justin
a97107de46
Image rebuild (skip scrape) / build (push) Failing after 1h37m12s
Dockerfile: self-contained image with corpus + Chroma + BM25 baked in. Drawbar's compose pulls + runs without volume mounts. Built from sources.json (labels schema), PRODUCT_NAME=crop_chem by default, HYBRID_SEARCH=true (always-on for production quality). RERANK_URL + OLLAMA_URL get set at compose time. .gitea/workflows/refresh.yml: monthly cron (1st @ 06:00 UTC) does full scrape → reindex → image push. Scrapes Bayer (~30 min) + EPA PPLS row-crop filtered (~7h). Skips reindex+push if no corpus diff. Tags pushed: :latest, :<sha12>, :corpus-<YYYY.MM.DD>. .gitea/workflows/image-only.yml: on-demand or auto on code-only pushes to main (paths: docs_mcp/, rag/, scrape/, requirements.txt, Dockerfile, sources.json). Reindexes from committed corpus, builds image, pushes. ~10 min vs ~9h full refresh. .gitignore: corpus/ now COMMITTED (4,159 labels, 265 MB of .md + sidecars). Lets image-only.yml rebuild indexes without re-scraping. chroma/ + bm25/ still gitignored (regenerable binary indexes). .dockerignore: drops venv, eval results, PLAN/README/CLAUDE.md, deploy/, .git/ — keeps the image lean. corpus + chroma + bm25 explicitly NOT in dockerignore (those go INTO the image). Co-Authored-By: Claude Opus 4.7 (1M context) <noreply@anthropic.com>
305 lines
16 KiB
Markdown
305 lines
16 KiB
Markdown
# DIMETHOATE 267 SYSTEMIC INSECTICIDE
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- EPA Reg No: **279-2821**
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- Registrant: FMC CORPORATION
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- Signal word: Warning
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- Active ingredients: Dimethoate (30.5%)
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- Label accepted: 1992-11-23
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- Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/000279-02821-19921123.pdf
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---
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)
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)
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~~ .2.1'!- .tg'.;2\
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Code 3273
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Dimethoate 267
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Systemic Insecticide
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For Agricultural or Commercial Use Only
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EPA Reg. No. 279-2821 AA EPA Esl279-
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Active Ingredients: By Wt.
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·O,O·Dimethyl S-[(methylcarbamoyl)methyl)
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phosphorodithioate .............................. 30.5%
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Inert Ingredients: .................................. 69.5%
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'Oimethoale
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Contains 2.67 pounds Oimethoate per gallon.
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·Contains xylene range aromatic SOlvents.
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1000%
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193
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Net Cont'ents
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The buyer of Ihis malerial (including its ultimale user) is granled a li
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cense under U.S. Palent No. 3.210.242 limiled to !he use of !he within
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contents. A prepaid royally being included in !he selUng pIice a n0n
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transferable license under such palenl may be obtained trom !he palent
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owner on currenl royally lerms whalever lhe source 01 Dimelnoale used.
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PRECAUTIONARY STATEMENTS
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Hazards to Humans (and Domestic Animals)
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Warning
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Vapor harmful. Concenlrated material causes eye irrilalion. Avoid
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breathing vapor or spray misl. Use 0nIY.~ill)ecJ.equale ventilation. Avoid
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contacl wilh skin and eyes. Hm~A<iIil! if swallowed. Wash thor-
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KEEP OUT OF REACH OF CHIILDREN oughly after han;.),. a., '- ~"j)R ~eatirg.
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WARNING "iNVI~ON . N'· _ ' ~KB~/b "1//1. -lIb, II h,s pr~UCI .s t _!'if!!. ~!~pr~?J~ Ireated areas may be
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f"~ ~'I//''' . ,,~ ;_ led. Oflnol . __ J ;o.q{off by cleamng 01 eoUIPment or d.sposal
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'" c'/~ '.~ '~. '1P, ·.~'~i ,wasleS\ apply where runoff is ~kely te occur. 00 nol allCWlhis
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A \/IS II W~ 'M ':w.~ 'K@ ''!!!Ifi ~ 1~l)!IIlenal"iO' onlo neighboring crop or non-crop areas or use .n a
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. -, • ?iHWf/!" ~fI'-~ "'~%;b. ~ ;~III/1/A "J) rii'amer or al a lime olher than_ in accordance with lhe label direclions
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PRECAUCIOJt~ .. U;~.. ,;rSJo lee.) s.~·_\€;)! _e'!llb"- because ammal. planl or crop IOlul)' •• lIegai residues or other undeSlt-
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ducto hasta:~ Ii¥-tl - e.· S~~II· - . i"'illiamente. able results may occur. Apply lhis producl only as $peC.fied on this label.
