justin
a97107de46
Image rebuild (skip scrape) / build (push) Failing after 1h37m12s
Dockerfile: self-contained image with corpus + Chroma + BM25 baked in. Drawbar's compose pulls + runs without volume mounts. Built from sources.json (labels schema), PRODUCT_NAME=crop_chem by default, HYBRID_SEARCH=true (always-on for production quality). RERANK_URL + OLLAMA_URL get set at compose time. .gitea/workflows/refresh.yml: monthly cron (1st @ 06:00 UTC) does full scrape → reindex → image push. Scrapes Bayer (~30 min) + EPA PPLS row-crop filtered (~7h). Skips reindex+push if no corpus diff. Tags pushed: :latest, :<sha12>, :corpus-<YYYY.MM.DD>. .gitea/workflows/image-only.yml: on-demand or auto on code-only pushes to main (paths: docs_mcp/, rag/, scrape/, requirements.txt, Dockerfile, sources.json). Reindexes from committed corpus, builds image, pushes. ~10 min vs ~9h full refresh. .gitignore: corpus/ now COMMITTED (4,159 labels, 265 MB of .md + sidecars). Lets image-only.yml rebuild indexes without re-scraping. chroma/ + bm25/ still gitignored (regenerable binary indexes). .dockerignore: drops venv, eval results, PLAN/README/CLAUDE.md, deploy/, .git/ — keeps the image lean. corpus + chroma + bm25 explicitly NOT in dockerignore (those go INTO the image). Co-Authored-By: Claude Opus 4.7 (1M context) <noreply@anthropic.com>
344 lines
12 KiB
Markdown
344 lines
12 KiB
Markdown
# PYDRIN 4 INSECTICIDE ULV CONCENTRATE
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- EPA Reg No: **352-496**
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- Registrant: CORTEVA AGRISCIENCE, LLC
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- Signal word: Caution
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- Active ingredients: Fenvalerate (47.9%)
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- Label accepted: 1984-11-15
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- Source PDF: https://www3.epa.gov/pesticides/chem_search/ppls/000201-00417-19841115.pdf
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---
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U.S. ENVIRONMENTAL PROTECTION AGENCY
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OFFICE OF PESTICIDES PROGRAMS
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REGISTRATION DIVISION (WH-.561>
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W .... HINGTON.D.CZ'O
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HOTICE OF f'c' ~.CIDE: .,.,n"AT'ON o III:~A£Ci'ITR"'TION
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r
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L
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(UndC"r the Federal Insecticide, Fun,icide.
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and Rodenticide Act, •. ; .mended)
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Shell. Oil C~pany
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1025 Connecticut Ave., NW.
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Washinqton, DC 20036
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201-417
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Pydrin 4 Insecticide tJLV Concentrate
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.J
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TEl ,Cbanpa In labeU.QI rormula dillerlnc in aubel_nee from that accepted in cormecUoa with thla re.tau.UOD lD~t be
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aubmitled to and accepted b, the Re"tatraUoa Dlv1aion. p-ior to \IS. 01 tt. label in commerce. In any correapoodence on t!::~1
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product a ••• ,. refer 1'1 the .boYe U.S. EPA rea:iat,..Uoa Dumber.
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copy of the labelin& accepled in cuaDec\loo with thla RecilltraUon!Re,..,iatnUon ia returned herewith,
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14I~"iUo;lrI't1C)n.ia In I)() "ay to be cOMtrued •• an !adoraement or apprOOlal d. thie product by thia Al(eftCy, In ord.r to protect
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• ... 'u" •• Dd th.:- .Dvironmeat. the Adllliniatrator, on hie lDotloa, mil,. .t .ny time auspend or cancel the reciAtnlUon or • peat.
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lie-ide in accord.DCe with the Act. ThP. .ccept,nce 01. anJ', aame In connecUon with the reliab-.Uon or. p'oduct under thta
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~A('t t.. not to be C'otlliuued •• elvin, tb" relwtrant a richt to •• elusive uae of the name 011 to it. u.~ if it bit. been Co¥el"'8d
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~by oth@ra.
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; This ~Oduct t. conditionally regi.tered in accordance with FIYRA Bec •
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.3(c)(7)(A) PE'ovidll4 that you.
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1.
