be cf a quality and temperature that w111 not cause
|
||
.11lness or in~ur7 when it centacts the skin or eyes or 1f 1t lS
|
||
:s~al10wed. The s:te must also contain a clean chanoe of clothing,
|
||
':0) Each pers:~ mus: carry an ~yefl'!sh d13penser ~c~taini~g ~t
|
||
least one pint of water that meets the 1uallty and tem~erature
|
||
~riter1a llst@d for de:ontamlnat10n water 1n (9) abeve.
|
||
Ill) After the actlvity 1n tne entry-restricted area, scap, clean
|
||
,tQwels. and an adequate amount of water for thorough wash1ng must be I
|
||
: ~vallable at the place where the person removes the PPE. The water
|
||
:must meet the quallty and temperature cr1teria listed fer
|
||
:decontamination water ln (9 1 above.
|
||
: ( 12) Each per,·=r. :nust wash the-roughly aite:' rem':Vlnc; ?PE.
|
||
: 1131 P~rscnal p~ot~ctlve equlpm·!nt worn during early entry must not
|
||
:b~ W0r~ hJme. :IC perscn. other :han J~ne~s ot the fa=~ an~ members
|
||
:of t~e~= Imm~d13te f3~11y, may t3~a hcm~--b~fore It is cleaned--PPE
|
||
~wcrn j~rl~g ~a=:'l e~try .
|
||
:Personal ?:,ctec:~':e Eq~lpment f~r Early Entry: PPE requI:'ed for
|
||
:ear1y entry to treated areas that lS permItted on this label is:
|
||
:Coveralis over long-sleeved shirt a~d long pants
|
||
:ChemIcal-resls:a~t glcves, such as E3rrier Lamlnate and Viton
|
||
:?~ct~ctlve eyewear
|
||
:Chemloal-resistant heaj~ear for overhead exposure
|
||
:Notl~lcatlon About Applicat:on And Entry Restrlctlons:
|
||
:Notify workers (Jther than wor~ers who are members of the farm
|
||
:owners' immedlate famlly) of the applIcatIon by wa~Qh~~ th~~.~allY
|
||
:If they w:ll be WithIn, mlla ot the treated area. :I~ ~ddltlgn,
|
||
:traated areas must be posted With WPS signs at (or'100'fee~ o~tside'
|
||
: all US'.la':' pCInts of entry or at (lGO feet outside) '~'!: the·..,5t)ners
|
||
:of the treat~d areas affordIng maXImum visitility. •••• • • ••••••
|
||
+--------------------------------------------------~~~.---~----------+
|
||
•• • ••••• • •• •• • ••••
|
||
IIIST .IIILABLE eM J .. ::"
|
||
|
||
•
|
||
•
|
||
9
|
||
NOTIFICATION TO FARM OWNER/OPERATOR
|
||
A certIfIed commercial applicator must not apply this parathion
|
||
product on a farm until he or she makes sure the owner of the farm (or
|
||
person responsIble for managing the farm) has the followIng
|
||
InformatIon in wrIting: (1) specific location and descri~tion of area
|
||
to be treated. (2) time and date of application. (3) product name. EPA
|
||
registration number. and active ingredients, (4) the entry
|
||
restrIctions including the restricted-entry interval. (5) the
|
||
requirement for both oral warnIngs to workers and posting of t~eated
|
||
areas. (6) the requirement that crops treated with parathion be
|
||
harvested mechanically and the prohibitIon on hand ha~vesting, (7) the
|
||
IncIdent reportIng requirements set forth on thIS label. and workers
|
||
or other persons during or after applIcation. This requirement is
|
||
satisfied if the owner/operato~ of the farm has a copy of this
|
||
labelIng.
|
||
PROTECTION OF APPLICATORS AND MIXER/LOADERS
|
||
Applicato~ ProtectIon: The CCCk~lt of the aircraft used to apply thIS
|
||
product must be fully enclosed whIle this product IS being applied. No
|
||
pl!ot may apply thIS product if the pilot has earlier durIng the 6ay
|
||
ot ap91lcatIJn performed any mix:ngiloadlng activitIes (othar than
|
||
ac~:ng as a~ observer' involvIng any pestlcide product contaInIng
|
||
parathlO~. Human flaggers are prohIbited.