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FIRST At@bh. '!WA~ ";~~'/I/IA - ~I/I' This produel is highly toxic to bees exposed to direcltreatment or resi-
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" ./;~ ;~ .,. dues on crops • .Restrict appllcation to the Period after dark when bees
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If in eyes. -".r.w.6}les with plenty of water for at least t5 minutes; get are .nside the hive or.n the eanr mornmg before.lhe bees are forag.ng
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medical anention. .n lhe f.elds. Protective IOformatlOn may be obIa.,ed from your Coop
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erat.ve Agncunural ExtenSIon Sennee.
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Antidote
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NOle To Physician: This product may cause cho~nesterase Inh.bition.
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Atropme is antidotal.
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For Emergency AssIstance Can 716-735-3765
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See O1her Panels fot Additional Precautionary Information
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- 'iJ-1
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-PMC.)
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FMC Corporation
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Agricultural Chemical Group
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Philadelphia PA 19103
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6-87
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CHEMICAL OR PHYSICAL HAZARDS
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Flammable! Keep away from heal and open flame.
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DIRECTIONS FOR USE
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II is a violalion 01 Federal law to use Ihis product in a manner .ncon
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sistenl with ilS labefing.
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00 nol apply Ih.s producl through any type of irrigalion system.
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00 nol apply this produel in such a manner as 10 directly or through
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drift expose workers or olher persons. The area being Ireated must be
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vacated by unprotected persons.
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00 nol enter trealed areas wiIhoul prolective clothing for 4 days.
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Protective clolhing means. at least. a hal or other suitable head cov·
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ering. a IonQ sleeved shirt and ~ legged lrousers or a coveral type
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garment (aiT ot ctoseIy woven fabric covering !he body. including the
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arms and legs). shOes and socks.
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Because certain slales may require more restrictive reentl)' intervals for
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~anous crOllS treated wilh this product. consult yOfoJ/t State Department
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ot Agriculture for further information.
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Wrinen Jr (l(aI warnings must be given 10 WOrker.. 'Who are expected 10
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be in a Ireated area or in an areo lhn·t '.0 be Irwl,..{""~ this product.
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fnform workers of areas or fields I.)al nta) J>oI be enter,:l without specifIC
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protective clothing. period of time 4ield m'ist be vacaled and appropriale
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actions 10 take in case 01 ~tal expOsure. An 'exampfe of SUCh
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i~tormation is given under written ·;.am·ngs. WherI bt'aI warningS are
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given. waming1 sha. be givl!f1 in a I.Jt19!Iage cuslomarity understood by
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workers. Oral warnings must 00 giye" r, there i!Z:"",sd1.IO belteve that
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written wamj~s cannot be und",sx..c!l by wor)(ers .• 'Nrinen warnings
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must include the following informat'?n: : •
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wl.fiNlNG ..,
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Area Ireated with Oimethoale 267 on (.nsert 1:1.:", 00 not enler
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without appropriate protective clothing 'Of 4 d.ys· (i~sert State
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Department of AgrICulture's re-entry Interval.:l~ mo.e,rpstncllve).
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In case 0' aCCidental exposure to pesticide ~ra.,.' '" dust. wash
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the skin thOroughly With soap and waler. Remove contaminated
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clomlng and wash before reuse. It In eyes. flush with plenty 0'
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waler. It Inhaled. go to an area where the pesticide has not been
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applied. Get me-cheal attention ., needed.
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'STORAGE AND DISPOSAL
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Pest,cide Storage
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Do not store betow 32 F. (O·C).
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Do nor use or store near heat. open lIame or hot surlaces.
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Keep out at reach at children and animals. Store In anginal con
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tainers only. Store In a cool. dry place and avoid excess heat.
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Carefully open containers. Aber partoat use. reptace hds and close
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tightly. 00 not put concentrate or dilute matenallnla food or drink
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containers. 00 not conlamenale other pestiCIdes. ferti.zers, waler.
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food. or feed by storage or disposat.