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f your
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an<Vor cite all data required for regia'ration/rerelJietration
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W\4.r FITRA .ee. J,t c) (5) wban thf! Aq.-ncy requirea all
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'I Ii,,, cri ol1:ranY 01' .taUer product. to .w.it nch data. f
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• ,
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SUbmit an acute inhalation .tudy on this formulation by Decembar 31,
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3. Make the labeling change. liwted below betor~ you relea.e the
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Ihrc"ld,lCi:"· for .hipMnt t
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a. Add the phra.e "EPA Regiatration No. 20~17 ••
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b. Delete tr~ the tront panel precautionary labeling the
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following.
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May be irritating to akin, eyea, noa. and throat.
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Cauaes ""'erate eye injury. Harmful it a"lallow..d.
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insert inatead the follO¥ing'
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~e pr~cftutionary ~t.tpmenta on Aide panel.
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o ATTAt,.;HYI!NT IS APPLICABLI!
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0,. A~~"O"IHG
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".., •• 1,.IS.D UNTIL 'U~~LY'I RkHAUIT.D.
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I
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:
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I
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tC
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I
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.
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'. ,
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....
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"-.'
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., ,
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"
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-2-
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c. Delete the atat •• at (See .&Siti __ l ...-atlC!II8rY atat_a ..
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aUa ...-1).
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4. ioIdcJ the tolh.s., ata~t tit tIM ~ to. eM ca.ati ••
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&_lel 11th-latta..
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J. 8aMdt fh. {St oopl .. of ,.,. fPal pdate4 l.ab.1J.a9 bet •• 1'W
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"lea- tM IRG II t foIr aIat .... ~ ~ tiD ~ ... ,. -.clue •• f •• f. tIw.
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II .. dptl_ rIC fJaal JC1IIted "bell.,.
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U t-. Utt_ an .. C £U .. 1I1tll. tM ngUtnti_ will be
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""MIt to .. DdladAa Sa un .... 1 WStt. nna _ •• Cat. ~ nlaue ~
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...... ~ of tile a-04wt a ,titat. eo.ptaoa of tts c ,ttl_.
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I
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~tIJ)t a. CU4aU
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... trt .al, I (t7)
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J> .. ~cSiII a cS..Uo1de 1IIr.-ia
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...,..trau_ DiY1.1_ (ft.'H7)
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-_.
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t ,
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1
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·1
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1
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(
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.J or '1
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REST~Ir:TED USE PESTICIDE
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For retait sate to and use onty by Certifier< Appli·
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cators or ~erson' under their direct supervision and
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only for those covered by the Certified Applicator's
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certification.
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Shell ULV Concentrate
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EPA Reg. No. 201-
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EPA Est. No.
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This Product Contains 4 lbs of PYDRIN Per Gallon.
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ACTIVE INGREDIENT BY WEIGHT
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fenvalerate: Cyano (3-phenoxyphenyl) methyl'
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4-chloro-alpha-(1-methylethyl)
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benzeneacetate ............... " ..... , ..... " .. , 47.9%
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INERT INGREDIENTS ................................ 52.1%
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KEEP OUT OF REACH OF CHILDREN
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CAUTION
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TOTAL 100.0%
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Shell
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__ tau
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NOV151984
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fJtIIM It.. JI\~ ~
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~. .,,<1 :~nn,..;l, ,\<"t
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........ Ill.... ~ lbfW ~FAt"jc1.ot'
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"I . &MIl ttTldw~ ttJll\ IfWt ~
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2.~/-4.f17
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May be irritating to skin, ey~s, nose and throat. Causes moderate eye injury.
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Harmful if swallowed.
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STATEMENT OF PRACTICAL TREATMENT
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IF SWALLOWED, do not induce vomiting. Call a physician. Gastric lavag<! .s~,oulct:'·:·:
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be supervised by a physician or the professional staff because of thepo~~ible ......
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pulmonary damage via aspiration of the solvent. • •••
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IF ON SKIN, wash with plenty of soap anc water. Get medical attention if ..... • irritation persists. • ••••
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IF IN EYES, flush with plenty of water. Get medical attention if irr ihtion •
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persist~. ..: •. :
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(See additional pre~autionary statements on side panel.)
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CD8404102
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....... • • .. .,
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(
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PRECAUTIL~ARY STATEMENTS
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~AZARDS TO HUMANS - CAUTION
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Ca.:<es moderate eye injury. Wear goggles while handling. Can cause irritation
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to sk'n such as burning and tingling. Do not get in eyes, on skin, or on
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clothing. Wear protective gloves while handling. Harmful if swallowed or
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absorbed through skin. Wash thoroughly with plenty of soa!> and water after
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handling. Remove and wash clothing before reuse.