|
||
Mixer/Loader Protection: An observer must be present durIng all
|
||
miXIng/loadIng actIVIties in order to f';rnlsh assistance ln the event
|
||
of an accIdent. The observer must not act as a mixer/loader and need
|
||
not wear personal protective eqUIpment.
|
||
ThIS product must be mixed and loaded in a closed system. as described
|
||
below:
|
||
When handlers uae closed systems. enclosed cabs. or a:rcraft In a
|
||
manner that meets t~e reqUIrement IlsLed In the Worker ProtectIon
|
||
Standard (WPS) for agricultural pestICIdes [40C?R 17r.2~O·d)(4-6)1,
|
||
the handler PPE reqUIrements may be reduced or ~0dified as specified
|
||
in the WPS.
|
||
The lIquid pesticide must be ~erJved from l~S original shIPPIng
|
||
container and transfQ:red t~reugh ccnnectlng hoses. pipes. and/or
|
||
couplIngs that ~re sufficiently tlght tJ prevent handlers or other
|
||
perscns from contactIng th~ pa:ath:oc concentrate. use d:lu:ion. or
|
||
rlnsate solutIon. A complete seal by d~y break or screw-on couplIng to
|
||
the openIng of the orIgInal containe: sha~l be req~l~ed.
|
||
All hoses. pIpIng. tanks. and conneC~lons used In the system shall be
|
||
of a type appropriate for the produc: beIng used and the pressure and
|
||
vaC'lum lev"!ls lnvolv"!d. The svstem ahall be desloned and ooe·; .. t.ed so -~ . - ....!..!.... . •••
|
||
~hat the concentrated form 0: th12 pr~duct IS not ul~eJ:more ~han 25
|
||
pSl or pressure at any pOInt in the syst"!m beyond or do~nstr~a~ from a
|
||
pu;np prcduclng poslt:ve pressure. The closed system "I1Io.!>"1: be·adQ1Juate
|
||
LO make ner:essar'[ measurements of Lhe product beIng uW. E.:tecrlal . h l' t :l h ••••••. slgnt '1auges s a J. e q'...l1pper WIL '!alves se that ttM:(o~ow ef
|
||
pestlc:de to tte SIght gauge can be shut off In caa~.~~·breakage or
|
||
leakage from the gauge. : ••••
|
||
( IlST AflfUBl£ co;o
|
||
••••
|
||
• ••• • ••••
|
||
|
||
•
|
||
•
|
||
10
|
||
Shut-off devlces ~ust be installed on the e:~it end of all hoses and at
|
||
all disconnect points to prevent leakage of parathion when the
|
||
transfer is stopped and the hose is removed or disconnected. If a hose
|
||
carried parathion concentrate and has not been rlnsed In accordance
|
||
with the Instructions In thlS section, a dry ccuple shutoff device
|
||
that will mlnimi=e parathIon drippage to not more than 2 mI. per
|
||
disconnect must be Installed at the disconnect point. If the hose
|
||
carried diluted-for-use parathion or r~nsate solution, a reversing
|
||
ac:ion pump or a si~ilar system that wlll empty the hose and eliminate
|
||
drlpplng of liquid from the end of the hose may be used as an
|
||
alternative to a shut-off devlce.
|
||
In mIxlng/loading operations do not pour this product fr~m Its
|
||
container. Before opening the ccntainer. make sure that the container
|
||
IS restlng securely on the grollnd or a sturdy support, wlth the top
|
||
(opening) end up and approxlmately level.
|
||
Remove the product from the contalner only by use of a vacuum
|
||
producing pump system connected to a probe system that IS llsted by
|
||
t~e State of CalIfornia under that 3tate's program establlshlng
|
||
cr:teria for closed-system handlIng of TOXlcity Category I pestlcides.
|
||
Sxa~ples of Callfornla Ilsted systems are the Chemprobei~! Model II
|
||
syst~m 501·j by Charlor ~fg. Co., Inc .. P. O. Box 2174. SalInas, CA
|
||
93 Q 02. telephone 402-422-5477 or the Pr~tect-O-Loader Mode~ XM-l
|
||
sy3t~m soLd by Protec~c Mig. C2 .. 20~39 ~lrerock Road, Bend. Or.