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In case 01 spill, avoid contact, isolate area and keep out animals
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and unprotected persons. Confine spills. Call FMC coItect: (716)
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735·3765.
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To ':onfine spilt: If liquid. dike surrounding area or absorb with
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sand. cattl\1er or commercial clay. If dry rroaterial. cover to pre·
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vent dispersal. Place darroaged package in a holding container.
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Identify contents.
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Pesticide Di, - osal
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Pesticide wa' _.as are acutely hazardous. Imr>roper disposal of
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excess pesticide. spray mixture, or rinsale is a violation of Fed
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eral law. If these wastes cannot be disposed of by use accordIng
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to label instructions, contact your State PestICide or EnViron
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mental Control Agency. or the Hazardous Waste representative
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at the nearest EPA Regional Office for gUIdance.
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Container Disposal
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,iple rinse (or equivalent). Then offer for recycling or reco~di-
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I
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bmng. or puncture and dispose of In a sanitary landfill. nr by
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other procedures approved by state and local authOrities. 00 not
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cui or weld melal containers.
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ENDANGERED SPECIES RESTRICTIONS
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The follOWing restnctlons apply to use oJf this prodlict after February 1.
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1988.
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Before uSing thiS pestiCide on wheat andlor cor.on In the counttes Itsted
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below. you must obtaIn the PESTICIDE USE BULLETIN FOR PRO·
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TECTION OF ENDANGERED SPECIES tor the county In which the
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product is to be used. The bulletin is available from your County Exten
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sion Agent. State Fish and Game Office. or your pestICide dealer. USE
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of this product In a manner inconsistent with the PESTICIDE USE
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BULLETIN FOR PROTECTION OF ENDANGERED SPECIES is a
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violallon of Federal laws.
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Alabama
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Colbert. Greene. Jackson. Lamar. Lauderdale. limestone. Madeson.
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Marshall. Morgan. Pickens and Sumter
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Arkansa.
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Clark. Clay. Cross. Lawrence. Lee. Poinsette. RandOlph. Sharp and
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ctl. FranCIS
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~rnJa
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ll1e. COlusa. Glenn. Kern. Merced. Sacramento. Solano. Sutter.
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Tehema and Yolo
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Florida
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Broward. Dade. Glades and Palm Beach
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Kentucky
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Ballard. Buller. Edmundson. Greer,. Hart. Jackson. Laurel. LIvingston.
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Marshall. McCracken. McCreary. Pulaski. Rockcaslle. Taylor. Warren
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and Wayne
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Mloslasippl
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Itawamba. Lowndes. Monroe and Noxubee
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North Carotina
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Edgecombe. Nash and Pin Tenne __
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Bedford. Blount. Claiborne. Decatur. Franldin. Hancock. Hardin.
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Hickman. Knox. Lincoln. Loudon. Marshal. Maury. Meigs. Monroe.
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Morgan. Rhea. Roane. Scan. Sequatchie. Smith. Sullivan and Wayne
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Virginia
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Lee. Russell. Scott. Smyth. Tazewell. Washington and Wise
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Required Clothing and Equipment for
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Application
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All applicators. including homE"owncrs. tlaggers and all personnel in
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volved With the mixing. loading. and transfernng operations must wear
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the protechve clothing and eqUipment enu!T' .... rated below. Pilots are
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exempt from thiS reqUIrement The protecllvl ~IJthmg and equipment
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to be worn IS as follOWS
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a. Impermeable gloves (for example. rubber or plastiC covered rein-
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forced gloves).
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b Boots or boot covers
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c long· sleeved shirt and long pants.
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d Wide-bummed hat.
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e ResPl~ators must be worn by Ilaggers and miller loaders
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Aerial Application
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When applYing by air. automatic flagging deVices shOuld be used when
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ever feaSible. If human flaggers are employed. they must wear the
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protective clothing and respirator speclhed on thiS labe!
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ThiS product is Intended for use by the c:)mmerclal grower or commer·
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clal appbcator In conventional hydmuhc sprayers. ground applicators or
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airplane sprayers. When applytng by 9fOund eQUIpmen~. use fecom
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me',ded amount In suHic;ent wa:€r tor thorou0h coverage. by aircraft
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equipment, In 2 to 10 galtons of water. Rep€'3t ~pphr::atloflS as r.ecess3ry
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unless otherwise speCified Consult your State Experrment Siatloo or
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State Extenston Service lor proper timing 01 appltC3ti~n. Oose:ve days
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Interval between )ast apphcation and harvest Ind!cated by m;mber ....