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For 24-hour emergency assistance, call (713) 473-9461.
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ENVIRONMENTAL HAZARDS
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This pesticide is extremely toxic to fish. Use with care when applying in areas
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adjacent to any body of water. Do not apply di rect ly to water. Do not apply
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when weather conditions favor drift from treated areas. Do not contaminate water
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by cleaning of equipment or disposal of waste~. Apply this product only as
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specified on this label.
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WILDLIFE PROTECTION IS EVERYONE'S RESPONSIBILITY
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Thi s product is hi gh ly ,toxi c to bees exposed to di rect treatment on b 1 oomi ng
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crops or weeds. Do not apply PYDR:;:N or allow it to drift to blooming crons or
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weeds whil e bees are actively· vi s it i ng the treatment area. Add; tiona 1
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information may be obtained by consulting your Cooperative Extension Service.
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DIRECTIO~S FOR USE
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It is a violation of Federal Law to use this ~roduct in a manner inconsistent
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with the labeling.
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RE-ENTRY STATEMENT
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Do not apply th's product in such a manner as to directly or through drift expose
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( workers or other persons. The area being treated must be vdcctpd by unprotected
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persons.
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Do not enter treated areas without protective clothing until sprays have dried.
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Because certain states may require more restrictive
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crops treated with this prodlJct, consult your State
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further information.
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reentry intervals for various
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Department 0f Agriculture for
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. ..... . "
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Written or oral warnings must be given to workers who are expected to 'be'~n a ......
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treated area or in an area about to be treated with this product. (In!:licate ••
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specific oral warnings which inform workers of areas of fieids that may not be •• ; •. ,
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entered without specific protective clothing, period of time field. mu~t be .. ' ..
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vacated and appropriate actions to take in case of accidental exposur~:}"When
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oral warnings are given, warnings shall be given in a language custoVlarily";";
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understood by workers. Oral warnings must be g'ven if there is reason to.beJieve "
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that written · ... arnings cannot be understood by workers. Written warni'ngs.must::;:::
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include the following information: "CAUTI()N' Area treated with PYD:~}/I on
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.ldate of application). Dc not enter without appropriate protective '(~uthing
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unti 1 sprays have dried. (Insert here action to take in caoe of accldental
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exposure. See front panel 5:TATEf'lENT OF PRACTICAL TREATMENT for detai ls.)"
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(
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(
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STORAbE AND DISPOSAL
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STORAGE: Store in a secure, dry and temperate area. Keep container closed when
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not in use. Do not store near food or feed. Do not use or store around the
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home. Avoid contact with water. In case of spill or leak, soak up with sand,
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earth or synthetic absorbent (do not use soda ash or other alkaline absorbent)
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and dispose of wastes in compliance with Pesticide Disposal instructions given
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below.
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PESTICIDE DISPOSAL: Pe ,ticide wastes are toxic. Improper dispC'sal of excess
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pesticide, spray mixture, or rinsate is a violation of Federal Law, If these
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wastes cannot be disposed of by use according to label instructions, contact your
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State Pesticide or Environmental Control Agency, or the Hazardous Waste
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representative at the nearest EPA Regional Office for guidance.
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CONTAINER DISPOSAL: Triple rinse (or equivalent), Then offer for recycling or
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recol,ditioning if container reuse is permitted. If container reuse is
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prohibited, puncture metal containers and dispose of in a sanitary landfill, or
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by other approved State and local procedures. Dispose of plastic containers in a
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sanitary landfill, or by incineration if allowed by State and local authorities,
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Dispose of glass containers in a sanitary landfill, or by (1ther approved State
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and local procedures.
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In case of significant spill, call (713) 473-9461 or CHEMTREC (800) 424-9300.
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GENERAL DIRECTIONS
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PYDRIN® 4 Insecticide ULV Concentrate contains 4 pounds of active ingredient per
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gallon. This product is intended for use as an ultra-low volume spray in once
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refined vegetable oil. Do Not Attempt To Mix With Water. Mix the required
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amount of PYDRIN 4 in vegetable 0;1 as directed irllthe specific use instruction
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for each crop. Do not plant root crops other than potatoes within 12 months
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after the last application. Potatoes and all other rotational crops may be
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planted immediately following the last application.