|
||
97701: telephone 503/382-6386. The probe system shall be screwed into
|
||
the threaded openlng In the top 0: the contalner to ferm a watertlght
|
||
connectlon. uSlng approprlate adaptors provlded by the probe
|
||
manufacturer as necessary. The Instructlons provlded by tne seller of
|
||
the probe system shall be followed. except that a removable probe may
|
||
not be removed frem the contaIner until tne contaIner IS empty and the
|
||
contaIner and probe have been thoroughl? rlnsed as requlred by thls
|
||
se·::tlon.
|
||
T~e cJo3~d-system must pr~v:de for adEq~at? rins:ng ci an~' r~mcv~bl~
|
||
probe a~d of all ccnt31ne=s that are net lajeled for =et~rn to the
|
||
reglstra~t. Rlns~ng must ~e done us:~g a l!qUld tha: con~alns no
|
||
pestlclde. ~he rlns:ng system m~s: be capable cf spr3y-rlnslng the
|
||
Inner surface of tte contalner. The rlnse Solutlon snaIl De r~mcved
|
||
from the pes:lclde ccnta:ner c~nc~rrent wlth tje l~tr~d~ct~on of the
|
||
rlnse medium. The rl~se Solutlon sha~l go Into tre pest::lce mlX tank
|
||
cr appl:cator ~ehicle Vla the closed system.
|
||
rh~ syst~m shall be ::~sed ac=ordl~g tc the 3p~c:i:~3tl,:n3 0~ t~e
|
||
man~fact~rer of the probe system. or. in the absence of such
|
||
speclflcatlcns. by movlng at least one half of the c~ntalDer volume
|
||
through the system. A mInlmum pressure of i5 PSl shall be used for the
|
||
spray rlnse. Parathlon contalners shall be pr~tected agaIns~.~:cesslve
|
||
pressure .jurlng the contaIner rlnse operatlon. Meas\Hf~.sha'V.·~ taken
|
||
t·::> pre'lent the spr"!y rlnse procedure fr.)m caLs:ng ail J!n;rea.~e.ln
|
||
pre:;sure on the IDs:de of tl:e contalner wal':'s of mote tnan :. ~s.:..
|
||
Elther the operatDr of the closed system m~st ha'/e ~t-~·rt1ble..a~: the
|
||
tlme of operatl:n 3 compl",te set of W:-ltten Instr~ctlOO.3 fOf."f'pper
|
||
operatlon of the sys:em. c·r tne ce::-tlf led app;'lcatol"'~'~t ,:t>cu;nent In
|
||
·.n1tlng bef'Jre an :!Jeratcr uses che cl'::>sed s'!stem t:wt..the )p~rator
|
||
h'l.s been adeql,ately traIned In the pr)per operatlon cf the i;:!~!:oa'l\'
|
||
llUT InlUBlE elif]
|
||
•••• • ••••
|
||
|
||
•
|
||
•
|
||
11
|
||
INCIDENT REPORTING
|
||
A telephone notltlcation must be made lf mixing. loading. or use of a
|
||
product contalnlng parathion results in inadvertent or unexpected
|
||
human exposure to the product or liiness resulting from exposure to
|
||
the product. splll of the product, an investigatlon by Federal, State
|
||
or local authorltles of allegatlons lnvolving drift of the product, or
|
||
the deaths of blrds or other wildlife. The certified applicator or the
|
||
owner of the treated land must notlfy by telephone the Chlef.
|
||
Compliance Branch. Office of Compliance Monitoring, U.S. EPA. at 202-
|
||
260-33 7 5 wlthln seven days of becomlng aware of the lncldent.
|
||
GENERAL INFORMATION
|
||
Mix Paratjlon 4EC ln water to form an emulsion spray solution. To make
|
||
the spray Solutlon. flll the spray tank half full with water. agitate,
|
||
add the proper amount of Parathion 4EC and then fill the spray tank
|
||
witt water whlle still agitating. Continue to agitate during use.