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( ) following the crop.
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58 I 01 .f C bbaps 113 dlld 8abbsQe L r m 'bg [-'-5 Sf Di~
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~;;:08:·:~Ji;!:~) ::e.:e:ttt~~7:t2::ie ISt;:. 8; ng:-
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Swiss Chard T"mip5 I' j lctiSCe.I.ICIO.IS. Pcos. F~¢p ~ Rnt?'?8S.
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Tomatoes -cd "'E'E Ell Pi IE be sssj· eo t 613 n en~p
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s'''iI m I et· For pn,.t' &ecu:50llet Ii::Ir II & '~'·I'9r'S d;~CCk
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-. Alla"a (grown lor hay): Aphids. Leafhoppers. Lygus Bugs. Gra>shop
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pars. reduction of Alfalfa Weevil Larvae--4:' to l'/Z pints per acre. Do
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not apply to alfalfa In the bloom ponod. Do not apply w'th,n 10 days of
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harvest or pasturing, Make only one application per season, EHectlve
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only on cullmg to whIch applied.
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A"a"a (grown for seed}: Aphids. Leafhoppers. Lygus B"gs. GrESS
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hoppers. reduction of Alfalfa Weevil larvae-- J " to , ',. pr:'-.ts pe-r acre.
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Do not apply to alfalfa dur.ng breom perrod. Do net fe&.j or graze live
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stock on treated crops. hay or s!ubb~e wlth,n 10 days of a~p'J~at:~~
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Apples (28). Pears (28): AphIds. Leafhoppers. M"es (:xc~Pt Rust M'loL
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Use 3,:' to 11/z pints per 100 gallo!1s of water. 0::.. no! a~j)j~· dunng tne
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bloom period. Do not allow livestock. to graze In !rt:ateo vrcnarlis.
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Be3n" (Green. Lima, Snap. Dry) (0): Aphids. Lea!tc ~p€'rs. LeG-fml'
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ners. ·_ygus Bugs. tJlies-Li~e):" '0 ,',;,> p'ots oer acre. Beans rnav be
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harvestec! on day of applicauon. Do not ieed treated Vln&s to r:vestOCK
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Broccoli (7). Cauliflower (7): Aphids-Use ~, to 1',;, pints per a.:re
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Cabbage (7): Aphids-Use ~/" to l"z ,-,,,nts per acr!:.
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Cauliflower: See Broccoli
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Collards (14). Endive (Esc.rol_) (14). Kal. ('4}. LeEf Letluce (14}.
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Must.rd Greens (14). Spinach (I'}. Swiss Chard (14}. Turnips (tops
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~~ .-oats) (14): Aphids. Leafhopperz. leafmmers-Use .; .. pints per
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~~re.
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C.,ttor, (Early Season) (14): AphIds. Fleahoppe,s. Miles. Thrips-Use
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'13 :0 ¥. pint per acre. Do not repeat apphcattOns Within 14 days. Do not
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feed Ireated forage or graze livestock on treated f,elds.
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Cotton (grown in Calif. and Arizona} (14): Black Fleahoppers. lygus
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BU9s. le~f~rs-Use 3,:. to 11/2 pints per acre. Do not repeat apph~
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catrons Within 14 days. At thp. hIgher rate make only two applications
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per season. Do not feed treated iorage or graze livestock on treated
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fields.
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Endive (Esc.role): See Collards.
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Lemons .nd Oranges: Do not apply durmg bloom perIOd. Do not use
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on ,cItruS seedhngs. Make no more than two (2} applications to mature
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fruli. Do no! enter groves WIthin 4 days of last applicatIOn.