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CROP
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Cotton
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----
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Field C()r-n
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I INSECT
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Pink Bollworm
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Cotton Leaf
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Perforator
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I Cotton Bollworm,
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I Tobacco Budworms.
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1 Lygus Bugs,
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Cabbage Looper,
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Beet Armyworm,
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Bo 11 Weevil,
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Wh i tefly"
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"Aids in Suppress
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----- ---- ---
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Cutworm
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Grasshoppers
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·\.''!steFri Bean
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- - ~lKw~rm
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DOSAGE
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LB AI!
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A~RE
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0.05-0.1
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0.10
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0.10-0.20
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I
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·on
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.--~-
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1 0. 1- 0. 2
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I
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0.05-0.1
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COTTON
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NUMBER ACRES
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FLozl TREAIED WITH
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ACRE GALLON
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1. 6-3. 2 80-40
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3.2 40
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3.2-6.4
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40-20 ,
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.-
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3.2-6.4 40-20
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1. 6- 3.2 80-40
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FURTtJER USE
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INSTRUCTIONS
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In nonvolatile once
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refined vegetable 01
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apply a total spray
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volume of one or mOl
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quarts/acre. Repeal
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necessary throughoul
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season to maintain
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contro l. Apply no n
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than 2 lbs/ai to a (
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in a growing season.
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For the r.ontrol of
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Boll Weevil, a 3-5 (
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i nterva 1 between
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sprays may be requil
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Do not feed or grazl
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livestock on treate(
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trash.
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Apply in nonvolatill
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refined vegetable 0-
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in a total spray vo
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of 1 or more quarts,
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Repeat as necessary
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to maintain control
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Do not exceed 1.0 11
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a.i. per acre per
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season. See addit il
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instructions for Oti
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insects.
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Apply as necessary
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maintain control.
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plication must be m
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before larvae enter
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the ear.
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JJOSAGE NUMBER ACRES CROP IHSECT LB All FL Oll TREATED WITH FURTHER USE DAYS TO ACRE ACRE GALLON INSTRUC.I IONS HARVEST
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Field Corn C0rn Earworm 0.1-0.2 3.2-6.4 40-20 First application
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should be at or before
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s ilk i ng. Subsequent
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applications should be
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made at 3-5 day inter-
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va 1 s until silking is
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, completed. Repeat ap-
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plications may be applied
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I
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if economically damaging
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populations exist.
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rstal k Borer 0.1-0.2 3.2-6.4 40-20 Application must be
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made early in migration
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from grassy areas to
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corn, before borers enter
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the plant. More than
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one application may be
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necessary.
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--Corn Rootworm 0.1-0.2 3.2-5.4 40-20 Spray at first sign of
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(adult control) silk feeding. Reinfestation
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may occur. Should rein-
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festation occur, repeat
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as necessary to maintain
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control.
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Southwestern
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Corn Borer 0.1-0.2 3.2-6.4 40-20 Apply as necessary to
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I
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maintain control. Two or
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more applications may be
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... requi red. Higher rates .
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(0.15-0.2 lb . a.i.) are . . .
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. .. recommended for moderate to .
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heavy populations.
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----r--------~---OOS .. G .. E-----.-rnNU"'MOnB"'ER"....AC;;;R .. E"'S----------,----"-----"-
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I.B p.T7~ ='r"', ~--"-oz""7r- TREATED WITH "URTfiER USE DAYS TU CROP INSECT
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ACRE ACRE_-+ ___ G::::A-'-'L:..:L:.::.O:..:.N _____ ---=.I:..:.N:.:..ST:B!_JCT.Iij~"~ __________ " !iA~iL?'J
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Fiela Corn Armyworm 0.1-0.2 3.2-6.4
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(True Armyworm)
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40-20 Apply as necessary tn
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maintain control.
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;:oa les oy ;:O'le II Lnemlca I Lompany OT prooucts contalnlng tne aCtlve lngreOlenl. are
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made under agreements with Sumitomo Chemical Company, Ltd.
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Shell Cher,ical ComlJdny
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A Division of Shell Oil Company
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P.O. Box 3871
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Houston, Texas 77001
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NOVI51384
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[Jt.t1f"- • lot., or, .... " ~" !~ "'l ,-tJ.,
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"",,_1 I( .tt :J-1C-fl'}I.,.-+, '"
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.. II;rl>, ''';'1''1 -," d,t- "'':(,'1" ~
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...... tt.,'U IJT,U,;,r Et-'.\ RJ)"j.' ~,
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20/--¥/7
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