|
||
Aircraft should apply the recommended amount of Parathion 4EC in not
|
||
less than 1 gallon of water per acre. Always use suff:clent water for
|
||
ade~uate coverage of the crop follage.
|
||
~her~ a dosage range :s glven, use the lower rate on small cr young
|
||
p:ants or wlth Ilght lnsect lnf3statlons. Use the hlg~er rat~ on
|
||
mat~r~ pla~ts or Wl:~ heavy Ins~c: lni~statlon.
|
||
Th~ lffioun: gl'/~~ tJ use are the 3mc~n~s of ?3rat~lon ~Z~ :0 apply per
|
||
acre per appllcat:cn. The hazard; and precautio~s for handllng
|
||
Parathion 4EC are equally appllcabl~ to it after d:lut:on With water
|
||
for spray applicatlon.
|
||
ALFALFA: For three-cornered alfa:fa hoppers. alfalfa caterpillars. and
|
||
spittlebugs. use ~pint per acre. Fer aphIds. alfa:fa weevll larvae
|
||
~nd adult weevlls. armyworms up to thlrd lnstar. clover leaf weevlls.
|
||
cll:nblng :utwcr~3. wetworms, grasshoppers. crlckets, s~ctt~d alfalfa
|
||
aphIds. leafhoppers. Lygus bugs. thrlps. and tortlc:d ~oths. use ~to
|
||
1 plnt pe: acre. Fe: alfali3 s~ed c~alc:ds centrel en a!falfa grcwn
|
||
for soeed. use 1ft. to 1 pint per acre. Callfornla and Ne"/ada regt.:latlons
|
||
:Iml~ the use of thls material to not mere than 3/4 pInt per acre. For
|
||
=lcver w~e~:ls. spljer mltes. blIster beetles. ASlatl= garden ~eetles.
|
||
sw~et clover weeVils. and green June beetles. use 1 pint per acre. For
|
||
teet armyworms anc corn earwor';lS use 1 to 1 '12. pint per '\cre. [:0 net
|
||
s~ray alfalfa durIng bleom rerled to avold lnJury to heney bees. Do
|
||
not apply wlthln 15 days of harvest. cuttIng or forage t.:se. Do not
|
||
aprly lf the srep or weeds ln tje treatment area are ln bloom. The
|
||
restrlcted-entry interval is 3 days.
|
||
CORN: Fo;:- centrol of European corn borers, use 1 plnt ~er a(i~·~~.APply
|
||
• • ••• •• • •• tne first spray when 75% ot the corn plants show sh~:- .~le fe~dlng and
|
||
i''Jllow With two additional sprays at 5 to 7 day inte=rva~s. !J~e •
|
||
sufflclent water per acre to provvle complete cever~t'"<Snd ~e.·o:~r,:ain
|
||
whorls of plants are woell treated. F·)[ corn leaf aphl~io" USQ 'j..nint - '"1 d 1 •••••• poer acre. r or t11 . ar:nyworms .:orn rc·otworm a u ts. ~!I!lo'"wcr:.ls up to
|
||
third lns':ar, -::11;r.D1WI cutworms. grClssnoppers and Ja.fa~.E!"s~ cee-tles.
|
||
use 3/~ pint per acre. To control stink bugs and spider mlt~~~·~se 1
|
||
plnt poer acre. ':'0 control corn ean/orm. use 1 plnt per acre ~'1M apply
|
||
to Silks as soon as they appear. Make 3 to 4 appllcatlons a~.~·to 3
|
||
day lntoervals as lnfestatlon warrants. Re-apply lmmedlately after
|
||
rain.
|
||
{ BESl AYlIUBffcOFl)
|
||
|
||
•
|
||
•
|
||
•
|
||
12
|
||
To control chinch bugs, use 1 'h,pint per acre. Do not apply within 12
|
||
days of harvest, cuttlng or forage use. The restricted-entry inlerval
|
||
lS 6 days.
|
||
CORN (Sweet): 1'e, contr·:)l fall armyworms, a~hlds and sllkflies. use 'b
|
||
plnt per acre. To control sap beetles and spider mi:es, use 1 pint per
|
||
acre. To control corn ear~orm apply to sllks as soon as they appear.