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Aphids-Oo not apply withIn 15 days of harvest-Aircraft Equipment:
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Use 3 to 6 pints per acre in 15 to 20 gallons 01 water.-Ground Equip·
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ment: Use v.to 1 'h pints per 100 gallons of water. Apply as an outside
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coverage spray. MItes (except Rust Mitesl-Do no! apply within t 5 day,
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of harvest--Gtound Equipmenl: Use V. to 1 V. ponts per 100 gallons 01
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water. ArlI>IY as a thorough distribution coverage spray. ScaleS (except
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Slack or Snowl-Do not apply within 45 days of harv'!st--Ground
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Equipment: Use 1 V. to 2V. pints per 100 gallons of wat~r. ";>ply as a
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thorough Cf'YeI'age spray. Thripr-Do noo'dr-JoI)'wilhin 15 daY'o·.lf har
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vest-Ai",,./! Equipment: Use 3 to 6 pont; pe,.arie In 15 to ?O gallons
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of water--Ground Equipment: Use V. to '1 'I> pir.1s per 100 qallons of
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water. Whiteflies-Do not apply w,th,n 1.~. 1'· ... of harve,t-Ground
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Equipment: Use t V. pints per 100 gallons of .. aie.'. Apply as a thorough
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distnbution coverage spray. Do not allow live,l%k to grl1e '". treated
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orchards. " .
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Kale: See Collards
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Head Lettuce ('T): Aphids. Leafhoppers. L~af;";,"ers-U3e ~. ~Inl ;;er
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acre. ' . •
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Leaf Lettuce: See Collards
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Melons (3). eJ:cept Watermelons: AphIdS. leafhopper:;. lc 3'mlners.
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Thrrps-Use 111" pints per acre. Watermelons only (3): AphIds, leaf
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hoppers. leafmlners-U5e v ... '0 "';0 PInts per acre
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Must.rd Green.: See Collards
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Oranges: See Lemons , lEST AYAILAIL[ can
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-.. _-- ,.,
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)
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)
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Pears: See Apples
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Peas (0): Aphids-Use 'f, pint per acre. Peas mal' be harvested on day
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of application. 00 not feed or graze hay within 21 days after last appli
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cation when a staftonary viner IS USed. 00 nol feeJ or graze when a
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mobile viner is used. Only 1 appltcalion per season permitted.
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Pecans (21): Aphi"s. Lealhoppers. Mites-Use In grou~d equipment
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only at lhe rale of 1 pint per acre. 00 not graze 'vestock In Irealed
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groves.
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Peppers (0): Aphids. Lealmlners. Maggols-US~ 'f. to 1 pint per acre.
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Peppers may be harvested on day of application.
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Potatoes (0): Aphids. Lcalminers. Lealhoppers-Use 11.10 1 'I, oints per
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acre. May be harvested on day of applicatiOn.
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SplnKh: See Collards
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Swiss Chlll'd: See Collards
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TobKco (21): Aphids-Use 11. to 1 pint per acre.
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Tomatoes (7): Aphids. Leafhoppers. Lealminers-Use ¥. to 1 Yo pints
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per acre.
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Turnips: See Collards
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Wheat (Grown in Texas. Oklahoma anI! Kansas): Aphids (Green·
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bug)-Use ¥. 10 1 pont per acre. Brown Wheat Mil..-Use 'h to ~, pint
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per acre. 00 not apply within 14 d.ys of grazing immature plant. 00 not
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harvest grain within 60 days 01 last ~pplieation. ;)nly 2 applications per
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season permitted.
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Dealers Should Sell in Original Packages Only.
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Terms of Sate or Use: On purchase of this product buyer and user
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agree to the follOWing conditions:
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Warranty: FMC makes no warranry, expressed or implied. concernlllQ
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the use 01 this product other than Indicated on the 12bet. Except as S<l
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warranted. the product is sold as is. Buyer and user assume all nsk of
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use andior handling and. or storage of this matenal when such use and:
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or handling and.'or storage is contrary to label Instructions.
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Directions and Recommendations: Follow directions carefully. TIming
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and method of applicatIon. weather and crop condItions. mixture with
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other chemicals not specdically recommended and other inlluencing
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factors in the use of thiS product are beyond the control of the seller
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and are assumed by the buyer at his own risk.
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Use of Product: FMC's recommendatIons for the use of this product
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are based upon tests believed to be reliable. The use of ,hiS product
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being beyond the control 01 the manulacturer. no guarantee. expressed
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or Implied. IS made as to the eHects of such or the results to be obtained
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If not used in accordance With directions or established safe practIce
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Damages: Buyer's or user's exclusive remedy for damages for breach
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at warranty or negligence shall be lirrNted to direct damages not g]l:
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c.eding the purchase price paid and shall not Include incidental or con
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sequential damages.
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4MC-FMC Tradema'~ (3273-687\
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