|
||
Make 3 to 4 applications at 2 to 3 day lntervals as infestation
|
||
warrants. Reapply immediately after ra:n. To control chinch bugs, use
|
||
1 In. pln t per acre. : f crop is intended for canning, consult your
|
||
cannery fleldmen prlor to applicatlon. Do not apply withln 12 days of
|
||
harvest. The restrlcted-entry interval is 6 days.
|
||
COTTON: To centrol aphids, mltes. cotton leaf~orms. cotten
|
||
f!eahoppers, garden webworms and thrlps, use + pint per acre. For
|
||
cabbage loopers. use 3/4 to l plnt per a~re. For boll weevlls and
|
||
sti~k bugs, use l to 1~ plnt per acre. For salt-marsh caterpillars,
|
||
use 1 to ~ plnts per acre. For bollworms. cottae leaf perforators,
|
||
Lyg~s bug3, fa:se chlach bugs, serpentl~e leaf m1ners and seuthern
|
||
garden leaihoppers. use 2 plnts per acre. Make f:rst appl1~at:on whe~
|
||
l~SeCt appear and repeat at 7 day intervals 1i required. I~ deslred,
|
||
:hlS f~rmtlllt:0~ may b~ c2mtlnEd Wlt~ ~ther !nSectlcld~E ~n a complete
|
||
,:c::cn Sp:3Y ;r0g~3m. Do nc: feed c~tton ~rash ~o da~ry an:mals or
|
||
a~l~als being r:nisned for s:aughter wlthln 15 jays or appl~:atlcn. JO
|
||
not har~est ~lthl~ 7 days after appl:cation. The restri:ted-entry
|
||
ln~erval 13 3 days.
|
||
8MALL GRA!NS '~heat. Barley): To con~rol arm?wcrms up to thlrd lnStar,
|
||
api1lds (:;reenbugz) and w1~ter t;'ra1n ml tes. use 'n. plnt per acre. For
|
||
tr.r:9s. use ¥Lto:) 3 4 pint per acra. For Say's pl"nt Dugs. use 3/4 r:nt
|
||
per acre. ?or b~ack g~ass bugs. s:lnk bugs. whlte splder mites.
|
||
leafho9gers. cllmtlng cut~or~s. grasshoppars and ~rQwn wtaat rnltes.
|
||
U5~ 1 p:~t per acre. ?or chin:h bugs. false chlnch but;'s and Banks
|
||
gr3.SS mltes. us-= l~t:l~t per acr'~. Do no: apply w:thln ~5 days of
|
||
jar~est. cuttlng. or forage use. The restrlcted-entry :nterval 15 3
|
||
daiS.
|
||
30RSHUH: 7c control sorghum mldge. apply at a rate of 1 to = plnts per
|
||
acre. ~ak2 2 3.?pi::at1cns 3 to 5 days apart wnen a~prox:mately 90' of
|
||
the heads nay! c:mple:ed emergej frcill t~e coot or not later than start
|
||
cf D:i.com.:.ng. For a;:nlds (9ree~bu<;:s) and mltes. use 'ir-p:nt per a·:r8.
|
||
For sorghum webworms. fall armyworms, armyworms up to thlrd lnstar and
|
||
cern earwcrms. use 3/4 to 1 plnt per acre. Leaf injury may occur on
|
||
some hybr:d varletles of sorghum. Spray a few rows a week o~~~ before •••••• •• ¥
|
||
boct:ng tc test e:fects cn pLmt.;;. Do n'Jt apply witlt.:.n:.t2 day~ of
|
||
har·/est. ·::utt:ng or ferage use. The restrlcted-entr'! lnrer-/a.L 10'5 3
|
||
day.:. •• : •• : ••••• :
|
||
• • •• •• 1/- ••••••
|
||
30YB~ANS: To con:ro: webwor~s. use nPlnt per acre. q~'~onttJl velvet
|
||
bean cat'3rplL.ar. green cloverworms. two-spotted ml~'.o1nd s:tnk bugs,
|
||
use 1 plnt per acre. To control corn ean/orms an:i fall army·~c.f~. use
|
||
1 tJ llL p:nt per ac~e. Do not apply wlth1n 20 days of harvest";·cutt1ng ~ ~ .... or rorage use. The restr1cted-entry lnterval 1S 3 days. ..:.
|
||
\ BUT ,"IUILE tift]
|
||
|
||
•
|
||
•
|
||
13
|
||
SUNFLOWERS: To control sunflower moth, use 1 to 2 pints per acre on a
|
||
schedule of 2 to 3 appl1cations at 5 day intervals. Hybr1d sunflowers
|
||
completely bloom in 12 to 15 days; thus the initial application should
|
||
be made when 10 - 20% of the plant have begun to flower and moths and
|
||
young larvae are present. Do not apply later than 30 days before
|
||
harvest. The restr1cted-entry interval is 3 days.
|
||
STORAGE AND DISPOSAL
|
||
DO NOT CONTAMINATE WATER, FOOD, OR FEED BY STORAGE OR DISPOSAL
|
||
3TORAGE: Store in a dry location away from children, an1mals, foods,
|
||
feeds, seeds, and other agricultural chemicals. Keep corrtainer closed
|
||
when not uS1ng. Do not allow water into container as th1s may cause
|
||
deter10ration of product. Personnel must wear the personal protective
|
||
equ1pment spec1fied for "ALL Other Handlers" Ilsted 1n the Hazards to
|
||
Humans section of this label when handl1ng open containers or cleaning
|
||
up sp1lls. Do not store under conditions where temperature may exceed
|
||
120xF or below 45xF. Keep storage area looked when not in use. In the
|
||
event of sp1llage or leakage, soak up material w1th absorbent clay,
|
||
s~nd, sawdust, or other absorbent mater1als wh1le wear1ng appropriate
|
||
protective equipment. Scrape up and d~spose of in accordance with
|
||
information glven under PESTICIDE rIS?OSAL. In case of fire or other
|
||
emergency. report at once by toll-free telephone to aOO-~21-9300.
|
||
DI3POSAL:
|
||
P~STICID~ DISPOSAL: Fastl0lde wastes are acutely nazardous. Improper
|
||
dIspcsal oI e:{cess pesticlde. sFray m:xt~re. or rlnsate 1S a v:olation
|
||
of Federal :aw. If these wastes cannot be d1sposed of by use according
|
||
to label instruct1ons, contact your State Pest1cide or Environmental
|
||
Control Agency or the Hazardous Waste representatlve at the nearest
|
||
EPA Reg10nal Office for gUIdance.
|
||
CONTAINER DISPOSAL: Metal Contalners - Tr1p:e r:nze (or equ1valent).
|
||
Then cfier fer recycling or recondltiOTIing, or puncture and dispose of
|
||
ln a sanItary :ana£1:1. or oy ot~er prccedures approved by s~ate and
|
||
ll:ca: author:tles .
|
||
WARRANTY - CONDITION OF SALE
|
||
OU? R2COMME:IDAT:ONS FOR USE of thIS product are based upon tests
|
||
belleved reliable. Follow directions carEfully. Timing and method of
|
||
"!::>r,ll··ati,)tl. ·".."U-,..,r and ~r<)p r:; 'ndl.tic:ls. mlxt:.lreS WIt.l I)ther
|
||
~hemicais no~ spec:flcally reccmmended. and cther influencIng Iactors
|
||
In the use of thiS product are ceyonc the control or the seller. Buyer
|
||
a3su~es 311 r:sks of use, storage and handl1ng of thls materIal not in
|
||
strlet accordance w1th d1rectlons gIven herewith.
|
||
In no case shall Drexel or the Seller be iiable for consequential.
|
||
speclal or indlrect damages resulting from the use or handl~tt'i·~f this
|
||
product when such use and/or ha::dling 1S r.ot in str!~~·:cccr·cf3.flce ',ollth
|
||
directlons given herewIth. The f:ngoH.g 15 a conditlkn· ~f sa).e Py
|
||
Drexel ChemIcal C.,m,:an·{ 3nd IS lc·::epted as such by t!Jo\:-·~uyet •.• ·.:
|
||
• • •• • • •••••• ".... . • • •• • •••••
|
||
t BUT AVAIlABLE con)
|
||
• •• •• • ••••
|
||
•••• • ••••
|
||
\
|
||
,
|
||
\
|